Chem

Article	Citations
Out-of-equilibrium chemical logic systems	461
In this issue	458
From trash to treasure: Vanadium-catalyzed upcycling of non-biodegradable plastics	447
Reaction: Harnessing reactive oxygen species (ROS) for water purification	369
Harnessing plastic depolymerization products to upcycle mixed waste into high-value chemicals	363
A high-throughput workflow to analyze sequence-conformation relationships and explore hydrophobic patterning in disordered peptoids	326
Probing enantioinduction in confined chiral spaces through asymmetric oxime reductions	268
Photoswitches and photochemical reactions for optically controlled phase transition and energy storage	239
A Star of David [2]catenane of single handedness	237
Selective recognition of quaternary ammonium cations	226
Variable nanosheets for highly efficient oxygen evolution reaction	215
Highly selective and efficient uranium recovery by size-sieving porous aromatic frameworks with rigidly functionalized windows	202
ElectroChemputer with integrated monitoring for programmable electrochemistry	196
An M60L60 metal-peptide capsid with a 60-crossing woven network	194
N-Heterocyclic carbene-derived second-period main-group radicals: Synthesis, fundamentals, and applications	179
Quasicrystal approximants in isoreticular metal-organic frameworks via Cairo pentagonal tiling	176
2D conjugated metal-organic framework as a proton-electron dual conductor	168
Ion-dipole-interaction-manipulated bilateral interface chemistry for deep rechargeability and high redox activity of Zn-organic batteries	163
Air-stable radical polycyclic aromatic hydrogen-bonded organic frameworks	162
Nanocellulose: New horizons in organic chemistry and beyond	161
Programming extracellular protein fate with peptide chimeras	159
Click chemistry in polymer science	155
Recent research progress of all-polymer solar cells based on PSMA-type polymer acceptors	154
Experimentally modeling the emergence of prebiotically plausible phospholipid vesicles	153
Transitioning aliphatic C–H functionalization from bench to plant: Is decatungstate photocatalysis ready for the leap yet?	152

Chem at 10: Ben Zhong Tang	152
Chem at 10: Jonathan L. Sessler	151
Catalysis, replication, and non-equilibrium behavior: Key determinants for life-like complexity realized using short peptides	150
B(C6F5)3-catalyzed selective C–H chalcogenation of arenes and heteroarenes	149
2D covalent organic framework via catenation	147
Multi-omics profiling of a self-assembling bioactive hydrogel for immunomodulation and myogenesis in volumetric muscle loss	143
Spatially resolved cell tagging and surfaceome labeling via targeted photocatalytic decaging	142
Excited-state protonation and reduction enable the umpolung Birch reduction of naphthalenes	138
Nature-inspired synthetic oligourea foldamer channels allow water transport with high salt rejection	137
Atom swap in triple bonds via nitrogen-deletion coupling with gem-diborylalkanes	136
The beauty of low symmetry: Non-statistical assembly of [Pd2(LA)(LB)(LC)(LD)]4+ cages	134
Catalytic strategies for upvaluing plastic wastes	133
Be your own star	133
Redox-couple-assisted CO2 capture on solid-electrolyte reactor	133
Molecular freaky Friday: Polarity reversal and resorcin[4]arenes as chloride receptors	127
Swapping benches from chemistry PhD student to science advisor at law firm	127
In this issue	125
para-Selective C–H alkylation of aroyl chlorides through organic photoredox-catalyzed radical tele-substitution	123
Improving productivity and stability for CO2 hydrogenation by using pincer-ligated Mn complexes with hemilabile ligands	122
Iridium-mediated methane dehydrogenation and methylidene (=CH2) transfer	122
Time-resolved fluorescence imaging with color-changing, “turn-on/turn-on” AIE nanoparticles	120
Reaction: Don’t hate the player in chemical AI; hate the game	119
An effective strategy to boost lattice-oxygen-mediated acidic oxygen evolution	118
Semiconducting ladder-type covalent organic frameworks	116
Battery detectives: Uncovering cathode impact on anode-free Li cell performance by operando NMR	114
In this issue	114
Supramolecular boosted superexchange	113
Photo-assembling cyclic peptides for dynamic light-driven peptide nanotubes	108
