Chem

Article	Citations
Lanthanide luminescence from supramolecular hydrogels consisting of bio-conjugated picolinic-acid-based guanosine quadruplexes	747
In this issue	445
Reaction: Harnessing reactive oxygen species (ROS) for water purification	387
Out-of-equilibrium chemical logic systems	354
From trash to treasure: Vanadium-catalyzed upcycling of non-biodegradable plastics	332
A Star of David [2]catenane of single handedness	288
Highly selective and efficient uranium recovery by size-sieving porous aromatic frameworks with rigidly functionalized windows	269
N-Heterocyclic carbene-derived second-period main-group radicals: Synthesis, fundamentals, and applications	259
A high-throughput workflow to analyze sequence-conformation relationships and explore hydrophobic patterning in disordered peptoids	248
Excited-state protonation and reduction enable the umpolung Birch reduction of naphthalenes	230
Spatially resolved cell tagging and surfaceome labeling via targeted photocatalytic decaging	223
Air-stable radical polycyclic aromatic hydrogen-bonded organic frameworks	214
Multi-omics profiling of a self-assembling bioactive hydrogel for immunomodulation and myogenesis in volumetric muscle loss	209
Nanocellulose: New horizons in organic chemistry and beyond	194
Probing enantioinduction in confined chiral spaces through asymmetric oxime reductions	189
An M60L60 metal-peptide capsid with a 60-crossing woven network	176
Nature-inspired synthetic oligourea foldamer channels allow water transport with high salt rejection	171
Quasicrystal approximants in isoreticular metal-organic frameworks via Cairo pentagonal tiling	169
2D covalent organic framework via catenation	168
Harnessing plastic depolymerization products to upcycle mixed waste into high-value chemicals	162
Variable nanosheets for highly efficient oxygen evolution reaction	157
Recent research progress of all-polymer solar cells based on PSMA-type polymer acceptors	153
B(C6F5)3-catalyzed selective C–H chalcogenation of arenes and heteroarenes	151
2D conjugated metal-organic framework as a proton-electron dual conductor	142
Experimentally modeling the emergence of prebiotically plausible phospholipid vesicles	138

Photoswitches and photochemical reactions for optically controlled phase transition and energy storage	138
Click chemistry in polymer science	135
Supramolecular boosted superexchange	132
Ion-dipole-interaction-manipulated bilateral interface chemistry for deep rechargeability and high redox activity of Zn-organic batteries	132
From G-protein-coupled receptors to solute carriers—mass spectrometry informs dynamics, function, and regulation	131
Observation of ultrafast electrons in pendant-embedded conducting two-dimensional polymers	130
Reaction: Don’t hate the player in chemical AI; hate the game	129
In This Issue	127
Switchable diversification of quaternary ammonium salts using photocatalysis	127
para-Selective C–H alkylation of aroyl chlorides through organic photoredox-catalyzed radical tele-substitution	126
In this issue	126
Molecular freaky Friday: Polarity reversal and resorcin[4]arenes as chloride receptors	126
An effective strategy to boost lattice-oxygen-mediated acidic oxygen evolution	125
Ionic surface propensity controls pH in nanopores	124
Structure-performance relationships for catalysis-driven molecular machinery	123
Swapping benches from chemistry PhD student to science advisor at law firm	123
Be your own star	117
Highly oxygenated organic molecules with high unsaturation formed upon photochemical aging of soot	117
Modular nucleic acid scaffolds for synthesizing monodisperse and sequence-encoded antibody oligomers	116
Breaking ampere-level current density limitations in multi-carbon products through crystal facet engineering	114
Oxygen reduction active site regulation enabled reverse photocurrent in photoelectrochemical sensing	114
Catalytic strategies for upvaluing plastic wastes	114
Redox-couple-assisted CO2 capture on solid-electrolyte reactor	113
Semiconducting ladder-type covalent organic frameworks	111
The beauty of low symmetry: Non-statistical assembly of [Pd2(LA)(LB)(LC)(LD)]4+ cages	109
Higher-order cycloadditions in the age of catalysis	106
