Organic Chemistry Frontiers

Article	Citations
Electrochemical [3 + 2]/[4 + 2] cyclization to indole-fused polycyclics	132
Carboxylation of C(sp2)–H bonds in quinolone derivatives with CO2: facile synthesis of quinolone carboxylic acids	92
CPL-tunable BN-embedded supramolecular macrocycles	90
Computational investigation of palladium-catalyzed allene–allene cross-coupling	87
N-heterocyclic carbene-catalyzed decarboxylative cross-electrophile coupling to access sterically hindered ketones	82
Visible-light-promoted desulfonylative radical difluoroalkylation between difluoroenol silyl ethers and difluoroalkyl sulfones to construct functionalized aryltetrafluoroethane derivatives	80
Copper-catalyzed anti-stereoselective 1,2-silylamination of alkynes	79
An efficient platform for decarboxylative functionalization of carboxylic acids using sulfuryl fluoride: Pd-catalyzed decarboxylative dehydrogenation of alkanecarboxylic acids and decarboxylative cros	78
Palladium-catalyzed Catellani-type selective C–H silylation of aryl-TT salts	78
Hierarchical amplification of chirality in anion-coordinated tetrahedral cages	73
One-step synthesis of polycyclic thianthrenes from unfunctionalized aromatics by thia-APEX reactions	71
Boron-catalyzed α-C–H fluorination of aryl acetic acids	70
Intramolecular exciplex formation between pyrene and tetraazapyrene in supramolecular assemblies	69
Synthesis of the cyclic heptapeptide core of callipeltin A	65
A nickel-catalyzed carbon–sulfur cross-coupling reaction with disulfides enabled by mechanochemistry	63
Emerging applications of acylsilanes in organic synthesis and beyond	59
Sequence-sorted redox-switchable hetero[3]rotaxanes	56
Catalytic asymmetric synthesis of 3,4′-indole–pyrazole derivatives featuring axially chiral bis-pentatomic heteroaryls	55
Bromide-catalyzed oxo-amination of alkenes towards the synthesis of α-amine ketones under photoelectrocatalysis conditions	55
Modular dehydrogenative cross-nucleophile coupling for direct construction of tetrasubstituted carbons	54
Exploring N-centered umpolung reactivity in photoredox-catalyzed amidation with an α-iminoester	54
Photoredox catalyzed hydroazolylation of alkenes via phosphoranyl radicals	54
Fe-Catalyzed B–H and N–H insertion reactions of iodonium ylides	53
An unexpected Lewis acid-catalyzed cascade reaction of bicyclo[1.1.0]butanes with triazinanes toward biscyclobutenyl amines	52
Copper-catalyzed synthesis of cyclopropyl bis(boronates) from aryl olefins and carbon monoxide	52

Visible light-promoted Pd-catalyzed regioselective 1,4-dicarbofunctionalization of 1,3-butadiene with unactivated bromides and malononitriles	52
Modular construction of sulfinimidate esters: expanding chemical space and enabling late-stage diversification	52
Visible-light induced C(sp3)–S cross-coupling via electron donor–acceptor complexes and 1,2-hydrogen atom transfer	51
Rapid construction of the [5–6–6] tricyclic core of sinudenoids B–D enabled by a tandem oxidation-intramolecular Diels–Alder reaction	51
Visible light-mediated syntheses of unsymmetrical methylene-bridged bis-heterocycles via an alkoxy radical relay reaction	51
Catalysts’ evolution in the asymmetric conjugate addition of nitroalkanes to electron-poor alkenes	51
A de novo synthesis of the bisindole alkaloid geissolosimine: collective synthesis of geissoschizoline, akuammicine, (16S)-deshydroxymethylstemmadenine and Aspidospermatan alkaloi	51
Reductive activation of arenes by potassium metal with potassium salts	51
Synthesis of a cross-chain bridging cryptand	50
Supramolecular chiroptical sensing by achiral AIE-active thiols	50
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Contents list	47
