Advanced Synthesis & Catalysis

Papers
(The TQCC of Advanced Synthesis & Catalysis is 10. The table below lists those papers that are above that threshold based on CrossRef citation counts [max. 250 papers]. The publications cover those that have been published in the past four years, i.e., from 2020-04-01 to 2024-04-01.)
ArticleCitations
A Review on the Latest Progress of Chan‐Lam Coupling Reaction187
Liquid‐Assisted Grinding Mechanochemistry in the Synthesis of Pharmaceuticals174
Recent Advances in the Construction of Spiro Compounds via Radical Dearomatization121
Recent Advances in the Synthesis of Heterocycles via Reactions Involving Elemental Sulfur113
Recent Advances in the Construction of Phosphorus‐Substituted Heterocycles, 2009–2019104
Radical C−C Bond Formation using Sulfonium Salts and Light102
Recent Advances in the Synthesis of C2‐Functionalized Pyridines and Quinolines Using N‐Oxide Chemistry100
Recent Advances in Metal‐Catalyzed Functionalization of Indoles92
Recent Developments in Radical Cross‐Coupling of Redox‐Active Cycloketone Oximes89
Synthesis of Seleno Oxindoles via Electrochemical Cyclization of N‐arylacrylamides with Diorganyl Diselenides86
Recent Advances in the Synthesis of Difluorinated Architectures from Trifluoromethyl Groups83
Visible Light Assisted Radical‐Polar/Polar‐Radical Crossover Reactions in Organic Synthesis82
Synthesis of Seleno‐Heterocycles via Electrophilic/Radical Cyclization of Alkyne Containing Heteroatoms79
Sulfonyl Hydrazides in Organic Synthesis: A Review of Recent Studies78
Photochemical and Electrochemical Strategies towards Benzylic C−H Functionalization: A Recent Update78
Progress in Electrochemical Trifluoromethylation Reactions74
Silicon‐Derived Singlet Nucleophilic Carbene Reagents in Organic Synthesis73
Fluorination and Fluoroalkylation Reactions Mediated by Hypervalent Iodine Reagents70
Direct Catalytic Functionalization of Indazole Derivatives70
Recent Advances in the Electrochemical Reduction of Substrates Involving N−O Bonds68
Oxidative Sulfonylation of Multiple Carbon‐Carbon bonds with Sulfonyl Hydrazides, Sulfinic Acids and their Salts68
Overview of Regioselective and Stereoselective Catalytic Hydroboration of Alkynes66
Utilization of C(sp3)‐Carboxylic Acids and Their Redox‐Active Esters in Decarboxylative Carbon−Carbon Bond Formation65
Aerobic Oxidative Functionalization of Indoles64
Ethylene Glycol: A Green Solvent for Visible Light‐Promoted Aerobic Transition Metal‐Free Cascade Sulfonation/Cyclization Reaction64
Aryldiazonium Salts in Photoredox Catalysis – Recent Trends62
Recent Advances in Cross‐Dehydrogenative Couplings (CDC) of C−H Bond in Aqueous Media62
Comprehensive Strategies for the Synthesis of Isoquinolines: Progress Since 200861
Synthesis of Organoselenium Compounds with Elemental Selenium60
Decarboxylation‐Initiated Intermolecular Carbon‐Heteroatom Bond Formation59
Recent Advances in Carbonylative Difunctionalization of Alkenes58
Advances in the Catalytic Asymmetric Synthesis of Atropisomeric Hexatomic N‐Heterobiaryls58
Ynamides in Free Radical Reactions57
Ruthenium Pincer Complex Catalyzed Selective Synthesis of C‐3 Alkylated Indoles and Bisindolylmethanes Directly from Indoles and Alcohols55
Multicomponent and One‐pot Syntheses of Quinoxalines55
