Nature Chemistry

Article	Citations
Not all catenanes with oriented rings are topologically chiral	438
Digital skills in chemical education	339
Author Correction: Discovery of the selenium-containing antioxidant ovoselenol derived from convergent evolution	310
General strategy for the synthesis of N-monofluoromethyl amides	258
Supramolecular crystals for hydrogen storage	253
DNA catch bonds demonstrate the art of getting stuck	201
Using symmetry to drive new protein assemblies	198
Pop-up rings to rule reactivity	196
In situ nonlinear optical spectroscopy for probing buried oxide–water interfaces	192
Expanding the substrate scope of pyrrolysyl-transfer RNA synthetase enzymes to include non-α-amino acids in vitro and in vivo	184
Corrole and squeezed coordination	176
Enantioselective fullerene functionalization through stereochemical information transfer from a self-assembled cage	172
A metalloenzyme platform for catalytic asymmetric radical dearomatization	162
Fullerene on non-iron cluster-matrix co-catalysts promotes collaborative H2 and N2 activation for ammonia synthesis	155
Excited-state intermediates in a designer protein encoding a phototrigger caught by an X-ray free-electron laser	152
Iron–sulfur clusters as inhibitors and catalysts of viral replication	151
O-GlcNAcylation modulates liquid–liquid phase separation of SynGAP/PSD-95	149
A near-linear lanthanide complex that displays magnet-like behaviour	148
Reversible self-assembly of small molecules for recyclable solid-state battery electrolytes	143
Zigzag graphene nanoribbons with periodic porphyrin edge extensions	140
Eric the AI research assistant for chemists	139
Digital micelles of encoded polymeric amphiphiles for direct sequence reading and ex vivo label-free quantification	139
Building enzymes from scratch	134
Sulfone cross-coupling outcompetes proton transfer	133
Enantiospecific cross-coupling of cyclic alkyl sulfones	132

Function without form in synthetic polymers mimicking protein hydration	132
Leveraging relaxation-optimized 1H–13CF correlations in 4-19F-phenylalanine as atomic beacons for probing structure and dynamics of large proteins	131
Understanding single-molecule reactions using nanopore-based techniques	130
Magnetic activation of spherical nucleic acids enables the remote control of synthetic cells	130
Tunable valence tautomerism in lanthanide–organic alloys	127
Discovery and synthesis of atropisomerically chiral acyl-substituted stable vinyl sulfoxonium ylides	124
A pseudo-cubic metal–organic cage with conformationally switchable faces for dynamically adaptive guest encapsulation	124
A soil-inspired dynamically responsive chemical system for microbial modulation	123
Baird’s rules at the tipping point	123
Protons undermine lithium-ion batteries with positively disastrous results	122
Amphoteric chalcogen-bonding and halogen-bonding rotaxanes for anion or cation recognition	121
Mass spectrometry captures biased signalling and allosteric modulation of a G-protein-coupled receptor	121
Reaction-induced unsaturated Mo oxycarbides afford highly active CO2 conversion catalysts	121
An air- and moisture-stable ruthenium precatalyst for diverse reactivity	120
Single crystals of purely organic free-standing two-dimensional woven polymer networks	119
The numerous paths of ferrocene	119
Machine learning designs new GCGR/GLP-1R dual agonists with enhanced biological potency	119
Beyond Hubble	118
Photomediated aliphatic C–H functionalization	118
The role of aromaticity in the cyclization and polymerization of alkyne-substituted porphyrins on Au(111)	118
Bottleable triplet nitrenes	117
New-to-nature biocompatible chemistry for plastic waste upcycling	115
Excitation energy transfer and vibronic coherence in intact phycobilisomes	114
Aryl ortho methoxylation	114
A template for artificial life	114
A bridged backbone strategy enables collective synthesis of strychnan alkaloids	111
Low-valent tungsten redox catalysis enables controlled isomerization and carbonylative functionalization of alkenes	110