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Synthesis of morpholino nucleosides starting from enantiopure glycidol	45
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Iridium-catalyzed highly enantioselective and chemodivergent coupling reaction of vinyl azides and vinyl benzoxazinones	44
Organocatalytic asymmetric [3 + 3] annulations of 3-carboxamide oxindoles with β,γ-unsaturated α-keto esters: facile access to chiral spiro-δ-lactam oxindoles	44
Iminophosphorane in perylenediimide chemistry: Staudinger reaction and a visible-light-driven competitive reaction of the Cadogan cyclization	44
Direct synthesis of gold(iii)-annulated perylene diimides via multiple C–H aurations	44
Cyclocondensation reactions of racemic diastereomers of dimethyl-2-oxocyclohexanepropionic acids with (R)-phenylglycinol: access to both enantiomers of dimethylcis-decahydroquinolines	44
Metal-free meta-halogenation of cyclic diaryliodonium salts via aryne intermediates	44
N-Heterocyclic carbene catalyzed base assisted C–C bond cleavage of cyclopropenones: an approach towards diastereoselective synthesis of azetidinones and benzoxazepines	43
Photoredox-catalyzed intramolecular oxy- and aminoacylation of alkenes with acyl oxime esters: facile synthesis of acylated saturated heterocycles	43
Fused-ring molecules based on B ← N and imide units with low energy levels	43
Syntheses of 3H-1,2,4-triazol-3-ones by copper-promoted oxidative N–N bond formation of amidines with isocyanates	42
Copper-catalyzed alkynyldisulfuration of arynes: efficient access to unsymmetrical disulfides	42
Regio- and stereo-selective synthesis of β-phenylthio enamidesviaintramolecular 1,2-thiol migration	42
Visible light metallaphotoredox catalysis in the late-stage functionalization of pharmaceutically potent compounds	41
Enantioselective total syntheses of (−)-mitragynine, (−)-quinine and (+)-quinidine enabled by Ir-catalysed asymmetric hydrogenation of all-carbon tetrasubstituted cycloalkenes	41
Asymmetric oxidative rearrangement of indoles enabled by dual catalysis with in situ generated acyl hypoiodite and chiral phosphoric acid	41
Pd-Free synthesis of dithienothiophene-based oligoaryls for effective hole-transporting materials by optimized Cu-catalyzed annulation and direct C–H arylation	40
Copper-mediated three-component synthesis of 2-trifluoromethyl benzimidazoles	40
4,7-Diarylbenzo[c][1,2,5]thiadiazoles as fluorophores and visible light organophotocatalysts	40
Pd-catalyzed site-selective C(sp2)–H chalcogenation of amino acids and peptides using a picolinamide auxiliary	40
Gold-catalyzed formal (3 + 2) and (4 + 2) cycloadditions of alkynes to highly functionalized dihydropyrroles and tetrahydropyridines	39
A photo-driven traceless group directed electron–donor–acceptor (EDA) complex initiated radical coupling/dehydrogenation tandem reaction: access to 1-allyl/benzyl-3,4-dihydroisoquinoline	39
Electrochemical switching in mechanically interlocked molecules (MIMs)	39
Bis(pentafluorophenyl)borane-catalyzed E-selective isomerization of terminal alkenes to internal alkenes	38
“Thiol-free synthesized” and sustainable thiolating synthons for nickel-catalyzed reductive assembly of sulfides with high efficiency	38
A Cu/Cd-cocatalysed cascade reaction for constructing nitrogen-tethered 1,6-enynes enabled by 1,5-hydride transfer	37
Electrochemical oxidative cyclization of alkenes, boronic acids, and dichalcogenides to access chalcogenated boronic esters and 1,3-diols	37
Paired electrochemical C–H bromination of (hetero)arenes with 2-bromoethan-1-ol	37
N-Heterocycle-fused Ni(ii) porphyrin dimers upon heating of meso-amino Ni(ii) porphyrins in nitrobenzene	37
