Organic Chemistry Frontiers

Papers
(The TQCC of Organic Chemistry Frontiers is 8. The table below lists those papers that are above that threshold based on CrossRef citation counts [max. 250 papers]. The publications cover those that have been published in the past four years, i.e., from 2020-02-01 to 2024-02-01.)
ArticleCitations
Stereoselective synthesis and applications of spirocyclic oxindoles161
Recent advances in multi-component reactions and their mechanistic insights: a triennium review152
Recent advances in organocatalytic asymmetric multicomponent cascade reactions for enantioselective synthesis of spirooxindoles120
Recent advance in the C–F bond functionalization of trifluoromethyl-containing compounds119
Recent advances in transition metal-catalyzed olefinic C–H functionalization111
Recent advances in cascade radical cyclization of radical acceptors for the synthesis of carbo- and heterocycles92
Palladium catalyzed C–C and C–N bond forming reactions: an update on the synthesis of pharmaceuticals from 2015–202090
Recent advances in sustainable synthesis of N-heterocycles following acceptorless dehydrogenative coupling protocol using alcohols89
Advances in organocatalytic asymmetric reactions of vinylindoles: powerful access to enantioenriched indole derivatives82
Recent developments in the difunctionalization of alkenes with C–N bond formation82
Nitriles as radical acceptors in radical cascade reactions69
Hole-mediated photoredox catalysis: tris(p-substituted)biarylaminium radical cations as tunable, precomplexing and potent photooxidants69
Recent advances in electrochemically driven radical fluorination and fluoroalkylation67
Fluorination and fluoroalkylation of alkenes/alkynes to construct fluoro-containing heterocycles67
Photochemical and electrochemical strategies in C–F bond activation and functionalization64
Recent advances in hydride transfer-involved C(sp3)–H activation reactions62
Recent advances on transition-metal-catalysed asymmetric reductive amination62
Visible light-mediated applications of methylene blue in organic synthesis62
Catalytic asymmetric synthesis of monofluoroalkenes and gem-difluoroalkenes: advances and perspectives59
Recent advances in annulation reactions based on zwitterionic π-allyl palladium and propargyl palladium complexes57
Green strategies for transition metal-catalyzed C–H activation in molecular syntheses56
Chemoselective hydroborative reduction of nitro motifs using a transition-metal-free catalyst54
RhIII-Catalyzed formal [5 + 1] cyclization of 2-pyrrolyl/indolylanilines using vinylene carbonate as a C1 synthon54
Recent advances in visible-light photocatalytic deuteration reactions52
Visible-light-induced metal-free cascade cyclization of N-arylpropiolamides to 3-phosphorylated, trifluoromethylated and thiocyanated azaspiro[4.5]trienones50
Generation of azolium dienolates as versatile nucleophilic synthonsvia N-heterocyclic carbene catalysis50
Benzannulation strategies for the synthesis of carbazoles, indolocarbazoles, benzocarbazoles, and carbolines49
Cycloaddition of CO2 to epoxides by highly nucleophilic 4-aminopyridines: establishing a relationship between carbon basicity and catalytic performance by experimental and DFT investigation49
State-of-the-art palladium-catalyzed alkoxycarbonylations47
The Ugi three-component reaction and its variants47
Recent advances in the electrochemical generation of 1,3-dicarbonyl radicals from C–H bonds47
Unravelling nitrene chemistry from acyclic precursors: recent advances and challenges46
Recent advances in the functionalization of saturated cyclic amines45
Recent progress in the total synthesis of pyrrole-containing natural products (2011–2020)45
Visible light photocatalysis in the synthesis of pharmaceutically relevant heterocyclic scaffolds45
Recent advances in the asymmetric transformations of achiral cyclohexadienones44
Recent advances in the synthesis and reactivity of quinoxaline43
