Chem

Article	Citations
Challenges for photocatalytic overall water splitting	455
Activity Origins and Design Principles of Nickel-Based Catalysts for Nucleophile Electrooxidation	419
Catalytic processing of plastic waste on the rise	303
Electrochemical ammonia synthesis: Mechanistic understanding and catalyst design	292
Identification of the Electronic and Structural Dynamics of Catalytic Centers in Single-Fe-Atom Material	281
Coordination Number Regulation of Molybdenum Single-Atom Nanozyme Peroxidase-like Specificity	259
Persistent and Stable Organic Radicals: Design, Synthesis, and Applications	251
A nitrogen-rich covalent organic framework for simultaneous dynamic capture of iodine and methyl iodide	247
Porous materials for hydrogen storage	233
Electrochemical Synthesis of H2O2 by Two-Electron Water Oxidation Reaction	217
Atropisomers beyond the C–C axial chirality: Advances in catalytic asymmetric synthesis	210
Redox Comediation with Organopolysulfides in Working Lithium-Sulfur Batteries	199
Advances in ammonia electrosynthesis from ambient nitrate/nitrite reduction	194
Critical effects of electrolyte recipes for Li and Na metal batteries	193
Homogeneous manganese-catalyzed hydrogenation and dehydrogenation reactions	173
Integration of Pd nanoparticles with engineered pore walls in MOFs for enhanced catalysis	171
Hydrogen-bonded organic frameworks: Chemistry and functions	170
Advances in higher alcohol synthesis from CO2 hydrogenation	168
Recent advances in carbon dioxide hydrogenation to produce olefins and aromatics	164
Constructing FeN4/graphitic nitrogen atomic interface for high-efficiency electrochemical CO2 reduction over a broad potential window	161
Main-group elements boost electrochemical nitrogen fixation	160
Covalent-Organic-Framework-Based Composite Materials	152
Propane Dehydrogenation on Single-Site [PtZn4] Intermetallic Catalysts	151
Open-Shell Graphene Fragments	147
Designing highly active nanoporous carbon H2O2 production electrocatalysts through active site identification	141

An analysis of the electrochemical mechanism of manganese oxides in aqueous zinc batteries	139
Pollutant removal with organic macrocycle-based covalent organic polymers and frameworks	136
Electrochemical CO2 reduction in membrane-electrode assemblies	136
Dissipative Self-Assembly: Fueling with Chemicals versus Light	133
Selectivity Control in Photocatalytic Valorization of Biomass-Derived Platform Compounds by Surface Engineering of Titanium Oxide	133
2D/3D perovskite engineering eliminates interfacial recombination losses in hybrid perovskite solar cells	128
Tuning the spin state of Fe single atoms by Pd nanoclusters enables robust oxygen reduction with dissociative pathway	128
Transition-metal-catalyzed C–H allylation reactions	113
Rational design and atroposelective synthesis of N–N axially chiral compounds	113
Hybrid monomer design for unifying conflicting polymerizability, recyclability, and performance properties	109
The concept and examples of type-III photosensitizers for cancer photodynamic therapy	109
Designer DNA nanostructures for therapeutics	109
Li-ion battery recycling challenges	109
Design principles for intrinsically circular polymers with tunable properties	108
Visible-light photoredox-catalyzed selective carboxylation of C(sp3)−F bonds with CO2	107
Protein-directed, hydrogen-bonded biohybrid framework	106
Emergent behavior in nanoconfined molecular containers	106
Forging C−heteroatom bonds by transition-metal-catalyzed enantioselective C–H functionalization	105
Nanoscale CaH2 materials for synergistic hydrogen-immune cancer therapy	105
Strategies for Pore Engineering in Zirconium Metal-Organic Frameworks	104
Programmable synthesis of radially gradient-structured mesoporous carbon nanospheres with tunable core-shell architectures	102
Selective, Catalytic Oxidations of C–H Bonds in Polyethylenes Produce Functional Materials with Enhanced Adhesion	100
An encapsulating lithium-polysulfide electrolyte for practical lithium–sulfur batteries	98
Ultra-dense carbon defects as highly active sites for oxygen reduction catalysis	98
Fast, reversible mechanochromism of regioisomeric oxazine mechanophores: Developing in situ responsive force probes for polymeric materials	98
Endohedral functionalization of chiral metal-organic cages for encapsulating achiral dyes to induce circularly polarized luminescence	98
In situ formation of polymer-inorganic solid-electrolyte interphase for stable polymeric solid-state lithium-metal batteries	95
