Advanced Synthesis & Catalysis

Article	Citations
Liquid‐Assisted Grinding Mechanochemistry in the Synthesis of Pharmaceuticals	206
Recent Advances in the Synthesis of C2‐Functionalized Pyridines and Quinolines Using N‐Oxide Chemistry	119
Recent Advances in Metal‐Catalyzed Functionalization of Indoles	114
Synthesis of Seleno Oxindoles via Electrochemical Cyclization of N‐arylacrylamides with Diorganyl Diselenides	102
Recent Developments in Radical Cross‐Coupling of Redox‐Active Cycloketone Oximes	97
Recent Advances in the Synthesis of Difluorinated Architectures from Trifluoromethyl Groups	97
Visible Light Assisted Radical‐Polar/Polar‐Radical Crossover Reactions in Organic Synthesis	97
Photochemical and Electrochemical Strategies towards Benzylic C−H Functionalization: A Recent Update	86
Progress in Electrochemical Trifluoromethylation Reactions	81
Utilization of C(sp3)‐Carboxylic Acids and Their Redox‐Active Esters in Decarboxylative Carbon−Carbon Bond Formation	80
Overview of Regioselective and Stereoselective Catalytic Hydroboration of Alkynes	76
Decarboxylation‐Initiated Intermolecular Carbon‐Heteroatom Bond Formation	74
Aryldiazonium Salts in Photoredox Catalysis – Recent Trends	71
Recent Advances in Cross‐Dehydrogenative Couplings (CDC) of C−H Bond in Aqueous Media	69
Synthesis of Organoselenium Compounds with Elemental Selenium	68
Electrochemical Functionalization of Imidazopyridine and Indazole: An Overview	65
Photocatalysis in Dual Catalysis Systems for Carbon‐Nitrogen Bond Formation	65
Multicomponent and One‐pot Syntheses of Quinoxalines	63
Advances in Transition‐Metal Catalyzed Carbonylative Suzuki‐Miyaura Coupling Reaction: An Update	62
Oxime‐Derived Iminyl Radicals in Selective Processes of Hydrogen Atom Transfer and Addition to Carbon‐Carbon π‐Bonds	61
Covalent Organic Frameworks in Catalytic Organic Synthesis	60
Recent Advances in Reactions Using Enaminone in Water or Aqueous Medium	59
Recent Advances in the Synthesis of Heterocyclics via Cascade Cyclization of Propargylic Alcohols	55
A3 Coupling Reaction in the Synthesis of Heterocyclic Compounds	54
Update on the Synthesis of N‐Heterocycles via Cyclization of Hydrazones (2017–2021)	52

Propargylic Alcohols as Coupling Partners in Transition‐Metal‐Catalyzed Arene C−H Activation	52
Visible Light Mediated Synthesis of Oxindoles	51
Direct Carboxylation with Carbon Dioxide via Cooperative Photoredox and Transition‐Metal Dual Catalysis	51
Threat to the Throne: Can Two Cooperating Boron Atoms Rival Transition Metals in Chemical Bond Activation and Catalysis?	51
Recent Advances in the Development of Direct Trifluoromethylselenolation Reagents and Methods	50
Recent Developments in Photo‐Catalyzed/Promoted Synthesis of Indoles and Their Functionalization: Reactions and Mechanisms	48
Recent Advances in Catalytic Asymmetric Aza‐Michael Addition Triggered Cascade Reactions	48
Recent Advances in Organocatalytic Enantioselective Synthesis of Axially Chiral Allenes	48
Recent Trends and Prospects in Homogeneous Manganese‐Catalysed Epoxidation	47
Recent Achievements in the Rhodium‐Catalyzed Concise Construction of Medium N‐Heterocycles, Azepines and Azocines	46
Recent Advances in Synthesis of Difluoromethylene Phosphonates for Biological Applications	45
Catalytic Asymmetric Aza‐Diels‐Alder Reaction: Pivotal Milestones and Recent Applications to Synthesis of Nitrogen‐Containing Heterocycles	45
