Advanced Synthesis & Catalysis

Article	Citations
Synthesis of 2‐Amino‐3‐arylindoles and their Fused Analogues via Intramolecular C‐Arylation	125
Tandem Enantioselective Cycloaromatization/Intramolecular Friedel–Crafts Desymmetrization of Cyclohexadienones	98
Ag(I)‐Catalyzed Synthesis of 2‐Aminoquinolines from 1‐Aminobutadiynes and Anilines	97
Cover Picture: Bench‐Stable Electrophilic Reagents for the Direct Di‐ and Trifluoroethylthiolation of Indoles (Adv. Synth. Catal. 20/2023)	87
Enantioselective Syntheses of Multiply Functionalized Six‐Membered Carbocycles from Nitroalkenes and γ,δ‐Unsaturated ß‐Ketoesters using Chiral Catalysts Derived from Cobalt(III) and 1,2‐Diphenylethyle	87
Asymmetric Synthesis of Tricycle‐Fused Dispirooxindoles via Organocatalyzed Three‐Component Cascade Reactions of 2‐Pyrones and Trifluoroethylisatin Ketimines	85
Regio‐ and Stereospecific Desulfinylative Chlorination of Spiroaziridine Oxindoles at Spiro‐Center for Formal [3+2]‐Cycloaddition with CS2: Sequential One‐Pot Synthesis of (−)‐Spirobrassini	79
Front Cover Picture: Filling the Gaps in the Challenging Asymmetric Hydrogenation of Exocyclic Benzofused Alkenes with Ir−P,N Catalysts (Adv. Synth. Catal. 2/2023)	64
A Gold(I)‐Catalyzed Cyclization/Semipinacol Rearrangement Cascade of 1,6‐Enynes to Access Spiro[4.5]decanes and 7‐Azaspiro[4.5]decanes	63
Gold(I)‐Catalyzed Cascade Cyclization of Nitrogen or Oxygen Containing Nucleophile Tethered‐Vinylidenecyclopropanes to Pyrrole, Furan, Pyrrolidine and Piperidine Skeletons	62
A Lewis Base Hydrogen Bond Donor (LB/HBD) Organocatalytic Approach to Dithiabridged Triarylamine Hetero[4]helicenes	61
Palladium‐Catalyzed Reaction of 2,3‐Allenols with Amines: Synthesis of [3]Dendralenes and 1,3‐Dienes Containing Allylic Amino and Hydroxy Groups	57
Visible Light Promoted Chan‐Lam Reaction and Cycloaddition to Prepare Chromeno[4,3‐c]isoxazolidines in One‐Pot Reaction	53
Asymmetric Synthesis of N‐Substituted γ‐Amino Esters and γ‐Lactams Containing α,γ‐Stereogenic Centers via a Stereoselective Enzymatic Cascade	53
Front Cover Picture: Chemo‐ and Regioselective Construction of Functionalized Isocoumarin, Flavone, and Isoquinolinedione via a One‐pot Reaction of o‐Quinol Acetate and Soft Nucleophiles	52
Chiral Aminomethylbinaphthol‐Catalyzed Diastereo‐ and Enantioselective Epoxidation of Trisubstituted Acrylonitriles	51
One Pot Synthesis of 1,2‐Disubstituted Ethanones by Base‐Mediated Reductive Homocoupling of Aldehydes	49
Catalyst‐Free, One‐Pot, Three‐Component Synthesis of 3‐Arylsulfonylated Thioflavones	48
Copper‐Catalyzed Acylhalogenation of 3‐Methylanthranils with Acid Halides: Synthesis of N‐(2‐(2‐Haloyl)phenyl)amides	48
Regio‐ and Stereoselective, Intramolecular [2+2] Cycloaddition of Allenes, Promoted by Visible Light Photocatalysis	48
Unusual Ring Opening of Bicyclic Terpenes During Pd‐Catalyzed Coupling with Aromatic Halides	46
Synthesis of Chiral Nine‐Membered N‐Heterocycles through Silver(I)‐Promoted Cycloaddition and Rearrangement from N‐Vinyl‐α,β‐Unsaturated Nitrones with Chiral 3‐Propioloyloxazolidin‐2‐Ones	46
Nickel‐Catalyzed Hydroborylative Polycyclization of Allenynes: an Atom‐Economical and Diastereoselective Synthesis of Bicyclic 5–5 Fused Rings.	46
Enzymatic Dimerization of Fungal Natural Products Through Intermolecular Disulfide Bridges	45
Hypervalent Iodine‐Mediated Regioselective Dearomatization of Non‐Activated Arenes	44

Enantioselective Synthesis of Five to Eight‐Membered P‐Stereogenic Benzo‐Fused Heterocycles via Copper‐Catalyzed Dynamic Kinetic Resolution	43
Solvent‐ and Temperature‐Switched Chemoselectivity: Controlled Synthesis of Diverse Pyrazolo[5,1‐a]isoquinolines	41
Selective α‐Deuteration of Cinnamonitriles using D2O as Deuterium Source	40
