Faraday Discussions

Article	Citations
MOFs industrialization: a complete assessment of production costs	78
Is reducing new particle formation a plausible solution to mitigate particulate air pollution in Beijing and other Chinese megacities?	78
The state of the field: from inception to commercialization of metal–organic frameworks	74
Trends in the thermal stability of two-dimensional covalent organic frameworks	61
Avoiding high ozone pollution in Delhi, India	50
Hybrid scanning electrochemical cell microscopy-interference reflection microscopy (SECCM-IRM): tracking phase formation on surfaces in small volumes	48
Raman spectroscopy of GaSe and InSe post-transition metal chalcogenides layers	46
Introductory lecture: air quality in megacities	44
Spiers Memorial Lecture: Coordination networks that switch between nonporous and porous structures: an emerging class of soft porous crystals	41
Can 3D electron diffraction provide accurate atomic structures of metal–organic frameworks?	39
Formation and growth of sub-3 nm particles in megacities: impact of background aerosols	36
Biodegradation of graphene materials catalyzed by human eosinophil peroxidase	34
Integration of aprotic CO2 reduction to oxalate at a Pb catalyst into a GDE flow cell configuration	33
Effect of thermal treatment on the stability of Na–Mn–W/SiO2 catalyst for the oxidative coupling of methane	31
The role of solvation in proton transfer reactions: implications for predicting salt/co-crystal formation using the ΔpKa rule	30
Renewable carbon feedstock for polymers: environmental benefits from synergistic use of biomass and CO2	30
Estimating the accuracy of the MARTINI model towards the investigation of peripheral protein–membrane interactions	29
Graphitic carbon nitrides as platforms for single-atom photocatalysis	28
Stability and universal encapsulation of epitaxial Xenes	28
Sources of non-methane hydrocarbons in surface air in Delhi, India	26
White graphene quantum dots as electrochemical sensing platform for ferritin	26
Identifying the liquid and glassy states of coordination polymers and metal–organic frameworks	25
Towards MOFs’ mass market adoption: MOF Technologies’ efficient and versatile one-step extrusion of shaped MOFs directly from raw materials	25
Electrochemical exfoliation of graphite in H2SO4, Li2SO4 and NaClO4 solutions monitored in situ by Raman microscopy and spectroscopy	25
CO2 utilization in built environment via the PCO2 swing carbonation of alkaline solid wastes with different mineralogy	25

Why copper catalyzes electrochemical reduction of nitrate to ammonia	25
High-throughput cryo-EM structure determination of amyloids	25
Exploring the dynamics of Zr-based metal–organic frameworks containing mechanically interlocked molecular shuttles	24
Multiphase chemistry experiment in Fogs and Aerosols in the North China Plain (McFAN): integrated analysis and intensive winter campaign 2018	24
Controlling polymorphism in molecular cocrystals by variable temperature ball milling	24
Mechanistic in situ investigation of heterogeneous hydrogenation over Rh/TiO2 catalysts: selectivity, pairwise route and catalyst nature	23
Visualization of catalyst dynamics and development of a practical procedure to study complex “cocktail”-type catalytic systems	23
Crystal melting and vitrification behaviors of a three-dimensional nitrile-based metal–organic framework	23
The role of surface oxidation and Fe–Ni synergy in Fe–Ni–S catalysts for CO2 hydrogenation	23
Time-resolved pump–probe spectroscopy with spectral domain ghost imaging	23
What stress components drive mechanochemistry? A study of ZDDP tribofilm formation	23
Concluding remarks: next generation nanoelectrochemistry – next generation nanoelectrochemists	23
Multi-channel photodissociation and XUV-induced charge transfer dynamics in strong-field-ionized methyl iodide studied with time-resolved recoil-frame covariance imaging	23
The role of temperature and adsorbate on negative gas adsorption transitions of the mesoporous metal–organic framework DUT-49	22
Unified quantum theory of electrochemical kinetics by coupled ion–electron transfer	22
Low-energy electron irradiation induced synthesis of molecular nanosheets: influence of the electron beam energy	22
Surface stability of perovskite oxides under OER operating conditions: a first principles approach	22
