Chem

Article	Citations
S-Scheme Heterojunction Photocatalyst	2025
Challenges for photocatalytic overall water splitting	339
Recent Developments and Future Challenges in Controlled Radical Polymerization: A 2020 Update	323
Activity Origins and Design Principles of Nickel-Based Catalysts for Nucleophile Electrooxidation	313
Triplet Energy Transfer Photocatalysis: Unlocking the Next Level	311
Organic-Inorganic-Induced Polymer Intercalation into Layered Composites for Aqueous Zinc-Ion Battery	281
Powering the Future: How Can Electrochemistry Make a Difference in Organic Synthesis?	279
Electrochemical ammonia synthesis: Mechanistic understanding and catalyst design	255
Catalytic processing of plastic waste on the rise	242
Identification of the Electronic and Structural Dynamics of Catalytic Centers in Single-Fe-Atom Material	235
High-Performance n-Type Polymer Semiconductors: Applications, Recent Development, and Challenges	234
Accelerated Dinitrogen Electroreduction to Ammonia via Interfacial Polarization Triggered by Single-Atom Protrusions	224
Coordination Number Regulation of Molybdenum Single-Atom Nanozyme Peroxidase-like Specificity	223
A nitrogen-rich covalent organic framework for simultaneous dynamic capture of iodine and methyl iodide	205
Synthesis of CaCO3-Based Nanomedicine for Enhanced Sonodynamic Therapy via Amplification of Tumor Oxidative Stress	202
Persistent and Stable Organic Radicals: Design, Synthesis, and Applications	202
Late-Stage Functionalization	178
Developments in Photoredox/Nickel Dual-Catalyzed 1,2-Difunctionalizations	177
Redox Comediation with Organopolysulfides in Working Lithium-Sulfur Batteries	176
Electrochemical Synthesis of H2O2 by Two-Electron Water Oxidation Reaction	165
Molten Salt-Directed Catalytic Synthesis of 2D Layered Transition-Metal Nitrides for Efficient Hydrogen Evolution	163
A Realistic Methodology for 30% Efficient Perovskite Solar Cells	161
Reducing Voltage Losses in the A-DA′D-A Acceptor-Based Organic Solar Cells	157
Atropisomers beyond the C–C axial chirality: Advances in catalytic asymmetric synthesis	153
Porous materials for hydrogen storage	152

Unconventional Mn Vacancies in Mn–Fe Prussian Blue Analogs: Suppressing Jahn-Teller Distortion for Ultrastable Sodium Storage	151
Catalysis for Selected C1 Chemistry	150
Light-free Generation of Singlet Oxygen through Manganese-Thiophene Nanosystems for pH-Responsive Chemiluminescence Imaging and Tumor Therapy	150
A Structure-Based Platform for Predicting Chemical Reactivity	149
Exploring and Understanding the Roles of Li2Sn and the Strategies to beyond Present Li-S Batteries	149
Critical effects of electrolyte recipes for Li and Na metal batteries	148
Integration of Pd nanoparticles with engineered pore walls in MOFs for enhanced catalysis	147
Homogeneous manganese-catalyzed hydrogenation and dehydrogenation reactions	145
Highly Selective Hydrogen Peroxide Electrosynthesis on Carbon: In Situ Interface Engineering with Surfactants	143
Outlook on K-Ion Batteries	140
Quasi-Solid-State Dual-Ion Sodium Metal Batteries for Low-Cost Energy Storage	138
Open-Shell Graphene Fragments	136
Constructing FeN4/graphitic nitrogen atomic interface for high-efficiency electrochemical CO2 reduction over a broad potential window	135
CO2 Hydrogenation to Ethanol over Cu@Na-Beta	134
Advances in higher alcohol synthesis from CO2 hydrogenation	134
Fluorescent Imaging of Reactive Oxygen and Nitrogen Species Associated with Pathophysiological Processes	131
Covalent-Organic-Framework-Based Composite Materials	130
Dynamic Covalent Synthesis of Crystalline Porous Graphitic Frameworks	127
Recent advances in carbon dioxide hydrogenation to produce olefins and aromatics	127