Rh-catalysed divergent synthesis of polysubstituted pyrroles from α,β-unsaturated ketones via selective single or double insertion of isocyanides	36
Synthesis of spirocyclopropylpyrazole derivatives via the cascade reaction of alkylidenecyclopropanes with pyrazolidinones and trifluoroethanol	36

Recent advances in trifluoroethylation reaction	36
Gold(i)-catalyzed diastereo- and enantioselective [4 + 3] cycloadditions: construction of functionalized furano-benzoxepins	36
Electrochemical benzylic C–H arylation of xanthenes and thioxanthenes without a catalyst and oxidant	36
Bond energy enabled amine distinguishing strategy: chemo-, regioselective 1,3-diamination of (trifluoromethyl)alkenes with different amines by two C(sp3)–F bond cleavages	36
A visible light-mediated deoxygenation protocol for the synthesis of dipeptides, amides and esters without racemization	36
Frustrated behavior of Lewis/Brønsted pairs inside molecular cages	36
Dinuclear zinc catalyzed asymmetric [3 + 2] spiroannulation for the synthesis of diverse bispirocyclic saccharines	36
Photocatalytic redox-neutral arylation of cyclopropanols with cyanoarenes via radical-mediated C–C and C–CN bond cleavage	36
Alkali-amide controlled selective synthesis of 7-azaindole and 7-azaindoline through domino reactions of 2-fluoro-3-methylpyridine and aldehydes	36
A gold-catalyzed cyclization/nucleophilic addition reaction of o-alkynylanilines with ynamides: stereoselective synthesis of 3-vinylindoles	36
Application of a transient directing strategy in cyclization reactionsviaC–H activation	35
Copper(ii)-catalyzed synthesis of sulfonyl-functionalized quinone-fused cyclopenta[b]indoles via four-component cascade annulation	35
Upper-rim functionalised calix[4]arenes for chemoselective Au3+ detection	35
Palladium-catalyzed [4 + 4] cycloadditions for highly diastereo- and enantioselective synthesis of functionalized benzo[b]oxocines	35
One-pot and sustainable liquid-phase peptide extension for synthesis of C-terminal amidation peptides aided by small molecular tags	35
Elucidating the mechanism and origin of diastereoselectivity in scandium-catalyzed β-C(sp3)–H activation and transformation of an aliphatic aldimine	35
Three-component synthesis of β-aminoxy amides	35
Commiphoratones C–E: three spiro-sesquiterpene dimers fromResina commiphora	34
BF3-enabled unusual (3 + 2) cycloaddition of bicyclobutanes with aldimine ester: access to 2-azabicyclo[2.1.1]hexanes	34
Synthesis of axially chiral biaryl-2-carboxamides through Pd(ii)-catalyzed atroposelective C–H olefination	34
The “cobra effect” in the imidazolinone series: how a donor can disable the nucleophilicity	34
Mechanistic insights into rhodium-catalyzed C–H activation and annulation using vinyl acetate to access cinnolines and cinnolin-4(1H)-ones	34
Visible-light heterogeneous photocatalysis with an ionic porous organic polymer (IPOP): synthesis of β-keto sulfoxides and benzothiophene diesters by tandem radical addition–oxidation reactions	34
Transition metal-catalyzed redox-neutral 1,3-dienylation of propargylic esters and divergent synthesis	34
Asymmetric total synthesis of norzoanthamine and formal synthesis of zoanthenol	33
Formal [5 + 2] cycloaddition of ortho-indolizinyl anilines with cyclopentenediones: access to planar indolizine-fused azepines	33
Photocatalytic ketone synthesis: recent advances in radical-based approaches from carboxylic acids and derivatives	33
Mechanisms of Cu/DMAP-cocatalyzed and DMAP-catalyzed C–N decarboxylative cross-coupling reactions	33
Visible-light-driven, catalyst-free intramolecular crossed and straight [2 + 2] cycloaddition	33
