Nature Catalysis

Article	Citations
N-heteroarenes via transmutation	716
Bioproduction from methanol	705
Greenwashed catalysis?	599
Reply to: Reassessment of the catalytic activity of bismuth for aqueous nitrogen electroreduction	573
Imagine polypropylene	569
Ammonia to chiral α-amino acid	538
Cations galore	451
Work in tandem	419
Non-innocent electrophiles unlock exogenous base-free coupling reactions	413
Recharge your batteries	409
Computer-aided enzymatic retrosynthesis	404
Intramolecular hydroxyl nucleophilic attack pathway by a polymeric water oxidation catalyst with single cobalt sites	383
Metallaphotoredox catalysis for sp3 C–H functionalizations through single-electron transfer	365
Zeolites as equilibrium-shifting agents in shuttle catalysis	365
Oxide mixology	359
Red light is ‘Go!’ for protein labelling	345
Pushing hybrids to the limits	344
Lanthanide chemodivergence	343
Scatter and conquer	322
Deconvoluting the cation effect on carbon monoxide electroreduction	287
A precious pair for aldols	279
CO2 fixation gets a second chance	273
Seeing double	265
Electric coupling	257
Setting the standard	249

Evidence of substrate binding and product release via belt-sulfur mobilization of the nitrogenase cofactor	231
Oxygen evolving atoms	229
Performance evaluation and multidisciplinary analysis of catalytic fixation reactions by material–microbe hybrids	225
Metal-free organocatalytic S-formylation of thiols using CO2	224
Repurposing organic pollutants	222
N-between the aryls	218
Drug design via single-carbon atom insertion	211
Modifying Fe–N interaction to boost catalytic performance	207
Four on the floor	200
Feeling the weight	197
Nickel catalysts for affordable fuel cells	196
1,3-Butadiene formation through selective acetylene electrolysis on partially oxidized copper	194
Atomically dispersed antimony on carbon nitride for the artificial photosynthesis of hydrogen peroxide	192
Interplay of electrochemical and electrical effects induces structural transformations in electrocatalysts	192
Zn2+-mediated catalysis for fast-charging aqueous Zn-ion batteries	190
Enzyme-like water preorganization in a synthetic molecular cleft for homogeneous water oxidation catalysis	187
Highly selective hydrogenation of CO2 to propane over GaZrOx/H-SSZ-13 composite	182
Mo3+ hydride as the common origin of H2 evolution and selective NADH regeneration in molybdenum sulfide electrocatalysts	179
Light-driven CO2 methanation over Au-grafted Ce0.95Ru0.05O2 solid-solution catalysts with activities approaching the thermodynamic limit	176
Pickering emulsion droplets and solid microspheres acting synergistically for continuous-flow cascade reactions	172
A heterogeneous iridium single-atom-site catalyst for highly regioselective carbenoid O–H bond insertion	170
Enantioconvergent and regioselective reductive coupling of propargylic esters with chlorogermanes by nickel catalysis	168
Harnessing electron-rich arenes in nickel photoredox catalysis	163
Radical control for enantioselective Csp3–Csp3 cross-coupling	162
Photobiocatalysts tame nitrogen-centred radicals	161
Coupling electrochemical CO2 conversion with CO2 capture	156
Decreasing the catalytic ignition temperature of diesel soot using electrified conductive oxide catalysts	155
Intermetallic synergy in platinum–cobalt electrocatalysts for selective C–O bond cleavage	154
A MOF-supported Pd1–Au1 dimer catalyses the semihydrogenation reaction of acetylene in ethylene with a nearly barrierless activation energy	153
Bacteria–photocatalyst sheet for sustainable carbon dioxide utilization	138
Operando proton-transfer-reaction time-of-flight mass spectrometry of carbon dioxide reduction electrocatalysis	138
Ensemble effect for single-atom, small cluster and nanoparticle catalysts	132
Exploration of the bio-analogous asymmetric C–C coupling mechanism in tandem CO2 electroreduction	132
Cation-doped ZnS catalysts for polysulfide conversion in lithium–sulfur batteries	130
Maximizing light-driven CO2 and N2 fixation efficiency in quantum dot–bacteria hybrids	130
Ultralow overpotential nitrate reduction to ammonia via a three-step relay mechanism	129
Structure and engineering of miniature Acidibacillus sulfuroxidans Cas12f1	128
Electrosynthesis of amino acids from NO and α-keto acids using two decoupled flow reactors	127
Engineering catalyst supports to stabilize PdOx two-dimensional rafts for water-tolerant methane oxidation	127
Selective deoxygenation of biomass-derived carbonyl compounds on Zn via electrochemical Clemmensen reduction	125
