Chem

Article	Citations
In This Issue	675
A high-throughput workflow to analyze sequence-conformation relationships and explore hydrophobic patterning in disordered peptoids	393
From trash to treasure: Vanadium-catalyzed upcycling of non-biodegradable plastics	336
Out-of-equilibrium chemical logic systems	305
Thermosetting supramolecular polymerization of compartmentalized DNA fibers with stereo sequence and length control	297
Excited-state protonation and reduction enable the umpolung Birch reduction of naphthalenes	291
Ion-dipole-interaction-manipulated bilateral interface chemistry for deep rechargeability and high redox activity of Zn-organic batteries	242
B(C6F5)3-catalyzed selective C–H chalcogenation of arenes and heteroarenes	237
In this issue	216
An M60L60 metal-peptide capsid with a 60-crossing woven network	214
Recent research progress of all-polymer solar cells based on PSMA-type polymer acceptors	210
Probing enantioinduction in confined chiral spaces through asymmetric oxime reductions	202
Variable nanosheets for highly efficient oxygen evolution reaction	193
Experimentally modeling the emergence of prebiotically plausible phospholipid vesicles	193
Harnessing plastic depolymerization products to upcycle mixed waste into high-value chemicals	182
Quasicrystal approximants in isoreticular metal-organic frameworks via Cairo pentagonal tiling	181
Air-stable radical polycyclic aromatic hydrogen-bonded organic frameworks	173
Revealing phase evolution mechanism for stabilizing formamidinium-based lead halide perovskites by a key intermediate phase	173
2D covalent organic framework via catenation	160
2D conjugated metal-organic framework as a proton-electron dual conductor	159
Multi-omics profiling of a self-assembling bioactive hydrogel for immunomodulation and myogenesis in volumetric muscle loss	156
A Star of David [2]catenane of single handedness	154
Reaction: Harnessing reactive oxygen species (ROS) for water purification	154
Click chemistry in polymer science	150
Lanthanide luminescence from supramolecular hydrogels consisting of bio-conjugated picolinic-acid-based guanosine quadruplexes	146

Spatially resolved cell tagging and surfaceome labeling via targeted photocatalytic decaging	144
Nanocellulose: New horizons in organic chemistry and beyond	144
Photoswitches and photochemical reactions for optically controlled phase transition and energy storage	142
Nature-inspired synthetic oligourea foldamer channels allow water transport with high salt rejection	137
Supramolecular boosted superexchange	134
Swapping benches from chemistry PhD student to science advisor at law firm	132
Reaction: Don’t hate the player in chemical AI; hate the game	131
Semiconducting ladder-type covalent organic frameworks	130
Time-resolved fluorescence imaging with color-changing, “turn-on/turn-on” AIE nanoparticles	125
An effective strategy to boost lattice-oxygen-mediated acidic oxygen evolution	125
Protein stabilization and refolding in a gigantic self-assembled cage	124
Transition metal-free difunctionalization of unactivated alkenes: Arylation/azidation, arylation/chlorination, and arylation/cyanation	124
General and selective metal-free radical α-C–H borylation of aliphatic amines	122
Higher-order cycloadditions in the age of catalysis	121
Atom swap in triple bonds via nitrogen-deletion coupling with gem-diborylalkanes	119
The beauty of low symmetry: Non-statistical assembly of [Pd2(LA)(LB)(LC)(LD)]4+ cages	119
Highly oxygenated organic molecules with high unsaturation formed upon photochemical aging of soot	116
Battery detectives: Uncovering cathode impact on anode-free Li cell performance by operando NMR	116
Be your own star	116
Redox-couple-assisted CO2 capture on solid-electrolyte reactor	115
In this issue	114
Molecular freaky Friday: Polarity reversal and resorcin[4]arenes as chloride receptors	113
Catalytic strategies for upvaluing plastic wastes	113
In this issue	113
para-Selective C–H alkylation of aroyl chlorides through organic photoredox-catalyzed radical tele-substitution	111
Ionic surface propensity controls pH in nanopores	109
In This Issue	109
Curved plane increases the d vacancy population of Pd for green production of cyclohexanone	107
