Advanced Synthesis & Catalysis

Papers
(The TQCC of Advanced Synthesis & Catalysis is 9. The table below lists those papers that are above that threshold based on CrossRef citation counts [max. 250 papers]. The publications cover those that have been published in the past four years, i.e., from 2022-08-01 to 2026-08-01.)
ArticleCitations
Palladium‐Catalyzed Reaction of 2,3‐Allenols with Amines: Synthesis of [3]Dendralenes and 1,3‐Dienes Containing Allylic Amino and Hydroxy Groups112
Electrochemical Stereoselective Synthesis of (Z)‐Allyl Aryl Selenides and Sulfides from Baylis‐Hillman Acetates112
Synthesis of 2‐Amino‐3‐arylindoles and their Fused Analogues via Intramolecular C‐Arylation107
Divergent Reactivity of E/Z‐Azobenzene‐Based Phosphine‐Gold Catalysts: Toward an ON‐ON Catalytic Photoswitch Process60
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Front Cover Picture: Chemo‐ and Regioselective Construction of Functionalized Isocoumarin, Flavone, and Isoquinolinedione via a One‐pot Reaction of o‐Quinol Acetate and Soft Nucleophiles51
Tandem Enantioselective Cycloaromatization/Intramolecular Friedel–Crafts Desymmetrization of Cyclohexadienones47
Front Cover Picture: Catalytic Asymmetric Arylations of Ketimines (Adv. Synth. Catal. 12/2024)47
Front Cover Picture: Filling the Gaps in the Challenging Asymmetric Hydrogenation of Exocyclic Benzofused Alkenes with Ir−P,N Catalysts (Adv. Synth. Catal. 2/2023)47
Cover Picture: Bench‐Stable Electrophilic Reagents for the Direct Di‐ and Trifluoroethylthiolation of Indoles (Adv. Synth. Catal. 20/2023)46
Unusual Ring Opening of Bicyclic Terpenes During Pd‐Catalyzed Coupling with Aromatic Halides46
Asymmetric Synthesis of Tricycle‐Fused Dispirooxindoles via Organocatalyzed Three‐Component Cascade Reactions of 2‐Pyrones and Trifluoroethylisatin Ketimines45
Copper‐Catalyzed Acylhalogenation of 3‐Methylanthranils with Acid Halides: Synthesis of N‐(2‐(2‐Haloyl)phenyl)amides43
Gold‐Catalyzed Annulation Between 1‐[2‐(Dimethoxymethyl)phenyl]prop‐2‐yn‐1‐yl Acetates and α‐Diazo Esters or Anilines to Form Substituted Naphthoates and Indeno[1,2‐b]quinoline, Respectively43
Electrochemical Oxidative C−C Bond Functionalization of Methylenecyclopropanes with Diselenides/Ditellurides Leading to 2‐Substituted‐3,4‐Dihydronaphthalenes42
Tandem Asymmetric Cycloaromatization/ Intramolecular Pictet‐Spengler‐Type Reaction. An Entry to Polycyclic Pyrroles42
One Pot Synthesis of 1,2‐Disubstituted Ethanones by Base‐Mediated Reductive Homocoupling of Aldehydes42
Magnesium and Calcium Bisguanidinates: Catalytic Activity in the Hydroboration of Unsaturated Molecules42
Synthesis of 2‐Aminopyridines via Cobalt‐Catalyzed Cycloaddition of Diynes with N‐Substituted and N‐Unsubstituted Cyanamides41
Access to 2‐Sulfonyl‐4‐arylphenols and 2,6‐Bis‐sulfonyl 5‐Aryl‐4‐arylidene‐2‐cyclohexenones via Metal Triflates‐Catalyzed Domino Cyclocondensation of 1,3‐Bis‐sulfonylacetones and 3‐Arylacroleins41
Palladium‐Catalyzed Aryloxycarbonylayion of Aryl Bromides with Phenols Using Inositol Hexaformate as an Efficient CO Source41
Harnessing Alkene Radical Anions via Electroreduction Strategy: An Emerging Paradigm for Alkene Functionalization40
Enantioselective Syntheses of Multiply Functionalized Six‐Membered Carbocycles from Nitroalkenes and γ,δ‐Unsaturated ß‐Ketoesters using Chiral Catalysts Derived from Cobalt(III) and 1,2‐Diphenylethyle39
Cooperative Photocatalysis of 9,10‐Phenanthrenequinone and Sn(OTf) 2 for Direct Mannich Reaction of Ethers via Hydrogen Atom Transfer Pathway38