Main-group elements boost electrochemical nitrogen fixation	127
Tailoring Polymer Dispersity by RAFT Polymerization: A Versatile Approach	126
Plug-and-Play Optical Materials from Fluorescent Dyes and Macrocycles	126
A Directional Synthesis for Topological Defect in Carbon	122
Geminal Dimethyl Substitution Enables Controlled Polymerization of Penicillamine-Derived β-Thiolactones and Reversed Depolymerization	120
Propane Dehydrogenation on Single-Site [PtZn4] Intermetallic Catalysts	118
Hydrogen-bonded organic frameworks: Chemistry and functions	118
Ion-Solvent Chemistry-Inspired Cation-Additive Strategy to Stabilize Electrolytes for Sodium-Metal Batteries	117
Catalysis, FLPs, and Beyond	115
Perovskite Solution Aging: What Happened and How to Inhibit?	115
Synthesis of a Mechanically Planar Chiral Rotaxane Ligand for Enantioselective Catalysis	114
Dissipative Self-Assembly: Fueling with Chemicals versus Light	114
Designing highly active nanoporous carbon H2O2 production electrocatalysts through active site identification	114
Pollutant removal with organic macrocycle-based covalent organic polymers and frameworks	113
Selectivity Control in Photocatalytic Valorization of Biomass-Derived Platform Compounds by Surface Engineering of Titanium Oxide	113
2D/3D perovskite engineering eliminates interfacial recombination losses in hybrid perovskite solar cells	111
Shaping Molecular Landscapes: Recent Advances, Opportunities, and Challenges in Dearomatization	108
Constructing an Ion Pathway for Uranium Extraction from Seawater	106
Radiation Controllable Synthesis of Robust Covalent Organic Framework Conjugates for Efficient Dynamic Column Extraction of 99TcO4−	106
Enhancing Magnetic Hysteresis in Single-Molecule Magnets by Ligand Functionalization	103
Covalent Organic Frameworks: An Amazing Chemistry Platform for Designing Polymers	100
Transition-metal-catalyzed C–H allylation reactions	100
Extremely Stable Anthraquinone Negolytes Synthesized from Common Precursors	99
Nickel-Catalyzed C−H Functionalization Using A Non-directed Strategy	99
An analysis of the electrochemical mechanism of manganese oxides in aqueous zinc batteries	98
Advances in ammonia electrosynthesis from ambient nitrate/nitrite reduction	98
Reaction: Rational Design of Highly Active Photocatalysts for CO2 Conversion	97
Emergent behavior in nanoconfined molecular containers	96
Digital Reticular Chemistry	96
Two-Dimensional Nanomaterials with Unconventional Phases	95
Chemistry and Biology of SARS-CoV-2	94

Designer DNA nanostructures for therapeutics	92
Prospects and Challenges in Anion Recognition and Transport	92
Porous Ligand Creates New Reaction Route: Bifunctional Single-Atom Palladium Catalyst for Selective Distannylation of Terminal Alkynes	92
Boosting Electrocatalytic Ammonia Production through Mimicking “π Back-Donation”	91
Strategies for Pore Engineering in Zirconium Metal-Organic Frameworks	91
Forging C−heteroatom bonds by transition-metal-catalyzed enantioselective C–H functionalization	91
Li-ion battery recycling challenges	90
Electrochemical CO2 reduction in membrane-electrode assemblies	90
Visible-light photoredox-catalyzed selective carboxylation of C(sp3)−F bonds with CO2	90
Rational design and atroposelective synthesis of N–N axially chiral compounds	88
Recent Advances in Using Transition-Metal-Catalyzed C–H Functionalization to Build Fluorescent Materials	87
Hydrazones as New Molecular Tools	83
Protein-directed, hydrogen-bonded biohybrid framework	83
Hybrid monomer design for unifying conflicting polymerizability, recyclability, and performance properties	83
DFT-Guided Phosphoric-Acid-Catalyzed Atroposelective Arene Functionalization of Nitrosonaphthalene	83