Front Cover Picture: Recent Advances in the Synthesis of C2‐Functionalized Pyridines and Quinolines Using N‐Oxide Chemistry (Adv. Synth. Catal. 1/2021)	45
Fluorinated Aryl Boronates as Building Blocks in Organic Synthesis	44
Recent Developments in Z‐Selective Olefin Metathesis Reactions by Molybdenum, Tungsten, Ruthenium, and Vanadium Catalysts	43
Advances in C(sp2)−H/C(sp2)−H Oxidative Coupling of (Hetero)arenes Using 3d Transition Metal Catalysts	43
Organic Azides: Versatile Synthons in Transition Metal‐Catalyzed C(sp2)−H Amination/Annulation for N‐Heterocycle Synthesis	42
Catalyst‐Free Decarbonylative Trifluoromethylthiolation Enabled by Electron Donor‐Acceptor Complex Photoactivation	41
Recent Advances in Asymmetric Organomulticatalysis	41
Visible Light‐Promoted Selenylation/Cyclization of Enaminones toward the Formation of 3‐Selanyl‐4H‐Chromen‐4‐Ones	40
Uncovering the Potential of Boronic Acid and Derivatives as Radical Source in Photo(electro)chemical Reactions	40
Advances in Electrochemical Hydrogenation Since 2010	40
Radical Cascade Reactions of β,γ‐Unsaturated Hydrazones/Oximes	40
Transition‐Metal‐Free C(sp2)‐H Dithiocarbamation and Chromone Annulation Cascade for 3‐Dithiocarbamyl Chromone Synthesis	40
Phosphorus Compounds as Precursors and Catalysts for Radical C−C Bond‐Forming Reactions	40
The Construction of Nitrogen‐Containing Heterocycles from Alkynyl Imines	39
Transition Metal‐Free Synthesis of Sulfonyl‐ and Bromo‐Substituted Indolo[2,1‐α]isoquinoline Derivatives through Electrochemical Radical Cascade Cyclization	39
Visible Light‐Induced Synthesis of Functionalized Coumarins	39
Selective Synthesis of 3‐(α‐Fluorovinyl)indoles and 3‐Acylindoles via the Cascade Reactions of 1‐Phenylpyrazolidinones with α,α‐Difluoromethylene Alkynes	39
Recent Advances in the Synthesis and Ring‐Opening Transformations of 2‐Oxazolidinones	38
Organocatalytic Enantioselective Friedel‐Crafts Alkylation Reactions of Pyrroles	38
Recent Advances in Phosphonium Salt Catalysis	38
Recent Advances in Transition‐Metal‐Catalyzed Reactions of N‐Tosylhydrazones	38
Recent Advances in Polychloromethylation Reactions	38
Synthesis of Substituted 1‐Hydroxy‐2‐Naphthaldehydes by Rhodium‐Catalyzed C−H Bond Activation and Vinylene Transfer of Enaminones with Vinylene Carbonate	37
Visible‐Light‐Induced Manganese‐Catalyzed Reactions: Present Approach and Future Prospects	37
A Cascade Rh(III)‐catalyzed C−H Activation/Chemodivergent Annulation of N‐carbamoylindoles with Sulfoxonium Ylides for the Synthesis of Dihydropyrimidoindolone and Tricyclic [1,3]Oxazino[3,4‐	37
Chiral Phosphoric Acid Catalyzed (4+1) Annulation of 3‐Diazooxindoles/4‐Diazooxisoquinolines with para‐Quinone Methides to Access Chiral Spiro[dihydrobenzofuran‐2,3′‐oxindoles/2,4′‐oxisoquinoli	36
Photoinduced Ligand‐to‐Metal Charge Transfer of Carboxylates: Decarboxylative Functionalizations, Lactonizations, and Rearrangements	36
Synthesis of Indolo[2,1‐a]isoquinolin‐6(5H)‐Ones Derivatives via Fe(OTf)3‐Promoted Tandem Selenylation/Cyclization of 2‐Arylindoles	35
Base Metal‐Catalyzed C‐Methylation Reactions Using Methanol	34
State of the Art in Crystallization‐Induced Diastereomer Transformations	34
Radical Polychloromethylation/Cyclization of Unactivated Alkenes: Access to Polychloromethyl‐Substituted Ring‐Fused Quinazolinones	34
Fast and Efficient Nickel(II)‐catalysed Transfer Hydrogenation of Quinolines with Ammonia Borane	34
