Chem

Papers
(The median citation count of Chem is 8. The table below lists those papers that are above that threshold based on CrossRef citation counts [max. 250 papers]. The publications cover those that have been published in the past four years, i.e., from 2020-02-01 to 2024-02-01.)
ArticleCitations
S-Scheme Heterojunction Photocatalyst1905
Microporous Metal-Organic Framework Materials for Gas Separation507
Enabling Direct H2O2 Production in Acidic Media through Rational Design of Transition Metal Single Atom Catalyst405
Challenges for photocatalytic overall water splitting303
Recent Developments and Future Challenges in Controlled Radical Polymerization: A 2020 Update300
Triplet Energy Transfer Photocatalysis: Unlocking the Next Level294
Activity Origins and Design Principles of Nickel-Based Catalysts for Nucleophile Electrooxidation291
All-Solid-State Z-Scheme α-Fe2O3/Amine-RGO/CsPbBr3 Hybrids for Visible-Light-Driven Photocatalytic CO2 Reduction270
2D Ti3C2Tz MXene Synthesized by Water-free Etching of Ti3AlC2 in Polar Organic Solvents266
Organic-Inorganic-Induced Polymer Intercalation into Layered Composites for Aqueous Zinc-Ion Battery265
Powering the Future: How Can Electrochemistry Make a Difference in Organic Synthesis?259
Electrochemical ammonia synthesis: Mechanistic understanding and catalyst design234
High-Performance n-Type Polymer Semiconductors: Applications, Recent Development, and Challenges225
Identification of the Electronic and Structural Dynamics of Catalytic Centers in Single-Fe-Atom Material223
Catalytic processing of plastic waste on the rise217
Accelerated Dinitrogen Electroreduction to Ammonia via Interfacial Polarization Triggered by Single-Atom Protrusions214
Coordination Number Regulation of Molybdenum Single-Atom Nanozyme Peroxidase-like Specificity209
Synthesis of CaCO3-Based Nanomedicine for Enhanced Sonodynamic Therapy via Amplification of Tumor Oxidative Stress194
A nitrogen-rich covalent organic framework for simultaneous dynamic capture of iodine and methyl iodide188
Persistent and Stable Organic Radicals: Design, Synthesis, and Applications175
Developments in Photoredox/Nickel Dual-Catalyzed 1,2-Difunctionalizations171
Late-Stage Functionalization170
Redox Comediation with Organopolysulfides in Working Lithium-Sulfur Batteries169
A Realistic Methodology for 30% Efficient Perovskite Solar Cells157
The Design of Dissipative Molecular Assemblies Driven by Chemical Reaction Cycles155
Molten Salt-Directed Catalytic Synthesis of 2D Layered Transition-Metal Nitrides for Efficient Hydrogen Evolution155
Exploring and Understanding the Roles of Li2Sn and the Strategies to beyond Present Li-S Batteries148
Catalysis for Selected C1 Chemistry145
A Structure-Based Platform for Predicting Chemical Reactivity143
Reducing Voltage Losses in the A-DA′D-A Acceptor-Based Organic Solar Cells143
Light-free Generation of Singlet Oxygen through Manganese-Thiophene Nanosystems for pH-Responsive Chemiluminescence Imaging and Tumor Therapy142
Electrochemical Synthesis of H2O2 by Two-Electron Water Oxidation Reaction141
Integration of Pd nanoparticles with engineered pore walls in MOFs for enhanced catalysis140
Atropisomers beyond the C–C axial chirality: Advances in catalytic asymmetric synthesis139
Unconventional Mn Vacancies in Mn–Fe Prussian Blue Analogs: Suppressing Jahn-Teller Distortion for Ultrastable Sodium Storage137
Highly Selective Hydrogen Peroxide Electrosynthesis on Carbon: In Situ Interface Engineering with Surfactants133
Atroposelective Synthesis of Axially Chiral Styrenes via an Asymmetric C–H Functionalization Strategy132
Open-Shell Graphene Fragments131
Porous materials for hydrogen storage130