Atom swap in triple bonds via nitrogen-deletion coupling with gem-diborylalkanes	105
Design of piezoelectric organic cage salts for energy harvesting	105
Time-resolved fluorescence imaging with color-changing, “turn-on/turn-on” AIE nanoparticles	104
Curved plane increases the d vacancy population of Pd for green production of cyclohexanone	104
Photo-assembling cyclic peptides for dynamic light-driven peptide nanotubes	102
In this issue	102
Stereodivergent asymmetric hydrogenation of quinoxalines	100
Battery detectives: Uncovering cathode impact on anode-free Li cell performance by operando NMR	99
Phosphine oxide additives for perovskite light-emitting diodes and solar cells	99
General and selective metal-free radical α-C–H borylation of aliphatic amines	98
Molecular design strategy for realizing vectorial electron transfer in photoelectrodes	98
Two-in-one metallaphotoredox cross-couplings enabled by a photoactive ligand	97
Strong halide anion binding within the cavity of a conformation-adaptive phenazine-based Pd2L4 cage	95
Bioinspired chemical design to control interfacial wet adhesion	93
Cation-exchange-upgraded nanostructures for photocatalysts	92
A light-driven chloride anion transporter	91
Transition metal-free difunctionalization of unactivated alkenes: Arylation/azidation, arylation/chlorination, and arylation/cyanation	91
Molecule-resolvable SERSome for metabolic profiling	91
Chemical probes of redox enzymes by rational, reactivity-based design	88
The role of concentration waves in synthesizing hollow multi-shelled structures	88
Upcycling waste PET and CO2 to useful chemicals: Multi-functional catalysis at its best	88
Metal-free photocatalyzed cyanation enables access to carbon-11-radiolabeled aryl nitriles	88
The key of Zn2+ transfer kinetics in zinc metal batteries	88
Ice quenching for sustained nucleate boiling at large superheats	85

Development of tumor-evolution-targeted anticancer therapeutic nanomedicineEVT	82
Pilot-scale reductive catalytic depolymerization of lignin: Challenges and guidelines	82
Colorless zinc colored by metal-metal orbital interaction	82
Revisiting the impacts of silica nanoparticles on endothelial cell junctions and tumor metastasis	81
The mechanical bond in biological systems	79
The 40th anniversary of covalent dendrimers	78
Challenges and perspectives for the perovskite module research	78
Programmable spatial organization of liquid-phase condensations	78
Designing generative dissipative networks for programming complex temporal dynamics and functions	78
Potent antimicrobial effect induced by disruption of chloride homeostasis	77
Enzymatic DNA orthogonal chemistry for multi-cancer diagnosis	77
Catalyst: A step forward for PVC manufacture from natural gas	77
Unexpected diastereoselective chemistry on a 2D protein surface	77
Direct enantioselective α-amination of amides guided by DFT prediction of E/Z selectivity in a sulfonium intermediate	76
Deprotection of benzyl-derived groups via photochemically mesolytic cleavage of C–N and C–O bonds	75
Emerging trends in CO carbonylation	75
Forging C−heteroatom bonds by transition-metal-catalyzed enantioselective C–H functionalization	75
Selective palladium recovery by a highly porous polyisothiocyanurate	75
Antigen spatial-matching polyaptamer nanostructure to block coronavirus infection and alleviate inflammation	75
Regulating liquid and solid-state electrolytes for solid-phase conversion in Li–S batteries	74
Cold-resilient zinc batteries with organic-free solvation structures	73
Bioorthogonal reactions and AIEgen-based metabolically engineered theranostic systems	72
Oxygen-tolerant photocatalytic conversion of simulated flue gas to ethylene	72
High-resolution transmission electron microscopy of beam-sensitive halide perovskites	72
Omics approach for electrolytes discovery	72
Industrial PhD: My way to go?	71
A clever trilayer assembly strategy for 2D materials	71
Molecule additive design for perovskite light-emitting diodes operated at high current densities	71
Light-intensity-dependent out-of-equilibrium processes toward dimensionally distinct nanopolymorphs	70
Reaction: Circular chemical imaginaries	70
A novel type of radical-addition-induced β-fragmentation and ensuing remote functionalization	70
