Chem

Article	Citations
Ion-dipole interaction manipulated bilateral interface chemistry for deep rechargeability and high redox activity of Zn-organic batteries	597
Artificial light-triggered smart nanochannels relying on optoionic effects	398
In This Issue	348
Harnessing the reactivity of borenium for methane activation	331
A high-throughput workflow to analyze sequence-conformation relationships and explore hydrophobic patterning in disordered peptoids	287
In this issue	273
Nanocellulose: New horizons in organic chemistry and beyond	256
From trash to treasure: Vanadium-catalyzed upcycling of non-biodegradable plastics	247
Excited-state protonation and reduction enable the umpolung Birch reduction of naphthalenes	214
Reaction: Harnessing reactive oxygen species (ROS) for water purification	209
Out-of-equilibrium chemical logic systems	200
Harnessing plastic depolymerization products to upcycle mixed waste into high-value chemicals	199
Thermosetting supramolecular polymerization of compartmentalized DNA fibers with stereo sequence and length control	195
Quasicrystal approximants in isoreticular metal-organic frameworks via Cairo pentagonal tiling	179
Probing enantioinduction in confined chiral spaces through asymmetric oxime reductions	178
Nature-inspired synthetic oligourea foldamer channels allow water transport with high salt rejection	175
Lanthanide luminescence from supramolecular hydrogels consisting of bio-conjugated picolinic-acid-based guanosine quadruplexes	159
Air-stable radical polycyclic aromatic hydrogen-bonded organic frameworks	157
Experimentally modeling the emergence of prebiotically plausible phospholipid vesicles	156
2D covalent organic framework via catenation	151
A Star of David [2]catenane of single handedness	145
Photoswitches and photochemical reactions for optically controlled phase transition and energy storage	145
Click chemistry in polymer science	139
Spatially resolved cell tagging and surfaceome labeling via targeted photocatalytic decaging	139
Recent research progress of all-polymer solar cells based on PSMA-type polymer acceptors	134

B(C6F5)3-catalyzed selective C–H chalcogenation of arenes and heteroarenes	132
Revealing phase evolution mechanism for stabilizing formamidinium-based lead halide perovskites by a key intermediate phase	131
2D conjugated metal-organic framework as a proton-electron dual conductor	131
Variable nanosheets for highly efficient oxygen evolution reaction	131
Supramolecular boosted superexchange	129
In this issue	128
Modular nucleic acid scaffolds for synthesizing monodisperse and sequence-encoded antibody oligomers	127
Swapping benches from chemistry PhD student to science advisor at law firm	126
In this issue	125
Catalytic strategies for upvaluing plastic wastes	123
Highly oxygenated organic molecules with high unsaturation formed upon photochemical aging of soot	122
Molecular design strategy for realizing vectorial electron transfer in photoelectrodes	120
Switchable diversification of quaternary ammonium salts using photocatalysis	120
Cation-exchange-upgraded nanostructures for photocatalysts	116
An effective strategy to boost lattice-oxygen-mediated acidic oxygen evolution	116
para-Selective C–H alkylation of aroyl chlorides through organic photoredox-catalyzed radical tele-substitution	116
Molecule-resolvable SERSome for metabolic profiling	113
General and selective metal-free radical α-C–H borylation of aliphatic amines	112
Observation of ultrafast electrons in pendant-embedded conducting two-dimensional polymers	111
Be your own star	110
Design of piezoelectric organic cage salts for energy harvesting	110
Reaction: Don’t hate the player in chemical AI; hate the game	106
Atom swap in triple bonds via nitrogen-deletion coupling with gem-diborylalkanes	105
Battery detectives: Uncovering cathode impact on anode-free Li cell performance by operando NMR	104
Curved plane increases the d vacancy population of Pd for green production of cyclohexanone	103
Redox-couple-assisted CO2 capture on solid-electrolyte reactor	103
Molecular freaky Friday: Polarity reversal and resorcin[4]arenes as chloride receptors	102
