Nature Catalysis

Article	Citations
Red light is ‘Go!’ for protein labelling	933
Greenwashed catalysis?	733
Bioproduction from methanol	647
Localized thermal levering events drive spontaneous kinetic oscillations during CO oxidation on Rh/Al2O3	589
Double alkyl–alkyl bond construction across alkenes enabled by nickel electron-shuttle catalysis	556
Imagine polypropylene	540
Enhancing the connection between computation and experiments in electrocatalysis	538
Enzyme-like water preorganization in a synthetic molecular cleft for homogeneous water oxidation catalysis	532
Structure and mechanism of haem-dependent nitrogen–nitrogen bond formation in piperazate synthase	520
Role of the human-in-the-loop in emerging self-driving laboratories for heterogeneous catalysis	504
Electrocatalytic upcycling of high-pressure captured CO2 to ethylene	490
PASADENA NMR	485
N-between the aryls	385
Electrosynthesis of amino acids from NO and α-keto acids using two decoupled flow reactors	374
An NAD⁺ analogue enables assembly of structurally diverse artificial photoenzymes for enantiodivergent [2 + 2] cycloadditions	373
Enantio- and diastereoselective construction of vicinal C(sp3) centres via nickel-catalysed hydroalkylation of alkenes	353
Exploration of the bio-analogous asymmetric C–C coupling mechanism in tandem CO2 electroreduction	346
Zn2+-mediated catalysis for fast-charging aqueous Zn-ion batteries	336
Organic electrolyte cations promote non-aqueous CO2 reduction by mediating interfacial electric fields	336
Methanotrophic catalysis for methane oxidation to formaldehyde	327
Neither H2 nor O2 in hydrogenative oxidations with water	321
Motorized catalysis	314
Pulsed away	310
Quantum computing for faster enzyme discovery and engineering	309
Electrochemistry-inspired design of thermocatalysts	308

Density control	304
The synchronized catalytic dance of CRISPR-Cas9	302
Author Correction: Epistasis arises from shifting the rate-limiting step during enzyme evolution of a β-lactamase	301
Behind the curtain	295
Understanding the interplay between electrocatalytic C(sp3)‒C(sp3) fragmentation and oxygenation reactions	291
Identifying and avoiding dead ends in the characterization of heterogeneous catalysts at the gas–solid interface	290
Symbiotic oxides in catalysts	290
The iron-catalysed Suzuki coupling of aryl chlorides	276
Room temperature photo-promoted iron-catalysed arene C–H alkenylation without Grignard reagents	258
Light-induced Pd catalyst enables C(sp2)–C(sp2) cross-electrophile coupling bypassing the demand for transmetalation	253
Electrocatalytic hydrogenation of alkenes with Pd/carbon nanotubes at an oil–water interface	251
Peripheral-nitrogen effects on the Ru1 centre for highly efficient propane dehydrogenation	239
Valence oscillation and dynamic active sites in monolayer NiCo hydroxides for water oxidation	236
Unified mechanistic understanding of CO2 reduction to CO on transition metal and single atom catalysts	236
Ternary platinum–cobalt–indium nanoalloy on ceria as a highly efficient catalyst for the oxidative dehydrogenation of propane using CO2	233
H2-reduced phosphomolybdate promotes room-temperature aerobic oxidation of methane to methanol	231
Direct conversion of methane with O2 at room temperature over edge-rich MoS2	231
O2 so good	229
Choreography of a self-splicing ribozyme	228
Heavy labels from gas surrogates	218
Optimizing iridium sites	217
Morphological and chemical state effects in pulsed CO2 electroreduction on Cu(100) unveiled by correlated spectro-microscopy	215
Electrolysis in tandem	214
Active sites overcrowding	209
Substrate promiscuity fuels biosynthesis success	209
Iminium catalysis in natural Diels–Alderase	204
Pulsed electrolysis through neutron lenses	199
A non-carboxylative route for the efficient synthesis of central metabolite malonyl-CoA and its derived products	194
Enzymatic catalysis favours eight-membered over five-membered ring closure in bicyclomycin biosynthesis	194
Photoelectrochemical asymmetric dehydrogenative [2 + 2] cycloaddition between C–C single and double bonds via the activation of two C(sp3)–H bonds	194
Iron-catalysed cooperative redox mechanism for the simultaneous conversion of nitrous oxide and nitric oxide	191
Enantioselective radical dearomative conjugate amination enabled by Co(II)-based metalloradical catalysis	187
Electrolyte effects in proton–electron transfer reactions and implications for renewable fuels and chemicals synthesis	181
Solution-based Cu+ transient species mediate the reconstruction of copper electrocatalysts for CO2 reduction	180
Remote site-selective arene C–H functionalization enabled by N-heterocyclic carbene organocatalysis	174
Steam methane reforming using a regenerable antenna–reactor plasmonic photocatalyst	174
The rise of ab initio surface thermodynamics	173
Current state and future prospects of liquid metal catalysis	171