Surface Chemistry Can Unlock Drivers of Surface Stability of SARS-CoV-2 in a Variety of Environmental Conditions	83
Fast, reversible mechanochromism of regioisomeric oxazine mechanophores: Developing in situ responsive force probes for polymeric materials	82
Design principles for intrinsically circular polymers with tunable properties	82
Encapsulated Nanodroplet Crystallization of Organic-Soluble Small Molecules	82
Tuning the spin state of Fe single atoms by Pd nanoclusters enables robust oxygen reduction with dissociative pathway	81
The concept and examples of type-III photosensitizers for cancer photodynamic therapy	80
Selective, Catalytic Oxidations of C–H Bonds in Polyethylenes Produce Functional Materials with Enhanced Adhesion	80
Confinement as a Unifying Element in Selective Catalysis	78
Redox-Neutral Photocatalytic C−H Carboxylation of Arenes and Styrenes with CO2	78
Atomically dispersed Ni induced by ultrahigh N-doped carbon enables stable sodium storage	77
An encapsulating lithium-polysulfide electrolyte for practical lithium–sulfur batteries	77
Nanoscale CaH2 materials for synergistic hydrogen-immune cancer therapy	77
Light-Promoted Bromine-Radical-Mediated Selective Alkylation and Amination of Unactivated C(sp3)–H Bonds	77
Programmable synthesis of radially gradient-structured mesoporous carbon nanospheres with tunable core-shell architectures	77
Endohedral functionalization of chiral metal-organic cages for encapsulating achiral dyes to induce circularly polarized luminescence	76
Hierarchical Defect Engineering for LiCoO2 through Low-Solubility Trace Element Doping	76
In situ formation of polymer-inorganic solid-electrolyte interphase for stable polymeric solid-state lithium-metal batteries	76
Magnetic-Field-Regulated TiO2 {100} Facets: A Strategy for C-C Coupling in CO2 Photocatalytic Conversion	76
Striding the threshold of an atom era of organic synthesis by single-atom catalysis	75
Optical processes in carbon nanocolloids	75
Neutrophil-Membrane-Directed Bioorthogonal Synthesis of Inflammation-Targeting Chiral Drugs	74
Product-Specific Active Site Motifs of Cu for Electrochemical CO2 Reduction	73
The chemical states of conjugated coordination polymers	72
Catalytic Decarboxylative Radical Sulfonylation	71
Rechargeable anion-shuttle batteries for low-cost energy storage	71
Dynamic molecular weaving in a two-dimensional hydrogen-bonded organic framework	70
Borane-Catalyzed Stereoselective C–H Insertion, Cyclopropanation, and Ring-Opening Reactions	70
Pumps through the Ages	70
Indoor Surface Chemistry: Developing a Molecular Picture of Reactions on Indoor Interfaces	70
Breaking the trade-off between selectivity and adsorption capacity for gas separation	69
Recent advances in radical chemistry proceeding through pro-aromatic radicals	69
Ultra-dense carbon defects as highly active sites for oxygen reduction catalysis	69
Anion chemistry enabled positive valence conversion to achieve a record high-voltage organic cathode for zinc batteries	69
Dual key co-activated nanoplatform for switchable MRI monitoring accurate ferroptosis-based synergistic therapy	68
Progress in anion receptor chemistry	68
Gigantic Porphyrinic Cages	68
Stable Carbenes, Nitrenes, Phosphinidenes, and Borylenes: Past and Future	68
Controlled Synthesis of PdII and PtII Supramolecular Copolymer with Sequential Multiblock and Amplified Phosphorescence	67
Theory-Guided Machine Learning Finds Geometric Structure-Property Relationships for Chemisorption on Subsurface Alloys	66
Carbon nitride of five-membered rings with low optical bandgap for photoelectrochemical biosensing	65
