OOIR: Observatory of International Research

Papers

(The TQCC of ACS Catalysis is 27. The table below lists those papers that are above that threshold based on CrossRef citation counts [max. 250 papers]. The publications cover those that have been published in the past four years, i.e., from 2021-05-01 to 2025-05-01.)

Article	Citations
Issue Publication Information	374
Issue Editorial Masthead	357
Issue Editorial Masthead	332
Correction to “Catalytic C(β)–O Bond Cleavage of Lignin in a One-Step Reaction Enabled by a Spin-Center Shift”	330
Electrochemical NADH Regeneration Mediated by Pyridine Amidate Iridium Complexes Interconverting 1,4- and 1,6-NADH	324
Issue Editorial Masthead	313
Issue Editorial Masthead	307
Issue Publication Information	303
Chiral Phosphate-Catalyzed Enantiodivergent Oxa-Diels–Alder Reaction of Trifluoropyruvate and Simple Dienes	296
In₂Cu₃O₆ Nanocluster in Siliceous Zeolite for Efficient CO₂ Methanation	296
Bifunctional NHC-Promoted C2-Alkylation of Pyridine via Ni–Al Bimetallic-Catalyzed Hydroarylation of Unactivated Alkenes	264
Versatile and Facile One-Pot Biosynthesis for Amides and Carboxylic Acids in E. coli by Engineering Auxin Pathways of Plant Microbiomes	259
Mechanistic Investigation into Copper(I) Hydride Catalyzed Formic Acid Dehydrogenation	257
Recent Advances in Theoretical Studies on Cu-Mediated Bond Formation Mechanisms Involving Radicals	241
Correction to “Facile Enzymatic Synthesis of Diverse Naturally Occurring β-d-Mannopyranosides Catalyzed by Glycoside Phosphorylases”	240
Ceria Incorporation in Sinter-Resistant Platinum-Based Catalysts	227
Copper(I)-Catalyzed Asymmetric Synthesis of α-Allenylamines and β-Lactams through Regioselective Mannich-Type Reactions	225
Simple Model and Spectral Analysis for a Fluxional Catalyst: Intermediate Abundances, Pathway Fluxes, Rates, and Transients	221
Axially Chiral 2-Hydroxybiaryls by Palladium-Catalyzed Enantioselective C–H Activation	219
Correction to “Photochemical Reductive Carboxylation of N-Benzoyl Imines with Oxalate Accelerated by Formation of EDA Complexes”	218
Nonlinear Acid Promotion of Oxidation Reactions by Mononuclear Nonheme Iron(III)-Aqua Complexes	214
Synergistic Catalyst–Mediator Pairings for Electroreductive Cross-Electrophile Coupling Reactions	213
Robust Bio-derived Polyoxometalate Hybrid for Selective Aerobic Oxidation of Benzylic C(sp³)–H Bonds	213
Elucidating the Pivotal Role of Acid-Catalyzed Hydration in Electrochemical Carbon Corrosion	209
Unveiling the Pivotal Role of Ce Coordination Structures and Their Surface Arrangements in Governing 2-Cyanopyridine Hydrolysis for Direct Dimethyl Carbonate Synthesis from CO₂ and Methanol	207

Keep the Ligands: Potential Benefits for Fuel Cell Performance	203
Geometrically Constrained Cofacial Bi-Titanium Olefin Polymerization Catalysts: Tuning and Enhancing Comonomer Incorporation Density	201
Correction to “Influence of Carbon Support on the Pyrolysis of Cobalt Phthalocyanine for the Efficient Electroreduction of CO₂”	199
Enantioselective Transformation of Hydrazones via Remote NHC Catalysis: Activation Across C═N and N–N Bonds	199
Correction to “Reductive Enzyme Cascades for Valorization of Polyethylene Terephthalate Deconstruction Products”	197
Straightforward Access to High-Performance Organometallic Catalysts by Fluoride Activation: Proof of Principle on Asymmetric Cyanation, Asymmetric Michael Addition, CO₂ Addition to Epoxide,	196
Regioselective Intermolecular Hydroamination of Unactivated Alkenes: “Co–H” Enabled Remote Functionalization	192
Valorization of Waste Polyester for 1,4-Cyclohexanedimethanol Production	192
