Nature Catalysis

Article	Citations
Red light is ‘Go!’ for protein labelling	962
Greenwashed catalysis?	765
Bioproduction from methanol	662
An NAD⁺ analogue enables assembly of structurally diverse artificial photoenzymes for enantiodivergent [2 + 2] cycloadditions	600
Localized thermal levering events drive spontaneous kinetic oscillations during CO oxidation on Rh/Al2O3	570
Enantio- and diastereoselective construction of vicinal C(sp3) centres via nickel-catalysed hydroalkylation of alkenes	552
Structure and mechanism of haem-dependent nitrogen–nitrogen bond formation in piperazate synthase	542
PASADENA NMR	533
Role of the human-in-the-loop in emerging self-driving laboratories for heterogeneous catalysis	515
N-between the aryls	501
Double alkyl–alkyl bond construction across alkenes enabled by nickel electron-shuttle catalysis	495
Organic electrolyte cations promote non-aqueous CO2 reduction by mediating interfacial electric fields	394
Enzyme-like water preorganization in a synthetic molecular cleft for homogeneous water oxidation catalysis	394
Imagine polypropylene	388
Enhancing the connection between computation and experiments in electrocatalysis	367
Electrocatalytic upcycling of high-pressure captured CO2 to ethylene	361
Electrosynthesis of amino acids from NO and α-keto acids using two decoupled flow reactors	351
Exploration of the bio-analogous asymmetric C–C coupling mechanism in tandem CO2 electroreduction	343
Zn2+-mediated catalysis for fast-charging aqueous Zn-ion batteries	338
Methanotrophic catalysis for methane oxidation to formaldehyde	324
Pulsed away	323
Neither H2 nor O2 in hydrogenative oxidations with water	323
Quantum computing for faster enzyme discovery and engineering	312
Electrochemistry-inspired design of thermocatalysts	306
Density control	304

The synchronized catalytic dance of CRISPR-Cas9	302
Author Correction: Epistasis arises from shifting the rate-limiting step during enzyme evolution of a β-lactamase	300
Behind the curtain	295
Understanding the interplay between electrocatalytic C(sp3)‒C(sp3) fragmentation and oxygenation reactions	278
Identifying and avoiding dead ends in the characterization of heterogeneous catalysts at the gas–solid interface	269
Motorized catalysis	268
Room temperature photo-promoted iron-catalysed arene C–H alkenylation without Grignard reagents	265
Symbiotic oxides in catalysts	244
Light-induced Pd catalyst enables C(sp2)–C(sp2) cross-electrophile coupling bypassing the demand for transmetalation	242
Peripheral-nitrogen effects on the Ru1 centre for highly efficient propane dehydrogenation	241
Valence oscillation and dynamic active sites in monolayer NiCo hydroxides for water oxidation	241
Direct conversion of methane with O2 at room temperature over edge-rich MoS2	240
Ternary platinum–cobalt–indium nanoalloy on ceria as a highly efficient catalyst for the oxidative dehydrogenation of propane using CO2	238
The iron-catalysed Suzuki coupling of aryl chlorides	236
H2-reduced phosphomolybdate promotes room-temperature aerobic oxidation of methane to methanol	232
Electrocatalytic hydrogenation of alkenes with Pd/carbon nanotubes at an oil–water interface	227
O2 so good	226
Choreography of a self-splicing ribozyme	223
Heavy labels from gas surrogates	222
Optimizing iridium sites	221
Electrolysis in tandem	219
Active sites overcrowding	216
Substrate promiscuity fuels biosynthesis success	216
Iminium catalysis in natural Diels–Alderase	210
Copper-catalysed enantioconvergent O-alkylation of alcohols with racemic α-tertiary haloamides to access enantioenriched hindered dialkyl ethers	200
Pulsed electrolysis through neutron lenses	196
Enantioselective radical dearomative conjugate amination enabled by Co(II)-based metalloradical catalysis	194
Electrolyte effects in proton–electron transfer reactions and implications for renewable fuels and chemicals synthesis	191
Exploring mesoscopic mass transport effects on electrocatalytic selectivity	187
The rise of ab initio surface thermodynamics	182
A non-carboxylative route for the efficient synthesis of central metabolite malonyl-CoA and its derived products	181
Current state and future prospects of liquid metal catalysis	180
Solution-based Cu+ transient species mediate the reconstruction of copper electrocatalysts for CO2 reduction	180
Enzymatic catalysis favours eight-membered over five-membered ring closure in bicyclomycin biosynthesis	178
Morphological and chemical state effects in pulsed CO2 electroreduction on Cu(100) unveiled by correlated spectro-microscopy	178
Iron-catalysed cooperative redox mechanism for the simultaneous conversion of nitrous oxide and nitric oxide	175
Remote site-selective arene C–H functionalization enabled by N-heterocyclic carbene organocatalysis	170
Photoelectrochemical asymmetric dehydrogenative [2 + 2] cycloaddition between C–C single and double bonds via the activation of two C(sp3)–H bonds	166
