Organic Chemistry Frontiers

Article	Citations
Pd-Free synthesis of dithienothiophene-based oligoaryls for effective hole-transporting materials by optimized Cu-catalyzed annulation and direct C–H arylation	115
Iminophosphorane in perylenediimide chemistry: Staudinger reaction and a visible-light-driven competitive reaction of the Cadogan cyclization	86
Copper-catalyzed alkynyldisulfuration of arynes: efficient access to unsymmetrical disulfides	80
Photoredox-catalyzed intramolecular oxy- and aminoacylation of alkenes with acyl oxime esters: facile synthesis of acylated saturated heterocycles	79
Modular dehydrogenative cross-nucleophile coupling for direct construction of tetrasubstituted carbons	73
Hierarchical amplification of chirality in anion-coordinated tetrahedral cages	70
Enantioselective total syntheses of (−)-mitragynine, (−)-quinine and (+)-quinidine enabled by Ir-catalysed asymmetric hydrogenation of all-carbon tetrasubstituted cycloalkenes	66
A photo-driven traceless group directed electron–donor–acceptor (EDA) complex initiated radical coupling/dehydrogenation tandem reaction: access to 1-allyl/benzyl-3,4-dihydroisoquinoline	65
Regio- and stereo-selective synthesis of β-phenylthio enamidesviaintramolecular 1,2-thiol migration	64
Cyclocondensation reactions of racemic diastereomers of dimethyl-2-oxocyclohexanepropionic acids with (R)-phenylglycinol: access to both enantiomers of dimethylcis-decahydroquinolines	61
Photoredox catalyzed hydroazolylation of alkenes via phosphoranyl radicals	59
Electrochemical oxidative cyclization of alkenes, boronic acids, and dichalcogenides to access chalcogenated boronic esters and 1,3-diols	58
Organocatalytic asymmetric [3 + 3] annulations of 3-carboxamide oxindoles with β,γ-unsaturated α-keto esters: facile access to chiral spiro-δ-lactam oxindoles	57
Bis(pentafluorophenyl)borane-catalyzed E-selective isomerization of terminal alkenes to internal alkenes	55
Bond energy enabled amine distinguishing strategy: chemo-, regioselective 1,3-diamination of (trifluoromethyl)alkenes with different amines by two C(sp3)–F bond cleavages	53
Synthesis of spirocyclopropylpyrazole derivatives via the cascade reaction of alkylidenecyclopropanes with pyrazolidinones and trifluoroethanol	49
Catalytic asymmetric synthesis of 3,4′-indole–pyrazole derivatives featuring axially chiral bis-pentatomic heteroaryls	49
Frustrated behavior of Lewis/Brønsted pairs inside molecular cages	48
Reductive activation of arenes by potassium metal with potassium salts	48
Direct synthesis of gold(iii)-annulated perylene diimides via multiple C–H aurations	48
Synthesis of morpholino nucleosides starting from enantiopure glycidol	46
Sequence-sorted redox-switchable hetero[3]rotaxanes	46
Fused-ring molecules based on B ← N and imide units with low energy levels	45
Copper-mediated three-component synthesis of 2-trifluoromethyl benzimidazoles	45
Photocatalytic redox-neutral arylation of cyclopropanols with cyanoarenes via radical-mediated C–C and C–CN bond cleavage	45

Front cover	44
Copper-catalyzed synthesis of cyclopropyl bis(boronates) from aryl olefins and carbon monoxide	44
Bromide-catalyzed oxo-amination of alkenes towards the synthesis of α-amine ketones under photoelectrocatalysis conditions	43
N-heterocyclic carbene-catalyzed decarboxylative cross-electrophile coupling to access sterically hindered ketones	43
Electrochemical benzylic C–H arylation of xanthenes and thioxanthenes without a catalyst and oxidant	42
Back cover	42
Boron-catalyzed α-C–H fluorination of aryl acetic acids	42
Modular construction of sulfinimidate esters: expanding chemical space and enabling late-stage diversification	42
Synthesis of a cross-chain bridging cryptand	41
Inside front cover	40