Switchable diversification of quaternary ammonium salts using photocatalysis	107
From G-protein-coupled receptors to solute carriers—mass spectrometry informs dynamics, function, and regulation	107
Molecular design strategy for realizing vectorial electron transfer in photoelectrodes	104
Design of piezoelectric organic cage salts for energy harvesting	104
Modular nucleic acid scaffolds for synthesizing monodisperse and sequence-encoded antibody oligomers	104
Bioinspired chemical design to control interfacial wet adhesion	104
Molecule-resolvable SERSome for metabolic profiling	102
Photo-assembling cyclic peptides for dynamic light-driven peptide nanotubes	102
Two-in-one metallaphotoredox cross-couplings enabled by a photoactive ligand	100
Strong halide anion binding within the cavity of a conformation-adaptive phenazine-based Pd2L4 cage	98
Cation-exchange-upgraded nanostructures for photocatalysts	98
Observation of ultrafast electrons in pendant-embedded conducting two-dimensional polymers	98
Stereodivergent asymmetric hydrogenation of quinoxalines	94
Phosphine oxide additives for perovskite light-emitting diodes and solar cells	93
Supramolecular triangular orthobicupola: Self-assembly of a giant Johnson solid J27	92
The role of concentration waves in synthesizing hollow multi-shelled structures	90
Colorless zinc colored by metal-metal orbital interaction	90
Pilot-scale reductive catalytic depolymerization of lignin: Challenges and guidelines	90
Antigen spatial-matching polyaptamer nanostructure to block coronavirus infection and alleviate inflammation	89
Selective palladium recovery by a highly porous polyisothiocyanurate	88
Direct enantioselective α-amination of amides guided by DFT prediction of E/Z selectivity in a sulfonium intermediate	88
Chemical probes of redox enzymes by rational, reactivity-based design	87

Enzymatic DNA orthogonal chemistry for multi-cancer diagnosis	87
Metal-free photocatalyzed cyanation enables access to carbon-11-radiolabeled aryl nitriles	85
A light-driven chloride anion transporter	85
Upcycling waste PET and CO2 to useful chemicals: Multi-functional catalysis at its best	83
The key of Zn2+ transfer kinetics in zinc metal batteries	83
Designing generative dissipative networks for programming complex temporal dynamics and functions	82
Development of tumor-evolution-targeted anticancer therapeutic nanomedicineEVT	81
Revisiting the impacts of silica nanoparticles on endothelial cell junctions and tumor metastasis	81
Challenges and perspectives for the perovskite module research	81
Ice quenching for sustained nucleate boiling at large superheats	80
Catalyst: A step forward for PVC manufacture from natural gas	80
The mechanical bond in biological systems	79
Emerging trends in CO carbonylation	78
Potent antimicrobial effect induced by disruption of chloride homeostasis	77
Spontaneous chiral self-assembly of CdSe@CdS nanorods	74
Programmable spatial organization of liquid-phase condensations	74
Deprotection of benzyl-derived groups via photochemically mesolytic cleavage of C–N and C–O bonds	73
Halogen-halogen bonds enable improved long-term operational stability of mixed-halide perovskite photovoltaics	73
Forging C−heteroatom bonds by transition-metal-catalyzed enantioselective C–H functionalization	72
Finding your voice in a diverse audience: Lessons in writing and advocacy	71
A novel type of radical-addition-induced β-fragmentation and ensuing remote functionalization	71
Regulating liquid and solid-state electrolytes for solid-phase conversion in Li–S batteries	71
A clever trilayer assembly strategy for 2D materials	71
Industrial PhD: My way to go?	71
Elucidating the role of cathode identity: Voltage-dependent reversibility of anode-free batteries	70
Molecule additive design for perovskite light-emitting diodes operated at high current densities	69
Cold-resilient zinc batteries with organic-free solvation structures	68
Frontier research in perovskite solar cells: Following the paths of European research and innovation	68
Programmable in vitro and in vivo folding of single-stranded nucleic-acid wireframe origami	68
Reaction: Circular chemical imaginaries	68
