Chem

Article	Citations
Out-of-equilibrium chemical logic systems	822
In this issue	434
Variable nanosheets for highly efficient oxygen evolution reaction	417
From trash to treasure: Vanadium-catalyzed upcycling of non-biodegradable plastics	388
Transitioning aliphatic C–H functionalization from bench to plant: Is decatungstate photocatalysis ready for the leap yet?	374
Nanocellulose: New horizons in organic chemistry and beyond	341
A Star of David [2]catenane of single handedness	329
Catalysis, replication, and non-equilibrium behavior: Key determinants for life-like complexity realized using short peptides	298
Reaction: Harnessing reactive oxygen species (ROS) for water purification	252
Multi-omics profiling of a self-assembling bioactive hydrogel for immunomodulation and myogenesis in volumetric muscle loss	225
Quasicrystal approximants in isoreticular metal-organic frameworks via Cairo pentagonal tiling	212
Harnessing plastic depolymerization products to upcycle mixed waste into high-value chemicals	208
B(C6F5)3-catalyzed selective C–H chalcogenation of arenes and heteroarenes	206
Nature-inspired synthetic oligourea foldamer channels allow water transport with high salt rejection	193
Photoswitches and photochemical reactions for optically controlled phase transition and energy storage	187
ElectroChemputer with integrated monitoring for programmable electrochemistry	181
Excited-state protonation and reduction enable the umpolung Birch reduction of naphthalenes	181
An M60L60 metal-peptide capsid with a 60-crossing woven network	163
Selective recognition of quaternary ammonium cations	161
Air-stable radical polycyclic aromatic hydrogen-bonded organic frameworks	159
Click chemistry in polymer science	153
Ion-dipole-interaction-manipulated bilateral interface chemistry for deep rechargeability and high redox activity of Zn-organic batteries	151
Experimentally modeling the emergence of prebiotically plausible phospholipid vesicles	151
N-Heterocyclic carbene-derived second-period main-group radicals: Synthesis, fundamentals, and applications	148
Programming extracellular protein fate with peptide chimeras	147

2D covalent organic framework via catenation	147
Highly selective and efficient uranium recovery by size-sieving porous aromatic frameworks with rigidly functionalized windows	144
Spatially resolved cell tagging and surfaceome labeling via targeted photocatalytic decaging	142
A high-throughput workflow to analyze sequence-conformation relationships and explore hydrophobic patterning in disordered peptoids	142
Recent research progress of all-polymer solar cells based on PSMA-type polymer acceptors	139
Probing enantioinduction in confined chiral spaces through asymmetric oxime reductions	134
2D conjugated metal-organic framework as a proton-electron dual conductor	134
Ionic surface propensity controls pH in nanopores	133
In This Issue	133
Switchable diversification of quaternary ammonium salts using photocatalysis	131
Oxygen reduction active-site regulation enables reverse photocurrent in photoelectrochemical sensing	128
Atom swap in triple bonds via nitrogen-deletion coupling with gem-diborylalkanes	128
Phosphine oxide additives for perovskite light-emitting diodes and solar cells	127
The beauty of low symmetry: Non-statistical assembly of [Pd2(LA)(LB)(LC)(LD)]4+ cages	127
Catalytic strategies for upvaluing plastic wastes	126
Redox-couple-assisted CO2 capture on solid-electrolyte reactor	125
Be your own star	123
Swapping benches from chemistry PhD student to science advisor at law firm	122
Molecular freaky Friday: Polarity reversal and resorcin[4]arenes as chloride receptors	121
In this issue	120
Iridium-mediated methane dehydrogenation and methylidene (=CH2) transfer	118
para-Selective C–H alkylation of aroyl chlorides through organic photoredox-catalyzed radical tele-substitution	118
Solvent-mediated electrochemical acetylene semihydrogenation for continuous production of polymer-grade ethylene	116
Time-resolved fluorescence imaging with color-changing, “turn-on/turn-on” AIE nanoparticles	114
Improving productivity and stability for CO2 hydrogenation by using pincer-ligated Mn complexes with hemilabile ligands	114
Two-in-one metallaphotoredox cross-couplings enabled by a photoactive ligand	112