Unraveling the physical chemistry and materials science of CeO2-based nanostructures	65
Water-involved methane-selective catalytic oxidation by dioxygen over copper zeolites	65
Oxygen-controlled photo-reforming of biopolyols to CO over Z-scheme CdS@g-C3N4	65
Modern strategies for C–H functionalization of heteroarenes with alternative coupling partners	65
Development of direct conversion of syngas to unsaturated hydrocarbons based on Fischer-Tropsch route	64
Multi-scale Imaging of Solid-State Battery Interfaces: From Atomic Scale to Macroscopic Scale	64
Learning to Make Chemical Predictions: The Interplay of Feature Representation, Data, and Machine Learning Methods	63
Creep-Enabled 3D Solid-State Lithium-Metal Battery	63
Topology Meets Reticular Chemistry for Chemical Separations: MOFs as a Case Study	62
Molecules in Confined Spaces: Reactivities and Possibilities in Cavitands	62
Catalytic strategies for upvaluing plastic wastes	62
Strategies for the Synthesis of Enantiopure Mechanically Chiral Molecules	62
Thermally Gated Bio-orthogonal Nanozymes with Supramolecularly Confined Porphyrin Catalysts for Antimicrobial Uses	62
Size sensitivity of supported Ru catalysts for ammonia synthesis: From nanoparticles to subnanometric clusters and atomic clusters	61
Regulating liquid and solid-state electrolytes for solid-phase conversion in Li–S batteries	61
An axial-to-axial chirality transfer strategy for atroposelective construction of C–N axial chirality	59
Quantum dots enable direct alkylation and arylation of allylic C(sp3)–H bonds with hydrogen evolution by solar energy	59
Peptide Late-Stage Diversifications by Rhodium-Catalyzed Tryptophan C7 Amidation	59
Confinement Self-Assembly of Metal-Organic Cages within Mesoporous Carbon for One-Pot Sequential Reactions	59
Tuning the gating energy barrier of metal-organic framework for molecular sieving	59
Halogen-halogen bonds enable improved long-term operational stability of mixed-halide perovskite photovoltaics	58
Engine-Trailer-Structured Nanotrucks for Efficient Nano-Bio Interactions and Bioimaging-Guided Drug Delivery	58
Molecular Configuration Fixation with C–H···F Hydrogen Bonding for Thermally Activated Delayed Fluorescence Acceleration	58
Progress in carbon dioxide capture materials for deep decarbonization	58
Selective Conversion of CO2 into Propene and Butene	58

Porous Liquids: The Next Frontier	58
Artificial transmembrane ion transporters as potential therapeutics	57
Nanorobots: Machines Squeezed between Molecular Motors and Micromotors	57
A general N-alkylation platform via copper metallaphotoredox and silyl radical activation of alkyl halides	57
Bridging the Gap between Reality and Ideality of Graphdiyne: The Advances of Synthetic Methodology	57
Shale gas revolution: Catalytic conversion of C1–C3 light alkanes to value-added chemicals	57
Interfacial Active Sites for CO2 Assisted Selective Cleavage of C–C/C–H Bonds in Ethane	57
Single-atom engineering of metal-organic frameworks toward healthcare	56
Programmable ATP-Fueled DNA Coacervates by Transient Liquid-Liquid Phase Separation	56
Precise recognition of palladium through interlaminar chelation in a covalent organic framework	56
Diastereo- and Enantioselective Catalytic Radical Oxysulfonylation of Alkenes in β,γ-Unsaturated Ketoximes	56
Stereodivergent total synthesis of rocaglaol initiated by synergistic dual-metal-catalyzed asymmetric allylation of benzofuran-3(2H)-one	55
Cu-Catalyzed Regio- and Stereodivergent Chemoselective sp/sp 1,3- and 1,4-Diborylations of CF3-Containing 1,3-Enynes	55
Photo-induced thiolate catalytic activation of inert Caryl-hetero bonds for radical borylation	55
Anisotropic Microparticles from Microfluidics	55