Highly oxygenated organic molecules with high unsaturation formed upon photochemical aging of soot	107
Structure-performance relationships for catalysis-driven molecular machinery	107
Observation of ultrafast electrons in pendant-embedded conducting two-dimensional polymers	107
From G-protein-coupled receptors to solute carriers—mass spectrometry informs dynamics, function, and regulation	105
Ionic surface propensity controls pH in nanopores	104
Breaking ampere-level current density limitations in multi-carbon products through crystal facet engineering	102
In This Issue	102
Transition metal-free difunctionalization of unactivated alkenes: Arylation/azidation, arylation/chlorination, and arylation/cyanation	99
General and selective metal-free radical α-C–H borylation of aliphatic amines	99
Modular nucleic acid scaffolds for synthesizing monodisperse and sequence-encoded antibody oligomers	97
Bioinspired chemical design to control interfacial wet adhesion	95
Switchable diversification of quaternary ammonium salts using photocatalysis	95
Strong halide anion binding within the cavity of a conformation-adaptive phenazine-based Pd2L4 cage	94
A radical–polar crossover approach to complex nitrogen heterocycles via the triplet state	93
Oxygen reduction active-site regulation enables reverse photocurrent in photoelectrochemical sensing	93
Stereodivergent asymmetric hydrogenation of quinoxalines	89
Cation-exchange-upgraded nanostructures for photocatalysts	89
Solvent-mediated electrochemical acetylene semihydrogenation for continuous production of polymer-grade ethylene	89
Curved plane increases the d vacancy population of Pd for green production of cyclohexanone	88
Two-in-one metallaphotoredox cross-couplings enabled by a photoactive ligand	88
Phosphine oxide additives for perovskite light-emitting diodes and solar cells	86
Molecule-resolvable SERSome for metabolic profiling	86

Design of piezoelectric organic cage salts for energy harvesting	86
Pilot-scale reductive catalytic depolymerization of lignin: Challenges and guidelines	85
Advances in polymer chemistry enabled by transition metal catalysis	84
Revisiting the impacts of silica nanoparticles on endothelial cell junctions and tumor metastasis	83
Potent antimicrobial effect induced by disruption of chloride homeostasis	83
Antigen spatial-matching polyaptamer nanostructure to block coronavirus infection and alleviate inflammation	83
A light-driven chloride anion transporter	83
Ice quenching for sustained nucleate boiling at large superheats	82
Designing generative dissipative networks for programming complex temporal dynamics and functions	81
The key of Zn2+ transfer kinetics in zinc metal batteries	81
Metal-free photocatalyzed cyanation enables access to carbon-11-radiolabeled aryl nitriles	80
The role of concentration waves in synthesizing hollow multi-shelled structures	80
From “heavy” water to “heavy” boron clusters	79
Enzymatic DNA orthogonal chemistry for multi-cancer diagnosis	78
Unexpected diastereoselective chemistry on a 2D protein surface	78
Colorless zinc colored by metal-metal orbital interaction	78
Direct enantioselective α-amination of amides guided by DFT prediction of E/Z selectivity in a sulfonium intermediate	77
From making molecules to redesigning discovery	76
Deprotection of benzyl-derived groups via photochemically mesolytic cleavage of C–N and C–O bonds	76
Development of tumor-evolution-targeted anticancer therapeutic nanomedicineEVT	74
Emerging trends in CO carbonylation	74
The 40th anniversary of covalent dendrimers	74
Challenges and perspectives for the perovskite module research	73
A dynamic charge-dependent nanofungicide platform for sustainable agrochemical deposition and delivery	72
The mechanical bond in biological systems	71
A clever trilayer assembly strategy for 2D materials	71
Industrial PhD: My way to go?	71
Molecule additive design for perovskite light-emitting diodes operated at high current densities	71
Omics approach for electrolytes discovery	70
Programmable in vitro and in vivo folding of single-stranded nucleic-acid wireframe origami	70
Reaction: Circular chemical imaginaries	70