Photoelectrochemical alcohol oxidation by mixed-linker metal–organic frameworks	21
Multiple pathways in NaCl homogeneous crystal nucleation	21
iR drop in scanning electrochemical cell microscopy	21
Long-term trends in the contribution of PM2.5sources to organic carbon (OC) in the Los Angeles basin and the effect of PM emission regulations	20
Effect of dynamic correlation on the ultrafast relaxation of uracil in the gas phase	20
Tracer-based characterization of source variations of PM2.5 and organic carbon in Shanghai influenced by the COVID-19 lockdown	20
Cryomicroscopy in situ: what is the smallest molecule that can be directly identified without labels in a cell?	20
Manipulating twisted electrons in strong-field ionization	19
Molecular interactions of the M and E integral membrane proteins of SARS-CoV-2	19
Understanding entrapped molecular photosystem and metal–organic framework synergy for improved solar fuel production	19
Capturing spatially resolved kinetic data and coking of Ga–Pt supported catalytically active liquid metal solutions during propane dehydrogenationin situ	19
Formation sequence of solid electrolyte interphases and impacts on lithium deposition and dissolution on copper: an in situ atomic force microscopic study	19
Interactions of polymyxin B with lipopolysaccharide-containing membranes	19
Atomistic insight in the flexibility and heat transport properties of the stimuli-responsive metal–organic framework MIL-53(Al) for water-adsorption applications using molecular simulations	18
Mapping static core-holes and ring-currents with X-ray scattering	18
Cooperative and synchronized rotation in motorized porous frameworks: impact on local and global transport properties of confined fluids	18
Electrochemically probing exciton transport in monolayers of two-dimensional semiconductors	18
Variability of physical meteorology in urban areas at different scales: implications for air quality	18
Concluding remarks: current and next generation MOFs	18
Gently does it!: in situ preparation of alkali metal–solid electrolyte interfaces for photoelectron spectroscopy	17
Reaction mechanism of low-temperature catalysis by surface protonics in an electric field	17
Air quality and health benefits of China’s current and upcoming clean air policies	17
Impact of metastable defect structures on carrier recombination in solar cells	17
MOF matrix isolation: cooperative conformational mobility enables reliable single crystal transformations	17
Core–shell graphene oxide–polymer hollow fibers as water filters with enhanced performance and selectivity	17
A component-specific exposure–mortality model for ambient PM2.5 in China: findings from nationwide epidemiology based on outputs from a chemical transport model	17
The persistence of a proxy for cooking emissions in megacities: a kinetic study of the ozonolysis of self-assembled films by simultaneous small and wide angle X-ray scattering (SAXS/WAXS) and Raman mi	17
Antimicrobial peptides: mechanism of action and lipid-mediated synergistic interactions within membranes	17
Why conductivity is not always king – physical properties governing the capacitance of 2D metal–organic framework-based EDLC supercapacitor electrodes: a Ni3(HITP)2 case study	17
Esterification catalyzed by an efficient solid acid synthesized from PTSA and UiO-66(Zr) for biodiesel production	17
Spiers Memorial Lecture: Next generation chalcogenide-based absorbers for thin-film solar cells	17
Insight into the mechanism of the water–gas shift reaction over Au/CeO2 catalysts using combined operando spectroscopies	17
The unexpected dominance of secondary over primary nucleation	16

Multi-nuclear, high-pressure, operando FlowNMR spectroscopic study of Rh/PPh3 – catalysed hydroformylation of 1-hexene	16
Printable hexagonal boron nitride ionogels	16
Electrochemical carbon dioxide reduction in ionic liquids at high pressure	16
Using highly time-resolved online mass spectrometry to examine biogenic and anthropogenic contributions to organic aerosol in Beijing	16
Determination of excited state molecular structures from time-resolved gas-phase X-ray scattering	16
The “η-sweet-spot” (ηmax) in liquid-assisted mechanochemistry: polymorph control and the role of a liquid additive as either a catalyst or an inhibitor in resonant acoustic mi	15