Metal‐Free, PhI(OAc)2‐Promoted Oxidative C(sp2)−H Difunctionalization: Synthesis of Thioaminated Naphthoquinones	33
Synthesis and Applications of Organic Selenols	33
Visible‐Light‐Promoted Switchable Synthesis of C‐3‐Functionalized Quinoxalin‐2(1H)‐ones	33
Phosphine‐Free Manganese(II)‐Catalyst Enables Acceptorless Dehydrogenative Coupling of Alcohols with Indoles	33
Recent Advances in the Synthesis of Spiro‐β‐Lactams and Spiro‐δ‐Lactams	32
Recent Advances in the Direct Functionalization of Isoindolinones for the Synthesis of 3,3‐Disubstituted Isoindolinones	32

Combined Photoredox and Carbene Catalysis for the Synthesis of γ‐Aryloxy Ketones	32
Electrosynthesis of CF3‐Substituted Polycyclic Quinazolinones via Cascade Trifluoromethylation/Cyclization of Unactivated Alkene	32
Recent Advances in Electron Donor‐Acceptor (EDA)‐Complex Reactions involving Quaternary Pyridinium Derivatives	32
Stereoselective Preparation of C‐Aryl Glycosides via Visible‐Light‐Induced Nickel‐Catalyzed Reductive Cross‐Coupling of Glycosyl Chlorides and Aryl Bromides	32
Visible‐Light‐Mediated Nitrogen‐Centered Radical Strategy: Preparation of 3‐Acylated Spiro[4,5]trienones	32
E/Z Photoisomerization of Olefins as an Emergent Strategy for the Control of Stereodivergence in Catalysis	32
Recent Progress in Palladium‐Catalyzed Radical Reactions	32
Reactions of Organophosphorus Compounds with Arynes: Reactivity and Mechanism	31
Transition‐Metal‐Catalyzed Selective Alkynylation of C−H Bonds	31
Photo‐Triggered Self‐Induced Homolytic Dechlorinative Sulfonylation/Cyclization of Unactivated Alkenes: Synthesis of Quinazolinones Containing a Sulfonyl Group	31
Aromatic C−H Hydroxylation Reactions with Hydrogen Peroxide Catalyzed by Bulky Manganese Complexes	31
Recent Advances in Iron‐Catalyzed Chemical and Enzymatic Carbene‐Transfer Reactions	31
Chiral Iron Complexes in Asymmetric Organic Transformations	31
Recent Trends in the Synthesis and Mechanistic Implications of Phenanthridines	30
Regioselective Decarboxylative Cycloaddition Route to Fully Substituted 3‐CF3‐Pyrazoles from Nitrilimines and Isoxazolidinediones	30
Borata‐Alkene Species as Nucleophilic Reservoir	30
Electrochemically Mediated Direct C(sp3)−H Sulfonylation of Xanthene Derivatives	30
[Bis(trifluoroacetoxy)iodo]benzene Mediated C‐3 Selenylation of Pyrido[1,2‐a]Pyrimidin‐4‐Ones Under Ambient Conditions	29
Selective Synthesis of Fused Tricyclic [1,3]oxazino[3,4‐a]indolone and Dihydropyrimido [1,6‐a]indolone via Rh(III)‐catalyzed [3+3] or [4+2] C−H Annulation	29
A Metal‐Free Direct Arene C−H Amination	29
Dimsyl Anion Enables Visible‐Light‐Promoted Charge Transfer in Cross‐Coupling Reactions of Aryl Halides	29
Halohydrin Dehalogenases and Their Potential in Industrial Application – A Viewpoint of Enzyme Reaction Engineering	28
Transition‐metal‐free Photo‐induced Cascade Sulfonylation/Addition/Cyclization of 3‐Arylethynyl‐[1,1′‐biphenyl]‐2‐carbonitriles with Aryldiazonium Tetrafluoroborates via the Insertion of Sulfur Dioxid	28
Catalytic Photoredox Allylation of Aldehydes Promoted by a Cobalt Complex	28
Synthesis and Reactivity of Allenylboron Compounds	28
Evolution and Future of Hetero‐ and Hydro‐Trifluoromethylations of Unsaturated C−C Bonds	28
Tailoring the Reactivity of the Langlois Reagent and Styrenes with Cyanoarenes Organophotocatalysts under Visible‐Light	27