Design of metal-organic framework catalysts for photocatalytic hydrogen peroxide production	55
Partially reduced Pd single atoms on CdS nanorods enable photocatalytic reforming of ethanol into high value-added multicarbon compound	55
A relay catalysis strategy for enantioselective nickel-catalyzed migratory hydroarylation forming chiral α-aryl alkylboronates	55
Exceptionally active and stable RuO2 with interstitial carbon for water oxidation in acid	54
Folding and Assembly of Metal-Linked Peptidic Nanostructures	54
When MOFs meet wood: From opportunities toward applications	54
Shape-Induced Selective Separation of Ortho-substituted Benzene Isomers Enabled by Cucurbit[7]uril Host Macrocycles	54
Electrochemical Aziridination of Internal Alkenes with Primary Amines	53
Revealing phase evolution mechanism for stabilizing formamidinium-based lead halide perovskites by a key intermediate phase	53
Reversibly modulating a conformation-adaptive fluorophore in [2]catenane	52
Deciphering and modulating energetics of solvation structure enables aggressive high-voltage chemistry of Li metal batteries	52
Engineering couplings for exciton transport using synthetic DNA scaffolds	52
Visible-Light-Initiated Free-Radical Polymerization by Homomolecular Triplet-Triplet Annihilation	51
Integrating the Mechanical Bond into Metal-Organic Frameworks	51
Aerobic Oxidative Cleavage and Esterification of C(OH)–C Bonds	51
A Fluorinated Ionic Liquid-Based Activatable 19F MRI Platform Detects Biological Targets	51
Perspectives for antimicrobial nanomaterials in cultural heritage conservation	50
Strain-Induced Corrosion Kinetics at Nanoscale Are Revealed in Liquid: Enabling Control of Corrosion Dynamics of Electrocatalysis	50
Catalytic carbon-carbon bond cleavage and carbon-element bond formation give new life for polyolefins as biodegradable surfactants	50
Synergizing palladium with Lewis base catalysis for stereodivergent coupling of 1,3-dienes with pentafluorophenyl acetates	49
An isolable, crystalline complex of square-planar silicon(IV)	49
Site-Selective C–H Benzylation of Alkanes with N-Triftosylhydrazones Leading to Alkyl Aromatics	49
Dual-Active-Sites Design of Co@C Catalysts for Ultrahigh Selective Hydrogenation of N-Heteroarenes	49
Controlling the shape and chirality of an eight-crossing molecular knot	49
Near-infrared photosensitization via direct triplet energy transfer from lanthanide nanoparticles	48
Sensors for In Situ Real-Time Fluorescence Imaging of Enzymes	48
Enhanced electroreduction of CO2 to C2+ products on heterostructured Cu/oxide electrodes	48
Establishing design principles for emissive organic SWIR chromophores from energy gap laws	48
Asymmetric radical cyclopropanation of dehydroaminocarboxylates: Stereoselective synthesis of cyclopropyl α-amino acids	48
Enantioselective Ring-Closing C–H Amination of Urea Derivatives	48
Synergy between β-Mo2C Nanorods and Non-thermal Plasma for Selective CO2 Reduction to CO	47
Mapping the Surface Groups of Amine-Rich Carbon Dots Enables Covalent Catalysis in Aqueous Media	47
Design principle of electrocatalysts for the electrooxidation of organics	47
In This Issue	46
Diindenoanthracene Diradicaloids Enable Rational, Incremental Tuning of Their Singlet-Triplet Energy Gaps	46
Nitrogenase inspired artificial photosynthetic nitrogen fixation	46
Biology-Inspired Supramolecular Peptide Systems	46
Catalyst: Aggregation-Induced Emission—How Far Have We Come, and Where Are We Going Next?	45
Evaluating Solid-Electrolyte Interphases for Lithium and Lithium-free Anodes from Nanoindentation Features	45
Unlocking the Friedel-Crafts arylation of primary aliphatic alcohols and epoxides driven by hexafluoroisopropanol	45