Multilayer stacks of polycyclic aromatic hydrocarbons	110
Global profiling of functional histidines in live cells using small-molecule photosensitizer and chemical probe relay labelling	108
A programmable biomimetic cytoskeleton	108
An electroaffinity labelling platform for chemoproteomic-based target identification	108
A dynamic metal–organic framework photocatalyst	108
Homogeneous multi-payload antibody–drug conjugates	106
Insights from an information thermodynamics analysis of a synthetic molecular motor	105
Air- and photo-stable luminescent carbodicarbene-azaboraacenium ions	104
Optical sequencing of single synthetic polymers	104
ATP hydrolysis captured in atomic detail	103
A living library concept to capture the dynamics and reactivity of mixed-metal clusters for catalysis	103
Synthesis and single-molecule imaging reveal stereospecific enhancement of binding kinetics by the antitumour eEF1A antagonist SR-A3	101
Interfacial assembly of biomimetic MOF-based porous membranes on coacervates to build complex protocells and prototissues	100
Constructing artificial gap junctions to mediate intercellular signal and mass transport	99
D3+ formation through photoionization of the molecular D2–D2 dimer	99
Synthesis of planar chiral ferrocenes via enantioselective remote C–H activation	98
A C–H activation-based enantioselective synthesis of lower carbo[n]helicenes	97
Growth of single-crystal imine-linked covalent organic frameworks using amphiphilic amino-acid derivatives in water	97
Mass photometric detection and quantification of nanoscale α-synuclein phase separation	95
The ribosome stabilizes partially folded intermediates of a nascent multi-domain protein	95
Aromaticity rules	95
Stepwise on-demand functionalization of multihydrosilanes enabled by a hydrogen-atom-transfer photocatalyst based on eosin Y	94
Milking riboflavin for all it’s worth	93

Challenges to developing materials for the transport and storage of hydrogen	93
Pluralistic teaching	93
Collisional alignment and molecular rotation control the chemi-ionization of individual conformers of hydroquinone with metastable neon	92
An open-shell molecule that exhibits conformational dynamics	92
Protein semisynthesis reveals plasticity in HECT E3 ubiquitin ligase mechanisms	92
Covalent organic frameworks as infinite building units for metal–organic frameworks with compartmentalized pores	92
Enabling nucleophilic reactivity in molecular calcium fluoride complexes	91
A single diiron enzyme catalyses the oxidative rearrangement of tryptophan to indole nitrile	90
Small-molecule-catalysed deamination enables transcriptome-wide profiling of N6-methyladenosine in RNA	90
Leveraging electron donor–acceptor complexes for kinetic resolution in catalytic asymmetric photochemical synthesis	90
Three-dimensional van der Waals open frameworks	88
Deciphering functional roles of protein succinylation and glutarylation using genetic code expansion	88
4f-orbital covalency enables a single-crystal-to-single-crystal ring-opening isomerization in a CeIV–cyclopropenyl complex	88
Artificial cell synthesis using biocatalytic polymerization-induced self-assembly	87
Molecular-scale dissipative chemistry drives the formation of nanoscale assemblies and their macroscale transport	87
Transient water wires mediate selective proton transport in designed channel proteins	87
Designing artificial fluorescent proteins and biosensors by genetically encoding molecular rotor-based amino acids	86
Molecular contacts with an orthogonal π-skeleton induce amorphization to enhance perovskite solar cell performance	85
Light-activated tetrazines enable precision live-cell bioorthogonal chemistry	84
Photoswitchable coordination cages	84
Standardized excitable elements for scalable engineering of far-from-equilibrium chemical networks	84
Fast and facile synthesis of amidine-incorporated degradable lipids for versatile mRNA delivery in vivo	83