Electrochemical Stereoselective Synthesis of (Z)‐Allyl Aryl Selenides and Sulfides from Baylis‐Hillman Acetates	40
Formal Insertion of a Metal Carbene Complex into a σ‐Carbon‐Carbon Bond. Gold‐Catalyzed Synthesis of 3H‐Indoles	39
Access to 2‐Sulfonyl‐4‐arylphenols and 2,6‐Bis‐sulfonyl 5‐Aryl‐4‐arylidene‐2‐cyclohexenones via Metal Triflates‐Catalyzed Domino Cyclocondensation of 1,3‐Bis‐sulfonylacetones and 3‐Arylacroleins	38
Nitrosonium Ion Catalyzed Oxidative Bromination of Arenes	38
Cobalt‐Catalyzed Selective Transformation of Levulinic Acid and Amines into Pyrrolidines and Pyrrolidinones using Hydrogen	38
Ir(I)‐Catalyzed C−H Glycosylation for Synthesis of 2‐Indolyl‐C‐Deoxyglycosides	38
Synthesis of 2‐Aminopyridines via Cobalt‐Catalyzed Cycloaddition of Diynes with N‐Substituted and N‐Unsubstituted Cyanamides	37
Gold‐Catalyzed Annulation Between 1‐[2‐(Dimethoxymethyl)phenyl]prop‐2‐yn‐1‐yl Acetates and α‐Diazo Esters or Anilines to Form Substituted Naphthoates and Indeno[1,2‐b]quinoline, Respectively	37
Electrochemical Oxidative C−C Bond Functionalization of Methylenecyclopropanes with Diselenides/Ditellurides Leading to 2‐Substituted‐3,4‐Dihydronaphthalenes	37
Front Cover Picture: Catalytic Asymmetric Arylations of Ketimines (Adv. Synth. Catal. 12/2024)	37
Ruthenium (II)‐Catalysed Regioselective C6 Alkylation of Indoles with Maleimides	36
Magnesium and Calcium Bisguanidinates: Catalytic Activity in the Hydroboration of Unsaturated Molecules	36
Divergent Reactivity of E/Z‐Azobenzene‐Based Phosphine‐Gold Catalysts: Toward an ON‐ON Catalytic Photoswitch Process	36
Recent Advances in Transition Metal Catalysed Dearomatization Toward the Synthesis of Complex Cyclic Compounds	34
	34
Synthesis of Furfural Sulfides and 4‐Alkylthiopyridines via Heterocyclization of α‐Acyl Ketene Dithioacetals	34
tert‐Butyl Nitrite Promoted Visible‐Light‐Induced Steric‐Hindrance‐Regulated Concurrent Cross‐Coupling and Regioselective Nitration of 3‐Alkylidene‐2‐oxindoles	34
Imidazolium‐Dithiocarboxylate Zwitterions Catalysed Ring‐Opening Additions of Cyclopropenones	32
Visible‐light‐induced and EDA Complex‐initiated Hydroxyselenization of α‐CF3 Alkenes: Access to α‐trifluoromethyl‐β‐selanyl tertiary Alcohols	32
Asymmetric Synthesis of Spirocyclopentane Oxindoles via [2+3] Annulation with 2‐(2‐Oxoindolin‐3‐yl)malononitriles as 1,2‐Carbon Bisnucleophiles	32
Cu(III) Trifluoromethyl Complexes with 1,3‐Diketonate Ligands and Their Versatile Reactivity in C−H Trifluoromethylation	31
First Bromide‐Catalyzed Selenylation of 2‐Alkyn‐1‐One O‐Methyloximes Enabled the Synthesis of 4‐Selenylated Isoxazoles	31
Copper‐Catalyzed Oxidative 1,2‐Alkylarylation of Styrenes with Unactivated C(sp3)‐H Alkanes and Electron‐Rich Aromatics via C(sp3)‐H/C(sp2)‐H Func	31
Site‐Selective Direct Intermolecular C(sp3)−H Alkylation of Saccharides and Switching of Reaction Sites by Changing Photocatalysts	31
Molecular Oxygen‐Mediated Radical Cyclization of Acrylamides with Boronic Acids	30
Hypervalent Halogen Compounds in Electrochemical Reactions: Advantages and Prospects	30
Martin Silicates as Partners in Photoredox/Ni Dual Catalysis for the Installation of CH3, CH2D, CD2H, CD3and13CH3Groups onto (Hetero)A	30
Constructing 5‐Methyl‐2,4‐diaryl‐1H‐imidazoles Using Calcium Carbide as Alkyne Source via A3‐Coupling Cyclization	30
Recent Advances in Transition‐Metal‐Catalyzed Reactions of N‐Tosylhydrazones	30
Aryne‐Based Synthesis of Cyclobutadiene‐Containing Oligoacenes and Related Extended Biphenylene Derivatives	30
Witnessing the Birth of Directed Evolution of Stereoselective Enzymes as Catalysts in Organic Chemistry	29
Direct Asymmetric Addition of Heteroatom Nucleophiles to Imines	29