Reaction: Don’t hate the player in chemical AI; hate the game	111
An effective strategy to boost lattice-oxygen-mediated acidic oxygen evolution	108
Design of piezoelectric organic cage salts for energy harvesting	106
Transition metal-free difunctionalization of unactivated alkenes: Arylation/azidation, arylation/chlorination, and arylation/cyanation	106
Semiconducting ladder-type covalent organic frameworks	105
Curved plane increases the d vacancy population of Pd for green production of cyclohexanone	103
Supramolecular boosted superexchange	103
In this issue	103
Battery detectives: Uncovering cathode impact on anode-free Li cell performance by operando NMR	103
Cation-exchange-upgraded nanostructures for photocatalysts	101
A radical–polar crossover approach to complex nitrogen heterocycles via the triplet state	101
Modular nucleic acid scaffolds for synthesizing monodisperse and sequence-encoded antibody oligomers	99
Observation of ultrafast electrons in pendant-embedded conducting two-dimensional polymers	98
Stereodivergent asymmetric hydrogenation of quinoxalines	96
Strong halide anion binding within the cavity of a conformation-adaptive phenazine-based Pd2L4 cage	96
Molecule-resolvable SERSome for metabolic profiling	95
From G-protein-coupled receptors to solute carriers—mass spectrometry informs dynamics, function, and regulation	93
Photo-assembling cyclic peptides for dynamic light-driven peptide nanotubes	91
Bioinspired chemical design to control interfacial wet adhesion	90
Structure-performance relationships for catalysis-driven molecular machinery	89
Breaking ampere-level current density limitations in multi-carbon products through crystal facet engineering	88
Highly oxygenated organic molecules with high unsaturation formed upon photochemical aging of soot	88
General and selective metal-free radical α-C–H borylation of aliphatic amines	87
A light-driven chloride anion transporter	87

Ice quenching for sustained nucleate boiling at large superheats	86
A dynamic charge-dependent nanofungicide platform for sustainable agrochemical deposition and delivery	85
Designing generative dissipative networks for programming complex temporal dynamics and functions	84
Development of tumor-evolution-targeted anticancer therapeutic nanomedicineEVT	84
The key of Zn2+ transfer kinetics in zinc metal batteries	82
The role of concentration waves in synthesizing hollow multi-shelled structures	82
From “heavy” water to “heavy” boron clusters	81
Metal-free photocatalyzed cyanation enables access to carbon-11-radiolabeled aryl nitriles	81
Revisiting the impacts of silica nanoparticles on endothelial cell junctions and tumor metastasis	81
Unexpected diastereoselective chemistry on a 2D protein surface	80
Direct enantioselective α-amination of amides guided by DFT prediction of E/Z selectivity in a sulfonium intermediate	79
Challenges and perspectives for the perovskite module research	79
Colorless zinc colored by metal-metal orbital interaction	78
Selective palladium recovery by a highly porous polyisothiocyanurate	78
Enzymatic DNA orthogonal chemistry for multi-cancer diagnosis	78
Potent antimicrobial effect induced by disruption of chloride homeostasis	78
Antigen spatial-matching polyaptamer nanostructure to block coronavirus infection and alleviate inflammation	77
The 40th anniversary of covalent dendrimers	77
Deprotection of benzyl-derived groups via photochemically mesolytic cleavage of C–N and C–O bonds	77
Emerging trends in CO carbonylation	75
Pilot-scale reductive catalytic depolymerization of lignin: Challenges and guidelines	74
The mechanical bond in biological systems	74
Molecule additive design for perovskite light-emitting diodes operated at high current densities	73
Industrial PhD: My way to go?	72
A clever trilayer assembly strategy for 2D materials	71
Omics approach for electrolytes discovery	70
Reaction: Circular chemical imaginaries	70
Bioorthogonal reactions and AIEgen-based metabolically engineered theranostic systems	69
Cross-assembly confined bifunctional catalysis via non-covalent interactions for asymmetric halogenation	69
Ultralong ionic chains with lengths over 10 μm: A control of ionic molecular engineering	68