Metal‐Free Multi‐Component Sulfur Dioxide Insertion Reaction Leading to Quinoxalin‐2‐One‐Containing Vinyl Sulfones under Visible‐Light Photoredox Catalysis	27
Chiral Binaphthyl‐Based Iodonium Salt (Hypervalent Iodine(III)) as Hydrogen‐ and Halogen‐Bonding Bifunctional Catalyst: Insight into Abnormal Counteranion Effect and Asymmetric Synthesis of N,<	27
Nickel‐Catalyzed Selective Synthesis of α‐Alkylated Ketones via Dehydrogenative Cross‐Coupling of Primary and Secondary Alcohols	27
Recent Advances in Metal‐Catalyzed Decarboxylative Reactions of Vinyl Benzoxazinanones	27
Iron‐Catalyzed Silylation and Spirocyclization of Biaryl‐Ynones: A Radical Cascade Process toward Silylated Spiro[5.5]trienones	27
Minisci‐Type Alkylation of N‐Heteroarenes by N‐(Acyloxy)phthalimide Esters Mediated by a Hantzsch Ester And Blue LED Light	27
Copper‐Catalyzed Selective N‐Arylation of Oxadiazolones by Diaryliodonium Salts	26
Alkene, Bromide, and ROH – How To Achieve Selectivity? Electrochemical Synthesis of Bromohydrins and Their Ethers	26
Rhodium(III)‐Catalyzed Annulation of 2‐Arylimidazo[1,2‐a]pyridines with Maleimides: Synthesis of 1H‐Benzo[e]pyrido[1′,2′:1,2]imidazo[4,5‐g]isoindole‐1,3(2H)‐Diones a	26
Strategic Applications of the β‐Silicon Effect	26
Generation of Alkyl Radicals from Thiols via Zinc Thiolates: Application for the Synthesis ofgem‐Difluorostyrenes	26
Photocatalytic Deoxygenative Carboimination towards Functionalized Pyrrolines by Using Unstrained γ,δ‐Unsaturated Oximes	26
Iodine‐Catalyzed Double [4+2] Oxidative Annulations for the Synthesis of Bipyrazines from Ketones and Diamines by a Domino Strategy	26
Palladium‐Catalyzed Carbonylative Synthesis of 2‐(Trifluoromethyl)quinazolin‐4(3H)‐ones from Trifluoroacetimidoyl Chlorides and Nitro Compounds	25
Glycosyltransferase Co‐Immobilization for Natural Product Glycosylation: Cascade Biosynthesis of the C‐Glucoside Nothofagin with Efficient Reuse of Enzymes	25
Selectivity in the Elaboration of Bicyclic Borazarenes	25
Regioselective and Chemodivergent Synthesis of Azulenolactones and Azulenolactams from Rhodium(III)‐Catalyzed Reactions of Azulenecarboxamides with Sulfoxonium Ylides	25
Kinetic Resolution of 2‐N‐Acylamido Tertiary Allylic Alcohols: Asymmetric Synthesis of Oxazolines	25
Recent Advances for Alkylation of Ketones and Secondary Alcohols Using Alcohols in Homogeneous Catalysis	25
Electrochemical‐Induced Hydrogenation of Electron‐Deficient Internal Olefins and Alkynes with CH3OH as Hydrogen Donor	25
Organocatalytic Enantioselective [4+3]‐Cycloadditions of Azaoxyallyl Cations with 2‐Aminophenyl Enones	25
Recent Developments in Remote Meta‐C−H Bond Functionalizations	25
Transition Metal‐Free, Free‐Radical Sulfenylation of the α‐C(sp3)−H Bond in Arylacetamides and Its Application Toward 2‐Thiomethyl Benzoxazoles Synthesis	25
Electrochemically Mediated Fixation of CO2: Synthesis of Functionalized Oxazolidine‐2,4‐Diones by Three‐Component Reactions	25
Ruthenium‐Catalyzed Vinylene Carbonate Annulation by C−H/N−H Functionalizations: Step‐Economical Access to Indoles	25
Visible‐Light‐Mediated C‐2 Functionalization and Deoxygenative Strategies in Heterocyclic N‐Oxides	25
Transition‐Metal‐Catalyzed, Chelation‐Assisted C−H Alkenylation and Allylation of Organic Molecules with Unactivated Alkenes	25
Asymmetric Synthesis of Chiral Amino Carboxylic‐Phosphonic Acid Derivatives	25
