Nature Catalysis

Article	Citations
Setting the standard	817
N-between the aryls	809
Greenwashed catalysis?	738
PASADENA NMR	707
Bioproduction from methanol	672
Enzyme-like water preorganization in a synthetic molecular cleft for homogeneous water oxidation catalysis	630
Localized thermal levering events drive spontaneous kinetic oscillations during CO oxidation on Rh/Al2O3	515
Enhancing the connection between computation and experiments in electrocatalysis	514
Enantio- and diastereoselective construction of vicinal C(sp3) centres via nickel-catalysed hydroalkylation of alkenes	510
Red light is ‘Go!’ for protein labelling	493
Exploration of the bio-analogous asymmetric C–C coupling mechanism in tandem CO2 electroreduction	480
Imagine polypropylene	446
Organic electrolyte cations promote non-aqueous CO2 reduction by mediating interfacial electric fields	434
Zn2+-mediated catalysis for fast-charging aqueous Zn-ion batteries	423
Role of the human-in-the-loop in emerging self-driving laboratories for heterogeneous catalysis	418
Structure and mechanism of haem-dependent nitrogen–nitrogen bond formation in piperazate synthase	409
Electrosynthesis of amino acids from NO and α-keto acids using two decoupled flow reactors	397
Double alkyl–alkyl bond construction across alkenes enabled by nickel electron-shuttle catalysis	383
Neither H2 nor O2 in hydrogenative oxidations with water	382
Silver linings	320
Methanotrophic catalysis for methane oxidation to formaldehyde	316
Density control	310
Identification of the active sites in supported subnanometric metal catalysts	284
Identifying and avoiding dead ends in the characterization of heterogeneous catalysts at the gas–solid interface	284
Programmed exosome fusion for energy generation in living cells	278

Understanding the interplay between electrocatalytic C(sp3)‒C(sp3) fragmentation and oxygenation reactions	269
Electrocatalytic hydrogenation of alkenes with Pd/carbon nanotubes at an oil–water interface	267
RNA-catalysed guanosine methylation	263
The synchronized catalytic dance of CRISPR-Cas9	256
Author Correction: Epistasis arises from shifting the rate-limiting step during enzyme evolution of a β-lactamase	251
Motorized catalysis	250
Electrochemistry-inspired design of thermocatalysts	250
The iron-catalysed Suzuki coupling of aryl chlorides	245
Room temperature photo-promoted iron-catalysed arene C–H alkenylation without Grignard reagents	244
Light-induced Pd catalyst enables C(sp2)–C(sp2) cross-electrophile coupling bypassing the demand for transmetalation	243
Unified mechanistic understanding of CO2 reduction to CO on transition metal and single atom catalysts	241
Ternary platinum–cobalt–indium nanoalloy on ceria as a highly efficient catalyst for the oxidative dehydrogenation of propane using CO2	240
Peripheral-nitrogen effects on the Ru1 centre for highly efficient propane dehydrogenation	234
H2-reduced phosphomolybdate promotes room-temperature aerobic oxidation of methane to methanol	233
Direct conversion of methane with O2 at room temperature over edge-rich MoS2	232
Symbiotic oxides in catalysts	230
Valence oscillation and dynamic active sites in monolayer NiCo hydroxides for water oxidation	217
Choreography of a self-splicing ribozyme	215
The rise of ab initio surface thermodynamics	213
O2 so good	207
Active sites overcrowding	201
Iminium catalysis in natural Diels–Alderase	199
Current state and future prospects of liquid metal catalysis	198
Iron-catalysed cooperative redox mechanism for the simultaneous conversion of nitrous oxide and nitric oxide	197
Enzymatic catalysis favours eight-membered over five-membered ring closure in bicyclomycin biosynthesis	195
Metabolic network remodelling enhances yeast’s fitness on xylose using aerobic glycolysis	194
Photoelectrochemical asymmetric dehydrogenative [2 + 2] cycloaddition between C–C single and double bonds via the activation of two C(sp3)–H bonds	190
A non-carboxylative route for the efficient synthesis of central metabolite malonyl-CoA and its derived products	186
Exploring mesoscopic mass transport effects on electrocatalytic selectivity	184
Pulsed electrolysis through neutron lenses	172
Optimizing iridium sites	172
Heavy labels from gas surrogates	169
Retro Hits	168
Steam methane reforming using a regenerable antenna–reactor plasmonic photocatalyst	166
Dinuclear Cu(I) molecular electrocatalyst for CO2-to-C3 product conversion	165
Remote site-selective arene C–H functionalization enabled by N-heterocyclic carbene organocatalysis	164
Probing electrolyte effects on cation-enhanced CO2 reduction on copper in acidic media	164
Solution-based Cu+ transient species mediate the reconstruction of copper electrocatalysts for CO2 reduction	162
