Organic & Biomolecular Chemistry

Article	Citations
Multi-purpose thiocyanate protic ionic liquids in chemodivergent transformations of imidazolidin-2-(thi)one-based diols	88
Cu2O-mediated regio- and stereoselective one-pot synthesis of (Z)-3-ylidenephthalides from 2-iodobenzoic acids and terminal alkynes	76
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Combining synthetic biology with synthetic electrochemistry to expand the chemical space of the indolocarbazole family	73
Asymmetric synthesis of (R)-baclofen and (3S,4S)-tetflupyrolimet via “on water” organocatalytic addition reactions: a tip on catalyst screening	67
Sequential condensation and double desulfonylative cyclopropanation of 1,2-bis(sulfonylmethyl)arenes with 3-arylacroleins: access to biscyclopropane-fused tetralins	67
A macrocycle-based new organometallic nano-vessel towards sustainable C2-selective arylation of free indole in water	66
Methyl group configuration on acyclic threoninol nucleic acids (aTNAs) impacts supramolecular properties	65
d-Mannose-appended 5,15-diazaporphyrin for photodynamic therapy	63
Sumanene–carbazole conjugate with push–pull structure and its chemoreceptor application	58
Facile tin(ii)-catalyzed synthesis of N-heterocycles from dicarboxylic acids and arylamines	55
Silver-mediated radical oxytrifluoromethylation of unsaturated carboxylic acids for the synthesis of γ-trifluoromethylthio lactones	53
Flavin-induced charge separation in transmembrane model peptides	52
Anthracene-isatoic anhydride hybrids for bioconjugation: chromophores with nucleophile dependent response	51
Electrochemical alkylation of C(sp2)–H bonds via halogen-atom transfer (XAT) from alkyl iodides	51
Total synthesis, stereochemical assignment, and biological evaluation of opantimycin A and analogues thereof	50
Oxa-azabenzobenzocyclooctynes (O-ABCs): heterobiarylcyclooctynes bearing an endocyclic heteroatom	50
Transition metal-free one-pot tandem chemoselective reduction and cyclization of 3/5-(2-nitrophenyl)-1H-pyrazoles using sodium dithionite	49
N-Functionalized fluorophores: detecting urinary albumin and imaging lipid droplets	49
Genome mining and heterologous expression reveal streptacidin, a new lasso peptide from Streptacidiphilus jiangxiensis	48
Metal-free oxidative formal C(sp2)–H arylation of cyclopentene-1,3-diones with β-naphthols	48
Synthesis of imidazolocoumarins by the amide-directed oxidative cyclisation of enol-Ugi derivatives	47
Oxidative decarboxylative ammonium hypoiodite-catalysed dihydrobenzofuran synthesis	47
α-Alkylation of ketones with primary alcohols by an active non-noble metal Cu/CuOx catalyst	47
Practical synthesis of unsymmetrical disulfides promoted by bromodimethylsulfonium bromide	46

Access to functionalized 2-pyrones through cascade reactions of α-halothioesters involving DBU-derived ammonium ylides	44
Fluorescent α-amino acids via Heck–Matsuda reactions of phenylalanine-derived arenediazonium salts	44
A substrate-induced dual utilization cascade reaction of N-alkyl anilines: highly site-selective sustainable synthesis of chromeno[4,3-b]quinolin-6-ones	44
Direct formylation of phenols using difluorocarbene as a safe CO surrogate	44
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A novel synthetic method for backbone-cyclized polypeptide POL7080 with the help of hydrophobic-support materials	43
A poly-pseudorotaxane constructed by threading pillar[5]arene onto an ion-pair recognition-based calix[4]pyrrole supramolecular polymer	43
Microwave-assisted palladium catalysed C–H acylation with aldehydes: synthesis and diversification of 3-acylthiophenes	42
An electron donor–acceptor complex-initiated C–H trifluoromethylation and perfluoroalkylation of enamides and quinoxalinones	41
The boron effect on radical difluoromethylation of N-sulfonyl cyclic ketimines	41
Structural variation of the 3-acetamido-4,5,6-trihydroxyazepane iminosugar through epimerization and C-alkylation leads to low micromolar HexAB and NagZ inhibitors	41
Au(iii)/TPPMS-catalyzed Friedel–Crafts benzylation of deactivated N-alkylanilines in water	41
