Organic Letters

Article	Citations
Heterologous Biosynthesis of the Sterol O-Acyltransferase Inhibitor Helvamide Unveils an α-Ketoglutarate-Dependent Cross-Linking Oxygenase	909576501
Tridentate Sulfoxide-N-olefin Hybrid Ligands in Rhodium-Catalyzed Asymmetric Allylic Substitution	889795337
Kinetic Resolution of Sulfoximines via Asymmetric Organocatalyzed Formation of Benzothiadiazine-1-oxides	842543667
Arylthianthrenium Salts as the Aryl Sources: Visible Light/Copper Catalysis-Enabled Intermolecular Azidosulfonylation of Alkenes	809120313
BI-OAc-Accelerated C3–H Alkylation of Quinoxalin-2(1H)-ones under Visible-Light Irradiation	100
Hidden Boron Catalysis: Nucleophile-Promoted Decomposition of HBpin	100
Arenesulfonyl Fluoride Synthesis via Copper-Catalyzed Fluorosulfonylation of Arenediazonium Salts	97
Acyl Radicals from α-Keto Acids: Metal-Free Visible-Light-Promoted Acylation of Heterocycles	95
Concise Synthesis of Isocoumarins through Rh-Catalyzed Direct Vinylene Annulation: Scope and Mechanistic Insight	87
Oxidative C–H/C–H Annulation of Imidazopyridines and Indazoles through Rhodium-Catalyzed Vinylene Transfer	85
Site-Selective C–H Functionalization–Sulfination Sequence to Access Aryl Sulfonamides	83
N-Heterocyclic Carbene-Catalyzed Radical Relay Enabling Synthesis of δ-Ketocarbonyls	78
Copper-free Sandmeyer-type Reaction for the Synthesis of Sulfonyl Fluorides	77
Fully Bridged Triphenylamine Derivatives as Color-Tunable Thermally Activated Delayed Fluorescence Emitters	75
SuFEx Activation with Ca(NTf2)2: A Unified Strategy to Access Sulfamides, Sulfamates, and Sulfonamides from S(VI) Fluorides	75
Electrochemical Annulation–Iodosulfonylation of 1,5-Enyne-containing para-Quinone Methides (p-QMs) to Access (E)-Spiroindenes	74
Alternating Current Electrolysis for Organic Electrosynthesis: Trifluoromethylation of (Hetero)arenes	73
Iodonium Ylides as Carbene Precursors in Rh(III)-Catalyzed C–H Activation	72
Functionalization of Pyridinium Derivatives with 1,4-Dihydropyridines Enabled by Photoinduced Charge Transfer	69
A Need for Caution in the Preparation and Application of Synthetically Versatile Aryl Diazonium Tetrafluoroborate Salts	69
Circularly Polarized Luminescence Designed from Molecular Orbitals: A Figure-Eight-Shaped [5]Helicene Dimer with D2 Symmetry	68
Co(III)-Catalyzed Annulative Vinylene Transfer via C–H Activation: Three-Step Total Synthesis of 8-Oxopseudopalmatine and Oxopalmatine	68
Copper-Catalyzed C–H Fluorination/Functionalization Sequence Enabling Benzylic C–H Cross Coupling with Diverse Nucleophiles	67
Visible-Light-Mediated β-C–H gem-Difluoroallylation of Aldehydes and Cyclic Ketones through C–F Bond Cleavage of 1-Trifluoromethyl Alkenes	67
Enantioselective Synthesis of Five-Membered-Ring Atropisomers with a Chiral Rh(III) Complex	67

Self-Catalyzed Phototandem Perfluoroalkylation/Cyclization of Unactivated Alkenes: Synthesis of Perfluoroalkyl-Substituted Quinazolinones	67
Cross-Dehydrogenative Coupling of Strong C(sp3)–H with N-Heteroarenes through Visible-Light-Induced Energy Transfer	67
Twisted Bodipy Derivative as a Heavy-Atom-Free Triplet Photosensitizer Showing Strong Absorption of Yellow Light, Intersystem Crossing, and a High-Energy Long-Lived Triplet State	66
Organophotoredox-Catalyzed Direct C–H Amination of 2H-Indazoles with Amines	65
Asymmetric (4 + 3) and (4 + 1) Annulations of Isatin-derived Morita–Baylis–Hillman Carbonates to Construct Diverse Chiral Heterocyclic Frameworks	65
Synthesis of (E)-Quinoxalinone Oximes through a Multicomponent Reaction under Mild Conditions	62
