Chem

Article	Citations
In this issue	500
In This Issue	341
Obtaining clean hydrogen from waste plastics	314
Repurposing myoglobin into an abiological asymmetric ketoreductase	281
Catalyst: Systems chemistry links reactions to molecular function	276
A bulky 1,4,7-triazacyclononane and acetonitrile, a Goldilocks system for probing the role of NiIII and NiI centers in cross-coupling catalysis	274
Concise chemoenzymatic synthesis of N-glycans	265
Weaving DNA strands to control energy	220
Harnessing the reactivity of borenium for methane activation	217
Accessing aliphatic alcohols for metallaphotoredox catalyzed C(sp3)-arylation	216
Growing twisted bilayer graphene at small angles	203
Economical and efficient access to polyselenophene derivatives	193
Reactive bonds for closed-loop chemical processing of polyethylene mimics	181
Ion-pair effects in photoredox chemistry	177
Perrhenate recognition within a superphane cavity	175
In this issue	174
Dual catalysis by homogeneous/heterogeneous ruthenium species	163
Quantum-dot-photocatalyzed production of allylic C–C products with hydrogen evolution	160
In this issue	150
Stereoselective synthesis of topologically chiral molecular entanglements	150
Elucidating non-radiative decay in near-infrared lumiphores: Leveraging new design principles to develop a telecom band organic dye laser	148
Machine learning photodynamics uncover blocked non-radiative mechanisms in aggregation-induced emission	147
Visible-light-induced coupling of carboxylic acids with alcohols/amines via a phosphorous linchpin strategy	144
Leukocyte-nanomedicine system for targeted delivery and precise theragnostics	144
Computational de novo protein design: From secondary to primary, then toward tertiary structures	142

Deciphering Catalytic Selectivity on Uneven Terraces	126
New insight into carrier transport in 2D layered perovskites	120
Perovskite intermediate phases fundamentally address the urgent stability issue	118
B(C6F5)3-catalyzed selective C–H chalcogenation of arenes and heteroarenes	116
From carbon superbases to superacids	115
Designing carbon dots for enhanced photo-catalysis: Challenges and opportunities	115
In situ probing the origin of interfacial instability of Na metal anode	113
Reaction: Is a circular economy for chemicals and materials possible?	113
Championing systems thinking to create a circular economy of chemicals	113
Making monodispersed ultralong graphene nanoribbons with an accelerated iterative approach	111
Ampere-level CO2-to-formate electrosynthesis using highly exposed bismuth(110) facets modified with sulfur-anchored sodium cations	109
The legacy of Professor Li-Xin Dai: Organometallic and asymmetric catalysis	109
Organic charge-transfer complex induces chemoselective decarboxylation to aryl radicals for general functionalization	109
Single-step conversion of wood lignin into phenolic amines	108
Camphor the polymerization; stay for the depolymerization	108
In this issue	107
Hierarchical toughening: A step toward matching the complexity of biological materials	106
One ring to rule them all	105
Grinding the way to enantiopurification	104
Divergent synthesis of conidiogenones B–F and 12β-hydroxyconidiogenone C	103
Variable nanosheets for highly efficient oxygen evolution reaction	102
Anchoring the AIEgen by Zr clusters in metal-organic gel for efficient X-ray detection and imaging	101
Lanthanide luminescence from supramolecular hydrogels consisting of bio-conjugated picolinic-acid-based guanosine quadruplexes	101
Measuring solubility automatically with vision	100
Construction of a caged single-molecule protein with ultra-stability	99
Synthesizing a nanographyne	97
Three-component aminofluorination of alkenes with electronically rich amino sources	95
Open-Shell Graphene Fragments	95
A nanopore distance away from next-generation protein sequencing	94
Reaction: Harnessing reactive oxygen species (ROS) for water purification	92
Out-of-equilibrium chemical logic systems	92
Exploiting charged groups for metal-catalyzed meta-C–H functionalization of arenes	91
Thermosetting supramolecular polymerization of compartmentalized DNA fibers with stereo sequence and length control	90
