Nature Catalysis

Article	Citations
Greenwashed catalysis?	951
Bioproduction from methanol	775
Red light is ‘Go!’ for protein labelling	594
PASADENA NMR	530
N-between the aryls	516
Zeolites like to move it	442
Supramolecular control of cationic intermediates	441
Enantio- and diastereoselective construction of vicinal C(sp3) centres via nickel-catalysed hydroalkylation of alkenes	437
Structure and mechanism of haem-dependent nitrogen–nitrogen bond formation in piperazate synthase	421
Imagine polypropylene	412
Localized thermal levering events drive spontaneous kinetic oscillations during CO oxidation on Rh/Al2O3	412
Enzyme-like water preorganization in a synthetic molecular cleft for homogeneous water oxidation catalysis	400
An NAD⁺ analogue enables assembly of structurally diverse artificial photoenzymes for enantiodivergent [2 + 2] cycloadditions	352
Electrocatalytic upcycling of high-pressure captured CO2 to ethylene	343
Zn2+-mediated catalysis for fast-charging aqueous Zn-ion batteries	332
Electrosynthesis of amino acids from NO and α-keto acids using two decoupled flow reactors	332
Double alkyl–alkyl bond construction across alkenes enabled by nickel electron-shuttle catalysis	311
Exploration of the bio-analogous asymmetric C–C coupling mechanism in tandem CO2 electroreduction	304
Organic electrolyte cations promote non-aqueous CO2 reduction by mediating interfacial electric fields	301
Role of the human-in-the-loop in emerging self-driving laboratories for heterogeneous catalysis	292
Methanotrophic catalysis for methane oxidation to formaldehyde	288
Neither H2 nor O2 in hydrogenative oxidations with water	283
Pulsed away	271
Room temperature photo-promoted iron-catalysed arene C–H alkenylation without Grignard reagents	266
Growing the carbon chain	259

Density control	258
The synchronized catalytic dance of CRISPR-Cas9	253
Symbiotic oxides in catalysts	250
Fluoroform for PET	244
Light-induced Pd catalyst enables C(sp2)–C(sp2) cross-electrophile coupling bypassing the demand for transmetalation	241
Behind the curtain	221
Quantum computing for faster enzyme discovery and engineering	215
Motorized catalysis	214
Electrochemistry-inspired design of thermocatalysts	213
Author Correction: Epistasis arises from shifting the rate-limiting step during enzyme evolution of a β-lactamase	211
The iron-catalysed Suzuki coupling of aryl chlorides	210
Understanding the interplay between electrocatalytic C(sp3)‒C(sp3) fragmentation and oxygenation reactions	210
H2-reduced phosphomolybdate promotes room-temperature aerobic oxidation of methane to methanol	210
Direct conversion of methane with O2 at room temperature over edge-rich MoS2	209
Electrocatalytic hydrogenation of alkenes with Pd/carbon nanotubes at an oil–water interface	206
Publisher Correction: Atomically precise layer-by-layer titration of perovskite oxides reveals the termination-specific reactivity in oxygen electrocatalysis	204
Iron-based single-atom catalysts for selective ammoxidation of C(sp3)–H bonds and oxidative C–C cleavage reactions	201
Rapid screening platform for peptide prenyltransferases to diversify pseudo-natural prenylated peptides	200
Identifying and avoiding dead ends in the characterization of heterogeneous catalysts at the gas–solid interface	197
Tailored water–surface interactions on cobalt oxide for stable proton-exchange-membrane water electrolysis	187
Peripheral-nitrogen effects on the Ru1 centre for highly efficient propane dehydrogenation	187
Choreography of a self-splicing ribozyme	186
Heavy labels from gas surrogates	183
Author Correction: Bifunctional molecular additives enable efficient oxygen reduction reaction on platinum electrodes in the presence of strongly binding anions	181
Iminium catalysis in natural Diels–Alderase	177
Iron-catalysed cooperative redox mechanism for the simultaneous conversion of nitrous oxide and nitric oxide	177