Engineering of a Reductive Aminase to Enable the Synthesis of a Key Intermediate to a CDK 2/4/6 Inhibitor	185
Regulation of Oxygen Activation Pathways to Optimize Photocatalytic Methane Oxidative Coupling Selectivity	184
Programmable Enzymatic Toolbox for the Assembly of Fucosylated Chondroitin Derivatives	184
Water-Stable Perovskite Nanocrystals to Overcome the Photocatalysis–Stability Trade-Off in Aqueous Photo-RAFT Polymerization	183
Assessing and Quantifying Thermodynamically Concomitant Degradation during Oxygen Evolution from Water on SrTiO₃	182
Metal Cations from Sacrificial Anodes Act as a Lewis Acid Co-Catalyst in Electrochemical Cross-Coupling of Aryl Bromides and Aziridines	182
Dual-Oriented Selectivity Switching for Highly Efficient Biomass Upgrading via Selective C–O Bond Activation	181
Coordination Tailoring of Epitaxial Perovskite-Derived Iron Oxide Films for Efficient Water Oxidation Electrocatalysis	180
Communication Breakdown: Dissecting the COM Interfaces between the Subunits of Nonribosomal Peptide Synthetases	180
Issue Publication Information	179
Efficient Reductive Amination of Furfural to a Primary Amine on a Pt/TiO₂ Catalyst: A Manifestation of the Nanocluster Proximity Effect	177
Sulfonium Ylide Enabled, Copper-Catalyzed Difluoromethylation, Monofluoromethylation, and Monofluoroalkylation of Lithium Aryl ⁿButyl Borates	173
Enhanced Photoelectrochemical Hydrogen Evolution over Crystalline Cu₂Sn_0.38Ge_0.62S₃ Particles Grown from LiCl-RbCl Flux	173
Ca Cations Impact the Local Environment inside HZSM-5 Pores during the Methanol-to-Hydrocarbons Reaction	172
In Situ SERS Probing the Effect of Additional Metals on Pt-Based Ternary Alloys toward Improving ORR Performance	168
Understanding the Role of the Surface Acidity of MFI Zeolites during LDPE Cracking: Decomposition Temperature and Product Distribution	166
Highly Efficient Rutile TiO₂ Endowed by Electron-Capturing Center and Plasma Effect for Enhanced Solar Water Splitting	166
Asymmetric Remote meta-C–H Activation Controlled by a Chiral Ligand	165
Halloysite Clay Nanotubes for Catalytic Conversion of Biomass: Synergy between Computational Modeling and Experimental Studies	163
Surface Diffusion Barriers and Catalytic Activity Driven by Terminal Groups at Zeolite Catalysts	161
P,N Ligand in Ni-Catalyzed Cross-Coupling Reactions: A Promising Tool for π-Functionalization	159
Amination of a Green Solvent via Immobilized Biocatalysis for the Synthesis of Nemtabrutinib	158
Breaking the Structure–Activity Relationship in Toluene Hydrogenation Catalysis by Designing Heteroatom Ensembles Based on a Single-Atom Alloying Approach	158
Deactivation by Potassium Accumulation on a Pt/TiO₂ Bifunctional Catalyst for Biomass Catalytic Fast Pyrolysis	157
Relation between Water Oxidation Activity and Coordination Environment of C,N-Coordinated Mononuclear Co Catalyst	154
Designing Highly Active and Stable Ni-Exsolved LaMnO₃ Perovskite Catalysts for Dry Reforming of Methane via Ca Substitution	154
Preparation of a Water–Gas Shift Database to Evaluate the Performance of Noble Metal Catalysts Using Theory-Guided Machine Learning	154
Triethoxysilane-Catalyzed Single and Sequential Regioselective Hydroboration of Terminal Alkynes: Sustainable Access to E-Alkenylboronate and Alkyl Gem-Diboronate Esters by Non-Covalent	154
Design and Implementation of a CO₂ Reduction Catalyst with an Internal Electron Transfer Mediator: Improving Turnover Frequency by More than 10-Fold	153
Pd(0)-Catalyzed Diastereoselective and Enantioselective Intermolecular Heck–Miyaura Borylation of Internal Enamides for the β-Aminoboronate Ester Synthesis	153