The role of Cu1–O3 species in single-atom Cu/ZrO2 catalyst for CO2 hydrogenation	159
One, two, three, four, five!	158
Catalytic borylation of tertiary C–H bonds	157
Onto the Surface	156
Organocatalytic acylation of remote arene C–H bonds	152
Catalysing rate and capacity	151
Organocatalytic olefin C–H functionalization for enantioselective synthesis of atropisomeric 1,3-dienes	150
Durable MnO2 electrocatalysts by stronger Mn–O bonds	149
Wireless potentiometry of thermochemical heterogeneous catalysis	147
Bubble trouble	147
Reassessment of the catalytic activity of bismuth for aqueous nitrogen electroreduction	142
In situ lysosomal proteomics enabled by bioorthogonal photocatalytic proximity labelling	142

Germanium-enriched double-four-membered-ring units inducing zeolite-confined subnanometric Pt clusters for efficient propane dehydrogenation	141
N-Heterocyclic carbenes as tunable ligands for catalytic metal surfaces	141
Concerted methane fixation at ambient temperature and pressure mediated by an alcohol oxidase and Fe-ZSM-5 catalytic couple	140
A fine adjustment	137
Lengthened by ethylene	136
Frustration-driven efficiency	134
Doing without diazos	134
CYP screening for a better terpenoid world	132
Author Correction: Stereoselective alkyl–alkyl cross-coupling	132
Tailored for semi-hydrogenation	125
Blowing in the tube	123
Publisher Correction: Parahydrogen-enhanced magnetic resonance identification of intermediates in [Fe]-hydrogenase catalysis	122
Uniting biological and chemical strategies for selective CO2 reduction	115
Synthesis of tri- and tetrasubstituted stereocentres by nickel-catalysed enantioselective olefin cross-couplings	115
Step bunching instability and its effects in electrocatalysis on platinum surfaces	113
Ammonia synthesis via an engineered nitrogenase assembly pathway in Escherichia coli	112
Active-site isolation in intermetallics enables precise identification of elementary reaction kinetics during olefin hydrogenation	112
Regioselective silyl installation for arene diversification	111
Enantioselective Chan–Lam S-arylation of sulfenamides	110
Bridging catalysis	110
High-purity carbon monoxide production via photothermal formic acid decomposition over fluorite ZrO2	107
Nickel-electrocatalysed C(sp3)–C(sp3) cross-coupling of unactivated alkyl halides	107
A synthetic methylotrophic Escherichia coli as a chassis for bioproduction from methanol	106
Reactant-induced dynamics of lithium imide surfaces during the ammonia decomposition process	106
The role of ruthenium in improving the kinetics of hydrogen oxidation and evolution reactions of platinum	105
An efficient Morita–Baylis–Hillmanase	105
Cationic-group-functionalized electrocatalysts enable stable acidic CO2 electrolysis	105
Chemoselective carbene transfer	103
Cations in alkaline hydrogen electrocatalysis	103
A hydrogenative oxidation strategy for the single-step synthesis of lactams from N-heteroarenes using water	103
Modular biocatalysis for polyamines	103
Divide and conquer towards synthetic autotrophy	102
The STRENDA Biocatalysis Guidelines for cataloguing metadata	101
Shining light to break planarity	99
Terpene synthases in giant viruses	98
Identifying restructured motifs on iridium oxide catalyst surfaces for water electrolysis	98
Monitoring catalytic nanosites in action	97
Atomically dispersed iridium on MgO(111) nanosheets catalyses benzene–ethylene coupling towards styrene	96
Thioester-mediated biocatalytic amide bond synthesis with in situ thiol recycling	95
Identifying high-spin hydroxyl-coordinated Fe3+N4 as the active centre for acidic oxygen reduction using molecular model catalysts	94
The shape of water in zeolites and its impact on epoxidation catalysis	93
Photoinduced gold-catalyzed divergent dechloroalkylation of gem-dichloroalkanes	93
Operando visualization of the hydrogen evolution reaction with atomic-scale precision at different metal–graphene interfaces	92
Electrocatalytic dual hydrogenation of organic substrates with a Faradaic efficiency approaching 200%	91
Metabolic engineering of Escherichia coli with electron channelling for the production of natural products	91
Mass-based biocatalyst metrics to guide protein engineering and bioprocess development	90
The catalytic role of glutathione transferases in heterologous anthocyanin biosynthesis	88
Atomically dispersed ruthenium hydride on beta zeolite as catalysts for the isomerization of muconates	88
Author Correction: Oxygen evolution reaction over catalytic single-site Co in a well-defined brookite TiO2 nanorod surface	87
Metastable nickel–oxygen species modulate rate oscillations during dry reforming of methane	86