A de novo synthesis of the bisindole alkaloid geissolosimine: collective synthesis of geissoschizoline, akuammicine, (16S)-deshydroxymethylstemmadenine and Aspidospermatan alkaloi	40
A visible light-mediated deoxygenation protocol for the synthesis of dipeptides, amides and esters without racemization	40
Gold(i)-catalyzed diastereo- and enantioselective [4 + 3] cycloadditions: construction of functionalized furano-benzoxepins	39
Inside front cover	39
“Thiol-free synthesized” and sustainable thiolating synthons for nickel-catalyzed reductive assembly of sulfides with high efficiency	39
Synthesis of the cyclic heptapeptide core of callipeltin A	39
Inside front cover	38
Front cover	38
Front cover	37
Back cover	37
Palladium-catalyzed Catellani-type selective C–H silylation of aryl-TT salts	36
4,7-Diarylbenzo[c][1,2,5]thiadiazoles as fluorophores and visible light organophotocatalysts	36
Contents list	36
Exploring N-centered umpolung reactivity in photoredox-catalyzed amidation with an α-iminoester	36
Fe-Catalyzed B–H and N–H insertion reactions of iodonium ylides	35
Alkali-amide controlled selective synthesis of 7-azaindole and 7-azaindoline through domino reactions of 2-fluoro-3-methylpyridine and aldehydes	35
Electrochemical [3 + 2]/[4 + 2] cyclization to indole-fused polycyclics	35
Metal-free meta-halogenation of cyclic diaryliodonium salts via aryne intermediates	35
Gold-catalyzed formal (3 + 2) and (4 + 2) cycloadditions of alkynes to highly functionalized dihydropyrroles and tetrahydropyridines	35
Asymmetric oxidative rearrangement of indoles enabled by dual catalysis with in situ generated acyl hypoiodite and chiral phosphoric acid	35
Application of a transient directing strategy in cyclization reactionsviaC–H activation	34
Emerging applications of acylsilanes in organic synthesis and beyond	34
Catalysts’ evolution in the asymmetric conjugate addition of nitroalkanes to electron-poor alkenes	34
Copper-catalyzed anti-stereoselective 1,2-silylamination of alkynes	34
Dinuclear zinc catalyzed asymmetric [3 + 2] spiroannulation for the synthesis of diverse bispirocyclic saccharines	34
Iridium-catalyzed highly enantioselective and chemodivergent coupling reaction of vinyl azides and vinyl benzoxazinones	34
A Cu/Cd-cocatalysed cascade reaction for constructing nitrogen-tethered 1,6-enynes enabled by 1,5-hydride transfer	34
CPL-tunable BN-embedded supramolecular macrocycles	33
Pd-catalyzed site-selective C(sp2)–H chalcogenation of amino acids and peptides using a picolinamide auxiliary	33
Paired electrochemical C–H bromination of (hetero)arenes with 2-bromoethan-1-ol	32
Carboxylation of C(sp2)–H bonds in quinolone derivatives with CO2: facile synthesis of quinolone carboxylic acids	32
Visible light metallaphotoredox catalysis in the late-stage functionalization of pharmaceutically potent compounds	32
An unexpected Lewis acid-catalyzed cascade reaction of bicyclo[1.1.0]butanes with triazinanes toward biscyclobutenyl amines	32
Visible-light-promoted desulfonylative radical difluoroalkylation between difluoroenol silyl ethers and difluoroalkyl sulfones to construct functionalized aryltetrafluoroethane derivatives	31
One-step synthesis of polycyclic thianthrenes from unfunctionalized aromatics by thia-APEX reactions	31
Syntheses of 3H-1,2,4-triazol-3-ones by copper-promoted oxidative N–N bond formation of amidines with isocyanates	31
Elucidating the mechanism and origin of diastereoselectivity in scandium-catalyzed β-C(sp3)–H activation and transformation of an aliphatic aldimine	31
Rh-catalysed divergent synthesis of polysubstituted pyrroles from α,β-unsaturated ketones via selective single or double insertion of isocyanides	31
N-Heterocycle-fused Ni(ii) porphyrin dimers upon heating of meso-amino Ni(ii) porphyrins in nitrobenzene	31