Enantioselective radical dearomative conjugate amination enabled by Co(II)-based metalloradical catalysis	173
Electrolysis in tandem	166
Substrate promiscuity fuels biosynthesis success	163
Active sites overcrowding	161
Subnanometre PtSn alloyed clusters encapsulated in silicalite-1 sustain high productivity in propane dehydrogenation	160
Quantum-sensing-enabled in situ imaging of free radicals in chemical reactions	160
The rise of ab initio surface thermodynamics	157
Copper-catalysed enantioconvergent O-alkylation of alcohols with racemic α-tertiary haloamides to access enantioenriched hindered dialkyl ethers	154
Pulsed electrolysis through neutron lenses	148
Overcoming conformational strain in directed C3-C(sp3)–H activation for saturated azacycles	147
The role of Cu1–O3 species in single-atom Cu/ZrO2 catalyst for CO2 hydrogenation	146
Steam methane reforming using a regenerable antenna–reactor plasmonic photocatalyst	146
Photoelectrochemical asymmetric dehydrogenative [2 + 2] cycloaddition between C–C single and double bonds via the activation of two C(sp3)–H bonds	145
Enzymatic catalysis favours eight-membered over five-membered ring closure in bicyclomycin biosynthesis	145
A non-carboxylative route for the efficient synthesis of central metabolite malonyl-CoA and its derived products	144
Remote site-selective arene C–H functionalization enabled by N-heterocyclic carbene organocatalysis	143
Electrolyte effects in proton–electron transfer reactions and implications for renewable fuels and chemicals synthesis	143
Dinuclear Cu(I) molecular electrocatalyst for CO2-to-C3 product conversion	141
Morphological and chemical state effects in pulsed CO2 electroreduction on Cu(100) unveiled by correlated spectro-microscopy	139
Ligand-mediated radical orientation enables asymmetric cyanation of unstabilized alkyl C-radicals	137
Exploring mesoscopic mass transport effects on electrocatalytic selectivity	137
Solution-based Cu+ transient species mediate the reconstruction of copper electrocatalysts for CO2 reduction	136
Probing electrolyte effects on cation-enhanced CO2 reduction on copper in acidic media	135
Catalytic borylation of tertiary C–H bonds	134

Organocatalytic acylation of remote arene C–H bonds	134
Current state and future prospects of liquid metal catalysis	134
Triplet quenchers for energy-transfer photobiocatalysis	133
Modulation to probe the interface	130
Catalysing rate and capacity	127
Bubble trouble	126
Practical conversion of carboxylic acids to nitriles	124
One, two, three, four, five!	122
Durable MnO2 electrocatalysts by stronger Mn–O bonds	118
Structural insights and engineering of the T4 td intron for improved RNA circularization	117
Organocatalytic olefin C–H functionalization for enantioselective synthesis of atropisomeric 1,3-dienes	117
Splitting water under dryness	117
Ligand binding to a Ni–Fe cluster orchestrates conformational changes of the CO-dehydrogenase–acetyl-CoA synthase complex	116
Dual protection	115
Determining CO adsorption free energies on CO2 electroreduction active sites through kinetic analysis	115
The interphase behind lithium-mediated ammonia	114
Germanium-enriched double-four-membered-ring units inducing zeolite-confined subnanometric Pt clusters for efficient propane dehydrogenation	112
Concerted methane fixation at ambient temperature and pressure mediated by an alcohol oxidase and Fe-ZSM-5 catalytic couple	112
Blowing in the tube	111
In situ lysosomal proteomics enabled by bioorthogonal photocatalytic proximity labelling	111
Wireless potentiometry of thermochemical heterogeneous catalysis	111
CYP screening for a better terpenoid world	110
Frustration-driven efficiency	108
Publisher Correction: Parahydrogen-enhanced magnetic resonance identification of intermediates in [Fe]-hydrogenase catalysis	108