Recent advances of Ritter reaction and its synthetic applications41
Recent advances in transition-metal-free trifluoromethylation with Togni's reagents41
The oxa-Michael reaction in the synthesis of 5- and 6-membered oxygen-containing heterocycles40
Structural characterisation of natural products by means of quantum chemical calculations of NMR parameters: new insights40
Multifunctional P-ligand-controlled “silicon-centered” selectivity in Rh/Cu-catalyzed Si–C bond cleavage of silacyclobutanes39
Recent advances in photo- and electro-enabled radical silylation38
Recent advances in quinazolinones as an emerging molecular platform for luminescent materials and bioimaging38
NHC-catalyzed oxindole synthesis via single electron transfer36
Recent advances in transition metal-catalyzed heteroannulative difunctionalization of alkenes via C–H activation for the synthesis of heterocycles36
Metal-hydride hydrogen atom transfer (MHAT) reactions in natural product synthesis36
C(sp3)–H functionalization with isocyanides36
Recent advances in the catalytic asymmetric construction of atropisomers by central-to-axial chirality transfer35
Recent advances of chromone-based reactants in the catalytic asymmetric domino annulation reaction35
Cyanation: a photochemical approach and applications in organic synthesis35
Photo-induced transition-metal and external photosensitizer-free organic reactions35
Visible-light-induced direct 3-ethoxycarbonylmethylation of 2-aryl-2H-indazoles in water34
An iron-catalyzed multicomponent reaction of cycloketone oxime esters, alkenes, DABCO·(SO2)2 and trimethylsilyl azide34
Recent progress on the construction of axial chirality through transition-metal-catalyzed benzannulation34
State of knowledge in photoredox-catalysed direct difluoromethylation34
Organocatalytic electrochemical amination of benzylic C–H bonds33
Photoinitiated stereoselective direct C(sp2)–H perfluoroalkylation and difluoroacetylation of enamides33
Synthesis of trisubstituted hydroxylamines by a visible light-promoted multicomponent reaction33
An unusual reaction mode of 1-phenylpyrazolidinones toward diazonaphthalen-2(1H)-ones featuring cascade C(sp2)–H and C(sp3)–H bond cleavage32
Recent advances in the direct transformation of propargylic alcohols to allenes32
Recent advances in the synthesis of indole embedded heterocycles with 3-diazoindolin-2-imines32
1,3-Difunctionalization of alkenes: state-of-the-art and future challenges31
Electrochemical synthesis of functionalized gem-difluoroalkenes with diverse alkyl sources via a defluorinative alkylation process31
Visible-light-induced iodine-anion-catalyzed decarboxylative/deaminative C–H alkylation of enamides31
Photocatalytic intramolecular radical cyclization involved synergistic SET and HAT: synthesis of 3,3-difluoro-γ-lactams30
Photoredox-catalyzed direct C(sp2)–H difluoromethylation of enamides or heterocycles with [bis(difluoroacetoxy)iodo]benzene30
I2-Promoted site-selective C–C bond cleavage of aryl methyl ketones as C1 synthons for constructing 5-acyl-1H-pyrazolo[3,4-b]pyridines30
An organophotoredox-catalyzed redox-neutral cascade involving N-(acyloxy)phthalimides and maleimides30
Covalent organic framework-based membranes for liquid separation30
Photocatalytic transition-metal-free direct 3-alkylation of 2-aryl-2H-indazoles in dimethyl carbonate30
Organocatalytic regio-, diastereo- and enantioselective γ-additions of isoxazol-5(4H)-ones to β,γ-alkynyl-α-imino esters for the synthesis of axially chiral tetrasubstituted α-amino allenoates30
Visible-light-induced radical cascade cyclization of 1-(allyloxy)-2-(1-arylvinyl)benzenes with sulfonyl chlorides for the synthesis of sulfonated benzoxepines30
Keep glowing and going: recent progress in diketopyrrolopyrrole synthesis towards organic optoelectronic materials30
J-aggregation induced emission enhancement of BODIPY dyes via H-bonding directed supramolecular polymerization: the importance of substituents at boron29