Supramolecular chiroptical sensing by achiral AIE-active thiols	31

Electrochemical switching in mechanically interlocked molecules (MIMs)	30
N-Heterocyclic carbene catalyzed base assisted C–C bond cleavage of cyclopropenones: an approach towards diastereoselective synthesis of azetidinones and benzoxazepines	30
Palladium-catalyzed [4 + 4] cycloadditions for highly diastereo- and enantioselective synthesis of functionalized benzo[b]oxocines	30
An efficient platform for decarboxylative functionalization of carboxylic acids using sulfuryl fluoride: Pd-catalyzed decarboxylative dehydrogenation of alkanecarboxylic acids and decarboxylative cros	30
A nickel-catalyzed carbon–sulfur cross-coupling reaction with disulfides enabled by mechanochemistry	30
Front cover	29
Contents list	29
Visible light-mediated syntheses of unsymmetrical methylene-bridged bis-heterocycles via an alkoxy radical relay reaction	29
Inside front cover	29
Back cover	29
Inside front cover	29
A gold-catalyzed cyclization/nucleophilic addition reaction of o-alkynylanilines with ynamides: stereoselective synthesis of 3-vinylindoles	29
Back cover	29
Visible-light-induced radical cascade cyclization of 2-isocyanobiaryls via 1,5-hydrogen atom transfer (1,5-HAT)	29
Recent advances in trifluoroethylation reaction	29
Front cover	28
Thermo-induced decarboxylative α-C(sp3)–H fluoroalkylation of glycine derivatives with fluorinated peroxy esters	28
Tetraphenylethylene[3]arene: synthesis, structure, and sensing of I−	28
Asymmetric total synthesis of norzoanthamine and formal synthesis of zoanthenol	28
Aqueous-phase tunable multi-color luminescent supramolecular assemblies based on cucurbit[10]uril-enhanced intermolecular charge-transfer interactions	28
Polyfluorinated reagents for peptide stapling	28
Generation and application of carbodiimide anions: efficient construction of 2-aminopyrimidines via a cascade [4 + 2] annulation/aromatization sequence	28
Metal-free assembly of diverse polysubstituted pyridines via an efficient cascade approach using tertiary enaminones and α,β-unsaturated sulfonylketimines	28
Front cover	28
Metal-free reductive acyldifluoroalkylation of alkenes through cooperative NHC and organophotocatalysis	28
Contents list	28
Recent advances in the diverse transformations of trifluoromethyl alkenes	28
Mechanisms of Cu/DMAP-cocatalyzed and DMAP-catalyzed C–N decarboxylative cross-coupling reactions	28
Access to chiral sulfones with an all-carbon quaternary stereocenter from sulfur dioxide	27
Efficient enantioselective synthesis of pyrazolines and isoxazolines enabled by an iridium-catalyzed intramolecular allylic substitution reaction	27
UV light-driven asymmetric vinylogous aldol reaction of isatins with 2-alkylbenzophenones and enantioselective synthesis of 3-hydroxyoxindoles	27
Platinum–P(BFPy)3-catalyzed regioselective diboration of terminal alkynes with (pin)B–B(aam)	27
Copper(i)-catalyzed multicomponent interrupted click reaction: modular synthesis of triazole sulfides from elemental sulfur	27
Pd(ii)-catalyzed B(9)-alkynylation of o/m-carboranes	27
Concise total synthesis of opioids	27
Photocatalyzed dehalogenative deuteration with silacarboxylic acids as halogen-atom transfer agents	27
Inside front cover	26
Synthesis of axially chiral biaryl-2-carboxamides through Pd(ii)-catalyzed atroposelective C–H olefination	26
Cobalt-catalyzed regioselective hydroazidation of 1-aryl-1,3-dienes: facile access to allylic azides	26
Fluorosulfonyl radicals: new horizons for the synthesis of sulfonyl fluorides	26
Formal allylic C(sp3)–H alkylation of α-alkylstyrenes by rearrangement of intermediate alkenyl sulfonium salts	26