Silver‐Enabled Inverse Electron Demand Thermal Decarbonylative Skeletal Expansion: A New Gateway to the Synthesis of Multifunctionalized Quinoline38
Bifunctional Photocatalysts for Asymmetric Epoxidation of Chalcones38
Three‐Dimensional Spirobifluorene‐Based COF for Metal‐Free Photocatalytic CH Oxidation Reaction38
Harnessing the Excited‐State Reactivity of o ‐Nitrobenzyl Alcohols for the Rapid Synthesis of N ‐Substitut37
Regio‐ and Stereoselective, Intramolecular [2+2] Cycloaddition of Allenes, Promoted by Visible Light Photocatalysis36
Aryne‐Based Synthesis of Cyclobutadiene‐Containing Oligoacenes and Related Extended Biphenylene Derivatives36
Formal Insertion of a Metal Carbene Complex into a σ‐Carbon‐Carbon Bond. Gold‐Catalyzed Synthesis of 3H‐Indoles36
Catalyst‐Free, One‐Pot, Three‐Component Synthesis of 3‐Arylsulfonylated Thioflavones36
A Gold(I)‐Catalyzed Cyclization/Semipinacol Rearrangement Cascade of 1,6‐Enynes to Access Spiro[4.5]decanes and 7‐Azaspiro[4.5]decanes35
Bis(oxazoline)–Nickel(II)‐Catalyzed Asymmetric Photochemical Hydroxylation of β‐Keto Esters With Nitrones35
Solvent‐ and Temperature‐Switched Chemoselectivity: Controlled Synthesis of Diverse Pyrazolo[5,1‐a]isoquinolines35
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Photoinduced Ligated Boryl Radical‐Mediated Functionalization of Organic Halides35
Visible‐light‐induced and EDA Complex‐initiated Hydroxyselenization of α ‐CF 3 Alkenes: Access to 34
Electrochemical Imidoyl Radical‐Involved Functionalization of Isocyanides to Construct Benzotriazole‐Sulfonamide and Guanidine Derivatives34
The Novel Strategies for the Construction of Homoallylic Alcohols via Photoredox Catalysis33
Machine Learning Guided d‐Orbital Electron Modulated Graphene‐Based Catalysts for Enhanced Electrochemical Ammonia Synthesis33
Enzymatic Dimerization of Fungal Natural Products Through Intermolecular Disulfide Bridges33
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Synthesis of Furfural Sulfides and 4‐Alkylthiopyridines via Heterocyclization of α‐Acyl Ketene Dithioacetals32
Highly Selective Generation of 1 O 2 via Peroxymonosulfate Activation by Nonmetal P‐Doped Carbon M32
Iron‐Catalyzed Regioselective Double Hydrothiolation and Double Hydrophosphination Reactions Toward Acetylene C≡C Triple Bond32
Palladium‐Catalyzed Crosscoupling Stereoselective Construction of Dienes via Z ‐Alkenylation of Vinyl Bromides32
Witnessing the Birth of Directed Evolution of Stereoselective Enzymes as Catalysts in Organic Chemistry31
Nitrosonium Ion Catalyzed Oxidative Bromination of Arenes31
Front Cover: Functionalized Diaryliodonium Salts with N ‐Reactive Amides: Versatile Reactivity for Constructing Benzo‐Fused Nitrogen Heterocycles (Adv. S31
A Lewis Base Hydrogen Bond Donor (LB/HBD) Organocatalytic Approach to Dithiabridged Triarylamine Hetero[4]helicenes30
Front Cover: Selective Oxidation of Primary Amines to Nitriles Catalyzed by the Ru‐Doped Hexagonal Perovskite SrMnO 3 (Adv. Synth. Catal. 13/2026)30
Enantioselective Synthesis of Five to Eight‐Membered P‐Stereogenic Benzo‐Fused Heterocycles via Copper‐Catalyzed Dynamic Kinetic Resolution30
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Ruthenium (II)‐Catalysed Regioselective C6 Alkylation of Indoles with Maleimides30
Gold(I)‐Catalyzed Cascade Cyclization of Nitrogen or Oxygen Containing Nucleophile Tethered‐Vinylidenecyclopropanes to Pyrrole, Furan, Pyrrolidine and Piperidine Skeletons30
Diastereoselective Synthesis of Tetracyclic Indoles via Stepwise Annulative Skeletal Editing of Azofurans29
Martin Silicates as Partners in Photoredox/Ni Dual Catalysis for the Installation of CH3, CH2D, CD2H, CD3 and 13CH3 Groups onto (Heter29
