(The TQCC of Chem is 30. The table below lists those papers that are above that threshold based on CrossRef citation counts [max. 250 papers]. The publications cover those that have been published in the past four years, i.e., from 2020-06-01 to 2024-06-01.)
S-Scheme Heterojunction Photocatalyst2157
Challenges for photocatalytic overall water splitting376
Activity Origins and Design Principles of Nickel-Based Catalysts for Nucleophile Electrooxidation349
Recent Developments and Future Challenges in Controlled Radical Polymerization: A 2020 Update333
Triplet Energy Transfer Photocatalysis: Unlocking the Next Level329
Powering the Future: How Can Electrochemistry Make a Difference in Organic Synthesis?297
Electrochemical ammonia synthesis: Mechanistic understanding and catalyst design273
Catalytic processing of plastic waste on the rise262
Identification of the Electronic and Structural Dynamics of Catalytic Centers in Single-Fe-Atom Material248
High-Performance n-Type Polymer Semiconductors: Applications, Recent Development, and Challenges247
Coordination Number Regulation of Molybdenum Single-Atom Nanozyme Peroxidase-like Specificity239
A nitrogen-rich covalent organic framework for simultaneous dynamic capture of iodine and methyl iodide224
Persistent and Stable Organic Radicals: Design, Synthesis, and Applications220
Synthesis of CaCO3-Based Nanomedicine for Enhanced Sonodynamic Therapy via Amplification of Tumor Oxidative Stress211
Late-Stage Functionalization186
Electrochemical Synthesis of H2O2 by Two-Electron Water Oxidation Reaction186
Redox Comediation with Organopolysulfides in Working Lithium-Sulfur Batteries185
Developments in Photoredox/Nickel Dual-Catalyzed 1,2-Difunctionalizations183
Atropisomers beyond the C–C axial chirality: Advances in catalytic asymmetric synthesis174
Porous materials for hydrogen storage171
Molten Salt-Directed Catalytic Synthesis of 2D Layered Transition-Metal Nitrides for Efficient Hydrogen Evolution169
Unconventional Mn Vacancies in Mn–Fe Prussian Blue Analogs: Suppressing Jahn-Teller Distortion for Ultrastable Sodium Storage167
A Realistic Methodology for 30% Efficient Perovskite Solar Cells166
Critical effects of electrolyte recipes for Li and Na metal batteries166
Reducing Voltage Losses in the A-DA′D-A Acceptor-Based Organic Solar Cells164
Exploring and Understanding the Roles of Li2Sn and the Strategies to beyond Present Li-S Batteries158
Catalysis for Selected C1 Chemistry157
Integration of Pd nanoparticles with engineered pore walls in MOFs for enhanced catalysis157
Light-free Generation of Singlet Oxygen through Manganese-Thiophene Nanosystems for pH-Responsive Chemiluminescence Imaging and Tumor Therapy154
Highly Selective Hydrogen Peroxide Electrosynthesis on Carbon: In Situ Interface Engineering with Surfactants154
Outlook on K-Ion Batteries154
Homogeneous manganese-catalyzed hydrogenation and dehydrogenation reactions154
A Structure-Based Platform for Predicting Chemical Reactivity152
Recent advances in carbon dioxide hydrogenation to produce olefins and aromatics147
Constructing FeN4/graphitic nitrogen atomic interface for high-efficiency electrochemical CO2 reduction over a broad potential window145
Advances in higher alcohol synthesis from CO2 hydrogenation143
Open-Shell Graphene Fragments140
CO2 Hydrogenation to Ethanol over Cu@Na-Beta139
Main-group elements boost electrochemical nitrogen fixation139
Covalent-Organic-Framework-Based Composite Materials135
Hydrogen-bonded organic frameworks: Chemistry and functions135
Plug-and-Play Optical Materials from Fluorescent Dyes and Macrocycles134
Propane Dehydrogenation on Single-Site [PtZn4] Intermetallic Catalysts131
Geminal Dimethyl Substitution Enables Controlled Polymerization of Penicillamine-Derived β-Thiolactones and Reversed Depolymerization130
Tailoring Polymer Dispersity by RAFT Polymerization: A Versatile Approach128
A Directional Synthesis for Topological Defect in Carbon128
Advances in ammonia electrosynthesis from ambient nitrate/nitrite reduction128
Ion-Solvent Chemistry-Inspired Cation-Additive Strategy to Stabilize Electrolytes for Sodium-Metal Batteries126
Pollutant removal with organic macrocycle-based covalent organic polymers and frameworks124
Dissipative Self-Assembly: Fueling with Chemicals versus Light122
Designing highly active nanoporous carbon H2O2 production electrocatalysts through active site identification122
Perovskite Solution Aging: What Happened and How to Inhibit?120