Catalyst Design for Selective Hydrogenation of Benzene to Cyclohexene through Density Functional Theory and Microkinetic Modeling	153
Asymmetric Hydroxymethylative Etherification of 1,3-Dienes with Isatins and Alcohols via Pd(0)-π-Lewis Base Catalysis	152
Recent Advances in Furfural Reduction via Electro- And Photocatalysis: From Mechanism to Catalyst Design	151
Regioselective Plasmon-Driven Decarboxylation of Mercaptobenzoic Acids Triggered by Distinct Reactive Oxygen Species	151
Aerobic Alcohol Oxidation with a Cerium–Phenanthrolinedione Complex: A Mimic of Lanthanide-Based Methanol Dehydrogenase	150
Elucidating Pt-Based Nanocomposite Catalysts for the Oxygen Reduction Reaction in Rotating Disk Electrode and Gas Diffusion Electrode Measurements	149
Cooperative Adsorption: Solvating the Hofmann Elimination of Alkylamines	149
Catalyst Deactivation via Rhodium–Support Interactions under High-Temperature Oxidizing Conditions: A Comparative Study on Hexaaluminates versus Al₂O₃	148
Hydrogen Adsorption, Reactivity, and Catalysis on Colloidal Iron Carbide Nanoparticles	148
Ni-Catalyzed Cyanation of (Hetero)aryl Halides with Acetonitrile as Cyano Source	147
Insights into Electrochemical CO₂ Reduction on Metallic and Oxidized Tin Using Grand-Canonical DFT and In Situ ATR-SEIRA Spectroscopy	145
Metal-Mediated Catalytic Polarization Transfer from para Hydrogen to 3,5-Dihalogenated Pyridines	145

Unusual Facet-Dependent Sintering in Pd–TiO₂ Catalysts Revealed by Theory and Experiment	144
Palladium-Catalyzed Enantioselective Intramolecular Heck Reaction to Access Chiral C3-Tertiary Indolines	144
Highly Efficient Layered Double Hydroxide-Derived Bimetallic Cu–Co Alloy Catalysts for the Reverse Water–Gas Shift Reaction	141
Subnano-FeO_x Clusters Anchored in an Ultrathin Amorphous Al₂O₃ Nanosheet for Styrene Epoxidation	139
Electrocatalytic Water Oxidation by a Trinuclear Copper(II) Complex	138
Frustrated Lewis-Pair Catalyst Based on Re Single Atoms for Efficient Solar-Driven CO₂ Conversion	138
Inducing Microstrain in Electrodeposited Pt through Polymer Addition for Highly Active Oxygen Reduction Catalysis	137
Divergent and Synergistic Photocatalysis: Hydro- and Oxoalkylation of Vinyl Arenes for the Stereoselective Synthesis of Cyclopentanols via a Formal [4+1]-Annulation of 1,3-Dicarbonyls	137
Graphene-Isolated Satellite Nanostructure Enhanced Raman Spectroscopy Reveals the Critical Role of Different Intermediates on the Oxygen Reduction Reaction	136
Dynamic Cu⁰/Cu⁺ Interface Promotes Acidic CO₂ Electroreduction	136
Controlled Synthesis of Palladium Phosphides with Tunable Crystal Phases and Their Sulfur-Tolerant Performance	136
Computational Screening of Single and Di-Atom Catalysts for Electrochemical CO₂ Reduction	136
Structural Effects of FeN₄ Active Sites Surrounded by Fourteen-Membered Ring Ligands on Oxygen Reduction Reaction Activity and Durability	136
Heterometallic Pd^II–Cl–Cu^I Catalyst for Efficient Hydrolysis of β-1,4-Glycosidic Bonds in 1-Butyl-3-methylimidazolium Chloride	134
Fast and Selective β-C–H Borylation of N-Heterocycles with a Supramolecular Iridium Catalyst: Circumventing Deactivation Pathways and Mechanistic Insights	133
Automated Mechanism Generation Using Linear Scaling Relationships and Sensitivity Analyses Applied to Catalytic Partial Oxidation of Methane	133
Functional and Structural Analyses of a Highly Multifunctional Enzyme TM1270 from the Hyperthermophile Thermotoga maritima	133
Ultrathin and Conformal TiO_x Overlayers on WO₃ Photoelectrodes for Simultaneous Surface Trap Passivation and Heterojunction Formation	132
“Anion-Switchable” Pincer-Mn(I) Catalyst for the Reductive N-Methylation of Amines with Formic Acid and CO₂	131