Author Correction: Stereoselective alkyl–alkyl cross-coupling	108
Regioselective silyl installation for arene diversification	107
A fine adjustment	106
Bridging catalysis	106
Author Correction: A polyketide-based biosynthetic platform for diols, amino alcohols and hydroxy acids	106
And yet it catalyses	103
Continuity of reaction kinetics across the pressure and materials gaps in CO oxidation on FeO–Pt interfaces	102
Cobalt-catalysed alkene hydronitration enabled by anomeric nitroamide	102
Enantioselective Chan–Lam S-arylation of sulfenamides	101
A synthetic methylotrophic Escherichia coli as a chassis for bioproduction from methanol	101
Nickel-electrocatalysed C(sp3)–C(sp3) cross-coupling of unactivated alkyl halides	100
Reactant-induced dynamics of lithium imide surfaces during the ammonia decomposition process	100
Silicon frustrated Lewis pairs catalyse α-deuteration of amides and esters	99
Synthesis of tri- and tetrasubstituted stereocentres by nickel-catalysed enantioselective olefin cross-couplings	98
Active-site isolation in intermetallics enables precise identification of elementary reaction kinetics during olefin hydrogenation	98
Tailored for semi-hydrogenation	98
Dissolved Fe species enable a cooperative solid–molecular mechanism for the oxygen evolution reaction on NiFe-based catalysts	98
Transient dynamics of flavonoid metabolons tune chalcone synthase specificity	97
Cationic-group-functionalized electrocatalysts enable stable acidic CO2 electrolysis	97
Step bunching instability and its effects in electrocatalysis on platinum surfaces	97
Direct electrochemical propylene epoxidation over amorphized perovskite oxide in non-halogenated aqueous electrolyte	97
Ammonia synthesis via an engineered nitrogenase assembly pathway in Escherichia coli	96
High-purity carbon monoxide production via photothermal formic acid decomposition over fluorite ZrO2	95
Understanding Mn-modulated restructuring of Fe-based catalysts for controlling selectivity in CO2 hydrogenation to olefins	95
Electrosynthesis of ethylene glycol from ethylene coupled with CO2 capture	95
Divide and conquer towards synthetic autotrophy	93
Terpene synthases in giant viruses	93
Shining light to break planarity	90
Identifying restructured motifs on iridium oxide catalyst surfaces for water electrolysis	88
Monitoring catalytic nanosites in action	88
Catalyst optimization through synthetic Darwinian evolution	88
A TIM-barrel metalloenzyme with sugar-cleavage activity	88
Molecular-scale interactions in heterogeneous (photo)electrocatalysis	88
Thioester-mediated biocatalytic amide bond synthesis with in situ thiol recycling	87
A modular synthesis of azetidines from reactive triplet imine intermediates using an intermolecular aza Paternò–Büchi reaction	87
The STRENDA Biocatalysis Guidelines for cataloguing metadata	86
Cations in alkaline hydrogen electrocatalysis	86
A hydrogenative oxidation strategy for the single-step synthesis of lactams from N-heteroarenes using water	86
Photoinduced gold-catalyzed divergent dechloroalkylation of gem-dichloroalkanes	86
Methyl formate as a hydrogen energy carrier	85
Long-range enhancements of micropollutant adsorption on metal-promoted photocatalysts	82
Metastable nickel–oxygen species modulate rate oscillations during dry reforming of methane	82
Identifying and alleviating the durability challenges in membrane-electrode-assembly devices for high-rate CO electrolysis	82
Cobalt hydride-mediated photocatalytic semihydrogenation of acetylene impurities for continuous-flow production of polymer-grade ethylene	80
Atomically dispersed ruthenium hydride on beta zeolite as catalysts for the isomerization of muconates	76
The catalytic role of glutathione transferases in heterologous anthocyanin biosynthesis	76