Quasi-Solid-State Dual-Ion Sodium Metal Batteries for Low-Cost Energy Storage130
Homogeneous manganese-catalyzed hydrogenation and dehydrogenation reactions130
Critical effects of electrolyte recipes for Li and Na metal batteries129
Fluorescent Imaging of Reactive Oxygen and Nitrogen Species Associated with Pathophysiological Processes126
Constructing FeN4/graphitic nitrogen atomic interface for high-efficiency electrochemical CO2 reduction over a broad potential window123
CO2 Hydrogenation to Ethanol over Cu@Na-Beta122
Direct Conversion of Syngas to Ethanol within Zeolite Crystals121
Dynamic Covalent Synthesis of Crystalline Porous Graphitic Frameworks120
Tailoring Polymer Dispersity by RAFT Polymerization: A Versatile Approach120
Covalent-Organic-Framework-Based Composite Materials120
Outlook on K-Ion Batteries120
Plug-and-Play Optical Materials from Fluorescent Dyes and Macrocycles119
Advances in higher alcohol synthesis from CO2 hydrogenation116
Recent advances in carbon dioxide hydrogenation to produce olefins and aromatics114
Ion-Solvent Chemistry-Inspired Cation-Additive Strategy to Stabilize Electrolytes for Sodium-Metal Batteries114
Main-group elements boost electrochemical nitrogen fixation113
Selectivity Control in Photocatalytic Valorization of Biomass-Derived Platform Compounds by Surface Engineering of Titanium Oxide111
Geminal Dimethyl Substitution Enables Controlled Polymerization of Penicillamine-Derived β-Thiolactones and Reversed Depolymerization111
A Directional Synthesis for Topological Defect in Carbon111
Strong Evidence of the Role of H2O in Affecting Methanol Selectivity from CO2 Hydrogenation over Cu-ZnO-ZrO2110
Catalysis, FLPs, and Beyond109
Synthesis of a Mechanically Planar Chiral Rotaxane Ligand for Enantioselective Catalysis109
Perovskite Solution Aging: What Happened and How to Inhibit?107
Propane Dehydrogenation on Single-Site [PtZn4] Intermetallic Catalysts106
Designing highly active nanoporous carbon H2O2 production electrocatalysts through active site identification105
Shaping Molecular Landscapes: Recent Advances, Opportunities, and Challenges in Dearomatization105
Dissipative Self-Assembly: Fueling with Chemicals versus Light105
Pollutant removal with organic macrocycle-based covalent organic polymers and frameworks105
Hydrogen-bonded organic frameworks: Chemistry and functions102
2D/3D perovskite engineering eliminates interfacial recombination losses in hybrid perovskite solar cells101
Constructing an Ion Pathway for Uranium Extraction from Seawater101
Enhancing Magnetic Hysteresis in Single-Molecule Magnets by Ligand Functionalization100
Radiation Controllable Synthesis of Robust Covalent Organic Framework Conjugates for Efficient Dynamic Column Extraction of 99TcO4−100
Extremely Stable Anthraquinone Negolytes Synthesized from Common Precursors98
Reaction: Rational Design of Highly Active Photocatalysts for CO2 Conversion96
Covalent Organic Frameworks: An Amazing Chemistry Platform for Designing Polymers96
Transition-metal-catalyzed C–H allylation reactions95
Nickel-Catalyzed C−H Functionalization Using A Non-directed Strategy95
Chemistry and Biology of SARS-CoV-293
Digital Reticular Chemistry92
Two-Dimensional Nanomaterials with Unconventional Phases92
Emergent behavior in nanoconfined molecular containers92
Porous Ligand Creates New Reaction Route: Bifunctional Single-Atom Palladium Catalyst for Selective Distannylation of Terminal Alkynes91
Forging C−heteroatom bonds by transition-metal-catalyzed enantioselective C–H functionalization89
An analysis of the electrochemical mechanism of manganese oxides in aqueous zinc batteries86
Strategies for Pore Engineering in Zirconium Metal-Organic Frameworks86
Designer DNA nanostructures for therapeutics85