ML helps predict enzyme turnover rates	123
Interfacial tuning of electrocatalytic Ag surfaces for fragment-based electrophile coupling	123
Stereodefined rhodium-catalysed 1,4-H/D delivery for modular syntheses and deuterium integration	121
Mind the gaps in CO2-to-methanol	120
Catalytic synthesis of β-lactam derivatives by carbonylative cycloaddition of acylsilanes with imines via a palladium Fischer-carbene intermediate	118
Stereoselective construction of β-, γ- and δ-lactam rings via enzymatic C–H amidation	118
Nickel-catalysed enantioselective hydrosulfenation of alkynes	117
Critical role of solvent-modulated hydrogen-binding strength in the catalytic hydrogenation of benzaldehyde on palladium	117
Double alkyl–alkyl bond construction across alkenes enabled by nickel electron-shuttle catalysis	117
Oxygenate-based routes regulate syngas conversion over oxide–zeolite bifunctional catalysts	116

Modulating the dynamics of Brønsted acid sites on PtWOx inverse catalyst	116
Redox-mediated electrosynthesis of ethylene oxide from CO2 and water	115
Reaction environment impacts charge transfer but not chemical reaction steps in hydrogen evolution catalysis	113
Harnessing the ambiphilicity of silyl nitronates in a catalytic asymmetric approach to aliphatic β3-amino acids	111
Regulating oxygen activity of perovskites to promote NOx oxidation and reduction kinetics	110
Enantio- and diastereoselective construction of vicinal C(sp3) centres via nickel-catalysed hydroalkylation of alkenes	106
Atomic metal–non-metal catalytic pair drives efficient hydrogen oxidation catalysis in fuel cells	104
Selective production of ethylene glycol at high rate via cascade catalysis	104
O2-tolerant CO dehydrogenase via tunnel redesign for the removal of CO from industrial flue gas	101
Acetylene hydrogenation to ethylene by water at low temperature on a Au/α-MoC catalyst	100
Enhancing the connection between computation and experiments in electrocatalysis	100
Without that crystalline touch	99
Enantioselective C–C cross-coupling of unactivated alkenes	98
Catalysts made from vapour	97
Ring expansion of indene by photoredox-enabled functionalized carbon-atom insertion	96
CO2 fixation into carbon nanofibres using electrochemical–thermochemical tandem catalysis	94
Author Correction: Denary oxide nanoparticles as highly stable catalysts for methane combustion	93
Metallaphotoredox-enabled aminocarboxylation of alkenes with CO2	93
Gas-balancing adsorption strategy towards noble-metal-based nanowire electrocatalysts	93
Publisher Correction: Catalyst control over sixfold stereogenicity	93
Epistasis arises from shifting the rate-limiting step during enzyme evolution of a β-lactamase	93
Publisher Correction: Solid–liquid phase transition induced electrocatalytic switching from hydrogen evolution to highly selective CO2 reduction	90
Author Correction: Coupling electrochemical CO2 conversion with CO2 capture	90
Surface (dis)order sleuthing	88
High-performance anion-exchange membrane water electrolysers using NiX (X = Fe,Co,Mn) catalyst-coated membranes with redox-active Ni–O ligands	87
Localized thermal levering events drive spontaneous kinetic oscillations during CO oxidation on Rh/Al2O3	87
PASADENA NMR	86
Self-adaptive dual-metal-site pairs in metal-organic frameworks for selective CO2 photoreduction to CH4	85
Publisher Correction: Switching of metal–oxygen hybridization for selective CO2 electrohydrogenation under mild temperature and pressure	85
Organic electrolyte cations promote non-aqueous CO2 reduction by mediating interfacial electric fields	84
Role of the human-in-the-loop in emerging self-driving laboratories for heterogeneous catalysis	83
An efficient catalytic route in haem peroxygenases mediated by O2/small-molecule reductant pairs for sustainable applications	83
Coupled catalytic states and the role of metal coordination in Cas9	82
Light on peroxide	82
Concentrating on ethanol	81
Density control	79
Ancient fixations	79
Electrocatalyst nanoparticles go with the flow	79
An electrochemical way to pure ethylene	77
Tuning the thermal activation atmosphere breaks the activity–stability trade-off of Fe–N–C oxygen reduction fuel cell catalysts	73
Valence oscillation and dynamic active sites in monolayer NiCo hydroxides for water oxidation	73
Alkali metal cations act as homogeneous cocatalysts for the oxygen reduction reaction in aqueous electrolytes	73
A titanic breakthrough	73
Acid-stable manganese oxides for proton exchange membrane water electrolysis	72
