Trends in Chemistry

Article	Citations
Challenges of Z-scheme photocatalytic mechanisms	189
Mechanochemical Cross-Coupling Reactions	156
Rational design of oxygen evolution reaction catalysts for seawater electrolysis	127
Carbon dots: mysterious past, vibrant present, and expansive future	118
Emerging frontiers of Z-scheme photocatalytic systems	116
Wearable Triboelectric Nanogenerators for Therapeutics	113
Mitigating ion migration in perovskite solar cells	100
Metal complexes for therapeutic applications	92
Ready, Set, Flow! Automated Continuous Synthesis and Optimization	87
Upscaling Mechanochemistry: Challenges and Opportunities for Sustainable Industry	86
Molecular Electrochemical Reduction of CO2 beyond Two Electrons	84
All sp2 carbon covalent organic frameworks	84
Toward Machine Learning-Enhanced High-Throughput Experimentation	82
Facing the capacity fading of vanadium-based zinc-ion batteries	81
Carbon-based catalyst supports for oxygen reduction in proton-exchange membrane fuel cells	80
Tailoring Light with Layered and Moiré Metasurfaces	79
Single-electron carbene catalysis in redox processes	78
Progress in halide-perovskite nanocrystals with near-unity photoluminescence quantum yield	74
The renaissance of polythiophene organic solar cells	71
High-efficiency thermocells driven by thermo-electrochemical processes	68
Defining and Exploring Chemical Spaces	67
Quantum Mechanical Tunneling Is Essential to Understanding Chemical Reactivity	67
Structural design and determination of 3D covalent organic frameworks	66
Carrier Dynamics and Evaluation of Lasing Actions in Halide Perovskites	66
Electrochemical C–N Bond Formation for Sustainable Amine Synthesis	64

Palladium-catalyzed enantioselective C–H functionalization via C–H palladation	63
H/F substitution for advanced molecular ferroelectrics	62
Accelerating Redox Kinetics of Lithium-Sulfur Batteries	52
Transition-Metal-Catalyzed Hydroaminocarbonylations of Alkenes and Alkynes	52
Triboelectric nanogenerators for self-powered drug delivery	51
Design Concepts for N-Heterocyclic Carbene Ligands	51
Laser-engraved graphene for flexible and wearable electronics	50
Advances in N-centered intermediates by energy transfer photocatalysis	50
Navigating through the Maze of Homogeneous Catalyst Design with Machine Learning	48
Ferroelectricity and Rashba effect in 2D organic–inorganic hybrid perovskites	48
From Macro- to Nanoscale: Finite Size Effects on Metal–Organic Framework Switchability	48
Designing Dynamic Materials from Dynamic Bonds to Macromolecular Architecture	47
Metal–Organic Frameworks and Water: ‘From Old Enemies to Friends’?	47
Electroactive covalent organic frameworks: a new choice for organic electronics	46
Molecular dimensionality and photoluminescence of hybrid metal halides	45
Single-atom M–N–C catalysts for oxygen reduction electrocatalysis	44
Electrolytes for high-voltage lithium batteries	44
Chemist versus Machine: Traditional Knowledge versus Machine Learning Techniques	44
A new carbon allotrope: graphdiyne	43
New reaction pathways by integrating chemo- and biocatalysis	43
Development of Second Near-Infrared Photoacoustic Imaging Agents	43
Solar-driven catalytic plastic upcycling	42
Metrics for Benchmarking and Uncertainty Quantification: Quality, Applicability, and Best Practices for Machine Learning in Chemistry	41
Emerging biomimetic nanotechnology in orthopedic diseases: progress, challenges, and opportunities	41
Anion-conducting polyelectrolytes for energy devices	40
‘Catalyst + X’ strategies for transition metal-catalyzed olefin-polar monomer copolymerization	39
Controlling X-ray-activated persistent luminescence for emerging applications	38
2D Material Bubbles: Fabrication, Characterization, and Applications	38
Structurally anisotropic hydrogels for tissue engineering	37
Water–active site interactions in zeolites and their relevance in catalysis	37
Single-atom heterogeneous catalysts for sustainable organic synthesis	37
Implications of Na-ion solvation on Na anode–electrolyte interphase	37
Highly reductive photocatalytic systems in organic synthesis	37
Developments in Photoredox-Mediated Alkylation for DNA-Encoded Libraries	36
Silver N-heterocyclic carbenes: emerging powerful catalysts	36
New trends in nonconventional carbon dot synthesis	36