Synthesis of 7-hydroxydibenzopyran-6-ones via benzannulation of coumarins	40
Facile construction of C,N-disulfonated 5-amino pyrazoles through an iodine-catalyzed cascade reaction	40
Rapid paper-based optical sensing of Spilosoma obliqua nucleopolyhedrovirus via ester hydrolysis	40
Complexation of specific residues by carboxylatopillar[6]arene for improving the zymolytic stability of arginine-containing peptides	39
Nonsilyl bicyclic secondary amine catalyzed Michael addition of nitromethane to β,β-disubstituted α,β-unsaturated aldehydes	39
Photoredox-catalysed radical difluoromethylation/cyclization of N-acryloyl-2-arylbenzimidazole to access CF2H-substituted benzimidazo[2,1-a]isoquinolin-6(5H)-ones	39
Deoxyfluorination tunes the aggregation of cellulose and chitin oligosaccharides and highlights the role of specific hydroxyl groups in the crystallization process	39
Concise total synthesis of (±)-applanatumol Y	38
Correction: Formal synthesis of cyclotheonellazole A	38
Synthesis of the matriglycan hexasaccharide, -3Xylα1-3GlcAβ1-trimer and its interaction with laminin	37
Fluoride ion coordination-induced turn-on fluorescence of tailoredN-methyl N-confused tripyrromonomethene analogues	37
DNA preference of indenoisoquinolines: a computational approach	36
Radical coupling of aryl halides to arenes facilitated by Ni(COD)(DQ) and other nickel sources	35
Design and synthesis of fluorescent-dye-labeled nucleotide with a new cleavable azo linker for DNA sequencing by synthesis	35
Chemoselective, osmium-free, dihydroxylation/oxidative cleavage of heteroaryl isoprenes by a contemporary Malaprade reaction	34
Glyoxylic acid monohydrate promoted reductive addition of sodium sulfinates to pillar[4]arene[1]quinone	34
Highly oxygenated steroids with immunosuppressive activity from Solanum undatum	33
3,5-Di(trifluoromethyl)phenyl(cyano)iodonium triflate as a novel and potential activator for p-tolyl thioglycoside donors	33
Visible-light-mediated radical difunctionalization of alkenes with aromatic aldehydes	33
Synthesis of 3-sulfonylisoindolin-1-ones from olefinic amides and sodium sulfinates via electrooxidative tandem cyclization	33
Dithioallyl cation (3 + 2) cycloadditions under aprotic reaction conditions: rapid access to spiro-fused cyclopentane scaffolds	32
Radical alkylation of acrylamides with peroxides to access mono/dialkylated fused N-heterocycles	32
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Albumin–ruthenium catalyst conjugate for bio-orthogonal uncaging of alloc group	32
Highly diastereo- and enantioselective synthesis of multisubstituted allylic amino acid derivatives by allylic alkylation of a chiral glycine-based nickel complex and vinylethylene carbonates	32
Hydroboration of vinylsilanes providing diversity-oriented hydrophobic building blocks for biofunctional molecules	32
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Front cover	31
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A rhodium-catalyzed cascade C–H activation/annulation strategy for the expeditious assembly of pyrrolidinedione-fused 1,2-benzothiazines	30
Lewis acid mediated allylation of vinyl diazonium ions by allylstannanes	30

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Chemistry of installing epitranscriptomic 5-modified cytidines in RNA oligomers	30
On the divergent reactivity of allenylstannanes generated from the O-directed free radical hydrostannation reaction of (±)-trans-3-(2-phenylcyclopropyl)prop-2-yn-1-ol. EPR evidence for the reve	29
Flexible and rigid “chirally distorted” π-systems: binaphthyl conjugates as organic CPL-active chromophores	29
(Dimethylamino)methylene hydantoins as building blocks in the synthesis of oxoaplysinopsins and parabanic acids with antifungal activity	29
Visible light-promoted cascade synthesis of pyrazolidinones via N-aryl glycine and azomethine imines	29
Synthesis of mixed phosphorotrithioates via thiol coupling with bis(diisopropylamino)chlorophosphine and sulphenyl chloride	28
Butterflyene: an entry into an aesthetically pleasing carbocycle via a Diels–Alder reaction on a tetrasubstituted olefin	28