A visible-light photoredox-catalyzed four-component reaction for the construction of sulfone-containing quinoxalin-2(1H)-ones29
Electrochemically promoted C-3 amination of 2H-indazoles29
Recent advances in transition metal-catalyzed reactions of carbamoyl chlorides29
Trichloranoids A–D, antimalarial sesquiterpenoid trimers from Chloranthus spicatus28
Recent developments in the asymmetric synthesis and functionalization of symmetrical and unsymmetricalgem-diborylalkanes28
Photocatalytic decarboxylative alkylation of silyl enol ether and enamide with N-(acyloxy)phthalimide using ammonium iodide28
Iminyl radical initiated sulfonylation of alkenes with rongalite under photoredox conditions28
Efficient access to β-amino acid ester/β-amino ketone derivatives via photocatalytic radical alkoxycabonylimidation/carbonylimidation of alkenes28
The dark side of photocatalysis: near-infrared photoredox catalysis for organic synthesis28
Data augmentation and transfer learning strategies for reaction prediction in low chemical data regimes28
Diastereoselective construction of cage-like and bridged azaheterocycles through dearomative maximization of the reactive sites of azaarenes28
Coordination-assisted, transition-metal-catalyzed enantioselective desymmetric C–H functionalization28
Recent advances in sustainable organic transformations using methanol: expanding the scope of hydrogen-borrowing catalysis28
Recent developments in the synthesis of azaindoles from pyridine and pyrrole building blocks28
Metal-free electrochemical C3-sulfonylation of imidazo[1,2-a]pyridines28
Aliphatic sulfonyl fluoride synthesis via reductive decarboxylative fluorosulfonylation of aliphatic carboxylic acid NHPI esters27
(±)-Pinnatifidaones A–D, four pairs of highly modified neolignan enantiomers with a rare spirocyclohexenone skeleton from Crataegus pinnatifida27
A photoredox- or metal-catalyzed three-component cyanoalkylsulfonylation reaction of 1-(allyloxy)-2-(1-arylvinyl)benzenes, potassium metabisulfite, and cycloketone oxime esters: synthesis of cyanoalky27
Visible-light induced divergent dearomatization of indole derivatives: controlled access to cyclobutane-fused polycycles and 2-substituted indolines27
Organophotoelectrochemical silylation cyclization for the synthesis of silylated 3-CF3-2-oxindoles27
Visible-light-promoted sulfonylation of thiols with aryldiazonium and sodium metabisulphite leading to unsymmetrical thiosulfonates27
An electrochemical perspective on the roles of ligands in the merger of transition-metal catalysis and electrochemistry27
A supramolecular dual-donor artificial light-harvesting system with efficient visible light-harvesting capacity27
Copper-catalyzed regio- and chemoselective selenosulfonylation of 1,6-enynes from sulfur dioxide27
Synthesis of 3-spirooxindole 3H-indoles through Rh(iii)-catalyzed [4 + 1] redox-neutral spirocyclization of N-aryl amidines with diazo oxindoles27
A comprehensive review of caged phosphines: synthesis, catalytic applications, and future perspectives26
Stereoselective synthetic strategies of stereogenic carbon centers featuring a difluoromethyl group26
Catalytic asymmetric dearomative [4 + 2] annulation of 2-nitrobenzofurans and 5H-thiazol-4-ones: stereoselective construction of dihydrobenzofuran-bridged polycyclic skeletons26
The ammoxidation of alcohols over heterogeneous catalysts for the green synthesis of nitriles26
Recent advances for the synthesis of chiral sulfones with the sulfone moiety directly connected to the chiral center26
A multi-component reaction of electron-rich arenes, potassium metabisulfite, aldehydes and aryldiazonium tetrafluoroborates26
Generation and precise control of sulfonyl radicals: visible-light-activated redox-neutral formation of sulfonates and sulfonamides25
Visible light-mediated radical-cascade addition/cyclization of arylacrylamides with aldehydes to form quaternary oxindoles at room temperature25
