Nature Catalysis

Article	Citations
Greenwashed catalysis?	909
Bioproduction from methanol	714
Red light is ‘Go!’ for protein labelling	594
PASADENA NMR	587
N-between the aryls	578
Zeolites like to move it	488
Supramolecular control of cationic intermediates	482
Structure and mechanism of haem-dependent nitrogen–nitrogen bond formation in piperazate synthase	442
An NAD⁺ analogue enables assembly of structurally diverse artificial photoenzymes for enantiodivergent [2 + 2] cycloadditions	410
Enzyme-like water preorganization in a synthetic molecular cleft for homogeneous water oxidation catalysis	405
Localized thermal levering events drive spontaneous kinetic oscillations during CO oxidation on Rh/Al2O3	399
Double alkyl–alkyl bond construction across alkenes enabled by nickel electron-shuttle catalysis	398
Exploration of the bio-analogous asymmetric C–C coupling mechanism in tandem CO2 electroreduction	395
Organic electrolyte cations promote non-aqueous CO2 reduction by mediating interfacial electric fields	390
Role of the human-in-the-loop in emerging self-driving laboratories for heterogeneous catalysis	372
Electrosynthesis of amino acids from NO and α-keto acids using two decoupled flow reactors	354
Zn2+-mediated catalysis for fast-charging aqueous Zn-ion batteries	329
Enantio- and diastereoselective construction of vicinal C(sp3) centres via nickel-catalysed hydroalkylation of alkenes	317
Imagine polypropylene	305
Electrocatalytic upcycling of high-pressure captured CO2 to ethylene	301
Methanotrophic catalysis for methane oxidation to formaldehyde	286
Neither H2 nor O2 in hydrogenative oxidations with water	285
Room temperature photo-promoted iron-catalysed arene C–H alkenylation without Grignard reagents	276
Pulsed away	276
Growing the carbon chain	274

Density control	273
The synchronized catalytic dance of CRISPR-Cas9	264
Symbiotic oxides in catalysts	257
Fluoroform for PET	256
Light-induced Pd catalyst enables C(sp2)–C(sp2) cross-electrophile coupling bypassing the demand for transmetalation	251
Iron-based single-atom catalysts for selective ammoxidation of C(sp3)–H bonds and oxidative C–C cleavage reactions	240
Behind the curtain	235
H2-reduced phosphomolybdate promotes room-temperature aerobic oxidation of methane to methanol	232
Identifying and avoiding dead ends in the characterization of heterogeneous catalysts at the gas–solid interface	227
Quantum computing for faster enzyme discovery and engineering	224
Motorized catalysis	211
Electrocatalytic hydrogenation of alkenes with Pd/carbon nanotubes at an oil–water interface	209
Understanding the interplay between electrocatalytic C(sp3)‒C(sp3) fragmentation and oxygenation reactions	207
Electrochemistry-inspired design of thermocatalysts	206
Author Correction: Epistasis arises from shifting the rate-limiting step during enzyme evolution of a β-lactamase	205
Direct conversion of methane with O2 at room temperature over edge-rich MoS2	202
The iron-catalysed Suzuki coupling of aryl chlorides	202
Tailored water–surface interactions on cobalt oxide for stable proton-exchange-membrane water electrolysis	195
Peripheral-nitrogen effects on the Ru1 centre for highly efficient propane dehydrogenation	191
Choreography of a self-splicing ribozyme	189
Heavy labels from gas surrogates	188
Optimizing iridium sites	187
Iminium catalysis in natural Diels–Alderase	183
A non-carboxylative route for the efficient synthesis of central metabolite malonyl-CoA and its derived products	180
The rise of ab initio surface thermodynamics	178
Current state and future prospects of liquid metal catalysis	178
Enantioselective radical dearomative conjugate amination enabled by Co(II)-based metalloradical catalysis	177
Electrolysis in tandem	172
Substrate promiscuity fuels biosynthesis success	172
Active sites overcrowding	168
