Nature Catalysis

Article	Citations
Matching the kinetics of natural enzymes with a single-atom iron nanozyme	665
Atomically dispersed antimony on carbon nitride for the artificial photosynthesis of hydrogen peroxide	637
Chemical and biological catalysis for plastics recycling and upcycling	538
Absence of CO2 electroreduction on copper, gold and silver electrodes without metal cations in solution	529
Performance enhancement and degradation mechanism identification of a single-atom Co–N–C catalyst for proton exchange membrane fuel cells	511
Self-adaptive dual-metal-site pairs in metal-organic frameworks for selective CO2 photoreduction to CH4	509
In-situ reconstructed Ru atom array on α-MnO2 with enhanced performance for acidic water oxidation	479
Identification of durable and non-durable FeNx sites in Fe–N–C materials for proton exchange membrane fuel cells	445
Understanding the inter-site distance effect in single-atom catalysts for oxygen electroreduction	423
Sulfur vacancy-rich MoS2 as a catalyst for the hydrogenation of CO2 to methanol	388
Electrochemical CO2-to-ethylene conversion on polyamine-incorporated Cu electrodes	376
Modulating electric field distribution by alkali cations for CO2 electroreduction in strongly acidic medium	373
Coupling electrochemical CO2 conversion with CO2 capture	369
Combined anodic and cathodic hydrogen production from aldehyde oxidation and hydrogen evolution reaction	366
High loading of single atomic iron sites in Fe–NC oxygen reduction catalysts for proton exchange membrane fuel cells	337
Redirecting dynamic surface restructuring of a layered transition metal oxide catalyst for superior water oxidation	332
Enhancing the stability of cobalt spinel oxide towards sustainable oxygen evolution in acid	331
Valence oscillation and dynamic active sites in monolayer NiCo hydroxides for water oxidation	325
Interface dynamics of Pd–CeO2 single-atom catalysts during CO oxidation	309
Cation-doped ZnS catalysts for polysulfide conversion in lithium–sulfur batteries	294
Ultralow overpotential nitrate reduction to ammonia via a three-step relay mechanism	288
High carbon utilization in CO2 reduction to multi-carbon products in acidic media	281
Proton-filtering covalent organic frameworks with superior nitrogen penetration flux promote ambient ammonia synthesis	261
The role of Cu1–O3 species in single-atom Cu/ZrO2 catalyst for CO2 hydrogenation	251
Advances in supramolecular host-mediated reactivity	250

The role of ruthenium in improving the kinetics of hydrogen oxidation and evolution reactions of platinum	246
Hydrogen bond network connectivity in the electric double layer dominates the kinetic pH effect in hydrogen electrocatalysis on Pt	233
Induced activation of the commercial Cu/ZnO/Al2O3 catalyst for the steam reforming of methanol	232
Atomically dispersed Pt and Fe sites and Pt–Fe nanoparticles for durable proton exchange membrane fuel cells	216
Oxygen evolution reaction over catalytic single-site Co in a well-defined brookite TiO2 nanorod surface	215
A selective Au-ZnO/TiO2 hybrid photocatalyst for oxidative coupling of methane to ethane with dioxygen	211
Reversely trapping atoms from a perovskite surface for high-performance and durable fuel cell cathodes	211
Unified mechanistic understanding of CO2 reduction to CO on transition metal and single atom catalysts	205
Denary oxide nanoparticles as highly stable catalysts for methane combustion	204
Upcycling CO2 into energy-rich long-chain compounds via electrochemical and metabolic engineering	202
Strong metal–support interactions on gold nanoparticle catalysts achieved through Le Chatelier’s principle	202
Steering the structure and selectivity of CO2 electroreduction catalysts by potential pulses	201
Analysis of the limitations in the oxygen reduction activity of transition metal oxide surfaces	201
High-purity and high-concentration liquid fuels through CO2 electroreduction	188
A single-Pt-atom-on-Ru-nanoparticle electrocatalyst for CO-resilient methanol oxidation	187
Fully exposed palladium cluster catalysts enable hydrogen production from nitrogen heterocycles	178
