Chem

Article	Citations
In This Issue	716
Out-of-equilibrium chemical logic systems	414
From trash to treasure: Vanadium-catalyzed upcycling of non-biodegradable plastics	355
N-Heterocyclic carbene-derived second-period main-group radicals: Synthesis, fundamentals, and applications	337
Air-stable radical polycyclic aromatic hydrogen-bonded organic frameworks	315
Reaction: Harnessing reactive oxygen species (ROS) for water purification	260
Multi-omics profiling of a self-assembling bioactive hydrogel for immunomodulation and myogenesis in volumetric muscle loss	237
B(C6F5)3-catalyzed selective C–H chalcogenation of arenes and heteroarenes	236
Variable nanosheets for highly efficient oxygen evolution reaction	227
Experimentally modeling the emergence of prebiotically plausible phospholipid vesicles	223
2D covalent organic framework via catenation	215
Quasicrystal approximants in isoreticular metal-organic frameworks via Cairo pentagonal tiling	210
Click chemistry in polymer science	202
Harnessing plastic depolymerization products to upcycle mixed waste into high-value chemicals	198
A high-throughput workflow to analyze sequence-conformation relationships and explore hydrophobic patterning in disordered peptoids	195
In this issue	185
Probing enantioinduction in confined chiral spaces through asymmetric oxime reductions	177
Spatially resolved cell tagging and surfaceome labeling via targeted photocatalytic decaging	167
Nanocellulose: New horizons in organic chemistry and beyond	165
A Star of David [2]catenane of single handedness	165
Excited-state protonation and reduction enable the umpolung Birch reduction of naphthalenes	164
An M60L60 metal-peptide capsid with a 60-crossing woven network	160
Photoswitches and photochemical reactions for optically controlled phase transition and energy storage	156
Ion-dipole-interaction-manipulated bilateral interface chemistry for deep rechargeability and high redox activity of Zn-organic batteries	153
Lanthanide luminescence from supramolecular hydrogels consisting of bio-conjugated picolinic-acid-based guanosine quadruplexes	151

Nature-inspired synthetic oligourea foldamer channels allow water transport with high salt rejection	147
Recent research progress of all-polymer solar cells based on PSMA-type polymer acceptors	142
2D conjugated metal-organic framework as a proton-electron dual conductor	140
Swapping benches from chemistry PhD student to science advisor at law firm	137
Be your own star	135
Supramolecular boosted superexchange	135
From G-protein-coupled receptors to solute carriers—mass spectrometry informs dynamics, function, and regulation	131
In this issue	130
Reaction: Don’t hate the player in chemical AI; hate the game	130
Curved plane increases the d vacancy population of Pd for green production of cyclohexanone	129
In This Issue	128
Molecular freaky Friday: Polarity reversal and resorcin[4]arenes as chloride receptors	122
In this issue	122
para-Selective C–H alkylation of aroyl chlorides through organic photoredox-catalyzed radical tele-substitution	121
Ionic surface propensity controls pH in nanopores	120
Catalytic strategies for upvaluing plastic wastes	120
Two-in-one metallaphotoredox cross-couplings enabled by a photoactive ligand	119
Higher-order cycloadditions in the age of catalysis	118
An effective strategy to boost lattice-oxygen-mediated acidic oxygen evolution	117
Highly oxygenated organic molecules with high unsaturation formed upon photochemical aging of soot	117
Structure-performance relationships for catalysis-driven molecular machinery	117
The beauty of low symmetry: Non-statistical assembly of [Pd2(LA)(LB)(LC)(LD)]4+ cages	116
Switchable diversification of quaternary ammonium salts using photocatalysis	114
Observation of ultrafast electrons in pendant-embedded conducting two-dimensional polymers	113
Redox-couple-assisted CO2 capture on solid-electrolyte reactor	112
Molecular design strategy for realizing vectorial electron transfer in photoelectrodes	112
Atom swap in triple bonds via nitrogen-deletion coupling with gem-diborylalkanes	112
Stereodivergent asymmetric hydrogenation of quinoxalines	112