Recent Advances in the Synthesis of Nitrogen Heterocycles Using Arenediazonium Salts as Nitrogen Sources54
Oxime‐Derived Iminyl Radicals in Selective Processes of Hydrogen Atom Transfer and Addition to Carbon‐Carbon π‐Bonds54
Advances in Transition‐Metal Catalyzed Carbonylative Suzuki‐Miyaura Coupling Reaction: An Update53
Emerging Nickel Catalysis in Heck Reactions: Recent Developments53
Recent Progress in the Construction of C−N Bonds via Metal‐Free Radical C(sp3)−H Functionalization50
Covalent Organic Frameworks in Catalytic Organic Synthesis50
Photocatalysis in Dual Catalysis Systems for Carbon‐Nitrogen Bond Formation50
Electrochemical Functionalization of Imidazopyridine and Indazole: An Overview50
Gold‐Catalyzed Oxidative Alkyne Functionalization by N−O/S−O/C−O Bond Oxidants49
Recent Advances in Organocatalyst‐Mediated Benzannulation Reactions49
Recent Advances in Squaramide‐Catalyzed Asymmetric Mannich Reactions49
Propargylic Alcohols as Coupling Partners in Transition‐Metal‐Catalyzed Arene C−H Activation48
Recent Advances in the Synthesis of Heterocyclics via Cascade Cyclization of Propargylic Alcohols48
Threat to the Throne: Can Two Cooperating Boron Atoms Rival Transition Metals in Chemical Bond Activation and Catalysis?48
Direct Carboxylation with Carbon Dioxide via Cooperative Photoredox and Transition‐Metal Dual Catalysis46
Stereoselective Construction of (E,Z)‐1,3‐Dienes and Its Application in Natural Product Synthesis45
A3 Coupling Reaction in the Synthesis of Heterocyclic Compounds45
Electrochemically Enabled Intramolecular and Intermolecular Annulations of Alkynes45
Recent Achievements in the Rhodium‐Catalyzed Concise Construction of Medium N‐Heterocycles, Azepines and Azocines44
Recent Developments in Photo‐Catalyzed/Promoted Synthesis of Indoles and Their Functionalization: Reactions and Mechanisms44
Double Carbonylation Reactions: Overview and Recent Advances44
Update on the Synthesis of N‐Heterocycles via Cyclization of Hydrazones (2017–2021)43
Recent Advances in Radical C−H Bond Functionalization of Imidazoheterocycles43
Visible Light Mediated Synthesis of Oxindoles43
Front Cover Picture: Recent Advances in the Synthesis of C2‐Functionalized Pyridines and Quinolines Using N‐Oxide Chemistry (Adv. Synth. Catal. 1/2021)43
Recent Developments in Enantioselective Multicatalyzed Tandem Reactions43
Recent Advances in the Development of Direct Trifluoromethylselenolation Reagents and Methods43
Recent Advances in Synthesis of Difluoromethylene Phosphonates for Biological Applications42
Transition‐Metal‐Catalyzed Carbohalogenative 1,2‐Difunctionalization of C−C Multiple Bonds42
Modern Synthetic Approaches to Phosphorus‐Sulfur Bond Formation in Organophosphorus Compounds42
Synthesis of Functional Chemicals from Lignin‐derived Monomers by Selective Organic Transformations42
Recent Advances in Reactions Using Enaminone in Water or Aqueous Medium41
Catalytic Asymmetric Aza‐Diels‐Alder Reaction: Pivotal Milestones and Recent Applications to Synthesis of Nitrogen‐Containing Heterocycles40
Iron‐Mediated Cyanoalkylsulfonylation/Arylation of Active Alkenes with Cycloketone Oxime Derivatives via Sulfur Dioxide Insertion40
Fluorinated Aryl Boronates as Building Blocks in Organic Synthesis39