Understanding two voltammetric features of water reduction and water oxidation in mild pH solutions	75
Key role of paracrystalline motifs on iridium oxide surfaces for acidic water oxidation	75
Iron-only Fe-nitrogenase underscores common catalytic principles in biological nitrogen fixation	75
Optimizing the p charge of S in p-block metal sulfides for sulfur reduction electrocatalysis	75
Electrocatalytic dual hydrogenation of organic substrates with a Faradaic efficiency approaching 200%	74
Boron clusters as efficient shuttles for electrocatalytic deuterium labelling via radical H/D exchange	74
Enhanced CO2 utilization in dry reforming of methane achieved through nickel-mediated hydrogen spillover in zeolite crystals	72
Metabolic engineering of Escherichia coli with electron channelling for the production of natural products	72
Stable acidic oxygen-evolving catalyst discovery through mixed accelerations	72
Generative machine learning produces kinetic models that accurately characterize intracellular metabolic states	70

Recharge your batteries	69
Identifying high-spin hydroxyl-coordinated Fe3+N4 as the active centre for acidic oxygen reduction using molecular model catalysts	69
A strongly coupled Ru–CrOx cluster–cluster heterostructure for efficient alkaline hydrogen electrocatalysis	69
Shielding PEM electrolysers from real-world water	68
Scatter and conquer	68
Author Correction: Co3O4 as full-solar-spectrum photocatalyst for selective methane conversion through reactive oxygen species control	67
Electrochemical imaging of thermochemical catalysis	67
Photobiocatalytic stereocontrol of two prochiral radicals	67
Taming palladium mobility by redox coupling	66
Industrial waste reformed	66
Acetylene hydrogenation to ethylene by water at low temperature on a Au/α-MoC catalyst	66
Enantioselective C(sp3)–C(sp3) bond formation by synergistic thiamine-dependent radical biocatalysis and photoredox catalysis	66
Ultralow overpotential nitrate reduction to ammonia via a three-step relay mechanism	65
Light-driven metabolic makeover	65
Stereoselective construction of β-, γ- and δ-lactam rings via enzymatic C–H amidation	65
An antidote for chemical reaction networks	65
Epistasis arises from shifting the rate-limiting step during enzyme evolution of a β-lactamase	65
Complex behaviour of isotopes in CO2 electroreduction	64
Photoenzymatic enantioselective intermolecular radical hydroamination	62
Shape matters too	62
Author Correction: Origin of active sites on silica–magnesia catalysts and control of reactive environment in the one-step ethanol-to-butadiene process	62
Synthesis of α,α-diheteroatomic carboxylic acids	62
Site-selective arene C–H amination with iron-aminyl radical	62
A metabolon that GATEs	62
Challenges and prospects in precision medicine with RNA-based biocatalysts	61
Achieving maximum overall light enhancement in plasmonic catalysis by combining thermal and non-thermal effects	61
Privileged Brønsted acid organocatalysis	61
Precision installation of silyl synthetic handles within arenes by regiocontrolled ruthenium C(sp2)–H functionalization	60
Seeking selectivity in alkene couplings	60
Critical insights into the steam electrolysis electrode in protonic ceramic cells for hydrogen production	60
Benign hyperpolarization	59
Unlocking iron spin states for oxygen reduction	59
Methane oxidation by catalyst reduction	58
Generating alkyl carbanions for organic synthesis	58
Publisher Correction: Gas-balancing adsorption strategy towards noble-metal-based nanowire electrocatalysts	57
Deciphering electrochemical methanol production	55
Organocatalytic asymmetric α-C–H functionalization of alkyl amines	55
A pyridoxal 5′-phosphate-dependent Mannich cyclase	55
Effective anions	55
The 3D secrets of fuel cell catalyst layers	55
Alkene 1,1-difunctionalizations via organometallic-radical relay	54