Catalysis, FLPs, and Beyond119
Selectivity Control in Photocatalytic Valorization of Biomass-Derived Platform Compounds by Surface Engineering of Titanium Oxide119
Constructing an Ion Pathway for Uranium Extraction from Seawater116
Shaping Molecular Landscapes: Recent Advances, Opportunities, and Challenges in Dearomatization115
2D/3D perovskite engineering eliminates interfacial recombination losses in hybrid perovskite solar cells115
Radiation Controllable Synthesis of Robust Covalent Organic Framework Conjugates for Efficient Dynamic Column Extraction of 99TcO4−115
An analysis of the electrochemical mechanism of manganese oxides in aqueous zinc batteries112
Enhancing Magnetic Hysteresis in Single-Molecule Magnets by Ligand Functionalization106
Electrochemical CO2 reduction in membrane-electrode assemblies105
Transition-metal-catalyzed C–H allylation reactions105
Covalent Organic Frameworks: An Amazing Chemistry Platform for Designing Polymers104
Boosting Electrocatalytic Ammonia Production through Mimicking “π Back-Donation”101
Rational design and atroposelective synthesis of N–N axially chiral compounds100
Extremely Stable Anthraquinone Negolytes Synthesized from Common Precursors100
Strategies for Pore Engineering in Zirconium Metal-Organic Frameworks100
Digital Reticular Chemistry99
Two-Dimensional Nanomaterials with Unconventional Phases99
Visible-light photoredox-catalyzed selective carboxylation of C(sp3)−F bonds with CO298
Emergent behavior in nanoconfined molecular containers97
Designer DNA nanostructures for therapeutics96
Li-ion battery recycling challenges96
Tuning the spin state of Fe single atoms by Pd nanoclusters enables robust oxygen reduction with dissociative pathway96
Forging C−heteroatom bonds by transition-metal-catalyzed enantioselective C–H functionalization96
Prospects and Challenges in Anion Recognition and Transport95
Chemistry and Biology of SARS-CoV-295
Porous Ligand Creates New Reaction Route: Bifunctional Single-Atom Palladium Catalyst for Selective Distannylation of Terminal Alkynes94
Hybrid monomer design for unifying conflicting polymerizability, recyclability, and performance properties94
Design principles for intrinsically circular polymers with tunable properties94
The concept and examples of type-III photosensitizers for cancer photodynamic therapy92
Recent Advances in Using Transition-Metal-Catalyzed C–H Functionalization to Build Fluorescent Materials91
Protein-directed, hydrogen-bonded biohybrid framework88
Surface Chemistry Can Unlock Drivers of Surface Stability of SARS-CoV-2 in a Variety of Environmental Conditions87
DFT-Guided Phosphoric-Acid-Catalyzed Atroposelective Arene Functionalization of Nitrosonaphthalene87
Selective, Catalytic Oxidations of C–H Bonds in Polyethylenes Produce Functional Materials with Enhanced Adhesion87
Encapsulated Nanodroplet Crystallization of Organic-Soluble Small Molecules87
An encapsulating lithium-polysulfide electrolyte for practical lithium–sulfur batteries86
Hydrazones as New Molecular Tools86
Confinement as a Unifying Element in Selective Catalysis85
In situ formation of polymer-inorganic solid-electrolyte interphase for stable polymeric solid-state lithium-metal batteries84
Programmable synthesis of radially gradient-structured mesoporous carbon nanospheres with tunable core-shell architectures83
Fast, reversible mechanochromism of regioisomeric oxazine mechanophores: Developing in situ responsive force probes for polymeric materials83
Nanoscale CaH2 materials for synergistic hydrogen-immune cancer therapy83
Endohedral functionalization of chiral metal-organic cages for encapsulating achiral dyes to induce circularly polarized luminescence82
Product-Specific Active Site Motifs of Cu for Electrochemical CO2 Reduction81
Striding the threshold of an atom era of organic synthesis by single-atom catalysis81
Atomically dispersed Ni induced by ultrahigh N-doped carbon enables stable sodium storage81
Rechargeable anion-shuttle batteries for low-cost energy storage80
Light-Promoted Bromine-Radical-Mediated Selective Alkylation and Amination of Unactivated C(sp3)–H Bonds80
Hierarchical Defect Engineering for LiCoO2 through Low-Solubility Trace Element Doping79
Redox-Neutral Photocatalytic C−H Carboxylation of Arenes and Styrenes with CO279
Dynamic molecular weaving in a two-dimensional hydrogen-bonded organic framework79
The chemical states of conjugated coordination polymers78