Bifunctinoal Phosphonium Salt‐Catalyzed Asymmetric Cyclodearomatization of 2‐Nitroindoles and 2‐Nitrobenzofurans for Constructing CF3‐Containing Spiro‐Polycycles	25
Nickel‐Catalyzed Reductive Acylation of Carboxylic Acids with Alkyl Halides and N‐Hydroxyphthalimide Esters Enabled by Electrochemical Process	25
A Synthetic Protocol for the Construction of Chroman‐Spiroquinazolin(thi)one Framework via a Metal‐Free, Three‐Component, Domino, Double Annulations	25
Visible‐Light‐Induced Decarboxylative Acylation of Pyridine N‐Oxides with α‐Oxocarboxylic Acids Using Fluorescein Dimethylammonium as a Photocatalyst	24
Nucleophilic Halogenation of HeterocyclicN‐Oxides: Recent Progress and a Practical Guide	24
Iron‐Catalyzed Three‐Component Cyanoalkylsulfonylation of 2,3‐Allenoic Acids, Sulfur Dioxide, and Cycloketone Oxime Esters: Access to Cyanoalkylsulfonylated Butenolides	24
Copper‐Catalyzed Regio‐ and Stereoselective Oxidative Vinylsulfonylation of Quinoxalinones with Alkynes and Sulfonyl Hydrazides	24
Synthetic Chemistry with Lewis Acidity‐Diminished B(aam) and B(dan) Groups: Borylation Reactions and Direct Cross‐Couplings	24
Visible‐Light‐Induced Three‐Component Intermolecular Trifluoromethyl‐Alkenylation Reactions of Unactivated Alkenes	24
Visible‐Light‐Induced Controlled Oxidation ofN‐Substituted 1,2,3,4‐Tetrahydroisoquinolines for the Synthesis of 3,4‐Dihydroisoquinolin‐1(2H)‐ones and Isoquinolin‐1(2H)‐ones	24
Molecular Oxygen‐Mediated Radical Cyclization of Acrylamides with Boronic Acids	24
Visible Light‐Induced [3+2] Cyclization Reactions of Hydrazones with Hypervalent Iodine Diazo Reagents for the Synthesis of 1‐Amino‐1,2,3‐Triazoles	23
Synthesis of Hydrophilic Phosphorus Ligands and Their Application in Aqueous‐Phase Metal‐Catalyzed Reactions	23
Electrochemically Enabled Dehydrogenative Phosphorothiolation of 2H‐Indazoles under Electrolyte‐Free Conditions	23
Highly Atom‐Economic and Efficient Electrochemical Selenylative Annulation of 2‐Alkynyl Biaryls	23
Benzyl Palladium Intermediates: Unique and Versatile Reactive Intermediates for Aromatic Functionalization	23
Metal‐Free Organoselenium‐Enabled Radical Relay Azidation‐Carbocyclization	23
Asymmetric Fluorination Reactions promoted by Chiral Hydrogen Bonding‐based Organocatalysts	23
Aldehyde‐Directed C(sp2)−H Functionalization under Transition‐Metal Catalysis	23
Visible Light Enabled Formal Cross Silyl Benzoin Reaction as an Access to α‐Hydroxyketones	22
Recent Development of Recoverable MacMillan Catalyst in Asymmetric Organic Transformations	22
Visible Light‐Promoted Recyclable Carbon Nitride‐Catalyzed Dioxygenation of β,γ‐Unsaturated Oximes	22
Organocatalytic Remote Asymmetric Inverse‐Electron‐Demand Oxa‐Diels‐Alder Reaction of Allyl Ketones with Isatin‐Derived Unsaturated Keto Esters	22
Indolizine Synthesis through Annulation of Pyridinium 1,4‐Thiolates and Copper Carbenes: A Predictive Catalysis Approach	22
A Concise Route to Cyclic Amines from Nitroarenes and Ketoacids under Iron‐Catalyzed Hydrosilylation Conditions	22

Synthesis of Dibenzosiloles through Electrocatalytic Sila‐Friedel‐Crafts Reaction	22
Nanoconfinement Effects of Micellar Media in Asymmetric Catalysis	22
A Metal‐ and Azide‐free Oxidative Coupling Reaction for the Synthesis of [1,2,3]Triazolo[1,5‐a]quinolines and their Application to Construct C−C and C‐P Bonds, 2‐Cyclopropylquinolines and Imidazo[1,5‐	22
Ruthenium‐Catalyzed C7‐Formylmethylation or Sequential Acetalization of Indolines with Vinylene Carbonate in Different Solvents	22