Computational design of graphitic carbon nitride photocatalysts for water splitting	15
Spiers Memorial Lecture: Catalytic activation of molecular nitrogen for green ammonia synthesis: introduction and current status	15
Transient resonant Auger–Meitner spectra of photoexcited thymine	15
Spiers Memorial Lecture: Mechanochemistry, tribochemistry, mechanical alloying – retrospect, achievements and challenges	15
Quantum electronic coherences by attosecond transient absorption spectroscopy: ab initio B-spline RCS-ADC study	15
Chiral and robust Zr(iv)-based metal–organic frameworks built from spiro skeletons	15
Improved photodegradation of anionic dyes using a complex graphitic carbon nitride and iron-based metal–organic framework material	15
Molecular characterization of size-segregated organic aerosols in the urban boundary layer in wintertime Beijing by FT-ICR MS	15
Monolithic metal–organic frameworks for carbon dioxide separation	15
The micromechanical model to computationally investigate cooperative and correlated phenomena in metal–organic frameworks	15
The diverse chemistry of protoplanetary disks as revealed by JWST	15
Spiers Memorial Lecture. Next generation nanoelectrochemistry: the fundamental advances needed for applications	15
Understanding crystal nucleation mechanisms: where do we stand? General discussion	15
Electro-mechanochemical approach towards the chloro sulfoximidations of allenes under solvent-free conditions in a ball mill	15
Stereoisomer-dependent unimolecular kinetics of 2,4-dimethyloxetanyl peroxy radicals	14
Photoresponsive frameworks: energy transfer in the spotlight	14
Cryo-EM samples of gas-phase purified protein assemblies using native electrospray ion-beam deposition	14
An evaluation of source apportionment of fine OC and PM2.5by multiple methods: APHH-Beijing campaigns as a case study	14
A high-throughput screening of metal–organic framework based membranes for biogas upgrading	14
Impact of antimicrobial peptides on E. coli-mimicking lipid model membranes: correlating structural and dynamic effects using scattering methods	14
Molecular fragmentation as a way to reveal early electron dynamics induced by attosecond pulses	14
The chemical inventory of the inner regions of planet-forming disks – the JWST/MINDS program	13
The rise of electrochemical NAPXPS operated in the soft X-ray regime exemplified by the oxygen evolution reaction on IrOx electrocatalysts	13
Spiers Memorial Lecture: Assembly-based pathways of crystallization	13
Antimicrobial peptide activity in asymmetric bacterial membrane mimics	13
Insights into soft short circuit-based degradation of lithium metal batteries	13
Rapid thermal annealing process for Se thin-film solar cells	13
On the completeness of three-dimensional electron diffraction data for structural analysis of metal–organic frameworks	13
Combination of theoretical and in situ experimental investigations of the role of lithium dopant in manganese nitride: a two-stage reagent for ammonia synthesis	13
Mineral carbonation for serpentine mitigation in nickel processing: a step towards industrial carbon capture and storage	13
Simulation of primary and secondary particles in the streets of Paris using MUNICH	13
Photoluminescence assessment of materials for solar cell absorbers	13
Enhanced liquid phase exfoliation of graphene in water using an insoluble bis-pyrene stabiliser	13
The application of machine learning for predicting the methane uptake and working capacity of MOFs	13
Crossed-beam and theoretical studies of multichannel nonadiabatic reactions: branching fractions and role of intersystem crossing for O(3P) + 1,3-butadiene	13
Coupled nuclear–electronic decay dynamics of O2 inner valence excited states revealed by attosecond XUV wave-mixing spectroscopy	12
Enhanced bio-production from CO2by microbial electrosynthesis (MES) with continuous operational mode	12
Manipulation of amorphous precursors to enhance zeolite nucleation	12
Photomechanochemical control over stereoselectivity in the [2 + 2] photodimerization of acenaphthylene	12
Inclusion of multiple cycling of potential in the deep neural network classification of voltammetric reaction mechanisms	12
Nanopore-based measurement of the interaction of P450cam monooxygenase and putidaredoxin at the single-molecule level	12