Omics approach for electrolytes discovery	68
Ultralong ionic chains with lengths over 10 μm: A control of ionic molecular engineering	68
Cross-assembly confined bifunctional catalysis via non-covalent interactions for asymmetric halogenation	67
Microporous B←N framework: A stable and efficient material for separating C2H2 and CO2	67
Remote optical chirality transfer via helical polyaromatic capsules upon encapsulation	67
Bioorthogonal reactions and AIEgen-based metabolically engineered theranostic systems	67
Transformable quadruply interpenetrated cage with multiple states of different reactivities	66
Aqueous electrocatalytic small-molecule valorization trilogy	66
Rationalizing the design and implementation of chiral hybrid perovskites	66
Metal-organic frameworks for water vapor adsorption	66
Rational structure transformation triggered by titanium modulation in metal-organic frameworks for efficient flue gas utilization	66
High-resolution transmission electron microscopy of beam-sensitive halide perovskites	66
Oxygen-tolerant photocatalytic conversion of simulated flue gas to ethylene	65
A B←N framework based on 1D dative B←N polymers for exclusive recognition and separation of benzene from its azeotrope	64
Amorphous materials emerging as prospective electrodes for electrochemical energy storage and conversion	64
Deciphering reactive intermediates in electrooxidative coupling of indoles through real-time mass spectrometry	64
Controlling dynamic reconstruction chemistry for superior oxygen-evolving catalysts	64
Hydrogen-bonded organic frameworks: Chemistry and functions	63
In this issue	63
Conceptually novel diarylation for sustainable synthesis	63
Protein-directed, hydrogen-bonded biohybrid framework	62
The road to industrialization of fine chemical carboxylation reactions	62
Self-assembly of 10-nm-sized pentagonal dodecahedra through heteroleptic complexation coupled with orientational self-sorting	62
Dispersion-driven formation of chiral twisted PAH double helices	62
Dynamic mechanoresponsive polymers enabled by ring-opening polymerization of cyclic propargyl carbonates	62
Innovative low-carbon technology for a sustainable electrolyte industry	62
Correlations between precipitation reactions and electrochemical performance of lithium-sulfur batteries probed by operando scattering techniques	61
In this issue	61
Self-adjusted aromatic cation-π binding promotes controlled self-assembly of positively charged π-electronic molecules	61
Selective cellular probes for mammalian thioredoxin reductase TrxR1: Rational design of RX1, a modular 1,2-thiaselenane redox probe	61
Activating a light-driven molecular motor by metal complexation	60
Sculpting photoproducts with DNA origami	60
Self-sorting as a versatile strategy in the synthesis of rotaxanes and catenanes	59
Microenvironment engineering of non-noble metal alloy for selective propane dehydrogenation	58
Phenanthrenequinone-like moiety functionalized carbon for electrocatalytic acidic oxygen evolution	58
Rational design and synthesis of two-dimensional conjugated metal-organic polymers for electrocatalysis applications	58
Metal-organic frameworks for fast electrochemical energy storage: Mechanisms and opportunities	57
Water, metal ions, and me: A chemist’s tale of serendipity and discovery	57
Supramolecular interactions enable pseudo-nanophase separation for constructing an ion-transport highway	57
Downsizing lactams via Rh-catalyzed C–C activation	56
Pursuing electrically pumped lasing with organic semiconductors	56
Synergizing palladium with Lewis base catalysis for stereodivergent coupling of 1,3-dienes with pentafluorophenyl acetates	55
Genetically enabling phosphorus fluoride exchange click chemistry in proteins	54
Atomically dispersed Ni induced by ultrahigh N-doped carbon enables stable sodium storage	54
In my blue-light era	53
Challenges for photocatalytic overall water splitting	53
Palladium-catalyzed asymmetric hydrophosphination of internal alkynes: Atroposelective access to phosphine-functionalized olefins	52
Hydrophenazine-linked two-dimensional ladder-type crystalline fused aromatic network with high charge transport	52
The cyclotriborate trianion	52
