Chem

Article	Citations
S-Scheme Heterojunction Photocatalyst	2198
Challenges for photocatalytic overall water splitting	391
Activity Origins and Design Principles of Nickel-Based Catalysts for Nucleophile Electrooxidation	359
Recent Developments and Future Challenges in Controlled Radical Polymerization: A 2020 Update	334
Triplet Energy Transfer Photocatalysis: Unlocking the Next Level	331
Powering the Future: How Can Electrochemistry Make a Difference in Organic Synthesis?	301
Electrochemical ammonia synthesis: Mechanistic understanding and catalyst design	276
Catalytic processing of plastic waste on the rise	264
Identification of the Electronic and Structural Dynamics of Catalytic Centers in Single-Fe-Atom Material	252
Coordination Number Regulation of Molybdenum Single-Atom Nanozyme Peroxidase-like Specificity	242
A nitrogen-rich covalent organic framework for simultaneous dynamic capture of iodine and methyl iodide	227
Persistent and Stable Organic Radicals: Design, Synthesis, and Applications	227
Electrochemical Synthesis of H2O2 by Two-Electron Water Oxidation Reaction	194
Redox Comediation with Organopolysulfides in Working Lithium-Sulfur Batteries	188
Late-Stage Functionalization	188
Porous materials for hydrogen storage	180
Atropisomers beyond the C–C axial chirality: Advances in catalytic asymmetric synthesis	179
Molten Salt-Directed Catalytic Synthesis of 2D Layered Transition-Metal Nitrides for Efficient Hydrogen Evolution	171
Critical effects of electrolyte recipes for Li and Na metal batteries	170
Unconventional Mn Vacancies in Mn–Fe Prussian Blue Analogs: Suppressing Jahn-Teller Distortion for Ultrastable Sodium Storage	169
Reducing Voltage Losses in the A-DA′D-A Acceptor-Based Organic Solar Cells	166
Integration of Pd nanoparticles with engineered pore walls in MOFs for enhanced catalysis	163
Exploring and Understanding the Roles of Li2Sn and the Strategies to beyond Present Li-S Batteries	161
Catalysis for Selected C1 Chemistry	160
Outlook on K-Ion Batteries	159

Homogeneous manganese-catalyzed hydrogenation and dehydrogenation reactions	159
Light-free Generation of Singlet Oxygen through Manganese-Thiophene Nanosystems for pH-Responsive Chemiluminescence Imaging and Tumor Therapy	154
Recent advances in carbon dioxide hydrogenation to produce olefins and aromatics	150
Constructing FeN4/graphitic nitrogen atomic interface for high-efficiency electrochemical CO2 reduction over a broad potential window	148
Advances in higher alcohol synthesis from CO2 hydrogenation	145
CO2 Hydrogenation to Ethanol over Cu@Na-Beta	143
Open-Shell Graphene Fragments	142
Advances in ammonia electrosynthesis from ambient nitrate/nitrite reduction	140
Main-group elements boost electrochemical nitrogen fixation	139
Hydrogen-bonded organic frameworks: Chemistry and functions	138
Covalent-Organic-Framework-Based Composite Materials	137
Plug-and-Play Optical Materials from Fluorescent Dyes and Macrocycles	137
Propane Dehydrogenation on Single-Site [PtZn4] Intermetallic Catalysts	135
Geminal Dimethyl Substitution Enables Controlled Polymerization of Penicillamine-Derived β-Thiolactones and Reversed Depolymerization	131
Ion-Solvent Chemistry-Inspired Cation-Additive Strategy to Stabilize Electrolytes for Sodium-Metal Batteries	129
A Directional Synthesis for Topological Defect in Carbon	129
Pollutant removal with organic macrocycle-based covalent organic polymers and frameworks	126
Dissipative Self-Assembly: Fueling with Chemicals versus Light	125
Designing highly active nanoporous carbon H2O2 production electrocatalysts through active site identification	124
Catalysis, FLPs, and Beyond	122
Selectivity Control in Photocatalytic Valorization of Biomass-Derived Platform Compounds by Surface Engineering of Titanium Oxide	121
