Advanced Synthesis & Catalysis

Article	Citations
N‐Containing Carbon Materials in Metal‐Free and Non‐Noble Metal Liquid Phase Heterogenous Catalysis	141
Hypervalent Iodine‐Mediated Regioselective Dearomatization of Non‐Activated Arenes	100
Asymmetric Synthesis of Tricycle‐Fused Dispirooxindoles via Organocatalyzed Three‐Component Cascade Reactions of 2‐Pyrones and Trifluoroethylisatin Ketimines	100
Cu(III) Trifluoromethyl Complexes with 1,3‐Diketonate Ligands and Their Versatile Reactivity in C−H Trifluoromethylation	85
Site‐Selective Direct Intermolecular C(sp3)−H Alkylation of Saccharides and Switching of Reaction Sites by Changing Photocatalysts	80
Gold‐Catalyzed Annulation Between 1‐[2‐(Dimethoxymethyl)phenyl]prop‐2‐yn‐1‐yl Acetates and α‐Diazo Esters or Anilines to Form Substituted Naphthoates and Indeno[1,2‐b]quinoline, Respectively	75
Synthesis of 3,4‐Dihydroquinazolinones via Base‐Promoted Formal [4 + 2] Cycloadditions	73
Ruthenium (II)‐Catalysed Regioselective C6 Alkylation of Indoles with Maleimides	73
Copper‐Catalyzed Acylhalogenation of 3‐Methylanthranils with Acid Halides: Synthesis of N‐(2‐(2‐Haloyl)phenyl)amides	72
Witnessing the Birth of Directed Evolution of Stereoselective Enzymes as Catalysts in Organic Chemistry	59
The Novel Strategies for the Construction of Homoallylic Alcohols via Photoredox Catalysis	57
First Bromide‐Catalyzed Selenylation of 2‐Alkyn‐1‐One O‐Methyloximes Enabled the Synthesis of 4‐Selenylated Isoxazoles	54
Martin Silicates as Partners in Photoredox/Ni Dual Catalysis for the Installation of CH3, CH2D, CD2H, CD3 and 13CH3 Groups onto (Heter	48
Synthesis of Furfural Sulfides and 4‐Alkylthiopyridines via Heterocyclization of α‐Acyl Ketene Dithioacetals	47
A Combined Halogen‐ and Chalcogen‐Bonding Organocatalyst	47
Cooperative Photocatalysis of 9,10‐Phenanthrenequinone and Sn(OTf)2 for Direct Mannich Reaction of Ethers via Hydrogen Atom Transfer Pathway	43
Regio‐ and Stereospecific Desulfinylative Chlorination of Spiroaziridine Oxindoles at Spiro‐Center for Formal [3+2]‐Cycloaddition with CS2: Sequential One‐Pot Synthesis of (−)‐Spirobrassini	43
A Gold(I)‐Catalyzed Cyclization/Semipinacol Rearrangement Cascade of 1,6‐Enynes to Access Spiro[4.5]decanes and 7‐Azaspiro[4.5]decanes	42
	41
Selective Formation of 2,3,5‐Trisubstituted Furans from 1,3‐Dicarbonyls and Hydroxyketones	41
Tandem Asymmetric Cycloaromatization/ Intramolecular Pictet‐Spengler‐Type Reaction. An Entry to Polycyclic Pyrroles	40
Synthesis of 2‐Aminopyridines via Cobalt‐Catalyzed Cycloaddition of Diynes with N‐Substituted and N‐Unsubstituted Cyanamides	38
Nitrosonium Ion Catalyzed Oxidative Bromination of Arenes	38
Constructing 5‐Methyl‐2,4‐diaryl‐1H‐imidazoles Using Calcium Carbide as Alkyne Source via A3‐Coupling Cyclization	38
Copper‐Catalyzed Oxidative 1,2‐Alkylarylation of Styrenes with Unactivated C(sp3)‐H Alkanes and Electron‐Rich Aromatics via C(sp3)‐H/C(sp2)‐H Func	38

Hypervalent Halogen Compounds in Electrochemical Reactions: Advantages and Prospects	37
Synthesis of Chiral Nine‐Membered N‐Heterocycles through Silver(I)‐Promoted Cycloaddition and Rearrangement from N‐Vinyl‐α,β‐Unsaturated Nitrones with Chiral 3‐Propioloyloxazolidin‐2‐Ones	36
Enantioselective Synthesis of Five to Eight‐Membered P‐Stereogenic Benzo‐Fused Heterocycles via Copper‐Catalyzed Dynamic Kinetic Resolution	36
Direct Asymmetric Addition of Heteroatom Nucleophiles to Imines	36
Synthesis of 2‐Amino‐3‐arylindoles and their Fused Analogues via Intramolecular C‐Arylation	36
Regio‐ and Stereoselective, Intramolecular [2+2] Cycloaddition of Allenes, Promoted by Visible Light Photocatalysis	36