The Domino Chromone Annulation and a Transient Halogenation-Mediated C–H Alkenylation toward 3-Vinyl Chromones	61
Copper-Catalyzed Regioselective 1,4-Selenosulfonylation of 1,3-Enynes to Access Cyanoalkylsulfonylated Allenes	60
Electrochemical Radical–Radical Cross-Coupling Approach between Sodium Sulfinates and 2H-Indazoles to 3-Sulfonylated 2H-Indazoles	60
Ag-Catalyzed Oxidative ipso-Cyclization via Decarboxylative Acylation/Alkylation: Access to 3-Acyl/Alkyl-spiro[4.5]trienones	59
Rh-Catalyzed C–H Amination/Annulation of Acrylic Acids and Anthranils by Using −COOH as a Deciduous Directing Group: An Access to Diverse Quinolines	59
Visible-Light-Enabled Paternò–Büchi Reaction via Triplet Energy Transfer for the Synthesis of Oxetanes	59
Electrochemical Trifluoromethylthiolation and Spirocyclization of Alkynes with AgSCF3: Access to SCF3-Containing Spiro[5,5]trienones	58
Dearomative Cycloadditions Utilizing an Organic Photosensitizer: An Alternative to Iridium Catalysis	58
Selective Synthesis of Pyrazolo[1,2-a]pyrazolones and 2-Acylindoles via Rh(III)-Catalyzed Tunable Redox-Neutral Coupling of 1-Phenylpyrazolidinones with Alkynyl Cyclobutanols	58
Asymmetric Synthesis of Silicon-Stereogenic Monohydrosilanes by Dehydrogenative C–H Silylation	57
Triphenylphosphine-Catalyzed Alkylative Iododecarboxylation with Lithium Iodide under Visible Light	57
Photoredox/Hydrogen Atom Transfer Cocatalyzed C–H Difluoroallylation of Amides, Ethers, and Alkyl Aldehydes	56
Nickel-Catalyzed Asymmetric Reductive Arylbenzylation of Unactivated Alkenes	56
Ruthenium(II)-Catalyzed C–C/C–N Coupling of 2-Arylquinazolinones with Vinylene Carbonate: Access to Fused Quinazolinones	56
Rh(III)-Catalyzed Chemodivergent Annulations between Indoles and Iodonium Carbenes: A Rapid Access to Tricyclic and Tetracyclic N-Heterocylces	56
Catalytic Enantioselective Synthesis of Difluoromethylated Tetrasubstituted Stereocenters in Isoindolones Enabled by a Multiple-Fluorine System	55
Transamidation for the Synthesis of Primary Amides at Room Temperature	54
Palladium-Catalyzed Disilylation and Digermanylation of Alkene Tethered Aryl Halides: Direct Access to Versatile Silylated and Germanylated Heterocycles	54
Decarboxylative and Deaminative Alkylation of Difluoroenoxysilanes via Photoredox Catalysis: A General Method for Site-Selective Synthesis of Difluoroalkylated Alkanes	54
Pd-Catalyzed Enantioselective Tandem C–C Bond Activation/Cacchi Reaction between Cyclobutanones and o-Ethynylanilines	54
Divergent Synthesis of Aziridine and Imidazolidine Frameworks under Blue LED Irradiation	53
Decatungstate as Direct Hydrogen Atom Transfer Photocatalyst for SOMOphilic Alkynylation	53
Methanol as the Hydrogen Source in the Selective Transfer Hydrogenation of Alkynes Enabled by a Manganese Pincer Complex	53
Radical Relay Trichloromethylacylation of Alkenes through N-Heterocyclic Carbene Catalysis	53
Germylation of Arenes via Pd(I) Dimer Enabled Sulfonium Salt Functionalization	53
Stereodivergent Synthesis of α-Quaternary Serine and Cysteine Derivatives Containing Two Contiguous Stereogenic Centers via Synergistic Cu/Ir Catalysis	53
Iodine-Mediated Electrochemical C(sp2)–H Amination: Switchable Synthesis of Indolines and Indoles	53
Synthesis of Thiazoles and Isothiazoles via Three-Component Reaction of Enaminoesters, Sulfur, and Bromodifluoroacetamides/Esters	53
Pd-Catalyzed Triple-Fold C(sp2)–H Activation with Enaminones and Alkenes for Pyrrole Synthesis via Hydrogen Evolution	52