Recent Advances in Organocatalytic Enantioselective Synthesis of Axially Chiral Allenes	29
Asymmetric Tandem Conjugate Addition and Reaction with Carbocations on Unsaturated Heterocycles	29
Selective Formation of 2,3,5‐Trisubstituted Furans from 1,3‐Dicarbonyls and Hydroxyketones	29
Continuous Flow Technology Enabling Photochemistry	29
Tandem Asymmetric Cycloaromatization/ Intramolecular Pictet‐Spengler‐Type Reaction. An Entry to Polycyclic Pyrroles	29
Copper‐Catalyzed Cross Coupling Reaction of Alkyl Bromides with (DMPU)2Zn(Rf)2 Reagent: A Method for the Synthesis of Perfluoroalkylated Compounds	28
A Combined Halogen‐ and Chalcogen‐Bonding Organocatalyst	28
Functionalized Alkylidenecyclobutanes from a Cyclopent‐2‐enone Substrate via a Tandem Photochemical Transformation and an Allylic Substitution Protocol	28
Renewable Platform Chemicals: The Bulk Chemicals of the Future	28
Catalyst‐Free and Oxidant‐Free Cascade Difluoroalkylation and Controllable C−F Bond Activation of Aryl Enol Acetates for the Synthesis of β‐Fluoroenones and β‐Enaminones	27
Rh(I)‐Catalyzed Decarboxylative Arylation of Alkynyl Cyclic Carbonates: Divergent Access to Substituted α‐Allenols and 1,3‐Butadienes	27
An Umpolung Route to Amides from α‐Aminonitriles under Metal‐Free Conditions	27
Flexible Construction of Functionalized‐Pyrroles under Palladium or Copper Catalysis in the Presence of BF3 ⋅ Et2O	27
Palladium Catalysis: Dependence of the Efficiency of C−C Bond Formation on Carboxylate Ligand and Alkali Metal Carboxylate or Carboxylic Acid Additive. Part C: The Domino Diarylation and Annelation Re	27
Umpolung Strategy for Arene C−H Etherification Leading to Functionalized Chromanes Enabled by I(III) N‐Ligated Hypervalent Iodine Reagents	26

Indazolones Directed Rh(III)‐Catalyzed C−H Amidation of Arenes	26
Selective Synthesis of 3‐(α‐Fluorovinyl)indoles and 3‐Acylindoles via the Cascade Reactions of 1‐Phenylpyrazolidinones with α,α‐Difluoromethylene Alkynes	26
Gold‐Catalyzed Annulation of Ynamides with Aminocarbonyls as a Route to 2‐Aminoquinolines Diversely Substituted at the 4th‐Position	26
An Organocatalytic Route to endo‐Vinylene Carbonates from Carbon Dioxide‐Based exo‐Vinylene Carbonates	26
N,N’‐Difluoro‐2,2’‐bipyridinium Bis(tetrafluoroborate): a New Terminal Oxidant for Iodoarene‐catalyzed Fluorination Reactions	26
Photoinduced Annulation of N‐Phenylbenzamides for the Synthesis of Phenanthridin‐6(5H)‐Ones	26
Enantioselective Vinylogous Mannich Reaction of Acyclic Vinylketene Silyl Acetals with Acyclic Ketimines	26
N−H Trifluoroethylation of Indoles and other Aromatic N‐Heterocycles with CF3CHCl2 by Copper‐Mediated Cross‐Coupling Reaction	26
Ring‐Opening Amino Esterification of Cyclic Ketones to Access Distal Amino Acid Derivatives	25
Gold‐Catalyzed Redox‐Neutral Reaction of Nitriles with Quinoline N‐Oxides	25
Cobalt(III)‐Catalyzed Aerobic Diamination of α‐Alkyl Styrenes with Anilines	25
One‐Pot Synthesis of Quinazolines via Elemental Sulfur‐Mediated Oxidative Condensation of Nitriles and 2‐(Aminomethyl)anilines	25
DABCO‐Promoted Selective Photochemical C−N Coupling: Access to Unsymmetrical Azahelicenes	25
Interrupted CuAAC‐Thiolation for the Construction of 1,2,3‐Triazole‐Fused Eight‐Membered Heterocycles from O‐/N‐Propargyl derived Benzyl Thiosulfonates with Organic Azides	25
K2S2O8‐Mediated Access to Alkylsulfonated Spiro[4,5] Trienones from N‐Arylpropiolamides with the Insertion of Sulfur Dioxide	25
Phosphine‐Catalyzed (4+2) Annulation of Alkenes with Acidic Hydrogen‐Tethered Allylic Carbonates	25
Stereoselective Synthesis of Aliphatic α‐Amino Acids by Chemo‐Enzymatic Hydroamination‐Hydrodesulfurisation	25
