Inorganic Chemistry Frontiers

Article	Citations
Contributors to the Inorganic Chemistry Frontiers Emerging Investigator series 2024	185
Profiting from light-induced metal-to-metal intramolecular electron transfer: towards highly efficient heterodinuclear photosensitizers for photodynamic therapy	151
Synthesis, oxidation and unusual coordination chemistry of the diphosphete complex [(Cp′′′Co) 2 (μ,η 4:4	145
Combined performance of circularly polarized luminescence and proton conduction in homochiral cadmium( ii )–terbium( iii	124
Ultra-small β-Ni(OH) 2 quantum dot catalyst with abundant edges for an efficient urea oxidation reaction	107
Back cover	105
Contents list	100
Back cover	99
Wavelength-selective duotone single-component photochromic gallophosphate-oxalate with multidirectional UVB/UVC/NIR photoswitch electron transfer	97
Achieving record-high birefringence in a 3D fluorozincoborate via coplanar alignment of π-conjugated [BO 3	94
Synergetic effect between non-metals and dual metal catalysts for nitrogen reduction reaction	93
Controlling interactions between peptide-heme and G-quadruplex DNA using Fe-bound NH 3 and H 2 O l	85
A composite proton exchange membrane with a three-dimensionally-reinforced hydrogen bonding network for durable hydrogen fuel cells	85
Cumulative 2c–2e vs. 3c–2e π-back donations: conformation preferences in germylene gold( i ) complexes	77
Contents list	74
Boosted charge transfer in Pt cluster anchored TiO 2 microspheres with rich oxygen vacancies for solar driven H 2	72
Charge-enriched RuO 2 nanoparticles decorating TiO 2 with Ti defects to promote oxygen evolution r	72
Organophosphonate- and dimethylarsinate-functionalized hexamolybdates( v ) and their solution and gas phase properties	72
Single-ion magnetism behaviors in lanthanide( iii ) based coordination frameworks	72
Spin state modulation and chiral hierarchical assembly via amine-driven single-crystal-to-single-crystal transformation	71
Tin as a co-catalyst for electrocatalytic oxidation and reduction reactions	70
1D and 2D coordination polymers based on ring-reduced free-base and copper-containing meso -tetra(4-pyridyl)porphyrins and M III	68
Centimeter-sized novel two-dimensional organic lead–tin mixed iodide single crystals for efficient photodetector applications	68
Favorable nucleation and continuous regulation direct uniform and oblate Li deposition	67
A noble metal-free triphenylamine-based coordination capsule with NADH mimics as a renewable vessel for enhanced biomimetic hydrogenation	67

Constant no more: reevaluating Hammett constants through spin-crossover	66
Contents list	65
Mass spectrometric imaging and quantitative analysis of the in vivo biodistribution of trastuzumab using a rhodium( iii	65
Exploring the substitution effect on the magnetic coupling of tetrazinyl-bridged Ln 2 single-molecule magnets	64
Methylated diammonium spacer modulated three-dimensional lead bromide perovskitoid hybrids with distinct photoconductivity anisotropy	63
Chirality-driven amplification of sensitive polarized light detection in alternating cation-intercalated perovskites	63
Regulation of stability and detonation performance: preparation of coordination compounds by using isomeric ligands	62
Back cover	62
Deficient TiO 2− x coated porous SiO anodes for high-rate lithium-ion batter	62
Remarkable enhancement of optical and electric properties by temperature-controlled solid-phase molecular motion	62
Stabilization of copper iodide hybrids with increased strength of ionic bonding for lighting and X-ray imaging	61
Cytotoxicity and immunogenic cell death studies of water-soluble tetrahedral Ga( iii ) or Fe( iii	60
Nickel-catalysed sequential hydrodefluorination of pyridines: mechanistic insights led to the discovery of bench-stable precatalysts	60
Back cover	59
Modulating anthracene excimer through guest engineering in two-dimensional lead bromide hybrids	58
The rise of functional organoarsenic chemistry	56
Temperature-dependent self-trapped models regulating energy transfer in rare earth double perovskites via 5s 2	56
Molten-salt-induced phosphorus vacancy defect engineering of heterostructured cobalt phosphides for efficient overall water splitting	55