Proton-triggered topological transformation in superbase-mediated selective polymerization enables access to ultrahigh-molar-mass cyclic polymers	83
Sustainable and degradable plastics	83
A physically encoded Bayesian assistant for the optimization of multicomponent reactions	82
Working towards a new job	82
Something new under the sun	82
In vivo metallophilic self-assembly of a light-activated anticancer drug	82
Author Correction: Circumventing the stability problems of graphene nanoribbon zigzag edges	82
Aldehyde-catalysed carboxylate exchange in α-amino acids with isotopically labelled CO2	81
Unmasking the reverse catalytic activity of ‘ene’-reductases for asymmetric carbonyl desaturation	81
Lattice O–O ligands in Fe-incorporated hydroxides enhance water oxidation electrocatalysis	80
Non-statistical assembly of multicomponent [Pd2ABCD] cages	80
The impact of UV light on synthetic photochemistry and photocatalysis	80
Multi-tiered chemical proteomic maps of tryptoline acrylamide–protein interactions in cancer cells	79
Modular chemoenzymatic synthesis of ten fusicoccane diterpenoids	79
An isolable germylyne radical with a one-coordinate germanium atom	79
Strong dipole-promoted N–O bond hydrogenolysis enables ampere-level electrosynthesis of methylamine	77
Ni-catalysed assembly of axially chiral alkenes from alkynyl tetracoordinate borons via 1,3-metallate shift	77
An evolved artificial radical cyclase enables the construction of bicyclic terpenoid scaffolds via an H-atom transfer pathway	76
Anticancer platinum-based photo-oxidants in a new light	74
Thickness control of organic semiconductor-incorporated perovskites	74
Protein nanopore reveals the renin–angiotensin system crosstalk with single-amino-acid resolution	73
Tricyclic cell-penetrating peptides for efficient delivery of functional antibodies into cancer cells	72
A versatile approach for the synthesis of degradable polymers via controlled ring-opening metathesis copolymerization	72
Triplet metallocarbenes featuring carbon-centred spin localization	72
Direct mapping of ligandable tyrosines and lysines in cells with chiral sulfonyl fluoride probes	72
Atomically dispersed low-valent Au boosts photocatalytic hydroxyl radical production	72
Bistability between π-diradical open-shell and closed-shell states in indeno[1,2-a]fluorene	72
Cooperative ligands enable cobalt-catalysed hydrogenation	71
Publisher Correction: Porous covalent organic nanotubes and their assembly in loops and toroids	71
A third strand for protein–DNA interactions	71
Masked alkynes for synthesis of threaded carbon chains	70
Amino amide assembly	70
Looking into luciferin	70
Quantum simulation of conical intersections using trapped ions	70
Heart of glass	69
Total synthesis of nine longiborneol sesquiterpenoids using a functionalized camphor strategy	69
Mapping the mechanisms of oxidative addition in cross-coupling reactions catalysed by phosphine-ligated Ni(0)	69
Tandem intermolecular [4 + 2] cycloadditions are catalysed by glycosylated enzymes for natural product biosynthesis	69
Enabling late-stage drug diversification by high-throughput experimentation with geometric deep learning	69
A crystalline stannyne	69
Operando film-electrochemical EPR spectroscopy tracks radical intermediates in surface-immobilized catalysts	68
Checking out metal cluster chemistry from living libraries	68
Concurrent control over sequence and dispersity in multiblock copolymers	68
Future-proofing calcium fluoride	68
Spatiotemporal protein interactome profiling through condensation-enhanced photocrosslinking	68
Upcycling chlorinated trash into synthetic organic treasure	67
Scalable and selective deuteration of (hetero)arenes	67
Isolation of halogen-substituted silylium ions	67
Janus-type emission from a cyclometalated iron(iii) complex	67
Discovery of the selenium-containing antioxidant ovoselenol derived from convergent evolution	67
How polymers dance to the pulses of ultrasound	67
Positive climate changes	66
Multi-compartment liposomes forge new paths in drug delivery	66