Enantioselective Remote C(sp3)–H Cyanation via Dual Photoredox and Copper Catalysis	52
Arylaminomethyl Radical-Initiated Cascade Annulation Reaction of Quinoxalin-2(1H)-ones Catalyzed by Recyclable Photocatalyst Perovskite	52
DMSO as a C1 Source for [2 + 2 + 1] Pyrazole Ring Construction via Metal-Free Annulation with Enaminones and Hydrazines	52
Thioether-Directed C4-Selective C–H Acylmethylation of Indoles Using α-Carbonyl Sulfoxonium Ylides	51
Visible-Light-Promoted Cross-Coupling Reactions of 4-Alkyl-1,4-dihydropyridines with Thiosulfonate or Selenium Sulfonate: A Unified Approach to Sulfides, Selenides, and Sulfoxides	51
Preparation of Thiazole-2-thiones through TBPB-Promoted Oxidative Cascade Cyclization of Enaminones with Elemental Sulfur	50
Iron-Catalyzed C–C Single-Bond Cleavage of Alcohols	50
Fast Amide Couplings in Water: Extraction, Column Chromatography, and Crystallization Not Required	50
Carbene-Catalyzed Atroposelective Annulation and Desymmetrization of Urazoles	49
Oxime Ether Synthesis through O–H Functionalization of Oximes with Diazo Esters under Blue LED Irradiation	49
Quantum Mechanical–NMR-Aided Configuration and Conformation of Two Unreported Macrocycles Isolated from the Soft Coral Lobophytum sp.: Energy Calculations versus Coupling Constants	49
Atroposelective Synthesis of Axially Chiral 3-Arylindoles by Copper-Catalyzed Asymmetric Cross-Coupling of Indoles with Quinones and Naphthoquinones	48
Photocatalytic [2 + 2] Cycloaddition in DNA-Encoded Chemistry	48
N-Heterocyclic Carbene/Magnesium Cocatalyzed Radical Relay Assembly of Aliphatic Keto Nitriles	48
Metal-Free Radical-Mediated C(sp3)–H Heteroarylation of Alkanes	48

Access to 5,6-Spirocycles Bearing Three Contiguous Stereocenters via Pd-Catalyzed Stereoselective [4 + 2] Cycloaddition of Azadienes	48
Merger of C–F and C–N Bond Cleavage in Cross-Electrophile Coupling for the Synthesis of gem-Difluoroalkenes	48
Lewis Acid Catalyzed Ring-Opening 1,3-Aminothiolation of Donor–Acceptor Cyclopropanes Using Sulfenamides	47
FeCl3-Mediated Synthesis of 2-(Trifluoromethyl)quinazolin-4(3H)-ones from Isatins and Trifluoroacetimidoyl Chlorides	47
A Robust Pd-Catalyzed C–S Cross-Coupling Process Enabled by Ball-Milling	47
Synthesis of 3,4-Fused Tricyclic Indoles through Cascade Carbopalladation and C–H Amination: Development and Total Synthesis of Rucaparib	47
Divergent Photocatalytic Reactions of α-Ketoesters under Triplet Sensitization and Photoredox Conditions	47
Sulfonylation of Aryl Halides by Visible Light/Copper Catalysis	47
Selective Catalytic Synthesis of α-Alkylated Ketones and β-Disubstituted Ketones via Acceptorless Dehydrogenative Cross-Coupling of Alcohols	47
Reductive Arylation of Aliphatic and Aromatic Aldehydes with Cyanoarenes by Electrolysis for the Synthesis of Alcohols	47
Additive-Controlled Divergent Synthesis of Tetrasubstituted 1,3-Enynes and Alkynylated 3H-Pyrrolo[1,2-a]indol-3-ones via Rhodium Catalysis	46
Photocatalytic Decarboxylative [2 + 2 + m] Cyclization of 1,7-Enynes Mediated by Tricyclohexylphosphine and Potassium Iodide	46
Visible-Light-Induced Radical Difluoromethylation/Cyclization of Unactivated Alkenes: Access to CF2H-Substituted Quinazolinones	46
Rhodium(III)/Chiral Carboxylic Acid Catalyzed Enantioselective C(sp3)–H Alkylation of 8-Ethylquinolines with α,β-Unsaturated Carbonyl Compounds	46
Flow Microreactor Technology for Taming Highly Reactive Chloroiodomethyllithium Carbenoid: Direct and Chemoselective Synthesis of α-Chloroaldehydes	46
Chemoselective Hydrogenation of Nitroarenes Using an Air-Stable Base-Metal Catalyst	46