Transition metal-free difunctionalization of unactivated alkenes: Arylation/azidation, arylation/chlorination, and arylation/cyanation	112
Modular nucleic acid scaffolds for synthesizing monodisperse and sequence-encoded antibody oligomers	111
Phosphine oxide additives for perovskite light-emitting diodes and solar cells	109
Strong halide anion binding within the cavity of a conformation-adaptive phenazine-based Pd2L4 cage	108
Design of piezoelectric organic cage salts for energy harvesting	104
Battery detectives: Uncovering cathode impact on anode-free Li cell performance by operando NMR	101
Time-resolved fluorescence imaging with color-changing, “turn-on/turn-on” AIE nanoparticles	98
General and selective metal-free radical α-C–H borylation of aliphatic amines	98
Photo-assembling cyclic peptides for dynamic light-driven peptide nanotubes	98
Semiconducting ladder-type covalent organic frameworks	97
Cation-exchange-upgraded nanostructures for photocatalysts	97
Molecule-resolvable SERSome for metabolic profiling	96
Bioinspired chemical design to control interfacial wet adhesion	95
The role of concentration waves in synthesizing hollow multi-shelled structures	94
Colorless zinc colored by metal-metal orbital interaction	94
Selective palladium recovery by a highly porous polyisothiocyanurate	93
Enzymatic DNA orthogonal chemistry for multi-cancer diagnosis	93
Designing generative dissipative networks for programming complex temporal dynamics and functions	92
Chemical probes of redox enzymes by rational, reactivity-based design	91
Antigen spatial-matching polyaptamer nanostructure to block coronavirus infection and alleviate inflammation	90
A light-driven chloride anion transporter	89
Metal-free photocatalyzed cyanation enables access to carbon-11-radiolabeled aryl nitriles	87

The key of Zn2+ transfer kinetics in zinc metal batteries	87
Unexpected diastereoselective chemistry on a 2D protein surface	85
Catalyst: A step forward for PVC manufacture from natural gas	84
Challenges and perspectives for the perovskite module research	82
Revisiting the impacts of silica nanoparticles on endothelial cell junctions and tumor metastasis	82
The mechanical bond in biological systems	81
Programmable spatial organization of liquid-phase condensations	80
Ice quenching for sustained nucleate boiling at large superheats	80
Pilot-scale reductive catalytic depolymerization of lignin: Challenges and guidelines	80
Upcycling waste PET and CO2 to useful chemicals: Multi-functional catalysis at its best	78
Emerging trends in CO carbonylation	78
Potent antimicrobial effect induced by disruption of chloride homeostasis	78
Regulating liquid and solid-state electrolytes for solid-phase conversion in Li–S batteries	77
Forging C−heteroatom bonds by transition-metal-catalyzed enantioselective C–H functionalization	76
Direct enantioselective α-amination of amides guided by DFT prediction of E/Z selectivity in a sulfonium intermediate	75
Halogen-halogen bonds enable improved long-term operational stability of mixed-halide perovskite photovoltaics	75
Deprotection of benzyl-derived groups via photochemically mesolytic cleavage of C–N and C–O bonds	75
Development of tumor-evolution-targeted anticancer therapeutic nanomedicineEVT	75
Finding your voice in a diverse audience: Lessons in writing and advocacy	74
A clever trilayer assembly strategy for 2D materials	74
Industrial PhD: My way to go?	74
Molecule additive design for perovskite light-emitting diodes operated at high current densities	73
Cross-assembly confined bifunctional catalysis via non-covalent interactions for asymmetric halogenation	72
Transformable quadruply interpenetrated cage with multiple states of different reactivities	72
Ultralong ionic chains with lengths over 10 μm: A control of ionic molecular engineering	72
Frontier research in perovskite solar cells: Following the paths of European research and innovation	72
A novel type of radical-addition-induced β-fragmentation and ensuing remote functionalization	72
Microporous B←N framework: A stable and efficient material for separating C2H2 and CO2	71
Reaction: Circular chemical imaginaries	71
Cold-resilient zinc batteries with organic-free solvation structures	71
Omics approach for electrolytes discovery	70
