OOIR: Observatory of International Research

Papers

(The median citation count of ACS Catalysis is 11. The table below lists those papers that are above that threshold based on CrossRef citation counts [max. 250 papers]. The publications cover those that have been published in the past four years, i.e., from 2021-08-01 to 2025-08-01.)

Article	Citations
Correction to “Facile Enzymatic Synthesis of Diverse Naturally Occurring β-d-Mannopyranosides Catalyzed by Glycoside Phosphorylases”	397
Correction to “Photochemical Reductive Carboxylation of N-Benzoyl Imines with Oxalate Accelerated by Formation of EDA Complexes”	362
Nonlinear Acid Promotion of Oxidation Reactions by Mononuclear Nonheme Iron(III)-Aqua Complexes	361
Geometrically Constrained Cofacial Bi-Titanium Olefin Polymerization Catalysts: Tuning and Enhancing Comonomer Incorporation Density	338
Correction to “Influence of Carbon Support on the Pyrolysis of Cobalt Phthalocyanine for the Efficient Electroreduction of CO₂”	332
Correction to “Reductive Enzyme Cascades for Valorization of Polyethylene Terephthalate Deconstruction Products”	327
Straightforward Access to High-Performance Organometallic Catalysts by Fluoride Activation: Proof of Principle on Asymmetric Cyanation, Asymmetric Michael Addition, CO₂ Addition to Epoxide,	263
Assessing and Quantifying Thermodynamically Concomitant Degradation during Oxygen Evolution from Water on SrTiO₃	262
Nickel-Catalyzed Mono- and Dihydrosilylation of Aliphatic Alkynes in Aqueous and Aerobic Conditions	260
Simple Model and Spectral Analysis for a Fluxional Catalyst: Intermediate Abundances, Pathway Fluxes, Rates, and Transients	253
In₂Cu₃O₆ Nanocluster in Siliceous Zeolite for Efficient CO₂ Methanation	251
Effects of Ni(OH)₂ Structures on the Electrochemical Conversion of KA Oil	244
Synergistic Effects of Strain and Oxygen Vacancies in Nanofiber Electrodes for Enhanced High-Temperature Electrochemical Ethane Dehydrogenation	243
Interface Engineering of a Bifunctional Cu-SSZ-13@CZO Core–Shell Catalyst for Boosting Potassium Ion and SO₂ Tolerance	239
Keep the Ligands: Potential Benefits for Fuel Cell Performance	234
Programmable Enzymatic Toolbox for the Assembly of Fucosylated Chondroitin Derivatives	234
Subnano-FeO_x Clusters Anchored in an Ultrathin Amorphous Al₂O₃ Nanosheet for Styrene Epoxidation	232
Inducing Microstrain in Electrodeposited Pt through Polymer Addition for Highly Active Oxygen Reduction Catalysis	229
Variable Metal Chelation Modes and Activation Sequence in Pd-Catalyzed B–H Poly-arylation of Carboranes	223
Enhanced Photoelectrochemical Hydrogen Evolution over Crystalline Cu₂Sn_0.38Ge_0.62S₃ Particles Grown from LiCl-RbCl Flux	219
Regioselective Plasmon-Driven Decarboxylation of Mercaptobenzoic Acids Triggered by Distinct Reactive Oxygen Species	208
Investigations via Kinetics and Multivariate Linear Regression Models of the Mechanism and Origins of Regioselectivity in a Palladium-Catalyzed Aryne Annulation	203
Hydrogen Adsorption, Reactivity, and Catalysis on Colloidal Iron Carbide Nanoparticles	203
From Micro-environments to Macroscopic Effects: How the Alkaline Hydrogen Evolution Reaction Drives Cu Cathodic Corrosion	202
Alcohol Solvent Assisted Synthesis of Metallic and Metal Oxide Catalysts: As-Prepared Cu/ZnO/Al₂O₃ Catalysts for Low-Temperature Methanol Synthesis with an Ultrahigh Yield	202

Tuning the Equilibrium of Excitons and Carriers in the (001) Plane-Exposed Bismuth Oxyhalide Enables Efficient Selective Photocatalytic Oxidation of 5-Hydroxymethylfurfural	201
Chiral Phosphate-Catalyzed Enantiodivergent Oxa-Diels–Alder Reaction of Trifluoropyruvate and Simple Dienes	200
Theoretical Design of the Electrocatalytic Urea Synthesis from Carbon Dioxide and Nitric Oxides	198