A simple method for N-arylation of secondary amides/amines through a NaH-initiated aryne generation strategy	26
Recent advances in transition metal-catalyzed heteroannulative difunctionalization of alkenes via C–H activation for the synthesis of heterocycles	26
Interception of RCONCl2: late-stage hydrolysis and esterification of primary amides	25
Synthesis of oxa-bridged carbocycles via rhodium/Lewis acid catalyzed [3 + 3] and [4 + 3] cycloadditions of carbonyl ylides with donor–acceptor strained carbocycles	25
Visible-light-driven, catalyst-free intramolecular crossed and straight [2 + 2] cycloaddition	25
Copper(ii)-catalyzed synthesis of sulfonyl-functionalized quinone-fused cyclopenta[b]indoles via four-component cascade annulation	25
One-pot and sustainable liquid-phase peptide extension for synthesis of C-terminal amidation peptides aided by small molecular tags	25
Conjugated figure-of-eight macrocycles derived from the anthracene photodimer: synthetic execution through intramolecular cyclization and topological manipulation through ring expansion	25
The synthesis of isoxazolines and dihydrooxazines by Pd-catalyzed oxyalkynylation alkenyl oximes with alkynyl bromides	25
Front cover	25
Mechanistic insights into rhodium-catalyzed C–H activation and annulation using vinyl acetate to access cinnolines and cinnolin-4(1H)-ones	25
NHC–amine Ru complex catalyzed selective mono-N-methylation of amines with methanol: understanding the effect of amine ligands	25
Mechanistic insights into the rhodium catalysed dehydrogenative cycloaddition of cyano-yne-allene substrates	25
Alkali ion-controlled chemoselective indolation of allylic alcohols by base catalysis	24
Hydroxylation of organoborons via uranyl photocatalysis	24
Feeding sequence-regulated divergent (4 + 1 + 1′) annulations of α-bromo carbonyls and 1-azadienes via computational calculation-based mechanism elucidation	24
Upper-rim functionalised calix[4]arenes for chemoselective Au3+ detection	24
Dithiocarbamate-mediated thioamidation of arylglyoxylic acids by decarboxylative–decarbonylative C–C bond formation reactions	24
(3 + 2)-Annulation of 1,3-N,Si-tetraorganosilane reagents TsHNCH2SiBnR1R2 with arynes for efficient synthesis of 3-silaindolines	24
Commiphoratones C–E: three spiro-sesquiterpene dimers fromResina commiphora	24
Rhodium(iii)-catalyzed successive C(sp2)–H and C(sp2)–C(sp2) bond activation of aryl oximes: synthetic and mechanistic studies	24
Iron(ii)-catalyzed annulation to construct novel quinone-fused cyclopenta[2,1-b]indoles: a promising type I photosensitizer	24
Strategic convergent synthesis en route to Veratrum steroidal alkaloids	24
Pyridine-based tricarboxamides: complementary monomers for supramolecular copolymerization with C3-symmetric oligophenylenetricarboxamides	24
Transition metal-catalyzed redox-neutral 1,3-dienylation of propargylic esters and divergent synthesis	24
Synthesis of structurally diverse silicon-incorporated indolinesviasilyl radical-triggered radical cascade reactions	24
Dearomative difunctionalization of arenes via highly selective radical relay reactions	24
Cooperative palladium-catalyzed P(NEt2)3-mediated (4 + 1) annulation of isatins with 2 hydroxymethylallylcarbonates	23
Synthesis, structures and fluorescence properties ofgem-linked cyclic tetraphenylethylenes and cyclic hexaphenylethylenes	23
Access to phosphorus-containing cyclopenta[b]benzofuranols via a serendipitous cascade reaction promoted by a bifunctional phosphonium salt	23
Mechanistic insight into Ni(i)-catalyzed regioselective alkene hydroarylation: is it carbonickelation or hydronickelation?	23
Widely applicable (radio)dihalogenation of alkynes and alkenes using two different nucleophilic alkali metal halides	23
The “cobra effect” in the imidazolinone series: how a donor can disable the nucleophilicity	23