4-Pyridyl perfluoroalkyl sulfide as a practical nucleophilic perfluoroalkylation reagent	90
A multistate memory cell based on electrochromic metallo-organic assemblies	90
Selective tumor targeting enabled by picomolar fibroblast activation protein inhibitors isolated from a DNA-encoded affinity maturation library	88
Photothermal tandem catalysis for CO2 hydrogenation to methanol	88
Bulk Grain-Boundary Materials from Nanocrystals	88
Element-specific electronic and structural dynamics using transient XUV and soft X-ray spectroscopy	85
Mucin-mimetic glycan arrays integrating machine learning for analyzing receptor pattern recognition by influenza A viruses	85
Anion-coordination- and π-π-stacking-interaction-driven assembly of a complex Frank-Kasper structure	84
Phonon-promoted superionic conduction in fluorite-structured compounds	84
Multiscale design of biological meta-composites with omnidirectional crack resistance	84
Catalytic cross-electrophile coupling of aryl chlorides with unactivated alkyl chlorides: The synergy of iron and Li	84
Reinforced double-threaded slide-ring networks for accelerated hydrogel discovery and 3D printing	82
Deciphering nickel-catalyzed electrochemical ammonia synthesis from nitric oxide	82
Probing enantioinduction in confined chiral spaces through asymmetric oxime reductions	81
Terahertz-Raman spectroscopy for in situ benchtop monitoring of changes to extended, supramolecular structure in milling mechanochemistry	79
Strong uranium-phosphorus antiferromagnetic exchange coupling in a crystalline diphosphorus radical trianion actinide complex	77
Selective hydrogenation catalysis enabled by nanoscale galvanic reactions	76

Quantity effect of heteroatom incorporation on the oxygen evolution mechanism in ruthenium oxide	76
One-pot catalytic conversion of polyethylene wastes to gasoline through a dual-catalyst system	76
Excited-state protonation and reduction enables the umpolung Birch reduction of naphthalenes	76
Nanocellulose: New horizons in organic chemistry and beyond	75
In this issue	74
Charge delocalization and global aromaticity in a partially fused 12-porphyrin nanoring	73
Oscillatory adaptive catalysis: Intramolecular chain shuttling regulated by stereo-autocorrection in stereoselective polymerization of lactide	73
A high-throughput workflow to analyze sequence-conformation relationships and explore hydrophobic patterning in disordered peptoids	73
Persistent and Stable Organic Radicals: Design, Synthesis, and Applications	72
Quantifying zinc and manganese reduction potentials in organic solvents	72
Metalloradical activation of carbonyl azides for enantioselective radical aziridination	71
2D covalent organic framework via catenation	68
Run-and-halt motility of droplets in response to light	67
Enhanced coherence by coupling spins through a delocalized π-system: Vanadyl porphyrin dimers	67
Enantioselective hydroamination of unactivated terminal alkenes	67
Developing real-time mechanochromic probes for polymeric materials	66
Precision in protein chemical modification and total synthesis	66
Porous organic polymers with heterocyclic crown ethers for selective lithium-ion capture	65
A plausible prebiotic selection of ribose for RNA - formation, dynamic isolation, and nucleotide synthesis based on metal-doped-clays	64
Spin-coupled electron densities of iron-sulfur cluster imaged by in situ serial Laue diffraction	64
Tuning the gating energy barrier of metal-organic framework for molecular sieving	64
Evolution of MOF single crystals	64
In situ characterization techniques and methodologies for high-temperature electrochemistry	64
Nanocomposite DNA hydrogels emerging as programmable and bioinstructive materials systems	64
Reticular chemistry in action: 3D porphyrinic COFs with scu topology	63
A new nexus in metal-organic frameworks	63
Quasicrystal approximants in isoreticular metal-organic frameworks via Cairo pentagonal tiling	62
New insights and discoveries in anion receptor chemistry	61
Organo-Se BTSAs-enabled performance: From racemic and asymmetric synthesis to click chemistry application	60
Computation-aided design of oxygen-ligand-steered single-atom catalysts: Sewing unzipped carbon nanotubes	59
Misorientation strategy on high-entropy metal oxides for enhanced acidic oxygen evolution reaction	59