Selective and Efficient Detoxification of Sulfur Mustard Gas Analogues with H₂O₂ Using Bioinspired Mo and W Dithiolene Catalysts	130
Dual Photoredox and Copper Catalysis: Enantioselective 1,2-Amidocyanation of 1,3-Dienes	130
Cobalt-Molybdenum Oxides for Effective Coupling of Ethane Activation and Carbon Dioxide Reduction Catalysis	130
Mechanism of Alternating Poly(lactic-co-glycolic acid) Formation by Polymerization of (S)- and (R)-3-Methyl Glycolide Using an Enantiopure Aluminum Complex	127
Theory-Guided Enhancement of CO₂ Reduction to Ethanol on Ag–Cu Tandem Catalysts via Particle-Size Effects	127
Polarization Manipulation of NiO Nanosheets Engineered with Fe/Pt Single Atoms for High-Performance Electrocatalytic Overall Alkaline Seawater Splitting	126
Regulating the Oxygen Vacancy of 3R-Phase Iridium Oxide by Loading Platinum Nanoparticles for Efficient Hydrogen Evolution	126
Unfolding the Role of B Site-Selective Doping of Aliovalent Cations on Enhancing Sacrificial Visible Light-Induced Photocatalytic H₂ and O₂ Evolution over BaTaO₂	126
Synergistic Catalytic Ozonation Mediated by Dual Active Sites of Oxygen Vacancies and Defects in Biomass-Derived Composites for Long-Lasting Water Decontamination	125
Structural Evolution of Oxide-Derived Nanostructured Silver Electrocatalysts during CO₂ Electroreduction	125
Integrated CO₂ Capture and Conversion to Methanol Leveraged by the Transfer Hydrogenation Approach	124
Hydrogen-Bonding Ability of Noyori–Ikariya Catalysts Enables Stereoselective Access to CF₃-Substituted syn-1,2-Diols via Dynamic Kinetic Resolution	124
Stabilizing Isolated Rhodium Cations by MFI Zeolite for Heterogeneous Methanol Carbonylation	124
Variable Metal Chelation Modes and Activation Sequence in Pd-Catalyzed B–H Poly-arylation of Carboranes	124
Engineering Morphology and Ni Substitution of Ni_xCo_3–xO₄ Spinel Oxides to Promote Catalytic Combustion of Ethane: Elucidating the Influence of Oxygen Def	123
Chiral Hypervalent Bromine(III) (Bromonium Salt): Hydrogen- and Halogen-Bonding Bifunctional Asymmetric Catalysis by Diaryl-λ³-bromanes	123
Nickel-Catalyzed Mono- and Dihydrosilylation of Aliphatic Alkynes in Aqueous and Aerobic Conditions	123
Unraveling the Oxygen Vacancy Site Mechanism of a Self-Assembly Hybrid Catalyst for Efficient Alkaline Water Oxidation	122
Investigations via Kinetics and Multivariate Linear Regression Models of the Mechanism and Origins of Regioselectivity in a Palladium-Catalyzed Aryne Annulation	122
Direct Alkylation of Glycine Derivatives via Photoinduced Palladium Catalysis, Utilizing Intermolecular Hydrogen Atom Transfer Mediated by Alkyl Radicals	121
What Controls Direct Hole-Mediated Oxidation Kinetics in a Carbon Nitride-Based Photocatalytic System: A Model Study for Aqueous Aromatic Compounds	121
Topology of DNA G-Quadruplexes Can Be Harnessed in Holliday Junction-Based DNA Suprastructures to Control and Optimize Their Biocatalytic Properties	120
Cobalt-Catalyzed Asymmetric Dearomative [3 + 2] Annulation of Quinolines, Isoquinolines, and Pyridines	120
Palladium-Catalyzed Modular Synthesis of Enantioenriched Pyridohelicenes through Double Imidoylative Cyclization	120
Design, Synthesis, and Insights into the Redox Mechanism of Highly Efficient One-Pot Cu-ZSM-5 Catalysts for the Reduction of NO_x by NH₃-SCR at Low Temperatures	120
Mechanistic Insights into Superoxide Dismutation Driven by Dinuclear Manganese Complexes: The Role of the Mn₂-Core	120
Catalyst–Substrate Pairings for Carbocyclic and Heterocyclic Systems in Atroposelective Quinazolinone Synthesis	119
Analogy in the Mechanism of Heterolytic H₂ Dissociation	119