Pd-Catalysed [3 + 2]-cycloaddition towards the generation of bioactive bis-heterocycles/identification of COX-2 inhibitors via in silico analysis	28
New reagent space and new scope for the Castagnoli–Cushman reaction of oximes and 3-arylglutaconic anhydrides	28
Green and efficient synthesis of pure β-sulfonyl aliphatic sulfonyl fluorides through simple filtration in aqueous media	28
Ligand release from silicon phthalocyanine dyes triggered by X-ray irradiation	28
Visible light-mediated synthesis of quinazolinones and benzothiadiazine-1,1-dioxides utilizing aliphatic alcohols	27
Design, synthesis, and biological evaluation of multiple F-18 S1PR1 radiotracers in rodent and nonhuman primate	27
Deciphering substitution effects on reductive hydroalkoxylation of alkynyl aminols for stereoselective synthesis of morpholines and 1,4-oxazepanes: total synthesis of tridemorph and fenpropimorph	27
Aggregation induced emission and volatile acid vapour sensing in acridine appended poly (aryl ether) based low molecular weight organogelator	27
An efficient and straightforward approach for accessing thionoesters via palladium-catalyzed C–N cleavage of thioamides	27
Bioorthogonal fluorogenic chemistry using a light-activated tetrazine	27
Light-driven reductive cyclization catalyzed by vitamin B 12 -based artificial photoenzymes	27
Copper( ii ) nanodots stabilized on Cassia fistula galactomannan: preparation and catalytic applicatio	26
Design, synthesis and evaluation of antiproliferative effects of ferritin-targeted degraders	26
Visible light-promoted C3–H alkoxycarbonylation of quinoxalin-2(1 H )-ones or coumarins with alkyloxalyl chlorides	26
Total synthesis of (−)-griseocazine D2 and D3	25
Mechanochemical arylative detrifluoromethylation of trifluoromethylarenes	25
Recent applications of Cyrene as a chiral synthon	25
Polymeric nanostructures based on azobenzene and their biomedical applications: synthesis, self-assembly and stimuli-responsiveness	25
Photocatalyst-free synthesis of quinazolinones from o -aminobenzamides and rongalite under visible light	25
Efficient synthesis of functionalized alkylidenephthalides, butenolides, pyranones, and isocoumarins via I 2	25
Complementary strategies for synthesis of sulfinamides from sulfur-based feedstock	25
Regioselective conjugate addition of isoxazol-5-ones to ethenesulfonyl fluoride	24
Amine adducts of triallylborane as highly reactive allylborating agents for Cu(i)-catalyzed allylation of chiral sulfinylimines	24
A mild one-pot transformation of nitroalkanes to ketones or aldehydes via a visible-light photocatalysis–hydrolysis sequence	24
Sequential regioselective arylation of pyrazolones with diaryliodonium salts	24
Synthesis of primary propargylic alcohols from terminal alkynes using rongalite as the C1 unit	24
Efficient construction of spirocyclopentane-1,3-dioxindoles via an annulation reaction of isocyanides and 3-methyleneoxindoles	24
Asymmetric synthesis of atropisomeric arylpyrazoles via direct arylation of 5-aminopyrazoles with naphthoquinones	24
BiCl3 catalyzed synthesis of 2-amino-1,4-naphthoquinones and 1,4-naphthoquinon-2-sulfides and one-pot sequential amine-arylation of 1,4-naphthoquinone	24
Recent advances in synthesis of stilbene derivativesviacross-coupling reaction	24
An efficient direct electrolysis method for the synthesis of 1,1,1,3,3,3-hexafluoroisopropyxy substituted imidazo[1,2-a]pyridines	24
Metallocenium incorporated charge-enhanced thiourea catalysts	24
Mechanochemical deprotection of t -butoxycarbonyl (Boc) group using basic alumina	24
Direct C–H functionalisation of azoles via Minisci reactions	24
Palladium-catalyzed α-arylation of sulfoxonium ylides with aryl fluorosulfates	23
Development of fluorophoric [2]pseudorotaxanes and [2]rotaxane: selective sensing of Zn(ii)	23
Copper-catalyzed cross-coupling reaction of epoxides with allyl boron ester	23
Conformationally rigid, π-extended annulated porphyrinoids derived from the naphthobipyrrole motif	23