Recent advances towards organocatalytic enantioselective desymmetrizing reactions	36
Emerging trends in sustainable battery chemistries	36
Development and applications of selective hydroesterification reactions	35
Competitive Solid-Electrolyte Interphase Formation on Working Lithium Anodes	35
Towards modeling spatiotemporal processes in metal–organic frameworks	35
Bioorthogonal catalysis for biomedical applications	33
The catalytic cycle of cytochrome P450: a fascinating choreography	33
Macrocycles and Related Hosts as Supramolecular Antidotes	33
Electron–orbital–lattice interactions in hollow multishelled structures	31
Photochemical upcycling of polystyrene plastics	31
Electrochemical Reduction of CO2 Using Group VII Metal Catalysts	30
Designing radical chemistry by visible light-promoted homolysis	30
Synthesis of Large-Area Single-Crystal Graphene	30
Electrically conductive 2D covalent organic frameworks	30

Establishing a unified framework for ion solvation and transport in liquid and solid electrolytes	29
Emerging trends in C(sp3)–H borylation	28
Macromolecular Topology Engineering	28
Computational enzyme redesign: large jumps in function	28
Nanoparticle Phototherapy in the Era of Cancer Immunotherapy	27
The temptation from homogeneous linear catechyl lignin	27
Oligothiophene-based photovoltaic materials for organic solar cells: rise, plateau, and revival	26
Titania-Based Micro/Nanomotors: Design Principles, Biomimetic Collective Behavior, and Applications	26
Dehydroalanine modification sees the light: a photochemical conjugate addition strategy	26
Exterior decorating: Lewis acid secondary coordination spheres for cooperative reactivity	26
Euclidean Symmetry and Equivariance in Machine Learning	25
Single sites in heterogeneous catalysts: separating myth from reality	25
Electrochemical nitrogen reduction: an intriguing but challenging quest	25
Asymmetric catalysis with chiral cyclopentadienyl complexes to access privileged scaffolds	24
When machine learning meets molecular synthesis	24
Design and structural engineering of single-atomic-site catalysts for acidic oxygen reduction reaction	24
Solvent-driven aqueous separations for hypersaline brine concentration and resource recovery	24
Cross-dehydrogenative coupling of unactivated alkanes	24
Materials chemistry-enabled platforms in detecting sexually transmitted infections: progress towards point-of-care tests	24
Extraction of mechanical work from stimuli-responsive molecular systems and materials	23
MXenes: promising 2D memristor materials for neuromorphic computing components	23
Carbon-based nanostructures for emerging photocatalysis: CO2 reduction, N2 fixation, and organic conversion	23
Autonomous flow reactors for discovery and invention	23
Symmetry breaking for semiconductor photocatalysis	22
Emerging Metallopharmaceuticals for the Treatment of Cancer	22
Reflections on Racemic Natural Products	22
Investigating carotenoid photophysics in photosynthesis with 2D electronic spectroscopy	21
Kinetic and Thermodynamic Control in Dynamic Covalent Synthesis	21
The halogen chemistry of halide perovskites	21
Insight into conjugated polymers for organic electrochemical transistors	21
Opportunity for eutectic mixtures in metal-ion batteries	21
Catalytic amyloids	20
Hydrophobicity: a key factor en route to applications of metal–organic frameworks	20
Recent advances of ruthenium-based electrocatalysts for hydrogen energy	20
Computational Data-Driven Materials Discovery	20
High-throughput directed evolution: a golden era for protein science	19
Direct photocatalytic conversion of methane to value-added chemicals	19
Progress of thiol-amine ‘alkahest’ solutions for thin film deposition	19
The chemistry of chemically fueled droplets	19
Early Transition Metal-Catalyzed Hydroaminoalkylation	19
Technology pull: scale-up of polymeric mechanochemical force sensors	18
Chemical bonds in topological materials	18
Combination of radical functional group migration (FGM) and hydrogen atom transfer (HAT)	18
Ultrafast synthesis of electrocatalysts	17
Environmental theoretical calculation for non-periodic systems	17
Pretreatment of biomass with protic ionic liquids	17
Mechanoresponsive Porosity in Metal-Organic Frameworks	17
Complex multilength-scale morphology in organic photovoltaics	17