Alcohol Solvent Assisted Synthesis of Metallic and Metal Oxide Catalysts: As-Prepared Cu/ZnO/Al₂O₃ Catalysts for Low-Temperature Methanol Synthesis with an Ultrahigh Yield	118
Active-Site Tailoring of Gold Cluster Catalysts for Electrochemical CO₂ Reduction	118
Conformational Selection in Biocatalytic Plastic Degradation by PETase	117
Catalytic Combustion of Methane over Noble Metal Catalysts	117
Kinetic Assessment of the Dry Reforming of Methane over a Ni–La₂O₃Catalyst	116
Halogen-Bond-Based Organocatalysis Unveiled: Computational Design and Mechanistic Insights	115
Designing Local Electron Delocalization in 2D Covalent Organic Frameworks for Enhanced Sunlight-Driven Photocatalytic Activity	115
Manipulating the Optically Active Defect–Defect Interaction of Colloidal Quantum Dots for Carbon Dioxide Photoreduction	115
Advanced Progress for Promoting Anodic Hydrogen Oxidation Activity and Anti-CO Poisoning in Fuel Cells	115
Tailoring the Electronic Structure of Single Ag Atoms in Ag/WO₃ for Efficient NO Reduction by CO in the Presence of O₂	114
Increased Hydrogenation Rates in Pd/La-Al₂O₃ Catalysts by Hydrogen Transfer O(-La) Sites Adjacent to Pd Nanoparticles	114
Enhancing Oxygen Evolution Reaction Activity by Using Switchable Polarization in Ferroelectric InSnO₂N	113
Hydrophobic Surface Modification of Cu-Based Catalysts for Enhanced Semihydrogenation of Acetylene in Excess Ethylene	113
Perspectives on Multifunctional Catalysts Derived from Layered Double Hydroxides toward Upgrading Reactions of Biomass Resources	113
Extending the π-Conjugated System in Conjugated Microporous Polymers to Modulate Excitonic Effects for Metal-Free Selective CO₂ Photoreduction to CH₄	113
Combining Theoretical and Experimental Methods to Probe Confinement within Microporous Solid Acid Catalysts for Alcohol Dehydration	112
Enhanced Activity of MOF-Based Pd/Electron-Transfer Mediator Catalysts in Oxidation Reactions Involving Isonitrile by Defect Engineering	112
A Review on the Impact of SO₂ on the Oxidation of NO, Hydrocarbons, and CO in Diesel Emission Control Catalysis	111
Mechanistic Study of Plasmon-Assisted In Situ Photoelectrochemical CO₂ Reduction to Acetate with a Ag/Cu₂O Nanodendrite Electrode	111
Theoretical Design of the Electrocatalytic Urea Synthesis from Carbon Dioxide and Nitric Oxides	111
Ni–In Synergy in CO₂ Hydrogenation to Methanol	110
Impact of Nonzeolite-Catalyzed Formation of Formaldehyde on the Methanol-to-Hydrocarbons Conversion	110
Subgroup Discovery Points to the Prominent Role of Charge Transfer in Breaking Nitrogen Scaling Relations at Single-Atom Catalysts on VS₂	109
Ceria-Based Materials for Thermocatalytic and Photocatalytic Organic Synthesis	109
Acid-Stable and Active M–N–C Catalysts for the Oxygen Reduction Reaction: The Role of Local Structure	109
Computational Redesign of an ω-Transaminase from Pseudomonas jessenii for Asymmetric Synthesis of Enantiopure Bulky Amines	108
Size-Dependent Adsorption and Adhesion Energetics of Ag Nanoparticles on Graphene Films on Ni(111) by Calorimetry	108
Unlocking the Production of Biomass-Derived Plastic Monomer 2,5-Furandicarboxylic Acid at Industrial-Level Concentration	108
Enantioselective Synthesis of Axially Chiral Diaryl Ethers through Chiral Phosphoric Acid-Catalyzed Desymmetric Acylation with Azlactones	107
Unraveling the Influence of Oxygen Vacancy Concentration on Electrocatalytic CO₂ Reduction to Formate over Indium Oxide Catalysts	107
Shape Reconstruction from Commercial Pt/C to High-Index Pt/C for Advanced Electrocatalysts	107
Mechanistic and Structural Insights into a Divergent PLP-Dependent l-Enduracididine Cyclase from a Toxic Cyanobacterium	107