Regioselective synthesis of enantiopure 1,2- and 1,3-dispirooxindoles along with a DFT study	23
Site-selective benzylic C–H hydroxylation in electron-deficient azaheterocycles	23
Self-assembly of azamacrocyclic ligands into vesicular structures: from design to functional properties and applications	23
Diazo compounds: synthesis, carbene generation and reactivity	23
C–H activation-initiated spiroannulation reactions and their applications in the synthesis of spirocyclic compounds	23
Light-induced ligand-to-metal charge transfer of Fe(iii)-OR species in organic synthesis	22
Carboxylate migration from ethyl cyanoformate to methylene: rapid access toward pyrrolo[1,2- a ]pyrazines	22
Recent advances in the multicomponent synthesis of pyrazoles	22
Trivalent dialkylaminopyridine-catalyzed site-selective mono-O-acylation of partially-protected pyranosides	22
Photochemistry of 2-(2-formylphenyloxy)acetic acid derivatives: synthesis of hydroxychromanones and benzofuranones	22
Correction: C–H bond cyanation: electrochemical synthesis of phenylbenzimidoyl cyanide derivatives	22
Base-mediated synthesis of aryl enol ethers from α-aryl allylic alcohols and arylsulfonium salts	22
Synthesis of fused 3-trifluoromethyl-1,2,4-triazoles via base-promoted [3 + 2] cycloaddition of nitrile imines and 1H-benzo[d]imidazole-2-thiols	22
A cationic AIEgen and hexametaphosphate based simple and convenient fluorometric assay for alkaline phosphatase and its inhibitor	22
ortho-Nitro-substituted diaryliodonium salts enabled regioselective cyclization of arylcarboxylic acids toward 3,4-naphthocoumarins	22
Advances in the synthesis of rearranged homoisoflavonoids	22
Recent progress in the homogeneous gold-catalysed cycloisomerisation reactions	22
Intermolecular hydrogen bonding behavior of amino acid radical cations	21
Recent advances in Ugi reaction and its post-transformation strategies for crafting diverse indole frameworks	21
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InCl3 catalyzed simultaneous reductive sulfoximination and O-silylation: synthesis of silyloxy benzylsulfoximine	21
Sarcanolides C–E: three new lindenane sesquiterpenoid dimers with anti-inflammatory activities from Sarcandra glabra	21
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Controllable conformation and reactivity of bicyclic α-methylene cyclopentanones and their NF-κB pathway inhibitory activity	21
Combinatorial synthesis of substituted pyrazolo-fused quinazolines by the Rh(iii)-catalyzed [5 + 1] annulation of phenyl-1H-pyrazol-5-amine with alkynoates and alkynamides	21
A mitochondria-targeted colorimetric and NIR ratiometric fluorescent probe for biothiols with large Stokes shift based on thiol–chromene click reaction	21
Transition metal-free functionalization of 2-oxindolesviasequential aldol and reductive aldol reactions using rongalite as a C1 reagent	21
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A facile approach to phenothiazinones via catalytic aerobic oxidation: discovery of an antiproliferative agent	21
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K2CO3-mediated annulation of 1,3-acetonedicarboxylates with 2-fluoro-1-nitroarenes: synthesis of indoles	20
Two short approaches to the COVID-19 drug β-d-N4-hydroxycytidine and its prodrug molnupiravir	20
Synthesis of dihydrogambirtannine by alkyne [2 + 2 + 2]-cyclotrimerisation	20
Multifunctional supramolecular receptors: aqueous ion recognition, HCl sensing and cytotoxic potential	20

Submicromolar fluorescence ‘turn-on’ detection of fluoride anions using meso-(tetra-aryl) calix[4]pyrrole	20
Synthesis of linear O-aryl carbamates and S-thiocarbamates via benign T3P-mediated condensation of phenols and thiols with amines and carbon dioxide	20
Correction: An NNN Pd(ii) pincer complex with 1,1-diaminoazine: a versatile catalyst for acceptorless dehydrogenative coupling reactions	20
ANRORC type rearrangement/intermolecular cyclocondensation cascade of 5,6-dicyano-3-(2-oxo-2-ethyl)pyrazin-2(1H)-ones with hydrazine hydrate for the synthesis of 2-(pyrazol-3-yl)imidazo[4,5-	20