Magnetic-Field-Regulated TiO2 {100} Facets: A Strategy for C-C Coupling in CO2 Photocatalytic Conversion77
Neutrophil-Membrane-Directed Bioorthogonal Synthesis of Inflammation-Targeting Chiral Drugs77
Ultra-dense carbon defects as highly active sites for oxygen reduction catalysis76
Optical processes in carbon nanocolloids76
Development of direct conversion of syngas to unsaturated hydrocarbons based on Fischer-Tropsch route75
Dual key co-activated nanoplatform for switchable MRI monitoring accurate ferroptosis-based synergistic therapy74
Anion chemistry enabled positive valence conversion to achieve a record high-voltage organic cathode for zinc batteries74
Recent advances in radical chemistry proceeding through pro-aromatic radicals74
Progress in anion receptor chemistry73
Regulating liquid and solid-state electrolytes for solid-phase conversion in Li–S batteries73
Catalytic strategies for upvaluing plastic wastes73
Gigantic Porphyrinic Cages73
Indoor Surface Chemistry: Developing a Molecular Picture of Reactions on Indoor Interfaces73
Pumps through the Ages72
Unraveling the physical chemistry and materials science of CeO2-based nanostructures71
Theory-Guided Machine Learning Finds Geometric Structure-Property Relationships for Chemisorption on Subsurface Alloys71
Stable Carbenes, Nitrenes, Phosphinidenes, and Borylenes: Past and Future71
Breaking the trade-off between selectivity and adsorption capacity for gas separation71
Size sensitivity of supported Ru catalysts for ammonia synthesis: From nanoparticles to subnanometric clusters and atomic clusters71
Multi-scale Imaging of Solid-State Battery Interfaces: From Atomic Scale to Macroscopic Scale70
Oxygen-controlled photo-reforming of biopolyols to CO over Z-scheme CdS@g-C3N470
Water-involved methane-selective catalytic oxidation by dioxygen over copper zeolites70
Borane-Catalyzed Stereoselective C–H Insertion, Cyclopropanation, and Ring-Opening Reactions70
Molecules in Confined Spaces: Reactivities and Possibilities in Cavitands69
Modern strategies for C–H functionalization of heteroarenes with alternative coupling partners69
Exceptionally active and stable RuO2 with interstitial carbon for water oxidation in acid68
Carbon nitride of five-membered rings with low optical bandgap for photoelectrochemical biosensing68
Topology Meets Reticular Chemistry for Chemical Separations: MOFs as a Case Study67
An axial-to-axial chirality transfer strategy for atroposelective construction of C–N axial chirality67
Porous Liquids: The Next Frontier67
Deciphering and modulating energetics of solvation structure enables aggressive high-voltage chemistry of Li metal batteries66
Strategies for the Synthesis of Enantiopure Mechanically Chiral Molecules65
Programmable ATP-Fueled DNA Coacervates by Transient Liquid-Liquid Phase Separation65
Halogen-halogen bonds enable improved long-term operational stability of mixed-halide perovskite photovoltaics65
Precise recognition of palladium through interlaminar chelation in a covalent organic framework65
Creep-Enabled 3D Solid-State Lithium-Metal Battery65
Atomically precise electrocatalysts for oxygen reduction reaction64
Learning to Make Chemical Predictions: The Interplay of Feature Representation, Data, and Machine Learning Methods64
Artificial transmembrane ion transporters as potential therapeutics64
Design of metal-organic framework catalysts for photocatalytic hydrogen peroxide production63
Progress in carbon dioxide capture materials for deep decarbonization63
Stereodivergent total synthesis of rocaglaol initiated by synergistic dual-metal-catalyzed asymmetric allylation of benzofuran-3(2H)-one63
Tuning the gating energy barrier of metal-organic framework for molecular sieving63
Shale gas revolution: Catalytic conversion of C1–C3 light alkanes to value-added chemicals62
Selective Conversion of CO2 into Propene and Butene61
A general N-alkylation platform via copper metallaphotoredox and silyl radical activation of alkyl halides61
When MOFs meet wood: From opportunities toward applications60
Peptide Late-Stage Diversifications by Rhodium-Catalyzed Tryptophan C7 Amidation60
A relay catalysis strategy for enantioselective nickel-catalyzed migratory hydroarylation forming chiral α-aryl alkylboronates60
Interfacial Active Sites for CO2 Assisted Selective Cleavage of C–C/C–H Bonds in Ethane60
Photo-induced thiolate catalytic activation of inert Caryl-hetero bonds for radical borylation59