Shaping Molecular Landscapes: Recent Advances, Opportunities, and Challenges in Dearomatization	120
2D/3D perovskite engineering eliminates interfacial recombination losses in hybrid perovskite solar cells	118
Constructing an Ion Pathway for Uranium Extraction from Seawater	118
Radiation Controllable Synthesis of Robust Covalent Organic Framework Conjugates for Efficient Dynamic Column Extraction of 99TcO4−	116
An analysis of the electrochemical mechanism of manganese oxides in aqueous zinc batteries	115
Enhancing Magnetic Hysteresis in Single-Molecule Magnets by Ligand Functionalization	108
Electrochemical CO2 reduction in membrane-electrode assemblies	108
Transition-metal-catalyzed C–H allylation reactions	107
Covalent Organic Frameworks: An Amazing Chemistry Platform for Designing Polymers	105
Tuning the spin state of Fe single atoms by Pd nanoclusters enables robust oxygen reduction with dissociative pathway	102
Rational design and atroposelective synthesis of N–N axially chiral compounds	102
Boosting Electrocatalytic Ammonia Production through Mimicking “π Back-Donation”	102
Visible-light photoredox-catalyzed selective carboxylation of C(sp3)−F bonds with CO2	101
Designer DNA nanostructures for therapeutics	101
Digital Reticular Chemistry	100
Strategies for Pore Engineering in Zirconium Metal-Organic Frameworks	100
Forging C−heteroatom bonds by transition-metal-catalyzed enantioselective C–H functionalization	98
Emergent behavior in nanoconfined molecular containers	98
Li-ion battery recycling challenges	97
Hybrid monomer design for unifying conflicting polymerizability, recyclability, and performance properties	97
Design principles for intrinsically circular polymers with tunable properties	97
The concept and examples of type-III photosensitizers for cancer photodynamic therapy	96
Recent Advances in Using Transition-Metal-Catalyzed C–H Functionalization to Build Fluorescent Materials	94
Porous Ligand Creates New Reaction Route: Bifunctional Single-Atom Palladium Catalyst for Selective Distannylation of Terminal Alkynes	94
Protein-directed, hydrogen-bonded biohybrid framework	92
Encapsulated Nanodroplet Crystallization of Organic-Soluble Small Molecules	90
Nanoscale CaH2 materials for synergistic hydrogen-immune cancer therapy	90
Selective, Catalytic Oxidations of C–H Bonds in Polyethylenes Produce Functional Materials with Enhanced Adhesion	89
Surface Chemistry Can Unlock Drivers of Surface Stability of SARS-CoV-2 in a Variety of Environmental Conditions	88

DFT-Guided Phosphoric-Acid-Catalyzed Atroposelective Arene Functionalization of Nitrosonaphthalene	87
Hydrazones as New Molecular Tools	87
Confinement as a Unifying Element in Selective Catalysis	87
An encapsulating lithium-polysulfide electrolyte for practical lithium–sulfur batteries	86
Endohedral functionalization of chiral metal-organic cages for encapsulating achiral dyes to induce circularly polarized luminescence	85
In situ formation of polymer-inorganic solid-electrolyte interphase for stable polymeric solid-state lithium-metal batteries	85
Programmable synthesis of radially gradient-structured mesoporous carbon nanospheres with tunable core-shell architectures	84
Fast, reversible mechanochromism of regioisomeric oxazine mechanophores: Developing in situ responsive force probes for polymeric materials	84
Striding the threshold of an atom era of organic synthesis by single-atom catalysis	82
Product-Specific Active Site Motifs of Cu for Electrochemical CO2 Reduction	82
Hierarchical Defect Engineering for LiCoO2 through Low-Solubility Trace Element Doping	82
Rechargeable anion-shuttle batteries for low-cost energy storage	81