DNA membrane nanopores with highly tunable shapes and sizes	52

Evidence for new enantiospecific interaction force in chiral biomolecules	52
Rethinking catalyst design by using data science	52
Biocatalytic activation of diazirines for carbene-transfer reactions	52
A 10-nm-sized multicompartment cuboctahedron and its 2D hierarchical arrays observed by cryo-EM	52
Operando scattering techniques for detecting precipitation reactions in lithium-sulfur batteries	52
Bioengineering of syrbactin megasynthetases for immunoproteasome inhibitor production	51
Interplay between remote single-atom active sites triggers speedy catalytic oxidation	51
Boosting single-molecule magnet performance	51
Information transduction via fuel-controlled chemical waves	51
Does in-situ-generated H2O2 promote important industrial reactions?	50
A sustainable cobalt separation with validation by techno-economic analysis and life-cycle assessment	50
Electrophilic selenium drives electron leakage	50
Remotely controllable supramolecular rotor mounted inside a porphyrinic cage	50
Supramolecular self-assembly of dinuclear alkynylplatinum(II) complexes into highly ordered crystalline hexagonal bipyramid superstructures	50
Versatile deacylative cross-coupling of aromatic ketones	50
In this issue	49
Engineering biotic-abiotic hybrid systems for solar-to-chemical conversion	49
Ligand-enabled stereodivergence in nickel-catalyzed regioselective hydroboration of internal allenes	49
Reaction: A three-pronged approach toward a sustainable chemical industry	49
Single-molecule spectroscopic probing of N-heterocyclic carbenes on a two-dimensional metal	49
Role of delocalized electrons on the doping effect in vanadia	49
Zero-valent species of group 13–15 elements	49
Two (AgI3I)4L4 cages elucidate the rules for silver-cluster vertex design	48
Indocyanine polymethine fluorophores with extended π-conjugation emitting beyond 1,200 nm for enhanced NIR-II imaging	48
Van der Waals organic/inorganic heterostructures in the two-dimensional limit	48
Tailoring dynamic hydrogels by controlling associative exchange rates	47
Bulk depolymerization of poly(methyl methacrylate) via chain-end initiation for catalyst-free reversion to monomer	47
Supramolecular repair of hydration lubrication surfaces	47
Dicobalt-catalyzed N=N coupling reactions of tertiary alkyl azides to form azoalkanes	47
Molecular design of covalent organic frameworks for seawater desalination: A state-of-the-art review	46
Electrolyte engineering for highly inorganic solid electrolyte interphase in high-performance lithium metal batteries	46
Surface and interface control of black phosphorus	46
Tumor microenvironment-tailored nanoplatform for companion diagnostic applications of precise cancer therapy	46
Phosphorus fluoride exchange: Multidimensional catalytic click chemistry from phosphorus connective hubs	46
Ribosomal pentapeptide nitration for non-ribosomal peptide antibiotic precursor biosynthesis	46
Terpenoid-based high-performance polyester with tacticity-independent crystallinity and chemical circularity	46
Applications of molecularly imprinted polymers and perspectives for their use as food quality trackers	46
4-Pyridyl perfluoroalkyl sulfide as a practical nucleophilic perfluoroalkylation reagent	46
Reaction: Navigating the promises and perils of AI-powered drug synthesis	45
Controlled radical depolymerization: Structural differentiation and molecular weight control	45
Carbon nitride of five-membered rings with low optical bandgap for photoelectrochemical biosensing	45
Mucin-mimetic glycan arrays integrating machine learning for analyzing receptor pattern recognition by influenza A viruses	45
Biosynthesis and genetic encoding of activated nitriles for fast protein conjugation and tunable fluorogenic labeling	45
Championing systems thinking to create a circular economy of chemicals	45
A single-crystalline 2D polymer network mechanically interlocked by [c2]daisy chains	45
Triazasupersumanenes: Bowl-shaped nanographenes with tunable properties and unexpected charge transport performance	44
Catalytic and selective chemical recycling of post-consumer rubbers into cycloalkenes	44