Efficient earth-abundant copper photocatalysis enabled by metal-arene interaction	58
Broken vows: Separation of carbene and the lone pair unleashes dicationic revelry	58
Curbing pollutant CO2 by using two-dimensional MXenes and MBenes	57
An angstrom-level d-spacing control of graphite oxide using organofillers for high-rate lithium storage	57
Solid-state photon energy storage via reversible [2+2] cycloaddition of donor-acceptor styrylpyrylium system	57
Selective hydroboration of terminal alkynes catalyzed by heterometallic clusters with uranium–metal triple bonds	57
Mirror-image protein and peptide drug discovery through mirror-image phage display	56
Recent research progress of all-polymer solar cells based on PSMA-type polymer acceptors	56
Trapping highly reactive photoinduced charge-transfer complex between amine and imide by light	56
New rhodamines with changeable π-conjugation for lengthening fluorescence wavelengths and imaging peroxynitrite	55
Uncovering strong π-metal interactions on Ag and Au nanosurfaces under ambient conditions via in-situ surface-enhanced Raman spectroscopy	55
Biosynthesis and genetic encoding of activated nitriles for fast protein conjugation and tunable fluorogenic labeling	54
Palladium/Xu-Phos-catalyzed enantioselective cascade Heck/remote C(sp2) –H alkylation reaction	54
Medium-independent hydrogen atom binding isotherms of nickel oxide electrodes	54
CO2-mediated oxidative dehydrogenation of propane enabled by Pt-based bimetallic catalysts	54
Accelerating Li-based battery design by computationally engineering materials	54
Design principle of electrocatalysts for the electrooxidation of organics	54
Deciphering and modulating energetics of solvation structure enables aggressive high-voltage chemistry of Li metal batteries	54
Porous materials for hydrogen storage	53
Bioorthogonal click and release: A general, rapid, chemically revertible bioconjugation strategy employing enamine N-oxides	53
Sequence-specific, mechanophore-free mechanochemistry of DNA	53
Revealing phase evolution mechanism for stabilizing formamidinium-based lead halide perovskites by a key intermediate phase	53
Sensitive short-wavelength infrared photodetection with a quinoidal ultralow band-gap n-type organic semiconductor	53
Carbon nitride of five-membered rings with low optical bandgap for photoelectrochemical biosensing	53
Nature-inspired synthetic oligourea foldamer channels allow water transport with high salt rejection	52
Weak bonding strategies for achieving regio- and site-selective transformations	51
Spatially resolved cell tagging and surfaceome labeling via targeted photocatalytic decaging	51
Water-involved methane-selective catalytic oxidation by dioxygen over copper zeolites	50
Universal self-driving laboratory for accelerated discovery of materials and molecules	50
Artificial light-triggered smart nanochannels relying on optoionic effects	50
Stabilizing the microstructure for Y6-series nonfullerene solar cells	50
Experimentally modeling the emergence of prebiotically plausible phospholipid vesicles	50
Generative design of de novo proteins based on secondary-structure constraints using an attention-based diffusion model	50
Click chemistry in polymer science	49
Reaction: Navigating the promises and perils of AI-powered drug synthesis	49
Photoswitches and photochemical reactions for optically controlled phase transition and energy storage	49
A Star of David [2]catenane of single handedness	49
Tetragonal gyroid structure from symmetry manipulation: A brand-new member of the gyroid surface family	49
Conformational selection accelerates catalysis by an organocatalytic molecular motor	49
Carbohydrate amphiphiles for supramolecular biomaterials: Design, self-assembly, and applications	49
An old polymer class revisited: Versatile, degradable, non-alternating polyketones	49
An evolutionary algorithm for interpretable molecular representations	48
In this issue	48
Rapid determination of experimental sorption isotherms from non-equilibrium sorption kinetic data	48
Selective nitrogen fixation via Janus C-N coupling in co-electrolysis	48
Peptide self-assembly through liquid-liquid phase separation	48