Prospects and Challenges in Anion Recognition and Transport85
Broadly Applicable Directed Catalytic Reductive Difunctionalization of Alkenyl Carbonyl Compounds85
Boosting Electrocatalytic Ammonia Production through Mimicking “π Back-Donation”85
Visible-light photoredox-catalyzed selective carboxylation of C(sp3)−F bonds with CO284
DFT-Guided Phosphoric-Acid-Catalyzed Atroposelective Arene Functionalization of Nitrosonaphthalene82
Tuning Polarity of Cu-O Bond in Heterogeneous Cu Catalyst to Promote Additive-free Hydroboration of Alkynes82
Rational design and atroposelective synthesis of N–N axially chiral compounds82
Recent Advances in Using Transition-Metal-Catalyzed C–H Functionalization to Build Fluorescent Materials81
Protein-directed, hydrogen-bonded biohybrid framework81
Surface Chemistry Can Unlock Drivers of Surface Stability of SARS-CoV-2 in a Variety of Environmental Conditions79
Hybrid monomer design for unifying conflicting polymerizability, recyclability, and performance properties79
Hydrazones as New Molecular Tools78
Fast, reversible mechanochromism of regioisomeric oxazine mechanophores: Developing in situ responsive force probes for polymeric materials77
Light-Promoted Bromine-Radical-Mediated Selective Alkylation and Amination of Unactivated C(sp3)–H Bonds77
Encapsulated Nanodroplet Crystallization of Organic-Soluble Small Molecules77
Atomically dispersed Ni induced by ultrahigh N-doped carbon enables stable sodium storage76
Li-ion battery recycling challenges76
Electrochemical CO2 reduction in membrane-electrode assemblies75
Programmable synthesis of radially gradient-structured mesoporous carbon nanospheres with tunable core-shell architectures74
Confinement as a Unifying Element in Selective Catalysis73
Redox-Neutral Photocatalytic C−H Carboxylation of Arenes and Styrenes with CO273
Design principles for intrinsically circular polymers with tunable properties73
Magnetic-Field-Regulated TiO2 {100} Facets: A Strategy for C-C Coupling in CO2 Photocatalytic Conversion73
Selective, Catalytic Oxidations of C–H Bonds in Polyethylenes Produce Functional Materials with Enhanced Adhesion72
An encapsulating lithium-polysulfide electrolyte for practical lithium–sulfur batteries72
Neutrophil-Membrane-Directed Bioorthogonal Synthesis of Inflammation-Targeting Chiral Drugs71
Hierarchical Defect Engineering for LiCoO2 through Low-Solubility Trace Element Doping71
Endohedral functionalization of chiral metal-organic cages for encapsulating achiral dyes to induce circularly polarized luminescence71
Radical 1,3-Difunctionalization of Allylboronic Esters with Concomitant 1,2-Boron Shift71
Optical processes in carbon nanocolloids70
The concept and examples of type-III photosensitizers for cancer photodynamic therapy69
Borane-Catalyzed Stereoselective C–H Insertion, Cyclopropanation, and Ring-Opening Reactions69
Striding the threshold of an atom era of organic synthesis by single-atom catalysis69
Recent advances in radical chemistry proceeding through pro-aromatic radicals68
The chemical states of conjugated coordination polymers68
Catalytic Decarboxylative Radical Sulfonylation68
Stable Carbenes, Nitrenes, Phosphinidenes, and Borylenes: Past and Future68
Product-Specific Active Site Motifs of Cu for Electrochemical CO2 Reduction67
Hybrid Nanostructures from the Self-Assembly of Proteins and DNA67
Advances in ammonia electrosynthesis from ambient nitrate/nitrite reduction67
In situ formation of polymer-inorganic solid-electrolyte interphase for stable polymeric solid-state lithium-metal batteries67
Nanoscale CaH2 materials for synergistic hydrogen-immune cancer therapy67
Pumps through the Ages66
Plasmon-Induced Interfacial Hot-Electron Transfer Directly Probed by Raman Spectroscopy66