Pulsed electrolysis through neutron lenses	167
Enzymatic catalysis favours eight-membered over five-membered ring closure in bicyclomycin biosynthesis	164
Steam methane reforming using a regenerable antenna–reactor plasmonic photocatalyst	164
Quantum-sensing-enabled in situ imaging of free radicals in chemical reactions	163
Copper-catalysed enantioconvergent O-alkylation of alcohols with racemic α-tertiary haloamides to access enantioenriched hindered dialkyl ethers	158
Dinuclear Cu(I) molecular electrocatalyst for CO2-to-C3 product conversion	157
Iron-catalysed cooperative redox mechanism for the simultaneous conversion of nitrous oxide and nitric oxide	155
Morphological and chemical state effects in pulsed CO2 electroreduction on Cu(100) unveiled by correlated spectro-microscopy	155
Remote site-selective arene C–H functionalization enabled by N-heterocyclic carbene organocatalysis	155
Probing electrolyte effects on cation-enhanced CO2 reduction on copper in acidic media	154
Electrolyte effects in proton–electron transfer reactions and implications for renewable fuels and chemicals synthesis	153
The role of Cu1–O3 species in single-atom Cu/ZrO2 catalyst for CO2 hydrogenation	151
Subnanometre PtSn alloyed clusters encapsulated in silicalite-1 sustain high productivity in propane dehydrogenation	149
Exploring mesoscopic mass transport effects on electrocatalytic selectivity	146
Solution-based Cu+ transient species mediate the reconstruction of copper electrocatalysts for CO2 reduction	145
Photoelectrochemical asymmetric dehydrogenative [2 + 2] cycloaddition between C–C single and double bonds via the activation of two C(sp3)–H bonds	144
Organocatalytic acylation of remote arene C–H bonds	139
Catalytic borylation of tertiary C–H bonds	138
Triplet quenchers for energy-transfer photobiocatalysis	137
Modulation to probe the interface	137

Catalysing rate and capacity	134
Organocatalytic olefin C–H functionalization for enantioselective synthesis of atropisomeric 1,3-dienes	133
Bubble trouble	133
Practical conversion of carboxylic acids to nitriles	132
One, two, three, four, five!	128
Durable MnO2 electrocatalysts by stronger Mn–O bonds	128
Structural insights and engineering of the T4 td intron for improved RNA circularization	128
Concerted methane fixation at ambient temperature and pressure mediated by an alcohol oxidase and Fe-ZSM-5 catalytic couple	125
Splitting water under dryness	125
Determining CO adsorption free energies on CO2 electroreduction active sites through kinetic analysis	123
Ligand binding to a Ni–Fe cluster orchestrates conformational changes of the CO-dehydrogenase–acetyl-CoA synthase complex	122
Wireless potentiometry of thermochemical heterogeneous catalysis	120
Germanium-enriched double-four-membered-ring units inducing zeolite-confined subnanometric Pt clusters for efficient propane dehydrogenation	119
In situ lysosomal proteomics enabled by bioorthogonal photocatalytic proximity labelling	118
Blowing in the tube	116
CYP screening for a better terpenoid world	114
Author Correction: Stereoselective alkyl–alkyl cross-coupling	112
Publisher Correction: Parahydrogen-enhanced magnetic resonance identification of intermediates in [Fe]-hydrogenase catalysis	112
Frustration-driven efficiency	112
Tailored for semi-hydrogenation	111
Bridging catalysis	109
Regioselective silyl installation for arene diversification	109
Cobalt-catalysed alkene hydronitration enabled by anomeric nitroamide	108
Author Correction: A polyketide-based biosynthetic platform for diols, amino alcohols and hydroxy acids	107
And yet it catalyses	107
A fine adjustment	107
Ammonia synthesis via an engineered nitrogenase assembly pathway in Escherichia coli	107
Silicon frustrated Lewis pairs catalyse α-deuteration of amides and esters	106