Molecular Configuration Fixation with C–H···F Hydrogen Bonding for Thermally Activated Delayed Fluorescence Acceleration59
Anisotropic Microparticles from Microfluidics59
Quantum dots enable direct alkylation and arylation of allylic C(sp3)–H bonds with hydrogen evolution by solar energy59
Confinement Self-Assembly of Metal-Organic Cages within Mesoporous Carbon for One-Pot Sequential Reactions59
Single-atom engineering of metal-organic frameworks toward healthcare59
Partially reduced Pd single atoms on CdS nanorods enable photocatalytic reforming of ethanol into high value-added multicarbon compound59
Diastereo- and Enantioselective Catalytic Radical Oxysulfonylation of Alkenes in β,γ-Unsaturated Ketoximes59
Revealing phase evolution mechanism for stabilizing formamidinium-based lead halide perovskites by a key intermediate phase59
Reversibly modulating a conformation-adaptive fluorophore in [2]catenane58
Bridging the Gap between Reality and Ideality of Graphdiyne: The Advances of Synthetic Methodology58
Visible-Light-Initiated Free-Radical Polymerization by Homomolecular Triplet-Triplet Annihilation56
Near-infrared photosensitization via direct triplet energy transfer from lanthanide nanoparticles56
Cu-Catalyzed Regio- and Stereodivergent Chemoselective sp/sp 1,3- and 1,4-Diborylations of CF3-Containing 1,3-Enynes55
Enhanced electroreduction of CO2 to C2+ products on heterostructured Cu/oxide electrodes55
Folding and Assembly of Metal-Linked Peptidic Nanostructures55
Electrochemical Aziridination of Internal Alkenes with Primary Amines55
Site-Selective C–H Benzylation of Alkanes with N-Triftosylhydrazones Leading to Alkyl Aromatics54
Strain-Induced Corrosion Kinetics at Nanoscale Are Revealed in Liquid: Enabling Control of Corrosion Dynamics of Electrocatalysis54
Design principle of electrocatalysts for the electrooxidation of organics54
Perspectives for antimicrobial nanomaterials in cultural heritage conservation54
Engineering couplings for exciton transport using synthetic DNA scaffolds54
Cationic lithium polysulfides in lithium–sulfur batteries53
Integrating the Mechanical Bond into Metal-Organic Frameworks53
Dual-Active-Sites Design of Co@C Catalysts for Ultrahigh Selective Hydrogenation of N-Heteroarenes53
Electrolyte engineering for highly inorganic solid electrolyte interphase in high-performance lithium metal batteries53
Establishing design principles for emissive organic SWIR chromophores from energy gap laws53
Aerobic Oxidative Cleavage and Esterification of C(OH)–C Bonds52
Synergizing palladium with Lewis base catalysis for stereodivergent coupling of 1,3-dienes with pentafluorophenyl acetates52
An isolable, crystalline complex of square-planar silicon(IV)51
Asymmetric radical cyclopropanation of dehydroaminocarboxylates: Stereoselective synthesis of cyclopropyl α-amino acids51
Sensors for In Situ Real-Time Fluorescence Imaging of Enzymes51
Mapping the Surface Groups of Amine-Rich Carbon Dots Enables Covalent Catalysis in Aqueous Media50
Unlocking the Friedel-Crafts arylation of primary aliphatic alcohols and epoxides driven by hexafluoroisopropanol50
Controlling the shape and chirality of an eight-crossing molecular knot50
Catalytic carbon-carbon bond cleavage and carbon-element bond formation give new life for polyolefins as biodegradable surfactants50
Rationally fabricating 3D porphyrinic covalent organic frameworks with scu topology as highly efficient photocatalysts50
Synergy between β-Mo2C Nanorods and Non-thermal Plasma for Selective CO2 Reduction to CO49
Enantioselective Copper-Catalyzed Trifluoromethylation of Benzylic Radicals via Ring Opening of Cyclopropanols49
Recent advances in electrode engineering strategies for aqueous Zn-based batteries49
Nitrogenase inspired artificial photosynthetic nitrogen fixation49
Exceptional electron conduction in two-dimensional covalent organic frameworks48
In This Issue48
Enantioselective Ring-Closing C–H Amination of Urea Derivatives48
Guest-molecule-induced self-adaptive pore engineering facilitates purification of ethylene from ternary mixture47
Palladium-catalyzed asymmetric hydrophosphination of internal alkynes: Atroposelective access to phosphine-functionalized olefins47
Observation of a potential-dependent switch of water-oxidation mechanism on Co-oxide-based catalysts47
Catalyst: Aggregation-Induced Emission—How Far Have We Come, and Where Are We Going Next?47
Biology-Inspired Supramolecular Peptide Systems47