The importance of community as a pre-tenure faculty member	66
Prebiotic synthesis of α-amino acids and orotate from α-ketoacids potentiates transition to extant metabolic pathways	66
ChatGPT saves the day	66
Asymmetric dearomative single-atom skeletal editing of indoles and pyrroles	66
Chiral control of spin-crossover dynamics in Fe(II) complexes	66

Asymmetric construction of sulfur(VI)–fluorine cores	65
Establishing the fundamental rules for genetic code expansion	65
Cyclopropenium functionalization	64
Olefin π-coordination chemistry at low-oxidation-state boron	63
End-of-life upcycling of polyurethanes using a room temperature, mechanism-based degradation	63
Mimicking the structure and function of tau folds associated with disease	63
Designer peptide–DNA cytoskeletons regulate the function of synthetic cells	62
Uniform segmented platelet micelles with compositionally distinct and selectively degradable cores	62
Multi-site programmable functionalization of alkenes via controllable alkene isomerization	61
Experimental quantitation of molecular conditions responsible for flow-induced polymer mechanochemistry	61
A lithium–aluminium heterobimetallic dimetallocene	60
Using supramolecular machinery to engineer directional charge propagation in photoelectrochemical devices	60
Zinc and manganese redox potentials in organic solvents and their influence on nickel-catalysed cross-electrophile coupling	59
Non-enzymatic methylcyclization of alkenes	58
Electric field maps in enzymes	58
A bismuth-based analogue of the π-allyl cation	58
Structure-specific amyloid precipitation in biofluids	58
On gene silencing by the X10-23 DNAzyme	58
Polymer connectivity governs electrophotocatalytic activity in the solid state	58
A terminal neptunium(V)–mono(oxo) complex	58
The dynamics of agonist-β2-adrenergic receptor activation induced by binding of GDP-bound Gs protein	57
Copper-catalysed asymmetric cross-coupling reactions tolerant of highly reactive radicals	57
Encoding signal propagation on topology-programmed DNA origami	57
A chiral interlocking auxiliary strategy for the synthesis of mechanically planar chiral rotaxanes	57
Enantioconvergent radical addition of racemic alkyl halides to access vicinal stereocentres	57
Adaptive insertion of a hydrophobic anchor into a poly(ethylene glycol) host for programmable surface functionalization	56
Exciton annihilation in molecular aggregates suppressed through quantum interference	56
Ten-electron count rule for the binding of adsorbates on single-atom alloy catalysts	55
The gas-phase formation mechanism of iodic acid as an atmospheric aerosol source	55
Photocatalytic nitrogen fixation under an ambient atmosphere using a porous coordination polymer with bridging dinitrogen anions	53
Chemical testing	53
A molecular sandwich with a lithium–aluminium filling	52
How many roads must a woman walk down?	52
Rings of power	52
Ethics education for chemists	52
Interweaving different metal–organic frameworks	51
Author Correction: Moiré two-dimensional covalent organic framework superlattices	51
Stereoselective alkylation of saturated heterocycles	51
Flexible interaction patches lead to building blocks with fluctuating valency	51
Author Correction: Introducing metal–sulfur active sites in metal–organic frameworks via post-synthetic modification for hydrogenation catalysis	51
Doing away with radium’s proxies	51
Selection of a promiscuous minimalist cAMP phosphodiesterase from a library of de novo designed proteins	51
Chemical upcycling of commodity thermoset polyurethane foams towards high-performance 3D photo-printing resins	51
Hydrogen splitting at a single phosphorus centre and its use for hydrogenation	50
Building ultramicroporous zirconium metal‒organic frameworks with ligands of high coordination density through a reticular approach	50
Hydrogenative double-bond deuteration	50
Heteromultivalency enables enhanced detection of nucleic acid mutations	50
Photoinduced stepwise charge hopping in π-stacked perylene bisimide donor–bridge–acceptor arrays	50