Electrosynthesis of ethylene glycol from ethylene coupled with CO2 capture	104
High-purity carbon monoxide production via photothermal formic acid decomposition over fluorite ZrO2	104
Direct electrochemical propylene epoxidation over amorphized perovskite oxide in non-halogenated aqueous electrolyte	103
Step bunching instability and its effects in electrocatalysis on platinum surfaces	103
Understanding Mn-modulated restructuring of Fe-based catalysts for controlling selectivity in CO2 hydrogenation to olefins	102
Enantioselective Chan–Lam S-arylation of sulfenamides	102
A synthetic methylotrophic Escherichia coli as a chassis for bioproduction from methanol	101
Reactant-induced dynamics of lithium imide surfaces during the ammonia decomposition process	101
Cationic-group-functionalized electrocatalysts enable stable acidic CO2 electrolysis	99
Dissolved Fe species enable a cooperative solid–molecular mechanism for the oxygen evolution reaction on NiFe-based catalysts	96
Synthesis of tri- and tetrasubstituted stereocentres by nickel-catalysed enantioselective olefin cross-couplings	95
Nickel-electrocatalysed C(sp3)–C(sp3) cross-coupling of unactivated alkyl halides	95
Continuity of reaction kinetics across the pressure and materials gaps in CO oxidation on FeO–Pt interfaces	95
Active-site isolation in intermetallics enables precise identification of elementary reaction kinetics during olefin hydrogenation	95
Divide and conquer towards synthetic autotrophy	94
Terpene synthases in giant viruses	94
Shining light to break planarity	93
Catalyst optimization through synthetic Darwinian evolution	93
Identifying restructured motifs on iridium oxide catalyst surfaces for water electrolysis	93
A TIM-barrel metalloenzyme with sugar-cleavage activity	92
Photoinduced gold-catalyzed divergent dechloroalkylation of gem-dichloroalkanes	92
Molecular-scale interactions in heterogeneous (photo)electrocatalysis	91
Atomically dispersed ruthenium hydride on beta zeolite as catalysts for the isomerization of muconates	90
Iron-only Fe-nitrogenase underscores common catalytic principles in biological nitrogen fixation	90
Thioester-mediated biocatalytic amide bond synthesis with in situ thiol recycling	90
A modular synthesis of azetidines from reactive triplet imine intermediates using an intermolecular aza Paternò–Büchi reaction	90
Cobalt hydride-mediated photocatalytic semihydrogenation of acetylene impurities for continuous-flow production of polymer-grade ethylene	90
Long-range enhancements of micropollutant adsorption on metal-promoted photocatalysts	89
A hydrogenative oxidation strategy for the single-step synthesis of lactams from N-heteroarenes using water	89
Monitoring catalytic nanosites in action	88
Key role of paracrystalline motifs on iridium oxide surfaces for acidic water oxidation	85
Understanding two voltammetric features of water reduction and water oxidation in mild pH solutions	85
Enhanced CO2 utilization in dry reforming of methane achieved through nickel-mediated hydrogen spillover in zeolite crystals	84
Cations in alkaline hydrogen electrocatalysis	83
The catalytic role of glutathione transferases in heterologous anthocyanin biosynthesis	83
Electrocatalytic dual hydrogenation of organic substrates with a Faradaic efficiency approaching 200%	81
Metabolic engineering of Escherichia coli with electron channelling for the production of natural products	80
Identifying and alleviating the durability challenges in membrane-electrode-assembly devices for high-rate CO electrolysis	79
Stable acidic oxygen-evolving catalyst discovery through mixed accelerations	78
The STRENDA Biocatalysis Guidelines for cataloguing metadata	78
Generative machine learning produces kinetic models that accurately characterize intracellular metabolic states	78
Metastable nickel–oxygen species modulate rate oscillations during dry reforming of methane	77