Enzymatic Dimerization of Fungal Natural Products Through Intermolecular Disulfide Bridges	35
Formal Insertion of a Metal Carbene Complex into a σ‐Carbon‐Carbon Bond. Gold‐Catalyzed Synthesis of 3H‐Indoles	35
Front Cover Picture: Catalytic Asymmetric Arylations of Ketimines (Adv. Synth. Catal. 12/2024)	35
Enantioselective Syntheses of Multiply Functionalized Six‐Membered Carbocycles from Nitroalkenes and γ,δ‐Unsaturated ß‐Ketoesters using Chiral Catalysts Derived from Cobalt(III) and 1,2‐Diphenylethyle	34
Cover Picture: Bench‐Stable Electrophilic Reagents for the Direct Di‐ and Trifluoroethylthiolation of Indoles (Adv. Synth. Catal. 20/2023)	34
Chiral Aminomethylbinaphthol‐Catalyzed Diastereo‐ and Enantioselective Epoxidation of Trisubstituted Acrylonitriles	33
Nickel‐Catalyzed Hydroborylative Polycyclization of Allenynes: an Atom‐Economical and Diastereoselective Synthesis of Bicyclic 5–5 Fused Rings.	33
Solvent‐ and Temperature‐Switched Chemoselectivity: Controlled Synthesis of Diverse Pyrazolo[5,1‐a]isoquinolines	33
Front Cover Picture: Filling the Gaps in the Challenging Asymmetric Hydrogenation of Exocyclic Benzofused Alkenes with Ir−P,N Catalysts (Adv. Synth. Catal. 2/2023)	33
A Lewis Base Hydrogen Bond Donor (LB/HBD) Organocatalytic Approach to Dithiabridged Triarylamine Hetero[4]helicenes	32
Unusual Ring Opening of Bicyclic Terpenes During Pd‐Catalyzed Coupling with Aromatic Halides	32
Electrochemical Oxidative C−C Bond Functionalization of Methylenecyclopropanes with Diselenides/Ditellurides Leading to 2‐Substituted‐3,4‐Dihydronaphthalenes	31
Recent Advances in Transition Metal Catalysed Dearomatization Toward the Synthesis of Complex Cyclic Compounds	31
Electrochemical Stereoselective Synthesis of (Z)‐Allyl Aryl Selenides and Sulfides from Baylis‐Hillman Acetates	31
Imidazolium‐Dithiocarboxylate Zwitterions Catalysed Ring‐Opening Additions of Cyclopropenones	31
Divergent Reactivity of E/Z‐Azobenzene‐Based Phosphine‐Gold Catalysts: Toward an ON‐ON Catalytic Photoswitch Process	31
Tandem Enantioselective Cycloaromatization/Intramolecular Friedel–Crafts Desymmetrization of Cyclohexadienones	31
Magnesium and Calcium Bisguanidinates: Catalytic Activity in the Hydroboration of Unsaturated Molecules	31
Cobalt‐Catalyzed Selective Transformation of Levulinic Acid and Amines into Pyrrolidines and Pyrrolidinones using Hydrogen	30
	30
tert‐Butyl Nitrite Promoted Visible‐Light‐Induced Steric‐Hindrance‐Regulated Concurrent Cross‐Coupling and Regioselective Nitration of 3‐Alkylidene‐2‐oxindoles	30
Visible‐light‐induced and EDA Complex‐initiated Hydroxyselenization of α‐CF3 Alkenes: Access to α‐trifluoromethyl‐β‐selanyl tertiary Alcohols	30
Access to 2‐Sulfonyl‐4‐arylphenols and 2,6‐Bis‐sulfonyl 5‐Aryl‐4‐arylidene‐2‐cyclohexenones via Metal Triflates‐Catalyzed Domino Cyclocondensation of 1,3‐Bis‐sulfonylacetones and 3‐Arylacroleins	30
Palladium‐Catalyzed Reaction of 2,3‐Allenols with Amines: Synthesis of [3]Dendralenes and 1,3‐Dienes Containing Allylic Amino and Hydroxy Groups	30
Front Cover Picture: Chemo‐ and Regioselective Construction of Functionalized Isocoumarin, Flavone, and Isoquinolinedione via a One‐pot Reaction of o‐Quinol Acetate and Soft Nucleophiles	29
Asymmetric Tandem Conjugate Addition and Reaction with Carbocations on Unsaturated Heterocycles	29
Aryne‐Based Synthesis of Cyclobutadiene‐Containing Oligoacenes and Related Extended Biphenylene Derivatives	29
Recent Advances in Organocatalytic Enantioselective Synthesis of Axially Chiral Allenes	28
Photoinduced Ligated Boryl Radical‐Mediated Functionalization of Organic Halides	28