Indoor Surface Chemistry: Developing a Molecular Picture of Reactions on Indoor Interfaces66
Dynamic molecular weaving in a two-dimensional hydrogen-bonded organic framework66
Freestanding Single-Atom-Layer Pd-Based Catalysts: Oriented Splitting of Energy Bands for Unique Stability and Activity66
Tuning the spin state of Fe single atoms by Pd nanoclusters enables robust oxygen reduction with dissociative pathway65
Rechargeable anion-shuttle batteries for low-cost energy storage65
Controlled Synthesis of PdII and PtII Supramolecular Copolymer with Sequential Multiblock and Amplified Phosphorescence64
Surpassing Robeson Upper Limit for CO2/N2 Separation with Fluorinated Carbon Molecular Sieve Membranes64
Breaking the trade-off between selectivity and adsorption capacity for gas separation64
Carbon nitride of five-membered rings with low optical bandgap for photoelectrochemical biosensing64
Cu Interstitials Enable Carriers and Dislocations for Thermoelectric Enhancements in n-PbTe0.75Se0.2564
Dual key co-activated nanoplatform for switchable MRI monitoring accurate ferroptosis-based synergistic therapy64
Gigantic Porphyrinic Cages64
Multi-scale Imaging of Solid-State Battery Interfaces: From Atomic Scale to Macroscopic Scale62
Water-involved methane-selective catalytic oxidation by dioxygen over copper zeolites62
Progress in anion receptor chemistry62
Modern strategies for C–H functionalization of heteroarenes with alternative coupling partners61
Topology Meets Reticular Chemistry for Chemical Separations: MOFs as a Case Study61
DNA Framework-Encoded Mineralization of Calcium Phosphate61
Unraveling the physical chemistry and materials science of CeO2-based nanostructures61
Theory-Guided Machine Learning Finds Geometric Structure-Property Relationships for Chemisorption on Subsurface Alloys60
Ultra-dense carbon defects as highly active sites for oxygen reduction catalysis59
Thermally Gated Bio-orthogonal Nanozymes with Supramolecularly Confined Porphyrin Catalysts for Antimicrobial Uses59
Anion chemistry enabled positive valence conversion to achieve a record high-voltage organic cathode for zinc batteries59
Strategies for the Synthesis of Enantiopure Mechanically Chiral Molecules58
Molecules in Confined Spaces: Reactivities and Possibilities in Cavitands58
Creep-Enabled 3D Solid-State Lithium-Metal Battery58
Selective Conversion of CO2 into Propene and Butene57
An axial-to-axial chirality transfer strategy for atroposelective construction of C–N axial chirality57
Interfacial Active Sites for CO2 Assisted Selective Cleavage of C–C/C–H Bonds in Ethane57
Shale gas revolution: Catalytic conversion of C1–C3 light alkanes to value-added chemicals57
Peptide Late-Stage Diversifications by Rhodium-Catalyzed Tryptophan C7 Amidation57
Quantum dots enable direct alkylation and arylation of allylic C(sp3)–H bonds with hydrogen evolution by solar energy56
Visible-Light-Induced Nickel-Catalyzed Cross-Coupling with Alkylzirconocenes from Unactivated Alkenes56
Molecular Configuration Fixation with C–H···F Hydrogen Bonding for Thermally Activated Delayed Fluorescence Acceleration56
Learning to Make Chemical Predictions: The Interplay of Feature Representation, Data, and Machine Learning Methods56
Development of direct conversion of syngas to unsaturated hydrocarbons based on Fischer-Tropsch route56
Oxygen-controlled photo-reforming of biopolyols to CO over Z-scheme CdS@g-C3N456
Regulating liquid and solid-state electrolytes for solid-phase conversion in Li–S batteries56
Confinement Self-Assembly of Metal-Organic Cages within Mesoporous Carbon for One-Pot Sequential Reactions55
Porous Liquids: The Next Frontier55