Polypeptide-based batteries toward sustainable and cyclic manufacturing	47
Hierarchical anions at the electrode-electrolyte interface for synergized neutral water oxidation	47
Liquid fuel synthesis via CO2 hydrogenation by coupling homogeneous and heterogeneous catalysis	47

Weaving on a molecular scale: A challenge in two dimensions	46
2D conjugated metal-organic framework as a proton-electron dual conductor	46
Heterogeneous manganese-oxide-catalyzed successive cleavage and functionalization of alcohols to access amides and nitriles	46
Construction of a three-state responsive framework from a bistable photoswitch	46
Rationally fabricating 3D porphyrinic covalent organic frameworks with scu topology as highly efficient photocatalysts	45
Fertilizer and oxygen from Martian atmosphere via microwave plasma	45
Non-covalent interactions of graphene surface: Mechanisms and applications	45
Catalyst: The roles of chemistry in clean water for all	44
Interface of biomolecular condensates modulates redox reactions	44
Emissive fluoren-triangles for solid-state fluorochromism and selective gas sorption	44
Iron-mediated modular decarboxylative cross-nucleophile coupling	44
Visible-light photoredox-catalyzed selective carboxylation of C(sp3)−F bonds with CO2	43
Real-time observation of the dynamics of an individual rotaxane molecular shuttle using a single-molecule junction	43
Switching the O–O bond-formation mechanism by controlling water activity	42
From trash to treasure: Vanadium-catalyzed upcycling of non-biodegradable plastics	42
Accelerating PERx reaction enables covalent nanobodies for potent neutralization of SARS-CoV-2 and variants	42
Unified sensing of the concentration and enantiomeric composition of chiral compounds with an achiral probe	42
Atropisomers beyond the C–C axial chirality: Advances in catalytic asymmetric synthesis	42
Cationic polaron delocalization in porphyrin nanoribbons	41
Engineering couplings for exciton transport using synthetic DNA scaffolds	41
Optical processes in carbon nanocolloids	41
Controlled radical depolymerization: Structural differentiation and molecular weight control	41
A prebiotic Krebs cycle analog generates amino acids with H2 and NH3 over nickel	41
Controlled radical depolymerization: Structural differentiation and molecular weight control	41
Reshaping quinolines by single-electron-transfer-triggered dearomatization	41
Electrochemical CO2 reduction in membrane-electrode assemblies	41
Bifunctional tandem catalytic upcycling of polyethylene to surfactant-range alkylaromatics	41
ortho-Aromatic polyamides by ring-opening polymerization of N-carboxyanhydrides	40
Transformative ligand effects in iron photocatalysis	40
Shining light on nitrogen: Alkene amination with N-heteroaromatic radicals via energy transfer	39
Development of an energy-dense and high-power Li-Cl2 battery using reversible interhalogen bonds	39
The progress and challenges of tin-lead alloyed perovskites: Toward the development of large-scale all-perovskite tandem solar cells	39
Fluorinating electrophilic interception in the oxidation or protonation of alkynyl tetracoordinate borons	39
Efficient flow synthesis of a Star of David [2]catenane and a pentafoil knot	39
Directed discovery of high-loading nanoaggregates enabled by drug-matched oligo-peptide excipients	38
Intramolecular [3 + 2] annulation of allenylsilane-enes: Direct synthesis of highly strained trans-fused 5/5 ring systems	38
Catalyst: Circular chemical economy: Facts, fictions, futures	38
Macrocyclic ligands open new channels in electrically conductive metal-organic frameworks	38
From low-res measurements to high-res insights: Revolutionizing COF structural determination	38
Catalyst metal-ligand design for rapid, selective, and solventless depolymerization of Nylon-6 plastics	38
Metal ions turn on a stereoselective nonenzymatic reduction of keto acids by the coenzyme NADH	37
Redox-couple-assisted CO2 capture on solid-electrolyte reactor	37
Kinetic sieving separation of a gating macrocyclic crystal for purification of propylene	37
Transfer hydroarylation of ketones using directing-group-free, unstrained alcohols	37
The legacy of Ei-ichi Negishi: Eternal optimism and excellence	37