Photo-assembling cyclic peptides for dynamic light-driven peptide nanotubes	101
Semiconducting ladder-type covalent organic frameworks	101
In this issue	100
Time-resolved fluorescence imaging with color-changing, “turn-on/turn-on” AIE nanoparticles	100
From G-protein-coupled receptors to solute carriers—mass spectrometry informs dynamics, function, and regulation	99
Two-in-one metallaphotoredox cross-couplings enabled by a photoactive ligand	98
Ionic surface propensity controls pH in nanopores	98
The beauty of low symmetry: Non-statistical assembly of [Pd2(LA)(LB)(LC)(LD)]4+ cages	98
Phosphine oxide additives for perovskite light-emitting diodes and solar cells	96
Stereodivergent asymmetric hydrogenation of quinoxalines	95
Strong halide anion binding within the cavity of a conformation-adaptive phenazine-based Pd2L4 cage	95
Transition metal-free difunctionalization of unactivated alkenes: Arylation/azidation, arylation/chlorination, and arylation/cyanation	95
Higher-order cycloadditions in the age of catalysis	94
Bioinspired chemical design to control interfacial wet adhesion	92
Supramolecular triangular orthobicupola: Self-assembly of a giant Johnson solid J27	92
Controlling the shape and chirality of an eight-crossing molecular knot	91
Protein stabilization and refolding in a gigantic self-assembled cage	91
A phosphorus analog of a bimetallic dinitrogen complex	89
The role of concentration waves in synthesizing hollow multi-shelled structures	87
Selective palladium recovery by a highly porous polyisothiocyanurate	87
Ice quenching for sustained nucleate boiling at large superheats	86
Colorless zinc colored by metal-metal orbital interaction	86
Potent antimicrobial effect induced by disruption of chloride homeostasis	85

Antigen spatial-matching polyaptamer nanostructure to block coronavirus infection and alleviate inflammation	84
Halogen-halogen bonds enable improved long-term operational stability of mixed-halide perovskite photovoltaics	84
Single-molecule mechanics of synthetic aromatic amide helices: Ultrafast and robust non-dissipative winding	84
Pilot-scale reductive catalytic depolymerization of lignin: Challenges and guidelines	84
Upcycling waste PET and CO2 to useful chemicals: Multi-functional catalysis at its best	83
Regulating liquid and solid-state electrolytes for solid-phase conversion in Li–S batteries	83
The mechanical bond in biological systems	83
Catalyst: A step forward for PVC manufacture from natural gas	82
Revisiting the impacts of silica nanoparticles on endothelial cell junctions and tumor metastasis	80
Engineering reversible isomerization at the nanoscale via intermolecular interactions	79
Emerging trends in CO carbonylation	79
Chemical probes of redox enzymes by rational, reactivity-based design	78
Dynamic enzymatic synthesis of γ-cyclodextrin using a photoremovable hydrazone template	78
Direct enantioselective α-amination of amides guided by DFT prediction of E/Z selectivity in a sulfonium intermediate	78
Challenges and perspectives for the perovskite module research	78
Spontaneous chiral self-assembly of CdSe@CdS nanorods	77
Metal-free photocatalyzed cyanation enables access to carbon-11-radiolabeled aryl nitriles	76
A light-driven chloride anion transporter	75
Development of tumor-evolution-targeted anticancer therapeutic nanomedicineEVT	75
The key of Zn2+ transfer kinetics in zinc metal batteries	75
Programmable spatial organization of liquid-phase condensations	74
Deprotection of benzyl-derived groups via photochemically mesolytic cleavage of C–N and C–O bonds	74
Forging C−heteroatom bonds by transition-metal-catalyzed enantioselective C–H functionalization	73
Microporous B←N framework: A stable and efficient material for separating C2H2 and CO2	72
Finding your voice in a diverse audience: Lessons in writing and advocacy	70
Omics approach for electrolytes discovery	69
Rational structure transformation triggered by titanium modulation in metal-organic frameworks for efficient flue gas utilization	68
Industrial PhD: My way to go?	68
Plumbing the depths of the graphene wetting controversy	67
A clever trilayer assembly strategy for 2D materials	66