Advances in C(sp2)−H/C(sp2)−H Oxidative Coupling of (Hetero)arenes Using 3d Transition Metal Catalysts39
Scalable Electrochemical Transition‐Metal‐Free Dehydrogenative Cross‐Coupling Amination Enabled Alkaloid Clausines Synthesis39
Catalyst‐Free Decarbonylative Trifluoromethylthiolation Enabled by Electron Donor‐Acceptor Complex Photoactivation38
Advances in Asymmetric Amino Acid Synthesis Enabled by Radical Chemistry38
Recent Advances in Catalytic Asymmetric Aza‐Michael Addition Triggered Cascade Reactions38
Recent Trends and Prospects in Homogeneous Manganese‐Catalysed Epoxidation38
Recent Developments in Z‐Selective Olefin Metathesis Reactions by Molybdenum, Tungsten, Ruthenium, and Vanadium Catalysts37
Synthesis of Unnatural α‐Amino Acid Derivatives via Light‐Mediated Radical Decarboxylative Processes37
NAD(P)H‐Dependent Enzymes for Reductive Amination: Active Site Description and Carbonyl‐Containing Compound Spectrum37
Recent Advances in Asymmetric Organomulticatalysis37
Organic Azides: Versatile Synthons in Transition Metal‐Catalyzed C(sp2)−H Amination/Annulation for N‐Heterocycle Synthesis37
Recent Progress on Reductive Coupling of Nitroarenes by Using Organosilanes as Convenient Reductants37
C(sp3)−C(sp3) Cross‐Coupling of Alkyl Bromides and Ethers Mediated by Metal and Visible Light Photoredox Catalysis37
Cu‐Catalysed Three‐Component Reaction of Aryldiazonium Salts with Fluorinated Diazo Reagents and Nitriles: Access to Difluoro‐ and Trifluoromethylated N1‐Aryl‐1,2,4‐triazoles37
Phosphorus Compounds as Precursors and Catalysts for Radical C−C Bond‐Forming Reactions36
Recent Advances in Organocatalytic Enantioselective Synthesis of Axially Chiral Allenes36
The Construction of Nitrogen‐Containing Heterocycles from Alkynyl Imines36
Transition Metal‐Free Synthesis of Sulfonyl‐ and Bromo‐Substituted Indolo[2,1‐α]isoquinoline Derivatives through Electrochemical Radical Cascade Cyclization36
Recent Developments in the Polychloroalkylation by Use of Simple Alkyl Chlorides35
Chiral Phosphoric Acid Catalyzed (4+1) Annulation of 3‐Diazooxindoles/4‐Diazooxisoquinolines with para‐Quinone Methides to Access Chiral Spiro[dihydrobenzofuran‐2,3′‐oxindoles/2,4′‐oxisoquinoli35
Recent Advances in Catalytic Enantioselective Synthesis of Fluorinated α‐ and β‐Amino Acids35
Visible‐Light‐Induced Radical Defluoroborylation of Trifluoromethyl Alkenes: An Access to gem‐Difluoroallylboranes35
Recent Advances in Polychloromethylation Reactions35
Recent Advances in Phosphonium Salt Catalysis35
Zinc‐Catalyzed N‐Alkylation of Aromatic Amines with Alcohols: A Ligand‐Free Approach35
Visible Light‐Induced Synthesis of Functionalized Coumarins34
Transition‐Metal‐Free C(sp2)‐H Dithiocarbamation and Chromone Annulation Cascade for 3‐Dithiocarbamyl Chromone Synthesis34
Recent Advances in Transition‐Metal‐Catalyzed Reactions of N‐Tosylhydrazones33
Advances in Oxosulfonylation Reaction33
β‐Trifluoromethyl α,β‐unsaturated Ketones: Efficient Building Blocks for Diverse Trifluoromethylated Molecules33
A Cascade Rh(III)‐catalyzed C−H Activation/Chemodivergent Annulation of N‐carbamoylindoles with Sulfoxonium Ylides for the Synthesis of Dihydropyrimidoindolone and Tricyclic [1,3]Oxazino[3,4‐32