Cu(III) Trifluoromethyl Complexes with 1,3‐Diketonate Ligands and Their Versatile Reactivity in C−H Trifluoromethylation29
Autocatalytic Reduction in the Synthesis of Multimetallic Nanocrystals: Mechanisms and Opportunities29
Regio‐ and Stereospecific Desulfinylative Chlorination of Spiroaziridine Oxindoles at Spiro‐Center for Formal [3+2]‐Cycloaddition with CS2: Sequential One‐Pot Synthesis of (−)‐Spirobrassini28
Hypervalent Halogen Compounds in Electrochemical Reactions: Advantages and Prospects28
Recent Advances in Transition Metal Catalysed Dearomatization Toward the Synthesis of Complex Cyclic Compounds28
Site‐Selective Direct Intermolecular C(sp3)−H Alkylation of Saccharides and Switching of Reaction Sites by Changing Photocatalysts28
Constructing 5‐Methyl‐2,4‐diaryl‐1H‐imidazoles Using Calcium Carbide as Alkyne Source via A3‐Coupling Cyclization28
First Bromide‐Catalyzed Selenylation of 2‐Alkyn‐1‐One O‐Methyloximes Enabled the Synthesis of 4‐Selenylated Isoxazoles27
Hypervalent Iodine‐Mediated Regioselective Dearomatization of Non‐Activated Arenes27
Synthesis of 3,4‐Dihydroquinazolinones via Base‐Promoted Formal [4 + 2] Cycloadditions27
Continuous Flow Technology Enabling Photochemistry27
N‐Containing Carbon Materials in Metal‐Free and Non‐Noble Metal Liquid Phase Heterogenous Catalysis27
A Combined Halogen‐ and Chalcogen‐Bonding Organocatalyst27
Selective Formation of 2,3,5‐Trisubstituted Furans from 1,3‐Dicarbonyls and Hydroxyketones27
tert‐Butyl Nitrite Promoted Visible‐Light‐Induced Steric‐Hindrance‐Regulated Concurrent Cross‐Coupling and Regioselective Nitration of 3‐Alkylidene‐2‐oxindoles27
Harnessing Carbenoid Reactivity From Imidazoles and Oxiranes27
Asymmetric Synthesis of Highly Substituted Spiro[2H‐pyrrole‐2,3‐Succinimide] Derivatives by Copper‐Catalyzed Post‐Ugi Reactions26
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Silver‐Mediated In‐Situ Generation of Alkynyl Selenium Intramolecular AAC Click Reactions26
Stereoselective Synthesis of Contiguous Cyclopropylaziridines: Enabling the Construction of Versatile Chiral Molecules Including γ‐Lactams via Ring‐Opening Reactions26
Visible‐Light Induced Ag‐Palladacycle‐Complex‐Mediated Regioselective C−H Arylation26
Synthesis of Dihydropyrazoles via Palladium‐Catalyzed Cascade Heterocyclization/Carbonylation/Arylation of β,γ‐Unsaturated N‐Tosyl Hydrazones26
Imidazolium‐Dithiocarboxylate Zwitterions Catalysed Ring‐Opening Additions of Cyclopropenones26
SuFEx Reactions When Shaken Not Stirred26
K2S2O8‐Mediated Access to Alkylsulfonated Spiro[4,5] Trienones from N‐Arylpropiolamides with the Insertion of Sulfur Dioxide26
Phosphine‐Catalyzed (4+2) Annulation of Alkenes with Acidic Hydrogen‐Tethered Allylic Carbonates25
Visible‐Light‐Induced Controlled C–H Cyanation or Thiocyanation of Indolizines25
Nickel/Copper Co‐catalyzed Enantioselective Reductive Coupling of Oxabenzonorbornadienes with Vinyl Bromides25
Special Issue Dedicated to Miquel A. Pericàs25
K3PO4–Mediated Synthesis of Chromeno–[3,4‐c]isoxazole from 3–Nitro–2H–chromene and α–Chloro Aldehyde via Michael Addition/C−Cl Bond Cleavage/Deformylation as25
Multifaceted Domino Knoevenagel‐Cyclization Reactions; Four Movements for 2H‐Chromenes and Chromans25
Renewable Platform Chemicals: The Bulk Chemicals of the Future25
N−H Trifluoroethylation of Indoles and other Aromatic N‐Heterocycles with CF3CHCl2 by Copper‐Mediated Cross‐Coupling Reaction25
N,N’‐Difluoro‐2,2’‐bipyridinium Bis(tetrafluoroborate): a New Terminal Oxidant for Iodoarene‐catalyzed Fluorination Reactions25