Diarylprolinol with Trifluoromethyl Substituents and Diphenylprolinol‐Derived Perfluoroalkanesulfonamide as Organocatalysts in the Cross‐Aldol Reaction of Aldehydes	25
Visible‐Light Induced Ag‐Palladacycle‐Complex‐Mediated Regioselective C−H Arylation	25
K3PO4–Mediated Synthesis of Chromeno–[3,4‐c]isoxazole from 3–Nitro–2H–chromene and α–Chloro Aldehyde via Michael Addition/C−Cl Bond Cleavage/Deformylation as	25
Special Issue Dedicated to Miquel A. Pericàs	24
Multifaceted Domino Knoevenagel‐Cyclization Reactions; Four Movements for 2H‐Chromenes and Chromans	24
A Mild Metal‐Free Approach for the Direct Synthesis of Carbamoyl Azides from Carboxylic Acid Redox Active Esters	24
Nickel/Copper Co‐catalyzed Enantioselective Reductive Coupling of Oxabenzonorbornadienes with Vinyl Bromides	24
Photo‐Catalyzed Stereospecific Synthesis of Trisubstituted Alkenes Incorporating 3,3‐Difluoro‐γ‐Lactams from Morita‐Baylis‐Hillman Acetates and N‐Allylbromodifluoroacetamides	24
Asymmetric synthesis of highly substituted spiro[2H‐pyrrole‐2,3‐succinimide] derivatives by copper‐catalyzed post‐Ugi reactions	24
Iron‐Catalyzed Oxyphosphorylation of Styrenes to Access β‐Ketophosphonates and α, β‐Unsaturated Ketones	24
Stereoselective Synthesis of Contiguous Cyclopropylaziridines: Enabling the Construction of Versatile Chiral Molecules Including γ‐Lactams via Ring‐Opening Reactions	24
Palladium‐Catalyzed Domino Synthesis of 2,3‐Difunctionalized Indoles via Migratory Insertion of Isocyanides in Batch and Continuous Flow	24
Silver‐Mediated In‐Situ Generation of Alkynyl Selenium Intramolecular AAC Click Reactions	23
Bidentate NHC‐Containing Ligands for Copper Catalysed Synthesis of Functionalised Diaryl Ethers	23
Synthesis of Dihydropyrazoles via Palladium‐Catalyzed Cascade Heterocyclization/Carbonylation/Arylation of β,γ‐Unsaturated N‐Tosyl Hydrazones	23
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2‐Aminoindoles and 2‐Iminoindolines as Viable Precursors of Indole‐Fused Nitrogenated Polyheterocycles	23
Total Synthesis of the Myrioneuron Alkaloid (−)‐Schoberine B and Its Enantiomer (+)‐Schoberine B	23
The Chemistry of α‐Enolizable Alkynones: A Comprehensive Review	23
Front Cover Picture: Redox‐Neutral Vicarious‐Type Nucleophilic Amination of Heterocyclic N‐Oxides with Organic Azides (Adv. Synth. Catal. 19/2024)	23
Copper‐Catalyzed Domino Synthesis of Spiropyrazoline Oxindoles via Condensation of Indolin‐2‐One and Phenylhydrazine Derivatives	22
Synthesis of Heterospirocycles through Gold‐(I) Catalysis: Useful Building Blocks for Medicinal Chemistry	22
Enantioselective Nitro‐Michael Addition Catalyzed by N‐Terminal Guanidinylated Helical Peptide	22
Catalyst‐Free Csp−Csp3Cross‐Coupling of Bromodifluoroacetamides with 1‐Iodoalkynes under Visible‐Light Irradiation	22
Organocatalytic Asymmetric Synthesis of Cyclic Acetals with Spirooxindole Skeleton	22
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Remote Giese Radical Addition by Photocatalytic Ring Opening of Activated Cycloalkanols	22
2‐Bromo‐3,3,3‐Trifluoropropene: A Versatile Reagent for the Synthesis of Fluorinated Compounds	22
Corrigendum: Cyclic Sulfoximine and Sulfonimidamide Derivatives by Copper‐Catalyzed Cross‐Coupling Reactions with Elemental Sulfur	22
Pyrrolidine‐Catalyzed Annulations of Quinone Monoacetals with Naphthols: Synthesis of 2‐Oxabicyclo[3.3.1]nonane Skeletons, Transformations and Reaction Mechanism	21
Unexpected Stereoselective Access to 2‐Aminooxazolines from Propargyl Ureas by Silver Salts under Mild Conditions	21
Pincer‐Ruthenium Catalyzed Oxygen Mediated Dehydrative Etherification of Alcohols and Ortho‐Alkylation of Phenols	21
Mechanistic Insight into Palladium‐Catalyzed Asymmetric Alkylation of Indoles with Diazoesters Employing Bipyridine‐N,N’‐dioxides as Chiral Controllers	21