Asymmetric Oxidative Mannich Reactions	22
Palladium‐Catalyzed Thiocarbonylation of Benzyl Chlorides with Sulfonyl Chlorides for the Synthesis of Arylacetyl Thioesters	22
Transition‐Metal‐Free C(sp2)−H Phosphorothiolation/Cyclization of o‐Hydroxyarylenaminones: Access to S‐3‐Chromon Phosphorothioates	22
Electrochemical Thiolation and Borylation of Arylazo Sulfones with Thiols and B2pin2	22
Direct Reductive Amination of Biobased Furans to N‐Substituted Furfurylamines by Engineered Reductive Aminase	21
Photoredox Fluoroalkylation of Hydrazones in Neutral and Reductive Modes	21
Iron‐Catalyzed and Air‐Mediated C(sp3)−H Phosphorylation of 1,3‐Dicarbonyl Compounds Involving C−C Bond Cleavage	21
Electrochemical‐Induced Hydroxysulfonylation of α‐CF3 Alkenes to Access Tertiary β‐Hydroxysulfones	21
Dual Cobalt and Photoredox Catalysis Enabled Redox‐Neutral Annulation of 2‐Propynolphenols	21
Gold‐Catalyzed Synthesis of π‐Extended Carbazole‐Based Systems and their Application as Organic Semiconductors	21
Transition‐Metal‐Free Radical Cyclization of 2‐Arylbenzoimidazoles with Unactivated AlkanesviaC(sp3)−H Functionalizations in Aqueous Media	21
Ag‐Catalyzed Cyclization of Arylboronic Acids with Elemental Selenium for the Synthesis of Selenaheterocycles	21
Enantiodivergent Reaction of Ketimines with Malononitriles Using Single Cinchona Alkaloid Sulfonamide Catalysts	21
Cooperative NHC/Photoredox Catalysis: Three Component Radical Coupling of Aroyl Fluorides, Styrenes and Alcohols	21
Recent Progress in Synthetic Applications of Cyclic Hypervalent Iodine(III) Reagents	21
Manganese(I)‐Catalyzed Site‐Selective C6‐Alkenylation of 2‐Pyridones Using Alkynes via C−H Activation	21
Copper(II)‐Mediated Intermolecular Radical [3+2]‐Annulation of N,N‐Dimethyl Enaminones: Direct Access to 5‐Acyl‐3‐Furancarboxaldehydes	21
Direct Use of Benzylic Alcohols for Multicomponent Synthesis of 2‐Aryl Quinazolinones Utilizing the π‐Benzylpalladium(II) System in Water	20
Interrupted CuAAC‐Thiolation for the Construction of 1,2,3‐Triazole‐Fused Eight‐Membered Heterocycles from O‐/N‐Propargyl derived Benzyl Thiosulfonates with Organic Azides	20
Construction of Indole‐Fused Heterocycles Starting from 2‐Thioxoindolines, Iminoindolines, and Their Derivatives	20
Zwitterion‐Initiated Hydroboration of Alkynes and Styrene	20
Recent Advances in Cobalt‐Catalyzed, Directing‐Group‐Assisted C−H Bond Amidation Reactions	20
1,2‐Benzothiazine Derivatives from Sulfonimidamides by Metal‐Catalyzed Annulation Reactions in Solution and under Solvent‐Free Mechanochemical Conditions	20
Oxidative Cyclization of Aryl Ynones with NaNO2 for the Divergent Synthesis of NO2‐Containing Spiro[5.5]trienones, Indenones and Thioflavones	20
Synthesis of Pyrazolo[1,2‐a]cinnolines via Rhodium(III)‐Catalyzed [4+2] Annulation Reactions of Pyrazolidinones with Sulfoxonium Ylides	20
Acridine Orange Hemi(Zinc Chloride) Salt as a Lewis Acid‐Photoredox Hybrid Catalyst for the Generation of α‐Carbonyl Radicals	20
Gold‐catalyzed C−H Functionalization of Phenothiazines with Aryldiazoacetates	20
Photoredox Catalyzed Trifluoromethyl Radical‐Triggered Trifunctionalization of 5‐HexenenitrilesviaCyano Migration	20
Well‐Defined Ni−SNS Complex Catalysed Borrowing Hydrogenative α‐Alkylation of Ketones and Dehydrogenative Synthesis of Quinolines	20