High-resolution transmission electron microscopy of beam-sensitive halide perovskites	70
Bioorthogonal reactions and AIEgen-based metabolically engineered theranostic systems	70
Programmable in vitro and in vivo folding of single-stranded nucleic-acid wireframe origami	70
Remote optical chirality transfer via helical polyaromatic capsules upon encapsulation	69
Metal-organic frameworks for water vapor adsorption	68
Deciphering reactive intermediates in electrooxidative coupling of indoles through real-time mass spectrometry	68
Rationalizing the design and implementation of chiral hybrid perovskites	68
Rational structure transformation triggered by titanium modulation in metal-organic frameworks for efficient flue gas utilization	68
Aqueous electrocatalytic small-molecule valorization trilogy	68
Elucidating the role of cathode identity: Voltage-dependent reversibility of anode-free batteries	67
Amorphous materials emerging as prospective electrodes for electrochemical energy storage and conversion	67
A B←N framework based on 1D dative B←N polymers for exclusive recognition and separation of benzene from its azeotrope	67
In this issue	66
Rewriting lysine reactivity: Lysine-targeted bioconjugation via biomimetic polarity reversal for diversified biomolecule modification	66
Hydrogen-bonded organic frameworks: Chemistry and functions	66
Controlling dynamic reconstruction chemistry for superior oxygen-evolving catalysts	66
Conceptually novel diarylation for sustainable synthesis	66
Oxygen-tolerant photocatalytic conversion of simulated flue gas to ethylene	66
Innovative low-carbon technology for a sustainable electrolyte industry	66
Downsizing lactams via Rh-catalyzed C–C activation	65
Activating a light-driven molecular motor by metal complexation	64
In this issue	64
Pursuing electrically pumped lasing with organic semiconductors	63
Correlations between precipitation reactions and electrochemical performance of lithium-sulfur batteries probed by operando scattering techniques	63
Microenvironment engineering of non-noble metal alloy for selective propane dehydrogenation	62
Rational design and synthesis of two-dimensional conjugated metal-organic polymers for electrocatalysis applications	62
Supramolecular interactions enable pseudo-nanophase separation for constructing an ion-transport highway	62
Sculpting photoproducts with DNA origami	61
Water, metal ions, and me: A chemist’s tale of serendipity and discovery	60
Self-adjusted aromatic cation-π binding promotes controlled self-assembly of positively charged π-electronic molecules	60
Self-assembly of 10-nm-sized pentagonal dodecahedra through heteroleptic complexation coupled with orientational self-sorting	60
Metal-organic frameworks for fast electrochemical energy storage: Mechanisms and opportunities	60
Dynamic mechanoresponsive polymers enabled by ring-opening polymerization of cyclic propargyl carbonates	60
Genetically enabling phosphorus fluoride exchange click chemistry in proteins	60
Unlocking the synthesis of homochiral carborane-fused boraphenanthrenes	59
Divergent scaffold redesign of ecteinascidin 743 as a gateway to anticancer macrocycles	58
Dispersion-driven formation of chiral twisted PAH double helices	58
Modular synthesis of fluoroalkyl-substituted cyclopropenes with fluoroalkylacylsilanes as carbynyl cation equivalents	58
Challenges for photocatalytic overall water splitting	57
Synergizing palladium with Lewis base catalysis for stereodivergent coupling of 1,3-dienes with pentafluorophenyl acetates	57
Phenanthrenequinone-like moiety functionalized carbon for electrocatalytic acidic oxygen evolution	57
The road to industrialization of fine chemical carboxylation reactions	56
Selective cellular probes for mammalian thioredoxin reductase TrxR1: Rational design of RX1, a modular 1,2-thiaselenane redox probe	56
Self-sorting as a versatile strategy in the synthesis of rotaxanes and catenanes	56
In my blue-light era	55
Bulk depolymerization of poly(methyl methacrylate) via chain-end initiation for catalyst-free reversion to monomer	55
Rethinking catalyst design by using data science	55
Operando scattering techniques for detecting precipitation reactions in lithium-sulfur batteries	55