Topology of DNA G-Quadruplexes Can Be Harnessed in Holliday Junction-Based DNA Suprastructures to Control and Optimize Their Biocatalytic Properties	196
Size-Dependent Adsorption and Adhesion Energetics of Ag Nanoparticles on Graphene Films on Ni(111) by Calorimetry	196
Palladium-Catalyzed Enantioselective Intramolecular Heck Reaction to Access Chiral C3-Tertiary Indolines	195
Frustrated Lewis-Pair Catalyst Based on Re Single Atoms for Efficient Solar-Driven CO₂ Conversion	195
Indole Photocatalysts and Secondary Amine Ligands Enable Nickel-Photoredox C(sp²)–Heteroatom Couplings	195
Design and Implementation of a CO₂ Reduction Catalyst with an Internal Electron Transfer Mediator: Improving Turnover Frequency by More than 10-Fold	189
Communication Breakdown: Dissecting the COM Interfaces between the Subunits of Nonribosomal Peptide Synthetases	187
Aerobic Alcohol Oxidation with a Cerium–Phenanthrolinedione Complex: A Mimic of Lanthanide-Based Methanol Dehydrogenase	182
Robust Bio-derived Polyoxometalate Hybrid for Selective Aerobic Oxidation of Benzylic C(sp³)–H Bonds	178
Stereocontrolled Construction of Multi-Chiral [2.2]Paracyclophanes via Cobaltaphotoredox Dual Catalysis	177
Enantioselective Synthesis of Fused Bicyclic Cyclohexadienes by Rh/Si-SDP-Catalyzed [2 + 2 + 2] Cycloaddition of 1,6-Diynes with Acrylamides or Enamides	177
Valorization of Waste Polyester for 1,4-Cyclohexanedimethanol Production	177
Vinylarylcyclopropanes (VACPs): All-Carbon Dipole Precursors for Controlling Linear Regioselectivity in Cycloaddition Reactions	174
Recent Advances in Theoretical Studies on Cu-Mediated Bond Formation Mechanisms Involving Radicals	172
Increased Hydrogenation Rates in Pd/La-Al₂O₃ Catalysts by Hydrogen Transfer O(-La) Sites Adjacent to Pd Nanoparticles	171
Mechanism of Hydrogen Sulfide-Dependent Inhibition of FeFe Hydrogenase	169
Ceria Incorporation in Sinter-Resistant Platinum-Based Catalysts	169
Selective Nitrate Reduction to Ammonia at Environmentally Relevant Concentrations with an Iron-Phthalocyanine Polymer	166
Functional and Structural Analyses of a Highly Multifunctional Enzyme TM1270 from the Hyperthermophile Thermotoga maritima	163
Enhanced Activity of MOF-Based Pd/Electron-Transfer Mediator Catalysts in Oxidation Reactions Involving Isonitrile by Defect Engineering	162
Boosting Energy Flow by Manipulating Core–Satellite Dielectric Function Ratio of Heterostructures for Efficient Plasmon-Enhanced Ammonia Borane Dehydrogenation	160
Comprehensive Study of Oxygen Vacancies on the Catalytic Performance of ZnO for CO/H₂ Activation Using Machine Learning-Accelerated First-Principles Simulations	159
Enantioselective Transformation of Hydrazones via Remote NHC Catalysis: Activation Across C═N and N–N Bonds	159
Coordination Tailoring of Epitaxial Perovskite-Derived Iron Oxide Films for Efficient Water Oxidation Electrocatalysis	156
Fast and Selective β-C–H Borylation of N-Heterocycles with a Supramolecular Iridium Catalyst: Circumventing Deactivation Pathways and Mechanistic Insights	155
Catalytic Combustion of Methane over Noble Metal Catalysts	155
Computational Screening of Single and Di-Atom Catalysts for Electrochemical CO₂ Reduction	153
Cobalt-Molybdenum Oxides for Effective Coupling of Ethane Activation and Carbon Dioxide Reduction Catalysis	153
Insights into Electrochemical CO₂ Reduction on Metallic and Oxidized Tin Using Grand-Canonical DFT and In Situ ATR-SEIRA Spectroscopy	153
Active-Site Tailoring of Gold Cluster Catalysts for Electrochemical CO₂ Reduction	152
Correction to “Catalytic C(β)–O Bond Cleavage of Lignin in a One-Step Reaction Enabled by a Spin-Center Shift”	150
“Cesium Effect”-Mediated/Controlled Divergent Synthesis via Synergistic Pd/Cu-Catalyzed Cascade Reactions	148