Optimizing the p charge of S in p-block metal sulfides for sulfur reduction electrocatalysis	77
Boron clusters as efficient shuttles for electrocatalytic deuterium labelling via radical H/D exchange	76
Identifying high-spin hydroxyl-coordinated Fe3+N4 as the active centre for acidic oxygen reduction using molecular model catalysts	76
A strongly coupled Ru–CrOx cluster–cluster heterostructure for efficient alkaline hydrogen electrocatalysis	76
Methyl formate as a hydrogen energy carrier	74
Recharge your batteries	74
Scatter and conquer	73
Shielding PEM electrolysers from real-world water	72
Author Correction: Co3O4 as full-solar-spectrum photocatalyst for selective methane conversion through reactive oxygen species control	71
Enantioselective C(sp3)–C(sp3) bond formation by synergistic thiamine-dependent radical biocatalysis and photoredox catalysis	71

Acetylene hydrogenation to ethylene by water at low temperature on a Au/α-MoC catalyst	71
Photobiocatalytic stereocontrol of two prochiral radicals	71
Stereoselective construction of β-, γ- and δ-lactam rings via enzymatic C–H amidation	70
Electrochemical imaging of thermochemical catalysis	69
Ultralow overpotential nitrate reduction to ammonia via a three-step relay mechanism	68
Epistasis arises from shifting the rate-limiting step during enzyme evolution of a β-lactamase	68
An antidote for chemical reaction networks	67
Author Correction: Origin of active sites on silica–magnesia catalysts and control of reactive environment in the one-step ethanol-to-butadiene process	67
Shape matters too	67
Synthesis of α,α-diheteroatomic carboxylic acids	66
Complex behaviour of isotopes in CO2 electroreduction	66
Challenges and prospects in precision medicine with RNA-based biocatalysts	66
Light-driven metabolic makeover	66
Privileged Brønsted acid organocatalysis	65
Precision installation of silyl synthetic handles within arenes by regiocontrolled ruthenium C(sp2)–H functionalization	65
Photoenzymatic enantioselective intermolecular radical hydroamination	65
Achieving maximum overall light enhancement in plasmonic catalysis by combining thermal and non-thermal effects	64
Site-selective arene C–H amination with iron-aminyl radical	64
Critical insights into the steam electrolysis electrode in protonic ceramic cells for hydrogen production	64
Seeking selectivity in alkene couplings	63
Defying thermodynamics to synthetize hydrazine	62
Benign hyperpolarization	62
Deciphering electrochemical methanol production	62
Methane oxidation by catalyst reduction	60
Effective anions	60
A pyridoxal 5′-phosphate-dependent Mannich cyclase	59
Publisher Correction: Gas-balancing adsorption strategy towards noble-metal-based nanowire electrocatalysts	59
Generating alkyl carbanions for organic synthesis	59
Unlocking iron spin states for oxygen reduction	59
The 3D secrets of fuel cell catalyst layers	58
Harnessing thia-Rh-carbenes for the enantioselective synthesis of chiral α,α-diheteroatomic carboxylic acids	58
Organocatalytic regio- and stereoselective cyclopropanation of olefins	57
Alkene 1,1-difunctionalizations via organometallic-radical relay	57
Nickel-catalysed enantioselective alkene dicarbofunctionalization enabled by photochemical aliphatic C–H bond activation	56
Eliminating redox-mediated electron transfer mechanisms on a supported molecular catalyst enables CO2 conversion to ethanol	56
Operando probing dynamic migration of copper carbonyl during electrocatalytic CO2 reduction	55
Organocatalytic asymmetric α-C–H functionalization of alkyl amines	55
Regioselective hydroformylation with subnanometre Rh clusters in MFI zeolite	55
Revealing in-plane movement of platinum in polymer electrolyte fuel cells after heavy-duty vehicle lifetime	55
A radical way to ethylene	55
Rising to the surface	54