Polyolefin recycling by C–C bond alumination	37
Precise recognition of palladium through interlaminar chelation in a covalent organic framework	36
Communication between active sites regulates heterogeneous catalysis	36
Deciphering the rational design of the early transition metals for ammonia synthesis	36
Advancing aromatic ketones as aryl electrophiles in versatile cross-coupling reactions	35
Quantitative and qualitative analysis of nitrogen species in carbon at the ppm level	35
New trends for transition metal-catalyzed ortho/ipso difunctionalizations of arenes	35
In this issue	35
Synthesis of polyethylene-polyacrylate block copolymers in continuous flow	35
Panchromatic light-harvesting antenna by supramolecular exciton band engineering for heteromeric dye foldamer	35
Acceleration of reverse intersystem crossing in multi-resonance TADF emitter	35
Controlled catalyst-transfer polymerization in graphene nanoribbon synthesis	34
An effective strategy to boost lattice-oxygen-mediated acidic oxygen evolution	34
Evolutionary features for task-specific machine-learning applications	34
In this issue	34
In this issue	34
Molecular freaky Friday: Polarity reversal and resorcin[4]arenes as chloride receptors	34
Synthetic chemistry recreates transitional forms in prebiotic membrane evolution	34
A chiral macrocycle for the stereoselective synthesis of mechanically planar chiral rotaxanes and catenanes	33
Tactics for uncovering intermediates in nickel Kumada cross-coupling catalysis	33
Direct air capture with bis-iminoguanidines: From discovery to commercialization	33
In this issue	33
Methane activation by a borenium complex	33
Higher-order cycloadditions in the age of catalysis	33
Swapping benches from chemistry PhD student to science advisor at law firm	33
In this issue	33
2D/3D perovskite engineering eliminates interfacial recombination losses in hybrid perovskite solar cells	33
Fast, reversible mechanochromism of regioisomeric oxazine mechanophores: Developing in situ responsive force probes for polymeric materials	32
Charging processes in lithium-oxygen batteries unraveled through the lens of the distribution of relaxation times	32
Modular nucleic acid scaffolds for synthesizing monodisperse and sequence-encoded antibody oligomers	32
Curved plane increases the d vacancy population of Pd for green production of cyclohexanone	32
Enantioselective sulfinylation of alcohols and amines by condensation with sulfinates	32
Electrochemical ammonia synthesis: Mechanistic understanding and catalyst design	32
In situ monitoring of mechanochemical covalent organic framework formation reveals templating effect of liquid additive	32
Biomimetic synthesis of pallavicinin, neopallavicinin, pallambins A–D, pallaviambins A/B, and pallavicinolides B/C	32
Synthesis of magnesium nanoparticle for NIR-II-photoacoustic-imaging-guided synergistic burst-like and H2 cancer therapy	32
Inverse doping IrOx/Ti with weakened Ir-O interaction toward stable and efficient acidic oxygen evolution	32
Dynamic restructuring of epitaxial Au–Cu biphasic interface for tandem CO2-to-C2+ alcohol conversion	31
Catalytic strategies for upvaluing plastic wastes	31
Constructing FeN4/graphitic nitrogen atomic interface for high-efficiency electrochemical CO2 reduction over a broad potential window	31
Rational design of enantiomeric lead-free double perovskites by achiral-chiral cation intercalation	31
Cation-exchange-upgraded nanostructures for photocatalysts	31
Negating Li+ transfer barrier at solid-liquid electrolyte interface in hybrid batteries	30
Discovery of the Pendulisporaceae: An extremotolerant myxobacterial family with distinct sporulation behavior and prolific specialized metabolism	30
In this issue	30
Combinatorial selective synthesis and excitation experiments for quantitative analysis of effects of Au on a semiconductor photocatalyst	30
Creation and optimization of artificial metalloenzymes: Harnessing the power of directed evolution and beyond	30
An ultra-dynamic anion-cluster-based organic framework	30
From G-protein-coupled receptors to solute carriers—mass spectrometry informs dynamics, function, and regulation	30
Poison to promise: The resurgence of organophosphorus fluoride chemistry	30