Hydrophobic thiol coatings to facilitate a triphasic interface for carbon dioxide reduction to ethylene at gas diffusion electrodes	12
Carbon nanospike coated nanoelectrodes for measurements of neurotransmitters	12
Can you break the oxo-wall? A multiconfigurational perspective	12
A zeolite crystallisation model confirmed by in situ observation	12
Influence of flexible side-chains on the breathing phase transition of pillared layer MOFs: a force field investigation	12
Mechanochemical reaction kinetics scales linearly with impact energy	12
Hydrogenation of ethylene over palladium: evolution of the catalyst structure byoperandosynchrotron-based techniques	12
The impact of AlphaFold2 on experimental structure solution	12
Tuning the degree of CO2 activation by carbon doping Cun− (n = 3–10) clusters: an IR spectroscopic study	11
New directions in the analysis of buried interfaces for device technology by hard X-ray photoemission	11
Predicting third-body collision efficiencies for water and other polyatomic baths	11
Strategies for picking membrane-associated particles within subtomogram averaging workflows	11
Time-resolved photoluminescence studies of perovskite chalcogenides	11
Towards improving the capacity of UiO-66 for antibiotic elimination from contaminated water	11
THz non-linear optical response in cuprates: predominance of the BCS response over the Higgs mode	11
Nanostructured carbon-fiber surfaces for improved neurochemical detection	11
Spiers Memorial Lecture: CO2 utilization: why, why now, and how?	11
A first-principles machine-learning force field for heterogeneous ice nucleation on microcline feldspar	11
A multiscale modelling approach to elucidate the mechanism of the oxygen evolution reaction at the hematite–water interface	11
Resolving multiphoton processes with high-order anisotropy ultrafast X-ray scattering	11
Multifunctional coatings of exfoliated and reassembled graphite on cellulosic substrates	10
Structural changes in the model of the outer cell membrane of Gram-negative bacteria interacting with melittin: an in situ spectroelectrochemical study	10
Mechanosynthesis and photophysics of colour-tunable photoluminescent group 13 metal complexes with sterically demanding salen and salophen ligands	10
Adsorber heat exchanger using Al-fumarate beads for heat-pump applications – a transport study	10
Caveolin induced membrane curvature and lipid clustering: two sides of the same coin?	10
Polyaniline nanowire arrays generated through oriented mesoporous silica films: effect of pore size and spectroelectrochemical response	10
CO2reduction to acetic acid on the greigite Fe3S4{111} surface	10
Nucleation in sessile saline microdroplets: induction time measurement via deliquescence–recrystallization cycling	10
Heterogeneity of cell membrane structure studied by single molecule tracking	10
Insights into air pollution chemistry and sulphate formation from nitrous acid (HONO) measurements during haze events in Beijing	10
Curing time: a temporally explicit life cycle CO2 accounting of mineralization, bioenergy, and CCS in the concrete sector	10
Diurnal and weekly patterns of primary pollutants in Beijing under COVID-19 restrictions	10
Structure and anomalous underscreening in ethylammonium nitrate solutions confined between two mica surfaces	10

Solid-state cross-coupling reactions of insoluble aryl halides under polymer-assisted grinding conditions	10
Function from configurational degeneracy in disordered framework materials	10
Strong-field induced fragmentation and isomerization of toluene probed by ultrafast femtosecond electron diffraction and mass spectrometry	10
The philosophy of carbon: meso-entropy materials	9
Possible embryos and precursors of crystalline nuclei of calcium carbonate observed by liquid-cell transmission electron microscopy	9
Fine-tuning non-covalent interactions between hybrid metal-oxo clusters and proteins	9
Asia Pacific road transportation emissions, 1900–2050	9
The structural pathway from its solvated molecular state to the solution crystallisation of the α- and β-polymorphic forms of para amino benzoic acid	9
Ultrafast branching in intersystem crossing dynamics revealed by coherent vibrational wavepacket motions in a bimetallic Pt(ii) complex	9
Addressing the uncertainty of DFT-determined hydrogenation mechanisms over coinage metal surfaces	9
Methanol synthesis from CO2and H2using supported Pd alloy catalysts	9