Three-component synthesis of β-aminoxy amides	23
Calix[4]pyrrole bis-crowns as ion pair receptors: cation selectivity modulated by counter anions	23
Access to enantioenriched dihydroquinoxalinones via Cu-catalyzed propargylic substitution	23
Theoretical insights into the mechanism and origin of chemoselectivity in the catalyst- and directing group-dependent oxidative cyclization of diynes with pyridine N-oxides	23
New chemistry of alkynyl trifluoroborates under transition metal catalyst-free conditions	23
Electrochemical 1,2-hydrogen atom transfer functionalizations of N-(benzyloxy)phthalimides	23

Selective halide ion binding templation effect for a quadruple-stranded-helicate enabling the activation of C–Br bonds	23
Pd-catalyzed double Heck and Heck–Suzuki cascade reaction of N-(o-bromo aryl) CF3-acrylamides	23
Leaving-group controlled N- or C-cyclization of azadienes via domino sequences: synthesis, mechanism, and chemoselectivity	22
Transition-metal-catalyzed regiodivergent sulfonylation of aziridrines for the synthesis of β-amino sulfones	22
Inside front cover	22
Formal [5 + 2] cycloaddition of ortho-indolizinyl anilines with cyclopentenediones: access to planar indolizine-fused azepines	22
Nickel-catalyzed hydroarylation reaction: a useful tool in organic synthesis	22
Regioselective construction of 2-substituted indolines enabled by a rhodium-catalyzed decarboxylation–hydroacylation sequence	22
Carbene-catalyzed imine reductive reaction: a new application of Breslow intermediates	22
H2O/D2O as the only H/D source for photocatalytic phosphine-mediated radical transfer hydrogenation/deuteration of α-aryl imino esters	22
Iodonitrene: a direct metal-free electrophilic aminating reagent	22
Distal iodine migration of arylalkynes via cyclic monoaryliodonium salts	22
Synthesis of fluorinated allylic alcoholsviaphotoinduced decarboxylative cross-coupling of α-fluoroacrylic acids and alcohols	22
Garynthone A–I, PPAPs with diverse skeletons isolated from Garcinia yunnanensis and their immunosuppressive activity	22
Recent developments on 1,2-difunctionalization and hydrofunctionalization of unactivated alkenes and alkynes involving C–S bond formation	21
Oxetane as a part of modern medicinal chemistry toolbox: the advanced synthesis of 3,3-disubstituted building blocks	21
Controlling rotary motion of molecular motors based on oxindole	21
Enantioselective construction of spirodihydrofuran oxindoles via one-pot organo-/iodine sequential catalysis	21
Ru(iii)-catalyzed C4–H bond cyanoalkoxylation of 1-naphthylamine derivatives with azobisisobutyronitrile	21
TFPN-mediated racemization/epimerization-free amide and peptide bond formation	21
Transition-metal catalyzed reactions of diazo compounds and N,N-dialkylnitrosoamines	21
Visible-light heterogeneous photocatalysis with an ionic porous organic polymer (IPOP): synthesis of β-keto sulfoxides and benzothiophene diesters by tandem radical addition–oxidation reactions	21
Nickel-catalysed C–N cross-coupling of organoboronic acids and isoxazoles	21
Visible-light-mediated defluorinative cyclization of α-fluoro-β-enamino esters catalyzed by 4-CzIPN	21
t BuOK-mediated selective 1,2-silacarboxylation of arylalkenes with Si–B/Si–Si/Si–Li reagents and CO2	21
Coupling partner-dependent unsymmetrical C–H functionalization of N-phenoxyacetamides leading to sophisticated spirocyclic scaffolds	21
The α-alkylation of carbonyl sulfoxonium ylides: studies and applications in the synthesis of new sulfur heterocycles	21
Visible light-enabled alkylation of enol acetates with alkylboronic acids for the synthesis of α-alkyl ketones	21
Photoinduced aerobic C–S borylation of aryl sulfides	21