Deciphering and modulating energetics of solvation structure enables aggressive high-voltage chemistry of Li metal batteries	94
Rechargeable anion-shuttle batteries for low-cost energy storage	93
Product-Specific Active Site Motifs of Cu for Electrochemical CO2 Reduction	93
Striding the threshold of an atom era of organic synthesis by single-atom catalysis	92
Catalytic strategies for upvaluing plastic wastes	92
Development of direct conversion of syngas to unsaturated hydrocarbons based on Fischer-Tropsch route	90
Progress in anion receptor chemistry	89
Atomically precise electrocatalysts for oxygen reduction reaction	88
Recent advances in radical chemistry proceeding through pro-aromatic radicals	88
Exceptionally active and stable RuO2 with interstitial carbon for water oxidation in acid	87
Unraveling the physical chemistry and materials science of CeO2-based nanostructures	86
Dynamic molecular weaving in a two-dimensional hydrogen-bonded organic framework	85
Anion chemistry enabled positive valence conversion to achieve a record high-voltage organic cathode for zinc batteries	85
Regulating liquid and solid-state electrolytes for solid-phase conversion in Li–S batteries	84
Size sensitivity of supported Ru catalysts for ammonia synthesis: From nanoparticles to subnanometric clusters and atomic clusters	83
The chemical states of conjugated coordination polymers	83
Design of metal-organic framework catalysts for photocatalytic hydrogen peroxide production	83
Atomically dispersed Ru oxide catalyst with lattice oxygen participation for efficient acidic water oxidation	83
Optical processes in carbon nanocolloids	83
Gigantic Porphyrinic Cages	82
Atomically dispersed Ni induced by ultrahigh N-doped carbon enables stable sodium storage	82
Oxygen-controlled photo-reforming of biopolyols to CO over Z-scheme CdS@g-C3N4	81
Dual key co-activated nanoplatform for switchable MRI monitoring accurate ferroptosis-based synergistic therapy	81

Indoor Surface Chemistry: Developing a Molecular Picture of Reactions on Indoor Interfaces	80
Breaking the trade-off between selectivity and adsorption capacity for gas separation	79
Selective Conversion of CO2 into Propene and Butene	78
Modern strategies for C–H functionalization of heteroarenes with alternative coupling partners	77
An axial-to-axial chirality transfer strategy for atroposelective construction of C–N axial chirality	77
Halogen-halogen bonds enable improved long-term operational stability of mixed-halide perovskite photovoltaics	77
Artificial transmembrane ion transporters as potential therapeutics	76
Water-involved methane-selective catalytic oxidation by dioxygen over copper zeolites	76
Electrolyte engineering for highly inorganic solid electrolyte interphase in high-performance lithium metal batteries	76
Creep-Enabled 3D Solid-State Lithium-Metal Battery	75
Theory-Guided Machine Learning Finds Geometric Structure-Property Relationships for Chemisorption on Subsurface Alloys	74
Confining Ti-oxo clusters in covalent organic framework micropores for photocatalytic reduction of the dominant uranium species in seawater	73
Stereodivergent total synthesis of rocaglaol initiated by synergistic dual-metal-catalyzed asymmetric allylation of benzofuran-3(2H)-one	73
Carbon nitride of five-membered rings with low optical bandgap for photoelectrochemical biosensing	73
When MOFs meet wood: From opportunities toward applications	72
Precise recognition of palladium through interlaminar chelation in a covalent organic framework	72
Design principle of electrocatalysts for the electrooxidation of organics	72
A relay catalysis strategy for enantioselective nickel-catalyzed migratory hydroarylation forming chiral α-aryl alkylboronates	71
Shale gas revolution: Catalytic conversion of C1–C3 light alkanes to value-added chemicals	71
Progress in carbon dioxide capture materials for deep decarbonization	71
Enhanced electroreduction of CO2 to C2+ products on heterostructured Cu/oxide electrodes	71
Tuning the gating energy barrier of metal-organic framework for molecular sieving	71
Porous Liquids: The Next Frontier	70
Anisotropic Microparticles from Microfluidics	67
Programmable ATP-Fueled DNA Coacervates by Transient Liquid-Liquid Phase Separation	67
Photo-induced thiolate catalytic activation of inert Caryl-hetero bonds for radical borylation	67
Single-atom engineering of metal-organic frameworks toward healthcare	64
A general N-alkylation platform via copper metallaphotoredox and silyl radical activation of alkyl halides	64