Microporous B←N framework: A stable and efficient material for separating C2H2 and CO2	68
A novel type of radical-addition-induced β-fragmentation and ensuing remote functionalization	68
Cold-resilient zinc batteries with organic-free solvation structures	68
Transformable quadruply interpenetrated cage with multiple states of different reactivities	66
Aqueous electrocatalytic small-molecule valorization trilogy	66
Frontier research in perovskite solar cells: Following the paths of European research and innovation	66
Elucidating the role of cathode identity: Voltage-dependent reversibility of anode-free batteries	66
Controlling dynamic reconstruction chemistry for superior oxygen-evolving catalysts	65
Rational structure transformation triggered by titanium modulation in metal-organic frameworks for efficient flue gas utilization	65
Regulating the topology and pore size of covalent metal-organic framework for boosting catalytic CO2 conversion	65
Water-centric framework for confinement catalysis: Beyond nanomaterials	65
Light-intensity-dependent out-of-equilibrium processes toward dimensionally distinct nanopolymorphs	65
One step further to efficient Li-mediated ammonia synthesis in flow cells	64
A B←N framework based on 1D dative B←N polymers for exclusive recognition and separation of benzene from its azeotrope	63
Remote optical chirality transfer via helical polyaromatic capsules upon encapsulation	63
Deciphering reactive intermediates in electrooxidative coupling of indoles through real-time mass spectrometry	63
Metal-organic frameworks for water vapor adsorption	63
Oxygen-tolerant photocatalytic conversion of simulated flue gas to ethylene	63
Amorphous materials emerging as prospective electrodes for electrochemical energy storage and conversion	63
Unlocking the synthesis of homochiral carborane-fused boraphenanthrenes	62
The Cation Shuffle: Interplay of silylium, carbenium, and arenium ions in superelectrophile catalysis	62
Hydrogen-bonded organic frameworks: Chemistry and functions	62
Divergent scaffold redesign of ecteinascidin 743 as a gateway to anticancer macrocycles	62
Programmable in vitro and in vivo folding of single-stranded nucleic-acid wireframe origami	62
Downsizing lactams via Rh-catalyzed C–C activation	61
Directional long-distance signal transmission on two-dimensional DNA origami assemblies	60
Long-wavelength photocatalysis enabled by an in-situ-assembled manganese platform	60
Sculpting photoproducts with DNA origami	60
Activating a light-driven molecular motor by metal complexation	60
Synergizing palladium with Lewis base catalysis for stereodivergent coupling of 1,3-dienes with pentafluorophenyl acetates	60
Dynamic mechanoresponsive polymers enabled by ring-opening polymerization of cyclic propargyl carbonates	60
Microenvironment engineering of non-noble metal alloy for selective propane dehydrogenation	60
Rewriting lysine reactivity: Lysine-targeted bioconjugation via biomimetic polarity reversal for diversified biomolecule modification	59
Innovative low-carbon technology for a sustainable electrolyte industry	59
Multiply entangled receptors for high-affinity anion recognition in water	59
Water, metal ions, and me: A chemist’s tale of serendipity and discovery	59
Rational design and synthesis of two-dimensional conjugated metal-organic polymers for electrocatalysis applications	59
DNA-mediated force transmission for precise and efficient mechanochemical activation	59
In this issue	58
Isoreactivity in chemistry	58
Supramolecular interactions enable pseudo-nanophase separation for constructing an ion-transport highway	58
Dispersion-driven formation of chiral twisted PAH double helices	58
Modular synthesis of fluoroalkyl-substituted cyclopropenes with fluoroalkylacylsilanes as carbynyl cation equivalents	58
Self-sorting as a versatile strategy in the synthesis of rotaxanes and catenanes	57
Genetically enabling phosphorus fluoride exchange click chemistry in proteins	57
Metal-organic frameworks for fast electrochemical energy storage: Mechanisms and opportunities	57
Confinement-induced chiroptical photoswitching —An encapsulation approach for advanced photochemical functions	57
Self-assembly of 10-nm-sized pentagonal dodecahedra through heteroleptic complexation coupled with orientational self-sorting	57