Visible-light-induced copper-catalyzed regiodivergent C(sp3)-sulfonylation of oxime esters with sodium sulfinates	21
Enantioselective Mannich reaction of ketone enolates with imines through cooperative B/Cu catalysis	20
Total synthesis of the indolocarbazole alkaloid ZHD-0501 and its seven isomers	20
Rapid modular synthesis of indole ethers via dehydrogenative cross-coupling reaction of indoles and alcohols	20
Photoredox catalyzed release of carbon-based radicals from 2-substituted-1,3-imidazolidines	20
Photoinduced cross-coupling of aryl halides enabled by n-tetrabutylphosphonium phthalate	20
BF3-promoted reactions of α-amino acetals with alkynes to 2,5-disubstituted pyrroles	20
An N-heterocyclic carbene-catalyzed enantioselective [3 + 2] annulation of enals with propargylic imines: access to γ,γ-disubstituted pyrrolidin-2-ones bearing quaternary stereogenic centers	20
Modular synthesis of conjugated enamidines and cascade annulation toward benzofuran-3-oxoacetate	20
Electrochemical oxidative carbonylation of hydrazides for the synthesis of 1,3,4-oxadiazole-2(3H)-ones	20
Lewis acid-catalyzed regiodivergent N-alkylation of indazoles with donor–acceptor cyclopropanes	20
Rapid construction of a polysubstituted “caged” oxa-bishomocubane framework from vinylidenecyclopropanes through a sequential dual catalysis of copper(i) and visible-light-induced photosens	20
Radical-mediated carboselenation of terminal alkynes under mild conditions	20
Direct C(sp2)–H activation of allenes via hydrogen-atom transfer (HAT) in organic synthesis	20
A catalyst- and solvent-free visible-light-promoted bromination and chlorination of tertiary C(sp3)–H bonds	20
Regio- and stereo-selective construction of cis-indeno[1,2-c]isoxazoles via a C–H allylation/1,3-dipolar cycloaddition cascade	19
Synthesis of a helical boron-doped PAH by post-functionalization of 3,9-diboraperylene	19
Transition metal-free synthesis of polyfluoroaryl sulfides via S-transfer reaction	19
Facile synthesis of 5α-functionalized pyrroles via multicomponent reactions of vicinal tricarbonyl compounds, enamines, and nucleophiles	19
A domino [3 + 2] cycloaddition/deamination/imine hydrolysis reaction of cyclopropyl spirooxindoles with thiourea for access to spiro-γ-thiolactone oxindoles	19
Carbene-enabled ether activation through the formation of oxonium: a theoretical view	19
Regioselective difluoroallylation of alkylidene malonates with trifluoromethyl alkenes: synthesis of gem-difluoro-1,5-dienes and their [2 + 2] photocycloaddition	19
TBHP-mediated denitrogenative synthesis of pyridine carboxamides from pyridine carbohydrazides and amines in water	19
Rhodium-catalyzed dearomative rearrangement of 2-oxypyridines with cyclopropenes: access to N-alkylated 2-pyridones	19
Asymmetric synthesis of δ-substituted-β-keto esters and β-substituted ketones via carboxyl-assisted site- and enantio-selective addition reactions	19
Iridium-catalyzed meta-selective C–H borylation of phenol derivatives	19
Carboxylic acid-assisted sterically demanding reductive cross-coupling between cycloalkenyl and alkyl bromides	19
Acid-catalyzed ring-expansion of 4-(1-hydroxycyclobutyl)-1,2,3-triazoles	19
Radical-mediated alkene carboamination/dearomatization of arylsulfonyl-o-allylanilines via photoredox catalysis	19
Unusual DBU-catalyzed decarboxylative formation of allylic thioethers from vinyl cyclic carbonates and thiols	19
Base-promoted transition metal-free phosphorylation/acylation of 2-vinyl pyridines with Ph2PCl and carboxylic acids	19
Bridgehead epoxide iso-euphoranin E from β-caryophyllene oxide via sequential cationic formation and scission of [4.3.2]propellane	19
Mechanistic insights into the rhodium-catalyzed aryl C–H carboxylation	19