Dibenzoylperoxide as a Versatile Oxidant for Oxidative Azidations of Phenols Using Quaternary Ammonium Iodides or Bromides.	21
DMAP‐promoted [4+2]/[3+3] Annulation Cascade Reaction of Morita–Baylis–Hillman Carbonates with Conjugated Imines to Access Functionalized Benzo[c][2,7]naphthyridine Skeletons	21
One‐Pot Tandem Cyclization of β‐Oxoamides, Primary Amines, and 3‐bromo‐1,1,1‐trifluoroacetone: Synthesis of 2/4‐trifluoromethyl‐substituted dihydropyrrol‐2/4‐ols	21
Bromo Radical‐Mediated Photoredox Aldehyde Decarbonylation towards Transition‐Metal‐Free Hydroalkylation of Acrylamides at Room Temperature	21
Directed Palladium‐Catalyzed pseudo‐Anomeric C−H Functionalization of Glycal‐Type Substrates: Access to Unsymmetrical gem‐Diarylmethyl C‐Glycosides	21
Preparation of Mesoporous Cu2O Nanospheres for Green Synthesis in the Enantioselective Boron Conjugate Addition of α,β‐Unsaturated Chiral Compounds in Aqueous Phase	20
Brønsted Acid‐Catalyzed Enantioselective and Para‐Selective Addition of Phenols to 1‐Alkynylnaphth‐2‐Ols	20
Palladium‐Catalyzed Chemoselective Borylation of (Poly)halogenated Aryl Triflates and Their Application in Consecutive Reactions	20
1,3‐Iodoesterification of 2‐Substituted Indoles via Csp2−H/Csp3−H Retained Dual Functionalization Using Hypervalent Iodine(III)	20
Hydroaminoalkyl Functionalization of Pyrimidin‐2(1H)‐ones by Visible Light Organophotocatalysis: A Radical Approach to Biginelli‐Type Dihydropyrimidines	20
Phospholanes via Twofold C‐H‐Addition to Phospholes	20
Stereoselective Organocatalyzed Glycosylation of Glycosyl Trichloroacetimidate Donors: Thiouracil as Brønsted Acid Catalyst	20
Synthesis of Deoxysugars from Aliphatic α‐Ketoacids and Aldoses Catalyzed by Thermostable Transketolase Variants from Geobacillus stearothermophilus	20
Copper‐Catalyzed α‐Indolmethylation of 2‐Pyridylacetates with 3‐Indoleacetic Acids via Alkylideneindolenine Intermediates	20
Recent Advance in Transition Metal‐Catalyzed Carboxylic Acid Guided B−H Functionalization of Carboranes	20
Thianthrenium Salts to Arynes: Base Promoted C−N Bond Construction	20
Front Cover Picture: Palladium‐Catalyzed Chemoselective Amination of Chloro(hetero)aryl Triflates Enabled by Alkyl‐Pyrazole‐Based Phosphine Ligands (Adv. Synth. Catal. 7/2024)	20
Modular Chiral Bithiophene‐2NO Ligands: Synthesis and Application in Asymmetric Palladium(II)‐Catalysed Friedel‐Crafts Alkylation	20
Photocatalytic Atom‐Transfer Radical Addition of Activated Chlorides to Alkenes	20
Update on the Synthesis of N‐Heterocycles via Cyclization of Hydrazones (2017–2021)	20
Transition‐Metal‐Catalyzed Selective Alkynylation of C−H Bonds	20
Multicomponent Heteroarylphosphorothiolation of Alkenes for Accessing β‐Phosphorothiolated Quinoxalinones	20
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Palladium‐Catalyzed Stereoselective Intramolecular Heck Dearomative Silylation of Indoles	20
Mechanochemically Induced Cross Dehydrogenative Coupling Reactions under Ball Milling	19
Recent Progress of Electron‐Withdrawing‐Group‐Tethered Arenes Involved Asymmetric Nucleophilic Aromatic Functionalizations	19
Lewis Acid‐Catalyzed Formal (4+2)‐ and (2+2+2)‐Cycloaddition Between 1‐Azadienes and Styrylmalonates as Analogues of Donor‐Acceptor Cyclopropanes	19
Au(I) and HOTf‐Catalyzed Cascade [5+1]‐Annulations between Allenylacetals and Diazo Esters To Form 1,3‐ and 2,3‐Disubstituted Naphthoates, Respectively	19
Diradical Polar Reactivity Induced by Electricity‐Mediated Ground State Triplet Nitrenium Species	19
Direct Use of Benzylic Alcohols for Multicomponent Synthesis of 2‐Aryl Quinazolinones Utilizing the π‐Benzylpalladium(II) System in Water	19