Ultralong ionic chains with lengths over 10 μm: A control of ionic molecular engineering	66
Cold-resilient zinc batteries with organic-free solvation structures	66
Reaction: Circular chemical imaginaries	66
A novel type of radical-addition-induced β-fragmentation and ensuing remote functionalization	66
Elucidating the role of cathode identity: Voltage-dependent reversibility of anode-free batteries	65
Oxygen-tolerant photocatalytic conversion of simulated flue gas to ethylene	65
Frontier research in perovskite solar cells: Following the paths of European research and innovation	64
Molecule additive design for perovskite light-emitting diodes operated at high current densities	64
Programmable in vitro and in vivo folding of single-stranded nucleic-acid wireframe origami	64
Remote optical chirality transfer via helical polyaromatic capsules upon encapsulation	64
Aqueous electrocatalytic small-molecule valorization trilogy	64
Transformable quadruply interpenetrated cage with multiple states of different reactivities	64
Deciphering reactive intermediates in electrooxidative coupling of indoles through real-time mass spectrometry	64
High-resolution transmission electron microscopy of beam-sensitive halide perovskites	63
Bioorthogonal reactions and AIEgen-based metabolically engineered theranostic systems	63
Cross-assembly confined bifunctional catalysis via non-covalent interactions for asymmetric halogenation	63
A B←N framework based on 1D dative B←N polymers for exclusive recognition and separation of benzene from its azeotrope	63
Amorphous materials emerging as prospective electrodes for electrochemical energy storage and conversion	63
Hydrogen-bonded organic frameworks: Chemistry and functions	62
Metal-organic frameworks for water vapor adsorption	62
Controlling dynamic reconstruction chemistry for superior oxygen-evolving catalysts	61
Rationalizing the design and implementation of chiral hybrid perovskites	61
In this issue	61
Stoichiometry alone can steer supramolecular systems on complex free energy surfaces with high selectivity	60
Genetically enabling phosphorus fluoride exchange click chemistry in proteins	60
Reversibly modulating a conformation-adaptive fluorophore in [2]catenane	60
Innovative low-carbon technology for a sustainable electrolyte industry	60
Conceptually novel diarylation for sustainable synthesis	60
Water, metal ions, and me: A chemist’s tale of serendipity and discovery	59
High-level hierarchical morphology reinforcing covalent adaptable networks	59
Microenvironment engineering of non-noble metal alloy for selective propane dehydrogenation	59
Synergizing palladium with Lewis base catalysis for stereodivergent coupling of 1,3-dienes with pentafluorophenyl acetates	59
In this issue	59
Electrocatalytic C–H phosphorylation through nickel(III/IV/II) catalysis	59
Single-chain polymerization dynamics and conformational mechanics of conjugated polymers	58
Atomically dispersed Ni induced by ultrahigh N-doped carbon enables stable sodium storage	57
Supramolecular interactions enable pseudo-nanophase separation for constructing an ion-transport highway	57
Self-adjusted aromatic cation-π binding promotes controlled self-assembly of positively charged π-electronic molecules	57
Stabilizing P≡P: P22–, P2⋅–, and P20 as bridging ligands	57
Correlations between precipitation reactions and electrochemical performance of lithium-sulfur batteries probed by operando scattering techniques	57
Synthesis of wafer-scale ultrathin graphdiyne for flexible optoelectronic memory with over 256 storage levels	57
Pursuing electrically pumped lasing with organic semiconductors	56
Sculpting photoproducts with DNA origami	56
Activating a light-driven molecular motor by metal complexation	55
Dispersion-driven formation of chiral twisted PAH double helices	55
The road to industrialization of fine chemical carboxylation reactions	54
Phenanthrenequinone-like moiety functionalized carbon for electrocatalytic acidic oxygen evolution	53
Self-sorting as a versatile strategy in the synthesis of rotaxanes and catenanes	53
Rational design and synthesis of two-dimensional conjugated metal-organic polymers for electrocatalysis applications	53