An electrochemical approach for designing thermochemical bimetallic nitrate hydrogenation catalysts	72
Cascade electrosynthesis of LiTFSI and N-containing analogues via a looped Li–N2 battery	72
Silver linings	71
Plasmonic bimetallic two-dimensional supercrystals for H2 generation	71
A breath of fresh air	71
Learning by osmosis	71
Halogens go retro	70
RNA-catalysed guanosine methylation	69
A radical strategy towards ortho-amination reactions	69
Acid solution	69
The synchronized catalytic dance of CRISPR-Cas9	68
Electrochemistry-inspired design of thermocatalysts	67
An antidote for chemical reaction networks	65
Understanding organic electrosynthesis	65
Motorized catalysis	64
Big Al for In	64
New tricks for old plastics	63
The identification and characterization of a selected SAM-dependent methyltransferase ribozyme that is present in natural sequences	63
Highly efficient additive-free dehydrogenation of neat formic acid	62
One-step conversion of crude oil to light olefins using a multi-zone reactor	61
Ternary platinum–cobalt–indium nanoalloy on ceria as a highly efficient catalyst for the oxidative dehydrogenation of propane using CO2	60
Dicarboxylation of alkenes, allenes and (hetero)arenes with CO2 via visible-light photoredox catalysis	60
Symbiotic oxides in catalysts	59
Electrocatalytic hydrogenation of alkenes with Pd/carbon nanotubes at an oil–water interface	59
Direct conversion of methane with O2 at room temperature over edge-rich MoS2	59
Achieving maximum overall light enhancement in plasmonic catalysis by combining thermal and non-thermal effects	58
Identifying and avoiding dead ends in the characterization of heterogeneous catalysts at the gas–solid interface	58
H2-reduced phosphomolybdate promotes room-temperature aerobic oxidation of methane to methanol	57
Electrochemical acetate production from high-pressure gaseous and liquid CO2	57
Best practices for experiments and reporting in photocatalytic CO2 reduction	56
On the role of metal cations in CO2 electrocatalytic reduction	55
Directed evolution of an efficient and thermostable PET depolymerase	55
Privileged Brønsted acid organocatalysis	55
Dynamic and reversible transformations of subnanometre-sized palladium on ceria for efficient methane removal	55
Identifying the activity of nanocatalyst sites	54
Enantioselective alkylation of α-amino C(sp3)−H bonds via photoredox and nickel catalysis	54

Olefin functionalization/isomerization enables stereoselective alkene synthesis	54
On the origin of multihole oxygen evolution in haematite photoanodes	53
A boronic enzyme	53
Reshaping catalysis beyond the conventional	53
Understanding the interplay between electrocatalytic C(sp3)‒C(sp3) fragmentation and oxygenation reactions	52
Synergistic interactions between PtRu catalyst and nitrogen-doped carbon support boost hydrogen oxidation	52
Room temperature photo-promoted iron-catalysed arene C–H alkenylation without Grignard reagents	51
Light-induced Pd catalyst enables C(sp2)–C(sp2) cross-electrophile coupling bypassing the demand for transmetalation	51
Deacylation-aided C–H alkylative annulation through C–C cleavage of unstrained ketones	51
Boron-catalysed hydrogenolysis of unactivated C(aryl)–C(alkyl) bonds	50
Site-selective arene C–H amination with iron-aminyl radical	50
Programmed exosome fusion for energy generation in living cells	50
Regulation of the electrocatalytic nitrogen cycle based on sequential proton–electron transfer	50
Amorphizing noble metal chalcogenide catalysts at the single-layer limit towards hydrogen production	49
Deep learning-based kcat prediction enables improved enzyme-constrained model reconstruction	49
Halide-guided active site exposure in bismuth electrocatalysts for selective CO2 conversion into formic acid	49
Steering the structure and selectivity of CO2 electroreduction catalysts by potential pulses	49
Modulating electric field distribution by alkali cations for CO2 electroreduction in strongly acidic medium	49
Unified mechanistic understanding of CO2 reduction to CO on transition metal and single atom catalysts	49
Atomically dispersed Pt and Fe sites and Pt–Fe nanoparticles for durable proton exchange membrane fuel cells	49
[Fe]-hydrogenase intermediates revealed	48
Methanotrophic catalysis for methane oxidation to formaldehyde	48
Ultrasmall amorphous zirconia nanoparticles catalyse polyolefin hydrogenolysis	47
Urea synthesis via electrocatalytic oxidative coupling of CO with NH3 on Pt	47
Photoenzymatic enantioselective intermolecular radical hydroamination	47