In this issue	55

The cyclotriborate trianion	55
Reaction: A three-pronged approach toward a sustainable chemical industry	55
Molecular design of covalent organic frameworks for seawater desalination: A state-of-the-art review	54
A 10-nm-sized multicompartment cuboctahedron and its 2D hierarchical arrays observed by cryo-EM	54
Van der Waals organic/inorganic heterostructures in the two-dimensional limit	54
Ribosomal pentapeptide nitration for non-ribosomal peptide antibiotic precursor biosynthesis	53
Phosphorus fluoride exchange: Multidimensional catalytic click chemistry from phosphorus connective hubs	53
Bioengineering of syrbactin megasynthetases for immunoproteasome inhibitor production	53
Supramolecular repair of hydration lubrication surfaces	52
Tailoring dynamic hydrogels by controlling associative exchange rates	52
Remotely controllable supramolecular rotor mounted inside a porphyrinic cage	51
Electrophilic selenium drives electron leakage	51
Photovoltaic potential of nitro-functionalized non-fullerene acceptors depends on its bonding site	51
Role of delocalized electrons on the doping effect in vanadia	51
Does in-situ-generated H2O2 promote important industrial reactions?	51
DNA membrane nanopores with highly tunable shapes and sizes	50
Information transduction via fuel-controlled chemical waves	50
Terpenoid-based high-performance polyester with tacticity-independent crystallinity and chemical circularity	50
Two (AgI3I)4L4 cages elucidate the rules for silver-cluster vertex design	50
Dicobalt-catalyzed N=N coupling reactions of tertiary alkyl azides to form azoalkanes	50
Boosting single-molecule magnet performance	50
Surface and interface control of black phosphorus	49
Single-molecule spectroscopic probing of N-heterocyclic carbenes on a two-dimensional metal	49
Indocyanine polymethine fluorophores with extended π-conjugation emitting beyond 1,200 nm for enhanced NIR-II imaging	49
Palladium-catalyzed asymmetric hydrophosphination of internal alkynes: Atroposelective access to phosphine-functionalized olefins	49
Biocatalytic activation of diazirines for carbene-transfer reactions	48
Versatile deacylative cross-coupling of aromatic ketones	48
A sustainable cobalt separation with validation by techno-economic analysis and life-cycle assessment	48
Ligand-enabled stereodivergence in nickel-catalyzed regioselective hydroboration of internal allenes	48
Interplay between remote single-atom active sites triggers speedy catalytic oxidation	48
Hydrophenazine-linked two-dimensional ladder-type crystalline fused aromatic network with high charge transport	48
Engineering biotic-abiotic hybrid systems for solar-to-chemical conversion	48
Zero-valent species of group 13–15 elements	48
Championing systems thinking to create a circular economy of chemicals	47
Tumor microenvironment-tailored nanoplatform for companion diagnostic applications of precise cancer therapy	47
Chlorine-free synthesis of axially chiral organophosphorus compounds from white phosphorus	47
Controlled radical depolymerization: Structural differentiation and molecular weight control	47
Supramolecular self-assembly of dinuclear alkynylplatinum(II) complexes into highly ordered crystalline hexagonal bipyramid superstructures	47
Electrolyte engineering for highly inorganic solid electrolyte interphase in high-performance lithium metal batteries	47
Visible-light-induced coupling of carboxylic acids with alcohols/amines via a phosphorous linchpin strategy	47
Applications of molecularly imprinted polymers and perspectives for their use as food quality trackers	47
4-Pyridyl perfluoroalkyl sulfide as a practical nucleophilic perfluoroalkylation reagent	46
Synthesizing a nanographyne	46
Elucidating non-radiative decay in near-infrared lumiphores: Leveraging new design principles to develop a telecom band organic dye laser	46
Depositing atom by atom: Pt–Ru–Co triple-atom catalysts	46
A single-crystalline 2D polymer network mechanically interlocked by [c2]daisy chains	46
Cancer nanomedicine: Concepts, promises, and challenges	46
Reaction: Navigating the promises and perils of AI-powered drug synthesis	46