Optimizing the Iodide/Iodonium/O2 Oxidation Cycle Enhances the Scope, Selectivity, and Yields of Hydroiodic Acid‐Catalyzed Multicomponent Cyclocondensation Reactions	19
Multicomponent Annulative SO2 Insertion of Heteroatom‐Linked 1,7‐Diynes for Accessing Tricyclic Sulfones	19
Enantioselective 1,6‐Conjugate Addition of Dialkyl α‐Diazo Methylphosphonate to para‐Quinone Methides	19
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Photoredox and Copper‐Catalyzed Sulfonylphosphorothiolation of Alkenes toward β‐Sulfonyl Phosphorothioates	19
Copper(I)‐Catalyzed Intramolecular Cyclization of o‐Propargyloxy Diketopiperazines to Access Diverse Diazabicyclic and Spiro‐Diketopiperazinochromanes	19
Asymmetric Synthesis of Chiral α‐CF2H Spiro[Indoline‐3,3′‐Thiophene] via Phase‐Transfer Catalyzed Sulfa‐Michael/Michael Domino Reaction	19
Synthesis of Oxadihydrophenanthroquinolizidinones by Photoinduced Rearrangement of 3‐Biphenyl‐1‐hydroxypropyl‐pyridin‐2(1H)‐ones	19
Ru(II) Catalyzed Oxidative Dehydrogenative Annulation and Spirocyclization of Isoquinolones with N‐Substituted Maleimides	19
Catalyst‐Free Electrophilic Ring Expansion of N‐Unprotected Aziridines with α‐Oxoketenes to Efficient Access 2‐Alkylidene‐1,3‐Oxazolidines	18
Photoinduced Transition‐Metal‐Free Chemodivergent Phosphorylation‐Peroxidation and Oxyphosphorylation of Alkenes	18
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A Mild Reductant NHC‐ligated Borane for N‑Formylation of Amines with CO2 under Ambient Conditions	18
Regioselective Construction of Indolylated Cyclic Tetrasubstituted Carbon Centers through Brønsted Acid‐Catalyzed Dearomative Skeletal Rearrangement of Azofurans	18
Asymmetric Epoxidation of Enones Promoted by Dinuclear Magnesium Catalyst	18
Rhodium(III)‐Catalyzed Redox‐Neutral Synthesis of Indenones from 2‐Aryl‐3‐nitrosoindoles with Alkynes	18
Asymmetric Conjugate Addition of 3‐Hydroxychromen‐4‐Ones to Electron‐Deficient Olefins Catalyzed by Recyclable C2‐Symmetric Squaramide	18
Molybdenum‐Catalyzed Direct Synthesis of Pyrroles from Nitroarenes with Glycols as Reductants	18
Directed Nickel‐Catalyzed pseudo‐Anomeric C−H Alkynylation of Glycals as an Approach towards C‐Glycoconjugate Synthesis	18
Iron Catalyzed Radical Alkylation of Cyclic Ketimines with Olefins via Metal Hydride Atom Transfer	18
Water‐Facilitated Nitromethane‐Mediated Cyclization of 2‐(Phenylvinyl)benzhydrols: Access to 1,3‐Diphenyl‐1H‐indenes with Antitumor Activity	18
Copper‐Catalyzed Tandem Cyclization of 2‐(Alkynylaryl)Acetonitriles and Amines: Access to 3‐Hydroxyisoindolinones	18
Arylation of Secondary Phosphines with Diaryliodonium Salts under Metal‐Free and Non‐Photochemical Conditions	18
Use of Iridium‐Catalyzed Transfer Vinylation for the Synthesis of Bio‐Based (bis)‐Vinyl Ethers	18
Synthesis of 1‐Aryl Isoquinolinones or o‐Diaryl Pyrimidines via Bismuth Triflate‐Mediated Intermolecular Annulation of Arylacetic Acids with Nitroarylaldehydes or Trimethoxybenzene in the Prese	18
Peroxidation and Skeletal Rearrangement for the Synthesis of Dioxole‐2‐Carboxamide Derivatives under Continuous‐Flow Conditions	18
Catalyst‐ and Substrate‐Dependent Chemodivergent Reactivity of Stabilised Sulfur Ylides with Salicylaldehydes	18
Well‐Defined [Cp*Co(N,O)I]‐Catalysts for Site‐Selective Intramolecular C−H Amidation	18
Advances of Chiral Metal Complexes as Standalone Photocatalyst for Asymmetric Organic Transformations	18
Asymmetric Boracarboxylation of Styrenes Using Carbon Dioxide	18
Stereoconvergent Access to Z‐Allylborons from E/Z‐Mixed 1,3‐Dienes via Cu‐Guanidine Catalysis	18
Corrigendum: Mechanistic Insights on the Enantioselective (4+3) cycloaddition between Oxyallylcations and Furans Catalyzed by BINOL‐based Phosphoramides	18