Site‐Selective C(sp3)−H and C(sp2)−H Functionalization of Amines Using a Directing‐Group‐Guided Strategy32
Visible‐Light‐Induced Manganese‐Catalyzed Reactions: Present Approach and Future Prospects32
Bench‐Stable Manganese NHC Complexes for the Selective Reduction of Esters to Alcohols with Silanes31
Synthesis of Aliphatic Amides through a Photoredox Catalyzed Radical Carbonylation Involving Organosilicates as Alkyl Radical Precursors31
Generalized Chemoselective Transfer Hydrogenation/Hydrodeuteration31
Gold(I) Complexes with Eight‐Membered NHC Ligands: Synthesis, Structures and Catalytic Activity31
Trifluoromethylation/Difluoromethylation‐Initiated Radical Cyclization of o‐Alkenyl Aromatic Isocyanides for Direct Construction of 4‐Cyano‐2‐Trifluoromethyl/Difluoromethyl‐Containing Quinoline31
Uncovering the Potential of Boronic Acid and Derivatives as Radical Source in Photo(electro)chemical Reactions31
Rhodium‐Catalyzed Cascade Reactions of Indoles with 4‐Hydroxy‐2‐Alkynoates for the Synthesis of Indole‐Fused Polyheterocycles31
Organocatalytic Enantioselective Friedel‐Crafts Alkylation Reactions of Pyrroles31
Visible Light‐Promoted Selenylation/Cyclization of Enaminones toward the Formation of 3‐Selanyl‐4H‐Chromen‐4‐Ones31
Synthesis of Substituted 1‐Hydroxy‐2‐Naphthaldehydes by Rhodium‐Catalyzed C−H Bond Activation and Vinylene Transfer of Enaminones with Vinylene Carbonate31
Advances in Electrochemical Hydrogenation Since 201031
Combined Photoredox and Carbene Catalysis for the Synthesis of γ‐Aryloxy Ketones30
Methods of Nitriles Synthesis from Amines through Oxidative Dehydrogenation30
Recent Advances in Transition‐Metal‐Catalyzed Oxidative Annulations to Benzazepines and Benzodiazepines30
Recent Progress in Palladium‐Catalyzed Radical Reactions30
State of the Art in Crystallization‐Induced Diastereomer Transformations30
Radical Cascade Reactions of β,γ‐Unsaturated Hydrazones/Oximes30
Base Metal‐Catalyzed C‐Methylation Reactions Using Methanol30
Metagenomic Mining for Amine Dehydrogenase Discovery30
An Easy, General and Practical Method for the Construction of Alkyl Sulfonyl Fluorides29
Recent Advancements on Transition‐Metal‐Catalyzed, Chelation‐Induced ortho‐Hydroxylation of Arenes29
Radical Polychloromethylation/Cyclization of Unactivated Alkenes: Access to Polychloromethyl‐Substituted Ring‐Fused Quinazolinones29
Selective Synthesis of 3‐(α‐Fluorovinyl)indoles and 3‐Acylindoles via the Cascade Reactions of 1‐Phenylpyrazolidinones with α,α‐Difluoromethylene Alkynes29
Photocatalytical and Photochemical Generation of Imidoyl Radicals: Synthetic Applications29
Borata‐Alkene Species as Nucleophilic Reservoir28
A Convenient FeCl3‐Mediated Synthesis of 5‐Trifluoromethyl‐1,2,4‐triazoles from Trifluoroacetimidoyl Chlorides and Hydrazides28
Reactions of Organophosphorus Compounds with Arynes: Reactivity and Mechanism28
Synthesis and Applications of Organic Selenols28
Recent Trends in the Synthesis and Mechanistic Implications of Phenanthridines28
[Bis(trifluoroacetoxy)iodo]benzene Mediated C‐3 Selenylation of Pyrido[1,2‐a]Pyrimidin‐4‐Ones Under Ambient Conditions28
Selective Aerobic Oxidation of 5‐(Hydroxymethyl)furfural over Heterogeneous Silver‐Gold Nanoparticle Catalysts28