Generative machine learning produces kinetic models that accurately characterize intracellular metabolic states	86
Methyl formate as a hydrogen energy carrier	86
Enhanced CO2 utilization in dry reforming of methane achieved through nickel-mediated hydrogen spillover in zeolite crystals	85
Key role of paracrystalline motifs on iridium oxide surfaces for acidic water oxidation	84
Iron-only Fe-nitrogenase underscores common catalytic principles in biological nitrogen fixation	82
Analysis of the limitations in the oxygen reduction activity of transition metal oxide surfaces	81
Long-range enhancements of micropollutant adsorption on metal-promoted photocatalysts	81
Identifying and alleviating the durability challenges in membrane-electrode-assembly devices for high-rate CO electrolysis	81
Optimizing the p charge of S in p-block metal sulfides for sulfur reduction electrocatalysis	81
Upcycling CO2 into energy-rich long-chain compounds via electrochemical and metabolic engineering	79
A strongly coupled Ru–CrOx cluster–cluster heterostructure for efficient alkaline hydrogen electrocatalysis	79
Stereoselective construction of β-, γ- and δ-lactam rings via enzymatic C–H amidation	78
Recharge your batteries	78
Scatter and conquer	78
Epistasis arises from shifting the rate-limiting step during enzyme evolution of a β-lactamase	78
Intramolecular hydroxyl nucleophilic attack pathway by a polymeric water oxidation catalyst with single cobalt sites	77
Coupling electrochemical CO2 conversion with CO2 capture	76
Ultralow overpotential nitrate reduction to ammonia via a three-step relay mechanism	75
Light on peroxide	75
Acetylene hydrogenation to ethylene by water at low temperature on a Au/α-MoC catalyst	75
Site-selective arene C–H amination with iron-aminyl radical	75
An antidote for chemical reaction networks	75
Author Correction: Origin of active sites on silica–magnesia catalysts and control of reactive environment in the one-step ethanol-to-butadiene process	75
Privileged Brønsted acid organocatalysis	73
Precision installation of silyl synthetic handles within arenes by regiocontrolled ruthenium C(sp2)–H functionalization	73
Critical insights into the steam electrolysis electrode in protonic ceramic cells for hydrogen production	71
Photoenzymatic enantioselective intermolecular radical hydroamination	71
Olefin functionalization/isomerization enables stereoselective alkene synthesis	70
Publisher Correction: Gas-balancing adsorption strategy towards noble-metal-based nanowire electrocatalysts	69
Amorphizing noble metal chalcogenide catalysts at the single-layer limit towards hydrogen production	69

Deciphering electrochemical methanol production	69
Achieving maximum overall light enhancement in plasmonic catalysis by combining thermal and non-thermal effects	69
Seeking selectivity in alkene couplings	68
Organocatalytic asymmetric α-C–H functionalization of alkyl amines	68
Self-correcting science at work	68
Benign hyperpolarization	68
Effective anions	67
Methane oxidation by catalyst reduction	65
Chiral phosphorus compounds by catalytic asymmetric C–P coupling	65
Generating alkyl carbanions for organic synthesis	65
Biocatalytic synthesis of non-standard amino acids by a decarboxylative aldol reaction	63
Revealing in-plane movement of platinum in polymer electrolyte fuel cells after heavy-duty vehicle lifetime	63
A pyridoxal 5′-phosphate-dependent Mannich cyclase	63
Alkene 1,1-difunctionalizations via organometallic-radical relay	62
Regioselective hydroformylation with subnanometre Rh clusters in MFI zeolite	62
The 3D secrets of fuel cell catalyst layers	62
Eliminating redox-mediated electron transfer mechanisms on a supported molecular catalyst enables CO2 conversion to ethanol	62
Defying thermodynamics to synthetize hydrazine	61
Nickel-catalysed enantioselective alkene dicarbofunctionalization enabled by photochemical aliphatic C–H bond activation	61
High-purity and high-concentration liquid fuels through CO2 electroreduction	60
Electrons are catalysts too	59
Assisting with protons	59
A structured catalyst for anion exchange membrane water electrolysis	59
Rising to the surface	59
Electrifying start-up	58
Artificial enzymes for artificial photosynthesis	58
Electrocatalytic conversion of carbon dioxide for the Paris goals	57
A red-light-powered silicon nanowire biophotochemical diode for simultaneous CO2 reduction and glycerol valorization	57
The value of negative results in data-driven catalysis research	56
Blocking the reverse reactions of overall water splitting on a Rh/GaN–ZnO photocatalyst modified with Al2O3	56