Atomically dispersed Ni induced by ultrahigh N-doped carbon enables stable sodium storage	81
Magnetic-Field-Regulated TiO2 {100} Facets: A Strategy for C-C Coupling in CO2 Photocatalytic Conversion	81
Light-Promoted Bromine-Radical-Mediated Selective Alkylation and Amination of Unactivated C(sp3)–H Bonds	80
Ultra-dense carbon defects as highly active sites for oxygen reduction catalysis	80
Neutrophil-Membrane-Directed Bioorthogonal Synthesis of Inflammation-Targeting Chiral Drugs	79
Development of direct conversion of syngas to unsaturated hydrocarbons based on Fischer-Tropsch route	79
Redox-Neutral Photocatalytic C−H Carboxylation of Arenes and Styrenes with CO2	79
Dynamic molecular weaving in a two-dimensional hydrogen-bonded organic framework	79
The chemical states of conjugated coordination polymers	78
Anion chemistry enabled positive valence conversion to achieve a record high-voltage organic cathode for zinc batteries	78
Optical processes in carbon nanocolloids	78
Recent advances in radical chemistry proceeding through pro-aromatic radicals	77
Dual key co-activated nanoplatform for switchable MRI monitoring accurate ferroptosis-based synergistic therapy	75
Breaking the trade-off between selectivity and adsorption capacity for gas separation	75
Gigantic Porphyrinic Cages	75
Regulating liquid and solid-state electrolytes for solid-phase conversion in Li–S batteries	75
Indoor Surface Chemistry: Developing a Molecular Picture of Reactions on Indoor Interfaces	74
Deciphering and modulating energetics of solvation structure enables aggressive high-voltage chemistry of Li metal batteries	74
Theory-Guided Machine Learning Finds Geometric Structure-Property Relationships for Chemisorption on Subsurface Alloys	74
Catalytic strategies for upvaluing plastic wastes	74
Multi-scale Imaging of Solid-State Battery Interfaces: From Atomic Scale to Macroscopic Scale	74
Progress in anion receptor chemistry	73
Oxygen-controlled photo-reforming of biopolyols to CO over Z-scheme CdS@g-C3N4	72
Unraveling the physical chemistry and materials science of CeO2-based nanostructures	72
Pumps through the Ages	72
Water-involved methane-selective catalytic oxidation by dioxygen over copper zeolites	71
Exceptionally active and stable RuO2 with interstitial carbon for water oxidation in acid	71
Size sensitivity of supported Ru catalysts for ammonia synthesis: From nanoparticles to subnanometric clusters and atomic clusters	71
Borane-Catalyzed Stereoselective C–H Insertion, Cyclopropanation, and Ring-Opening Reactions	70
Topology Meets Reticular Chemistry for Chemical Separations: MOFs as a Case Study	70
Halogen-halogen bonds enable improved long-term operational stability of mixed-halide perovskite photovoltaics	69
Modern strategies for C–H functionalization of heteroarenes with alternative coupling partners	69
Carbon nitride of five-membered rings with low optical bandgap for photoelectrochemical biosensing	69
An axial-to-axial chirality transfer strategy for atroposelective construction of C–N axial chirality	69
Precise recognition of palladium through interlaminar chelation in a covalent organic framework	68
Atomically precise electrocatalysts for oxygen reduction reaction	68
Design of metal-organic framework catalysts for photocatalytic hydrogen peroxide production	67
Porous Liquids: The Next Frontier	67
Stereodivergent total synthesis of rocaglaol initiated by synergistic dual-metal-catalyzed asymmetric allylation of benzofuran-3(2H)-one	65
Creep-Enabled 3D Solid-State Lithium-Metal Battery	65
Artificial transmembrane ion transporters as potential therapeutics	65
Progress in carbon dioxide capture materials for deep decarbonization	65
Strategies for the Synthesis of Enantiopure Mechanically Chiral Molecules	65