Revealing phase evolution mechanism for stabilizing formamidinium-based lead halide perovskites by a key intermediate phase	64
Partially reduced Pd single atoms on CdS nanorods enable photocatalytic reforming of ethanol into high value-added multicarbon compound	64
Recent advances in electrode engineering strategies for aqueous Zn-based batteries	63
Peptide Late-Stage Diversifications by Rhodium-Catalyzed Tryptophan C7 Amidation	63
Quantum dots enable direct alkylation and arylation of allylic C(sp3)–H bonds with hydrogen evolution by solar energy	63
Near-infrared photosensitization via direct triplet energy transfer from lanthanide nanoparticles	63
Perspectives for antimicrobial nanomaterials in cultural heritage conservation	63
Reversibly modulating a conformation-adaptive fluorophore in [2]catenane	62
Synergizing palladium with Lewis base catalysis for stereodivergent coupling of 1,3-dienes with pentafluorophenyl acetates	62
Nitrogenase inspired artificial photosynthetic nitrogen fixation	61
Synergy between β-Mo2C Nanorods and Non-thermal Plasma for Selective CO2 Reduction to CO	60
Visible-Light-Initiated Free-Radical Polymerization by Homomolecular Triplet-Triplet Annihilation	60
Electrochemical Aziridination of Internal Alkenes with Primary Amines	59
Establishing design principles for emissive organic SWIR chromophores from energy gap laws	59
Cationic lithium polysulfides in lithium–sulfur batteries	59
Rationally fabricating 3D porphyrinic covalent organic frameworks with scu topology as highly efficient photocatalysts	59
Rational design and synthesis of two-dimensional conjugated metal-organic polymers for electrocatalysis applications	58
An isolable, crystalline complex of square-planar silicon(IV)	58
Palladium-catalyzed asymmetric hydrophosphination of internal alkynes: Atroposelective access to phosphine-functionalized olefins	57
Sensors for In Situ Real-Time Fluorescence Imaging of Enzymes	57
Heterogeneous hydroformylation of alkenes by Rh-based catalysts	56
Guest-molecule-induced self-adaptive pore engineering facilitates purification of ethylene from ternary mixture	56
Mapping the Surface Groups of Amine-Rich Carbon Dots Enables Covalent Catalysis in Aqueous Media	55
Engineering couplings for exciton transport using synthetic DNA scaffolds	55
Catalytic carbon-carbon bond cleavage and carbon-element bond formation give new life for polyolefins as biodegradable surfactants	55
Controlling the shape and chirality of an eight-crossing molecular knot	54
Synthesis of amino acids by electrocatalytic reduction of CO2 on chiral Cu surfaces	54
Unlocking the Friedel-Crafts arylation of primary aliphatic alcohols and epoxides driven by hexafluoroisopropanol	54
Fe binuclear sites convert methane to acetic acid with ultrahigh selectivity	54
Dual-Active-Sites Design of Co@C Catalysts for Ultrahigh Selective Hydrogenation of N-Heteroarenes	54
Asymmetric radical cyclopropanation of dehydroaminocarboxylates: Stereoselective synthesis of cyclopropyl α-amino acids	54
A Robust Titanium Isophthalate Metal-Organic Framework for Visible-Light Photocatalytic CO2 Methanation	53
Observation of a potential-dependent switch of water-oxidation mechanism on Co-oxide-based catalysts	53
Palladium/Xu-Phos-catalyzed enantioselective cascade Heck/remote C(sp2) –H alkylation reaction	53
Exceptional electron conduction in two-dimensional covalent organic frameworks	53
Reversible isomerization of metal nanoclusters induced by intermolecular interaction	53
Rationalizing the design and implementation of chiral hybrid perovskites	53
Carbohydrate amphiphiles for supramolecular biomaterials: Design, self-assembly, and applications	53
Aerobic Oxidative Cleavage and Esterification of C(OH)–C Bonds	52
Interface of biomolecular condensates modulates redox reactions	52
In This Issue	51
Integrated strategy for the synthesis of aromatic building blocks via upcycling of real-life plastic wastes	50
Reactivity of an air-stable dihydrobenzoimidazole n-dopant with organic semiconductor molecules	50
The road to industrialization of fine chemical carboxylation reactions	50
Weak bonding strategies for achieving regio- and site-selective transformations	50
Active learning accelerates ab initio molecular dynamics on reactive energy surfaces	50
High-yield exfoliation of 2D semiconductor monolayers and reassembly of organic/inorganic artificial superlattices	50
Non-covalent interactions of graphene surface: Mechanisms and applications	50
Protein stabilization and refolding in a gigantic self-assembled cage	49