A Mild Metal‐Free Approach for the Direct Synthesis of Carbamoyl Azides from Carboxylic Acid Redox Active Esters25
Total Synthesis of the Myrioneuron Alkaloid (−)‐Schoberine B and Its Enantiomer (+)‐Schoberine B25
Functionalized Alkylidenecyclobutanes from a Cyclopent‐2‐enone Substrate via a Tandem Photochemical Transformation and an Allylic Substitution Protocol24
Photo‐Catalyzed Stereospecific Synthesis of Trisubstituted Alkenes Incorporating 3,3‐Difluoro‐γ‐Lactams from Morita‐Baylis‐Hillman Acetates and N‐Allylbromodifluoroacetamides24
Bidentate NHC‐Containing Ligands for Copper Catalysed Synthesis of Functionalised Diaryl Ethers24
Palladium‐Catalyzed Denitrative Decarboxylation of Nitroarenes with Alkynyl Carboxylic Acids24
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Ring‐Opening Amino Esterification of Cyclic Ketones to Access Distal Amino Acid Derivatives24
Palladium Catalysis: Dependence of the Efficiency of C−C Bond Formation on Carboxylate Ligand and Alkali Metal Carboxylate or Carboxylic Acid Additive. Part C: The Domino Diarylation and Annelation Re24
Construction of α‐Pyrones and Enamine Derivatives via Divergent Transformations of β‐Aminoacrylates24
Front Cover Picture: Redox‐Neutral Vicarious‐Type Nucleophilic Amination of Heterocyclic N‐Oxides with Organic Azides (Adv. Synth. Catal. 19/2024)24
Copper‐Catalyzed Domino Synthesis of Spiropyrazoline Oxindoles via Condensation of Indolin‐2‐One and Phenylhydrazine Derivatives24
Indazolones Directed Rh(III)‐Catalyzed C−H Amidation of Arenes24
Selective Hydrogenation of Nitriles to Secondary Imines Using a Pincer Manganese Complex23
Cobalt(III)‐Catalyzed Aerobic Diamination of α‐Alkyl Styrenes with Anilines23
Stereoselective Synthesis of Aliphatic α‐Amino Acids by Chemo‐Enzymatic Hydroamination‐Hydrodesulfurisation23
Gold‐Catalyzed Annulation of Ynamides with Aminocarbonyls as a Route to 2‐Aminoquinolines Diversely Substituted at the 4th‐Position23
The Chemistry of α‐Enolizable Alkynones: A Comprehensive Review23
An Organocatalytic Route to endo‐Vinylene Carbonates from Carbon Dioxide‐Based exo‐Vinylene Carbonates23
Pd‐Catalyzed Ring‐Opening Defluorinative Arylation of gemDifluorocyclopropanes with Arylsilanes23
Tailoring Surface Hydrophobicity of Fe–N–C Catalysts via Fluorine Substitution in Aniline Precursors for Improved AEMFC Performance23
Monofluorinated C1 Synthon Strategy for the Construction of Fluoromethylene‐Linked Bicyclo[1.1.1]Pentane Derivatives22
One‐Pot Synthesis of Quinazolines via Elemental Sulfur‐Mediated Oxidative Condensation of Nitriles and 2‐(Aminomethyl)anilines22
A Redox‐Neutral Organophotocatalytic Cascade: Difluoromethylation and Radical Truce–Smiles ‐Driven C( sp <22
Divergent Synthesis of 3‐Trifluoroethyl Benzofurans Through Rh‐Catalyzed CC Bond Activation Coupled with Transfer Hydrogenation22
Iron‐Catalyzed Oxyphosphorylation of Styrenes to Access β‐Ketophosphonates and α, β‐Unsaturated Ketones22
Copper‐Catalyzed Cross Coupling Reaction of Alkyl Bromides with (DMPU) 2 Zn(R f ) 22
DABCO‐Promoted Selective Photochemical C−N Coupling: Access to Unsymmetrical Azahelicenes22
Radical Sulfonylation of Diazo Compounds With Sulfinates Triggered by Formation of Photoactive Electron Donor–Acceptor Complex22
2‐Aminoindoles and 2‐Iminoindolines as Viable Precursors of Indole‐Fused Nitrogenated Polyheterocycles22
Gold‐Catalyzed Redox‐Neutral Reaction of Nitriles with Quinoline N‐Oxides22
Visible‐Light‐Driven Organocatalyzed Chemoselective Oxidation of Benzylamines22
Thianthrenium Salts to Arynes: Base Promoted C−N Bond Construction22