Programmable in vitro and in vivo folding of single-stranded nucleic-acid wireframe origami	70
Deciphering reactive intermediates in electrooxidative coupling of indoles through real-time mass spectrometry	70
Rationalizing the design and implementation of chiral hybrid perovskites	69
Microporous B←N framework: A stable and efficient material for separating C2H2 and CO2	69
Remote optical chirality transfer via helical polyaromatic capsules upon encapsulation	69
Ultralong ionic chains with lengths over 10 μm: A control of ionic molecular engineering	68
A B←N framework based on 1D dative B←N polymers for exclusive recognition and separation of benzene from its azeotrope	68
Rational structure transformation triggered by titanium modulation in metal-organic frameworks for efficient flue gas utilization	67
Elucidating the role of cathode identity: Voltage-dependent reversibility of anode-free batteries	67
Transformable quadruply interpenetrated cage with multiple states of different reactivities	67
Cross-assembly confined bifunctional catalysis via non-covalent interactions for asymmetric halogenation	65
Amorphous materials emerging as prospective electrodes for electrochemical energy storage and conversion	64
Frontier research in perovskite solar cells: Following the paths of European research and innovation	64
Metal-organic frameworks for water vapor adsorption	64
Controlling dynamic reconstruction chemistry for superior oxygen-evolving catalysts	64
Aqueous electrocatalytic small-molecule valorization trilogy	63
Hydrogen-bonded organic frameworks: Chemistry and functions	62
Water, metal ions, and me: A chemist’s tale of serendipity and discovery	61
Activating a light-driven molecular motor by metal complexation	61
Self-assembly of 10-nm-sized pentagonal dodecahedra through heteroleptic complexation coupled with orientational self-sorting	61
Divergent scaffold redesign of ecteinascidin 743 as a gateway to anticancer macrocycles	61
Downsizing lactams via Rh-catalyzed C–C activation	61
Dispersion-driven formation of chiral twisted PAH double helices	61
Rewriting lysine reactivity: Lysine-targeted bioconjugation via biomimetic polarity reversal for diversified biomolecule modification	60
Conceptually novel diarylation for sustainable synthesis	59
Innovative low-carbon technology for a sustainable electrolyte industry	59
In this issue	59
Isoreactivity in chemistry	58
In this issue	58
Sculpting photoproducts with DNA origami	58
Dynamic mechanoresponsive polymers enabled by ring-opening polymerization of cyclic propargyl carbonates	57
Unlocking the synthesis of homochiral carborane-fused boraphenanthrenes	57
Synergizing palladium with Lewis base catalysis for stereodivergent coupling of 1,3-dienes with pentafluorophenyl acetates	57
Selective cellular probes for mammalian thioredoxin reductase TrxR1: Rational design of RX1, a modular 1,2-thiaselenane redox probe	57
Self-sorting as a versatile strategy in the synthesis of rotaxanes and catenanes	56
Rational design and synthesis of two-dimensional conjugated metal-organic polymers for electrocatalysis applications	56
Microenvironment engineering of non-noble metal alloy for selective propane dehydrogenation	56
Metal-organic frameworks for fast electrochemical energy storage: Mechanisms and opportunities	56
Genetically enabling phosphorus fluoride exchange click chemistry in proteins	56
Correlations between precipitation reactions and electrochemical performance of lithium-sulfur batteries probed by operando scattering techniques	56
Self-adjusted aromatic cation-π binding promotes controlled self-assembly of positively charged π-electronic molecules	56
The cyclotriborate trianion	55
Modular synthesis of fluoroalkyl-substituted cyclopropenes with fluoroalkylacylsilanes as carbynyl cation equivalents	55
Challenges for photocatalytic overall water splitting	55
Supramolecular interactions enable pseudo-nanophase separation for constructing an ion-transport highway	55
Phenanthrenequinone-like moiety functionalized carbon for electrocatalytic acidic oxygen evolution	55
Boosting single-molecule magnet performance	54
Information transduction via fuel-controlled chemical waves	54