Multicolor luminescence and afterglow from Cs 2 NaScCl 6 :Sb 3+	55
Unraveling the transformative pathways of Au-NHC and Au-alkynyl complexes and bridging the gap between molecular and nanoscale gold systems	55
A charge-assisted hydrogen-bonded organic framework as a host platform for enzyme immobilization and robust biocatalysis	55
Bioorthogonal activation and mitochondrial targeting of a near-infrared-emitting iridium( iii ) nitrone complex via	53
Stabilizing NH 4 V 4 O 10 by Al-doping: boostin	53
Synergistic interplay between oxygen-vacancy and S-scheme charge transfer dynamics in an LaFeO 3 /FeOOH heterojunction towards sono-assisted photo-Fe	52
Hydrogen adsorption in CALF-20: a shallow energy landscape and adsorption-induced framework response	51
Halide-driven polarity tuning and optimized SHG-bandgap balance in (C 4 H 11 N	50
Oxygen vacancy-enhanced hydrogen spillover on a bifunctional PdFe/TiO 2− x c	50
Fabrication of ZnMn 2 O 4 @ZnIn 2 S	50
Photoinduced NO release of [Fe 2 (μ-SL) 2 (NO) 4	49
GSH/pH dual-activated POM@MOF for tumor cell-specific synergistic photothermal and chemodynamic therapy	49
Tailoring high-entropy borides for hydrogenation: crystal morphology and catalytic pathways	49
Frontiers in single-crystal covalent organic frameworks resolved by single crystal X-ray diffraction	49
A sunlight sensitive metal–organic framework film for the environment-friendly self-sterilization application	48
Flexible strontium-based metal–organic framework scintillation screens for high-resolution X-ray imaging	48
Abiotic transformations of nitrogen mediated by iron sulfides and related species from early Earth to catalyst design	47
Unraveling active ensembles consisting of clusters and single atoms for oxygen reduction: a synergy of machine learning and DFT calculations	46
A novel dual-mode broadband near-infrared phosphor Mg 5 Ga 2 Sn 2	46
Multi-structured and ligand-modified NiFe LDH with self-optimization for efficient oxygen evolution reaction	46
Synthesis of nano-sized SAPO-34 using a facile micron-meter seed processing method and their enhanced performance in methanol-to-olefin reactions	46
Sunlight-activated Eu 3+ -doped CaNaSb 2 O 6 F	45
Trigonal antiprismatic mononuclear Cr( ii ) spin-crossover complexes	45
A ligand dissociable copper complex activates non-ionophore cuproptosis by exposing Cu sites with photothermal synergistic cancer therapy	45
A novel cerium-based metal–organic framework supported Pd catalyst for semi-hydrogenation of phenylacetylene	45
Hierarchical Cu-MOF hollow nanowire modified copper mesh for efficient antibacterial PM filtration	44
NiCo layered double hydroxide nanocages for high-performance asymmetric supercapacitors	44
Construction of synergistic binding sites in a robust MOF for excellent C 2 H 4 purification and C	44
Recent advances towards increasing the Pt utilization efficiency for hydrogen evolution reaction: a review	44
Prussian blue-derived multiple yolk–single shell-structured Se-doped Fe 7 S 8 @NC@C microcube comp	44
Li 3 V 2 (PO 4 ) 3	44
High proton conductivity modulated by active protons in 1D ultra-stable metal–organic coordination polymers: a new insight into the coordination interaction/ability of metal ions	44

Flavoplatins: photoactivated platinum( iv ) prodrugs bearing axial N-donors that trigger pyroptosis and reduce drug resistance	43
Back cover	43
Manipulating photon absorption and trap energy supply for multimode dynamic anti-counterfeiting	43
Propene epoxidation over a low-cost Au/TS-1 catalyst: modulation of synergetic effects between Ti and Au sites	43
Contents list	42
A bifunctional heterostructure promoting the kinetics and stability of sulfur cathodes in advanced aluminum–sulfur batteries	42
Large optical anisotropy in noncentrosymmetric phosphate with pseudo 2D intercalated layer	42
Bimetallic Ni/Co single-atom catalysts guided by an energy descriptor for efficient CO 2 electroreduction to syngas	41
Unveiling Li and Sr-induced reinforced transition metal–oxygen interactions in P2-type layered oxide cathodes for highly stable sodium-ion batteries	41
Internal electric field at the Schottky junctions in an MXene–MnCdS heterostructure for complete uranium remediation	40