Copper-catalysed enantioconvergent O-alkylation of alcohols with racemic α-tertiary haloamides to access enantioenriched hindered dialkyl ethers	168
Dinuclear Cu(I) molecular electrocatalyst for CO2-to-C3 product conversion	167
The role of Cu1–O3 species in single-atom Cu/ZrO2 catalyst for CO2 hydrogenation	163
Exploring mesoscopic mass transport effects on electrocatalytic selectivity	159
Probing electrolyte effects on cation-enhanced CO2 reduction on copper in acidic media	158
Organocatalytic acylation of remote arene C–H bonds	154
One, two, three, four, five!	154
Ligand binding to a Ni–Fe cluster orchestrates conformational changes of the CO-dehydrogenase–acetyl-CoA synthase complex	150
Bubble trouble	146
Modulation to probe the interface	140
Wireless potentiometry of thermochemical heterogeneous catalysis	139
Catalysing rate and capacity	138

Reassessment of the catalytic activity of bismuth for aqueous nitrogen electroreduction	137
Organocatalytic olefin C–H functionalization for enantioselective synthesis of atropisomeric 1,3-dienes	136
In situ lysosomal proteomics enabled by bioorthogonal photocatalytic proximity labelling	136
Durable MnO2 electrocatalysts by stronger Mn–O bonds	136
Concerted methane fixation at ambient temperature and pressure mediated by an alcohol oxidase and Fe-ZSM-5 catalytic couple	135
Determining CO adsorption free energies on CO2 electroreduction active sites through kinetic analysis	132
Germanium-enriched double-four-membered-ring units inducing zeolite-confined subnanometric Pt clusters for efficient propane dehydrogenation	132
Catalytic borylation of tertiary C–H bonds	131
Blowing in the tube	130
Lengthened by ethylene	130
Author Correction: Stereoselective alkyl–alkyl cross-coupling	129
CYP screening for a better terpenoid world	128
Tailored for semi-hydrogenation	127
Publisher Correction: Parahydrogen-enhanced magnetic resonance identification of intermediates in [Fe]-hydrogenase catalysis	127
Enantioselective Chan–Lam S-arylation of sulfenamides	126
Frustration-driven efficiency	123
Active-site isolation in intermetallics enables precise identification of elementary reaction kinetics during olefin hydrogenation	121
A fine adjustment	119
Reactant-induced dynamics of lithium imide surfaces during the ammonia decomposition process	118
A synthetic methylotrophic Escherichia coli as a chassis for bioproduction from methanol	118
Uniting biological and chemical strategies for selective CO2 reduction	116
Synthesis of tri- and tetrasubstituted stereocentres by nickel-catalysed enantioselective olefin cross-couplings	116
Electrosynthesis of ethylene glycol from ethylene coupled with CO2 capture	116
Silicon frustrated Lewis pairs catalyse α-deuteration of amides and esters	116
Bridging catalysis	115
Regioselective silyl installation for arene diversification	115
Cobalt-catalysed alkene hydronitration enabled by anomeric nitroamide	114
Ammonia synthesis via an engineered nitrogenase assembly pathway in Escherichia coli	114
Step bunching instability and its effects in electrocatalysis on platinum surfaces	114
Dissolved Fe species enable a cooperative solid–molecular mechanism for the oxygen evolution reaction on NiFe-based catalysts	111
Nickel-electrocatalysed C(sp3)–C(sp3) cross-coupling of unactivated alkyl halides	110
High-purity carbon monoxide production via photothermal formic acid decomposition over fluorite ZrO2	110
Cationic-group-functionalized electrocatalysts enable stable acidic CO2 electrolysis	109
An efficient Morita–Baylis–Hillmanase	106
Understanding Mn-modulated restructuring of Fe-based catalysts for controlling selectivity in CO2 hydrogenation to olefins	106
Terpene synthases in giant viruses	103
Divide and conquer towards synthetic autotrophy	102
Identifying restructured motifs on iridium oxide catalyst surfaces for water electrolysis	101
Shining light to break planarity	101
Author Correction: Oxygen evolution reaction over catalytic single-site Co in a well-defined brookite TiO2 nanorod surface	100
Monitoring catalytic nanosites in action	98
A hydrogenative oxidation strategy for the single-step synthesis of lactams from N-heteroarenes using water	98
Photoinduced gold-catalyzed divergent dechloroalkylation of gem-dichloroalkanes	97
Upcycling CO2 into energy-rich long-chain compounds via electrochemical and metabolic engineering	97
The catalytic role of glutathione transferases in heterologous anthocyanin biosynthesis	97
Long-range enhancements of micropollutant adsorption on metal-promoted photocatalysts	97
Catalyst optimization through synthetic Darwinian evolution	95
Generative machine learning produces kinetic models that accurately characterize intracellular metabolic states	95
Key role of paracrystalline motifs on iridium oxide surfaces for acidic water oxidation	94
A TIM-barrel metalloenzyme with sugar-cleavage activity	94
Understanding two voltammetric features of water reduction and water oxidation in mild pH solutions	93