Electrochemical Oxidative Functionalization of Arylalkynes: Access to α,α‐Dibromo Aryl Ketones	20
Synthesis of 5‐Trifluoromethyl‐1,2,4‐Triazoles via Metal‐Free Annulation of Trifluoroacetimidohydrazides and Methyl Ketones	20
Recent Advances in the Synthetic Use of Migration Reactions of Allyl Alcohols	19
Manganese(III) Acetate Catalyzed Aerobic Dehydrogenation of Tertiary Indolines, Tetrahydroquinolines and an N‐Unsubstituted Indoline	19
Catalyst‐Free Electrophilic Ring Expansion of N‐Unprotected Aziridines with α‐Oxoketenes to Efficient Access 2‐Alkylidene‐1,3‐Oxazolidines	19
Haloalkenyl Imidoyl Halides as Multifacial Substrates in the Stereoselective Synthesis of N‐Alkenyl Compounds	19
Ylide‐Functionalized Diisopropyl Phosphine (prYPhos): A Ligand for Selective Suzuki‐Miyaura Couplings of Aryl Chlorides	19
Generation of Dimethyl Sulfoxide Coordinated Thermally Stable Halogen Cation Pools for C−H Halogenation	19
Gold Catalysis Meets Materials Science – A New Approach to π‐Extended Indolocarbazoles	19
Bu4NHSO4‐Catalyzed Direct N‐Allylation of Pyrazole and its Derivatives with Allylic Alcohols in Water: A Metal‐Free, Recyclable and Sustainable System	19
A 1,4‐Palladium Migration/Heck Sequence with Unactivated Alkenes: Stereoselective Synthesis of Trisubstituted 1,3‐Dienes	19
One‐Pot Asymmetric Oxidative Dearomatization of 2‐Substituted Indoles by Merging Transition Metal Catalysis with Organocatalysis to Access C2‐Tetrasubstituted Indolin‐3‐Ones	19
Bioproduction of Enantiopure (R)‐ and (S)‐2‐Phenylglycinols from Styrenes and Renewable Feedstocks	19
Decarbonylative C3‐Alkylation of Quinoxalin‐2(1H)‐Ones with Aliphatic Aldehydes via Photocatalysis	19
Electrochemically Induced Regio‐ and Stereoselective (E)‐β‐C(sp2)−H Trifluoromethylation and Arylsulfonylation of Enamides	19
Enantioselective Vinylogous Mannich Reaction of Acyclic Vinylketene Silyl Acetals with Acyclic Ketimines	19
Contemporary Approaches for Amide Bond Formation	19
Regioselective Photocatalytic Dialkylation/Cyclization Sequence of 3‐Aza‐1,5‐dienes: Access to 3,4‐Dialkylated 4‐Pyrrolin‐2‐ones	18
Copper‐catalyzed Reaction of Anthranils with Methyl Ketones: Site‐Selective C5‐Dicarbonylation of Anthranils	18
The Trityl‐Cation Mediated Phosphine Oxides Reduction	18
Ir(I)‐Catalyzed C−H Glycosylation for Synthesis of 2‐Indolyl‐C‐Deoxyglycosides	18
Advancements in the Preparation of 4H‐Chromenes: An Overview	18
Synthesis of Functionalized 4,1‐Benzothiazepines via a [4+3] Annulation between Aza‐o‐Quinone Methides and Pyridinium 1,4‐Zwitterionic Thiolates	18
Electrooxidative Metal‐Free Cyclization of 4‐Arylaminocoumarins with DMF as C1‐Source	18
Ir(NHC)‐Catalyzed Synthesis of β‐Alkylated Alcohols via Borrowing Hydrogen Strategy: Influence of Bimetallic Structure	18
Electrophotocatalytic C−H Hydroxyalkylation of Heteroaromatics with Aldehydes	18
Markovnikov Wacker‐Tsuji Oxidation of Allyl(hetero)arenes and Application in a One‐Pot Photo‐Metal‐Biocatalytic Approach to Enantioenriched Amines and Alcohols	18
2‐Bromo‐3,3,3‐Trifluoropropene: A Versatile Reagent for the Synthesis of Fluorinated Compounds	18
Direct C−H Arylation of Indole‐3‐Acetic Acid Derivatives Enabled by an Autonomous Self‐Optimizing Flow Reactor	18
Palladium Catalyzed Aminocarbonylation of Benzylic Ammonium Triflates with Nitroarenes: Synthesis of Phenylacetamides	18
Visible‐Light‐Mediated Synthesis of Sulfonyl Fluorides from Arylazo Sulfones	18