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Preparation of Mesoporous Cu2O Nanospheres for Green Synthesis in the Enantioselective Boron Conjugate Addition of α,β‐Unsaturated Chiral Compounds in Aqueous Phase21
Amide Synthesis via Transaminative Amidation of Aromatic Aldehydes/Ketones: An Entry to 15 N Isotopologs21
Peroxidation and Skeletal Rearrangement for the Synthesis of Dioxole‐2‐Carboxamide Derivatives under Continuous‐Flow Conditions21
1,3‐Iodoesterification of 2‐Substituted Indoles via Csp2−H/Csp3−H Retained Dual Functionalization Using Hypervalent Iodine(III)21
Novel Synthesis of Benzo[ e ][1,2,4]triazines via Cyclocondensation of Azooximes21
Iron Catalyzed Radical Alkylation of Cyclic Ketimines with Olefins via Metal Hydride Atom Transfer21
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Unexpected Stereoselective Access to 2‐Aminooxazolines from Propargyl Ureas by Silver Salts under Mild Conditions21
Pincer‐Ruthenium Catalyzed Oxygen Mediated Dehydrative Etherification of Alcohols and Ortho‐Alkylation of Phenols21
Ru(II) Catalyzed Oxidative Dehydrogenative Annulation and Spirocyclization of Isoquinolones with N‐Substituted Maleimides21
Front Cover Picture: Palladium‐Catalyzed Chemoselective Amination of Chloro(hetero)aryl Triflates Enabled by Alkyl‐Pyrazole‐Based Phosphine Ligands (Adv. Synth. Catal. 7/2024)21
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Copper‐Catalyzed α‐Indolmethylation of 2‐Pyridylacetates with 3‐Indoleacetic Acids via Alkylideneindolenine Intermediates21
Arylation of Secondary Phosphines with Diaryliodonium Salts under Metal‐Free and Non‐Photochemical Conditions21
Synthesis of Oxadihydrophenanthroquinolizidinones by Photoinduced Rearrangement of 3‐Biphenyl‐1‐hydroxypropyl‐pyridin‐2(1H)‐ones21
Modular Chiral Bithiophene‐2NO Ligands: Synthesis and Application in Asymmetric Palladium(II)‐Catalysed Friedel‐Crafts Alkylation21
Au(I) and HOTf‐Catalyzed Cascade [5+1]‐Annulations between Allenylacetals and Diazo Esters To Form 1,3‐ and 2,3‐Disubstituted Naphthoates, Respectively21
Molybdenum‐Catalyzed Direct Synthesis of Pyrroles from Nitroarenes with Glycols as Reductants20
Asymmetric Hydrogenation of Tetrahydro‐γ‐Carboline Derivatives with Phosphine‐Free Ruthenium Diamine Catalysts20
Diradical Polar Reactivity Induced by Electricity‐Mediated Ground State Triplet Nitrenium Species20
Corrigendum: Cyclic Sulfoximine and Sulfonimidamide Derivatives by Copper‐Catalyzed Cross‐Coupling Reactions with Elemental Sulfur20
Harnessing Photoredox Catalysis to Access β ‐Ketoamino Esters from 3‐(2‐Isocyanoethyl)indoles20
Phospholanes via Twofold C‐H‐Addition to Phospholes20
Stereoconvergent Access to Z‐Allylborons from E/Z‐Mixed 1,3‐Dienes via Cu‐Guanidine Catalysis20
A Sequence‐Controlled Di‐Functionalization of an SO2‐Surrogate with Amines for the Synthesis of Sulfonamides20
Recent Progress of Electron‐Withdrawing‐Group‐Tethered Arenes Involved Asymmetric Nucleophilic Aromatic Functionalizations20
Stereoselective Organocatalyzed Glycosylation of Glycosyl Trichloroacetimidate Donors: Thiouracil as Brønsted Acid Catalyst20
Synthesis of Deoxysugars from Aliphatic α‐Ketoacids and Aldoses Catalyzed by Thermostable Transketolase Variants from Geobacillus stearothermophilus20
Iron‐Catalyzed Regioselective C(sp 2 )H Alkylation and Heteroannulation of Hydroxyarenes With 2‐Aryl Aziridines20
Dibenzoylperoxide as a Versatile Oxidant for Oxidative Azidations of Phenols Using Quaternary Ammonium Iodides or Bromides.20
N ‐Fluoroalkylthiolation of Amines and Sulfonamides with Fluoroalkyl Sulfoxide as Fluoroalkylthiolating Reagent20