Self-adjusted aromatic cation-π binding promotes controlled self-assembly of positively charged π-electronic molecules	57
Challenges for photocatalytic overall water splitting	56

In this issue	56
Biocatalytic activation of diazirines for carbene-transfer reactions	56
DNA membrane nanopores with highly tunable shapes and sizes	55
Rethinking catalyst design by using data science	55
The cyclotriborate trianion	55
Electrophilic selenium drives electron leakage	54
A sustainable cobalt separation with validation by techno-economic analysis and life-cycle assessment	54
Dicobalt-catalyzed N=N coupling reactions of tertiary alkyl azides to form azoalkanes	54
Hydrophenazine-linked two-dimensional ladder-type crystalline fused aromatic network with high charge transport	53
Role of delocalized electrons on the doping effect in vanadia	53
In my blue-light era	53
Boosting single-molecule magnet performance	53
Information transduction via fuel-controlled chemical waves	53
Palladium-catalyzed asymmetric hydrophosphination of internal alkynes: Atroposelective access to phosphine-functionalized olefins	52
Versatile deacylative cross-coupling of aromatic ketones	52
Indocyanine polymethine fluorophores with extended π-conjugation emitting beyond 1,200 nm for enhanced NIR-II imaging	52
Tailoring dynamic hydrogels by controlling associative exchange rates	52
Single-molecule spectroscopic probing of N-heterocyclic carbenes on a two-dimensional metal	52
Bioengineering of syrbactin megasynthetases for immunoproteasome inhibitor production	51
Molecular design of covalent organic frameworks for seawater desalination: A state-of-the-art review	51
Interplay between remote single-atom active sites triggers speedy catalytic oxidation	51
Ribosomal pentapeptide nitration for non-ribosomal peptide antibiotic precursor biosynthesis	51
Applications of molecularly imprinted polymers and perspectives for their use as food quality trackers	51
Bulk depolymerization of poly(methyl methacrylate) via chain-end initiation for catalyst-free reversion to monomer	50
A critical assessment of fluorescent probes as cellular reporters for thioredoxin system enzyme activities	50
Terpenoid-based high-performance polyester with tacticity-independent crystallinity and chemical circularity	50
Two (AgI3I)4L4 cages elucidate the rules for silver-cluster vertex design	50
Photovoltaic potential of nitro-functionalized non-fullerene acceptors depends on its bonding site	49
Does in-situ-generated H2O2 promote important industrial reactions?	49
Reaction: A three-pronged approach toward a sustainable chemical industry	49
Supramolecular self-assembly of dinuclear alkynylplatinum(II) complexes into highly ordered crystalline hexagonal bipyramid superstructures	49
Engineering biotic-abiotic hybrid systems for solar-to-chemical conversion	49
Phosphorus fluoride exchange: Multidimensional catalytic click chemistry from phosphorus connective hubs	48
Ligand-enabled stereodivergence in nickel-catalyzed regioselective hydroboration of internal allenes	48
Reaction: Navigating the promises and perils of AI-powered drug synthesis	48
Electrolyte engineering for highly inorganic solid electrolyte interphase in high-performance lithium metal batteries	48
Depositing atom by atom: Pt–Ru–Co triple-atom catalysts	48
Controlled radical depolymerization: Structural differentiation and molecular weight control	48
Tumor microenvironment-tailored nanoplatform for companion diagnostic applications of precise cancer therapy	48
A single-crystalline 2D polymer network mechanically interlocked by [c2]daisy chains	48
Triazasupersumanenes: Bowl-shaped nanographenes with tunable properties and unexpected charge transport performance	47
Uncovering strong π-metal interactions on Ag and Au nanosurfaces under ambient conditions via in-situ surface-enhanced Raman spectroscopy	47
Visible-light-induced coupling of carboxylic acids with alcohols/amines via a phosphorous linchpin strategy	47
Cancer nanomedicine: Concepts, promises, and challenges	47
Iron-mediated modular decarboxylative cross-nucleophile coupling	47
4-Pyridyl perfluoroalkyl sulfide as a practical nucleophilic perfluoroalkylation reagent	47