The functional coupling between restriction and DNA phosphorothioate modification systems underlying the DndFGH restriction complex	56
Absence of CO2 electroreduction on copper, gold and silver electrodes without metal cations in solution	55
Congested C(sp3)-rich architectures enabled by iron-catalysed conjunctive alkylation	54
Immobilized cations boost acidic CO2 reduction	54
Visible-light photocatalytic di- and hydro-carboxylation of unactivated alkenes with CO2	54
Catalytic mechanism for Renilla-type luciferases	54
Active alloy ahoy!	53
Sustainable methanol synthesis	53
Author Correction: Reversely trapping atoms from a perovskite surface for high-performance and durable fuel cell cathodes	53
The masked synthon	53
Unlocking C–C cleavage in the electrochemical toolbox	53
Molecular mechanism of topoisomerase poisoning by the peptide antibiotic albicidin	52
Enantioconvergent copper-catalysed difluoromethylation of alkyl halides	52
The era of stable electrocatalysis	52
A semiconducting polymer bulk heterojunction photoanode for solar water oxidation	51
Catalytic cycle of formate dehydrogenase captured by single-molecule conductance	51
Tunable layered Mn oxides for oxygen electrocatalysis	51
Hydrogen-bonded organic framework-based bioorthogonal catalysis prevents drug metabolic inactivation	51
Threshold potentials for fast kinetics during mediated redox catalysis of insulators in Li–O2 and Li–S batteries	49
Structurally defined anti-π-allyliridium complexes catalyse Z-retentive asymmetric allylic alkylation of oxindoles	49
Iron-catalysed alkenylzincation of allenes via electrophilicity reversal	49
Principles of target DNA cleavage and the role of Mg2+ in the catalysis of CRISPR–Cas9	48
Reversely trapping atoms from a perovskite surface for high-performance and durable fuel cell cathodes	48
An enantioselective ambimodal cross-Diels–Alder reaction and applications in synthesis	48
Facile access to fused 2D/3D rings via intermolecular cascade dearomative [2 + 2] cycloaddition/rearrangement reactions of quinolines with alkenes	47
Enhancing the stability of cobalt spinel oxide towards sustainable oxygen evolution in acid	47
Rates against the machine	47
Different distributions of multi-carbon products in CO2 and CO electroreduction under practical reaction conditions	47
Following the structure of copper-zinc-alumina across the pressure gap in carbon dioxide hydrogenation	47
Edge sites dominate the hydrogen evolution reaction on platinum nanocatalysts	46
Sub-micro- and nano-sized polyethylene terephthalate deconstruction with engineered protein nanopores	46
Critical enzyme reactions in aromatic catabolism for microbial lignin conversion	45
Starch synthesis from CO2	45
A zero-gap bipolar solution	45
Publisher Correction: A selective Au-ZnO/TiO2 hybrid photocatalyst for oxidative coupling of methane to ethane with dioxygen	45
Microenvironment control	45
Radical dissolution	45
Activating catalysts by adsorbate-induced reconstructions	45
Iridium nitrenoid-enabled arene C−H functionalization	44
Mimicking hydrogen-atom-transfer-like reactivity in copper-catalysed olefin hydrofunctionalization	44
And yet it rotates!	44
Decoding CO2 hydrogenation	44
Unveiling metal mobility in a liquid Cu–Ga catalyst for ammonia synthesis	43
Birth of organocatalysis by N-heterocyclic carbenes	42
Photoenzymes for radical C–C coupling	41
Split cross-coupling via Rh-catalysed activation of unstrained aryl–aryl bonds	40
Delocalization state-induced selective bond breaking for efficient methanol electrosynthesis from CO2	39
Visible light-mediated intermolecular crossed [2+2] cycloadditions using a MOF-supported copper triplet photosensitizer	39
Direct propylene epoxidation with oxygen using a photo-electro-heterogeneous catalytic system	38
The why and how of NOx electroreduction to ammonia	38
Three-dimensional nanoimaging of fuel cell catalyst layers	38
Atomic-scale surface restructuring of copper electrodes under CO2 electroreduction conditions	38
Breaking structure sensitivity in CO2 hydrogenation by tuning metal–oxide interfaces in supported cobalt nanoparticles	37
Bimetallic monolayer catalyst breaks the activity–selectivity trade-off on metal particle size for efficient chemoselective hydrogenations	37
Four on the floor	37
Electrified synthesis of n-propanol using a dilute alloy catalyst	36
Work in tandem	36
Structure and engineering of miniature Acidibacillus sulfuroxidans Cas12f1	36
A precious pair for aldols	36
Oxide mixology	36
Oxygen evolving atoms	35
Reply to: Reassessment of the catalytic activity of bismuth for aqueous nitrogen electroreduction	35
Ammonia to chiral α-amino acid	35
Pushing hybrids to the limits	34
ML helps predict enzyme turnover rates	34