Platinum–P(BFPy)3-catalyzed regioselective diboration of terminal alkynes with (pin)B–B(aam)	33
Inside front cover	32
Contents list	32
Front cover	32
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Strategic convergent synthesis en route to Veratrum steroidal alkaloids	32
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Polyfluorinated reagents for peptide stapling	31
Mechanistic insight into Ni(i)-catalyzed regioselective alkene hydroarylation: is it carbonickelation or hydronickelation?	31
Synthesis of fluorinated allylic alcoholsviaphotoinduced decarboxylative cross-coupling of α-fluoroacrylic acids and alcohols	31
Cobalt-catalyzed regioselective hydroazidation of 1-aryl-1,3-dienes: facile access to allylic azides	31
Access to phosphorus-containing cyclopenta[b]benzofuranols via a serendipitous cascade reaction promoted by a bifunctional phosphonium salt	31
Dithiocarbamate-mediated thioamidation of arylglyoxylic acids by decarboxylative–decarbonylative C–C bond formation reactions	31
(3 + 2)-Annulation of 1,3-N,Si-tetraorganosilane reagents TsHNCH2SiBnR1R2 with arynes for efficient synthesis of 3-silaindolines	31
Access to enantioenriched dihydroquinoxalinones via Cu-catalyzed propargylic substitution	31
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Carbene-catalyzed imine reductive reaction: a new application of Breslow intermediates	31
Pyridine-based tricarboxamides: complementary monomers for supramolecular copolymerization with C3-symmetric oligophenylenetricarboxamides	31
Sulfonamide synthesis: unlocking new pathways with aryl triflates via photocatalytic coupling	30
Hydroxylation of organoborons via uranyl photocatalysis	30
t BuOK-mediated selective 1,2-silacarboxylation of arylalkenes with Si–B/Si–Si/Si–Li reagents and CO2	30
A simple method for N-arylation of secondary amides/amines through a NaH-initiated aryne generation strategy	30
Nickel-catalyzed hydroarylation reaction: a useful tool in organic synthesis	30
Recent advances in the diverse transformations of trifluoromethyl alkenes	30
Pd-catalyzed double Heck and Heck–Suzuki cascade reaction of N-(o-bromo aryl) CF3-acrylamides	30
Tetraphenylethylene[3]arene: synthesis, structure, and sensing of I−	30
The stereochemistry of substitution at S(vi)	30
Fluorosulfonyl radicals: new horizons for the synthesis of sulfonyl fluorides	29
Feeding sequence-regulated divergent (4 + 1 + 1′) annulations of α-bromo carbonyls and 1-azadienes via computational calculation-based mechanism elucidation	29
New chemistry of alkynyl trifluoroborates under transition metal catalyst-free conditions	29
Aqueous-phase tunable multi-color luminescent supramolecular assemblies based on cucurbit[10]uril-enhanced intermolecular charge-transfer interactions	29
Access to chiral sulfones with an all-carbon quaternary stereocenter from sulfur dioxide	29
Cooperative palladium-catalyzed P(NEt2)3-mediated (4 + 1) annulation of isatins with 2 hydroxymethylallylcarbonates	29
NHC–amine Ru complex catalyzed selective mono-N-methylation of amines with methanol: understanding the effect of amine ligands	29
Calix[4]pyrrole bis-crowns as ion pair receptors: cation selectivity modulated by counter anions	29
Transition-metal-catalyzed regiodivergent sulfonylation of aziridrines for the synthesis of β-amino sulfones	28
Iodonitrene: a direct metal-free electrophilic aminating reagent	28
Leaving-group controlled N- or C-cyclization of azadienes via domino sequences: synthesis, mechanism, and chemoselectivity	28
Pd(ii)-catalyzed B(9)-alkynylation of o/m-carboranes	28
Formal allylic C(sp3)–H alkylation of α-alkylstyrenes by rearrangement of intermediate alkenyl sulfonium salts	28