Highly Enantioselective Synthesis of Planar-Chiral Cyclophanes through a Brønsted Acid-Catalyzed Asymmetric Transfer Hydrogenation	107

N-Heterocyclic Carbene-Photocatalyzed Tricomponent Regioselective 1,2-Diacylation of Alkenes Illuminates the Mechanistic Details of the Electron Donor–Acceptor Complex-Mediated Radical Relay Proces	107
Selective Nitrate Reduction to Ammonia at Environmentally Relevant Concentrations with an Iron-Phthalocyanine Polymer	106
Quantitative Understanding of Cation Effects on the Electrochemical Reduction of CO₂ and H⁺ in Acidic Solution	106
New Mechanistic Insights into CO₂/CO Electroreduction to Acetate by Combining Computations and Experiments	106
Selective Transfer Semihydrogenation of Alkynes Catalyzed by an Iron PCP Pincer Alkyl Complex	106
Photoinduced Regioselective Sulfonylsulfination of Alkenes	106
Discovery of a Covalent Triazine Framework Photocatalyst for Visible-Light-Driven Chemical Synthesis using High-Throughput Screening	106
Mechanistic Insights into Enantiocontrolling of Styrene Monooxygenase-Catalyzed Epoxidation of Olefins	106
Active Surface Area and Intrinsic Catalytic Oxygen Evolution Reactivity of NiFe LDH at Reactive Electrode Potentials Using Capacitances	106
Screening Surface Structure–Electrochemical Activity Relationships of Copper Electrodes under CO₂ Electroreduction Conditions	105
Mechanism of Hydrogen Sulfide-Dependent Inhibition of FeFe Hydrogenase	105
Comprehensive Study of Oxygen Vacancies on the Catalytic Performance of ZnO for CO/H₂ Activation Using Machine Learning-Accelerated First-Principles Simulations	105
Electrooxidative Pd-Catalyzed Remote Hydrofunctionalization of Alkenes with Nucleophiles	104
Interface Engineering of a Bifunctional Cu-SSZ-13@CZO Core–Shell Catalyst for Boosting Potassium Ion and SO₂ Tolerance	104
Efficient Electrocatalytic Oxidation of 5-Hydroxymethylfurfural Coupled with 4-Nitrophenol Hydrogenation in a Water System	104
Efficient Visible-Light-Driven CO₂ Methanation with Self-Regenerated Oxygen Vacancies in Co₃O₄/NiCo₂O₄ Hetero-Nanocages: Vacancy-Mediated Selecti	104
Ligands Defect-Induced Structural Self-Reconstruction of Fe–Ni–Co-Hydroxyl Oxides with Crystalline/Amorphous Heterophase from a 2D Metal–Organic Framework for an Efficient Oxygen Evolution Reaction	104
Issue Publication Information	103
Expeditious Synthesis of Highly Functional 4-Trifluoromethyl-Substituted Oxazoles Enabled by Cobalt(II) Metalloradical Catalysis	103
PdS Cluster Promotes Photocatalytic Coproduction of Hydrogen and Biomass-Based Monomers	102
Photocatalytic Reaction of Aryl Halides with Tin(II) Acetate to Generate Arylstannane(IV) Reagents	101
Oxidative Dehydrogenation of Ethane Combined with CO₂ Splitting via Chemical Looping on In₂O₃ Modified with Ni–Cu Alloy	101
Mechanistic Insights into the Stereoselective Cationic Polymerization of N-Vinylcarbazole	101
Artificially Created UDP-Glucose 2-Epimerase Enables Concise UDP/GDP-Mannose Production via the Synthase–Epimerase Route	101
Bifunctional Imine Reductase Cascades for the Synthesis of Saturated N-Heterocycles	101
Hydrothermally Stable Zeolite-Encapsulated Metal Catalyst Promoted by Framework Sn Species	101
Computational Enzyme Stabilization Can Affect Folding Energy Landscapes and Lead to Catalytically Enhanced Domain-Swapped Dimers	100
Structural Basis for the Friedel–Crafts Alkylation in Cylindrocyclophane Biosynthesis	100
[4Fe–4S]-Mediated Proton-Coupled Electron Transfer Enables the Efficient Degradation of Chloroalkenes by Reductive Dehalogenases	100
Nickel-Catalyzed Defluorinative Coupling of Aliphatic Aldehydes with Trifluoromethyl Alkenes	99
Homogeneous Catalysis for the Conversion of CO₂, CO, CH₃OH, and CH₄ to C₂₊ Chemicals via C–C Bond Formation	98