Directed evolution of an efficient and thermostable PET depolymerase	177
Selective CO-to-acetate electroreduction via intermediate adsorption tuning on ordered Cu–Pd sites	176
N-Heterocyclic carbenes as tunable ligands for catalytic metal surfaces	174
Unifying views on catalyst deactivation	170
Engineering the Cu/Mo2CTx (MXene) interface to drive CO2 hydrogenation to methanol	168
Interpretable machine learning for knowledge generation in heterogeneous catalysis	168
Capabilities and limitations of rotating disk electrodes versus membrane electrode assemblies in the investigation of electrocatalysts	165
Room-temperature electrochemical acetylene reduction to ethylene with high conversion and selectivity	162
Ensemble effect for single-atom, small cluster and nanoparticle catalysts	160
Enhancing oxygen reduction electrocatalysis by tuning interfacial hydrogen bonds	158
Simultaneous oxidative and reductive reactions in one system by atomic design	156
Highly selective and productive reduction of carbon dioxide to multicarbon products via in situ CO management using segmented tandem electrodes	153
Deep learning-based kcat prediction enables improved enzyme-constrained model reconstruction	153
Long-chain hydrocarbons by CO2 electroreduction using polarized nickel catalysts	153
RetroBioCat as a computer-aided synthesis planning tool for biocatalytic reactions and cascades	152
Photocatalytic strategies for the activation of organic chlorides	151
Amorphizing noble metal chalcogenide catalysts at the single-layer limit towards hydrogen production	146
Overall photocatalytic water splitting by an organolead iodide crystalline material	145
α-Fe2O3 as a versatile and efficient oxygen atom transfer catalyst in combination with H2O as the oxygen source	141
Bimetallic monolayer catalyst breaks the activity–selectivity trade-off on metal particle size for efficient chemoselective hydrogenations	138
The role of alkali metal cations and platinum-surface hydroxyl in the alkaline hydrogen evolution reaction	135
Intramolecular hydroxyl nucleophilic attack pathway by a polymeric water oxidation catalyst with single cobalt sites	132
Strain enhances the activity of molecular electrocatalysts via carbon nanotube supports	130
Metal-free photosensitized oxyimination of unactivated alkenes with bifunctional oxime carbonates	129
Dicarboxylation of alkenes, allenes and (hetero)arenes with CO2 via visible-light photoredox catalysis	128
Following the structure of copper-zinc-alumina across the pressure gap in carbon dioxide hydrogenation	127
Au-ZSM-5 catalyses the selective oxidation of CH4 to CH3OH and CH3COOH using O2	127
General features to enhance enzymatic activity of poly(ethylene terephthalate) hydrolysis	126
A heterogeneous iridium single-atom-site catalyst for highly regioselective carbenoid O–H bond insertion	123
Recovering carbon losses in CO2 electrolysis using a solid electrolyte reactor	120
Selective electrocatalytic semihydrogenation of acetylene impurities for the production of polymer-grade ethylene	119
Engineering catalyst supports to stabilize PdOx two-dimensional rafts for water-tolerant methane oxidation	117
Photoelectrochemical asymmetric catalysis enables site- and enantioselective cyanation of benzylic C–H bonds	116
Highly efficient additive-free dehydrogenation of neat formic acid	115

Solid–liquid phase transition induced electrocatalytic switching from hydrogen evolution to highly selective CO2 reduction	113
Copper/alkaline earth metal oxide interfaces for electrochemical CO2-to-alcohol conversion by selective hydrogenation	112
Rational design of perovskite ferrites as high-performance proton-conducting fuel cell cathodes	112
Unlocking the potential of the formate pathway in the photo-assisted Sabatier reaction	108
Enhanced CO2 utilization in dry reforming of methane achieved through nickel-mediated hydrogen spillover in zeolite crystals	107
Ternary platinum–cobalt–indium nanoalloy on ceria as a highly efficient catalyst for the oxidative dehydrogenation of propane using CO2	107