Metastable nickel–oxygen species modulate rate oscillations during dry reforming of methane	93
Boron clusters as efficient shuttles for electrocatalytic deuterium labelling via radical H/D exchange	92
Cobalt hydride-mediated photocatalytic semihydrogenation of acetylene impurities for continuous-flow production of polymer-grade ethylene	92
Cations in alkaline hydrogen electrocatalysis	91
Atomically dispersed ruthenium hydride on beta zeolite as catalysts for the isomerization of muconates	91
A modular synthesis of azetidines from reactive triplet imine intermediates using an intermolecular aza Paternò–Büchi reaction	91
Identifying and alleviating the durability challenges in membrane-electrode-assembly devices for high-rate CO electrolysis	91
Atomically dispersed iridium on MgO(111) nanosheets catalyses benzene–ethylene coupling towards styrene	88
Thioester-mediated biocatalytic amide bond synthesis with in situ thiol recycling	88
Methyl formate as a hydrogen energy carrier	88
Metabolic engineering of Escherichia coli with electron channelling for the production of natural products	87
Electrocatalytic dual hydrogenation of organic substrates with a Faradaic efficiency approaching 200%	87
Enhanced CO2 utilization in dry reforming of methane achieved through nickel-mediated hydrogen spillover in zeolite crystals	86
Mass-based biocatalyst metrics to guide protein engineering and bioprocess development	85
The STRENDA Biocatalysis Guidelines for cataloguing metadata	85
Identifying high-spin hydroxyl-coordinated Fe3+N4 as the active centre for acidic oxygen reduction using molecular model catalysts	83
Optimizing the p charge of S in p-block metal sulfides for sulfur reduction electrocatalysis	82
Recharge your batteries	81
A strongly coupled Ru–CrOx cluster–cluster heterostructure for efficient alkaline hydrogen electrocatalysis	81
Iron-only Fe-nitrogenase underscores common catalytic principles in biological nitrogen fixation	81
Intramolecular hydroxyl nucleophilic attack pathway by a polymeric water oxidation catalyst with single cobalt sites	80
Scatter and conquer	80
Stereoselective construction of β-, γ- and δ-lactam rings via enzymatic C–H amidation	78
Ultralow overpotential nitrate reduction to ammonia via a three-step relay mechanism	78
Acetylene hydrogenation to ethylene by water at low temperature on a Au/α-MoC catalyst	78
Epistasis arises from shifting the rate-limiting step during enzyme evolution of a β-lactamase	78
Coupling electrochemical CO2 conversion with CO2 capture	78
An antidote for chemical reaction networks	77
Author Correction: Origin of active sites on silica–magnesia catalysts and control of reactive environment in the one-step ethanol-to-butadiene process	76

Challenges and prospects in precision medicine with RNA-based biocatalysts	76
Shape matters too	76
Privileged Brønsted acid organocatalysis	76
Complex behaviour of isotopes in CO2 electroreduction	75
Precision installation of silyl synthetic handles within arenes by regiocontrolled ruthenium C(sp2)–H functionalization	74
Site-selective arene C–H amination with iron-aminyl radical	74
Critical insights into the steam electrolysis electrode in protonic ceramic cells for hydrogen production	73
Photoenzymatic enantioselective intermolecular radical hydroamination	73
Achieving maximum overall light enhancement in plasmonic catalysis by combining thermal and non-thermal effects	73
Self-correcting science at work	72
Amorphizing noble metal chalcogenide catalysts at the single-layer limit towards hydrogen production	72
Deciphering electrochemical methanol production	70
Seeking selectivity in alkene couplings	70
Effective anions	70
Chiral phosphorus compounds by catalytic asymmetric C–P coupling	69
Benign hyperpolarization	69
Generating alkyl carbanions for organic synthesis	68
Defying thermodynamics to synthetize hydrazine	68
A radical way to ethylene	68
Methane oxidation by catalyst reduction	67
Publisher Correction: Gas-balancing adsorption strategy towards noble-metal-based nanowire electrocatalysts	66
Organocatalytic asymmetric α-C–H functionalization of alkyl amines	65
Organocatalytic regio- and stereoselective cyclopropanation of olefins	65
Biocatalytic synthesis of non-standard amino acids by a decarboxylative aldol reaction	65
Nickel-catalysed enantioselective alkene dicarbofunctionalization enabled by photochemical aliphatic C–H bond activation	64
A pyridoxal 5′-phosphate-dependent Mannich cyclase	64
Unlocking iron spin states for oxygen reduction	63
Alkene 1,1-difunctionalizations via organometallic-radical relay	63
The 3D secrets of fuel cell catalyst layers	63
Operando probing dynamic migration of copper carbonyl during electrocatalytic CO2 reduction	61
Regioselective hydroformylation with subnanometre Rh clusters in MFI zeolite	61
Revealing in-plane movement of platinum in polymer electrolyte fuel cells after heavy-duty vehicle lifetime	61