Amide synthesis via transaminative amidation of aromatic aldehydes/ketones: An entry to 15N isotopologs	18
Visible Light Induced EDA‐mediated Deaminative C‐2 Alkylation of Heterocyclic‐N‐Oxides using Katritzky salts	18
Enantioselective Catalyzed Synthesis of Amino Derivatives Using Electrophilic Open‐Chain N‐Activated Ketimines	18
Protein Engineering of d‐Succinylase from Cupriavidus sp. for d‐Amino Acid Synthesis and the Structural Implications	18
In Situ Generation of Copper Nanoparticle‐Graphitic Carbon Nitride Composite for Stereoselective Transfer Semihydrogenation of Alkynes: Evaluation of Catalytic Activity Using Fluorescence‐Based	18
Carboxylic acids as enabling directing groups in C‐H activation and functionalization: A decade review	17
One‐Pot Synthesis of 1,2,3‐Triazolo Polycyclic Systems via Copper‐Catalyzed/TsOH‐Promoted Tandem Annulation of 1,6‐Allenynes with Organic Azides	17
Auxiliary‐Free Remote Dearomatizative Nitrenoid Transfer for Enantioselective Construction of Spirolactams	17
Reaction of Indole‐2‐Carboxylates/Carboxylic Acids with Propargylic Alcohols: Dearomative Ring Expansion/Spirocyclization vs Fused Pentacyclics	17
Iron‐Catalyzed Alkene Trifluoromethylation in Tandem with Phenol Dearomatizing Spirocyclization: Regioselective Construction of Trifluoromethylated Spirocarbocycles	17
Synthesis of Indoline‐Fused 2,5‐Diketopiperazine Scaffolds via Ugi‐4CR in the Basic Mediated Tandem Consecutive Cyclization	17
Electrochemical Decarboxylative Coupling of N‐Substituted Glycines under Air: Access to C3‐Aminomethylated Imidazo[1,2‐a]pyridines	17
Photocatalyzed Aerobic Dearomatization of Naphthylamines under Visible‐Light Irradiation	17
Controllable Synthesis of Oxa‐/Thia‐Spirohydroquinolines by [3+(2+1)] Annulation of Aromatic Amines with Bimolecular O/S‐Heterocyclic Ketones	17
Recent Advances in the 1,2‐Diarylation of Alkenes	17
Visible‐Light‐Induced Stereoselective C(sp3)−C(sp3)−H Glycosylation for the Synthesis of C‐Glycoamino Acid Derivatives	17
Synthesis of Functionalized Benzo[f]chromanes and Hydroxyalkyl Naphthols: Catalytic Coupling of Naphthols and Allylic Alcohols	17
Oxoammonium Salt‐Mediated Vicinal Oxyazidation of Alkenes with NaN3: Access to β‐Aminooxy Azides	17
Visible‐Light‐Induced Oxidative Carboazidation of Arylacrylamides	17
Synthesis of SCF3‐Substituted Sulfonium Ylides from Sulfonium Salts or α‐Bromoacetic Esters	17
A Solely Fe‐Catalyzed Sonogashira‐Type Coupling of non‐Activated Secondary Alkyl Iodides with Terminal Alkynes	17
Front Cover Picture: Aromatic C−H Hydroxylation Reactions with Hydrogen Peroxide Catalyzed by Bulky Manganese Complexes (15/2021)	17
Cobalt Catalyst‐Controlled Selective Dioxygenation of Styrenes Using N‐Hydroxyphthalimide with Molecular Oxygen	17
Synthesis of 5‐Trifluoromethyl‐1,2,4‐Triazoles via Metal‐Free Annulation of Trifluoroacetimidohydrazides and Methyl Ketones	17
Synthesis of 2‐Aryl‐2H‐1,2,3‐triazoles via P(OMe)3‐Promoted Intramolecular Transannulation of 4‐Diazenylisoxazol‐5(4H)‐ones	17
Iron‐Catalyzed C−C and C−N Bond‐Forming Tandem Amidation Offering Access to 3‐Amino‐3‐Aminomethyl‐2‐Oxindole Frameworks	17
Visible‐Light Photoredox‐Catalyzed Tandem One‐Pot Construction of C4‐Difluoroalkylated Phthalazin‐1(2H)‐Ones	17
Transition‐Metal‐Free Regioselective Direct C2, C4 Difunctionalization and C2, C4, C6 Trifunctionalization of Pyridines	17
Front Cover Picture: Mechanochemical Ni‐Catalysed Arylation of ortho‐Hydroxyarylenaminones: Synthesis of Isoflavones (Adv. Synth. Catal. 20/2022)	17
Controllable Access to Furans and Dihydrofurans through Cyclization/Coupling of Internal Acetylenic β‐Ketoesters with Aryl Bromides	17
Strategies and Methods for the Synthesis of 2‐Pyrazolines: Recent Developments (2012–2022)	17