Harnessing thia-Rh-carbenes for the enantioselective synthesis of chiral α,α-diheteroatomic carboxylic acids	54
Organocatalytic regio- and stereoselective cyclopropanation of olefins	54
A radical way to ethylene	54
Eliminating redox-mediated electron transfer mechanisms on a supported molecular catalyst enables CO2 conversion to ethanol	53
Defying thermodynamics to synthetize hydrazine	53
Nickel-catalysed enantioselective alkene dicarbofunctionalization enabled by photochemical aliphatic C–H bond activation	53
Revealing in-plane movement of platinum in polymer electrolyte fuel cells after heavy-duty vehicle lifetime	52
Regioselective hydroformylation with subnanometre Rh clusters in MFI zeolite	51
Rising to the surface	51
Operando probing dynamic migration of copper carbonyl during electrocatalytic CO2 reduction	51
Iron-catalysed carbene and carbene radical cascade reactions for the synthesis of carbocyclic molecules	50
Controlling carbocations	50
A structured catalyst for anion exchange membrane water electrolysis	49
Immobilized cations boost acidic CO2 reduction	49
Direct copper-catalysed deaminative cyanation of aliphatic primary amines	47
Pushing the boundaries of biocatalysis	47
The value of negative results in data-driven catalysis research	46
A red-light-powered silicon nanowire biophotochemical diode for simultaneous CO2 reduction and glycerol valorization	46
Blocking the reverse reactions of overall water splitting on a Rh/GaN–ZnO photocatalyst modified with Al2O3	46
Artificial enzymes for artificial photosynthesis	46
Strain boosts propanol electrosynthesis from CO on copper	46
Congested C(sp3)-rich architectures enabled by iron-catalysed conjunctive alkylation	46
Visible-light photocatalytic di- and hydro-carboxylation of unactivated alkenes with CO2	45
Catalytic mechanism for Renilla-type luciferases	45
Sustainable methanol synthesis	44
The functional coupling between restriction and DNA phosphorothioate modification systems underlying the DndFGH restriction complex	44
Unlocking C–C cleavage in the electrochemical toolbox	44
The return of the nickel(I) isocyanide	44
Active alloy ahoy!	44
Tunable layered Mn oxides for oxygen electrocatalysis	43
Molecular mechanism of topoisomerase poisoning by the peptide antibiotic albicidin	43
Rates against the machine	42
Principles of target DNA cleavage and the role of Mg2+ in the catalysis of CRISPR–Cas9	42
Iron-catalysed alkenylzincation of allenes via electrophilicity reversal	42
Author Correction: Reversely trapping atoms from a perovskite surface for high-performance and durable fuel cell cathodes	42
Structurally defined anti-π-allyliridium complexes catalyse Z-retentive asymmetric allylic alkylation of oxindoles	41
Clustering for methane	41
Alkali metal cation impurities stabilize Cu+ in oxide-derived copper for CO2 electrolysis	41
Hydrogen-bonded organic framework-based bioorthogonal catalysis prevents drug metabolic inactivation	41
Enantioconvergent copper-catalysed difluoromethylation of alkyl halides	41
Catalytic cycle of formate dehydrogenase captured by single-molecule conductance	40
Atroposelective organocatalytic nucleophilic aromatic substitution for C–O bond construction	40
Different distributions of multi-carbon products in CO2 and CO electroreduction under practical reaction conditions	40
Edge sites dominate the hydrogen evolution reaction on platinum nanocatalysts	39
Sub-micro- and nano-sized polyethylene terephthalate deconstruction with engineered protein nanopores	39
A geometric foundation model for enzyme retrieval with evolutionary insights	39
The era of stable electrocatalysis	38
Radical dissolution	38
Degradation through filaments	38
Microenvironment control	38
Decoding CO2 hydrogenation	38
Split cross-coupling via Rh-catalysed activation of unstrained aryl–aryl bonds	38
Establishing coupling trends	38
The deuterium source matters	38