Asymmetric CH Functionalization Enabled by a Traceless Oxidizing Chiral Auxiliary20
Sustainable Photoelectrochemical Geminal α‐Fluorosulfenylation of Diazo Compounds through Carbene Radical Anion Intermediate19
A Mild Reductant N‐Heterocyclic‐Carbene‐Ligated Borane for N ‐Formylation of Amines with CO 2 under Am19
Photoredox and Copper‐Catalyzed Sulfonylphosphorothiolation of Alkenes toward β‐Sulfonyl Phosphorothioates19
Brønsted Acid‐Catalyzed Enantioselective and Para‐Selective Addition of Phenols to 1‐Alkynylnaphth‐2‐Ols19
Multicomponent Annulative SO2 Insertion of Heteroatom‐Linked 1,7‐Diynes for Accessing Tricyclic Sulfones19
Metal‐Free Chemoselective Amide Bond Cleavage for the Synthesis of N ‐Acyl Sulfoximines in Batch and Flow19
Front Cover Picture: (Adv. Synth. Catal. 10/2025)19
One‐Pot Tandem Cyclization of β‐Oxoamides, Primary Amines, and 3‐bromo‐1,1,1‐trifluoroacetone: Synthesis of 2/4‐trifluoromethyl‐substituted dihydropyrrol‐2/4‐ols19
Photocatalytic Radical Transformations of Diazo Compounds: Beyond Carbene19
Direct Site‐Selective Deoxygenation of Benzylalcohol Derivatives19
Directed Palladium‐Catalyzed pseudo‐Anomeric C−H Functionalization of Glycal‐Type Substrates: Access to Unsymmetrical gem‐Diarylmethyl C‐Glycosides19
DMAP‐promoted [4+2]/[3+3] Annulation Cascade Reaction of Morita–Baylis–Hillman Carbonates with Conjugated Imines to Access Functionalized Benzo[c][2,7]naphthyridine Skeletons19
Recent Advances in Photocatalytic Cleavage Reactions of Halogenated Difluoromethyl Reagents19
Tailoring Benzylic C(sp 3 ) H Bond Functionalization Strategies of Benzyl Alcohols: A Review on Selec19
Recent Advance in Transition Metal‐Catalyzed Carboxylic Acid Guided B−H Functionalization of Carboranes19
In Situ Generation of Copper Nanoparticle‐Graphitic Carbon Nitride Composite for Stereoselective Transfer Semihydrogenation of Alkynes: Evaluation of Catalytic Activity Using Fluorescence‐Based19
Halogen Atom Transfer Enabled Radical Fluoroalkyl‐Thiolation of Unactivated Alkenes19
Multicomponent Heteroarylphosphorothiolation of Alkenes for Accessing β‐Phosphorothiolated Quinoxalinones19
Visible Light Induced EDA‐mediated Deaminative C‐2 Alkylation of Heterocyclic‐ N ‐Oxides using Katritzky salts18
Mechanistic Insight into Palladium‐Catalyzed Asymmetric Alkylation of Indoles with Diazoesters Employing Bipyridine‐N,N’‐dioxides as Chiral Controllers18
Controllable Access to Furans and Dihydrofurans through Cyclization/Coupling of Internal Acetylenic β‐Ketoesters with Aryl Bromides18
Solvent‐Switchable Regiodivergent Chlorination of Quinone Monoacetals: A Practical Route to 2‐ and 3‐Chlorophenols18
Divergent Synthesis of Oxindole Derivatives via Cascade Deoxygenative Friedel–Crafts Cyclization of α ‐Ket18
Visible‐Light‐Induced Oxidative Carboazidation of Arylacrylamides18
Controllable Synthesis of Oxa‐/Thia‐Spirohydroquinolines by [3+(2+1)] Annulation of Aromatic Amines with Bimolecular O/S‐Heterocyclic Ketones18
Rhodium(III)‐Catalyzed Redox‐Neutral Synthesis of Indenones from 2‐Aryl‐3‐nitrosoindoles with Alkynes18
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Hydroaminoalkyl Functionalization of Pyrimidin‐2(1H)‐ones by Visible Light Organophotocatalysis: A Radical Approach to Biginelli‐Type Dihydropyrimidines18
Water‐Facilitated Nitromethane‐Mediated Cyclization of 2‐(Phenylvinyl)benzhydrols: Access to 1,3‐Diphenyl‐1H‐indenes with Antitumor Activity18
Iron‐Catalyzed C−C and C−N Bond‐Forming Tandem Amidation Offering Access to 3‐Amino‐3‐Aminomethyl‐2‐Oxindole Frameworks18