Solvent-dependent valence tautomerism and polarization switching in a heterodinuclear [CrCo] complex	40
Back cover	40
Tuning ionic conduction and structure stability of ammonium vanadate by intercalating polyaniline molecules for advanced aqueous zinc-ion batteries	40
Enhancers of amyloid aggregation: novel ferrocene-based compounds selective toward amyloid models	40
Solid state molecular motion in Cd-based halides monitored by photoluminescence switching	39
Continuous regulation of Cu electronic states by rectifying Schottky contacts enhancing electrochemical nitrate reduction to ammonia	39
Alkaline earth-tuned polyoxometalate frameworks: enhanced selectivity in styrene epoxidation	38
The importance of second sphere interactions on single molecule magnet performance	38
Metal centers and aromatic moieties in Schiff base complexes: impact on G-quadruplex stabilization and oncogene downregulation	38
Nanometer-sized nickel and cobalt doped forsterite synthesis for investigating critical element recovery from mafic and ultramafic rocks	38
Tricky but repeatable synthetic approach to branched, multifunctional silsesquioxane dendrimer derivatives	38
High capacitive performances obtained in sandwich structured Bi 0.5 Na 0.5 TiO	38
Simultaneous broadening and enhancement of Cr 3+ photoluminescence in Ba 3 ZrTa	37
Exploring the computational design of anionic spin-crossover systems	37
Steric modulation of o -carborane enables tunable single and dual emission in multi-resonance TADF compounds	37
Redox-switchable bistable nickel corrole	37
meso -Aryl substituents modify the electrochemical profile and palladium( ii ) coordination of redox-active tripyrrin liga	37
Inside front cover	37
Unprecedented direct spatiotemporal imaging of a reversible interface propagation in a switchable cooperative Fe( iii ) spin crossover material	36
High-temperature biferroicity in a chiral 3D hybrid rare-earth-based double perovskite	36
Polar and tropical regioisomeric decanuclear cuprofullerenes	36
Achieving superior oxygen evolution performance on multi-cation boride catalysts	36
A mixed-valence biotinylated Cu( i / ii ) complex for tumor-targeted chemodynamic therapy accompan	36
A hundredfold enhancement of relaxation times among Er( iii ) single-molecule magnets with comparable energy barriers	36
Csp 3 –H bond activation mediated by a Pd( ii ) complex under mild conditions	36
Ultrathin core–shell Au@RuNi nanowires for superior electrocatalytic hydrogen evolution	36
Design strategies and applications of electrochemiluminescence from metal nanoclusters	35
Activation of residual sodium via in situ neutralization toward practical layered oxides	35
A hybrid halide lead-free pseudo-perovskite with large birefringence	35
Metal sites in MFI zeolites: integrating crystallography, energetics, and vibrational fingerprints for site-selective manganese incorporation	35
Amino-imidazolin-2-imine Cu( i ) complexes: ligand screening and tuning of photophysical properties	35
A strong metal–support interaction strategy for enhanced binder-free electrocatalytic nitrate reduction	34
Strontium-doped RuO 2 electrocatalyst with abundant oxygen vacancies for boosting OER performance	34
Enhancing the stability of poly(ionic liquids)@MOFs@COFs via core–shell protection strategy for 99 TcO	34
Discovering the polymerization mechanism of aromatic carbon nitride	34
Interfacial interaction of Ag–MnO x heterostructure for efficient CO 2	34
Two solvent-dependent Al 16 nanorings: design, synthesis and nonlinear optical limiting behavior	34
Si regulation of hydrogen adsorption on nanoporous PdSi hybrids towards enhancing electrochemical hydrogen evolution activity	34
Mn doping for regulating the electronic structure of Co 3 O 4 to construct dual active sites for o	34
Molecular engineering of pyridinium-functionalized metal–organic cages for iodine capture in multiple phase media	34
Photo-mediated performance change of a 1,8-dihydroxyanthraquinone-based Dy 6 single molecule magnet	34
H x ZIF-8/TiO 2 with a step-scheme heterojuncti	33
Lanthanide contraction-driven modulation of photoswitchable macrocyclic complexes reveals unprecedented glass-induced re-isomerization and luminescence thermometry	33
Rapid room-temperature H 2 S detection based on Bi 2 S 3	33