An umpolung mechanism of B(pin)-mediated Cu/B rearrangement and origin of regioselectivity for NHC-Cu-catalyzed allylation of imines	19
2,7-Dinitrophenanthrene-9,10-dione as a photosensitizer for the dehydrogenative lactonization of 2-arylbenzoic acids	19
N-heterocyclic nitrenium charge transfer catalysis via inner-sphere electron transfer in concert with halogen-atom dissociation	18
A rhodium-catalyzed ylide formation/Smiles rearrangement reaction of chalcogenide ether and triazoles	18
Enantioselective [3 + 2] annulation of tryptanthrin-derived ketimines and 2-naphthols: access to polycyclic indolo[2,1-b]quinazoline derivatives	18
Transition-metal free oxidative carbo-carboxylation of alkenes with formate in air	18
Catalytic asymmetric cyclopropanation of sulfoxonium ylides catalyzed by a chiral-at-metal rhodium complex	18
Acid-mediated decarboxylative C–H coupling between arenes and O-allyl carbamates	18
Dendron-mediated control over self-assembly of chlorophyll rosettes into columnar vs. discrete aggregates	18
Coordination assembly and NIR photothermal conversion of Cp*Rh-based supramolecular topologies based on distinct conjugated systems	18
Front cover	18
Experimental and computational studies on the palladium-catalyzed intramolecular dearomatization, electrophilic addition, intermolecular coupling sequence	18
N-Sulfenyl phthalimide enabled Markovnikov hydrothiolation of unactivated alkenes via ligand promoted cobalt catalysis	18
New tertiary amine-derived C2-symmetric chiral pyridine-N,N′-dioxide ligands and their applications in asymmetric catalysis	18
A strategy for regioselective B–H functionalization ofo-carboranesviabase metal catalysis	18
Chemical transformation of doubly N-confused porphodimethenes to variants of (anti)aromatic doubly N-confused porphyrinoids and σ-aromatic doubly N-confused isophlorinoids	18
How the electron-deficient Cp ligand facilitates Rh-catalyzed annulations with alkynes	18
A visible-light-induced cascade cyclization strategy for the synthesis of N,S-containing polycyclic compounds	18
Successive energy-transfer catalytic dearomative reactions of quinolines with bicyclo[1.1.0]butanes for the synthesis of pyridine-fused 3D complicated molecules	18
21-Carba-23-oxaporphyrinoids and 21-oxo-21-carba-23-oxaporphyrinoids: macrocyclic π-conjugation involving the carbonyl moiety	18
Electrochemical synthesis and transformation of organoboron compounds	18
Front cover	18
Atom-controlled divergent synthesis of spiro and fused rings via base-catalyzed chemoselective annulation	18
A cascade indazolone-directed Ir(iii)- and Rh(iii)-catalyzed C(sp2)–H functionalization/[4 + 2] annulation of 1-arylindazolones with sulfoxonium ylides to access chemi	18
Silver-catalyzed [4 + 3] cycloaddition of 1,3-dienes with alkenyl-N-triftosylhydrazones: a practical approach to 1,4-cycloheptadienes	18
Phenanthrene[2]arene: synthesis and application as nonporous adaptive crystals in the separation of benzene from cyclohexane	18
Catalytic alkane C–H functionalization by carbene insertion into unactivated C(sp3)–H bonds	18
Copper-catalyzed regioselective 1,4-sulfonylcyanation of 1,3-enynes with sulfonyl chlorides and TMSCN	18
Inside front cover	18
Enantioselective construction of planar, axially and central chiral ferrocenyl phosphines via a Pd-catalyzed domino reaction and diastereoselective phosphination	17
Phosphine-mediated formal [5 + 1] aminobenzannulations of Morita–Baylis–Hillman carbonates with isocyanates	17
Design, synthesis and application of bipyridine-N,N′-dioxide catalysts in asymmetric synthesis of chiral cyclopropanes	17
A metal-free sigmatropic rearrangement/cyclization/aromatization cascade reaction of hydroxy/aminophenyl propargyl alcohols with fluoroalkanesulfinyl chlorides: synthesis of 3-fluoroalkanesulfonyl ben	17