Mechanistic Insights into Superoxide Dismutation Driven by Dinuclear Manganese Complexes: The Role of the Mn₂-Core	148
Copper(I)-Catalyzed Asymmetric Synthesis of α-Allenylamines and β-Lactams through Regioselective Mannich-Type Reactions	147
Halogen-Bond-Based Organocatalysis Unveiled: Computational Design and Mechanistic Insights	147
Mechanistic Investigation into Copper(I) Hydride Catalyzed Formic Acid Dehydrogenation	146
Fe(III)–H₂O₂ as an Alternative Oxidant for Catalytic Sulfoxidation in Cytochrome P450 Enzymes: Combined Theoretical and Experimental Evidence	145
Regulation of Oxygen Activation Pathways to Optimize Photocatalytic Methane Oxidative Coupling Selectivity	145
Elucidating the Pivotal Role of Acid-Catalyzed Hydration in Electrochemical Carbon Corrosion	145
Unusual Facet-Dependent Sintering in Pd–TiO₂ Catalysts Revealed by Theory and Experiment	145
What Controls Direct Hole-Mediated Oxidation Kinetics in a Carbon Nitride-Based Photocatalytic System: A Model Study for Aqueous Aromatic Compounds	144
Pd(0)-Catalyzed Diastereoselective and Enantioselective Intermolecular Heck–Miyaura Borylation of Internal Enamides for the β-Aminoboronate Ester Synthesis	144
Enhancing Oxygen Evolution Reaction Activity by Using Switchable Polarization in Ferroelectric InSnO₂N	143
Asymmetric Remote meta-C–H Activation Controlled by a Chiral Ligand	143
Dual-Oriented Selectivity Switching for Highly Efficient Biomass Upgrading via Selective C–O Bond Activation	143
Structural Evolution and Stability of Rh/TiO₂ Catalysts under CO₂ Hydrogenation Conditions: Influence of the Initial Rh Structure	143
Selective C–H Activation Facilitated by the Cooperative Effect of Extrinsic O₂ and Na on Ag(111)	143

Metal-Mediated Catalytic Polarization Transfer from para Hydrogen to 3,5-Dihalogenated Pyridines	142
Catalyst–Substrate Pairings for Carbocyclic and Heterocyclic Systems in Atroposelective Quinazolinone Synthesis	142
Surface Diffusion Barriers and Catalytic Activity Driven by Terminal Groups at Zeolite Catalysts	141
Unfolding the Role of B Site-Selective Doping of Aliovalent Cations on Enhancing Sacrificial Visible Light-Induced Photocatalytic H₂ and O₂ Evolution over BaTaO₂	140
Efficient Reductive Amination of Furfural to a Primary Amine on a Pt/TiO₂ Catalyst: A Manifestation of the Nanocluster Proximity Effect	139
Structural Effects of FeN₄ Active Sites Surrounded by Fourteen-Membered Ring Ligands on Oxygen Reduction Reaction Activity and Durability	138
Ni-Catalyzed Cyanation of (Hetero)aryl Halides with Acetonitrile as Cyano Source	137
Amination of a Green Solvent via Immobilized Biocatalysis for the Synthesis of Nemtabrutinib	136
Conformational Selection in Biocatalytic Plastic Degradation by PETase	136
Bifunctional NHC-Promoted C2-Alkylation of Pyridine via Ni–Al Bimetallic-Catalyzed Hydroarylation of Unactivated Alkenes	135
N-Heterocyclic Carbene-Photocatalyzed Tricomponent Regioselective 1,2-Diacylation of Alkenes Illuminates the Mechanistic Details of the Electron Donor–Acceptor Complex-Mediated Radical Relay Proces	135
Heterometallic Pd^II–Cl–Cu^I Catalyst for Efficient Hydrolysis of β-1,4-Glycosidic Bonds in 1-Butyl-3-methylimidazolium Chloride	135
Controlled Synthesis of Palladium Phosphides with Tunable Crystal Phases and Their Sulfur-Tolerant Performance	134
Preparation of a Water–Gas Shift Database to Evaluate the Performance of Noble Metal Catalysts Using Theory-Guided Machine Learning	134
Triethoxysilane-Catalyzed Single and Sequential Regioselective Hydroboration of Terminal Alkynes: Sustainable Access to E-Alkenylboronate and Alkyl Gem-Diboronate Esters by Non-Covalent	133
Unlocking the Production of Biomass-Derived Plastic Monomer 2,5-Furandicarboxylic Acid at Industrial-Level Concentration	133