Operando visualization of the hydrogen evolution reaction with atomic-scale precision at different metal–graphene interfaces	106
Visible-light photocatalytic di- and hydro-carboxylation of unactivated alkenes with CO2	106
A new-to-nature carboxylation module to improve natural and synthetic CO2 fixation	105
Photocatalytic sacrificial H2 evolution dominated by micropore-confined exciton transfer in hydrogen-bonded organic frameworks	105
A kinetic descriptor for the electrolyte effect on the oxygen reduction kinetics on Pt(111)	102
Copper-catalysed amination of alkyl iodides enabled by halogen-atom transfer	99
Light-driven CO2 sequestration in Escherichia coli to achieve theoretical yield of chemicals	99
Supramolecular tuning of supported metal phthalocyanine catalysts for hydrogen peroxide electrosynthesis	98
Delocalization state-induced selective bond breaking for efficient methanol electrosynthesis from CO2	98
Nickel–molybdenum–niobium metallic glass for efficient hydrogen oxidation in hydroxide exchange membrane fuel cells	93
Ternary ruthenium complex hydrides for ammonia synthesis via the associative mechanism	90
Uniting biological and chemical strategies for selective CO2 reduction	90
Quantifying the electrochemical active site density of precious metal-free catalysts in situ in fuel cells	90
Interplay of electrochemical and electrical effects induces structural transformations in electrocatalysts	89
Optimizing the p charge of S in p-block metal sulfides for sulfur reduction electrocatalysis	89
Linear paired electrochemical valorization of glycerol enabled by the electro-Fenton process using a stable NiSe2 cathode	88
Tuning the thermal activation atmosphere breaks the activity–stability trade-off of Fe–N–C oxygen reduction fuel cell catalysts	87
Switching of metal–oxygen hybridization for selective CO2 electrohydrogenation under mild temperature and pressure	87
Blocking the reverse reactions of overall water splitting on a Rh/GaN–ZnO photocatalyst modified with Al2O3	86
A residue-free approach to water disinfection using catalytic in situ generation of reactive oxygen species	86
Cationic-group-functionalized electrocatalysts enable stable acidic CO2 electrolysis	86
Direct propylene epoxidation with oxygen using a photo-electro-heterogeneous catalytic system	84
Switchable wetting of oxygen-evolving oxide catalysts	84
Cobalt-catalysed enantioselective C(sp3)–C(sp3) coupling	83
The shape of water in zeolites and its impact on epoxidation catalysis	82
Silica-supported Fe/Fe–O nanoparticles for the catalytic hydrogenation of nitriles to amines in the presence of aluminium additives	82
Selective electrochemical synthesis of urea from nitrate and CO2 via relay catalysis on hybrid catalysts	81
Direct methane activation by atomically thin platinum nanolayers on two-dimensional metal carbides	81
Bridging the complexity gap in computational heterogeneous catalysis with machine learning	80
Experimental Sabatier plot for predictive design of active and stable Pt-alloy oxygen reduction reaction catalysts	79
Performance metrics for sustainable catalysis in industry	79
Best practices for experiments and reporting in photocatalytic CO2 reduction	79
Construction of axial chirality via asymmetric radical trapping by cobalt under visible light	76
Biocatalytic reductive amination from discovery to commercial manufacturing applied to abrocitinib JAK1 inhibitor	76
Correlating hydration free energy and specific adsorption of alkali metal cations during CO2 electroreduction on Au	75
Peripheral-nitrogen effects on the Ru1 centre for highly efficient propane dehydrogenation	75
Oxygen reduction reaction electrocatalysis in neutral media for bioelectrochemical systems	75
Regulating oxygen activity of perovskites to promote NOx oxidation and reduction kinetics	75
Atomic-scale surface restructuring of copper electrodes under CO2 electroreduction conditions	72
One-step conversion of crude oil to light olefins using a multi-zone reactor	72
Electrochemically induced nickel catalysis for oxygenation reactions with water	72