Fast and Efficient Nickel(II)‐catalysed Transfer Hydrogenation of Quinolines with Ammonia Borane27
Chiral Iron Complexes in Asymmetric Organic Transformations27
Catalytic Photoredox Allylation of Aldehydes Promoted by a Cobalt Complex27
Aromatic C−H Hydroxylation Reactions with Hydrogen Peroxide Catalyzed by Bulky Manganese Complexes27
Synthesis and Reactivity of Allenylboron Compounds27
Tandem Annulations of Propargylic Alcohols to Indole Derivatives27
Post‐Pictet‐Spengler Cyclization (PPSC): A Strategy to Synthesize Polycyclic β‐Carboline‐Derived Natural Products and Biologically Active N‐Heterocycles27
Metal‐Free, PhI(OAc)2‐Promoted Oxidative C(sp2)−H Difunctionalization: Synthesis of Thioaminated Naphthoquinones26
Electrochemical Nonacidic N‐Nitrosation/N‐Nitration of Secondary Amines through a Biradical Coupling Reaction26
Transition‐Metal‐Catalyzed Selective Alkynylation of C−H Bonds26
Dimsyl Anion Enables Visible‐Light‐Promoted Charge Transfer in Cross‐Coupling Reactions of Aryl Halides26
Selective Synthesis of Fused Tricyclic [1,3]oxazino[3,4‐a]indolone and Dihydropyrimido [1,6‐a]indolone via Rh(III)‐catalyzed [3+3] or [4+2] C−H Annulation26
Stereoselective Preparation of C‐Aryl Glycosides via Visible‐Light‐Induced Nickel‐Catalyzed Reductive Cross‐Coupling of Glycosyl Chlorides and Aryl Bromides26
Phosphine‐Free Manganese(II)‐Catalyst Enables Acceptorless Dehydrogenative Coupling of Alcohols with Indoles26
Supported Bifunctional Chiral Thioureas as Catalysts in the Synthesis of 3‐Amino‐2‐Oxindoles through Enantioselective aza‐Friedel‐Crafts Reaction: Application in Continuous Flow Processes26
Transition‐metal‐free Photo‐induced Cascade Sulfonylation/Addition/Cyclization of 3‐Arylethynyl‐[1,1′‐biphenyl]‐2‐carbonitriles with Aryldiazonium Tetrafluoroborates via the Insertion of Sulfur Dioxid26
Visible‐Light‐Mediated Nitrogen‐Centered Radical Strategy: Preparation of 3‐Acylated Spiro[4,5]trienones26
Radical‐Mediated Non‐Dearomative Strategies in Construction of Spiro Compounds26
Visible‐Light‐Induced Radical Cascade Cyclizations of 1,7‐Enynes with Sulfinic Acids: Direct Access to Sulfonated Chromanes and Sulfonated Tetrahydroquinolines under Metal‐Free Conditions26
Synthesis of Indolo[2,1‐a]isoquinolin‐6(5H)‐Ones Derivatives via Fe(OTf)3‐Promoted Tandem Selenylation/Cyclization of 2‐Arylindoles26
Recent Advances in Iron‐Catalyzed Chemical and Enzymatic Carbene‐Transfer Reactions26
Direct Dehydrogenation for the Synthesis of α,β‐Unsaturated Carbonyl Compounds26
Recent Advances in the Synthesis of Spiro‐β‐Lactams and Spiro‐δ‐Lactams26
Iodine‐Catalyzed Double [4+2] Oxidative Annulations for the Synthesis of Bipyrazines from Ketones and Diamines by a Domino Strategy26
A Metal‐Free Direct Arene C−H Amination25
Photocatalytic Deoxygenative Carboimination towards Functionalized Pyrrolines by Using Unstrained γ,δ‐Unsaturated Oximes25
Copper‐Catalyzed Enantioselective Cyano(Fluoro)Alkylation of Alkenes25
Direct Asymmetric Arylation of Imines25
E/Z Photoisomerization of Olefins as an Emergent Strategy for the Control of Stereodivergence in Catalysis25
Metal‐Free Synthesis of (E)‐Vinyl Sulfones via An Insertion of Sulfur Dioxide/1,5‐Hydrogen Atom Transfer Sequence25
Visible‐Light‐Promoted Switchable Synthesis of C‐3‐Functionalized Quinoxalin‐2(1H)‐ones25