Programmable ATP-Fueled DNA Coacervates by Transient Liquid-Liquid Phase Separation	65
Selective Conversion of CO2 into Propene and Butene	64
Tuning the gating energy barrier of metal-organic framework for molecular sieving	64
Learning to Make Chemical Predictions: The Interplay of Feature Representation, Data, and Machine Learning Methods	64
Shale gas revolution: Catalytic conversion of C1–C3 light alkanes to value-added chemicals	63
Interfacial Active Sites for CO2 Assisted Selective Cleavage of C–C/C–H Bonds in Ethane	62
When MOFs meet wood: From opportunities toward applications	62
A relay catalysis strategy for enantioselective nickel-catalyzed migratory hydroarylation forming chiral α-aryl alkylboronates	62
A general N-alkylation platform via copper metallaphotoredox and silyl radical activation of alkyl halides	61
Peptide Late-Stage Diversifications by Rhodium-Catalyzed Tryptophan C7 Amidation	61
Single-atom engineering of metal-organic frameworks toward healthcare	61
Revealing phase evolution mechanism for stabilizing formamidinium-based lead halide perovskites by a key intermediate phase	61
Confinement Self-Assembly of Metal-Organic Cages within Mesoporous Carbon for One-Pot Sequential Reactions	60
Partially reduced Pd single atoms on CdS nanorods enable photocatalytic reforming of ethanol into high value-added multicarbon compound	60
Photo-induced thiolate catalytic activation of inert Caryl-hetero bonds for radical borylation	60
Anisotropic Microparticles from Microfluidics	60
Quantum dots enable direct alkylation and arylation of allylic C(sp3)–H bonds with hydrogen evolution by solar energy	59
Reversibly modulating a conformation-adaptive fluorophore in [2]catenane	59
Diastereo- and Enantioselective Catalytic Radical Oxysulfonylation of Alkenes in β,γ-Unsaturated Ketoximes	59
Molecular Configuration Fixation with C–H···F Hydrogen Bonding for Thermally Activated Delayed Fluorescence Acceleration	59
Bridging the Gap between Reality and Ideality of Graphdiyne: The Advances of Synthetic Methodology	58
Visible-Light-Initiated Free-Radical Polymerization by Homomolecular Triplet-Triplet Annihilation	58
Site-Selective C–H Benzylation of Alkanes with N-Triftosylhydrazones Leading to Alkyl Aromatics	57
Synergizing palladium with Lewis base catalysis for stereodivergent coupling of 1,3-dienes with pentafluorophenyl acetates	57
Design principle of electrocatalysts for the electrooxidation of organics	57

Enhanced electroreduction of CO2 to C2+ products on heterostructured Cu/oxide electrodes	57
Folding and Assembly of Metal-Linked Peptidic Nanostructures	56
Near-infrared photosensitization via direct triplet energy transfer from lanthanide nanoparticles	56
Establishing design principles for emissive organic SWIR chromophores from energy gap laws	56
Electrochemical Aziridination of Internal Alkenes with Primary Amines	55
Cu-Catalyzed Regio- and Stereodivergent Chemoselective sp/sp 1,3- and 1,4-Diborylations of CF3-Containing 1,3-Enynes	55
Electrolyte engineering for highly inorganic solid electrolyte interphase in high-performance lithium metal batteries	55
Strain-Induced Corrosion Kinetics at Nanoscale Are Revealed in Liquid: Enabling Control of Corrosion Dynamics of Electrocatalysis	55
Perspectives for antimicrobial nanomaterials in cultural heritage conservation	54
Engineering couplings for exciton transport using synthetic DNA scaffolds	54
Cationic lithium polysulfides in lithium–sulfur batteries	53
Dual-Active-Sites Design of Co@C Catalysts for Ultrahigh Selective Hydrogenation of N-Heteroarenes	53
Integrating the Mechanical Bond into Metal-Organic Frameworks	53
Aerobic Oxidative Cleavage and Esterification of C(OH)–C Bonds	52