Transforming Hydroxide-Containing Metal–Organic Framework Nodes for Transition Metal Catalysis	17
Pursuing a Prospective Perspective	17
The hot mitochondrion paradox: reconciling theory and experiment	17
2D conjugated polymers: exploiting topological properties for the rational design of metal-free photocatalysts	17
Cation-coupled chloride cotransporters: chemical insights and disease implications	16
Renewable N-cycle catalysis	16
Photocatalytic Materials: An Apollo’s Arrow to Tumor Cells	16
Paper-based biosensors for cancer diagnostics	16
New catalytic reactions by enzyme engineering	16
Asymmetric radical cyclopropanation of alkenes	16
Lignin condensation, an unsolved mystery	16
Magnetic field effects on singlet fission dynamics	16
Harnessing chemical functionality of lignin towards stimuli-responsive materials	15
Advances and challenges in metal ion separation from water	15
Single-electron transfer oxidation-induced C–H bond functionalization via photo-/electrochemistry	15
Selective and sensitive environmental gas sensors enabled by membrane overlayers	15
Organopalladium Intermediates in Coordination-Directed C(sp3)-H Functionalizations	15
Mechanistically guided survey of enantioselective palladium-catalyzed alkene functionalization	15
Recommended practices and benchmarking of foam electrodes in water splitting	15
Mechanisms and Evolution of Diversity-Generating RiPP Biosynthesis	15
Photodynamic covalent bonds regulated by visible light for soft matter materials	15
Cyclobutane-containing scaffolds in bioactive small molecules	15
Light-induced switchable adsorption in azobenzene- and stilbene-based porous materials	14
Smart surface-based cell sheet engineering for regenerative medicine	14
Tetradentate Pt complexes for organic light-emitting diodes	14
High-throughput and machine-learning accelerated design of high entropy alloy catalysts	14
Deciphering the structure of heterogeneous catalysts across scales using pair distribution function analysis	14
Perspective of p-block single-atom catalysts for electrocatalysis	14
Emerging applications of curved aromatic compounds	14
Exploring chemistry with single-molecule and -particle fluorescence microscopy	14
Strategies for the synthesis of water-soluble conjugated polymers	14
Advances and challenges in user-friendly alkyne metathesis catalysts	13

Upscaling perovskite solar cells via the ambient deposition of perovskite thin films	13
Metal–organic framework-based electrocatalysts for acidic oxygen evolution reaction	13
Predictive catalysis: a valuable step towards machine learning	13
Progress in all-inorganic heterometallic halide layered double perovskites	13
Metal-organic frameworks for multicomponent gas separation	13
Reductive Csp2–N Coupling by PIII/PV=O–Catalysis	12
Host–guest behavior of pillar[n]arene-based supramolecular assemblies	12
Production of natural colorants by metabolically engineered microorganisms	12
Engineering strategies for two-dimensional perovskite solar cells	12
Advances in organic materials for chiral luminescence-based OLEDs	12
Semiconductor cooperative photocatalysis with TEMPO	11
Redox catalysts for chemical looping methane conversion	11
Engineering strategies for sustainable synthetic cells	11
Plasmonic hot carriers scratch the surface	11
How the Shape of Chemical Data Can Enable Data-Driven Materials Discovery	11
Heterogeneous photocatalysis: what is being overlooked?	11
Photoswitch designs for molecular solar thermal energy storage	11
Exploiting chemical cooperativity in main-group bimetallic catalysis	11
Aqueous two-phase emulsions toward biologically relevant applications	11
C–N and C–S bond formation by cytochrome P450 enzymes	10
Interface chemistry of conductive crystalline porous thin films	10
Application of Single-Site Catalysts in the Hydrogen Economy	10
Emerging organic electrode materials for aqueous proton batteries	10
Guidelines for the characterization of metal halide nanocrystals	10
Catalytic prenylation and reverse prenylation of aromatics	10
Metal-promoted synthetic chemistry within living cells	10
Ab initio quantum dynamics of plasmonic charge carriers	10
When all C–C breaks LO–Ose	10
Mitigating Raman relaxation for high-temperature single-molecule magnets	10
Single-crystalline covalent organic frameworks	10
Learning from Nature: Bio-inspired Heterobinuclear Electrocatalysts for Selective CO2 Reduction	10