Highly Efficient Layered Double Hydroxide-Derived Bimetallic Cu–Co Alloy Catalysts for the Reverse Water–Gas Shift Reaction	133
Screening Surface Structure–Electrochemical Activity Relationships of Copper Electrodes under CO₂ Electroreduction Conditions	133
Dual Photoredox and Copper Catalysis: Enantioselective 1,2-Amidocyanation of 1,3-Dienes	133
Kinetic Assessment of the Dry Reforming of Methane over a Ni–La₂O₃Catalyst	132
A Review on the Impact of SO₂ on the Oxidation of NO, Hydrocarbons, and CO in Diesel Emission Control Catalysis	129
Deactivation by Potassium Accumulation on a Pt/TiO₂ Bifunctional Catalyst for Biomass Catalytic Fast Pyrolysis	126
“Anion-Switchable” Pincer-Mn(I) Catalyst for the Reductive N-Methylation of Amines with Formic Acid and CO₂	125
Mechanism of Alternating Poly(lactic-co-glycolic acid) Formation by Polymerization of (S)- and (R)-3-Methyl Glycolide Using an Enantiopure Aluminum Complex	125
Palladium-Catalyzed Modular Synthesis of Enantioenriched Pyridohelicenes through Double Imidoylative Cyclization	125
New Mechanistic Insights into CO₂/CO Electroreduction to Acetate by Combining Computations and Experiments	125
Acid-Stable and Active M–N–C Catalysts for the Oxygen Reduction Reaction: The Role of Local Structure	125
Issue Editorial Masthead	124
Highly Efficient Rutile TiO₂ Endowed by Electron-Capturing Center and Plasma Effect for Enhanced Solar Water Splitting	124
Issue Editorial Masthead	122
Issue Publication Information	122
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Unveiling the Pivotal Role of Ce Coordination Structures and Their Surface Arrangements in Governing 2-Cyanopyridine Hydrolysis for Direct Dimethyl Carbonate Synthesis from CO₂ and Methanol	120
Engineering of a Reductive Aminase to Enable the Synthesis of a Key Intermediate to a CDK 2/4/6 Inhibitor	119
Design, Synthesis, and Insights into the Redox Mechanism of Highly Efficient One-Pot Cu-ZSM-5 Catalysts for the Reduction of NO_x by NH₃-SCR at Low Temperatures	119
Designing Highly Active and Stable Ni-Exsolved LaMnO₃ Perovskite Catalysts for Dry Reforming of Methane via Ca Substitution	119
P,N Ligand in Ni-Catalyzed Cross-Coupling Reactions: A Promising Tool for π-Functionalization	119
Analogy in the Mechanism of Heterolytic H₂ Dissociation	119
Efficient Electrocatalytic Oxidation of 5-Hydroxymethylfurfural Coupled with 4-Nitrophenol Hydrogenation in a Water System	119
Integrated CO₂ Capture and Conversion to Methanol Leveraged by the Transfer Hydrogenation Approach	118
Structure of Iridium Oxides and Their Oxygen Evolution Electrocatalysis in Acidic Media	118
Manipulating the Optically Active Defect–Defect Interaction of Colloidal Quantum Dots for Carbon Dioxide Photoreduction	117
Ultrathin and Conformal TiO_x Overlayers on WO₃ Photoelectrodes for Simultaneous Surface Trap Passivation and Heterojunction Formation	117
Efficient Visible-Light-Driven CO₂ Methanation with Self-Regenerated Oxygen Vacancies in Co₃O₄/NiCo₂O₄ Hetero-Nanocages: Vacancy-Mediated Selecti	117
Highly Enantioselective Synthesis of Planar-Chiral Cyclophanes through a Brønsted Acid-Catalyzed Asymmetric Transfer Hydrogenation	116
Mechanistic and Structural Insights into a Divergent PLP-Dependent l-Enduracididine Cyclase from a Toxic Cyanobacterium	116
Selective Transfer Semihydrogenation of Alkynes Catalyzed by an Iron PCP Pincer Alkyl Complex	115
Hydrophobic Surface Modification of Cu-Based Catalysts for Enhanced Semihydrogenation of Acetylene in Excess Ethylene	115
Metal Cations from Sacrificial Anodes Act as a Lewis Acid Co-Catalyst in Electrochemical Cross-Coupling of Aryl Bromides and Aziridines	115
Structural Evolution of Oxide-Derived Nanostructured Silver Electrocatalysts during CO₂ Electroreduction	115