Tetragonal gyroid structure from symmetry manipulation: A brand-new member of the gyroid surface family	47
New insights and discoveries in anion receptor chemistry	47
Elucidating non-radiative decay in near-infrared lumiphores: Leveraging new design principles to develop a telecom band organic dye laser	46
Biosynthesis and genetic encoding of activated nitriles for fast protein conjugation and tunable fluorogenic labeling	46
Light-controlled colloidal crystallization	46
Divergent synthesis of conidiogenones B–F and 12β-hydroxyconidiogenone C	46
Synthesizing a nanographyne	46
Championing systems thinking to create a circular economy of chemicals	46
Selective hydrogenation catalysis enabled by nanoscale galvanic reactions	46
Catalytic and selective chemical recycling of post-consumer rubbers into cycloalkenes	46
Porous organic polymers with heterocyclic crown ethers for selective lithium-ion capture	46
Chlorine-free synthesis of axially chiral organophosphorus compounds from white phosphorus	46
Targeted spin regulation in multi-spin systems via σ-bond rotation	46
Zeolite-based catalysts for methane conversion: Challenges and opportunities	45
Accelerating PERx reaction enables covalent nanobodies for potent neutralization of SARS-CoV-2 and variants	45
Solar-to-chemical conversion in catalytic plastic transformation	45
Nanocomposite DNA hydrogels emerging as programmable and bioinstructive materials systems	45
An angstrom-level d-spacing control of graphite oxide using organofillers for high-rate lithium storage	45
Photoinduced, ground-state charge-transfer complex	44
Finding sustainable solutions	44
The Co/NbN interphase as an effective ammonia synthesis catalyst	44
Reversible topochemical polymerization and depolymerization of a crystalline 3D porous organic polymer with C–C bond linkages	44
Reaction: The challenge of open-shell transition metal catalysis in “systems chemistry”	43
Fluoride up- and down-regulates guest encapsulation for ZnII6L4 and ZnII4L4 cages	43
Out-of-equilibrium chemical logic systems: Light- and sound-controlled programmable spatiotemporal patterns and mechanical functions	43
The sustainability potential of single-atom catalysts in chemical process	43
Selection of assembly complexity in a space of tetrapeptides	42
Integrating two contrasting biosynthetic pathways for peptide natural products	42
The subtle art of radical control	41
Inverse doping IrOx/Ti with weakened Ir-O interaction toward stable and efficient acidic oxygen evolution	41
Self-activated energy release cascade from anthracene-based solid-state molecular solar thermal energy storage systems	41
In This Issue	41
Versatile selective-absorber-based photothermocatalytic reactor for solar fuel synthesis	41
p-p orbital hybridization enables durable aqueous zinc-iodine batteries	41
Circumventing the activity-selectivity trade-off: Pt-Fe-Pt active sites for selective heterogeneous hydrogenation of crotonaldehyde	41
3D-printing technologies for C1 chemistry	41
Intrinsic circularly polarized luminescence with a record-high dissymmetry factor via dynamic through-space conjugation	41
Osmium atomic sites on CuS nanoplates for efficient two-electron oxygen reduction into H2O2	40
Construction of chiral nitrogen stereocenters via enantioselective C–H activation	40
BINOLates as potent reducing photocatalysts for inert-bond activation and reduction of unsaturated systems	40
Dynamic active sites behind Cu-based electrocatalysts: Original or restructuring-induced catalytic activity	40
Out-of-equilibrium confinement catalysis mediated by compressive force	39
Acceleration of reverse intersystem crossing in multi-resonance TADF emitter	39
Programmable reconfiguration of one-dimensional supramolecular polymers into multidimensional topological nanostructures	39
Quantitative and qualitative analysis of nitrogen species in carbon at the ppm level	39
Connecting single-nucleotide polymorphisms, glycosylation status, and interactions of plasma serine protease inhibitors	39
A metal-ion-linked self-assembled molecular layer as a robust hole-selective contact for perovskite solar cells	39
Mechanochemistry: Looking back and ahead	39
The third wave of enzyme engineering: Navigating the AI-powered IDEA paradigm	38