Covalent Adduct Formation as a Strategy for Efficient CO₂ Fixation in Crotonyl-CoA Carboxylases/Reductases	98
Dynamics at Polarized Carbon Dioxide–Iron Oxyhydroxide Interfaces Unveil the Origin of Multicarbon Product Formation	98
A P450 Harboring Manganese Protoporphyrin IX Generates a Manganese Analogue of Compound I by Activating Dioxygen	98
Emerging Applications of ¹⁷O Solid-State NMR Spectroscopy for Catalytic Oxides	98
Discovery of a P450-Catalyzed Oxidative Defluorination Mechanism toward Chiral Organofluorines: Uncovering a Hidden Pathway	97
Rhodium-Catalyzed Chemodivergent Synthesis of Organosilicons Enabled by Controllable C–Si Bond Activation	97
A General Base-free Route toward the Building of Metal N-Heterocyclic Carbenes into Covalent Organic Frameworks for CO₂ Conversion	96
Chlorine-Mediated Electrooxidation of Cyclohexene at High Current Density in a Liquid Diffusion Electrode Reactor	96
Ambient Hydrogen Storage and Release Using CO₂ and an l-Arginine-Functionalized PdAu Catalyst via pH Control	95
P-Block Elements Activate Pt Surfaces for the Electrooxidation of Alcohols and Polyols When Promoting the −OH formation	95
Acetonitrile Adsorption and Adhesion Energies onto the Pt(111) Surface by Calorimetry	95
Structure Dynamics of Carbon-Supported Platinum-Neodymium Nanoalloys during the Oxygen Reduction Reaction	94
Elucidating the Formation and Structural Evolution of Platinum Single-Site Catalysts for the Hydrogen Evolution Reaction	94
Heck-Type Coupling of Fused Bicyclic Vinylcyclopropanes: Synthesis of 1,2-Dihydropyridines, 2,3-Dihydro-1H-azepines, 1,4-Cyclohexadienes, and 2H-Pyrans	94
Mechanism and Reaction Channels of Iron-Catalyzed Primary Amination of Alkenes by Hydroxylamine Reagents	94
Understanding Supported Nanocatalysts under Operando Conditions through Systematic Kinetic Simulations	94
Multifunctional Zn-N4 Catalysts for the Coupling of CO₂ with Epoxides into Cyclic Carbonates	94
Multifaceted Role of the Noninnocent Mabiq Ligand in Promoting Selective Reduction of CO₂ to CO	94
Cooperative Redox Transitions Drive Electrocatalysis of the Oxygen Evolution Reaction on Cobalt–Iron Core–Shell Nanoparticles	93
Modulating the Energy Band to Inhibit the Over-oxidation for Highly Selective Anisaldehyde Production Coupled with Robust H₂ Evolution from Water Splitting	92
Tailoring the Coordination Environment of Cu Single Atoms for Achieving Regioselective C–C Bond Activation of Amides	92
Molecular Degradation of Iron Phthalocyanine during the Oxygen Reduction Reaction in Acidic Media	92
Identification of 2-Hydroxyacyl-CoA Synthases with High Acyloin Condensation Activity for Orthogonal One-Carbon Bioconversion	92
Diastereoselective Decarboxylative Alkynylation of Anomeric Carboxylic Acids Using Cu/Photoredox Dual Catalysis	91
Atomically Dispersed Co on N-Doped Porous Carbon for the Highly Efficient Catalytic Oxidation of Aromatic Alcohols to Acids and Nitriles	91
Insight into the Role of Na₂WO₄ in a Low-Temperature Light-off Mn₇SiO₁₂–Na₂WO₄/Cristobalite Catalyst for Oxidative Coupling of Methane	91
Molecular Orbital Engineering of Mixed-Addenda Polyoxometalates Boosts Light-Driven Hydrogen Evolution Activity	91
En Route to Recyclable Semi-Heterogeneous Photocatalysis with Photoinert CeCl₃	91
Use of Noncanonical Tyrosine Analogues to Probe Control of Radical Intermediates during Endoperoxide Installation by Verruculogen Synthase (FtmOx1)	90
Chemical Vapor Deposition for N/S-Doped Single Fe Site Catalysts for the Oxygen Reduction in Direct Methanol Fuel Cells	90
Dioxygen Activation Kinetics over Distinct Cu Site Types in Cu-Chabazite Zeolites	90