Metal-free visible-light-induced aerobic oxidation of α-diazoesters leading to α-ketoesters in air25
Organocatalytic stereoselective 1,6-addition of thiolacetic acids to alkynyl indole imine methides: access to axially chiral sulfur-containing tetrasubstituted allenes25
Facile access to benzofuran-fused tetrahydropyridines via catalytic asymmetric [4 + 2] cycloaddition of aurone-derived 1-azadienes with 3-vinylindoles25
A desulphurization strategy for Sonogashira couplings by visible light/copper catalysis25
Recent developments on 1,2-difunctionalization and hydrofunctionalization of unactivated alkenes and alkynes involving C–S bond formation25
Regio- and stereoselective electrochemical selenoalkylation of alkynes with 1,3-dicarbonyl compounds and diselenides25
Multiple-fold C–F bond functionalization for the synthesis of (hetero)cyclic compounds: fluorine as a detachable chemical handle25
Recent advances in thiolation via sulfur electrophiles25
Paired electrochemical C–H bromination of (hetero)arenes with 2-bromoethan-1-ol25
Pyrene and triphenylamine substituted cyanostyrene and cyanostilbene derivatives with dual-state emission for high-contrast mechanofluorochromism and cell imaging24
Divergent synthesis of fused N-heterocyclesviarhodium-catalysed [4 + 2] cyclization of pyrazolidinones with iodonium ylides24
Construction of sulfonated spiro[5,5]trienones from sulfur dioxide via iron-catalyzed dearomative spirocyclization of biaryls24
Phthalimide-based-SSCF3 reagent for enantioselective dithiotrifluoromethylation24
Electrochemical radical C(sp3)–H arylation of xanthenes with electron-rich arenes24
Modulating the properties of buckybowls containing multiple heteroatoms24
Direct synthetic routes to functionalised crown ethers24
Synthetic developments on the preparation of sulfides from thiol-free reagents24
Palladium-catalyzed direct reductive cross-coupling of aryltrimethylammonium salts with aryl bromides23
Synthesis of C3-alkylated benzofurans via palladium-catalyzed regiocontrolled hydro-furanization of unactivated alkenes23
Pd/LA-catalyzed decarboxylation enabled exclusive [5 + 2] annulation toward N-aryl azepanes and DFT insights23
Remote C(sp3)–H functionalizationviacatalytic cyclometallation: beyond five-membered ring metallacycle intermediates23
Nine sesquiterpenoid dimers with four unprecedented types of carbon skeleton from Chloranthus henryi var. hupehensis23
Cp*Ir(iii)- and Cp*Rh(iii)-catalyzed C(sp2)–H amination of arenes using thioethers as directing groups23
Recent development in asymmetric organocatalytic domino reactions involving 1,6-addition as a key step23
Synthesis of isoxazolidines via catalyst-free one-pot three-component cycloaddition of sulfoxonium ylides, nitrosoarenes and alkenes23
C–H hetero-functionalization of arenes through palladacyclopentane-type intermediates23
Molecular editing in natural product synthesis23
Photoredox-catalyzed chemoselective aerobic Cα–H oxidation of propargylamines: synthesis of substituted 2-ynamide and oxazolo[2,3-a]isoquinolinone derivatives23
Site-selective modification of peptide backbones23
Photoinduced C–H monofluoroalkenylation with gem-difluoroalkenes through hydrogen atom transfer under batch and flow conditions22
Strategies and methodologies for the construction of spiro-γ-lactams: an update22
Regio- and enantioselective ring-opening reaction of vinylcyclopropanes with indoles under cooperative catalysis22
A one-pot stepwise approach to axially chiral quinoline-3-carbaldehydes enabled by iminium–allenamine cascade catalysis22
Electrochemical oxidative selenocyclization of olefinic amides towards the synthesis of iminoisobenzofurans22
Photoredox-catalyzed 2,2,2-trifluoroethylation and 2,2-difluoroethylation of alkenes with concomitant introduction of a quinoxalin-2(1H)-one moiety22
Organocatalytic asymmetric synthesis of multifunctionalized α-carboline-spirooxindole hybrids that suppressed proliferation in colorectal cancer cells22