Halide-guided active site exposure in bismuth electrocatalysts for selective CO2 conversion into formic acid	72
Electrocatalytic conversion of carbon dioxide for the Paris goals	72
Unlocking direct CO2 electrolysis to C3 products via electrolyte supersaturation	71
Iron-catalysed asymmetric carboazidation of styrenes	71
Breaking structure sensitivity in CO2 hydrogenation by tuning metal–oxide interfaces in supported cobalt nanoparticles	71
An organic perspective on photocatalytic production of hydrogen peroxide	71
Photoinduced chemomimetic biocatalysis for enantioselective intermolecular radical conjugate addition	70
Identification of the active sites in supported subnanometric metal catalysts	69
Enhancing acetate selectivity by coupling anodic oxidation to carbon monoxide electroreduction	69
Threshold potentials for fast kinetics during mediated redox catalysis of insulators in Li–O2 and Li–S batteries	68
Catalytic enantioselective synthesis of chiral tetraarylmethanes	68
Biomimetic active sites on monolayered metal–organic frameworks for artificial photosynthesis	68
Surface molecular imprinting over supported metal catalysts for size-dependent selective hydrogenation reactions	67
Enhancing the connection between computation and experiments in electrocatalysis	67
Chemical gradients in automotive Cu-SSZ-13 catalysts for NOx removal revealed by operando X-ray spectrotomography	64
Light-driven CO2 methanation over Au-grafted Ce0.95Ru0.05O2 solid-solution catalysts with activities approaching the thermodynamic limit	64
Bacteria–photocatalyst sheet for sustainable carbon dioxide utilization	64
Machine-learning-assisted design of a binary descriptor to decipher electronic and structural effects on sulfur reduction kinetics	63
Coordination and activation of nitrous oxide by iron zeolites	63
Critical enzyme reactions in aromatic catabolism for microbial lignin conversion	63
Critical role of solvent-modulated hydrogen-binding strength in the catalytic hydrogenation of benzaldehyde on palladium	63
Decreasing the catalytic ignition temperature of diesel soot using electrified conductive oxide catalysts	61
Redox-mediated electrosynthesis of ethylene oxide from CO2 and water	61
Mechanism-guided tunnel engineering to increase the efficiency of a flavin-dependent halogenase	61
Water-induced deactivation of cobalt-based Fischer–Tropsch catalysts	60
Unusual zymogen activation patterns in the protein corona of Ca-zeolites	60
Reversible H2 oxidation and evolution by hydrogenase embedded in a redox polymer film	60
Energy transfer-enabled unsymmetrical diamination using bifunctional nitrogen-radical precursors	59
Standardized protocols for evaluating platinum group metal-free oxygen reduction reaction electrocatalysts in polymer electrolyte fuel cells	59
Reaction product-driven restructuring and assisted stabilization of a highly dispersed Rh-on-ceria catalyst	59
On the origin of multihole oxygen evolution in haematite photoanodes	59
Catalytic enantio- and diastereoselective domino halocyclization and spiroketalization	58
Experimental evidence of distinct sites for CO2-to-CO and CO conversion on Cu in the electrochemical CO2 reduction reaction	57

Highly selective hydrogenation of CO2 to propane over GaZrOx/H-SSZ-13 composite	57
A semiconducting polymer bulk heterojunction photoanode for solar water oxidation	57
Potassium hydride-intercalated graphite as an efficient heterogeneous catalyst for ammonia synthesis	55
Heterogeneous electrocatalysis goes chemical	55
Regioirregular and catalytic Mizoroki–Heck reactions	55
Ultrasmall amorphous zirconia nanoparticles catalyse polyolefin hydrogenolysis	54
Photoinduced gold-catalyzed divergent dechloroalkylation of gem-dichloroalkanes	54
Modulating the dynamics of Brønsted acid sites on PtWOx inverse catalyst	54
Germanium-enriched double-four-membered-ring units inducing zeolite-confined subnanometric Pt clusters for efficient propane dehydrogenation	54
Deciphering the oxygen activation mechanism at the CuC site of particulate methane monooxygenase	53