Isostructural chiral metal–organic frameworks with metal-regulated performances for electrochemical enantiomeric recognition of tyrosine and tryptophan	33
A broad perspective on metal complex-based optical recognition of fluoride ions: twelve years (2014–2025) of innovations and applications	33
Aqueous phase synthesis and electronic spectroscopy of nanostructured layered double hydroxides	33
Seeded growth of urea-promoted ZSM-5 nanoplates with short b -axis thickness for enhanced methanol-to-olefin reactions	33
Mechanism of the generation of ultra-stable radicals in fast photochromic naphthalenediimide-based coordination polymers	33
Polyoxovanadate-based supramolecular vesicles for enhancing lithium–sulfur battery performance under high rates, high loadings, and subzero-temperature conditions	33
Emerging trends in mesoporous silica nanoparticle-based catalysts for CO 2 utilization reactions	32
Metal-involved C⋯d z 2 -Pt II	32
Crystal phase transformation of tungsten oxide: a novel route to oxygen vacancy engineering for highly active epoxidation catalysts	32
An efficient oxygen evolution reaction by Ru( ii ) polypyridyl complex-based AIEgen	32
Demonstration of low-symmetry rhombohedral GeTe single crystals with anisotropic thermoelectric properties	32
Interfacial electronic engineering of a Ni 3 ZnC 0.7 /Ni heterostructure embedded in N-doped carbo	32
C 2 O 4 2− -templated cage-shaped Ln 28	32
Molecular insights into the role of selenoenzymes in the toxicity of methylmercury	32
Regulation of the electronic structure and surface wettability of a Co 9 S 8 electrocatalyst by ni	32
Fabrication of grape-like C@SnO 2 sphere anodes with a large tap density for stable lithium storage	32
Heterometallic ruthenium–osmium complexes: dual photodynamic and photothermal therapy for melanoma and drug-resistant lung tumour in vivo	32
Back cover	32
Application of a ferrocene-chelating heteroscorpionate ligand in nickel mediated radical polymerization	32
Nested NiPd nanocatalysts fabricated by reactive laser ablation in liquids: a breakthrough in selective nitroarene reduction to anilines	32
Comparative reactivity study of Group 9 metal heavy carbynes: CH, NH, OH, H 2 addition, gold electrophile addition and Cp*Al-substitution	31
A waste-to-treasure strategy: molasses-modified NiFe layered double hydroxide for stable alkaline seawater oxidation	31
Integrating RuO 2 @TiO 2 catalyzed electrochemical chlorine evolution with a NO oxidation reaction	31
Crystal phase of nickel sulfide dictates hydrogen evolution activity of various semiconducting photocatalysts	31
Selective ethylene tetramerization: an overview	31
Homoleptic biisoquinolinedioxide lanthanide complexes for near-infrared circularly polarized luminescence	31

2D pyrene-based metal–organic framework nanobelts as efficient photocatalysts for the coupling of thiols into disulfides	31
Universal synthesis of surface-wrinkled Pd-based nanowires boosts ethylene glycol and ethanol oxidation electrocatalysis	31
A defect and heterointerface engineered CoZnFe 2 O 4 @PAMPS/GA aerogel for broadband EMW absorptio	31
Deposition of Fe 3 O 4 overlayers on nickel-anchored molybdenum oxide for enhanced and stable oxyg	31
Direct CO 2 photoreduction from flue gas by synergistic catalysis of a nickel metal–organic framework and a ruthenium polypyridyl complex	31
High-nuclearity Ag-substituted tetrameric sandwich-type polyoxometalates for excellent catalytic performance in C–C bond formation	30
Synthesis of Co 9 S 8 nanoflakes by a one-step solvent-free solid-state method for multiple electr	30
Tunable functional groups on MXene regulating the catalytic property of anchored cobalt phthalocyanine for electrochemical CO 2 reduction	30
LiMn 0.8 Fe 0.2 PO 4 @C cathode prepared	30
β-Perhalogenated porphyrins enable sensitive cryogenic NIR lanthanide thermometry	30
Exploration of functional group effects on D 2 /H 2 separation selectivity within the UiO-66 frame	30
Back cover	30
Unlocking ultra-long stability of Zn–air batteries: synergistic role of antiperovskite carbide Fe 3 SnC and Fe 3	30
Photocatalytic arylterpyridine iridium( iii ) complexes trigger oncosis in 2D and 3D cancer cell models via	30