Perovskite intermediate phases fundamentally address the urgent stability issue	44
Chlorine-free synthesis of axially chiral organophosphorus compounds from white phosphorus	43
Cancer nanomedicine: Concepts, promises, and challenges	43
Divergent synthesis of conidiogenones B–F and 12β-hydroxyconidiogenone C	43
Accelerating PERx reaction enables covalent nanobodies for potent neutralization of SARS-CoV-2 and variants	43
Nanocomposite DNA hydrogels emerging as programmable and bioinstructive materials systems	43
Visible-light-induced coupling of carboxylic acids with alcohols/amines via a phosphorous linchpin strategy	43
Uncovering strong π-metal interactions on Ag and Au nanosurfaces under ambient conditions via in-situ surface-enhanced Raman spectroscopy	42
New insights and discoveries in anion receptor chemistry	42
Tetragonal gyroid structure from symmetry manipulation: A brand-new member of the gyroid surface family	42
Non-covalent interactions of graphene surface: Mechanisms and applications	42
Synthesizing a nanographyne	42
An angstrom-level d-spacing control of graphite oxide using organofillers for high-rate lithium storage	42
Elucidating non-radiative decay in near-infrared lumiphores: Leveraging new design principles to develop a telecom band organic dye laser	42
Selective hydrogenation catalysis enabled by nanoscale galvanic reactions	42
Iron-mediated modular decarboxylative cross-nucleophile coupling	42
The Co/NbN interphase as an effective ammonia synthesis catalyst	41
Selection of assembly complexity in a space of tetrapeptides	41
Communication between active sites regulates heterogeneous catalysis	41
Interfacial water regulation for water-participating electrocatalytic hydrogenation reactions	41
Depositing atom by atom: Pt–Ru–Co triple-atom catalysts	41
The subtle art of radical control	41
Versatile selective-absorber-based photothermocatalytic reactor for solar fuel synthesis	41
Photoinduced, ground-state charge-transfer complex	41
Porous organic polymers with heterocyclic crown ethers for selective lithium-ion capture	41
The sustainability potential of single-atom catalysts in chemical process	41
A molecular communication channel consisting of a single reversible chain of hydrogen bonds in a conformationally flexible oligomer	41
In This Issue	41
Connecting single-nucleotide polymorphisms, glycosylation status, and interactions of plasma serine protease inhibitors	40
Reaction: The challenge of open-shell transition metal catalysis in “systems chemistry”	40
Deciphering the rational design of the early transition metals for ammonia synthesis	40
Integrating two contrasting biosynthetic pathways for peptide natural products	40
BINOLates as potent reducing photocatalysts for inert-bond activation and reduction of unsaturated systems	40
Circumventing the activity-selectivity trade-off: Pt-Fe-Pt active sites for selective heterogeneous hydrogenation of crotonaldehyde	40
Finding sustainable solutions	40
Osmium atomic sites on CuS nanoplates for efficient two-electron oxygen reduction into H2O2	39
Dynamic active sites behind Cu-based electrocatalysts: Original or restructuring-induced catalytic activity	39
Self-activated energy release cascade from anthracene-based solid-state molecular solar thermal energy storage systems	39
Electrochemical 6Li isotope enrichment based on selective insertion in 1D tunnel-structured V2O5	39
3D-printing technologies for C1 chemistry	39
Chiral inorganic nanomaterials for biomedical applications	39
New light on proton transfer: Spectral and kinetic signature of a transient Eigen complex	39
Programmable reconfiguration of one-dimensional supramolecular polymers into multidimensional topological nanostructures	39
Design of metal-organic framework catalysts for photocatalytic hydrogen peroxide production	38
An ultra-dynamic anion-cluster-based organic framework	38
Reversible topochemical polymerization and depolymerization of a crystalline 3D porous organic polymer with C–C bond linkages	38
Fluoride up- and down-regulates guest encapsulation for ZnII6L4 and ZnII4L4 cages	38
Selective and stable upgrading of biomass-derived furans into plastic monomers by coupling homogeneous and heterogeneous catalysis	38