Iron-catalysed carbene and carbene radical cascade reactions for the synthesis of carbocyclic molecules	54
Controlling carbocations	54
Strain boosts propanol electrosynthesis from CO on copper	54
Congested C(sp3)-rich architectures enabled by iron-catalysed conjunctive alkylation	53
Immobilized cations boost acidic CO2 reduction	53
Artificial enzymes for artificial photosynthesis	53
A structured catalyst for anion exchange membrane water electrolysis	53
The value of negative results in data-driven catalysis research	52
The functional coupling between restriction and DNA phosphorothioate modification systems underlying the DndFGH restriction complex	51
Blocking the reverse reactions of overall water splitting on a Rh/GaN–ZnO photocatalyst modified with Al2O3	51
Catalytic mechanism for Renilla-type luciferases	50
A red-light-powered silicon nanowire biophotochemical diode for simultaneous CO2 reduction and glycerol valorization	50
Pushing the boundaries of biocatalysis	50
Active alloy ahoy!	50
Visible-light photocatalytic di- and hydro-carboxylation of unactivated alkenes with CO2	50
Sustainable methanol synthesis	49
Unlocking C–C cleavage in the electrochemical toolbox	49
Iron-catalysed alkenylzincation of allenes via electrophilicity reversal	48
The return of the nickel(I) isocyanide	48
Atroposelective organocatalytic nucleophilic aromatic substitution for C–O bond construction	48
Author Correction: Reversely trapping atoms from a perovskite surface for high-performance and durable fuel cell cathodes	46
Rates against the machine	46
Tunable layered Mn oxides for oxygen electrocatalysis	45
Clustering for methane	45
Principles of target DNA cleavage and the role of Mg2+ in the catalysis of CRISPR–Cas9	45
Hydrogen-bonded organic framework-based bioorthogonal catalysis prevents drug metabolic inactivation	44
A geometric foundation model for enzyme retrieval with evolutionary insights	44
Molecular mechanism of topoisomerase poisoning by the peptide antibiotic albicidin	44
Sub-micro- and nano-sized polyethylene terephthalate deconstruction with engineered protein nanopores	43
The era of stable electrocatalysis	43
Different distributions of multi-carbon products in CO2 and CO electroreduction under practical reaction conditions	43
Structurally defined anti-π-allyliridium complexes catalyse Z-retentive asymmetric allylic alkylation of oxindoles	42
Catalytic cycle of formate dehydrogenase captured by single-molecule conductance	42
Edge sites dominate the hydrogen evolution reaction on platinum nanocatalysts	42
Enantioconvergent copper-catalysed difluoromethylation of alkyl halides	42
Microenvironment control	41
Decoding CO2 hydrogenation	41
Establishing coupling trends	41
Unveiling active sites and the cooperative role of non-thermal plasma and copper–zinc catalysts in the hydrogenation of CO2 to methanol	41
Degradation through filaments	40
Iridium nitrenoid-enabled arene C−H functionalization	40
Radical dissolution	40
And yet it rotates!	39
Visible light-mediated intermolecular crossed [2+2] cycloadditions using a MOF-supported copper triplet photosensitizer	39
Photoenzymes for radical C–C coupling	39
Mimicking hydrogen-atom-transfer-like reactivity in copper-catalysed olefin hydrofunctionalization	39
Iron–sulfur cluster with double duty	39
Split cross-coupling via Rh-catalysed activation of unstrained aryl–aryl bonds	38
Three-dimensional nanoimaging of fuel cell catalyst layers	38
Unveiling metal mobility in a liquid Cu–Ga catalyst for ammonia synthesis	38
The why and how of NOx electroreduction to ammonia	37
Selective electrooxidation of 5-hydroxymethylfurfural at pilot scale by engineering a solid polymer electrolyte reactor	37
Delocalization state-induced selective bond breaking for efficient methanol electrosynthesis from CO2	37
The deuterium source matters	37