Programmable ATP-Fueled DNA Coacervates by Transient Liquid-Liquid Phase Separation54
Nanorobots: Machines Squeezed between Molecular Motors and Micromotors54
Insight into Single-Atom-Induced Unconventional Size Dependence over CeO2-Supported Pt Catalysts54
Bridging the Gap between Reality and Ideality of Graphdiyne: The Advances of Synthetic Methodology54
Size sensitivity of supported Ru catalysts for ammonia synthesis: From nanoparticles to subnanometric clusters and atomic clusters54
Engine-Trailer-Structured Nanotrucks for Efficient Nano-Bio Interactions and Bioimaging-Guided Drug Delivery54
Diastereo- and Enantioselective Catalytic Radical Oxysulfonylation of Alkenes in β,γ-Unsaturated Ketoximes54
Cu-Catalyzed Regio- and Stereodivergent Chemoselective sp/sp 1,3- and 1,4-Diborylations of CF3-Containing 1,3-Enynes54
Folding and Assembly of Metal-Linked Peptidic Nanostructures54
Partially reduced Pd single atoms on CdS nanorods enable photocatalytic reforming of ethanol into high value-added multicarbon compound54
Halogen-halogen bonds enable improved long-term operational stability of mixed-halide perovskite photovoltaics54
Photo-induced thiolate catalytic activation of inert Caryl-hetero bonds for radical borylation53
Single-atom engineering of metal-organic frameworks toward healthcare53
Anisotropic Microparticles from Microfluidics53
Tuning the gating energy barrier of metal-organic framework for molecular sieving53
A general N-alkylation platform via copper metallaphotoredox and silyl radical activation of alkyl halides53
A relay catalysis strategy for enantioselective nickel-catalyzed migratory hydroarylation forming chiral α-aryl alkylboronates53
Stereodivergent total synthesis of rocaglaol initiated by synergistic dual-metal-catalyzed asymmetric allylation of benzofuran-3(2H)-one52
Shape-Induced Selective Separation of Ortho-substituted Benzene Isomers Enabled by Cucurbit[7]uril Host Macrocycles51
When MOFs meet wood: From opportunities toward applications50
Precise recognition of palladium through interlaminar chelation in a covalent organic framework50
Progress in carbon dioxide capture materials for deep decarbonization49
Electrochemical Aziridination of Internal Alkenes with Primary Amines49
Visible-Light-Initiated Free-Radical Polymerization by Homomolecular Triplet-Triplet Annihilation49
An isolable, crystalline complex of square-planar silicon(IV)48
Enantioselective Ring-Closing C–H Amination of Urea Derivatives48
Revealing phase evolution mechanism for stabilizing formamidinium-based lead halide perovskites by a key intermediate phase48
Aerobic Oxidative Cleavage and Esterification of C(OH)–C Bonds48
Engineering couplings for exciton transport using synthetic DNA scaffolds48
Catalytic strategies for upvaluing plastic wastes47
Integrating the Mechanical Bond into Metal-Organic Frameworks47
Reversibly modulating a conformation-adaptive fluorophore in [2]catenane47
A Fluorinated Ionic Liquid-Based Activatable 19F MRI Platform Detects Biological Targets47
Synergy between β-Mo2C Nanorods and Non-thermal Plasma for Selective CO2 Reduction to CO47
Exceptionally active and stable RuO2 with interstitial carbon for water oxidation in acid47
Diindenoanthracene Diradicaloids Enable Rational, Incremental Tuning of Their Singlet-Triplet Energy Gaps46
Catalytic carbon-carbon bond cleavage and carbon-element bond formation give new life for polyolefins as biodegradable surfactants46
Dual-Active-Sites Design of Co@C Catalysts for Ultrahigh Selective Hydrogenation of N-Heteroarenes46
Controlling the shape and chirality of an eight-crossing molecular knot46
Perspectives for antimicrobial nanomaterials in cultural heritage conservation46