A Synthetic Protocol for the Construction of Chroman‐Spiroquinazolin(thi)one Framework via a Metal‐Free, Three‐Component, Domino, Double Annulations25
Synthesis of Pyridothiazepines via a 1,5‐Dipolar Cycloaddition Reaction between Pyridinium 1,4‐Zwitterionic Thiolates and Activated Allenes24
Rhodium(III)‐Catalyzed Annulation of 2‐Arylimidazo[1,2‐a]pyridines with Maleimides: Synthesis of 1H‐Benzo[e]pyrido[1′,2′:1,2]imidazo[4,5‐g]isoindole‐1,3(2H)‐Diones a24
Recent Advances in the Synthesis and Ring‐Opening Transformations of 2‐Oxazolidinones24
Selectivity in the Elaboration of Bicyclic Borazarenes24
Regioselective Decarboxylative Cycloaddition Route to Fully Substituted 3‐CF3‐Pyrazoles from Nitrilimines and Isoxazolidinediones24
Bifunctinoal Phosphonium Salt‐Catalyzed Asymmetric Cyclodearomatization of 2‐Nitroindoles and 2‐Nitrobenzofurans for Constructing CF3‐Containing Spiro‐Polycycles24
Recent Advances of Applying Boron‐Reagents in Asymmetric Total Syntheses of Natural Products and Bio‐Active Molecules24
Recent Advances in the Direct Functionalization of Isoindolinones for the Synthesis of 3,3‐Disubstituted Isoindolinones24
A Copper‐Catalyzed Sonogashira Coupling Reaction of Diverse Activated Alkyl Halides with Terminal Alkynes Under Ambient Conditions24
Recent Advances in Metal‐Catalyzed Decarboxylative Reactions of Vinyl Benzoxazinanones24
Kinetic Resolution of 2‐N‐Acylamido Tertiary Allylic Alcohols: Asymmetric Synthesis of Oxazolines24
Ruthenium‐Catalyzed Vinylene Carbonate Annulation by C−H/N−H Functionalizations: Step‐Economical Access to Indoles24
Electrosynthesis of CF3‐Substituted Polycyclic Quinazolinones via Cascade Trifluoromethylation/Cyclization of Unactivated Alkene24
Recent Developments in Remote Meta‐C−H Bond Functionalizations24
Still–Gennari Olefination and its Applications in Organic Synthesis23
One‐Pot Tandem Protocol for the Synthesis of 1,3‐Bis(β‐aminoacrylate)‐Substituted 2‐Mercaptoimidazole Scaffolds23
Chiral Binaphthyl‐Based Iodonium Salt (Hypervalent Iodine(III)) as Hydrogen‐ and Halogen‐Bonding Bifunctional Catalyst: Insight into Abnormal Counteranion Effect and Asymmetric Synthesis of N,<23
Recent Trends in the Iron‐Catalyzed Cyanation Reactions23
Halogen Bond‐Catalyzed Povarov Reactions23
Electrochemical Synthesis of O‐Phthalimide Oximes from α‐Azido Styrenes via Radical Sequence: Generation, Addition and Recombination of Imide‐N‐Oxyl and Iminyl Radicals wit23
Regioselective and Chemodivergent Synthesis of Azulenolactones and Azulenolactams from Rhodium(III)‐Catalyzed Reactions of Azulenecarboxamides with Sulfoxonium Ylides23
HFIP‐Mediated Decarboxylative [4+3]‐Annulation of Azaoxyallyl Cations with Isatoic Anhydride23
Nickel‐Catalyzed Selective Synthesis of α‐Alkylated Ketones via Dehydrogenative Cross‐Coupling of Primary and Secondary Alcohols23
Palladium‐Catalyzed Carbonylative Synthesis of 2‐(Trifluoromethyl)quinazolin‐4(3H)‐ones from Trifluoroacetimidoyl Chlorides and Nitro Compounds23
Recent Advances in the Synthesis of Imidazolines (2009–2020)23
Photochemical O−H Functionalization Reactions of Cyclic Diazoamides23
Transition Metal‐Free, Free‐Radical Sulfenylation of the α‐C(sp3)−H Bond in Arylacetamides and Its Application Toward 2‐Thiomethyl Benzoxazoles Synthesis23