Enantioselective Copper-Catalyzed Trifluoromethylation of Benzylic Radicals via Ring Opening of Cyclopropanols	44
Solution-Processable, Crystalline π-Conjugated Two-Dimensional Polymers with High Charge Carrier Mobility	44
Palladium/Xu-Phos-catalyzed enantioselective cascade Heck/remote C(sp2) –H alkylation reaction	44
Guest-molecule-induced self-adaptive pore engineering facilitates purification of ethylene from ternary mixture	43
Reactivity of an air-stable dihydrobenzoimidazole n-dopant with organic semiconductor molecules	43
Carbohydrate amphiphiles for supramolecular biomaterials: Design, self-assembly, and applications	43
Established and Emerging Computational Tools to Study Homogeneous Catalysis—From Quantum Mechanics to Machine Learning	43
Dual Stimuli Switching: Interconverting Cationic and Radical Polymerizations with Electricity and Light	43
Transition to sustainable chemistry through digitalization	43
Rationally fabricating 3D porphyrinic covalent organic frameworks with scu topology as highly efficient photocatalysts	43
Active learning accelerates ab initio molecular dynamics on reactive energy surfaces	42
Observation of a potential-dependent switch of water-oxidation mechanism on Co-oxide-based catalysts	42
Palladium-catalyzed asymmetric hydrophosphination of internal alkynes: Atroposelective access to phosphine-functionalized olefins	42
Cationic lithium polysulfides in lithium–sulfur batteries	42
Fe binuclear sites convert methane to acetic acid with ultrahigh selectivity	42
Exceptional electron conduction in two-dimensional covalent organic frameworks	42
The road to industrialization of fine chemical carboxylation reactions	42
Stereospecific and stereoconvergent nucleophilic substitution reactions at tertiary carbon centers	42
A Robust Titanium Isophthalate Metal-Organic Framework for Visible-Light Photocatalytic CO2 Methanation	41
In This Issue	41
Identifying the Conformational Isomers of Single-Molecule Cyclohexane at Room Temperature	41
Organometallic lanthanide bismuth cluster single-molecule magnets	41
Quantifying Electrocatalytic Reduction of CO2 on Twin Boundaries	41
Recent advances in electrode engineering strategies for aqueous Zn-based batteries	40
Discovery of a Small Molecule Drug Candidate for Selective NKCC1 Inhibition in Brain Disorders	40
A Bioinspired Multicomponent Catalytic System for Converting Carbon Dioxide into Methanol Autocatalytically	40
Weak bonding strategies for achieving regio- and site-selective transformations	40
Molecular Representation: Going Long on Fingerprints	40
Supramolecular Purification and Regioselective Functionalization of Fullerenes and Endohedral Metallofullerenes	40
Reversible isomerization of metal nanoclusters induced by intermolecular interaction	39
On-the-fly interpretable machine learning for rapid discovery of two-dimensional ferromagnets with high Curie temperature	39
Laser-Microstructured Copper Reveals Selectivity Patterns in the Electrocatalytic Reduction of CO2	39
Dynamic optimization of guest binding in a library of diastereomeric heteroleptic coordination cages	39
A see-through electrochromic display via dynamic metal-ligand interactions	39
Atomically precise electrocatalysts for oxygen reduction reaction	39
A base-controlled switch of SO2 reincorporation in photocatalyzed radical difunctionalization of alkenes	38
Protein stabilization and refolding in a gigantic self-assembled cage	38
Mass Photometry of Membrane Proteins	38
Electrolyte engineering for highly inorganic solid electrolyte interphase in high-performance lithium metal batteries	38
Redox Control of Charge Transport in Vertical Ferrocene Molecular Tunnel Junctions	38