Forging the tricyclic core framework of euphordraculoate B via a Barbier-type allyl addition	20
Metal-free aminofluorination of α-diazo 2H-benzopyran-4-one: convenient access to β-fluoramides	20
Multistep synthesis of cationic lipid-like compounds based on a difluorotetrahydropyridine scaffold as amphiphilic nanocarriers	20
Multicomponent synthesis of pyrrolo[2,1-a]isoindolylidene-malononitrile (PIYM) fluorophores and their photophysical properties	20
Electrochemically enabled decyanative C(sp3)–H oxygenation of N-cyanomethylamines to formamides	20
ION Thallos-HTL: a fluorescent thallium indicator that enables cell-selective and localizable thallium flux assays	20
New P,Nsp3ligands for palladium-catalyzed asymmetric allylic substitutions	20
Development of an activity-based chemiluminogenic probe for γ-glutamylcyclotransferase	20
Copper-catalyzed enantioselective propargylic [3 + 2] cycloaddition: access to oxygen heterocycles featuring a CF3-substituted quaternary stereocenter	20
Damage of amino acids by aliphatic peroxyl radicals: a kinetic and computational study	19
Alkylation and silylation of α-fluorobenzyl anion intermediates	19
Synthesis and cholinesterase inhibitory activity study of Amaryllidaceae alkaloid analogues with N-methyl substitution	19
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Transition-metal-free alkylation strategy: facile access to alkylated oxindoles via alkyl transfer	19
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“Cation Pool” generated from DMSO and 1,2-dihaloethanes and their application in organic synthesis	19
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HFIP-mediated C-3-alkylation of indoles and synthesis of indolo[2,3-b]quinolines & related natural products	19
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Exploring α-electron-deficiency-induced [1,2]-fluorine migration	19
Theoretical study of the rearrangement reaction in bisorbicillinoid biosynthesis: insights into the molecular mechanisms involved	19
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A HMPA–H2O mediated oxygenative carbocyclization of 2-alkynylphenyl-substituted p-quinone methides to indenones	18
Straightforward access to α-carbonyloxy esters and β-keto thioethers from aryldiazoacetates	18
Persulfate-nitrogen doped graphene mixture as an oxidant for the synthesis of 3-nitro-4-aryl-2H-chromen-2-ones from aryl alkynoate esters and nitrite	18
Unusual immunosuppressive pyridine-containing bisnor- (c23), tetranor- (c21) and pentanor- (c20) sesterterpenoids from Tibetan Leucosceptrum ca	18
Transition metal-free, base mediated one-pot approach for the construction of the benzo[b][1,4,5]oxathiazepine 1-oxide core	18
Photoinduced halogen-bonding enabled synthesis of oxindoles and isoindolinones from aryl iodides	18
Nickel-catalyzed reductive cross-coupling of aziridines and benzyl chlorides	18
Access to 4-methylene-phospholenes through BF3·Et2O catalyzed isomerization of 3,4-dimethylphosphole sulfides	18
Diastereoselective synthesis of tetrahydropyranes via Ag(i)-initiated dimerization of cinnamyl ethers	18
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Computational discoveries of reaction mechanisms: recent highlights and emerging challenges	18
Visible-light promoted oxidative annulation of 2-naphthols with phenylglyoxal monohydrates toward hydroxy-naphthofuranone and its derivatives	18
Substituted anilides from chitin-based 3-acetamido-furfural	18
Pyrrolizinofluorene-embedded dithiacalixcorrole(1.0.1.1)s	18
Combining local conformational preferences and solvophobic effects in helical aromatic oligoamide foldamers	18
Computational insights into the origins of regio- and enantioselectivities in palladium-catalyzed allylic substitution reactions	18
Atropisomerism about aryl–C(sp3) bonds: chemically driven rotational pathway in cannabidiol derivatives	18
Organocatalytic formal [3 + 3] cyclization of α-(6-indolyl) propargylic alcohols	18
Racemic peptide assembly boosts biocatalysis	18
Enhanced molecular binding affinity toward aromatic dications by anthracene-derived crown ethers in water	18