Ligand-Controlled, Palladium-Catalyzed Asymmetric [4+4] and [2+4] Cycloadditions	45
Acyl Radicals from α-Keto Acids Using a Carbonyl Photocatalyst: Photoredox-Catalyzed Synthesis of Ketones	45
Nickel-Catalyzed Guerbet Type Reaction: C-Alkylation of Secondary Alcohols via Double (de)Hydrogenation	45
Visible-Light-Mediated C–H Alkylation of Pyridine Derivatives	44
One-Pot Synthesis of Furo[3,4-c]indolo[2,1-a]isoquinolines through Rh(III)-Catalyzed Cascade Reactions of 2-Phenylindoles with 4-Hydroxy-2-alkynoates	44
Nickel-Catalyzed Decarboxylative Cross-Coupling of Bicyclo[1.1.1]pentyl Radicals Enabled by Electron Donor–Acceptor Complex Photoactivation	44
Visible-Light-Driven Radical Multicomponent Reaction of 2-Vinylanilines, Sulfonyl Chlorides, and Sulfur Ylides for Synthesis of Indolines	44
Electrochemical Radical Selenylation of Alkenes and Arenes via Se–Se Bond Activation	44
Titanocene-Catalyzed Reductive Domino Epoxide Ring Opening/Defluorinative Cross-Coupling Reaction	44
Direct Electrochemical Defluorinative Carboxylation of gem-Difluoroalkenes with Carbon Dioxide	44
Defluorinative Alkylation of Trifluoromethylbenzimidazoles Enabled by Spin-Center Shift: A Synergistic Photocatalysis/Thiol Catalysis Process with CO2•–	44
K2S as Sulfur Source and DMSO as Carbon Source for the Synthesis of 2-Unsubstituted Benzothiazoles	44
Cu/Pd-Catalyzed cis-Borylfluoroallylation of Alkynes for the Synthesis of Boryl-Substituted Monofluoroalkenes	43
Regio- and Stereoselective Photoredox-Catalyzed Atom Transfer Radical Addition of Thiosulfonates to Aryl Alkynes	43
2-(Dimesitylboryl)phenyl-Substituted [2.2]Paracyclophanes Featuring Intense and Sign-Invertible Circularly Polarized Luminescence	43
Organocatalytic Enantioselective Construction of Heterocycle-Substituted Styrenes with Chiral Atropisomerism	43
Photoinduced Ligand-to-Metal Charge Transfer (LMCT) of Fe Alkoxide Enabled C–C Bond Cleavage and Amination of Unstrained Cyclic Alcohols	43
Organocatalytic Three-Component 1,2-Cyanoalkylacylation of Alkenes via Radical Relay	43
Telescoped Continuous Flow Synthesis of Optically Active γ-Nitrobutyric Acids as Key Intermediates of Baclofen, Phenibut, and Fluorophenibut	43
Ni-Catalyzed Denitrogenative Cross-Coupling of Benzotriazinones and Cyclopropanols: An Easy Access to Functionalized β-Aryl Ketones	43
Multicomponent Synthesis of Biologically Relevant S-Aryl Dithiocarbamates Using Diaryliodonium Salts	42
Organophotoredox-Catalyzed Three-Component Coupling of Heteroatom Nucleophiles, Alkenes, and Aliphatic Redox Active Esters	42
Cobalt-Catalyzed Direct C–H Carbonylative Synthesis of Free (NH)-Indolo[1,2-a]quinoxalin-6(5H)-ones	42
Synthesis of Unnatural α-Amino Acids via Photoinduced Decatungstate-Catalyzed Giese Reactions of Aldehydes	42
Rhodium(III)-Catalyzed [4+3] Annulation of N-Aryl-pyrazolidinones and Propargylic Acetates: Access to Benzo[c][1,2]diazepines	42
Electroreductive 4-Pyridylation of Electron-deficient Alkenes with Assistance of Ni(acac)2	42
Redox Neutral Radical-Relay Cobalt Catalysis toward C–H Fluorination and Amination	42
Hydrogenation or Dehydrogenation of N-Containing Heterocycles Catalyzed by a Single Manganese Complex	42
Ru(II)-Catalyzed C–H Functionalization of N-Hydroxyoximes with 1,3-Diynes Unveils a Regioselective Disparity	42
Iron-Catalyzed Photoinduced Remote C(sp3)–H Amination of Free Alcohols	41
Visible-Light-Catalyzed Tandem Radical Addition/1,5-Hydrogen Atom Transfer/Cyclization of 2-Alkynylarylethers with Sulfonyl Chlorides	41