Probing electrolyte effects on cation-enhanced CO2 reduction on copper in acidic media	159
The role of Cu1–O3 species in single-atom Cu/ZrO2 catalyst for CO2 hydrogenation	157
Steam methane reforming using a regenerable antenna–reactor plasmonic photocatalyst	156
Dinuclear Cu(I) molecular electrocatalyst for CO2-to-C3 product conversion	156
One, two, three, four, five!	149
Organocatalytic acylation of remote arene C–H bonds	148
Modulation to probe the interface	146
Wireless potentiometry of thermochemical heterogeneous catalysis	143
In situ lysosomal proteomics enabled by bioorthogonal photocatalytic proximity labelling	142
Concerted methane fixation at ambient temperature and pressure mediated by an alcohol oxidase and Fe-ZSM-5 catalytic couple	139
Determining CO adsorption free energies on CO2 electroreduction active sites through kinetic analysis	138
Bubble trouble	138

Catalytic borylation of tertiary C–H bonds	137
Ligand binding to a Ni–Fe cluster orchestrates conformational changes of the CO-dehydrogenase–acetyl-CoA synthase complex	135
Structural insights and engineering of the T4 td intron for improved RNA circularization	134
Organocatalytic olefin C–H functionalization for enantioselective synthesis of atropisomeric 1,3-dienes	133
Triplet quenchers for energy-transfer photobiocatalysis	133
Durable MnO2 electrocatalysts by stronger Mn–O bonds	132
Reassessment of the catalytic activity of bismuth for aqueous nitrogen electroreduction	132
Germanium-enriched double-four-membered-ring units inducing zeolite-confined subnanometric Pt clusters for efficient propane dehydrogenation	131
Catalysing rate and capacity	131
Lengthened by ethylene	130
Author Correction: Stereoselective alkyl–alkyl cross-coupling	126
Blowing in the tube	126
CYP screening for a better terpenoid world	124
Tailored for semi-hydrogenation	124
Publisher Correction: Parahydrogen-enhanced magnetic resonance identification of intermediates in [Fe]-hydrogenase catalysis	123
Electrosynthesis of ethylene glycol from ethylene coupled with CO2 capture	121
Cobalt-catalysed alkene hydronitration enabled by anomeric nitroamide	119
Synthesis of tri- and tetrasubstituted stereocentres by nickel-catalysed enantioselective olefin cross-couplings	119
Frustration-driven efficiency	118
Silicon frustrated Lewis pairs catalyse α-deuteration of amides and esters	118
A synthetic methylotrophic Escherichia coli as a chassis for bioproduction from methanol	117
Bridging catalysis	117
A fine adjustment	117
Regioselective silyl installation for arene diversification	117
Understanding Mn-modulated restructuring of Fe-based catalysts for controlling selectivity in CO2 hydrogenation to olefins	117
Nickel-electrocatalysed C(sp3)–C(sp3) cross-coupling of unactivated alkyl halides	112
Enantioselective Chan–Lam S-arylation of sulfenamides	109
High-purity carbon monoxide production via photothermal formic acid decomposition over fluorite ZrO2	109
Step bunching instability and its effects in electrocatalysis on platinum surfaces	106
Active-site isolation in intermetallics enables precise identification of elementary reaction kinetics during olefin hydrogenation	106
Reactant-induced dynamics of lithium imide surfaces during the ammonia decomposition process	105
Dissolved Fe species enable a cooperative solid–molecular mechanism for the oxygen evolution reaction on NiFe-based catalysts	104
Ammonia synthesis via an engineered nitrogenase assembly pathway in Escherichia coli	104
Cationic-group-functionalized electrocatalysts enable stable acidic CO2 electrolysis	104
An efficient Morita–Baylis–Hillmanase	102
Terpene synthases in giant viruses	101
Divide and conquer towards synthetic autotrophy	100
Shining light to break planarity	100
Catalyst optimization through synthetic Darwinian evolution	99
A TIM-barrel metalloenzyme with sugar-cleavage activity	99
Identifying restructured motifs on iridium oxide catalyst surfaces for water electrolysis	99
Cations in alkaline hydrogen electrocatalysis	98
A modular synthesis of azetidines from reactive triplet imine intermediates using an intermolecular aza Paternò–Büchi reaction	98
A hydrogenative oxidation strategy for the single-step synthesis of lactams from N-heteroarenes using water	98
Monitoring catalytic nanosites in action	98
Atomically dispersed ruthenium hydride on beta zeolite as catalysts for the isomerization of muconates	98
Cobalt hydride-mediated photocatalytic semihydrogenation of acetylene impurities for continuous-flow production of polymer-grade ethylene	97
Understanding two voltammetric features of water reduction and water oxidation in mild pH solutions	96
Boron clusters as efficient shuttles for electrocatalytic deuterium labelling via radical H/D exchange	95
Upcycling CO2 into energy-rich long-chain compounds via electrochemical and metabolic engineering	94
Author Correction: Oxygen evolution reaction over catalytic single-site Co in a well-defined brookite TiO2 nanorod surface	94