Synergistic photoredox and tertiary amine catalysis: generation of allylic sulfones from Morita–Baylis–Hillman acetates and sulfur dioxide22
Synthesis of 5-trifluoromethyl-1,2,3-triazoles via base-mediated cascade annulation of diazo compounds with trifluoroacetimidoyl chlorides22
Brønsted acid-catalyzed homogeneous O–H and S–H insertion reactions under metal- and ligand-free conditions22
Photocatalyst- and additive-free decarboxylative alkylation ofN-aryl tetrahydroisoquinolines induced by visible light22
Asymmetric total synthesis and antidepressant activity of (−)-sila-mesembranol bearing a silicon stereocenter22
Generation of (E)-β-sulfonyl enamines from sulfur dioxide via a radical process21
Tunable C–H arylation and acylation of azoles with carboxylic acids by Pd/Cu cooperative catalysis21
Metal-free visible-light-induced photoredox-catalyzed intermolecular pyridylation/phosphinoylation of alkenes21
Visible-light-mediated synthesis of quinolines21
Site-selective and diastereoselective functionalization of α-amino acid and peptide derivatives via palladium-catalyzed sp3 C–H activation21
Construction and transformations of 2,2-difluoro-2,3-dihydrofurans from enaminones and diflurocarbene21
Visible-light-initiated catalyst-free trifluoromethylselenolation of arylsulfonium salts with [Me4N][SeCF3]21
Copper-catalyzed, N-directed remote C(sp3)–H azidation and thiocyanation21
Three-component photoredox 1,2-alkylamination of styrenes with alkanes and nitrogen nucleophiles via C(sp3)–H bond cleavage21
Recent advances in transition-metal catalyzed directed C–H functionalization with fluorinated building blocks21
Cyanation and cyanomethylation of trimethylammonium salts via electrochemical cleavage of C–N bonds21
Alkoxycarbonyl radicals from alkyloxalyl chlorides: photoinduced synthesis of isoquinolinediones under visible light irradiation21
Visible light induced deaminative alkylation of difluoroenoxysilanes: a transition metal free strategy20
Electrochemically-mediated C–H functionalization of allenes and 1,3-dicarbonyl compounds to construct tetrasubstituted furans20
Copper-mediated [3 + 2] cycloaddition of trifluoroacetimidoyl chlorides and N-isocyanoiminotriphenylphosphorane for the synthesis of 3-trifluoromethyl-1,2,4-triazoles20
A unique high-diversity natural product collection as a reservoir of new therapeutic leads20
Noncovalent interactions in Ir-catalyzed remote C–H borylation: a recent update20
Visible light mediated functionalization of allenes20
Trimeric and dimeric sesquiterpenoids from Artemisia atrovirens and their cytotoxicities20
Ruthenium-catalysed C–H/C–N bond activation: facile access to isoindolinones20
The indole nucleus as a selective COX-2 inhibitor and anti-inflammatory agent (2011–2022)20
Asymmetric total synthesis of cephanolide B20
Ruthenium(ii)-catalyzed synthesis of CF3-isoquinolinones via C–H activation/annulation of benzoic acids and CF3-imidoyl sulfoxonium ylides20
Nickel-catalyzed reductive aminocarbonylation of vinyl triflates with nitro compounds for the synthesis of α,β-unsaturated amides20
Iron-catalysed chemo- and ortho-selective C–H bond functionalization of phenols with α-aryl-α-diazoacetates20
Advances in circularly polarized electroluminescence based on chiral TADF-active materials20
Achievements in fluorination using variable reagents through a deoxyfluorination reaction20
Insights into the chiral sulfide/selenide-catalyzed electrophilic carbothiolation of alkynes: mechanism and origin of axial chirality19
Metal-free synthesis of sulfonylated indolo[2,1-a]isoquinolines from sulfur dioxide19
ortho-Ethynyl group assisted regioselective and diastereoselective [2 + 2] cross-photocycloaddition of alkenes under photocatalyst-, additive-, and solvent-free conditions19
Recent advances in the application of ylide-like species in [4 + 1]-annulation reactions: an updated review19