Sensors for In Situ Real-Time Fluorescence Imaging of Enzymes	52
Mapping the Surface Groups of Amine-Rich Carbon Dots Enables Covalent Catalysis in Aqueous Media	52
Rationally fabricating 3D porphyrinic covalent organic frameworks with scu topology as highly efficient photocatalysts	52
Catalytic carbon-carbon bond cleavage and carbon-element bond formation give new life for polyolefins as biodegradable surfactants	52
Enantioselective Copper-Catalyzed Trifluoromethylation of Benzylic Radicals via Ring Opening of Cyclopropanols	52
An isolable, crystalline complex of square-planar silicon(IV)	51
Controlling the shape and chirality of an eight-crossing molecular knot	51
Asymmetric radical cyclopropanation of dehydroaminocarboxylates: Stereoselective synthesis of cyclopropyl α-amino acids	51
Synergy between β-Mo2C Nanorods and Non-thermal Plasma for Selective CO2 Reduction to CO	51
Nitrogenase inspired artificial photosynthetic nitrogen fixation	50
Unlocking the Friedel-Crafts arylation of primary aliphatic alcohols and epoxides driven by hexafluoroisopropanol	50
Recent advances in electrode engineering strategies for aqueous Zn-based batteries	50
Observation of a potential-dependent switch of water-oxidation mechanism on Co-oxide-based catalysts	49
Evaluating Solid-Electrolyte Interphases for Lithium and Lithium-free Anodes from Nanoindentation Features	49
Atomically dispersed Ru oxide catalyst with lattice oxygen participation for efficient acidic water oxidation	49
Exceptional electron conduction in two-dimensional covalent organic frameworks	48
In This Issue	48
A Robust Titanium Isophthalate Metal-Organic Framework for Visible-Light Photocatalytic CO2 Methanation	48
Enantioselective Ring-Closing C–H Amination of Urea Derivatives	48
Guest-molecule-induced self-adaptive pore engineering facilitates purification of ethylene from ternary mixture	48
Solution-Processable, Crystalline π-Conjugated Two-Dimensional Polymers with High Charge Carrier Mobility	47
Weak bonding strategies for achieving regio- and site-selective transformations	47
Palladium-catalyzed asymmetric hydrophosphination of internal alkynes: Atroposelective access to phosphine-functionalized olefins	47
Dual Stimuli Switching: Interconverting Cationic and Radical Polymerizations with Electricity and Light	47
Rationalizing the design and implementation of chiral hybrid perovskites	46
A see-through electrochromic display via dynamic metal-ligand interactions	46
The road to industrialization of fine chemical carboxylation reactions	46
Transition to sustainable chemistry through digitalization	46
Palladium/Xu-Phos-catalyzed enantioselective cascade Heck/remote C(sp2) –H alkylation reaction	46
Confining Ti-oxo clusters in covalent organic framework micropores for photocatalytic reduction of the dominant uranium species in seawater	46
Reversible isomerization of metal nanoclusters induced by intermolecular interaction	46
Quantifying Electrocatalytic Reduction of CO2 on Twin Boundaries	45
Carbohydrate amphiphiles for supramolecular biomaterials: Design, self-assembly, and applications	45
Active learning accelerates ab initio molecular dynamics on reactive energy surfaces	45
Fe binuclear sites convert methane to acetic acid with ultrahigh selectivity	45
Reactivity of an air-stable dihydrobenzoimidazole n-dopant with organic semiconductor molecules	45
In This Issue	45
Discovery of a Small Molecule Drug Candidate for Selective NKCC1 Inhibition in Brain Disorders	44
A “universal” catalyst for aerobic oxidations to synthesize (hetero)aromatic aldehydes, ketones, esters, acids, nitriles, and amides	44
Supramolecular Purification and Regioselective Functionalization of Fullerenes and Endohedral Metallofullerenes	44