Copper‐Catalyzed Olefinic C(sp2)−H Activation/Carbene Insertion/Ester Hydrolysis/Cyclization with Aryl Diazo Esters for the Synthesis of Multisubstituted Furanones18
Maleimide‐Controlled Formation of Indanonylpyrrolinediones and Spiroindanonylpyrrolinediones via Rh(III)‐Catalyzed C−H Activation of Sulfoxonium Ylides18
Copper‐Catalyzed Tandem Cyclization of 2‐(Alkynylaryl)Acetonitriles and Amines: Access to 3‐Hydroxyisoindolinones18
Front Cover Picture: Mechanochemical Ni‐Catalysed Arylation of ortho‐Hydroxyarylenaminones: Synthesis of Isoflavones (Adv. Synth. Catal. 20/2022)18
Front Cover: Gold(I)‐Catalyzed Enantioselective Cycloisomerization of 1,6‐Oxygenated Enynes: An Entry to Hedonic Derivatives (Adv. Synth. Catal. 19/2025)18
Enantioselective Synthesis of Triarylmethanes Containing Three Different Aryl/Heteroaryl Moieties by Chiral Phosphoric Acids Catalyzed Friedel−Crafts Reactions18
Silver‐Catalyzed [3+2] Cycloaddition for the Diastereoselective Synthesis of anti‐3‐Substituted Hydroindolin‐2‐Imines18
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Heterogeneous Copper‐Catalyzed 1,4‐Conjugate Additions of Grignard Reagents to Cyclic and Linear Enones18
Accessing 2‐(Chalcogen)benzothiazoles via Electrochemical Intermolecular Cyclization of Isocyanides with Thiols or Diselenides18
Selective Access to Sultams and Spirocyclic Sultams by the Divergent Annulations of (N‐Aryl)‐Alkynyl Sulphonamides18
An Acid Promoted, Domino Approach for the Selective Synthesis of Spirocyclic Systems#18
Noncovalent‐Interaction‐Dictated Product Selectivity in Intermolecular and Intramolecular Controllable Oxidation of Aromatic Amines Using 2,2′‐Diperoxyphenic Acid17
Synthesis of 3‐Arylazoindoles through Iron(III)‐Catalyzed C−H Azolation of Indoles and Arylhydrazines17
Manganese‐Mediated Electrooxidative Ring‐Opening Azidation of Cyclobutanol Derivatives with TMSN317
Electrochemical α‐Functionalization of N‐Aryl‐Activated Tertiary Amines17
Regioselective Construction of Indolylated Cyclic Tetrasubstituted Carbon Centers through Brønsted Acid‐Catalyzed Dearomative Skeletal Rearrangement of Azofurans17
Electrochemically‐Driven Organocatalytic Enantioselective Oxidative Coupling of Tetrahydroisoquinolines and Acrylaldehyde17
Strategies and Methods for the Synthesis of 2‐Pyrazolines: Recent Developments (2012–2022)17
Molecular Oxygen‐Induced Transamidation of Unactivated Amides in Diethyl Carbonate in the Presence of a Palladium Catalyst17
A Solely Fe‐Catalyzed Sonogashira‐Type Coupling of non‐Activated Secondary Alkyl Iodides with Terminal Alkynes17
Synthesis of Difluorocyclopropanes via Visible‐Light‐Mediated [1+2] Cycloaddition of Diazo Esters with gem‐Difluoroalkenes and Evaluation of their Antifungal Activity17
Electrosynthesis of 2,5‐Disubstituted Furans through a CC Double Bond Cleavage Radical Cascade17
Visible‐Light Photoredox‐Catalyzed Tandem One‐Pot Construction of C4‐Difluoroalkylated Phthalazin‐1(2H)‐Ones17
Modular Photochemical Flow Synthesis of Structurally Diverse Benzyne and Triazine Precursors17
Advances of Chiral Metal Complexes as Standalone Photocatalyst for Asymmetric Organic Transformations17
Deoxygenative Coupling Between Morita–Baylis–Hillman Acetates and Unprotected Cycloketone Oximes Enabled by Photoredox/Ti Dual Catalysis17
Synthesis of β‐Enamino Sulfoxides via Cine ‐Substitution of 1‐Chlorovinyl p ‐Tolyl Sulfoxides with Lithium17
Synthesis of 4‐Phosphinylpyrrolidin‐3‐ones via [3+2] Cycloaddition of Nitrones with Phosphinylallenes17
Synthesis of Functionalized Benzo[f]chromanes and Hydroxyalkyl Naphthols: Catalytic Coupling of Naphthols and Allylic Alcohols17