Triazasupersumanenes: Bowl-shaped nanographenes with tunable properties and unexpected charge transport performance	45
An angstrom-level d-spacing control of graphite oxide using organofillers for high-rate lithium storage	45
Mucin-mimetic glycan arrays integrating machine learning for analyzing receptor pattern recognition by influenza A viruses	45
Divergent synthesis of conidiogenones B–F and 12β-hydroxyconidiogenone C	45
Selective hydrogenation catalysis enabled by nanoscale galvanic reactions	45
Porous organic polymers with heterocyclic crown ethers for selective lithium-ion capture	45
Accelerating PERx reaction enables covalent nanobodies for potent neutralization of SARS-CoV-2 and variants	45
Nanocomposite DNA hydrogels emerging as programmable and bioinstructive materials systems	45
The Co/NbN interphase as an effective ammonia synthesis catalyst	45
Perovskite intermediate phases fundamentally address the urgent stability issue	45
Biosynthesis and genetic encoding of activated nitriles for fast protein conjugation and tunable fluorogenic labeling	45
Catalytic and selective chemical recycling of post-consumer rubbers into cycloalkenes	44
Iron-mediated modular decarboxylative cross-nucleophile coupling	44
Tetragonal gyroid structure from symmetry manipulation: A brand-new member of the gyroid surface family	44
Non-covalent interactions of graphene surface: Mechanisms and applications	44
Uncovering strong π-metal interactions on Ag and Au nanosurfaces under ambient conditions via in-situ surface-enhanced Raman spectroscopy	44
Communication between active sites regulates heterogeneous catalysis	43
Solar-to-chemical conversion in catalytic plastic transformation	43
New light on proton transfer: Spectral and kinetic signature of a transient Eigen complex	43
The sustainability potential of single-atom catalysts in chemical process	43
The subtle art of radical control	43
New insights and discoveries in anion receptor chemistry	43
Circumventing the activity-selectivity trade-off: Pt-Fe-Pt active sites for selective heterogeneous hydrogenation of crotonaldehyde	42
Versatile selective-absorber-based photothermocatalytic reactor for solar fuel synthesis	42
Selection of assembly complexity in a space of tetrapeptides	42
In This Issue	42
Finding sustainable solutions	42
Reversible topochemical polymerization and depolymerization of a crystalline 3D porous organic polymer with C–C bond linkages	41
Inverse doping IrOx/Ti with weakened Ir-O interaction toward stable and efficient acidic oxygen evolution	41
Fluoride up- and down-regulates guest encapsulation for ZnII6L4 and ZnII4L4 cages	41
3D-printing technologies for C1 chemistry	41
Interfacial water regulation for water-participating electrocatalytic hydrogenation reactions	41
Connecting single-nucleotide polymorphisms, glycosylation status, and interactions of plasma serine protease inhibitors	41
Quantitative and qualitative analysis of nitrogen species in carbon at the ppm level	40
Out-of-equilibrium chemical logic systems: Light- and sound-controlled programmable spatiotemporal patterns and mechanical functions	40
Deciphering the rational design of the early transition metals for ammonia synthesis	40
Construction of chiral nitrogen stereocenters via enantioselective C–H activation	40
Electrochemical 6Li isotope enrichment based on selective insertion in 1D tunnel-structured V2O5	40
Reaction: The challenge of open-shell transition metal catalysis in “systems chemistry”	40
Photoinduced, ground-state charge-transfer complex	40
An ultra-dynamic anion-cluster-based organic framework	40
Programmable reconfiguration of one-dimensional supramolecular polymers into multidimensional topological nanostructures	40
Integrating two contrasting biosynthetic pathways for peptide natural products	40
BINOLates as potent reducing photocatalysts for inert-bond activation and reduction of unsaturated systems	39
Design of metal-organic framework catalysts for photocatalytic hydrogen peroxide production	39
Selective and stable upgrading of biomass-derived furans into plastic monomers by coupling homogeneous and heterogeneous catalysis	39
Osmium atomic sites on CuS nanoplates for efficient two-electron oxygen reduction into H2O2	39