Construction of surface electron island by a simple organic molecule adsorption strategy: tuning the energy band structure and boosting the photocatalytic performance	30
Superior energy storage performance with a record high breakdown strength in bulk Ba 0.85 Ca 0.15	30
Partial substitution with a significant effect: coexistence of a wide band gap and large birefringence in the oxychalcogenide AEGe 2 O	30
Localized photothermal effect of Co 3 O 4 nanowires boosts catalytic performance in glucose electr	30
Ethanol combustion-assisted fast synthesis of tri-metal oxides with reduced graphene oxide for superior overall water splitting performance	30
Incorporation of a one-dimensional electron-rich chain in viologen-based coordination polymers for super photochromic properties and improved optical applications in polyvinyl alcohol film	30
Modulating the coordinated microenvironments of single Co( ii ) sites in metal–organic frameworks for harnessing acyl radicals	30
Conducting oxide surface engineering enables the growth of a low-defect carbon nitride film for unbiased photoelectrochemical water splitting	30
Competition mechanism of self-trapped excitons and Te 4+ ions emission in the Te 4+ doped vacancy-	30
Revealing the role of a unique local structure in lanthanide-doped Cs 2 LiInCl 6 in boosting visib	30
Data-driven ligand field exploration of Fe( iv )–oxo sites for C–H activation	30
Stable lead succinate-iodides with strong second-harmonic generation response and large birefringence	30
Electronic structures of two-dimensional covalent organic frameworks based on a series of period 4 transition metal phthalocyanines and ethynyl moieties	30
A high-pressure phase of Na 2 CuF 4 with eight-coordinated Cu 2+	29
Towards scalability: progress in metal oxide charge transport layers for large-area perovskite solar cells	29
At the intersection of X- and Z-type ligands: an inverted ligand field in carbene-supported borylnickel complexes	29
Stable oxygen vacancies engineered via microenvironment-regulated diglyceryl ether decomposition for solar-driven clean water generation	29
Does it mix? Insights and attempts to predict the formability of single phase mixed A-cation lead iodide perovskites	29
Hierarchical self-assembly of a radical naphthalenediimide-based N-heterocyclic carbene-Au( i ) macrocycle	29
Design and synthesis of RNA-responsive o -phenanthroline Eu( iii ) complexes as probes for STED super-	29
Insights into the application of cerium dioxide nanoparticle-modified cobalt phosphide as an efficient electrocatalyst for high-performance lithium–sulfur batteries	29
Correction: Mechanical force-driven multi-state memory in WO 3− δ thin films	29
A robust and flexible Cu-based metal–organic framework for gas separation and volatile organic compounds detection	29
Lysosome-targeted Ru( ii ) complexes as oncosis inducers for boosting photodynamic anticancer therapy	29
Photocontrol of catalysis in CuAAC reactions by air stable Cu( i ) complexes of phenylazopyrazole-incorporated ligands	29
A Ni–N–C catalyst for CO 2 electroreduction based on the MOF@MOF configuration exhibiting wide active reaction sites	28
Front cover	28
Acetate ion-intercalated NiCo-LDH with quasi-theoretical capacitance for high energy/power density aqueous supercapacitors	28
Dual-band white light emission and temperature-dependent luminescence of Sn 2+ in the metastable structure of Cs 2	28
Investigating the reactivity of a Lewis base-supported terminal uranium imido metallocene	28
Facile template-guided synthesis of conformal Bi 2 O 3 -coated LiMn 2	28
Catalytic microdomain engineering enables low-temperature fabrication of high-rate carbon anodes	28
New EDOT–SQ systems for electrochromic applications	28
Disruption of lipid metabolism to induce ferroptosis using multifunctional fibrate-Pt( iv ) prodrugs for cancer treatment	28
H/F substitution activating tunable dimensions and dielectric–optical properties in organic lead-bromide hybrids	28
Back cover	28
Exploring multi-stimuli-responsive Pt( ii ) complexes: supramolecular self-assembly, lysosome-specific targeted photodynamic therapy and photodegrada	28
Back cover	28
Design of a robust rod-packing scandium–organic framework for C 2 H x	28