General, Quantified Structure-Performance Correlations for Synergistic Heteronuclear Electro-, Polymerization, and Asymmetric Catalysts	115
A Branchpoint Cytochrome P450 CYP512A13 Interconverts Different Types of Ganoderma Triterpenoids	114
Impact of Nonzeolite-Catalyzed Formation of Formaldehyde on the Methanol-to-Hydrocarbons Conversion	114
Axially Chiral 2-Hydroxybiaryls by Palladium-Catalyzed Enantioselective C–H Activation	113
Ligands Defect-Induced Structural Self-Reconstruction of Fe–Ni–Co-Hydroxyl Oxides with Crystalline/Amorphous Heterophase from a 2D Metal–Organic Framework for an Efficient Oxygen Evolution Reaction	113
Divergent and Synergistic Photocatalysis: Hydro- and Oxoalkylation of Vinyl Arenes for the Stereoselective Synthesis of Cyclopentanols via a Formal [4+1]-Annulation of 1,3-Dicarbonyls	113
Direct Alkylation of Glycine Derivatives via Photoinduced Palladium Catalysis, Utilizing Intermolecular Hydrogen Atom Transfer Mediated by Alkyl Radicals	112
Chiral Hypervalent Bromine(III) (Bromonium Salt): Hydrogen- and Halogen-Bonding Bifunctional Asymmetric Catalysis by Diaryl-λ³-bromanes	112
Photoinduced Regioselective Sulfonylsulfination of Alkenes	112
Designing Local Electron Delocalization in 2D Covalent Organic Frameworks for Enhanced Sunlight-Driven Photocatalytic Activity	112
Unraveling the Oxygen Vacancy Site Mechanism of a Self-Assembly Hybrid Catalyst for Efficient Alkaline Water Oxidation	110
Mechanistic Insights into Enantiocontrolling of Styrene Monooxygenase-Catalyzed Epoxidation of Olefins	109
Halloysite Clay Nanotubes for Catalytic Conversion of Biomass: Synergy between Computational Modeling and Experimental Studies	109
Electrochemical NADH Regeneration Mediated by Pyridine Amidate Iridium Complexes Interconverting 1,4- and 1,6-NADH	109
Catalyst Design for Selective Hydrogenation of Benzene to Cyclohexene through Density Functional Theory and Microkinetic Modeling	109
Ruthenium-Based Nanoparticles-Loaded Layered Silica Nanosheets-Assembled Stacked-Structure Nanoreactors for Efficient Production of Biomass-Based Pyrrolidinones	109
Enantioselective Synthesis of Axially Chiral Diaryl Ethers through Chiral Phosphoric Acid-Catalyzed Desymmetric Acylation with Azlactones	109
Synergistic Catalytic Ozonation Mediated by Dual Active Sites of Oxygen Vacancies and Defects in Biomass-Derived Composites for Long-Lasting Water Decontamination	108
Computational Redesign of an ω-Transaminase from Pseudomonas jessenii for Asymmetric Synthesis of Enantiopure Bulky Amines	107
Shape Reconstruction from Commercial Pt/C to High-Index Pt/C for Advanced Electrocatalysts	107
Engineering Morphology and Ni Substitution of Ni_xCo_3–xO₄ Spinel Oxides to Promote Catalytic Combustion of Ethane: Elucidating the Influence of Oxygen Def	107
Active Surface Area and Intrinsic Catalytic Oxygen Evolution Reactivity of NiFe LDH at Reactive Electrode Potentials Using Capacitances	107
Selective and Efficient Detoxification of Sulfur Mustard Gas Analogues with H₂O₂ Using Bioinspired Mo and W Dithiolene Catalysts	106
Versatile and Facile One-Pot Biosynthesis for Amides and Carboxylic Acids in E. coli by Engineering Auxin Pathways of Plant Microbiomes	106
Discovery of a Covalent Triazine Framework Photocatalyst for Visible-Light-Driven Chemical Synthesis using High-Throughput Screening	106
Asymmetric Hydroxymethylative Etherification of 1,3-Dienes with Isatins and Alcohols via Pd(0)-π-Lewis Base Catalysis	105
Relation between Water Oxidation Activity and Coordination Environment of C,N-Coordinated Mononuclear Co Catalyst	105

Tailoring the Electronic Structure of Single Ag Atoms in Ag/WO₃ for Efficient NO Reduction by CO in the Presence of O₂	104