One Pot Synthesis of 1,2‐Disubstituted Ethanones by Base‐Mediated Reductive Homocoupling of Aldehydes	28
Flexible Construction of Functionalized‐Pyrroles under Palladium or Copper Catalysis in the Presence of BF3 ⋅ Et2O	28
Continuous Flow Technology Enabling Photochemistry	28
Gold(I)‐Catalyzed Cascade Cyclization of Nitrogen or Oxygen Containing Nucleophile Tethered‐Vinylidenecyclopropanes to Pyrrole, Furan, Pyrrolidine and Piperidine Skeletons	28
Copper‐Catalyzed Cross Coupling Reaction of Alkyl Bromides with (DMPU)2Zn(Rf)2 Reagent: A Method for the Synthesis of Perfluoroalkylated Compounds	28
Catalyst‐Free, One‐Pot, Three‐Component Synthesis of 3‐Arylsulfonylated Thioflavones	28
SuFEx Reactions When Shaken Not Stirred	28
Indazolones Directed Rh(III)‐Catalyzed C−H Amidation of Arenes	27
Special Issue Dedicated to Miquel A. Pericàs	27
Diarylprolinol with Trifluoromethyl Substituents and Diphenylprolinol‐Derived Perfluoroalkanesulfonamide as Organocatalysts in the Cross‐Aldol Reaction of Aldehydes	27
Iron‐Catalyzed Oxyphosphorylation of Styrenes to Access β‐Ketophosphonates and α, β‐Unsaturated Ketones	27
Phosphine‐Catalyzed (4+2) Annulation of Alkenes with Acidic Hydrogen‐Tethered Allylic Carbonates	27
N−H Trifluoroethylation of Indoles and other Aromatic N‐Heterocycles with CF3CHCl2 by Copper‐Mediated Cross‐Coupling Reaction	27
Total Synthesis of the Myrioneuron Alkaloid (−)‐Schoberine B and Its Enantiomer (+)‐Schoberine B	27
Construction of α‐Pyrones and Enamine Derivatives via Divergent Transformations of β‐Aminoacrylates	26

An Organocatalytic Route to endo‐Vinylene Carbonates from Carbon Dioxide‐Based exo‐Vinylene Carbonates	26
Cobalt(III)‐Catalyzed Aerobic Diamination of α‐Alkyl Styrenes with Anilines	26
Gold‐Catalyzed Redox‐Neutral Reaction of Nitriles with Quinoline N‐Oxides	26
Palladium Catalysis: Dependence of the Efficiency of C−C Bond Formation on Carboxylate Ligand and Alkali Metal Carboxylate or Carboxylic Acid Additive. Part C: The Domino Diarylation and Annelation Re	26
Nickel/Copper Co‐catalyzed Enantioselective Reductive Coupling of Oxabenzonorbornadienes with Vinyl Bromides	26
	25
Copper‐Catalyzed Domino Synthesis of Spiropyrazoline Oxindoles via Condensation of Indolin‐2‐One and Phenylhydrazine Derivatives	25
Visible‐Light Induced Ag‐Palladacycle‐Complex‐Mediated Regioselective C−H Arylation	25
Functionalized Alkylidenecyclobutanes from a Cyclopent‐2‐enone Substrate via a Tandem Photochemical Transformation and an Allylic Substitution Protocol	25
Renewable Platform Chemicals: The Bulk Chemicals of the Future	25
A Redox‐Neutral Organophotocatalytic Cascade: Difluoromethylation and Radical Truce–Smiles‐Driven C(sp3)–H Functionalization to Access Benzothiazine Dioxides and Oxindoles	25
Palladium‐Catalyzed Denitrative Decarboxylation of Nitroarenes with Alkynyl Carboxylic Acids	25
A Mild Metal‐Free Approach for the Direct Synthesis of Carbamoyl Azides from Carboxylic Acid Redox Active Esters	25
Asymmetric Synthesis of Highly Substituted Spiro[2H‐pyrrole‐2,3‐Succinimide] Derivatives by Copper‐Catalyzed Post‐Ugi Reactions	25
Stereoselective Synthesis of Aliphatic α‐Amino Acids by Chemo‐Enzymatic Hydroamination‐Hydrodesulfurisation	25
Front Cover Picture: Redox‐Neutral Vicarious‐Type Nucleophilic Amination of Heterocyclic N‐Oxides with Organic Azides (Adv. Synth. Catal. 19/2024)	24
An Umpolung Route to Amides from α‐Aminonitriles under Metal‐Free Conditions	24
Photoinduced Annulation of N‐Phenylbenzamides for the Synthesis of Phenanthridin‐6(5H)‐Ones	24
Ring‐Opening Amino Esterification of Cyclic Ketones to Access Distal Amino Acid Derivatives	24