A novel type of radical-addition-induced β-fragmentation and ensuing remote functionalization	70
Deciphering reactive intermediates in electrooxidative coupling of indoles through real-time mass spectrometry	69
Rational structure transformation triggered by titanium modulation in metal-organic frameworks for efficient flue gas utilization	69
Ultralong ionic chains with lengths over 10 μm: A control of ionic molecular engineering	68
Bioorthogonal reactions and AIEgen-based metabolically engineered theranostic systems	68
Microporous B←N framework: A stable and efficient material for separating C2H2 and CO2	68
Remote optical chirality transfer via helical polyaromatic capsules upon encapsulation	68
The Cation Shuffle: Interplay of silylium, carbenium, and arenium ions in superelectrophile catalysis	67
Interfacial hydrogen-bond network regulation enables selective CO2 reduction to ethanol on copper-free electrocatalysts	67
Aqueous electrocatalytic small-molecule valorization trilogy	67
One step further to efficient Li-mediated ammonia synthesis in flow cells	66
Regulating the topology and pore size of covalent metal-organic framework for boosting catalytic CO2 conversion	66
Transformable quadruply interpenetrated cage with multiple states of different reactivities	65
Water-centric framework for confinement catalysis: Beyond nanomaterials	65
Cross-assembly confined bifunctional catalysis via non-covalent interactions for asymmetric halogenation	65
Cold-resilient zinc batteries with organic-free solvation structures	65
Light-intensity-dependent out-of-equilibrium processes toward dimensionally distinct nanopolymorphs	64
Frontier research in perovskite solar cells: Following the paths of European research and innovation	64
An isolable nitrene radical anion as a nucleophilic open-shell nitrogen synthon	63
Amorphous materials emerging as prospective electrodes for electrochemical energy storage and conversion	63
Oxygen-tolerant photocatalytic conversion of simulated flue gas to ethylene	63
Metal-organic frameworks for water vapor adsorption	62
Unlocking the synthesis of homochiral carborane-fused boraphenanthrenes	62
A B←N framework based on 1D dative B←N polymers for exclusive recognition and separation of benzene from its azeotrope	62
Hydrogen-bonded organic frameworks: Chemistry and functions	62
Elucidating the role of cathode identity: Voltage-dependent reversibility of anode-free batteries	62
Controlling dynamic reconstruction chemistry for superior oxygen-evolving catalysts	62
Divergent scaffold redesign of ecteinascidin 743 as a gateway to anticancer macrocycles	61
Sculpting photoproducts with DNA origami	60
Water, metal ions, and me: A chemist’s tale of serendipity and discovery	60
Rewriting lysine reactivity: Lysine-targeted bioconjugation via biomimetic polarity reversal for diversified biomolecule modification	60
Long-wavelength photocatalysis enabled by an in-situ-assembled manganese platform	60
Innovative low-carbon technology for a sustainable electrolyte industry	60
In this issue	60
Synergizing palladium with Lewis base catalysis for stereodivergent coupling of 1,3-dienes with pentafluorophenyl acetates	60
DNA-mediated force transmission for precise and efficient mechanochemical activation	60
Directional long-distance signal transmission on two-dimensional DNA origami assemblies	59
Isoreactivity in chemistry	59
Self-assembly of 10-nm-sized pentagonal dodecahedra through heteroleptic complexation coupled with orientational self-sorting	59
Genetically enabling phosphorus fluoride exchange click chemistry in proteins	58
Downsizing lactams via Rh-catalyzed C–C activation	58
Confinement-induced chiroptical photoswitching —An encapsulation approach for advanced photochemical functions	58
Dispersion-driven formation of chiral twisted PAH double helices	57
Multiply entangled receptors for high-affinity anion recognition in water	57
Metal-organic frameworks for fast electrochemical energy storage: Mechanisms and opportunities	57
Supramolecular interactions enable pseudo-nanophase separation for constructing an ion-transport highway	56
Dynamic mechanoresponsive polymers enabled by ring-opening polymerization of cyclic propargyl carbonates	56