In this issue	54

Zero-valent species of group 13–15 elements	54
Bioengineering of syrbactin megasynthetases for immunoproteasome inhibitor production	53
Photovoltaic potential of nitro-functionalized non-fullerene acceptors depends on its bonding site	53
Ligand-enabled stereodivergence in nickel-catalyzed regioselective hydroboration of internal allenes	53
Does in-situ-generated H2O2 promote important industrial reactions?	53
Reaction: A three-pronged approach toward a sustainable chemical industry	53
Two (AgI3I)4L4 cages elucidate the rules for silver-cluster vertex design	53
Biocatalytic activation of diazirines for carbene-transfer reactions	52
Rethinking catalyst design by using data science	52
Single-molecule spectroscopic probing of N-heterocyclic carbenes on a two-dimensional metal	52
Operando scattering techniques for detecting precipitation reactions in lithium-sulfur batteries	52
Remotely controllable supramolecular rotor mounted inside a porphyrinic cage	52
DNA membrane nanopores with highly tunable shapes and sizes	52
Versatile deacylative cross-coupling of aromatic ketones	51
Supramolecular self-assembly of dinuclear alkynylplatinum(II) complexes into highly ordered crystalline hexagonal bipyramid superstructures	51
In my blue-light era	51
Applications of molecularly imprinted polymers and perspectives for their use as food quality trackers	51
Surface and interface control of black phosphorus	50
Dicobalt-catalyzed N=N coupling reactions of tertiary alkyl azides to form azoalkanes	50
A 10-nm-sized multicompartment cuboctahedron and its 2D hierarchical arrays observed by cryo-EM	50
Hydrophenazine-linked two-dimensional ladder-type crystalline fused aromatic network with high charge transport	50
Electrolyte engineering for highly inorganic solid electrolyte interphase in high-performance lithium metal batteries	49
Supramolecular repair of hydration lubrication surfaces	49
Phosphorus fluoride exchange: Multidimensional catalytic click chemistry from phosphorus connective hubs	49
Terpenoid-based high-performance polyester with tacticity-independent crystallinity and chemical circularity	49
Tumor microenvironment-tailored nanoplatform for companion diagnostic applications of precise cancer therapy	49
Electrophilic selenium drives electron leakage	49
Role of delocalized electrons on the doping effect in vanadia	49
Palladium-catalyzed asymmetric hydrophosphination of internal alkynes: Atroposelective access to phosphine-functionalized olefins	48
Ribosomal pentapeptide nitration for non-ribosomal peptide antibiotic precursor biosynthesis	48
Engineering biotic-abiotic hybrid systems for solar-to-chemical conversion	48
Tailoring dynamic hydrogels by controlling associative exchange rates	48
Indocyanine polymethine fluorophores with extended π-conjugation emitting beyond 1,200 nm for enhanced NIR-II imaging	48
Molecular design of covalent organic frameworks for seawater desalination: A state-of-the-art review	48
Bulk depolymerization of poly(methyl methacrylate) via chain-end initiation for catalyst-free reversion to monomer	48
Reaction: Navigating the promises and perils of AI-powered drug synthesis	47
A sustainable cobalt separation with validation by techno-economic analysis and life-cycle assessment	47
A single-crystalline 2D polymer network mechanically interlocked by [c2]daisy chains	47
Interplay between remote single-atom active sites triggers speedy catalytic oxidation	47
Depositing atom by atom: Pt–Ru–Co triple-atom catalysts	47
Controlled radical depolymerization: Structural differentiation and molecular weight control	47
Divergent synthesis of conidiogenones B–F and 12β-hydroxyconidiogenone C	46
Biosynthesis and genetic encoding of activated nitriles for fast protein conjugation and tunable fluorogenic labeling	46
Visible-light-induced coupling of carboxylic acids with alcohols/amines via a phosphorous linchpin strategy	46
Synthesizing a nanographyne	46
Championing systems thinking to create a circular economy of chemicals	46
Chlorine-free synthesis of axially chiral organophosphorus compounds from white phosphorus	46
4-Pyridyl perfluoroalkyl sulfide as a practical nucleophilic perfluoroalkylation reagent	45