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Recent Advances in Cyclization Reactions of 1,6‐Enynes	16
Palladium‐Catalyzed Chemoselective Amination of Chloro(hetero)aryl Triflates Enabled by Alkyl‐Pyrazole‐Based Phosphine Ligands	16
Selective Access to Sultams and Spirocyclic Sultams by the Divergent Annulations of (N‐Aryl)‐Alkynyl Sulphonamides	16
Molecular Oxygen‐Induced Transamidation of Unactivated Amides in Diethyl Carbonate in the Presence of a Palladium Catalyst	16
Synthesis of 3‐Arylazoindoles through Iron(III)‐Catalyzed C−H Azolation of Indoles and Arylhydrazines	16
Ruppert‐Prakash Reagent (TMSCF3)‐Catalyzed Chemoselective Esterification of Weinreb Amides	16
Maleimide‐Controlled Formation of Indanonylpyrrolinediones and Spiroindanonylpyrrolinediones via Rh(III)‐Catalyzed C−H Activation of Sulfoxonium Ylides	16
Visible‐Light‐Enabled Photosensitizer‐ and Additive‐Free Decarboxylative Coupling Cyclization of Enaminone withN‐Arylglycine for 3‐Aminoalkyl Chromones	16
Synthesis of 4‐Phosphinylpyrrolidin‐3‐ones via [3+2] Cycloaddition of Nitrones with Phosphinylallenes	16
Bu4NHSO4‐Catalyzed Direct N‐Allylation of Pyrazole and its Derivatives with Allylic Alcohols in Water: A Metal‐Free, Recyclable and Sustainable System	16
An Acid Promoted, Domino Approach for the Selective Synthesis of Spirocyclic Systems#	16
Three‐Component Allylic Alkylation Reaction of α‐Diazo Ketones with Water and Allyl Carbonates for Construction of Homoallylic Alcohols	16
Synthesis of Monofluorocyclohexene via Photocatalytic Defluorinative [4+2] Annulation of gem‐Difluoroalkenes with Unactivated Alkenes	16
Cobalt‐Catalyzed C−H Alkoxylation of Ferrocenes with Alcohols under Mild Conditions	16
C−N Coupling between Aryl Azides and Cyclopropanols by Photoredox/Copper Dual Catalysis	16
TEMPO Mediated Cyclopropanols Ring Opening C−N Cross‐Coupling with Nitrogen Nucleophiles	16
Electrochemically‐Driven Organocatalytic Enantioselective Oxidative Coupling of Tetrahydroisoquinolines and Acrylaldehyde	16
Brønsted Base‐Catalyzed Tandem [2+4] Annulation/Tautomerization/Aromatization Reaction of α‐Alkylidene Succinimides with 5‐Alkenyl Thiazolones	16
Modular Synthesis of 2,3,4,6‐Tetrasubstituted Thieno[2,3‐c]furans Based on Formal [3+2] Cycloaddition Utilizing [1,2]‐Phospha‐Brook Rearrangement / Brønsted Base‐Mediated Cyclization Strategy	16
Organocatalytic Enantioselective Construction of Acyclic N,N‐Acetals via Aza‐Addition of Arylamines to Ketimines	16
Manganese‐Mediated Electrooxidative Ring‐Opening Azidation of Cyclobutanol Derivatives with TMSN3	16
Electrochemical α‐Functionalization of N‐Aryl‐Activated Tertiary Amines	16
Accessing 2‐(Chalcogen)benzothiazoles via Electrochemical Intermolecular Cyclization of Isocyanides with Thiols or Diselenides	16
Silver‐Catalyzed [3+2] Cycloaddition for the Diastereoselective Synthesis of anti‐3‐Substituted Hydroindolin‐2‐Imines	16
Modular Photochemical Flow Synthesis of Structurally Diverse Benzyne and Triazine Precursors	16
Synthesis of Functionalized 3‐(1H‐Isochromen)‐chromones via Ag2O‐Catalyzed Cascade Cyclization Reaction of o‐Hydroxyarylenaminones with o‐Alkynylbenzaldehydes	16
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γ‐Terpinene: Biorenewable Reductant for the Molybdenum‐Catalyzed Reduction of Sulfoxides, N‐Oxides and Nitroarenes	16
[(5+1)−1] Cyclization of Nitroepoxides to Pyridinium 1,4‐Zwitterionic Thiolates for the Synthesis of Indolizine Derivatives	16
Copper‐Catalyzed Olefinic C(sp2)−H Activation/Carbene Insertion/Ester Hydrolysis/Cyclization with Aryl Diazo Esters for the Synthesis of Multisubstituted Furanones	16
CeO2‐Nanorods‐Catalyzed Protoboration of Alkenes and Alkynes with Bis(pinacolato)diboron	15