Metal‐Free, Multicomponent Anti‐Markovnikov Hydroarylsulfonylation and Alkoxyarylsulfonylation of Vinyl Arenes	18
Synthesis of Functionalized 3‐(1H‐Isochromen)‐chromones via Ag2O‐Catalyzed Cascade Cyclization Reaction of o‐Hydroxyarylenaminones with o‐Alkynylbenzaldehydes	18
Photoredox and Copper‐Catalyzed Sulfonylphosphorothiolation of Alkenes toward β‐Sulfonyl Phosphorothioates	18
Palladium‐Catalyzed Distal C−H Selenylation of 2‐Aryl Acetamides with Diselenides and Selenyl Chlorides	18
Access to 10‐Phenanthrenols via Electrochemical C−H/C−H Arylation	18
Mechanochemical Transformation of CF3 Group: Synthesis of Amides and Schiff Bases	18
Visible‐Light‐Induced Photoredox 1,1‐Dichloromethylation of Alkenes with Chloroform	18
Development of an NAD(H)‐Driven Biocatalytic System for Asymmetric Synthesis of Chiral Amino Acids	18
Mechanochemical Synthesis of 2‐Arylquinoxalines and 3‐Arylquinoxalin‐2(1H)‐ones via Aryldiazonium Salts	18
tert‐Butyl Hydroperoxide‐Initiated Radical Cyclization of 1‐(Allyloxy)‐2‐(1‐Arylvinyl)Benzenes with Sulfinic Acids to Access Sulfonated Benzoxepines	18
Synthesis of Polysubstituted Phenols by Rhodium‐Catalyzed C−H/Diazo Coupling and Tandem Annulation	18
One‐Pot Two‐Step Double Annulation of N‐Methoxybenzamides with Alkynes and Alkenes: Regioselective Construction of Isoindolo[2,1‐b]isoquinolin‐5(7H)‐ones	17
Recent Advances in Catalytic Asymmetric Syntheses of Functionalized Heterocycles via Halogenation/Chalcogenation of Carbon‐Carbon Unsaturated Bonds	17
Transition‐Metal‐Catalyzed Cross‐Coupling and Sequential Reactions of Azides with Isocyanides	17
Reduction of Electron‐Deficient Alkenes Enabled by a Photoinduced Hydrogen Atom Transfer	17
Methyl Radical Initiated Kharasch and Related Reactions	17
Photoinduced Three‐Component Cyclization of Arylamines, Enaminones and Difluorobromoacetates to 2,3‐Difunctionalized Quinolines	17
Synthesis of 4‐(Trifluoromethyl)‐2,3‐Dihydrothiazoles from α‐Enolic Dithioesters and Imidoyl Sulfoxonium Ylides	17
Palladium‐Catalyzed [4+2] Cycloaddition of Hydroxy‐Tethered Allylic Carbonates with Alkenes: Synthesis of Functionalized Tetrahydropyrans	17
Catalytic Formal Hydroamination of Allylic Alcohols Using Manganese PNP‐Pincer Complexes	17
Hydrogenation of Esters by Manganese Catalysts	17
Rhodium(III)‐Catalyzed Direct C7‐Selective Alkenylation and Alkylation of Indoles with Maleimides	17
Recent Developments in Enantioselective Domino Reactions. Part A: Noble Metal Catalysts	17
Construction of Enantioenriched 4,5,6,7‐Tetrahydrofuro[2,3‐b]pyridines through a Multicatalytic Sequence Merging Gold and Amine Catalysis	17
Pull‐Pull Alkenes in the Aza‐Michael Reaction	17
Rhodium(III)‐Catalyzed Divergent C−H Functionalization of N‐Aryl Amidines with Iodonium Ylides: Access to Carbazolones and Zwitterionic Salts	17
Metal‐Free Photoinduced Deformylative Minisci‐Type Reaction	17
Gold(I)‐Catalyzed Selective Cyclization and 1,2‐Shift to Prepare Pseudorutaecarpine Derivatives	17
Free‐radical Initialized Cyclization of 2‐(3‐Arylpropioloyl)benzaldehydes with Toluene Derivatives: Access to Benzylated 1,4‐Naphthoquinones via Copper‐Catalyzed Cascade Reaction	17
Asymmetric Synthesis of Spirocyclopentane Oxindoles via [2+3] Annulation with 2‐(2‐Oxoindolin‐3‐yl)malononitriles as 1,2‐Carbon Bisnucleophiles	16
Synthesis of Hydrobenzoimidazoles from para‐Quinamines and 1,3,5‐Triazinanes via a Formal [3+2] Annulation Reaction	16