Cu-Catalyzed Synthesis of Tetrasubstituted 2,3-Allenols through Decarboxylative Silylation of Alkyne-Substituted Cyclic Carbonates	41
Chiral Naphthyl-C2-Indole as Scaffold for Phosphine Organocatalysis: Application in Asymmetric Formal [4 + 2] Cycloaddition Reactions	41
Combined KOH/BEt3 Catalyst for Selective Deaminative Hydroboration of Aromatic Carboxamides for Construction of Luminophores	41
Carbamates: A Directing Group for Selective C–H Amidation and Alkylation under Cp*Co(III) Catalysis	41
Organoelectrophotocatalytic C–H Silylation of Heteroarenes	41
Sulfoxonium-Ylide-Directed C–H Activation and Tandem (4 + 1) Annulation	41
Site-Selective Silylation of Arenes Mediated by Thianthrene S-Oxide	40
Kinetically Controllable Pd-Catalyzed Decarboxylation Enabled [5 + 2] and [3 + 2] Cycloaddition toward Carbocycles Featuring Quaternary Carbons	40
Traceless Bidentate Directing Group Assisted Cobalt-Catalyzed sp2-C–H Activation and [4 + 2]-Annulation Reaction with 1,3-Diynes	40
Enantioselective Dehydrative γ-Arylation of α-Indolyl Propargylic Alcohols with Phenols: Access to Chiral Tetrasubstituted Allenes and Naphthopyrans	40
Single C–F Transformations of o-Hydrosilyl Benzotrifluorides with Trityl Compounds as All-in-One Reagents	40
Transition-Metal-Free, Formal C–H Germylation of Arenes and Styrenes via Dibenzothiophenium Salts	40
Decarboxylative Thiolation of Redox-Active Esters to Thioesters by Merging Photoredox and Copper Catalysis	40
Visible-Light-Driven Copper-Catalyzed C(sp3)–O Cross-Coupling of Benzylic Radicals with Phenols	40
Photoinduced Copper-Catalyzed Site-Selective C(sp2)–C(sp) Cross-Coupling via Aryl Sulfonium Salts	40
Photoinduced EDA Complexes Enabled Radical Tandem Cyclization/Arylation of Unactivated Alkene with 2-Amino-1,4-naphthoquinones	40
NaI/PPh3-Mediated Photochemical Reduction and Amination of Nitroarenes	40
Perovskite as Recyclable Photocatalyst for Annulation Reaction of N-Sulfonyl Ketimines	40
Asymmetric Synthesis of N–N Axially Chiral Compounds by Phase-Transfer-Catalyzed Alkylations	40
Unnatural α-Amino Acid Synthesized through α-Alkylation of Glycine Derivatives by Diacyl Peroxides	40
Sequential Visible-Light and N-Heterocyclic Carbene Catalysis: Stereoselective Synthesis of Tetrahydropyrano[2,3-b]indoles	40
Photocatalytic C–H Trifluoromethylthiolation by the Decatungstate Anion	39
Atroposelective Synthesis of Axially Chiral 4-Aryl α-Carbolines via N-Heterocyclic Carbene Catalysis	39
Asymmetric Synthesis of Axially Chiral Naphthyl-C3-indoles via a Palladium-Catalyzed Cacchi Reaction	39
Asymmetric Photocatalytic C(sp3)–H Bond Addition to α-Substituted Acrylates	39
Visible-Light-Induced Regioselective Dicarbonylation of Indolizines with Oxoaldehydes via Direct C–H Functionalization	39
Brønsted Base and Lewis Acid Cooperatively Catalyzed Asymmetric exo′-Selective [3 + 2] Cycloaddition of Trifluoromethylated Azomethine Ylides and Methyleneindolinones	39
Copper-Catalyzed Remote C(sp3)–H Amination of Carboxamides	39
Acylation of Aryl Halides and α-Bromo Acetates with Aldehydes Enabled by Nickel/TBADT Cocatalysis	39
Palladium-Catalyzed Enantioselective 7-exo-Trig Carbopalladation/Carbonylation: Cascade Reactions To Achieve Atropisomeric Dibenzo[b,d]azepin-6-ones	39
Unactivated Alkyl Chloride Reactivity in Excited-State Palladium Catalysis	38
Electrochemical Decarboxylative N-Alkylation of Heterocycles	38
Regioselective and Diastereoselective Dearomative Multifunctionalization of In-Situ-Activated Azaarenes: An Access to Bridged Azaheterocycles	38