A “universal” catalyst for aerobic oxidations to synthesize (hetero)aromatic aldehydes, ketones, esters, acids, nitriles, and amides	49
An integrated solid-state lithium-oxygen battery with highly stable anionic covalent organic frameworks electrolyte	49
TADF molecules with π-extended acceptors for simplified high-efficiency blue and white organic light-emitting diodes	49

A see-through electrochromic display via dynamic metal-ligand interactions	48
Transition to sustainable chemistry through digitalization	48
Computer-aided design of RNA-targeted small molecules: A growing need in drug discovery	48
In situ monitoring of mechanochemical covalent organic framework formation reveals templating effect of liquid additive	47
Dynamic optimization of guest binding in a library of diastereomeric heteroleptic coordination cages	47
Aza-heterocycles via copper-catalyzed, remote C–H desaturation of amines	47
Quantifying Electrocatalytic Reduction of CO2 on Twin Boundaries	47
Organometallic lanthanide bismuth cluster single-molecule magnets	47
Sulfondiimidamides as new functional groups for synthetic and medicinal chemistry	47
A base-controlled switch of SO2 reincorporation in photocatalyzed radical difunctionalization of alkenes	47
Stereospecific and stereoconvergent nucleophilic substitution reactions at tertiary carbon centers	47
Bulk depolymerization of poly(methyl methacrylate) via chain-end initiation for catalyst-free reversion to monomer	47
Wettability of graphene and interfacial water structure	47
Metal-organic-framework-based materials as platforms for energy applications	47
Long carrier diffusion length in two-dimensional lead halide perovskite single crystals	46
In This Issue	46
Supramolecular Purification and Regioselective Functionalization of Fullerenes and Endohedral Metallofullerenes	46
Aqueous rechargeable zinc air batteries operated at −110°C	46
EDA photochemistry: Mechanistic investigations and future opportunities	45
Small amines bring big benefits to perovskite-based solar cells and light-emitting diodes	45
Hydrogen-bond activation of N2 molecules and photocatalytic nitrogen fixation	45
Porous polyisothiocyanurates for selective palladium recovery and heterogeneous catalysis	45
On-the-fly interpretable machine learning for rapid discovery of two-dimensional ferromagnets with high Curie temperature	44
One-Dimensional Segregated Single Au Sites on Step-Rich ZnO Ladder for Ultrasensitive NO2 Sensors	44
Mass Photometry of Membrane Proteins	44
Carbon-centered radical capture at nickel(II) complexes: Spectroscopic evidence, rates, and selectivity	44
Synthesis of C-glycosides by Ti-catalyzed stereoselective glycosyl radical functionalization	43
Peptide self-assembly through liquid-liquid phase separation	43
Phenanthrenequinone-like moiety functionalized carbon for electrocatalytic acidic oxygen evolution	43
Stabilizing lattice oxygen in slightly Li-enriched nickel oxide cathodes toward high-energy batteries	43
Liquid fuel synthesis via CO2 hydrogenation by coupling homogeneous and heterogeneous catalysis	43
Titanium radical redox catalysis: Recent innovations in catalysts, reactions, and modes of activation	42
Surface lattice engineering through three-dimensional lead iodide perovskitoid for high-performance perovskite solar cells	42
Field-induced oscillation of magnetization blocking barrier in a holmium metallacrown single-molecule magnet	42
Reaction: Semiconducting MOFs Offer New Strategy for Uranium Extraction from Seawater	42
Highly effective conversion of CO2 into light olefins abundant in ethene	42
Surface and interface control of black phosphorus	41
Synthesis of wafer-scale ultrathin graphdiyne for flexible optoelectronic memory with over 256 storage levels	41
Asymmetrically coordinated cobalt single atom on carbon nitride for highly selective photocatalytic oxidation of CH4 to CH3OH	41
New rhodamines with changeable π-conjugation for lengthening fluorescence wavelengths and imaging peroxynitrite	41
Unveiling the synergistic effect of multi-valence Cu species to promote formaldehyde oxidation for anodic hydrogen production	40
Impact of novel detergents on membrane protein studies	40
Three-component enantioselective alkenylation of organophosphonates via nickel metallaphotoredox catalysis	40
Design and Applications of Single-Component Radical Conductors	39
Generative design of de novo proteins based on secondary-structure constraints using an attention-based diffusion model	39