Graphene-Isolated Satellite Nanostructure Enhanced Raman Spectroscopy Reveals the Critical Role of Different Intermediates on the Oxygen Reduction Reaction	104
Recent Advances in Furfural Reduction via Electro- And Photocatalysis: From Mechanism to Catalyst Design	104
Cobalt-Catalyzed Asymmetric Dearomative [3 + 2] Annulation of Quinolines, Isoquinolines, and Pyridines	104
Regulating the Oxygen Vacancy of 3R-Phase Iridium Oxide by Loading Platinum Nanoparticles for Efficient Hydrogen Evolution	104
Polarization Manipulation of NiO Nanosheets Engineered with Fe/Pt Single Atoms for High-Performance Electrocatalytic Overall Alkaline Seawater Splitting	103
Advanced Progress for Promoting Anodic Hydrogen Oxidation Activity and Anti-CO Poisoning in Fuel Cells	102
Understanding the Role of the Surface Acidity of MFI Zeolites during LDPE Cracking: Decomposition Temperature and Product Distribution	102
In Situ SERS Probing the Effect of Additional Metals on Pt-Based Ternary Alloys toward Improving ORR Performance	102
Quantitative Understanding of Cation Effects on the Electrochemical Reduction of CO₂ and H⁺ in Acidic Solution	102
Water-Stable Perovskite Nanocrystals to Overcome the Photocatalysis–Stability Trade-Off in Aqueous Photo-RAFT Polymerization	102
Synergistic Catalyst–Mediator Pairings for Electroreductive Cross-Electrophile Coupling Reactions	102
Sulfonium Ylide Enabled, Copper-Catalyzed Difluoromethylation, Monofluoromethylation, and Monofluoroalkylation of Lithium Aryl ⁿButyl Borates	102
Combining Theoretical and Experimental Methods to Probe Confinement within Microporous Solid Acid Catalysts for Alcohol Dehydration	102
Dynamic Cu⁰/Cu⁺ Interface Promotes Acidic CO₂ Electroreduction	102
Ca Cations Impact the Local Environment inside HZSM-5 Pores during the Methanol-to-Hydrocarbons Reaction	102
Theory-Guided Enhancement of CO₂ Reduction to Ethanol on Ag–Cu Tandem Catalysts via Particle-Size Effects	102
Mitigating Hydrogen Poisoning for Robust Ammonia-to-Hydrogen Conversion over Photothermal Catalysts	101
Mechanistic Study of Plasmon-Assisted In Situ Photoelectrochemical CO₂ Reduction to Acetate with a Ag/Cu₂O Nanodendrite Electrode	100
Breaking the Structure–Activity Relationship in Toluene Hydrogenation Catalysis by Designing Heteroatom Ensembles Based on a Single-Atom Alloying Approach	100
Ni–In Synergy in CO₂ Hydrogenation to Methanol	100
Extending the π-Conjugated System in Conjugated Microporous Polymers to Modulate Excitonic Effects for Metal-Free Selective CO₂ Photoreduction to CH₄	100
Expeditious Synthesis of Highly Functional 4-Trifluoromethyl-Substituted Oxazoles Enabled by Cobalt(II) Metalloradical Catalysis	99
Mechanism and Reaction Channels of Iron-Catalyzed Primary Amination of Alkenes by Hydroxylamine Reagents	99
Acetonitrile Adsorption and Adhesion Energies onto the Pt(111) Surface by Calorimetry	99
Understanding Supported Nanocatalysts under Operando Conditions through Systematic Kinetic Simulations	99
Unraveling the Influence of Oxygen Vacancy Concentration on Electrocatalytic CO₂ Reduction to Formate over Indium Oxide Catalysts	99
Hydrogen-Bonding Ability of Noyori–Ikariya Catalysts Enables Stereoselective Access to CF₃-Substituted syn-1,2-Diols via Dynamic Kinetic Resolution	99
Skeletal Ring Contractions via I(I)/I(III) Catalysis: Stereoselective Synthesis of cis-α,α-Difluorocyclopropanes	98
Artificially Created UDP-Glucose 2-Epimerase Enables Concise UDP/GDP-Mannose Production via the Synthase–Epimerase Route	98
Microfluidic Photocatalytic Ring Expansion of Sulfonium Salts for the Synthesis of Cyclic Sulfides	98
Photo-Induced Formal Trifluoropropanation of Organic Halides	97
Enzymatic Fluoroethylation by a Fluoroethyl Selenium Analogue of S-Adenosylmethionine	97