Synthesis of 1,2,3,4‐Tetrahydrobenzofuro[3,2‐d]pyrimidines via [4+2] Annulation Reaction of 1,3,5‐Triazinanes and Aurone‐Derived α,β‐Unsaturated Imines23
Catalytic Asymmetric Halohydroxylation of α,β‐Unsaturated Ketones with Water as the Nucleophile22
Catalyst‐Free and Visible Light Promoted Aminofluoroalkylation of Unactivated Alkenes: An Access to Fluorinated Aziridines22
The Dichotomy of Gold‐catalyzed Interplay between Cyanamides and Ynamides: Controllable Switch from [2+2+2] to [4+2] Cycloaddition22
Photo‐Triggered Self‐Induced Homolytic Dechlorinative Sulfonylation/Cyclization of Unactivated Alkenes: Synthesis of Quinazolinones Containing a Sulfonyl Group22
Diastereodivergent Formal 1,3‐Dipolar Cycloaddition of 5‐alkenyl thiazolones to Access Stereochemically Diverse Pyrrolidinyl Spirooxindoles22
Iron‐Catalyzed Silylation and Spirocyclization of Biaryl‐Ynones: A Radical Cascade Process toward Silylated Spiro[5.5]trienones22
Generation of Alkyl Radicals from Thiols via Zinc Thiolates: Application for the Synthesis of gem‐Difluorostyrenes22
Hydrosilylation of Aldehydes and Ketones Catalysed by Bis(phosphinite) Pincer Platinum Hydride Complexes22
Glycosyltransferase Co‐Immobilization for Natural Product Glycosylation: Cascade Biosynthesis of the C‐Glucoside Nothofagin with Efficient Reuse of Enzymes22
Metal‐Free Organoselenium‐Enabled Radical Relay Azidation‐Carbocyclization22
Tailoring the Reactivity of the Langlois Reagent and Styrenes with Cyanoarenes Organophotocatalysts under Visible‐Light22
Molecular Oxygen‐Mediated Radical Cyclization of Acrylamides with Boronic Acids22
Enantioselective Synthesis of Functionalized Diazaspirocycles from 4‐Benzylideneisoxazol‐5(4H)‐one Derivatives and Isocyanoacetate Esters22
Visible‐Light Induced C(sp3)−H Functionalization for the Formation of C−N Bonds under Metal Catalyst‐Free Conditions22
Electrochemically Mediated Direct C(sp3)−H Sulfonylation of Xanthene Derivatives22
Visible‐Light‐Induced Three‐Component Intermolecular Trifluoromethyl‐Alkenylation Reactions of Unactivated Alkenes22
Synthesis and Applications of β‐Aminoalkylboronic Acid Derivatives22
Preparation of Oxindoles via Visible‐Light‐Induced Amination/Cyclization of Arylacrylamides with Alkyl Amines22
Benzyl Palladium Intermediates: Unique and Versatile Reactive Intermediates for Aromatic Functionalization22
Halohydrin Dehalogenases and Their Potential in Industrial Application – A Viewpoint of Enzyme Reaction Engineering21
Asymmetric Synthesis of Chiral Amino Carboxylic‐Phosphonic Acid Derivatives21
Visible‐Light‐Mediated S−H Bond Insertion Reactions of Diazoalkanes with Cysteine Residues in Batch and Flow21
Nickel‐Catalyzed Reductive Acylation of Carboxylic Acids with Alkyl Halides and N‐Hydroxyphthalimide Esters Enabled by Electrochemical Process21
Asymmetric Fluorination Reactions promoted by Chiral Hydrogen Bonding‐based Organocatalysts21
A Metal‐Free Synthesis of N‐Aryl Oxazolidin‐2‐Ones by the One‐Pot Reaction of Carbon Dioxide with N‐Aryl Aziridines21
Copper‐Catalyzed Selective N‐Arylation of Oxadiazolones by Diaryliodonium Salts21
Organocatalytic Enantioselective [4+3]‐Cycloadditions of Azaoxyallyl Cations with 2‐Aminophenyl Enones21