Iron(ii)-catalyzed annulation to construct novel quinone-fused cyclopenta[2,1-b]indoles: a promising type I photosensitizer	28
UV light-driven asymmetric vinylogous aldol reaction of isatins with 2-alkylbenzophenones and enantioselective synthesis of 3-hydroxyoxindoles	28
Generation and application of carbodiimide anions: efficient construction of 2-aminopyrimidines via a cascade [4 + 2] annulation/aromatization sequence	28
Efficient enantioselective synthesis of pyrazolines and isoxazolines enabled by an iridium-catalyzed intramolecular allylic substitution reaction	28
Regioselective construction of 2-substituted indolines enabled by a rhodium-catalyzed decarboxylation–hydroacylation sequence	28

Selective halide ion binding templation effect for a quadruple-stranded-helicate enabling the activation of C–Br bonds	28
Facile access to indolo[2,3-b]quinoline alkaloids via DMSO-mediated cascade cyclization: unveiling their photophysical potential	28
Photocatalyzed dehalogenative deuteration with silacarboxylic acids as halogen-atom transfer agents	28
Interception of RCONCl2: late-stage hydrolysis and esterification of primary amides	28
Metal-free assembly of diverse polysubstituted pyridines via an efficient cascade approach using tertiary enaminones and α,β-unsaturated sulfonylketimines	28
Controlling rotary motion of molecular motors based on oxindole	28
Electrochemical 1,2-hydrogen atom transfer functionalizations of N-(benzyloxy)phthalimides	27
Synthesis, structures and fluorescence properties ofgem-linked cyclic tetraphenylethylenes and cyclic hexaphenylethylenes	27
HBF4-mediated direct alcoholysis of amides under mild conditions	27
Conjugated figure-of-eight macrocycles derived from the anthracene photodimer: synthetic execution through intramolecular cyclization and topological manipulation through ring expansion	27
Unraveling steric and dispersion effects in gold catalysis: a DFT study of asymmetric cyclization/Mannich reactions	27
The α-alkylation of carbonyl sulfoxonium ylides: studies and applications in the synthesis of new sulfur heterocycles	27
Visible light-enabled alkylation of enol acetates with alkylboronic acids for the synthesis of α-alkyl ketones	27
Metal-free reductive acyldifluoroalkylation of alkenes through cooperative NHC and organophotocatalysis	27
Oxetane as a part of modern medicinal chemistry toolbox: the advanced synthesis of 3,3-disubstituted building blocks	27
Rhodium(iii)-catalyzed successive C(sp2)–H and C(sp2)–C(sp2) bond activation of aryl oximes: synthetic and mechanistic studies	27
Widely applicable (radio)dihalogenation of alkynes and alkenes using two different nucleophilic alkali metal halides	27
Concise total synthesis of opioids	26
Synthesis of oxa-bridged carbocycles via rhodium/Lewis acid catalyzed [3 + 3] and [4 + 3] cycloadditions of carbonyl ylides with donor–acceptor strained carbocycles	26
Mechanistic insights into the rhodium catalysed dehydrogenative cycloaddition of cyano-yne-allene substrates	26
Visible-light-induced radical cascade cyclization of 2-isocyanobiaryls via 1,5-hydrogen atom transfer (1,5-HAT)	26
The synthesis of isoxazolines and dihydrooxazines by Pd-catalyzed oxyalkynylation alkenyl oximes with alkynyl bromides	26
Theoretical insights into the mechanism and origin of chemoselectivity in the catalyst- and directing group-dependent oxidative cyclization of diynes with pyridine N-oxides	26
Distal iodine migration of arylalkynes via cyclic monoaryliodonium salts	26
Alkali ion-controlled chemoselective indolation of allylic alcohols by base catalysis	26
H2O/D2O as the only H/D source for photocatalytic phosphine-mediated radical transfer hydrogenation/deuteration of α-aryl imino esters	26