Ethylene-Triggered Regioselectivity Switch of Dimethylbutadiene in Their Copolymerization: Formation of “Plastic” Rubber and Mechanism	97
C–H Functionalization as a Powerful Method for Direct Synthesis of Lactones	97
Enhanced Electrocatalysis on Copper Nanostructures: Role of the Oxidation State in Sulfite Oxidation	96
Breaking the Trend: Insight into Unforeseen Reactivity of Alkynes in Cobalt-Catalyzed Weak Chelation-Assisted Regioselective C(4)–H Functionalization of 3-Pivaloyl Indole	96
Enantioselective Hydrogenation toward Chiral 3-Aryloxy Tetrahydrofurans Enabled by Spiro Ir-PNN Catalysts Containing an Unusual 5-Substituted Chiral Oxazoline Unit	96
Collaborative Mechanistic Effects between Vanadia and Titania during the Oxidative Dehydrogenation of Propane Investigated by Operando and Transient Spectroscopies	95
Targeted Intermetallic Nanocatalysts for Sustainable Biomass and CO₂ Valorization	95
Nickel-Based Catalysts for the Selective Monoarylation of Dichloropyridines: Ligand Effects and Mechanistic Insights	95
Enantioselective Copper-Catalyzed Desymmetric Olefination via the Boron-Wittig Reaction	94
NH₃ Synthesis from N₁ Compounds by Photocatalytic Technology: Promotion Mechanism, Reaction Pathways, and Efficiency Evaluation Criteria	94
Ambient Hydrogen Storage and Release Using CO₂ and an l-Arginine-Functionalized PdAu Catalyst via pH Control	94
Use of Noncanonical Tyrosine Analogues to Probe Control of Radical Intermediates during Endoperoxide Installation by Verruculogen Synthase (FtmOx1)	94
Functional Studies on an Indel Loop between the Subtypes of meso-Diaminopimelate Dehydrogenase	93
Catalytic Arylboration of Spirocyclic Cyclobutenes: Rapid Access to Highly Substituted Spiro[3.n]alkanes	93
Nitrogen Source-Tailored Multicomponent C–H Di/Triannulation of α-Oxocarboxylic Acids and Alkynes to Diverse Cationic N-Doped PAHs	93
Biocatalytic Formal Asymmetric para-Aminoethylation of Unprotected Phenols to Chiral Amines	93
Gem-Difluorocyclopropenes as Versatile β-Monofluorinated Three-sp² Carbon Sources for Cp*Rh(III)-Catalyzed [4 + 3] Annulation: Experimental Development and Mechanistic Insight	93
Chitin Deacetylase as a Biocatalyst for the Selective N-Acylation of Chitosan Oligo- and Polymers	92
Emerging Applications of ¹⁷O Solid-State NMR Spectroscopy for Catalytic Oxides	92
Identifying the Optimal Pd Ensemble Size in Dilute PdAu Alloy Nanomaterials for Benzaldehyde Hydrogenation	92
Electrophilic Selenium-Catalyzed Desymmetrizing Cyclization to Access P-Stereogenic Heterocycles	92
Electrocatalytic Formate Oxidation by Cobalt–Phosphine Complexes	92
Identification of 2-Hydroxyacyl-CoA Synthases with High Acyloin Condensation Activity for Orthogonal One-Carbon Bioconversion	92
Ligand-Exchange-Enabled Axially Chiral Recognition in Asymmetric Aminopalladation/Olefination of 2-Alkynylanilides	92
Substrate and Product Selective Supramolecular Catalysis by Pillar[5]arene in the Alkylation of Primary Linear Amines with Allyl Bromide	92
Correction to “Multiple Cuprous Centers Supported on a Titanium-Based Metal–Organic Framework Catalyze CO₂ Hydrogenation to Ethylene”	91
Copper-Catalyzed Formal Dihydrosilylation of Terminal Alkynes: A C(sp)–H Silylation-Hydrosilylation-Hydrogenation Sequence	91
Gold(I)-Catalyzed Access to 1-Alkynyl C-Glycosides from 1-Silylated Alkynes: An Alternative Paradigm for the Direct and α-Stereoselective Alkynylation of Glycosides	91
Synthesis–Structure–Activity Relationship in Cu-MOR for Partial Methane Oxidation: Al Siting via Inorganic Structure-Directing Agents	91
Repurposing a Nitric Oxide Transport Hemoprotein Nitrophorin 2 for Olefin Cyclopropanation	91
Exceptional Low-Temperature CO Oxidation over Noble-Metal-Free Iron-Doped Hollandites: An In-Depth Analysis of the Influence of the Defect Structure on Catalytic Performance	91