Metal-organic frameworks for fast electrochemical energy storage: Mechanisms and opportunities	53

Challenges for photocatalytic overall water splitting	51
Selective cellular probes for mammalian thioredoxin reductase TrxR1: Rational design of RX1, a modular 1,2-thiaselenane redox probe	51
Protein-directed, hydrogen-bonded biohybrid framework	51
Two (AgI3I)4L4 cages elucidate the rules for silver-cluster vertex design	50
Operando scattering techniques for detecting precipitation reactions in lithium-sulfur batteries	50
In my blue-light era	50
Supramolecular self-assembly of dinuclear alkynylplatinum(II) complexes into highly ordered crystalline hexagonal bipyramid superstructures	50
Borylation of azines via a Minisci-type reaction	50
Rethinking catalyst design by using data science	50
Aliphatic C–H bond methylation enabled by hydrogen atom transfer	49
Reaction: A three-pronged approach toward a sustainable chemical industry	49
DNA membrane nanopores with highly tunable shapes and sizes	49
In this issue	49
Boosting single-molecule magnet performance	49
Biocatalytic activation of diazirines for carbene-transfer reactions	49
The cyclotriborate trianion	49
Information transduction via fuel-controlled chemical waves	48
Engineering biotic-abiotic hybrid systems for solar-to-chemical conversion	48
Hydrophenazine-linked two-dimensional ladder-type crystalline fused aromatic network with high charge transport	48
Evidence for new enantiospecific interaction force in chiral biomolecules	48
Does in-situ-generated H2O2 promote important industrial reactions?	48
Ligand-enabled stereodivergence in nickel-catalyzed regioselective hydroboration of internal allenes	47
Bioengineering of syrbactin megasynthetases for immunoproteasome inhibitor production	47
Indocyanine polymethine fluorophores with extended π-conjugation emitting beyond 1,200 nm for enhanced NIR-II imaging	47
Ribosomal pentapeptide nitration for non-ribosomal peptide antibiotic precursor biosynthesis	46
Terpenoid-based high-performance polyester with tacticity-independent crystallinity and chemical circularity	46
Electrophilic selenium drives electron leakage	45
Bulk depolymerization of poly(methyl methacrylate) via chain-end initiation for catalyst-free reversion to monomer	45
Phosphorus fluoride exchange: Multidimensional catalytic click chemistry from phosphorus connective hubs	45
Palladium-catalyzed asymmetric hydrophosphination of internal alkynes: Atroposelective access to phosphine-functionalized olefins	45
Dicobalt-catalyzed N=N coupling reactions of tertiary alkyl azides to form azoalkanes	45
Zero-valent species of group 13–15 elements	45
Surface and interface control of black phosphorus	44
Tailoring dynamic hydrogels by controlling associative exchange rates	44
Electrolyte engineering for highly inorganic solid electrolyte interphase in high-performance lithium metal batteries	44
A sustainable cobalt separation with validation by techno-economic analysis and life-cycle assessment	44
Van der Waals organic/inorganic heterostructures in the two-dimensional limit	44
Supramolecular repair of hydration lubrication surfaces	43
A 10-nm-sized multicompartment cuboctahedron and its 2D hierarchical arrays observed by cryo-EM	43
Role of delocalized electrons on the doping effect in vanadia	43
Applications of molecularly imprinted polymers and perspectives for their use as food quality trackers	43
Versatile deacylative cross-coupling of aromatic ketones	43
Molecular design of covalent organic frameworks for seawater desalination: A state-of-the-art review	43
Interplay between remote single-atom active sites triggers speedy catalytic oxidation	43
Tumor microenvironment-tailored nanoplatform for companion diagnostic applications of precise cancer therapy	43
Single-molecule spectroscopic probing of N-heterocyclic carbenes on a two-dimensional metal	43
Remotely controllable supramolecular rotor mounted inside a porphyrinic cage	43
Championing systems thinking to create a circular economy of chemicals	42
Reaction: Navigating the promises and perils of AI-powered drug synthesis	42
Selective hydrogenation catalysis enabled by nanoscale galvanic reactions	42