N,N’‐Difluoro‐2,2’‐bipyridinium Bis(tetrafluoroborate): a New Terminal Oxidant for Iodoarene‐catalyzed Fluorination Reactions	24
DABCO‐Promoted Selective Photochemical C−N Coupling: Access to Unsymmetrical Azahelicenes	24
Stereoselective Synthesis of Contiguous Cyclopropylaziridines: Enabling the Construction of Versatile Chiral Molecules Including γ‐Lactams via Ring‐Opening Reactions	24
2‐Aminoindoles and 2‐Iminoindolines as Viable Precursors of Indole‐Fused Nitrogenated Polyheterocycles	24
K2S2O8‐Mediated Access to Alkylsulfonated Spiro[4,5] Trienones from N‐Arylpropiolamides with the Insertion of Sulfur Dioxide	24
Interrupted CuAAC‐Thiolation for the Construction of 1,2,3‐Triazole‐Fused Eight‐Membered Heterocycles from O‐/N‐Propargyl derived Benzyl Thiosulfonates with Organic Azides	24
Multifaceted Domino Knoevenagel‐Cyclization Reactions; Four Movements for 2H‐Chromenes and Chromans	24
Synthesis of Dihydropyrazoles via Palladium‐Catalyzed Cascade Heterocyclization/Carbonylation/Arylation of β,γ‐Unsaturated N‐Tosyl Hydrazones	23
The Chemistry of α‐Enolizable Alkynones: A Comprehensive Review	23
Photo‐Catalyzed Stereospecific Synthesis of Trisubstituted Alkenes Incorporating 3,3‐Difluoro‐γ‐Lactams from Morita‐Baylis‐Hillman Acetates and N‐Allylbromodifluoroacetamides	23
Bidentate NHC‐Containing Ligands for Copper Catalysed Synthesis of Functionalised Diaryl Ethers	23
One‐Pot Synthesis of Quinazolines via Elemental Sulfur‐Mediated Oxidative Condensation of Nitriles and 2‐(Aminomethyl)anilines	23
Monofluorinated C1 Synthon Strategy for the Construction of Fluoromethylene‐Linked Bicyclo[1.1.1]Pentane Derivatives	23
Gold‐Catalyzed Annulation of Ynamides with Aminocarbonyls as a Route to 2‐Aminoquinolines Diversely Substituted at the 4th‐Position	23
2‐Bromo‐3,3,3‐Trifluoropropene: A Versatile Reagent for the Synthesis of Fluorinated Compounds	23
Visible‐Light‐Induced Controlled C–H Cyanation or Thiocyanation of Indolizines	23
Rh(I)‐Catalyzed Decarboxylative Arylation of Alkynyl Cyclic Carbonates: Divergent Access to Substituted α‐Allenols and 1,3‐Butadienes	23
Pd‐Catalyzed Ring‐Opening Defluorinative Arylation of gem‐Difluorocyclopropanes with Arylsilanes	23
Remote Giese Radical Addition by Photocatalytic Ring Opening of Activated Cycloalkanols	22
Modular Chiral Bithiophene‐2NO Ligands: Synthesis and Application in Asymmetric Palladium(II)‐Catalysed Friedel‐Crafts Alkylation	22
One‐Pot Tandem Cyclization of β‐Oxoamides, Primary Amines, and 3‐bromo‐1,1,1‐trifluoroacetone: Synthesis of 2/4‐trifluoromethyl‐substituted dihydropyrrol‐2/4‐ols	22
Silver‐Mediated In‐Situ Generation of Alkynyl Selenium Intramolecular AAC Click Reactions	22
Organocatalytic Asymmetric Synthesis of Cyclic Acetals with Spirooxindole Skeleton	22
Amide Synthesis via Transaminative Amidation of Aromatic Aldehydes/Ketones: An Entry to 15N Isotopologs	22
Front Cover Picture: Palladium‐Catalyzed Chemoselective Amination of Chloro(hetero)aryl Triflates Enabled by Alkyl‐Pyrazole‐Based Phosphine Ligands (Adv. Synth. Catal. 7/2024)	22
K3PO4–Mediated Synthesis of Chromeno–[3,4‐c]isoxazole from 3–Nitro–2H–chromene and α–Chloro Aldehyde via Michael Addition/C−Cl Bond Cleavage/Deformylation as	22
In Situ Generation of Copper Nanoparticle‐Graphitic Carbon Nitride Composite for Stereoselective Transfer Semihydrogenation of Alkynes: Evaluation of Catalytic Activity Using Fluorescence‐Based	22
Front Cover Picture: (Adv. Synth. Catal. 10/2025)	22
Peroxidation and Skeletal Rearrangement for the Synthesis of Dioxole‐2‐Carboxamide Derivatives under Continuous‐Flow Conditions	21