New insights and discoveries in anion receptor chemistry	45
Solar-to-chemical conversion in catalytic plastic transformation	45
The Co/NbN interphase as an effective ammonia synthesis catalyst	45
Tetragonal gyroid structure from symmetry manipulation: A brand-new member of the gyroid surface family	45
Nanocomposite DNA hydrogels emerging as programmable and bioinstructive materials systems	45
Accelerating PERx reaction enables covalent nanobodies for potent neutralization of SARS-CoV-2 and variants	44
An angstrom-level d-spacing control of graphite oxide using organofillers for high-rate lithium storage	44
Uncovering strong π-metal interactions on Ag and Au nanosurfaces under ambient conditions via in-situ surface-enhanced Raman spectroscopy	44
Triazasupersumanenes: Bowl-shaped nanographenes with tunable properties and unexpected charge transport performance	44
Non-covalent interactions of graphene surface: Mechanisms and applications	44
Cancer nanomedicine: Concepts, promises, and challenges	44
Iron-mediated modular decarboxylative cross-nucleophile coupling	44
Selective hydrogenation catalysis enabled by nanoscale galvanic reactions	44
Versatile selective-absorber-based photothermocatalytic reactor for solar fuel synthesis	43
Elucidating non-radiative decay in near-infrared lumiphores: Leveraging new design principles to develop a telecom band organic dye laser	43
Communication between active sites regulates heterogeneous catalysis	43
The sustainability potential of single-atom catalysts in chemical process	43
Catalytic and selective chemical recycling of post-consumer rubbers into cycloalkenes	43
The subtle art of radical control	43
Porous organic polymers with heterocyclic crown ethers for selective lithium-ion capture	43
Out-of-equilibrium chemical logic systems: Light- and sound-controlled programmable spatiotemporal patterns and mechanical functions	42
Connecting single-nucleotide polymorphisms, glycosylation status, and interactions of plasma serine protease inhibitors	42
In This Issue	42
Selection of assembly complexity in a space of tetrapeptides	42
Reaction: The challenge of open-shell transition metal catalysis in “systems chemistry”	41
Programmable reconfiguration of one-dimensional supramolecular polymers into multidimensional topological nanostructures	41
New light on proton transfer: Spectral and kinetic signature of a transient Eigen complex	41
Integrating two contrasting biosynthetic pathways for peptide natural products	41
3D-printing technologies for C1 chemistry	41
Fluoride up- and down-regulates guest encapsulation for ZnII6L4 and ZnII4L4 cages	41
An ultra-dynamic anion-cluster-based organic framework	41
Finding sustainable solutions	41
Circumventing the activity-selectivity trade-off: Pt-Fe-Pt active sites for selective heterogeneous hydrogenation of crotonaldehyde	41
Reversible topochemical polymerization and depolymerization of a crystalline 3D porous organic polymer with C–C bond linkages	41
BINOLates as potent reducing photocatalysts for inert-bond activation and reduction of unsaturated systems	40
Construction of chiral nitrogen stereocenters via enantioselective C–H activation	40
Inverse doping IrOx/Ti with weakened Ir-O interaction toward stable and efficient acidic oxygen evolution	40
Dynamic active sites behind Cu-based electrocatalysts: Original or restructuring-induced catalytic activity	40
Quantitative and qualitative analysis of nitrogen species in carbon at the ppm level	40
Electrochemical 6Li isotope enrichment based on selective insertion in 1D tunnel-structured V2O5	39
Selective and stable upgrading of biomass-derived furans into plastic monomers by coupling homogeneous and heterogeneous catalysis	39
Photoinduced, ground-state charge-transfer complex	39
Chiral inorganic nanomaterials for biomedical applications	39
Self-activated energy release cascade from anthracene-based solid-state molecular solar thermal energy storage systems	39
Interfacial water regulation for water-participating electrocatalytic hydrogenation reactions	38
Anisotropy-guided interface molecular engineering for stable blue electroluminescence	38
Design of metal-organic framework catalysts for photocatalytic hydrogen peroxide production	38