Single-component organic solar cells with over 11% efficiency	42
4-Pyridyl perfluoroalkyl sulfide as a practical nucleophilic perfluoroalkylation reagent	42
Synthesizing a nanographyne	41
Mucin-mimetic glycan arrays integrating machine learning for analyzing receptor pattern recognition by influenza A viruses	41
Perovskite intermediate phases fundamentally address the urgent stability issue	41
Elucidating non-radiative decay in near-infrared lumiphores: Leveraging new design principles to develop a telecom band organic dye laser	40
Controlled radical depolymerization: Structural differentiation and molecular weight control	40
Chlorine-free synthesis of axially chiral organophosphorus compounds from white phosphorus	40
Biosynthesis and genetic encoding of activated nitriles for fast protein conjugation and tunable fluorogenic labeling	40
Uncovering strong π-metal interactions on Ag and Au nanosurfaces under ambient conditions via in-situ surface-enhanced Raman spectroscopy	39
Non-covalent interactions of graphene surface: Mechanisms and applications	39
An angstrom-level d-spacing control of graphite oxide using organofillers for high-rate lithium storage	39
Iron-mediated modular decarboxylative cross-nucleophile coupling	39
Quantum-dot-photocatalyzed production of allylic C–C products with hydrogen evolution	39
Visible-light-induced coupling of carboxylic acids with alcohols/amines via a phosphorous linchpin strategy	39
A single-crystalline 2D polymer network mechanically interlocked by [c2]daisy chains	39
Divergent synthesis of conidiogenones B–F and 12β-hydroxyconidiogenone C	39
New insights and discoveries in anion receptor chemistry	39
Accelerating PERx reaction enables covalent nanobodies for potent neutralization of SARS-CoV-2 and variants	39
Carbon nitride of five-membered rings with low optical bandgap for photoelectrochemical biosensing	39
Porous organic polymers with heterocyclic crown ethers for selective lithium-ion capture	38
The subtle art of radical control	38
Communication between active sites regulates heterogeneous catalysis	38
Out-of-equilibrium chemical logic systems: Light- and sound-controlled programmable spatiotemporal patterns and mechanical functions	38
Selection of assembly complexity in a space of tetrapeptides	38
The sustainability potential of single-atom catalysts in chemical process	38
A molecular communication channel consisting of a single reversible chain of hydrogen bonds in a conformationally flexible oligomer	38
Stereodynamics of E/Z isomerization in rotaxanes through mechanical shuttling and covalent bond rotation	38
Photoinduced, ground-state charge-transfer complex	38
Tetragonal gyroid structure from symmetry manipulation: A brand-new member of the gyroid surface family	38
Nanocomposite DNA hydrogels emerging as programmable and bioinstructive materials systems	38
New light on proton transfer: Spectral and kinetic signature of a transient Eigen complex	38
Reaction: The challenge of open-shell transition metal catalysis in “systems chemistry”	38
Deciphering the rational design of the early transition metals for ammonia synthesis	37
Circumventing the activity-selectivity trade-off: Pt-Fe-Pt active sites for selective heterogeneous hydrogenation of crotonaldehyde	37
Versatile selective-absorber-based photothermocatalytic reactor for solar fuel synthesis	37
BINOLates as potent reducing photocatalysts for inert-bond activation and reduction of unsaturated systems	37
Fluoride up- and down-regulates guest encapsulation for ZnII6L4 and ZnII4L4 cages	37
Programmable reconfiguration of one-dimensional supramolecular polymers into multidimensional topological nanostructures	37
In This Issue	37
An ultra-dynamic anion-cluster-based organic framework	36
Acceleration of reverse intersystem crossing in multi-resonance TADF emitter	36
Chiral inorganic nanomaterials for biomedical applications	36
Interfacial water regulation for water-participating electrocatalytic hydrogenation reactions	36
Selective and stable upgrading of biomass-derived furans into plastic monomers by coupling homogeneous and heterogeneous catalysis	36