Atomic metal–non-metal catalytic pair drives efficient hydrogen oxidation catalysis in fuel cells	53
Enantioselective synthesis of amino acids from ammonia	53
Elucidating electron-transfer events in polypyridine nickel complexes for reductive coupling reactions	53
Controlling biocatalytic cascades with enzyme–DNA dynamic networks	52
Mo3+ hydride as the common origin of H2 evolution and selective NADH regeneration in molybdenum sulfide electrocatalysts	52
Machine learning-enabled retrobiosynthesis of molecules	51
Development of a versatile and efficient C–N lyase platform for asymmetric hydroamination via computational enzyme redesign	51
A cell-free self-replenishing CO2-fixing system	50
Facile access to fused 2D/3D rings via intermolecular cascade dearomative [2 + 2] cycloaddition/rearrangement reactions of quinolines with alkenes	50
Electrocatalytic dual hydrogenation of organic substrates with a Faradaic efficiency approaching 200%	50
Adsorbed cobalt porphyrins act like metal surfaces in electrocatalysis	49
Exploration of the bio-analogous asymmetric C–C coupling mechanism in tandem CO2 electroreduction	49
Engineering and emerging applications of artificial metalloenzymes with whole cells	49
Shape-selective C–H activation of aromatics to biarylic compounds using molecular palladium in zeolites	49
Urea group-directed organocatalytic asymmetric versatile dihalogenation of alkenes and alkynes	47
Site-selective amination towards tertiary aliphatic allylamines	47
DYW domain structures imply an unusual regulation principle in plant organellar RNA editing catalysis	47
Influence of framework Al density in chabazite zeolites on copper ion mobility and reactivity during NOx selective catalytic reduction with NH3	46
Linkage-engineered donor–acceptor covalent organic frameworks for optimal photosynthesis of hydrogen peroxide from water and air	46
Thermochemical aerobic oxidation catalysis in water can be analysed as two coupled electrochemical half-reactions	46
Maximizing light-driven CO2 and N2 fixation efficiency in quantum dot–bacteria hybrids	46
Exploring catalytic reaction networks with machine learning	45
Atomically dispersed iridium on MgO(111) nanosheets catalyses benzene–ethylene coupling towards styrene	45
Deacylation-aided C–H alkylative annulation through C–C cleavage of unstrained ketones	45
Solar methanol energy storage	45
Efficient exploration of terpenoid biosynthetic gene clusters in filamentous fungi	44
Electrosynthesis of amino acids from NO and α-keto acids using two decoupled flow reactors	44
Design and evolution of chimeric streptavidin for protein-enabled dual gold catalysis	44
Catalyst control over sixfold stereogenicity	44
Elucidation of radical- and oxygenate-driven paths in zeolite-catalysed conversion of methanol and methyl chloride to hydrocarbons	44
Synergistic interactions between PtRu catalyst and nitrogen-doped carbon support boost hydrogen oxidation	44
Metal–support cooperation in Al(PO3)3-supported platinum nanoparticles for the selective hydrogenolysis of phenols to arenes	43
Palladium-catalysed enantioselective diacetoxylation of terminal alkenes	43
Mechanistic study of an immobilized molecular electrocatalyst by in situ gap-plasmon-assisted spectro-electrochemistry	43
Deciphering the dichotomy exerted by Zn(ii) in the catalytic sp2 C–O bond functionalization of aryl esters at the molecular level	41
Blocking the sulfonate group in Nafion to unlock platinum’s activity in membrane electrode assemblies	41
Light-driven synthesis of C2H6 from CO2 and H2O on a bimetallic AuIr composite supported on InGaN nanowires	41
Catalytic mechanism and endo-to-exo selectivity reversion of an octalin-forming natural Diels–Alderase	40
Catalytic pyrolysis as a platform technology for supporting the circular carbon economy	40
Catalytic access to carbocation intermediates via nitrenoid transfer leading to allylic lactams	40
Hydrogen-bonded organic framework-based bioorthogonal catalysis prevents drug metabolic inactivation	39
Molecular water oxidation catalysts based on first-row transition metal complexes	39