Electron scattering properties of biological macromolecules and their use for cryo-EM map sharpening	9
The impact of antibacterial peptides on bacterial lipid membranes depends on stage of growth	9
A post-deposition annealing approach for organic residue control in TiO2 and its impact on Sb2Se3/TiO2 device performance	9
Fingerprinting fragments of fragile interstellar molecules: dissociation chemistry of pyridine and benzonitrile revealed by infrared spectroscopy and theory	9
Conversion of CO2 and small alkanes to platform chemicals over Mo2C-based catalysts	9
Spiers Memorial Lecture : Carbon nanostructures by macromolecular design – from branched polyphenylenes to nanographenes and graphene nanoribbons	9
The origin of overpotential in lithium-mediated nitrogen reduction	9
Chemical conditions on Hycean worlds	9
Thermodynamic exploration of xenon/krypton separation based on a high-throughput screening	9
Developing a triple helix approach for CO2 utilisation assessment	9
A GPx-mimetic copper vanadate nanozyme mediates the release of nitric oxide fromS-nitrosothiols	9
Sol–gel synthesis of 2-dimensional TiO2: self-assembly of Ti–oxoalkoxy–acetate complexes by carboxylate ligand directed condensation	8
Hydrogenation of substituted nitroaromatics on non-noble metal catalysts: mechanistic insights to improve selectivity	8
Unimolecular isomerisation of 1,5-hexadiyne observed by threshold photoelectron photoion coincidence spectroscopy	8
High-resolution rovibrational and rotational spectroscopy of the singly deuterated cyclopropenyl cation, c-C3H2D+	8
Autoperforation of two-dimensional materials to generate colloidal state machines capable of locomotion	8
The influence of phosphatidylserine localisation and lipid phase on membrane remodelling by the ESCRT-II/ESCRT-III complex	8
First-principles spectroscopy of aqueous interfaces using machine-learned electronic and quantum nuclear effects	8
Molecular motion in the nanospace of MOFs upon gas adsorption investigated byin situRaman spectroscopy	8
Spiers Memorial Lecture: Understanding reaction mechanisms in heterogeneously catalysed reactions	8
Stoichiometry modulates the optoelectronic functionality of zinc phosphide (Zn3−xP2+x)	8
Out-of-equilibrium dynamics driven by photoinduced charge transfer in CsCoFe Prussian blue analogue nanocrystals	8
Corrosion inhibition in acidic environments: key interfacial insights with photoelectron spectroscopy	8
The role of oxygenated species in the catalytic self-coupling of MeOH on O pre-covered Au(111)	8
Understanding catalytic CO2 and CO conversion into methanol using computational fluid dynamics	8
Polymeric integration of structure-switching aptamers on transistors for histamine sensing	8
Improved microcanonical instanton theory	8
Time-resolved imaging of correlation-driven charge migration in light-induced molecular magnets by X-ray scattering	8
Visualizing optically-induced strains by five-dimensional ultrafast electron microscopy	8
Spiers Memorial Lecture: Theory of unimolecular reactions	8
Predicting observable infrared signatures of nanosilicates in the diffuse interstellar medium	8
Singlet oxygen formation in non-aqueous oxygen redox chemistry: direct spectroscopic evidence for formation pathways and reliability of chemical probes	7
A screening of results on the decay length in concentrated electrolytes	7
Elucidating the role of H2O in promoting the formation of methacrylic acid during the oxidation of methacrolein over heteropolyacid compounds	7
Face-selective adsorption of a prochiral compound on the chiral pore-surface of a metal–macrocycle framework (MMF) directed towards stereoselective reactions	7
On the mechanism of calcium carbonate polymorph selection via confinement	7
Electronic relaxation of aqueous aminoazobenzenes studied by time-resolved photoelectron spectroscopy and surface hopping TDDFT dynamics calculations	7
Intermediate-spin iron(iv)-oxido species with record reactivity	7
Electrochemical characterization of individual oil micro-droplets by high-frequency nanocapacitor array imaging	7
Difference in ambient-personal exposure to PM2.5 and its inflammatory effect in local residents in urban and peri-urban Beijing, China: results of the AIRLESS project	7
Mechanism of ammonia synthesis on Fe3Mo3N	7