Cu-Catalyzed radical-triggered spirotricyclization of enediynes and enyne-nitriles for the synthesis of pentacyclic spiroindenes19
Atroposelective carbonylation of aryl iodides with amides: facile synthesis of enantioenriched cyclic and acyclic amides19
Silver-catalyzed decarboxylative radical relay difluoroalkylation–carbocyclization: convenient access to CF2-containing quinolinones19
Redox-triggered dearomative [5 + 1] annulation of indoles with O-alkyl ortho-oxybenzaldehydes for the synthesis of spirochromanes19
Visible-light-induced and copper-catalyzed oxidative cyclization of substituted o-aminophenylacetylene for the synthesis of quinoline and indole derivatives19
Visible light metallaphotoredox catalysis in the late-stage functionalization of pharmaceutically potent compounds19
Metal-free electrochemical synthesis of α-ketoamides via decarboxylative coupling of α-keto acids with isocyanides and water19
Pyrrole synthesis through Cu-catalyzed cascade [3 + 2] spiroannulation/aromatization of oximes with azadienes19
Electrochemical oxidative synthesis of 1,3,4-thiadiazoles from isothiocyanates and hydrazones19
Chiral phosphoric acid-catalyzed regio- and enantioselective reactions of functionalized propargylic alcohols19
Palladium-catalyzed [2 + 2 + 1] annulation: access to chromone fused cyclopentanones with cyclopropenone as the CO source19
An electrolyte- and catalyst-free electrooxidative sulfonylation of imidazo[1,2-a]pyridines19
Synthesis of tetracyclic indenopyrazolopyrazolones through cascade reactions of aryl azomethine imines with propargyl alcohols19
Photo-induced weak base-catalyzed synthesis of α-haloboronates from vinylboronates and polyfluoroalkyl halides19
Metal-free oxidative cyclization of trifluoroacetimidohydrazides with methylhetarenes: a facile access to 3-hetaryl-5-trifluoromethyl-1,2,4-triazoles19
Phenolate anion-catalyzed direct activation of inert alkyl chlorides driven by visible light18
Synthesis of γ-amino acids via photocatalyzed intermolecular carboimination of alkenes18
Photocatalytic three-component radical cascade: a general route to heterocyclic-substituted alkyl sulfones18
Lewis acid-catalyzed regioselective C–H carboxamidation of indolizines with dioxazolonesviaan acyl nitrene type rearrangement18
A visible light-mediated three-component strategy based on the ring-opening of cyclic ethers with aryldiazoacetates and nucleophiles18
Dibenzopleiadiene-embeded polyaromatics via [4 + 3] annulative decarbonylation/decarboxylation18
Design of (β-diazo-α,α-difluoroethyl)phosphonates and their application as masked carbenes in visible light-promoted coupling reactions with sulfonic acids18
Site-selective electrochemical thiocyanation of benzylic C–H bonds18
General and practical intramolecular decarbonylative coupling of thioesters via palladium catalysis18
Nickel-catalyzed electrochemical reductive relay cross-coupling of alkyl halides with alkyl carboxylic acids18
Photocatalytic intermolecular anti-Markovnikov hydroamination of unactivated alkenes with N-hydroxyphthalimide18
Regioselective intramolecular sp2 C–H amination: direct vs. mediated electrooxidation18
Rh(iii)-Catalyzed tandem C(sp2)–H allylation/N-alkylation annulation of arene amides with 2-alkylidenetrimethylene carbonates18
Theoretical model for N-heterocyclic carbene-catalyzed decarboxylation reactions18
Direct C(sp3)–H difluoromethylation via radical–radical cross-coupling by visible-light photoredox catalysis18
Merging dearomatization with redox-neutral C(sp3)–H functionalization via hydride transfer/cyclization: recent advances and perspectives18
Palladium-catalyzed tandem Heck/carbonylation/aminocarbonylation en route to chiral heterocyclic α-ketoamides18
Catalyst-controlled cycloisomerization/[4 + 3] cycloaddition sequence to construct 2,3-furan-fused dihydroazepines and 2,3-pyrrole-fused dihydrooxepines18
Total synthesis of kopsine, fruticosine, and structurally related polycyclic caged Kopsia indole alkaloids18