Modular synthesis of fluoroalkyl-substituted cyclopropenes with fluoroalkylacylsilanes as carbynyl cation equivalents	56
Self-sorting as a versatile strategy in the synthesis of rotaxanes and catenanes	56

Microenvironment engineering of non-noble metal alloy for selective propane dehydrogenation	55
In this issue	55
Activating a light-driven molecular motor by metal complexation	55
Boosting single-molecule magnet performance	55
Self-adjusted aromatic cation-π binding promotes controlled self-assembly of positively charged π-electronic molecules	55
The cyclotriborate trianion	55
Electrophilic selenium drives electron leakage	54
Role of delocalized electrons on the doping effect in vanadia	54
Supramolecular self-assembly of dinuclear alkynylplatinum(II) complexes into highly ordered crystalline hexagonal bipyramid superstructures	53
Dicobalt-catalyzed N=N coupling reactions of tertiary alkyl azides to form azoalkanes	53
A critical assessment of fluorescent probes as cellular reporters for thioredoxin system enzyme activities	53
Interplay between remote single-atom active sites triggers speedy catalytic oxidation	53
In my blue-light era	53
Rethinking catalyst design by using data science	52
Reaction: A three-pronged approach toward a sustainable chemical industry	52
Ligand-enabled stereodivergence in nickel-catalyzed regioselective hydroboration of internal allenes	52
Versatile deacylative cross-coupling of aromatic ketones	52
Photovoltaic potential of nitro-functionalized non-fullerene acceptors depends on its bonding site	52
A sustainable cobalt separation with validation by techno-economic analysis and life-cycle assessment	51
Low-pressure CO₂ insertion chemistry enables predictive kinetics for epoxide/CO2 copolymerization catalysis	51
Single-molecule spectroscopic probing of N-heterocyclic carbenes on a two-dimensional metal	51
Palladium-catalyzed asymmetric hydrophosphination of internal alkynes: Atroposelective access to phosphine-functionalized olefins	51
Bioengineering of syrbactin megasynthetases for immunoproteasome inhibitor production	51
Information transduction via fuel-controlled chemical waves	50
Ribosomal pentapeptide nitration for non-ribosomal peptide antibiotic precursor biosynthesis	50
Hydrophenazine-linked two-dimensional ladder-type crystalline fused aromatic network with high charge transport	50
Bulk depolymerization of poly(methyl methacrylate) via chain-end initiation for catalyst-free reversion to monomer	50
Tumor microenvironment-tailored nanoplatform for companion diagnostic applications of precise cancer therapy	50
Applications of molecularly imprinted polymers and perspectives for their use as food quality trackers	50
Terpenoid-based high-performance polyester with tacticity-independent crystallinity and chemical circularity	49
Phosphorus fluoride exchange: Multidimensional catalytic click chemistry from phosphorus connective hubs	49
Two (AgI3I)4L4 cages elucidate the rules for silver-cluster vertex design	49
Indocyanine polymethine fluorophores with extended π-conjugation emitting beyond 1,200 nm for enhanced NIR-II imaging	49
Tailoring dynamic hydrogels by controlling associative exchange rates	49
Engineering biotic-abiotic hybrid systems for solar-to-chemical conversion	49
Electrolyte engineering for highly inorganic solid electrolyte interphase in high-performance lithium metal batteries	49
Reaction: Navigating the promises and perils of AI-powered drug synthesis	48
Molecular design of covalent organic frameworks for seawater desalination: A state-of-the-art review	48
A single-crystalline 2D polymer network mechanically interlocked by [c2]daisy chains	48
Depositing atom by atom: Pt–Ru–Co triple-atom catalysts	48
Controlled radical depolymerization: Structural differentiation and molecular weight control	48
Zeolite-based catalysts for methane conversion: Challenges and opportunities	47
Championing systems thinking to create a circular economy of chemicals	47
Elucidating non-radiative decay in near-infrared lumiphores: Leveraging new design principles to develop a telecom band organic dye laser	47
Synthesizing a nanographyne	47
Chlorine-free synthesis of axially chiral organophosphorus compounds from white phosphorus	47
Light-controlled colloidal crystallization	47