Benzylic C–H bond functionalization through photo-mediated mesyloxy radical formation	26
Dearomative difunctionalization of arenes via highly selective radical relay reactions	26
Recent developments on 1,2-difunctionalization and hydrofunctionalization of unactivated alkenes and alkynes involving C–S bond formation	26
Synthesis of structurally diverse silicon-incorporated indolinesviasilyl radical-triggered radical cascade reactions	25
Dendron-mediated control over self-assembly of chlorophyll rosettes into columnar vs. discrete aggregates	25
Rapid synthesis of benzofulvenes from α-bromodiarylethylenes based on a 1,4-palladium shift strategy	25
Photocatalytic anti-Markovnikov hydroalkylation of 2-aryl enamides via 1,2-hydrogen atom transfer of amidyl radicals	25
Coupling partner-dependent unsymmetrical C–H functionalization of N-phenoxyacetamides leading to sophisticated spirocyclic scaffolds	25
C–H bond halogenation: unlocking regiodivergence and enhancing selectivity through directing group strategies	25
Iridium-catalyzed meta-selective C–H borylation of phenol derivatives	25
Unusual DBU-catalyzed decarboxylative formation of allylic thioethers from vinyl cyclic carbonates and thiols	25
Thermo-induced decarboxylative α-C(sp3)–H fluoroalkylation of glycine derivatives with fluorinated peroxy esters	25
TFPN-mediated racemization/epimerization-free amide and peptide bond formation	25
Recent advances in transition metal-catalyzed heteroannulative difunctionalization of alkenes via C–H activation for the synthesis of heterocycles	25
N-heterocyclic nitrenium charge transfer catalysis via inner-sphere electron transfer in concert with halogen-atom dissociation	25
Gold catalysed regio- and chemoselective azo coupling of 1,2- and 1,4-diazoquinones with 1H-indoles	25
Copper(i)-catalyzed multicomponent interrupted click reaction: modular synthesis of triazole sulfides from elemental sulfur	25
Garynthone A–I, PPAPs with diverse skeletons isolated from Garcinia yunnanensis and their immunosuppressive activity	25
Transition-metal catalyzed reactions of diazo compounds and N,N-dialkylnitrosoamines	25
A metal-free sigmatropic rearrangement/cyclization/aromatization cascade reaction of hydroxy/aminophenyl propargyl alcohols with fluoroalkanesulfinyl chlorides: synthesis of 3-fluoroalkanesulfonyl ben	24
Photocatalytic anti-Markovnikov addition of carboxylic acids to alkenes: an ionic mechanism under radical conditions	24
Contents list	24
Silver-catalyzed [4 + 3] cycloaddition of 1,3-dienes with alkenyl-N-triftosylhydrazones: a practical approach to 1,4-cycloheptadienes	24
Photo-induced 1,2-alkylarylation/cyclization of alkenes, alkyl halides and N-alkylindoles via an EDA-complex	24
Electrochemical oxidative carbonylation of hydrazides for the synthesis of 1,3,4-oxadiazole-2(3H)-ones	24
Enantioselective [3 + 2] annulation of tryptanthrin-derived ketimines and 2-naphthols: access to polycyclic indolo[2,1-b]quinazoline derivatives	24
Photoinduced cross-coupling of aryl halides enabled by n-tetrabutylphosphonium phthalate	24
Conformation-tunable hydrogen-bonded calix[2]aramide macrocycles: bridging aggregation-induced emission and charge-transfer host–guest chemistry	24
Total synthesis of the indolocarbazole alkaloid ZHD-0501 and its seven isomers	24
Synthesis of 3,3-dialkyl-substituted isochroman-1,4-diones via copper/photoredox dual-catalyzed carbolactonization of alkenes	24
Lewis acid-catalyzed regiodivergent N-alkylation of indazoles with donor–acceptor cyclopropanes	24
Influencing optical and charge transport properties by controlling the molecular interactions of merocyanine thin films	24