Iron-catalysed regioselective thienyl C–H/C–H coupling	39
Regulation of the electrocatalytic nitrogen cycle based on sequential proton–electron transfer	39
Mild and metal-free Birch-type hydrogenation of (hetero)arenes with boron carbonitride in water	39
Olefin functionalization/isomerization enables stereoselective alkene synthesis	39
Selective production of ethylene glycol at high rate via cascade catalysis	39
Bridging adsorption analytics and catalytic kinetics for metal-exchanged zeolites	38
Enzymatic control of endo- and exo-stereoselective Diels–Alder reactions with broad substrate scope	38
Programmable late-stage C−H bond functionalization enabled by integration of enzymes with chemocatalysis	38
Synthesis of tri- and tetrasubstituted stereocentres by nickel-catalysed enantioselective olefin cross-couplings	38
Promoting Cu-catalysed CO2 electroreduction to multicarbon products by tuning the activity of H2O	37
A strategic Ser/Cys exchange in the catalytic triad unlocks an acyltransferase-mediated synthesis of thioesters and tertiary amides	37
P-chirogenic phosphorus compounds by stereoselective Pd-catalysed arylation of phosphoramidites	37
Metabolic engineering of Escherichia coli with electron channelling for the production of natural products	37
Evidence of substrate binding and product release via belt-sulfur mobilization of the nitrogenase cofactor	37
Enhanced activity for the oxygen reduction reaction in microporous water	36
Catalytic role of carbonyl oxygens and water in selinadiene synthase	36
Photoenzymatic enantioselective intermolecular radical hydroamination	36
Site-selective proteolytic cleavage of plant viruses by photoactive chiral nanoparticles	36
Reaction environment impacts charge transfer but not chemical reaction steps in hydrogen evolution catalysis	35
Generation of oxide surface patches promoting H-spillover in Ru/(TiOx)MnO catalysts enables CO2 reduction to CO	35
Principles of target DNA cleavage and the role of Mg2+ in the catalysis of CRISPR–Cas9	34
Oxygenate-based routes regulate syngas conversion over oxide–zeolite bifunctional catalysts	33
Co(CN)3 catalysts with well-defined coordination structure for the oxygen reduction reaction	33
Biocatalytic synthesis of non-standard amino acids by a decarboxylative aldol reaction	33
Gold-catalysed asymmetric net addition of unactivated propargylic C–H bonds to tethered aldehydes	33
Ammonia history in the making	32
Artificial spherical chromatophore nanomicelles for selective CO2 reduction in water	32
Lewis acid-mediated Suzuki–Miyaura cross-coupling reaction	31
A strongly coupled Ru–CrOx cluster–cluster heterostructure for efficient alkaline hydrogen electrocatalysis	31
Anti-Markovnikov hydrochlorination and hydronitrooxylation of α-olefins via visible-light photocatalysis	31
Catalytic asymmetric α C(sp3)–H addition of benzylamines to aldehydes	31
Enantio- and diastereoselective construction of vicinal C(sp3) centres via nickel-catalysed hydroalkylation of alkenes	31
Solution-based Cu+ transient species mediate the reconstruction of copper electrocatalysts for CO2 reduction	30
Mechanically interlocked pyrene-based photocatalysts	30
An enantioselective ambimodal cross-Diels–Alder reaction and applications in synthesis	30
Electrolyte-assisted polarization leading to enhanced charge separation and solar-to-hydrogen conversion efficiency of seawater splitting	30
Selective synthesis of butane from carbon monoxide using cascade electrolysis and thermocatalysis at ambient conditions	30
Revisiting the universal principle for the rational design of single-atom electrocatalysts	30
High-throughput activity screening and sorting of single catalyst particles with a droplet microreactor using dielectrophoresis	29
Solving the activity–stability trade-off riddle	29
Engineering yeast metabolism for the discovery and production of polyamines and polyamine analogues	29
Three-dimensional nanoimaging of fuel cell catalyst layers	29
Dynamic and reversible transformations of subnanometre-sized palladium on ceria for efficient methane removal	29