Functional Enhancement of Flavin-Containing Monooxygenase through Machine Learning Methodology	90
Understanding and Modifying the Scaling Relations for Ammonia Synthesis on Dilute Metal Alloys: From Single-Atom Alloys to Dimer Alloys	90
Dual Photoredox/Cobalt-Catalyzed Reductive Cyclization of Alkynals	89
Selective Enhancement of Methane Formation in Electrochemical CO₂ Reduction Enabled by a Raman-Inactive Oxygen-Containing Species on Cu	89
Mechanical Activation of Zero-Valent Metal Reductants for Nickel-Catalyzed Cross-Electrophile Coupling	89
Rapid Hole Extraction Based on Cascade Band Alignment Boosts Photoelectrochemical Water Oxidation Efficiency	89
Leveraging Atomic-Scale Synergy for Selective CO₂ Electrocatalysis to CO over CuNi Dual-Atom Catalysts	89
Pd(II)-Catalyzed C═C Bond Cleavage by a Formal Group-Exchange Reaction	89
Visible-Light-Driven Enantioselective Radical Addition to Imines Enabled by the Excitation of a Chiral Phosphoric Acid–Imine Complex	88
Skeletal Ring Contractions via I(I)/I(III) Catalysis: Stereoselective Synthesis of cis-α,α-Difluorocyclopropanes	88
Enhanced Electrocatalysis on Copper Nanostructures: Role of the Oxidation State in Sulfite Oxidation	88
Microfluidic Photocatalytic Ring Expansion of Sulfonium Salts for the Synthesis of Cyclic Sulfides	88
Nickel-Based Catalysts for the Selective Monoarylation of Dichloropyridines: Ligand Effects and Mechanistic Insights	87
Site-Selective and Late-Stage Deuteration of (Hetero)arenes with Supported Iridium Nanoparticles	87
In-Depth Analysis of Key Factors Affecting the Catalysis of Oxidized Carbon Blacks for Cellulose Hydrolysis	87
Substrate and Product Selective Supramolecular Catalysis by Pillar[5]arene in the Alkylation of Primary Linear Amines with Allyl Bromide	87
Electrophilic Selenium-Catalyzed Desymmetrizing Cyclization to Access P-Stereogenic Heterocycles	87
Changes to the 2024 ACS Catalysis Lectureship Awards	87
Biocatalytic Formal Asymmetric para-Aminoethylation of Unprotected Phenols to Chiral Amines	87
Kinetic Monte Carlo Analysis Reveals Non-mean-field Active Site Dynamics in Cu–Zeolite-Catalyzed NO_x Reduction	86
Gallium-Promoted Strong Metal–Support Interaction over a Supported Cu/ZnO Catalyst for Methanol Steam Reforming	86
Redox-Neutral Photocatalytic Germylative Difunctionalization of Unactivated Olefins via Selective Radical Capture by Ge(II)	86
Breaking the Trend: Insight into Unforeseen Reactivity of Alkynes in Cobalt-Catalyzed Weak Chelation-Assisted Regioselective C(4)–H Functionalization of 3-Pivaloyl Indole	86
Double Asymmetric Hydrogenation of α-Iminoketones: Facile Synthesis of Enantiopure Vicinal Amino Alcohols	86
Copper-Catalyzed Formal Dihydrosilylation of Terminal Alkynes: A C(sp)–H Silylation-Hydrosilylation-Hydrogenation Sequence	86
On the Promotional and Inhibitory Effects of Water on Wacker-Type Ethylene Oxidation Over Pd–Cu/Zeolite Y	86
High-Ionic-Strength Wastewater Treatment via Catalytic Wet Oxidation over a MnCeO_x Catalyst	86
Electrocatalytic Formate Oxidation by Cobalt–Phosphine Complexes	86
Carbon Dioxide Origin during High-Yield Partial Oxidation of Methane to Protected Methyl Esters	85
Multifunctional Photoelectroactive Platform for CO₂ Reduction toward C₂₊ Products─Programmable Selectivity with a Bioinspired Polymer Coating	85
Co_1–xFe_xO_y Oxygen Evolution Nanocatalysts: On the Way To Resolve (Electro)Chemically Triggered Surface-Bulk Discrepancy	85
Synthesis–Structure–Activity Relationship in Cu-MOR for Partial Methane Oxidation: Al Siting via Inorganic Structure-Directing Agents	85
Correction to “High-Performance and Durable Pd₅P₂/PdP₂ Heterointerface for All-pH Hydrogen Evolution Reactions”	85