ZnSe/FeSe 2 heterojunctions confined in N-doped carbon framework: built-in electric field and p-band center modulation toward superior sodium storage	27
Long-range disordered MoZn electrocatalyst with a synergistic AEM-LOM mechanism for efficient oxygen evolution	27
A rigid–flexible double-layer steric strategy promoting ethylene polymerization and copolymerization in alkane solvents	27
Inorganic Cu 2 ZnSnS 4 hole transport layer for perovskite light-emitting diodes	27
Immunogenic cell death-inducing Rh( i ) and Ir( i ) complexes with bis(imino)acenaphthene-derived	27
Soft seed-mediated dimensional control of metal–organic framework nanocrystals through oil-in-water microemulsions	27
Applications of metal N-heterocyclic carbene complexes in olefin polymerizations	27
Inside front cover	27
Encapsulation of toxic liquid molecules and adsorption of water pollutants by a versatile pre-organized single crystalline coating material	27
Synergistic Fe,Ce doping of Ni 3 S 2 for enhancing oxygen evolution reaction performance	27
Mg 2+ -modified LiBaF 3 :Ni 2+ perovskite singl	27
Front cover	27
Facilely synthesized crosslinked gel polymer electrolytes for high-performance quasi-solid-state rechargeable magnesium batteries	27
Optimizing Bi active sites by Ce doping for boosting formate production in a wide potential window	27
In situ conversion reaction of magnesium fluoride to boost the performance of the sulfide-based electrolyte Li 6 PS	27
Geometric and electronic perspectives on dual-atom catalysts for advanced oxidation processes	27
Stereochemically active lone pair-induced large optical anisotropy in a novel infrared birefringent crystal Ba 2 La 2	27
Contents list	27
Anion-modulated photoswitching of a tetraurea-bridged azobenzene	27
Dual-cation doping precisely reducing the energy barrier of the rate-determining step for promoting oxygen-evolving activity	26
Cu 3+ /Ni 3+ dual active sites for high-voltage driven electrocatalytic production of 2,5-furanedi	26
Recent progress and strategies on the design of catalysts for electrochemical ammonia synthesis from nitrate reduction	26
Interfacial engineering of cobalt phosphide heterostructures confined in N,P-doped carbon for efficient bifunctional electrocatalysis in Zn–air batteries	26
Electrosynthesis unlocks high-valent lanthanide complexes	26
Ultrahigh energy storage performance of a 0.75Bi 0.47 Na 0.47 Ba 0.06	26
Terpyridine–thiophene–triphenylamine conjugated ligand design enabling green-colored, multistate electrochromic Fe( ii ) metallopolymers	26
Oxygen vacancy assisted Ru–Ni(OH) 2 for efficient ethylene glycol electrooxidation reaction	26
Circumventing photoanode bandgap limits via oxidative photoelectro–hole primed photoredox catalysis for energy-demanding solar-to-chemical synthesis	26
Ammonia activation using a heteroleptic stannylene and lithium stannylenoid formation facilitated by hemilabile iminophosphorane-based ligands	26
An interface-engineered Co 2 P/CoMoP 2 heterojunction with greatly improved electrocatalytic activ	26
Ammonia and formate cosynthesis via nitrate electroreduction combined with methanol electrooxidation over nitrogen-doped carbon-encapsulated nickel iron	25
A tris-azo anion radical ligand-wrapped singlet Co( ii ) complex with multiple redox for an efficient molecular memristor towards neuromorphic comput	25
Front cover	25
Structural transformation in isomeric 0D copper( i ) iodide hybrids and their utilization as water-stable luminophores for furaltadone detection	25
Divergent deazotation and nitrene group transfer pathways at cobalt phospha-triazene species	25
Self-supported CoWO 4 nanoarrays enhance the electrochemical reduction of nitrite to ammonia	25
Ion-selective capacitive deionization enabled by codoped core–shell carbon architectures for efficient uranium recovery	25
Back cover	25
How do quantum chemical descriptors shape hydrogen atom abstraction reactivity in cupric-superoxo species? A combined DFT and machine learning perspective	25
S/V co-doped Ni 2 P microflowers enable efficient and stable saline water electrolysis through local microenvironment engineering	25
High-performance organic–inorganic hybrid manganese halide scintillator array for superior-resolution X-ray imaging	25
Back cover	25