Organometallic lanthanide bismuth cluster single-molecule magnets	44
Established and Emerging Computational Tools to Study Homogeneous Catalysis—From Quantum Mechanics to Machine Learning	44
Stereospecific and stereoconvergent nucleophilic substitution reactions at tertiary carbon centers	44
High-yield exfoliation of 2D semiconductor monolayers and reassembly of organic/inorganic artificial superlattices	44
Rational design and synthesis of two-dimensional conjugated metal-organic polymers for electrocatalysis applications	44
An integrated solid-state lithium-oxygen battery with highly stable anionic covalent organic frameworks electrolyte	43
A Bioinspired Multicomponent Catalytic System for Converting Carbon Dioxide into Methanol Autocatalytically	43
Dynamic optimization of guest binding in a library of diastereomeric heteroleptic coordination cages	43
On-the-fly interpretable machine learning for rapid discovery of two-dimensional ferromagnets with high Curie temperature	42
Heterogeneous hydroformylation of alkenes by Rh-based catalysts	42
Protein stabilization and refolding in a gigantic self-assembled cage	42
Long carrier diffusion length in two-dimensional lead halide perovskite single crystals	42
A base-controlled switch of SO2 reincorporation in photocatalyzed radical difunctionalization of alkenes	42
Synthesis of amino acids by electrocatalytic reduction of CO2 on chiral Cu surfaces	42
One-Dimensional Segregated Single Au Sites on Step-Rich ZnO Ladder for Ultrasensitive NO2 Sensors	42
Mass Photometry of Membrane Proteins	42
In situ monitoring of mechanochemical covalent organic framework formation reveals templating effect of liquid additive	42
Identifying the Conformational Isomers of Single-Molecule Cyclohexane at Room Temperature	41
Computer-aided design of RNA-targeted small molecules: A growing need in drug discovery	41
Small amines bring big benefits to perovskite-based solar cells and light-emitting diodes	41
Integrated strategy for the synthesis of aromatic building blocks via upcycling of real-life plastic wastes	41
TADF molecules with π-extended acceptors for simplified high-efficiency blue and white organic light-emitting diodes	41
Aza-heterocycles via copper-catalyzed, remote C–H desaturation of amines	40
Laser-Microstructured Copper Reveals Selectivity Patterns in the Electrocatalytic Reduction of CO2	40
Reaction: Semiconducting MOFs Offer New Strategy for Uranium Extraction from Seawater	40
Non-covalent interactions of graphene surface: Mechanisms and applications	40
Sulfondiimidamides as new functional groups for synthetic and medicinal chemistry	40
Aqueous rechargeable zinc air batteries operated at −110°C	40
Liquid fuel synthesis via CO2 hydrogenation by coupling homogeneous and heterogeneous catalysis	39
Surface lattice engineering through three-dimensional lead iodide perovskitoid for high-performance perovskite solar cells	39
Porous Ladder Polymer Networks	39
Synthesis of wafer-scale ultrathin graphdiyne for flexible optoelectronic memory with over 256 storage levels	39
Hydrogen-bond activation of N2 molecules and photocatalytic nitrogen fixation	39
Wettability of graphene and interfacial water structure	39
Synthetic Supramolecular Systems in Life-like Materials and Protocell Models	38
Porous polyisothiocyanurates for selective palladium recovery and heterogeneous catalysis	38
Field-induced oscillation of magnetization blocking barrier in a holmium metallacrown single-molecule magnet	38
Tumor Cell Dissociation Removes Malignant Bladder Tumors	37
Heterometallic Titanium-Organic Frameworks as Dual-Metal Catalysts for Synergistic Non-buffered Hydrolysis of Nerve Agent Simulants	37
In this issue	37
Impact of novel detergents on membrane protein studies	37