An experimental and theoretical investigation of the N(2D) + C6H6 (benzene) reaction with implications for the photochemical models of Titan	7
Simulating intergrowth formation in zeolite crystals: impact on habit and functionality	7
Pulsed electrolysis – explained	7
Dynamics over a Cu–graphite electrode during the gas-phase CO2 reduction investigated by APXPS	7
Evolution of the electrical double layer with electrolyte concentration probed by second harmonic scattering	7
Strong-field ionization of polyatomic molecules: ultrafast H atom migration and bond formation in the photodissociation of CH3OH	7
Supported FexNiy catalysts for the co-activation of CO2 and small alkanes	7
Mechanochemical solid-state vinyl polymerization with anionic initiator	7
Mechanochemical synthesis of non-stoichiometric copper sulfide Cu1.8S applicable as a photocatalyst and antibacterial agent and synthesis scalability verification	7
Interplay between interdiffusion and shape transformations in nanoalloys evolving from core–shell to intermixed structures	7
Shear-activated chemisorption and association of cyclic organic molecules	7
Hunting for interstellar molecules: rotational spectra of reactive species	7
The kesterite–stannite structural transition as a way to avoid Cu/Zn disorder in kesterites: the exemplary case of the Cu2(Zn,Mn)SnSe4	7
Crystal growth of the core and rotated epitaxial shell of a heterometallic metal–organic framework revealed with atomic force microscopy	7
Towards novel probes for valence charges via X-ray optical wave mixing	7
Comprehensive rear surface passivation of superstrate Sb2Se3 solar cells via post-deposition selenium annealing treatments and the application of an electron blocking laye	7
Lipid specificity of the immune effector perforin	7
Cu segregation in Au–Cu nanoparticles exposed to hydrogen atmospheric pressure: how is fcc symmetry maintained?	6
Structural evolution under physical and chemical stimuli of metastable Au–Fe nanoalloys obtained by laser ablation in liquid	6
Engineering PtCu nanoparticles for a highly efficient methanol electro-oxidation reaction	6
Searches for bridged bicyclic molecules in space—norbornadiene and its cyano derivatives	6
A mechanochemical approach to the synthesis of sydnones and derivatives	6
Examining the accuracy of methods for obtaining pressure dependent rate coefficients	6
Single catalyst particle diagnostics in a microreactor for performing multiphase hydrogenation reactions	6
O2 reduction by iron porphyrins with electron withdrawing groups: to scale or not to scale	6
Advancing electrocatalytic nitrogen fixation: insights from molecular systems	6
Binding of the substrate analog methanol in the oxygen-evolving complex of photosystem II in the D1-N87A genetic variant of cyanobacteria	6
Plasmon-driven methanol oxidation on PtAg nanoalloys prepared by improved pulsed laser deposition	6
Quantum dynamics simulations of the thermal and light-induced high-spin to low-spin relaxation in Fe(bpy)3 and Fe(mtz)6	6
Attosecond electronic delay response in dielectric materials	6
Graphene-supported 2D cobalt oxides for catalytic applications	6
Effect of ionic conductivity of electrolyte on printed planar and vertical organic electrochemical transistors	6
Streamers feeding the SVS13-A protobinary system: astrochemistry reveals accretion shocks?	6
Towards sub-millisecond cryo-EM grid preparation	6
Characterization of buried interfaces using Ga Kα hard X-ray photoelectron spectroscopy (HAXPES)	6
Sustainable ammonia synthesis through electrochemical dinitrogen activation using an Ag2VO2PO4 catalyst	6
Concluding remarks: Carbon dioxide utilization: where are we now?… and where are we going?	6
Photoelectrocatalyzed undirected C–H trifluoromethylation of arenes: catalyst evaluation and scope	6
A combined periodic DFT and QM/MM approach to understand the radical mechanism of the catalytic production of methanol from glycerol	6
Unveiling the capabilities of bipolar conical channels in neuromorphic iontronics	6
An experimental and computational study of the reaction between pent-3-en-2-yl radicals and oxygen molecules: switching from pure stabilisation to pure decomposition with increasing temperature	6
Master equation study of hydrogen abstraction from HCHO by OH via a chemically activated intermediate	6
GeSe photovoltaics: doping, interfacial layer and devices	6