Photocatalytic three-component annulation enabling stereoselective generation of (Z)-thiochromene 1,1-dioxides18
Synthetic applications of α,α-difluoroarylacetic acids and salts via decarboxylative functionalization18
Photoredox-catalyzed synthesis of sulfonated oxazolines from N-allylamides through the insertion of sulfur dioxide18
Chemo- and enantioselective hetero-coupling of hydroxycarbazoles catalyzed by a chiral vanadium(v) complex18
Organocatalytic dimensions to the C–H functionalization of the carbocyclic core in indoles: a review update18
Decarboxylative C–H alkylation of heteroarenes by copper catalysis18
Nickel-catalyzed direct cross-coupling of heterocyclic phosphonium salts with aryl bromides18
A photocatalytic radical relay reaction of 2-methylthiolated phenylalkynones and potassium metabisulfite17
Cu-Catalyzed highly selective silylation and borylation of alkenylsulfonium salts17
Synthesis of benzofuro- and benzothieno[2,3-c]pyridines via copper-catalyzed [4 + 2] annulation of ketoxime acetates with acetoacetanilide17
Reagent-free aerobic oxidative synthesis of amides from aldehydes and isothiocyanates17
Divergent synthesis of unsymmetrical azobenzenes via Cu-catalyzed C–N coupling17
Rhodium(iii)-catalyzed C–H activation/annulation of N-iminopyridinium ylides with alkynes and diazo compounds17
Ruthenium catalyzed α-methylation of sulfones with methanol as a sustainable C1 source17
SOMOphilic alkynylation using acetylenic sulfones as functional reagents17
Asymmetric hydrogenation and transfer hydrogenation in the enantioselective synthesis of flavonoids17
Xanthanoltrimer A–C: three xanthanolide sesquiterpene trimers from the fruits of Xanthium italicum Moretti isolated by HPLC-MS-SPE-NMR17
Metal-free visible-light-induced multi-component reactions of α-diazoesters leading to S-alkyl dithiocarbamates17
Multiple [n]helicenes with various aromatic cores17
Recent advances in NHC–palladium catalysis for alkyne chemistry: versatile synthesis and applications17
Pd(ii)-Catalyzed enantioconvergent twofold C–H annulation to access atropisomeric aldehydes: a platform for diversity-oriented-synthesis17
Construction of diverse C–S/C–Se bonds via nickel catalyzed reductive coupling employing thiosulfonates and a selenosulfonate under mild conditions17
Phenanthrene[2]arene: synthesis and application as nonporous adaptive crystals in the separation of benzene from cyclohexane17
Amidyl radical-mediated aminodifluoroallylation of alkenes via photoredox catalysis17
K2S2O8-mediated acylarylation of unactivated alkenes via acyl radical addition/C–H annulation cascade of N-allyl-indoles with silver cocatalysis17
Electrochemical benzylic C–H arylation of xanthenes and thioxanthenes without a catalyst and oxidant17
The catalytic role of elemental sulfur in the DMSO-promoted oxidative coupling of methylhetarenes with amines: synthesis of thioamides and bis-aza-heterocycles17
Access to axially chiral aryl 1,3-dienes by transient group directed asymmetric C–H alkenylations17
Palladium-catalyzed synthesis of spirooxindoles and [3,4]-fused oxindoles from alkene-tethered carbamoyl chlorides17
Recent progress in rare-earth metal-catalyzed sp2 and sp3 C–H functionalization to construct C–C and C–heteroelement bonds17
Alkylsulfonium salts for the photochemical desulphurizative functionalization of heteroarenes17
Transition-metal-free synthesis of 5-amino-1,2,3-triazoles via nucleophilic addition/cyclization of carbodiimides with diazo compounds17
Recent advances in cyclization reactions of isatins or thioisatins via C–N or C–S bond cleavage17
Visible light-driven fluoroalkylthiocyanation of alkenes via electron donor–acceptor complexes17
Zirconium-hydride-catalyzed transfer hydrogenation of quinolines and indoles with ammonia borane17
Derivatization based on tetrazine scaffolds: synthesis of tetrazine derivatives and their biomedical applications17
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