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Pyrrolidine‐Catalyzed Annulations of Quinone Monoacetals with Naphthols: Synthesis of 2‐Oxabicyclo[3.3.1]nonane Skeletons, Transformations and Reaction Mechanism	21
Asymmetric CH Functionalization Enabled by a Traceless Oxidizing Chiral Auxiliary	21
1,3‐Iodoesterification of 2‐Substituted Indoles via Csp2−H/Csp3−H Retained Dual Functionalization Using Hypervalent Iodine(III)	21
Stereoconvergent Access to Z‐Allylborons from E/Z‐Mixed 1,3‐Dienes via Cu‐Guanidine Catalysis	21
DMAP‐promoted [4+2]/[3+3] Annulation Cascade Reaction of Morita–Baylis–Hillman Carbonates with Conjugated Imines to Access Functionalized Benzo[c][2,7]naphthyridine Skeletons	21
Au(I) and HOTf‐Catalyzed Cascade [5+1]‐Annulations between Allenylacetals and Diazo Esters To Form 1,3‐ and 2,3‐Disubstituted Naphthoates, Respectively	21
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Asymmetric Hydrogenation of Tetrahydro‐γ‐Carboline Derivatives with Phosphine‐Free Ruthenium Diamine Catalysts	21
Stereoselective Organocatalyzed Glycosylation of Glycosyl Trichloroacetimidate Donors: Thiouracil as Brønsted Acid Catalyst	20
Direct Site‐Selective Deoxygenation of Benzylalcohol Derivatives	20
Diradical Polar Reactivity Induced by Electricity‐Mediated Ground State Triplet Nitrenium Species	20
Unexpected Stereoselective Access to 2‐Aminooxazolines from Propargyl Ureas by Silver Salts under Mild Conditions	20
Synthesis of Heterospirocycles through Gold‐(I) Catalysis: Useful Building Blocks for Medicinal Chemistry	20
Visible Light Induced EDA‐mediated Deaminative C‐2 Alkylation of Heterocyclic‐N‐Oxides using Katritzky salts	20
Pincer‐Ruthenium Catalyzed Oxygen Mediated Dehydrative Etherification of Alcohols and Ortho‐Alkylation of Phenols	20
Synthesis of Oxadihydrophenanthroquinolizidinones by Photoinduced Rearrangement of 3‐Biphenyl‐1‐hydroxypropyl‐pyridin‐2(1H)‐ones	20
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A Sequence‐Controlled Di‐Functionalization of an SO2‐Surrogate with Amines for the Synthesis of Sulfonamides	20
Corrigendum: Cyclic Sulfoximine and Sulfonimidamide Derivatives by Copper‐Catalyzed Cross‐Coupling Reactions with Elemental Sulfur	20
Multicomponent Heteroarylphosphorothiolation of Alkenes for Accessing β‐Phosphorothiolated Quinoxalinones	20
Preparation of Mesoporous Cu2O Nanospheres for Green Synthesis in the Enantioselective Boron Conjugate Addition of α,β‐Unsaturated Chiral Compounds in Aqueous Phase	20
Copper‐Catalyzed α‐Indolmethylation of 2‐Pyridylacetates with 3‐Indoleacetic Acids via Alkylideneindolenine Intermediates	20
Recent Advance in Transition Metal‐Catalyzed Carboxylic Acid Guided B−H Functionalization of Carboranes	20
Directed Palladium‐Catalyzed pseudo‐Anomeric C−H Functionalization of Glycal‐Type Substrates: Access to Unsymmetrical gem‐Diarylmethyl C‐Glycosides	20
Iron Catalyzed Radical Alkylation of Cyclic Ketimines with Olefins via Metal Hydride Atom Transfer	20
Palladium‐Catalyzed Chemoselective Borylation of (Poly)halogenated Aryl Triflates and Their Application in Consecutive Reactions	20
γ‐Terpinene: Biorenewable Reductant for the Molybdenum‐Catalyzed Reduction of Sulfoxides, N‐Oxides and Nitroarenes	19
Mechanistic Insight into Palladium‐Catalyzed Asymmetric Alkylation of Indoles with Diazoesters Employing Bipyridine‐N,N’‐dioxides as Chiral Controllers	19
Molybdenum‐Catalyzed Direct Synthesis of Pyrroles from Nitroarenes with Glycols as Reductants	19
Synthesis of 1‐Aryl Isoquinolinones or o‐Diaryl Pyrimidines via Bismuth Triflate‐Mediated Intermolecular Annulation of Arylacetic Acids with Nitroarylaldehydes or Trimethoxybenzene in the Prese	19
Multicomponent Annulative SO2 Insertion of Heteroatom‐Linked 1,7‐Diynes for Accessing Tricyclic Sulfones	19