Site-Selective C–H Benzylation of Alkanes with N-Triftosylhydrazones Leading to Alkyl Aromatics46
Total Synthesis of Natural Products Containing a Bridgehead Double Bond46
Artificial transmembrane ion transporters as potential therapeutics46
Near-infrared photosensitization via direct triplet energy transfer from lanthanide nanoparticles45
Catalyst: Aggregation-Induced Emission—How Far Have We Come, and Where Are We Going Next?45
Sensors for In Situ Real-Time Fluorescence Imaging of Enzymes45
Synergizing palladium with Lewis base catalysis for stereodivergent coupling of 1,3-dienes with pentafluorophenyl acetates45
In This Issue45
Strain-Induced Corrosion Kinetics at Nanoscale Are Revealed in Liquid: Enabling Control of Corrosion Dynamics of Electrocatalysis45
Mapping the Surface Groups of Amine-Rich Carbon Dots Enables Covalent Catalysis in Aqueous Media45
Establishing design principles for emissive organic SWIR chromophores from energy gap laws45
Asymmetric radical cyclopropanation of dehydroaminocarboxylates: Stereoselective synthesis of cyclopropyl α-amino acids44
Design of metal-organic framework catalysts for photocatalytic hydrogen peroxide production44
Solution-Processable, Crystalline π-Conjugated Two-Dimensional Polymers with High Charge Carrier Mobility44
Enantioselective Copper-Catalyzed Trifluoromethylation of Benzylic Radicals via Ring Opening of Cyclopropanols43
Biology-Inspired Supramolecular Peptide Systems42
Dual Stimuli Switching: Interconverting Cationic and Radical Polymerizations with Electricity and Light42
Established and Emerging Computational Tools to Study Homogeneous Catalysis—From Quantum Mechanics to Machine Learning42
Identifying the Conformational Isomers of Single-Molecule Cyclohexane at Room Temperature41
Deciphering and modulating energetics of solvation structure enables aggressive high-voltage chemistry of Li metal batteries41
Observation of a potential-dependent switch of water-oxidation mechanism on Co-oxide-based catalysts41
Evaluating Solid-Electrolyte Interphases for Lithium and Lithium-free Anodes from Nanoindentation Features41
Design principle of electrocatalysts for the electrooxidation of organics41
Palladium-catalyzed asymmetric hydrophosphination of internal alkynes: Atroposelective access to phosphine-functionalized olefins40
A Robust Titanium Isophthalate Metal-Organic Framework for Visible-Light Photocatalytic CO2 Methanation40
Exceptional electron conduction in two-dimensional covalent organic frameworks40
Quantifying Electrocatalytic Reduction of CO2 on Twin Boundaries40
Carbohydrate amphiphiles for supramolecular biomaterials: Design, self-assembly, and applications39
Transition to sustainable chemistry through digitalization39
Palladium/Xu-Phos-catalyzed enantioselective cascade Heck/remote C(sp2) –H alkylation reaction39
Nitrogenase inspired artificial photosynthetic nitrogen fixation39
Reactivity of an air-stable dihydrobenzoimidazole n-dopant with organic semiconductor molecules39
Unlocking the Friedel-Crafts arylation of primary aliphatic alcohols and epoxides driven by hexafluoroisopropanol39
Active learning accelerates ab initio molecular dynamics on reactive energy surfaces38
A Bioinspired Multicomponent Catalytic System for Converting Carbon Dioxide into Methanol Autocatalytically38
Discovery of a Small Molecule Drug Candidate for Selective NKCC1 Inhibition in Brain Disorders38
Molecular Representation: Going Long on Fingerprints38
Redox Control of Charge Transport in Vertical Ferrocene Molecular Tunnel Junctions38
The road to industrialization of fine chemical carboxylation reactions38
Weak bonding strategies for achieving regio- and site-selective transformations38
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