Evolution of Zr nodes in metal–organic frameworks	9
Modern Synthetic Strategies for One-Electron Injection	9
Crafting chemical space with sulfur functional groups	9
High-throughput workflows in the service of (photo)electrocatalysis research	9
Electrifying biosynthesis for CO2 upcycling	9
Interrupted Kinugasa allylic alkylation	9
Solar-driven H2 production from formic acid	9
Interphasial engineering for Ni-rich NMC cathode materials	9
Porous aromatic frameworks with engineered properties for gas separation membranes	9
Wildfire atmospheric chemistry: climate and air quality impacts	9
Unlocking lignin’s potential with innovative DES technology	8
Ring-opening 1,3-difunctionalization of aryl cyclopropanes	8
Developing sophisticated microenvironments in metal-organic cages	8
Electrochemistry with plasmons	8
Multistep automated synthesis of pharmaceuticals	8
Ion migration in hydride materials	8
Comparison of direct and CO2-oxidative dehydrogenation of propane	8
Toward improved sustainability in lithium ion batteries using bio-based materials	8
Cellulosic ethanol production with bio- and chemo-catalytic methods	8
Flow chemistry of main group and transition metal complexes	8
Probing molecular vibrations by monochromated electron microscopy	8
Light-assisted dual catalysis for C–N bond construction	8
Navigating CO utilization in tandem electrocatalysis of CO2	8
Palladium-catalyzed oxidative arene C–H alkenylation reactions involving olefins	8
Automation in DFT-based computational materials science	8
Opportunities and challenges of chiral perovskites for spin-LEDs	7
The evolution of directing group strategies for C(sp)–H activation	7
Collaborative catalysis for solar biosynthesis	7
Chances and challenges for tin perovskites	7
Emerging green approaches for valorization of plastics with saturated carbon backbones	7
Subphthalocyanines: contracted porphyrinoids with expanded applications	7
Double-edged roles of intrinsic defects in two-dimensional MoS2	7
Catalyst for change: future of DEI in academia	7
Recent advances in the application of machine-learning algorithms to predict adsorption energies	7
3D-printing design for continuous flow catalysis	7
Biomimetic metal–organic frameworks for biological applications	7
Application of Atomic Layer Deposition in Dye-Sensitized Photoelectrosynthesis Cells	7
Design strategy for redox-active organic materials derived from N-heterocyclic carbenes	7
In Situ Detection of Low Amounts of Ammonia	7
Connecting ‘multi-omics’ approaches to endogenous protein complexes	7
Advancing data-driven chemistry by beating benchmarks	7
Chemical modification of polysaccharides for sustainable bioplastics	6
Metal–ligand cooperative transfer of protons and electrons	6
Anomalous small-angle X-ray scattering for materials chemistry	6
On-surface synthesis – there will be light	6
Perovskite oxynitrides as tunable materials for electrocatalytic nitrogen reduction to ammonia	6
Engineering active sites and recognizing mechanisms for CO2 fixation to dimethyl carbonate	6
Bioorthogonal chemistry-driven anticancer nanotherapeutics	6
A new type of catalysts: catalysts of singly dispersed bimetallic sites	6
Electrolyte engineering can improve electrochemical heat engine and refrigeration efficiency	6
Transmembrane anion transport mediated by sigma-hole interactions	6
Current advancements in the bio-based production of polyamides	6
Defect engineering of inorganic sensitizers for efficient triplet–triplet annihilation upconversion	5
Synthesis of atropisomers via transition-metal-catalyzed enantioselective carbene transformations	5
Interface engineering for single-molecule devices	5
New functionality of electrode materials with highly concentrated electrolytes	5
Real-Time Single-Polymer Growth towards Single-Monomer Resolution	5
Discovery, function, and engineering of graspetides	5
Retrosynthetic polyketide disconnections for unnatural aromatics	5
Copper defects for CO2 electrocatalysis toward a specific multicarbon product	5
Scalable solution processing of amorphous and crystalline chalcogenide films	5
Nanomachines in living matters: the soft-robot cytochrome P450	4
Integrating protein engineering into biocatalytic process scale-up	4
Designing nanoparticles for sustainable agricultural applications	4