Modular Synthesis of 2,3,4,6‐Tetrasubstituted Thieno[2,3‐ c ]furans Based on Formal [3+2] Cycloaddition Utilizing [1,2]‐Phospha‐Brook Rearrangement / Brø17
Palladium‐Catalyzed Chemoselective Amination of Chloro(hetero)aryl Triflates Enabled by Alkyl‐Pyrazole‐Based Phosphine Ligands17
C−N Coupling between Aryl Azides and Cyclopropanols by Photoredox/Copper Dual Catalysis17
Corrigendum: Mechanistic Insights on the Enantioselective (4+3) cycloaddition between Oxyallylcations and Furans Catalyzed by BINOL‐based Phosphoramides17
Facile Access to 2‐Substituted‐1,2,3,4‐Tetrahydroquinoxalines via Borane‐Catalyzed One‐Pot Tandem Cyclization/Hydrosilylation17
Asymmetric Boracarboxylation of Styrenes Using Carbon Dioxide17
Cu(I) Catalyzed Germyl S ‐Phosphorothiolation of Electron‐Deficient Alkene17
Recent Advances in the 1,2‐Diarylation of Alkenes17
Synthesis of Monofluorocyclohexene via Photocatalytic Defluorinative [4+2] Annulation of gem‐Difluoroalkenes with Unactivated Alkenes17
Selectfluor‐Mediated Directing Group and Transition Metal Catalyst‐Free Site‐Selective C7 Fluorination of 2‐Oxindoles17
Synthesis of Functionalized 3‐(1H‐Isochromen)‐chromones via Ag2O‐Catalyzed Cascade Cyclization Reaction of o‐Hydroxyarylenaminones with o‐Alkynylbenzaldehydes17
Deconstructive Alkynylation of Spiro‐Dihydroquinazolinones via Aromatization‐Driven Ring Opening Under Visible Light Irradiation16
Biocatalytic Application of Goodfellowiella coeruleoviolacea Imine Reductase: Enantioselective Synthesis of Cyclic Secondary Amines in Deep Eutectic Solv16
Water‐Mediated 1,7‐Palladium Aryl‐to‐Aryl Migration in an Unusual Aryne Trimerization Enables the Synthesis of Multihelicenes with Profoundly Hindered Stereogenic Axes16
16
Nucleophile Promoted Functionalization of Cross‐Conjugated Enynone Gives Sulfonylated Furan16
Copper‐Mediated ortho ‐C–H Etherification of Arylaldehydes Enabled by a Transient Directing Group16
γ‐Terpinene: Biorenewable Reductant for the Molybdenum‐Catalyzed Reduction of Sulfoxides, N ‐Oxides and Nitroarenes16
[(5+1)−1] Cyclization of Nitroepoxides to Pyridinium 1,4‐Zwitterionic Thiolates for the Synthesis of Indolizine Derivatives16
Visible‐Light‐Induced Stereoselective C(sp3)−C(sp3)−H Glycosylation for the Synthesis of C‐Glycoamino Acid Derivatives16
Photoinduced Transition‐Metal‐Free Chemodivergent Phosphorylation‐Peroxidation and Oxyphosphorylation of Alkenes16
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Palladium‐Catalyzed Two‐fold Annulation Reaction of 2,6‐Dihalogenobiphenyls with o‐Chloroaromatic Carboxylic Acids to Access (Aza)dibenzo[fg,op]tetracenes16
Base‐Controlled Stereodivergent Synthesis of Pyrrolidines Containing An Enaminone Moiety via Regioselective Formal (3 + 2) Cycloaddition Reactions†16
Photocatalyzed Aerobic Dearomatization of Naphthylamines under Visible‐Light Irradiation16
Synthesis of 2‐Aryl‐2 H ‐1,2,3‐triazoles via P(OMe) 3 ‐Promoted Intramolecular Transannulation of 4‐Di16
Organophosphine‐Mediated Reductive Homocoupling of Hydrated α‐Acylaldehydes16
Photocatalytic Silacyclization of 1,7‐Enynes via Selective Functionalization of Si‐H/Silyl C(sp 3 )‐H Bonds: Access to Densely Functionalized Silacyc16
Direct Assembly of Polysubstituted Furans with Dimethyl Sulfoxide as a Multipurpose Precursor via β‐C(sp3)−H Functionalization of Saturated Ketones16
Halogen‐Atom‐Transfer Enabled Radical Fluoroalkyl‐Thiolation of Unactivated Alkenes16
Zinc Hydride Complexes Stabilized by Anionic N ‐Heterocyclic Carbenes for Hydrosilylation of Aldehydes and Ketones16
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