Divergent synthesis of conidiogenones B–F and 12β-hydroxyconidiogenone C	47
Accelerating PERx reaction enables covalent nanobodies for potent neutralization of SARS-CoV-2 and variants	47
4-Pyridyl perfluoroalkyl sulfide as a practical nucleophilic perfluoroalkylation reagent	47
Visible-light-induced coupling of carboxylic acids with alcohols/amines via a phosphorous linchpin strategy	47
Porous organic polymers with heterocyclic crown ethers for selective lithium-ion capture	47
Chemistry beyond the outer shell	46
Solar-to-chemical conversion in catalytic plastic transformation	46
Biosynthesis and genetic encoding of activated nitriles for fast protein conjugation and tunable fluorogenic labeling	46
Targeted spin regulation in multi-spin systems via σ-bond rotation	45
Uncovering strong π-metal interactions on Ag and Au nanosurfaces under ambient conditions via in-situ surface-enhanced Raman spectroscopy	44
New insights and discoveries in anion receptor chemistry	44
In This Issue	43
Fluoride up- and down-regulates guest encapsulation for ZnII6L4 and ZnII4L4 cages	43
Cancer nanomedicine: Concepts, promises, and challenges	43
Iron-mediated modular decarboxylative cross-nucleophile coupling	43
Catalytic and selective chemical recycling of post-consumer rubbers into cycloalkenes	43
3D-printing technologies for C1 chemistry	43
Reversible topochemical polymerization and depolymerization of a crystalline 3D porous organic polymer with C–C bond linkages	43
Selective hydrogenation catalysis enabled by nanoscale galvanic reactions	43
Triazasupersumanenes: Bowl-shaped nanographenes with tunable properties and unexpected charge transport performance	43
The Co/NbN interphase as an effective ammonia synthesis catalyst	43
Finding sustainable solutions	43
The subtle art of radical control	43
An angstrom-level d-spacing control of graphite oxide using organofillers for high-rate lithium storage	43
Tetragonal gyroid structure from symmetry manipulation: A brand-new member of the gyroid surface family	43
The third wave of enzyme engineering: Navigating the AI-powered IDEA paradigm	42
Steering cobalt phase evolution for efficient syngas-to-light-olefin conversion	42
Communication between active sites regulates heterogeneous catalysis	42
Integrating two contrasting biosynthetic pathways for peptide natural products	42
New light on proton transfer: Spectral and kinetic signature of a transient Eigen complex	41
Reaction: The challenge of open-shell transition metal catalysis in “systems chemistry”	41
Connecting single-nucleotide polymorphisms, glycosylation status, and interactions of plasma serine protease inhibitors	41
Out-of-equilibrium confinement catalysis mediated by compressive force	41
Electrochemical 6Li isotope enrichment based on selective insertion in 1D tunnel-structured V2O5	40
Aqueous-phase organic photochemistry: Distinct modes and interfaces	40
Circumventing the activity-selectivity trade-off: Pt-Fe-Pt active sites for selective heterogeneous hydrogenation of crotonaldehyde	40
Intrinsic circularly polarized luminescence with a record-high dissymmetry factor via dynamic through-space conjugation	40
Versatile selective-absorber-based photothermocatalytic reactor for solar fuel synthesis	40
High-entropy materials toward next-generation energy conversion and storage systems	39
Photoinduced, ground-state charge-transfer complex	39
A metal-ion-linked self-assembled molecular layer as a robust hole-selective contact for perovskite solar cells	39
The sustainability potential of single-atom catalysts in chemical process	39
Cluster-enabled control of single-electron photoredox catalysis in reticular frameworks	39
Self-activated energy release cascade from anthracene-based solid-state molecular solar thermal energy storage systems	39
Out-of-equilibrium chemical logic systems: Light- and sound-controlled programmable spatiotemporal patterns and mechanical functions	38
Chiral inorganic nanomaterials for biomedical applications	38
Osmium atomic sites on CuS nanoplates for efficient two-electron oxygen reduction into H2O2	38
Programmable reconfiguration of one-dimensional supramolecular polymers into multidimensional topological nanostructures	38