Synthesis of enantioenriched spirocyclic 2-arylpiperidines via kinetic resolution	18
Samarium diiodide/samarium-mediated direct deoxygenative hydroborylation of ketones with hydroborane esters	18
Direct transition-metal-free synthesis of 2-heteroaryl-4-quinolones via ANRORC type rearrangement of 3-(2-(2-nitrophenyl)-2-oxoethyl)quinoxalin-2(1	18
Reductive cross-coupling of N-acyl pyrazole and nitroarene using tetrahydroxydiboron: synthesis of secondary amides	18
Computational studies on the possible formation of glycine via open shell gas-phase chemistry in the interstellar medium	17
Supramolecular assembly of pyrene–DNA conjugates: influence of pyrene substitution pattern and implications for artificial LHCs	17
Coordination complexes of PIII-doped heterobuckybowls and their applications in catalysis	17
Development of a novel phosphoramidite-selenide ligand for Pd-catalyzed asymmetric allylic substitution	17
Diastereoselective synthesis of trans-2,3-dihydroindoles via formal [4 + 1] annulation reactions of a sulfonium ylide	17
Rhodium(iii)-catalyzed C–H alkylation of arylhydrophthalazinediones with α-Cl ketones as sp3-carbon alkylated agents	17
Catalyst-controlled regiodivergent Friedel–Crafts reactions of 1-naphthols with 2,3-dioxopyrrolidines: synthesis of polycyclic 2-pyrrolidinones	17
An overview of metal-free sustainable nitrogen-based catalytic knoevenagel condensation reaction	17
Asymmetric total syntheses of passifetilactones A, C, E and 4-epi-passifetilactone B	17
The chemistry of 2-hydroxy-β-nitrostyrenes: versatile intermediates in synthetic organic chemistry	17
Copper-catalyzed 4-HO-TEMPOH mediated phosphorylation of alkenes	17
Cyclopropanation reactions by a class I unspecific peroxygenase	17
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4,9- and 4,10-Substituted pyrenes: synthesis, successful isolation, and optoelectronic properties	17
SnCl4-mediated one-pot synthesis of 2,4,5-trisubstituted thiazoles from nitro-substituted donor–acceptor cyclopropanes and thioamides	17
Synthesis of tetracyclic dibenzo[b,f][1,4]oxazepine-fused β-lactams via visible-light-induced Staudinger annulation	17
BF3·OEt2-catalyzed/mediated alkyne cyclization: a comprehensive review of heterocycle synthesis with mechanistic insights	17
Phthalimide-based sulfur transfer reagents for the preparation of biologically relevant trisulfides	17
Photo-induced radical transformations of tosyl cyanide	17
Well-defined cobalt(ii)-catalyzed synthesis of perimidine derivatives via acceptorless dehydrogenative annulation	17
Ribosomal incorporation of N -acetyl-3,5-bis(chloromethyl)benzylthio- l -alanine for developing an mRN	17
Asymmetric magnesium catalysis for important chiral scaffold synthesis	17
Cu-catalyzed convenient synthesis of 2-trifluoromethyl benzimidazoles via cyclization of o-phenylenediamines with hexafluoroacetylacetone	17
Manganese(iii)-promoted highly stereoselective phosphorylation of acyclic tertiary enamides to synthesize E-selective β-phosphoryl enamides	17
On the potential intermediacy of PhIBr 2 as a brominating agent	17
Monoterpenoid selenophenes derived from (−)-carvone with GPx-like activity	17
TsOH-catalyzed acyl migration reaction of the Bz-group: innovative assembly of various building blocks for the synthesis of saccharides	17
Synthesis of tetrahydropyrrolo[1,2- a ]quinolinone analogues via CoCl 2	17
Recent advances in photocatalytic and transition metal-catalyzed synthesis of disulfide compounds	16
Electrochemically enabled oxidative aromatization of pyrazolines	16
TiCl4-mediated deoxygenative reduction of aromatic ketones to alkylarenes with ammonia borane	16
Recent advances in 3-aminoindazoles as versatile synthons for the synthesis of nitrogen heterocycles	16
Serine-mediated hydrazone ligation displaying insulin-like peptides on M13 phage pIII	16
Divergent synthesis of two types of indolizines from pyridine-2-acetonitrile, (hetero)arylglyoxal, and TMSCN	16
Cu(OAc)2/DABCO-mediated domino reaction of vinyl malononitriles with cyclic sulfamidate imines: access to 6-hydroxyaryl-2-aminonicotinonitriles	16