Halogen Atom Transfer Enabled Radical Fluoroalkyl‐Thiolation of Unactivated Alkenes	19
Mechanochemically Induced Cross Dehydrogenative Coupling Reactions under Ball Milling	19
Palladium‐Catalyzed Stereoselective Intramolecular Heck Dearomative Silylation of Indoles	19
Ru(II) Catalyzed Oxidative Dehydrogenative Annulation and Spirocyclization of Isoquinolones with N‐Substituted Maleimides	19
Bromo Radical‐Mediated Photoredox Aldehyde Decarbonylation towards Transition‐Metal‐Free Hydroalkylation of Acrylamides at Room Temperature	19
Update on the Synthesis of N‐Heterocycles via Cyclization of Hydrazones (2017–2021)	19
Hydroaminoalkyl Functionalization of Pyrimidin‐2(1H)‐ones by Visible Light Organophotocatalysis: A Radical Approach to Biginelli‐Type Dihydropyrimidines	19
Dibenzoylperoxide as a Versatile Oxidant for Oxidative Azidations of Phenols Using Quaternary Ammonium Iodides or Bromides.	19
Thianthrenium Salts to Arynes: Base Promoted C−N Bond Construction	19
A Mild Reductant NHC‐ligated Borane for N‑Formylation of Amines with CO2 under Ambient Conditions	19
Recent Progress of Electron‐Withdrawing‐Group‐Tethered Arenes Involved Asymmetric Nucleophilic Aromatic Functionalizations	19
Selective Access to Sultams and Spirocyclic Sultams by the Divergent Annulations of (N‐Aryl)‐Alkynyl Sulphonamides	19
Photoredox and Copper‐Catalyzed Sulfonylphosphorothiolation of Alkenes toward β‐Sulfonyl Phosphorothioates	19
Phospholanes via Twofold C‐H‐Addition to Phospholes	19
Well‐Defined [Cp*Co(N,O)I]‐Catalysts for Site‐Selective Intramolecular C−H Amidation	19
Brønsted Acid‐Catalyzed Enantioselective and Para‐Selective Addition of Phenols to 1‐Alkynylnaphth‐2‐Ols	19
Asymmetric Synthesis of Chiral α‐CF2H Spiro[Indoline‐3,3′‐Thiophene] via Phase‐Transfer Catalyzed Sulfa‐Michael/Michael Domino Reaction	19
Arylation of Secondary Phosphines with Diaryliodonium Salts under Metal‐Free and Non‐Photochemical Conditions	19
Sustainable Photoelectrochemical Geminal α‐Fluorosulfenylation of Diazo Compounds through Carbene Radical Anion Intermediate	19
Synthesis of Deoxysugars from Aliphatic α‐Ketoacids and Aldoses Catalyzed by Thermostable Transketolase Variants from Geobacillus stearothermophilus	19
Asymmetric Boracarboxylation of Styrenes Using Carbon Dioxide	18
Synthesis of SCF3‐Substituted Sulfonium Ylides from Sulfonium Salts or α‐Bromoacetic Esters	18
Copper‐Catalyzed Olefinic C(sp2)−H Activation/Carbene Insertion/Ester Hydrolysis/Cyclization with Aryl Diazo Esters for the Synthesis of Multisubstituted Furanones	18
Electrochemical α‐Functionalization of N‐Aryl‐Activated Tertiary Amines	18
Synthesis of Monofluorocyclohexene via Photocatalytic Defluorinative [4+2] Annulation of gem‐Difluoroalkenes with Unactivated Alkenes	18
Synthesis of Functionalized Benzo[f]chromanes and Hydroxyalkyl Naphthols: Catalytic Coupling of Naphthols and Allylic Alcohols	18
Synthesis of 2‐Aryl‐2H‐1,2,3‐triazoles via P(OMe)3‐Promoted Intramolecular Transannulation of 4‐Diazenylisoxazol‐5(4H)‐ones	18
Auxiliary‐Free Remote Dearomatizative Nitrenoid Transfer for Enantioselective Construction of Spirolactams	18
Modular Photochemical Flow Synthesis of Structurally Diverse Benzyne and Triazine Precursors	18
Photocatalyzed Aerobic Dearomatization of Naphthylamines under Visible‐Light Irradiation	18
Copper‐Catalyzed Tandem Cyclization of 2‐(Alkynylaryl)Acetonitriles and Amines: Access to 3‐Hydroxyisoindolinones	18
Front Cover Picture: Mechanochemical Ni‐Catalysed Arylation of ortho‐Hydroxyarylenaminones: Synthesis of Isoflavones (Adv. Synth. Catal. 20/2022)	18