Correction to “High-Performance and Durable Pd₅P₂/PdP₂ Heterointerface for All-pH Hydrogen Evolution Reactions”	91
Rising Opportunities in Catalytic Dehydrogenative Polymerization	91
Recent Advances in Desulfurization of VOSCs: Multiple Catalysts and Coupling Enzymes	90
Structural Modulation and Adsorptive Behavior of CuFe-LDHs-derived Catalysts through Mn Doping: Dual Enhancement of Low-Temperature Catalytic Performance and Sulfur Resistance	90
Kinetic Monte Carlo Analysis Reveals Non-mean-field Active Site Dynamics in Cu–Zeolite-Catalyzed NO_x Reduction	90
Nickel-Catalyzed Regio- and Stereoselective Hydroalkylation of Allenes: Exploiting the Unique Reactivity of Diazo Compounds as an Alkylating Source	90
Nickel-Catalyzed Defluorinative Coupling of Aliphatic Aldehydes with Trifluoromethyl Alkenes	90
Oxidative Dehydrogenation of Ethane Combined with CO₂ Splitting via Chemical Looping on In₂O₃ Modified with Ni–Cu Alloy	90
Stereoblock vs Stereoblend: Orchestrating Competing Living Coordination Chain Transfer Polymerizations for the One-Pot Production of New Viscoelastic Grades of Poly(4-methyl-1-pentene)	90
Thermally Robust and Highly Active PCP Cobalt(II) Catalyst for Linear-Selective Hydroboration of Terminal and Internal Olefins	90
Structural Basis for the Friedel–Crafts Alkylation in Cylindrocyclophane Biosynthesis	89
Changes to the 2024 ACS Catalysis Lectureship Awards	89
Heck-Type Coupling of Fused Bicyclic Vinylcyclopropanes: Synthesis of 1,2-Dihydropyridines, 2,3-Dihydro-1H-azepines, 1,4-Cyclohexadienes, and 2H-Pyrans	89
Regio- and Stereoselective Addition of Secondary Phosphine Oxides to Allenoates Catalyzed by Main-Group Lewis Pairs	89
Selective C(sp³)-C(sp³) Cleavage/Alkynylation of Cycloalkylamides Enables Aminoalkyne Synthesis with Hypervalent Iodine Reagents	89
Mechanistic Studies on Iron-Catalyzed Dehydrogenation of Amines Involving Cyclopentadienone Iron Complexes─Evidence for Stepwise Hydride and Proton Transfer	88
Carbon Dioxide Origin during High-Yield Partial Oxidation of Methane to Protected Methyl Esters	88
Autonomous Exploitation of Reaction Pathways for Electrochemical C–N Coupling on Single-Atom Catalysts	88
Computational Enzyme Stabilization Can Affect Folding Energy Landscapes and Lead to Catalytically Enhanced Domain-Swapped Dimers	88
Bifunctional Imine Reductase Cascades for the Synthesis of Saturated N-Heterocycles	88
Unraveling the Contrasting Dynamics of Reconstruction in Wolframite Cobalt Molybdate Polymorphs for Oxygen Evolution Reaction Electrocatalysis	88
Discovery of a P450-Catalyzed Oxidative Defluorination Mechanism toward Chiral Organofluorines: Uncovering a Hidden Pathway	88
Enantioselective Inverse-Electron Demand Aza-Diels–Alder Reaction: ipso,α-Selectivity of Silyl Dienol Ethers	88
Tailoring the Coordination Environment of Cu Single Atoms for Achieving Regioselective C–C Bond Activation of Amides	88
CO Oxidation with Atomically Dispersed Catalysts: Insights from the Energetic Span Model	87
Carbon-Interacted AlF₃ Clusters as Robust Catalyst for Dehydrofluorination Reaction with Enhanced Undercoordination and Stability	87
Elucidating the Formation and Structural Evolution of Platinum Single-Site Catalysts for the Hydrogen Evolution Reaction	87
Sequential C–H Aroylation and Formal [4 + 2] Cycloaddition of Naphthalenes with Aroylfluorides and Styrenes	87
Highly Active and Durable Iridium Nickel Oxide Platelets for a Proton Exchange Membrane Water Electrolyzer with Low Iridium Loading	87
A P450 Harboring Manganese Protoporphyrin IX Generates a Manganese Analogue of Compound I by Activating Dioxygen	87
Unraveling the Surface Termination and Evolution of Surface States for Electrocatalyst PtSn₄ in Alkaline HER	87