Methyl formate as a hydrogen energy carrier	92
Long-range enhancements of micropollutant adsorption on metal-promoted photocatalysts	91
Mass-based biocatalyst metrics to guide protein engineering and bioprocess development	91
The catalytic role of glutathione transferases in heterologous anthocyanin biosynthesis	91
Optimizing the p charge of S in p-block metal sulfides for sulfur reduction electrocatalysis	90
The STRENDA Biocatalysis Guidelines for cataloguing metadata	89
Generative machine learning produces kinetic models that accurately characterize intracellular metabolic states	89
Identifying and alleviating the durability challenges in membrane-electrode-assembly devices for high-rate CO electrolysis	88
Key role of paracrystalline motifs on iridium oxide surfaces for acidic water oxidation	88
Electrocatalytic dual hydrogenation of organic substrates with a Faradaic efficiency approaching 200%	86
Thioester-mediated biocatalytic amide bond synthesis with in situ thiol recycling	86
A strongly coupled Ru–CrOx cluster–cluster heterostructure for efficient alkaline hydrogen electrocatalysis	85
Iron-only Fe-nitrogenase underscores common catalytic principles in biological nitrogen fixation	83
Enhanced CO2 utilization in dry reforming of methane achieved through nickel-mediated hydrogen spillover in zeolite crystals	82
Photoinduced gold-catalyzed divergent dechloroalkylation of gem-dichloroalkanes	82
Identifying high-spin hydroxyl-coordinated Fe3+N4 as the active centre for acidic oxygen reduction using molecular model catalysts	81
Metastable nickel–oxygen species modulate rate oscillations during dry reforming of methane	81
Metabolic engineering of Escherichia coli with electron channelling for the production of natural products	81
Stereoselective construction of β-, γ- and δ-lactam rings via enzymatic C–H amidation	80
Scatter and conquer	80
Epistasis arises from shifting the rate-limiting step during enzyme evolution of a β-lactamase	80
Recharge your batteries	80
Acetylene hydrogenation to ethylene by water at low temperature on a Au/α-MoC catalyst	79
An antidote for chemical reaction networks	78
Ultralow overpotential nitrate reduction to ammonia via a three-step relay mechanism	78
Intramolecular hydroxyl nucleophilic attack pathway by a polymeric water oxidation catalyst with single cobalt sites	78
Challenges and prospects in precision medicine with RNA-based biocatalysts	76
Shape matters too	76
Author Correction: Origin of active sites on silica–magnesia catalysts and control of reactive environment in the one-step ethanol-to-butadiene process	76

Complex behaviour of isotopes in CO2 electroreduction	75
Photoenzymatic enantioselective intermolecular radical hydroamination	74
Precision installation of silyl synthetic handles within arenes by regiocontrolled ruthenium C(sp2)–H functionalization	74
Site-selective arene C–H amination with iron-aminyl radical	73
Privileged Brønsted acid organocatalysis	73
Critical insights into the steam electrolysis electrode in protonic ceramic cells for hydrogen production	73
Self-correcting science at work	72
Achieving maximum overall light enhancement in plasmonic catalysis by combining thermal and non-thermal effects	72
Seeking selectivity in alkene couplings	72
Amorphizing noble metal chalcogenide catalysts at the single-layer limit towards hydrogen production	72
Deciphering electrochemical methanol production	71
Benign hyperpolarization	70
Chiral phosphorus compounds by catalytic asymmetric C–P coupling	70
A radical way to ethylene	69
Publisher Correction: Gas-balancing adsorption strategy towards noble-metal-based nanowire electrocatalysts	68
Defying thermodynamics to synthetize hydrazine	68
Methane oxidation by catalyst reduction	68
The 3D secrets of fuel cell catalyst layers	67
Generating alkyl carbanions for organic synthesis	67
Organocatalytic regio- and stereoselective cyclopropanation of olefins	65
Organocatalytic asymmetric α-C–H functionalization of alkyl amines	65
Biocatalytic synthesis of non-standard amino acids by a decarboxylative aldol reaction	64
Alkene 1,1-difunctionalizations via organometallic-radical relay	63
A pyridoxal 5′-phosphate-dependent Mannich cyclase	63
Revealing in-plane movement of platinum in polymer electrolyte fuel cells after heavy-duty vehicle lifetime	63
Nickel-catalysed enantioselective alkene dicarbofunctionalization enabled by photochemical aliphatic C–H bond activation	62
Unlocking iron spin states for oxygen reduction	62
Regioselective hydroformylation with subnanometre Rh clusters in MFI zeolite	61
Effective anions	60
Eliminating redox-mediated electron transfer mechanisms on a supported molecular catalyst enables CO2 conversion to ethanol	60
Operando probing dynamic migration of copper carbonyl during electrocatalytic CO2 reduction	59
Rising to the surface	59
Pushing the boundaries of biocatalysis	59
Controlling carbocations	59