A Solely Fe‐Catalyzed Sonogashira‐Type Coupling of non‐Activated Secondary Alkyl Iodides with Terminal Alkynes	18
Regioselective Construction of Indolylated Cyclic Tetrasubstituted Carbon Centers through Brønsted Acid‐Catalyzed Dearomative Skeletal Rearrangement of Azofurans	18
Water‐Facilitated Nitromethane‐Mediated Cyclization of 2‐(Phenylvinyl)benzhydrols: Access to 1,3‐Diphenyl‐1H‐indenes with Antitumor Activity	18
Corrigendum: Mechanistic Insights on the Enantioselective (4+3) cycloaddition between Oxyallylcations and Furans Catalyzed by BINOL‐based Phosphoramides	18
Three‐Component Allylic Alkylation Reaction of α‐Diazo Ketones with Water and Allyl Carbonates for Construction of Homoallylic Alcohols	18
Palladium‐Catalyzed Chemoselective Amination of Chloro(hetero)aryl Triflates Enabled by Alkyl‐Pyrazole‐Based Phosphine Ligands	18
Carboxylic acids as enabling directing groups in C−H activation and functionalization: A decade review	18
[(5+1)−1] Cyclization of Nitroepoxides to Pyridinium 1,4‐Zwitterionic Thiolates for the Synthesis of Indolizine Derivatives	18
Visible‐Light‐Induced Stereoselective C(sp3)−C(sp3)−H Glycosylation for the Synthesis of C‐Glycoamino Acid Derivatives	18
Accessing 2‐(Chalcogen)benzothiazoles via Electrochemical Intermolecular Cyclization of Isocyanides with Thiols or Diselenides	18
Controllable Synthesis of Oxa‐/Thia‐Spirohydroquinolines by [3+(2+1)] Annulation of Aromatic Amines with Bimolecular O/S‐Heterocyclic Ketones	18
Molecular Oxygen‐Induced Transamidation of Unactivated Amides in Diethyl Carbonate in the Presence of a Palladium Catalyst	18
Controllable Access to Furans and Dihydrofurans through Cyclization/Coupling of Internal Acetylenic β‐Ketoesters with Aryl Bromides	18
Transition‐Metal‐Free Regioselective Direct C2, C4 Difunctionalization and C2, C4, C6 Trifunctionalization of Pyridines	18
Facile Access to 2‐Substituted‐1,2,3,4‐Tetrahydroquinoxalines via Borane‐Catalyzed One‐Pot Tandem Cyclization/Hydrosilylation	17
Silver‐Catalyzed [3+2] Cycloaddition for the Diastereoselective Synthesis of anti‐3‐Substituted Hydroindolin‐2‐Imines	17
Strategies and Methods for the Synthesis of 2‐Pyrazolines: Recent Developments (2012–2022)	17
Cu(I) Catalyzed Germyl S‐Phosphorothiolation of Electron‐Deficient Alkene	17
Synthesis of Difluorocyclopropanes via Visible‐Light‐Mediated [1+2] Cycloaddition of Diazo Esters with gem‐Difluoroalkenes and Evaluation of their Antifungal Activity	17
Maleimide‐Controlled Formation of Indanonylpyrrolinediones and Spiroindanonylpyrrolinediones via Rh(III)‐Catalyzed C−H Activation of Sulfoxonium Ylides	17
Iron‐Catalyzed C−C and C−N Bond‐Forming Tandem Amidation Offering Access to 3‐Amino‐3‐Aminomethyl‐2‐Oxindole Frameworks	17
Recent Advances in Cyclization Reactions of 1,6‐Enynes	17
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Visible‐Light Photoredox‐Catalyzed Tandem One‐Pot Construction of C4‐Difluoroalkylated Phthalazin‐1(2H)‐Ones	17
Advances of Chiral Metal Complexes as Standalone Photocatalyst for Asymmetric Organic Transformations	17
Electrosynthesis of 2,5‐Disubstituted Furans through a CC Double Bond Cleavage Radical Cascade	17
Electrochemically‐Driven Organocatalytic Enantioselective Oxidative Coupling of Tetrahydroisoquinolines and Acrylaldehyde	17
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Noncovalent‐Interaction‐Dictated Product Selectivity in Intermolecular and Intramolecular Controllable Oxidation of Aromatic Amines Using 2,2′‐Diperoxyphenic Acid	17
Heterogeneous Copper‐Catalyzed 1,4‐Conjugate Additions of Grignard Reagents to Cyclic and Linear Enones	17
Manganese‐Mediated Electrooxidative Ring‐Opening Azidation of Cyclobutanol Derivatives with TMSN3	17