Copper-Catalyzed Trifluoromethylation of Ynones Coupled with Dearomatizing Spirocyclization of Indoles: Access to CF3-Containing Spiro[cyclopentane-1,3′-indole]	38
Rhodium-Catalyzed Dehydrogenative Annulation of N-Arylmethanimines with Vinylene Carbonate for Synthesizing Quinolines	38
Organocatalytic Formal (3 + 2) Cycloaddition toward Chiral Pyrrolo[1,2-a]indoles via Dynamic Kinetic Resolution of Allene Intermediates	38
Visible-Light-Driven Nitrogen Radical-Catalyzed [3 + 2] Cyclization of Vinylcyclopropanes and N-Tosyl Vinylaziridines with Alkenes	38
Visible-Light-Mediated C–I Difluoroallylation with an α-Aminoalkyl Radical as a Mediator	38
Rh(III)-Catalyzed [5 + 1] Annulation of Indole-enaminones with Diazo Compounds To Form Highly Functionalized Carbazoles	38
Photoinduced Rapid Multicomponent Cascade Reaction of Aryldiazonium Salts with Unactivated Alkenes and TMSN3	38
Schiff Base Cobalt(II) Complex-Catalyzed Highly Markovnikov-Selective Hydrosilylation of Alkynes	38
Metal-Free Chemoselective Reaction of Sulfoxonium Ylides and Thiosulfonates: Diverse Synthesis of 1,4-Diketones, Aryl Sulfursulfoxonium Ylides, and β-Keto Thiosulfones Derivatives	38
Visible-Light-Induced Multicomponent Synthesis of γ-Amino Esters with Diazo Compounds	38
Visible-Light-Driven Multicomponent Cyclization by Trapping a 1,3-Vinylimine Ion Intermediate: A Direct Approach to Pyrimido[1,2-b]indazole Derivatives	38
Thianthrenation-Enabled α-Arylation of Carbonyl Compounds with Arenes	38
Visible-Light-Induced Palladium-Catalyzed Intermolecular Narasaka–Heck Reaction at Room Temperature	38
Three-Component 1,2-Carboamidation of Bridged Bicyclic Alkenes via RhIII-Catalyzed Addition of C–H Bonds and Amidating Reagents	38
Pd/Cu-Catalyzed C–H/C–H Cross Coupling of (Hetero)Arenes with Azoles through Arylsulfonium Intermediates	38
Electrochemically Mediated Carboxylative Cyclization of Allylic/Homoallylic Amines with CO2 at Ambient Pressure	38
Cu(I)-Catalyzed Asymmetric Arylation of Pyrroles with Diaryliodonium Salts toward the Synthesis of N–N Atropisomers	38
Cobaloxime Catalysis for Enamine Phosphorylation with Hydrogen Evolution	37
Pyrrole Strategy for the γ-Lactam-Containing Stemona Alkaloids: (±)Stemoamide, (±)Tuberostemoamide, and (±)Sessilifoliamide A	37
Visible-Light-Induced Pd-Catalyzed Radical Strategy for Constructing C-Vinyl Glycosides	37
Cobalt-Catalyzed Regio- and Enantioselective Allylic Alkylation of Malononitriles	37
Rigid π-Extended Boron Difluoride Complex with Mega-Stokes Shift for Bioimaging	37
Electrochemical Oxidative Phosphorylation of Aldehyde Hydrazones	37
Enantioselective Ruthenium-Catalyzed C–H Alkylations by a Chiral Carboxylic Acid with Attractive Dispersive Interactions	37
Photochemical (Hetero-)Arylation of Aryl Sulfonium Salts	37
Construction of Atropisomeric 3-Arylindoles via Enantioselective Cacchi Reaction	37
Asymmetric Reductive Amination/Ring-Closing Cascade: Direct Synthesis of Enantioenriched Biaryl-Bridged NH Lactams	37
Visible-Light-Promoted Regioselective 1,3-Fluoroallylation of gem-Difluorocyclopropanes	37
Modular Domino Process toward Highly Functionalized Pyrroles via Pd-Catalyzed [4 + 1] Annulation under Mild Conditions	37
Ligand-Enabled Pd(II)-Catalyzed C(sp3)–H Lactonization Using Molecular Oxygen as Oxidant	37
Visible Light-Induced Cascade Cyclization of 3-Aminoindazoles, Ynals, and Chalcogens: Access to Chalcogen-Containing Pyrimido[1,2-b]-indazoles	37
A Readily Available Trifluoromethylation Reagent and Its Difunctionalization of Alkenes	37
A Family of BODIPY-like Highly Fluorescent and Unsymmetrical Bis(BF2) Pyrrolyl–Acylhydrazone Chromophores: BOAPY	37