Catalyst‐ and Additive‐Free Decarboxylative C‐4 Phosphorylation of Coumarin‐3‐Carboxylic Acids at Ambient Conditions21
Visible‐Light‐Induced Controlled Oxidation ofN‐Substituted 1,2,3,4‐Tetrahydroisoquinolines for the Synthesis of 3,4‐Dihydroisoquinolin‐1(2H)‐ones and Isoquinolin‐1(2H)‐ones21
Photoinduced Ligand‐to‐Metal Charge Transfer of Carboxylates: Decarboxylative Functionalizations, Lactonizations, and Rearrangements21
Catalytic Aerobic Dehydrogenatin of N‐Heterocycles by N‐Hydoxyphthalimide21
Transition‐Metal‐Catalyzed, Chelation‐Assisted C−H Alkenylation and Allylation of Organic Molecules with Unactivated Alkenes21
Iridium(I) Complexes with Anionic N‐Heterocyclic Carbene Ligands as Catalysts for H/D Exchange in Nonpolar Media21
Synthesis of Hydrophilic Phosphorus Ligands and Their Application in Aqueous‐Phase Metal‐Catalyzed Reactions21
Synthetic Chemistry with Lewis Acidity‐Diminished B(aam) and B(dan) Groups: Borylation Reactions and Direct Cross‐Couplings21
Asymmetric Oxidative Mannich Reactions20
Hydroboration of Enynes and Mechanistic Insights20
Asymmetric Construction of Bispiro‐Cyclopropane‐Pyrazolones via a [2+1] Cyclization Reaction by Dipeptide‐Based Phosphonium Salt Catalysis20
Graphitic Carbon Nitride Polymer as a Recyclable Photoredox Catalyst for Decarboxylative Alkynylation of Carboxylic Acids20
Transition Metal‐Free Aroylation of Diarylmethanes with N‐Bn‐N‐Boc Arylamides and N‐Acylpyrroles20
Asymmetric Nazarov Cyclizations of Unactivated Dienones by Hydrogen‐Bond‐Donor/Lewis Acid Co–Catalyzed, Enantioselective Proton‐Transfer20
Copper(II)‐Mediated Intermolecular Radical [3+2]‐Annulation of N,N‐Dimethyl Enaminones: Direct Access to 5‐Acyl‐3‐Furancarboxaldehydes20
Catalytic Asymmetric Synthesis of Isochroman Derivatives20
Alkene, Bromide, and ROH – How To Achieve Selectivity? Electrochemical Synthesis of Bromohydrins and Their Ethers20
Minisci‐Type Alkylation of N‐Heteroarenes by N‐(Acyloxy)phthalimide Esters Mediated by a Hantzsch Ester And Blue LED Light20
Zwitterion‐Initiated Hydroboration of Alkynes and Styrene20
Deconjugated‐Ketone‐Derived Dienolates in Remote, Stereocontrolled, Aromative aza‐Diels‐Alder Cycloaddition20
Visible‐Light‐Mediated C‐2 Functionalization and Deoxygenative Strategies in Heterocyclic N‐Oxides20
Photoredox Fluoroalkylation of Hydrazones in Neutral and Reductive Modes20
Metal‐Free Multi‐Component Sulfur Dioxide Insertion Reaction Leading to Quinoxalin‐2‐One‐Containing Vinyl Sulfones under Visible‐Light Photoredox Catalysis20
A Metal‐ and Azide‐free Oxidative Coupling Reaction for the Synthesis of [1,2,3]Triazolo[1,5‐a]quinolines and their Application to Construct C−C and C‐P Bonds, 2‐Cyclopropylquinolines and Imidazo[1,5‐19
Well‐Defined Ni−SNS Complex Catalysed Borrowing Hydrogenative α‐Alkylation of Ketones and Dehydrogenative Synthesis of Quinolines19
Ag‐Catalyzed Cyclization of Arylboronic Acids with Elemental Selenium for the Synthesis of Selenaheterocycles19
Palladium‐Catalyzed Regioselective Domino Spirocyclization of Carbamoyl Chlorides with Alkynes and Benzynes19
Manganese(I)‐Catalyzed Site‐Selective C6‐Alkenylation of 2‐Pyridones Using Alkynes via C−H Activation19
Iridium‐Catalysed Reductive Deoxygenation of Ketones with Formic Acid as Traceless Hydride Donor19
0.065881967544556