Large-area self-standing thin film of porous hydrogen-bonded organic framework for efficient uranium extraction from seawater	39
An angstrom-level d-spacing control of graphite oxide using organofillers for high-rate lithium storage	39
Iridium boosts the selectivity and stability of cobalt catalysts for syngas to liquid fuels	39
A unified topology approach to dot-, rod-, and sheet-MOFs	38
Kinetic trapping of 3D-printable cyclodextrin-based poly(pseudo)rotaxane networks	38
Heterometallic Titanium-Organic Frameworks as Dual-Metal Catalysts for Synergistic Non-buffered Hydrolysis of Nerve Agent Simulants	38
Catalyst: Uranium Extraction from Seawater, a Paradigm Shift in Resource Recovery	38
Nickel-catalyzed site- and stereoselective reductive alkylalkynylation of alkynes	37
Controlling dynamic reconstruction chemistry for superior oxygen-evolving catalysts	37
Dynamic restructuring of epitaxial Au–Cu biphasic interface for tandem CO2-to-C2+ alcohol conversion	37
In this issue	37
Direct upcycling of mixed Ni-lean polycrystals to single-crystal Ni-rich cathode materials	37
Catalyst: Challenges in development of adsorbents for recovery of uranium from seawater	37
Twisted pentagonal prisms: AgnL2 metal-organic pillars	37
Dynamic organic room-temperature phosphorescent systems	37
Recent updates and future perspectives in aziridine synthesis and reactivity	36
Low-temperature aerobic oxidation of thiophenic sulfides over atomic Mo hosted by cobalt hydroxide sub-nanometer sheets	36
Real-time observation of the dynamics of an individual rotaxane molecular shuttle using a single-molecule junction	36
Atomic-level insights into the activation of nitrogen via hydrogen-bond interaction toward nitrogen photofixation	36
Control of the pore chemistry in metal-organic frameworks for efficient adsorption of benzene and separation of benzene/cyclohexane	35
Metalloradical activation of carbonyl azides for enantioselective radical aziridination	35
Detachable all-carbon-linked 3D covalent organic framework films for semiconductor/COF heterojunctions by continuous flow synthesis	35
Alignment of linear polymeric grains for highly stable N-type thin-film transistors	35
Superfast desulfurization for protein chemical synthesis and modification	35
A “nucleophilic” iodine in a halogen-bonded iodonium complex manifests an unprecedented I+···Ag+ interaction	35
Selective functionalization of benzylic C(sp3)–H bonds to synthesize complex molecules	34
Block copolymer self-assembly: Polydisperse corona-forming blocks leading to uniform morphologies	33
Supramolecular triangular orthobicupola: Self-assembly of a giant Johnson solid J27	33
How computations accelerate electrocatalyst discovery	33
Charging processes in lithium-oxygen batteries unraveled through the lens of the distribution of relaxation times	33
The mechanical bond in biological systems	33
Precise Spatial Arrangement and Interaction between Two Different Mobile Components in a Metal-Organic Framework	33
Topological Strain-Induced Regioselective Linker Elimination in a Chiral Zr(IV)-Based Metal-Organic Framework	32
The impact of alkali and alkaline earth metals on green ammonia synthesis	32
Tailoring chirality and porosity in metal-organic frameworks for efficient enantioselective recognition	32
Methane activation by a borenium complex	32
Interstellar Formation of Biorelevant Pyruvic Acid (CH3COCOOH)	32
Ni-catalyzed enantioselective [2 + 2 + 2] cycloaddition of malononitriles with alkynes	32
Diarylation of N- and O-nucleophiles through a metal-free cascade reaction	32
Selective and stable upgrading of biomass-derived furans into plastic monomers by coupling homogeneous and heterogeneous catalysis	32
A homogeneous high-throughput array for the detection and discrimination of influenza A viruses	32
Constructing matched active sites for robust photocatalytic dry reforming of methane	32
Isolated metal atoms and clusters for alkane activation: Translating knowledge from enzymatic and homogeneous to heterogeneous systems	31
Copper lattice tension boosts full-cell CO electrolysis to multi-carbon olefins and oxygenates	31
Iron-mediated modular decarboxylative cross-nucleophile coupling	31
Molecular-strain engineering of double-walled tetrahedra	31
The first carbon-carbon bond formation mechanism in methanol-to-hydrocarbons process over chabazite zeolite	31
Radical Cyclic [3]Daisy Chains	31
Lasing of carbon dots: Chemical design, mechanisms, and bright future	31
Multi-stimuli-engendered radical-anionic MOFs: Visualization of structural transformation upon radical formation	31