Visible-Light-Induced, Base-Promoted Transition-Metal-Free Dehalogenation of Aryl Fluorides, Chlorides, Bromides, and Iodides	37
Directing-Group-Enabled Cycloaddition of Azides and Alkynes toward Functionalized Triazoles	37
Asymmetric Synthesis of Quinoline-Naphthalene Atropisomers by Central-to-Axial Chirality Conversion	37
Photocatalytic Remote Oxyfluoroalkylation of Heteroalkynes: Regio-, Stereo-, and Site-Selective Access to Complex Fluoroalkylated (Z)-Alkenes	37
Hydride Transfer Initiated Redox-Neutral Cascade Cyclizations of Aurones: Facile Access to [6,5] Spirocycles	37
Alkylative Dearomatization by Using an Unactivated Aryl Nitro Group as a Leaving Group: Access to Diversified Alkylated Spiro[5.5]trienones	37
Rhodium(III)-Catalyzed C–H Alkenylation/Directing Group Migration for the Regio- and Stereoselective Synthesis of Tetrasubstituted Alkenes	37
B(C6F5)3-Catalyzed Electron Donor–Acceptor Complex-Mediated Aerobic Sulfenylation of Indoles under Visible-Light Conditions	37
Copper-Catalyzed Thiolation of Terminal Alkynes Employing Thiocyanate as the Sulfur Source Leading to Enaminone-Based Alkynyl Sulfides under Ambient Conditions	37
Regioselective Radical Borylation of α,β-Unsaturated Esters and Related Compounds by Visible Light Irradiation with an Organic Photocatalyst	37
Visible-Light Decatungstate/Disulfide Dual Catalysis for the Hydro-Functionalization of Styrenes	37
Programmable One-Pot Synthesis of Heparin Pentasaccharide Fondaparinux	36
Visible-Light-Mediated Oxidative Debenzylation Enables the Use of Benzyl Ethers as Temporary Protecting Groups	36
Photoredox Generation of N-Centered Hydrazonyl Radicals Enables the Construction of Dihydropyrazole-Fused gem-Difluoroalkenes	36
Regioselective C–H Phosphorothiolation of (Hetero)arenes Enabled by the Synergy of Electrooxidation and Ultrasonic Irradiation	36
Iron-Catalyzed Borylation of Aryl Ethers via Cleavage of C–O Bonds	36
Photoredox-Catalyzed α-Sulfonylation of Ketones from Sulfur Dioxide and Thianthrenium Salts	36
Photochemical O–H Functionalization of Aryldiazoacetates with Phenols via Proton Transfer	36
Rh(I)-Catalyzed C6-Selective Decarbonylative Alkylation of 2-Pyridones with Alkyl Carboxylic Acids and Anhydrides	36
Ruthenium-Catalyzed α-Alkylation of Ketones Using Secondary Alcohols to β-Disubstituted Ketones	36
Three-Component Carbosilylation of Alkenes by Merging Iron and Visible-Light Photocatalysis	36
Electrochemical Alkoxyhalogenation of Alkenes with Organohalides as the Halide Sources via Dehalogenation	36
Silyl Radical Mediated Cross-Electrophile Coupling of N-Acyl-imides with Alkyl Bromides under Photoredox/Nickel Dual Catalysis	36
Organocatalytic Atroposelective Construction of Axially Chiral N-Aryl Benzimidazoles Involving Carbon–Carbon Bond Cleavage	36
Palladium-Catalyzed Stereoselective Hydrodefluorination of Tetrasubstituted gem-Difluoroalkenes	36
Sulfinates from Amines: A Radical Approach to Alkyl Sulfonyl Derivatives via Donor–Acceptor Activation of Pyridinium Salts	36
Base-Promoted Annulative Difluoromethylenation of Enaminones with BrCF2CO2Et toward 2,2-Difluorinated 2,3-Dihydrofurans	36
Regioselective Hydroboration and Hydrosilylation of N-Heteroarenes Catalyzed by a Zinc Alkyl Complex	36
A Traceless Heterocyclic Amine Mediator in Regioselectivity−Switchable Formal [1 + 2 + 2] Cycloaddition Reaction to 1,3,4- and 1,4,5-Trisubstituted Pyrazoles	36
Visible Light Mediated Photocatalyst Free C–S Cross Coupling: Domino Synthesis of Thiochromane Derivatives via Photoinduced Electron Transfer	35