Molecular basis for the diversification of lincosamide biosynthesis by pyridoxal phosphate-dependent enzymes	50
Recyclable and malleable thermosets enabled by activating dormant dynamic linkages	50
Diversified ring expansion of saturated cyclic amines enabled by azlactone insertion	50
Efficient room-temperature phosphorescence of covalent organic frameworks through covalent halogen doping	50
Hydrophobic assembly of molecular catalysts at the gas–liquid–solid interface drives highly selective CO2 electromethanation	50
Isolation and characterization of a two-coordinate phosphinidene oxide	50
Nanoparticle stereochemistry-dependent endocytic processing improves in vivo mRNA delivery	50
Decarboxylative cross-nucleophile coupling via ligand-to-metal charge transfer photoexcitation of Cu(ii) carboxylates	49
A para- to meta-isomerization of phenols	49
Direct conversion of white phosphorus to versatile phosphorus transfer reagents via oxidative onioation	49
A general alkene aminoarylation enabled by N-centred radical reactivity of sulfinamides	48
Different timescales during ultrafast stilbene isomerization in the gas and liquid phases revealed using time-resolved photoelectron spectroscopy	48
Near-infrared-activated anticancer platinum(IV) complexes directly photooxidize biomolecules in an oxygen-independent manner	48
Ion-pair reorganization regulates reactivity in photoredox catalysts	48
Active template strategy for the preparation of π-conjugated interlocked nanocarbons	48
Colouring by force	48
Publisher Correction: OregonFluor enables quantitative intracellular paired agent imaging to assess drug target availability in live cells and tissues	47
Reconfiguring hydrogel assemblies using a photocontrolled metallopolymer adhesive for multiple customized functions	47
Observation of robust energy transfer in the photosynthetic protein allophycocyanin using single-molecule pump–probe spectroscopy	47
The fruit fly of photophysics	47
Mirror-image trypsin digestion and sequencing of D-proteins	47
Tunable acetylene sorption by flexible catenated metal–organic frameworks	46
Advances in single-molecule junctions as tools for chemical and biochemical analysis	46
Enhanced active-site electric field accelerates enzyme catalysis	46
Emulsion-oriented assembly for Janus double-spherical mesoporous nanoparticles as biological logic gates	46
Low-temperature liquid platinum catalyst	46
Navigating protein landscapes with a machine-learned transferable coarse-grained model	46
Biosynthesis of an elusive sulfur-containing functional group	45
Triarylmethyl cation redox mediators enhance Li–O2 battery discharge capacities	45
Carbon-to-nitrogen atom swap enables direct access to benzimidazoles from drug-like indoles	45
Synthesis of highly strained para-cyclophanes via ring-expansion [5,5]-sigmatropic rearrangement reaction	45
Metastable gallium hydride mediates propane dehydrogenation on H2 co-feeding	45
From geranium lakes to catalysis with light	45
Halogen-bond-assisted radical activation of glycosyl donors enables mild and stereoconvergent 1,2-cis-glycosylation	45
Copper catalysed asymmetric amination	44
Intramolecular alkene and functional group translocation	44
Icing a three-layer cake for predictive modelling of adsorption	44
Quinine fever	44
An unnatural base pair for the detection of epigenetic cytosine modifications in DNA	44
Critical race theory and its relevance for chemistry	44
Selective arylation of atypical C–F bonds in polyfluoroarenes with aryl chlorides	44
Arenes participate in 1,3-dipolar cycloaddition with in situ-generated diazoalkenes	43
Iterative synthesis of 1,3-polyboronic esters with high stereocontrol and application to the synthesis of bahamaolide A	43
WT19F	43
Structural basis of the Meinwald rearrangement catalysed by styrene oxide isomerase	43
Recyclable plastics from a manganese catalyst	42
Release of linker histone from the nucleosome driven by polyelectrolyte competition with a disordered protein	42