Transition to sustainable chemistry through digitalization46
The road to industrialization of fine chemical carboxylation reactions46
Solution-Processable, Crystalline π-Conjugated Two-Dimensional Polymers with High Charge Carrier Mobility46
Diindenoanthracene Diradicaloids Enable Rational, Incremental Tuning of Their Singlet-Triplet Energy Gaps46
Evaluating Solid-Electrolyte Interphases for Lithium and Lithium-free Anodes from Nanoindentation Features46
A Robust Titanium Isophthalate Metal-Organic Framework for Visible-Light Photocatalytic CO2 Methanation45
Reactivity of an air-stable dihydrobenzoimidazole n-dopant with organic semiconductor molecules45
Reversible isomerization of metal nanoclusters induced by intermolecular interaction45
Weak bonding strategies for achieving regio- and site-selective transformations45
Atomically dispersed Ru oxide catalyst with lattice oxygen participation for efficient acidic water oxidation45
Fe binuclear sites convert methane to acetic acid with ultrahigh selectivity45
Palladium/Xu-Phos-catalyzed enantioselective cascade Heck/remote C(sp2) –H alkylation reaction45
Rationalizing the design and implementation of chiral hybrid perovskites45
A see-through electrochromic display via dynamic metal-ligand interactions45
Dual Stimuli Switching: Interconverting Cationic and Radical Polymerizations with Electricity and Light45
Organometallic lanthanide bismuth cluster single-molecule magnets44
Quantifying Electrocatalytic Reduction of CO2 on Twin Boundaries44
Established and Emerging Computational Tools to Study Homogeneous Catalysis—From Quantum Mechanics to Machine Learning44
Discovery of a Small Molecule Drug Candidate for Selective NKCC1 Inhibition in Brain Disorders44
Supramolecular Purification and Regioselective Functionalization of Fullerenes and Endohedral Metallofullerenes44
Carbohydrate amphiphiles for supramolecular biomaterials: Design, self-assembly, and applications44
High-yield exfoliation of 2D semiconductor monolayers and reassembly of organic/inorganic artificial superlattices43
Active learning accelerates ab initio molecular dynamics on reactive energy surfaces43
Stereospecific and stereoconvergent nucleophilic substitution reactions at tertiary carbon centers43
Rational design and synthesis of two-dimensional conjugated metal-organic polymers for electrocatalysis applications43
In This Issue43
Confining Ti-oxo clusters in covalent organic framework micropores for photocatalytic reduction of the dominant uranium species in seawater42
An integrated solid-state lithium-oxygen battery with highly stable anionic covalent organic frameworks electrolyte42
A Bioinspired Multicomponent Catalytic System for Converting Carbon Dioxide into Methanol Autocatalytically42
On-the-fly interpretable machine learning for rapid discovery of two-dimensional ferromagnets with high Curie temperature42
Molecular Representation: Going Long on Fingerprints42
A base-controlled switch of SO2 reincorporation in photocatalyzed radical difunctionalization of alkenes42
Heterogeneous hydroformylation of alkenes by Rh-based catalysts42
A “universal” catalyst for aerobic oxidations to synthesize (hetero)aromatic aldehydes, ketones, esters, acids, nitriles, and amides42
Small amines bring big benefits to perovskite-based solar cells and light-emitting diodes41
Mass Photometry of Membrane Proteins41
In situ monitoring of mechanochemical covalent organic framework formation reveals templating effect of liquid additive41
Dynamic optimization of guest binding in a library of diastereomeric heteroleptic coordination cages41
Synthesis of amino acids by electrocatalytic reduction of CO2 on chiral Cu surfaces41
One-Dimensional Segregated Single Au Sites on Step-Rich ZnO Ladder for Ultrasensitive NO2 Sensors41
Identifying the Conformational Isomers of Single-Molecule Cyclohexane at Room Temperature41
Protein stabilization and refolding in a gigantic self-assembled cage41
TADF molecules with π-extended acceptors for simplified high-efficiency blue and white organic light-emitting diodes40
Long carrier diffusion length in two-dimensional lead halide perovskite single crystals40
Laser-Microstructured Copper Reveals Selectivity Patterns in the Electrocatalytic Reduction of CO240
Computer-aided design of RNA-targeted small molecules: A growing need in drug discovery40
Liquid fuel synthesis via CO2 hydrogenation by coupling homogeneous and heterogeneous catalysis39