Visible-Light Photocatalytic Tri- and Difluoroalkylation Cyclizations: Access to a Series of Indole[2,1-a]isoquinoline Derivatives in Continuous Flow	35
Co-Catalyzed Transannulation of Pyridotriazoles with Isothiocyanates and Xanthate Esters	35
Visible-Light-Mediated Enantioselective Photoreactions of 3-Alkylquinolones with 4-O-Tethered Alkenes and Allenes	35
Palladium-Catalyzed Amide N–C Hiyama Cross-Coupling: Synthesis of Ketones	35
Visible-Light-Induced Photocatalytic Synthesis of β-Keto Dithiocarbamates via Difunctionalization of Styrenes	35
Synthesis of β-Silyl α-Amino Acids via Visible-Light-Mediated Hydrosilylation	35
Photochemical Chemoselective Alkylation of Tryptophan-Containing Peptides	35
Electrochemical Synthesis of α-Ketoamides under Catalyst-, Oxidant-, and Electrolyte-Free Conditions	35
Photoredox Catalysis Enables Decarboxylative Cyclization with Hypervalent Iodine(III) Reagents: Access to 2,5-Disubstituted 1,3,4-Oxadiazoles	35
Copper-Catalyzed Asymmetric Cyanation of Alkenes via Carbonyl-Assisted Coupling of Alkyl-Substituted Carbon-Centered Radicals	35
Strategic Construction of Ethene-Bridged BODIPY Arrays with Absorption Bands Reaching the Near-Infrared II Region	35
Iridium-Catalyzed Cage B(4)-Amidation Reaction of o-Carboranes with Dioxazolones: Selective Synthesis of Amidated o-Carboranes and Amidated and Methoxycarbonylated nido-Carboranes	35
Palladium-Catalyzed C–H Allylation of Electron-Deficient Polyfluoroarenes with gem-Difluorinated Cyclopropanes	35
Construction of Axial Chirality and Silicon-Stereogenic Center via Rh-Catalyzed Asymmetric Ring-Opening of Silafluorenes	35
Primary Sulfonamide Synthesis Using the Sulfinylamine Reagent N-Sulfinyl-O-(tert-butyl)hydroxylamine, t-BuONSO	35
Construction of Cyclophane-Braced Peptide Macrocycles via Palladium-Catalyzed Picolinamide-Directed Intramolecular C(sp2)–H Arylation	35
Visible-Light-Induced Intermolecular Oxyimination of Alkenes	35
Copper-Catalyzed Functionalization of Benzylic C–H Bonds with N-Fluorobenzenesulfonimide: Switch from C–N to C–F Bond Formation Promoted by a Redox Buffer and Brønsted Base	35
Palladium-Catalyzed Mizoroki–Heck Reaction of Nitroarenes and Styrene Derivatives	35
Deoxyfluorination of Carboxylic Acids with CpFluor: Access to Acyl Fluorides and Amides	35
Remote Trifluoromethylthiolation Enabled by Organophotocatalytic C–C Bond Cleavage	35
N-Heterocyclic Carbene-Catalyzed 1,4-Alkylacylation of 1,3-Enynes	35
cis-Selective, Enantiospecific Addition of Donor–Acceptor Cyclopropanes to Activated Alkenes: An Iodination/Michael-Cyclization Cascade	35
N-Heterocyclic-Carbene-Catalyzed C–H Acylation via Radical Relay	35
A Dual-Protein Cascade Reaction for the Regioselective Synthesis of Quinoxalines	35
Electrochemical Oxidative Dehydrogenative Phosphorylation of N-Heterocycles with P(O)–H Compounds in Imidazolium-Based Ionic Liquid	35
Catalytic, Enantioselective C2-Functionalization of 3-Aminobenzofurans Using N-Heterocyclic Carbenes	35
Photoredox-Catalyzed Four-Component Reaction for the Synthesis of Complex Secondary Amines	35
Catalytic Decarboxylative Fluorosulfonylation Enabled by Energy-Transfer-Mediated Photocatalysis	35
Enantioselective Copper-Catalyzed Remote C(sp3)–H Alkynylation of Linear Primary Sulfonamides	35
Construction of Pyridine-Based Chiral Ionic Covalent Organic Frameworks as a Heterogeneous Catalyst for Promoting Asymmetric Henry Reactions	34
Iron-Catalyzed Alkylazidation of 1,1-Disubstituted Alkenes with Diacylperoxides and TMSN3	34