Reaction of Indole‐2‐Carboxylates/Carboxylic Acids with Propargylic Alcohols: Dearomative Ring Expansion/Spirocyclization vs Fused Pentacyclics	17
Photoinduced Transition‐Metal‐Free Chemodivergent Phosphorylation‐Peroxidation and Oxyphosphorylation of Alkenes	17
Electrochemical Decarboxylative Coupling of N‐Substituted Glycines under Air: Access to C3‐Aminomethylated Imidazo[1,2‐a]pyridines	16
Recent Advances in the 1,2‐Diarylation of Alkenes	16
Synthesis of 4‐Phosphinylpyrrolidin‐3‐ones via [3+2] Cycloaddition of Nitrones with Phosphinylallenes	16
An Acid Promoted, Domino Approach for the Selective Synthesis of Spirocyclic Systems#	16
Modular Synthesis of 2,3,4,6‐Tetrasubstituted Thieno[2,3‐c]furans Based on Formal [3+2] Cycloaddition Utilizing [1,2]‐Phospha‐Brook Rearrangement / Brønsted Base‐Mediated Cyclization Strategy	16
Rhodium(CAAC)‐Catalyzed Arene Hydrogenation of Benzo‐Fused N‐Heterocycles to Saturated Building Blocks with an all‐cis Configuration	16
Synthesis of 4,6‐Difluoro‐Tryptophan as a Probe for Protein 19F NMR	16
Catalytic Cycloisomerization of Enyne Diesters Derived from Biaryls and Related Substrates	16
TEMPO Mediated Cyclopropanols Ring Opening C−N Cross‐Coupling with Nitrogen Nucleophiles	16
Front Cover: Gold(I)‐Catalyzed Enantioselective Cycloisomerization of 1,6‐Oxygenated Enynes: An Entry to Hedonic Derivatives (Adv. Synth. Catal. 19/2025)	16
Rhodium(III)‐Catalyzed Redox‐Neutral Synthesis of Indenones from 2‐Aryl‐3‐nitrosoindoles with Alkynes	16
Ruppert‐Prakash Reagent (TMSCF3)‐Catalyzed Chemoselective Esterification of Weinreb Amides	16
Use of Iridium‐Catalyzed Transfer Vinylation for the Synthesis of Bio‐Based (bis)‐Vinyl Ethers	16
Water‐Mediated 1,7‐Palladium Aryl‐to‐Aryl Migration in an Unusual Aryne Trimerization Enables the Synthesis of Multihelicenes with Profoundly Hindered Stereogenic Axes	16
Recent Advances in Ni‐Catalyzed 1,1‐Difunctionalization of Unactivated Olefins	16
Direct Assembly of Polysubstituted Furans with Dimethyl Sulfoxide as a Multipurpose Precursor via β‐C(sp3)−H Functionalization of Saturated Ketones	16
Iron‐Catalyzed Alkene Trifluoromethylation in Tandem with Phenol Dearomatizing Spirocyclization: Regioselective Construction of Trifluoromethylated Spirocarbocycles	16
Visible‐Light‐Induced Oxidative Carboazidation of Arylacrylamides	16
Synthesis of 3‐Arylazoindoles through Iron(III)‐Catalyzed C−H Azolation of Indoles and Arylhydrazines	16
Synthesis of Functionalized 3‐(1H‐Isochromen)‐chromones via Ag2O‐Catalyzed Cascade Cyclization Reaction of o‐Hydroxyarylenaminones with o‐Alkynylbenzaldehydes	16
C−N Coupling between Aryl Azides and Cyclopropanols by Photoredox/Copper Dual Catalysis	16
Visible‐Light‐Enabled Photosensitizer‐ and Additive‐Free Decarboxylative Coupling Cyclization of Enaminone with N‐Arylglycine for 3‐Aminoalkyl Chromones	16
A Direct Silver‐Catalyzed Three‐Component Approach to Trifluoromethylated Cyanopyrazoles and Cyanopyrazolines	16
Single‐Atom Cobalt‐Catalyzed Transfer Hydrogenation of Azides and One‐Pot Synthesis of Pyrroles	16
	16
Synthesis of Secondary Trifluoromethyl Boronic Esters through Visible Light Induced Decarboxylative Alkylation Reactions	15
CeO2‐Nanorods‐Catalyzed Protoboration of Alkenes and Alkynes with Bis(pinacolato)diboron	15
Visible Light‐Assisted Direct C−H Acyloxylation of Polycyclic Aromatic Hydrocarbons using Carboxylic Acids	15
RuHCl(CO)(PPh3)3‐Catalyzed Isomerization of Homoallyl Silyl Ethers and Carbonates to Allyl Silyl Ethers and Carbonates	15
Ruthenium‐Catalyzed Regioselective Tandem Cycloisomerization/Diels‐Alder Reaction of 1,7‐Enynes	15