Asymmetric synthesis of δ-substituted-β-keto esters and β-substituted ketones via carboxyl-assisted site- and enantio-selective addition reactions	23
Regioselective difluoroallylation of alkylidene malonates with trifluoromethyl alkenes: synthesis of gem-difluoro-1,5-dienes and their [2 + 2] photocycloaddition	23
Catalytic alkane C–H functionalization by carbene insertion into unactivated C(sp3)–H bonds	23
Photoredox catalyzed release of carbon-based radicals from 2-substituted-1,3-imidazolidines	23
Transition-metal free oxidative carbo-carboxylation of alkenes with formate in air	23
Catalytic asymmetric cyclopropanation of sulfoxonium ylides catalyzed by a chiral-at-metal rhodium complex	23
Regio- and stereo-selective construction of cis-indeno[1,2-c]isoxazoles via a C–H allylation/1,3-dipolar cycloaddition cascade	23
Mechanistic insights into the rhodium-catalyzed aryl C–H carboxylation	23
Nickel-catalysed C–N cross-coupling of organoboronic acids and isoxazoles	23
BF3-promoted reactions of α-amino acetals with alkynes to 2,5-disubstituted pyrroles	23
Successive energy-transfer catalytic dearomative reactions of quinolines with bicyclo[1.1.0]butanes for the synthesis of pyridine-fused 3D complicated molecules	23
An N-heterocyclic carbene-catalyzed enantioselective [3 + 2] annulation of enals with propargylic imines: access to γ,γ-disubstituted pyrrolidin-2-ones bearing quaternary stereogenic centers	23
Synthesis of a helical boron-doped PAH by post-functionalization of 3,9-diboraperylene	23
Base-promoted transition metal-free phosphorylation/acylation of 2-vinyl pyridines with Ph2PCl and carboxylic acids	23
Photoinduced aerobic C–S borylation of aryl sulfides	23
Photo-induced redox cascade reaction of nitroarenes and amines	23
Facile synthesis of 5α-functionalized pyrroles via multicomponent reactions of vicinal tricarbonyl compounds, enamines, and nucleophiles	23
Rapid modular synthesis of indole ethers via dehydrogenative cross-coupling reaction of indoles and alcohols	22
Front cover	22
Contributors to the Organic Chemistry Frontiers Emerging Investigator Series 2022–2023	22
Bridgehead epoxide iso-euphoranin E from β-caryophyllene oxide via sequential cationic formation and scission of [4.3.2]propellane	22
Carboxylic acid-assisted sterically demanding reductive cross-coupling between cycloalkenyl and alkyl bromides	22
Front cover	22
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A visible-light-induced cascade cyclization strategy for the synthesis of N,S-containing polycyclic compounds	22
An umpolung mechanism of B(pin)-mediated Cu/B rearrangement and origin of regioselectivity for NHC-Cu-catalyzed allylation of imines	22
Ru(iii)-catalyzed C4–H bond cyanoalkoxylation of 1-naphthylamine derivatives with azobisisobutyronitrile	22
Inside front cover	22
Modular synthesis of conjugated enamidines and cascade annulation toward benzofuran-3-oxoacetate	22
Visible-light-induced copper-catalyzed regiodivergent C(sp3)-sulfonylation of oxime esters with sodium sulfinates	21
Enantioselective construction of spirodihydrofuran oxindoles via one-pot organo-/iodine sequential catalysis	21
Acid-mediated decarboxylative C–H coupling between arenes and O-allyl carbamates	21
How the electron-deficient Cp ligand facilitates Rh-catalyzed annulations with alkynes	21
Diverse C(sp3)–H functionalizations through electrochemical benzylic oxygenation	21
Electrochemical synthesis of phosphorylated Glycine-containing oligopeptides	21
Metal-free synthesis of sulfonylated indolo[2,1-a]isoquinolines from sulfur dioxide	21
N-Sulfenyl phthalimide enabled Markovnikov hydrothiolation of unactivated alkenes via ligand promoted cobalt catalysis	21