Chemical Society Reviews

Article	Citations
Front cover	1386
Contents list	831
Contents list	682
Front cover	528
Contents list	501
Front cover	463
Unifying thermochemistry concepts in computational heterogeneous catalysis	450
Reactions of main group compounds with azides forming organic nitrogen-containing species	422
Understanding and modelling the magnitude of the change in current of nanopore sensors	415
Medicinal inorganic chemistry – challenges, opportunities and guidelines to develop the next generation of radioactive, photoactivated and active site inhibiting metal-based medicines	411
Pore confined time-of-flight secondary ion electrochemical mass spectrometry	408
Interfacial engineering of halide perovskites and two-dimensional materials	405
Lignin-based porous carbon adsorbents for CO2 capture	373
Electro-/photocatalytic alkene-derived radical cation chemistry: recent advances in synthetic applications	362
Decoding recombination dynamics in perovskite solar cells: an in-depth critical review	349
The past 10 years of molecular ferroelectrics: structures, design, and properties	349
Recent advances in point-of-care testing of COVID-19	348
Organoboron molecules and polymers for organic solar cell applications	345
Defect-enabling zirconium-based metal–organic frameworks for energy and environmental remediation applications	344
Immunological nanomaterials to combat cancer metastasis	326
Black phosphorus-based nanoplatforms for cancer therapy: chemistry, design, biological and therapeutic behaviors	325
Contents list	319
Front cover	312
Progress on transition metal catalyzed asymmetric hydroesterification, hydrocarboxylation, and hydroamidation reactions of olefins	311
Cooperative approaches in catalytic hydrogenation and dehydrogenation	310

C–H bond activation and sequential addition to two different coupling partners: a versatile approach to molecular complexity	307
Molecular vessels from preorganised natural building blocks	302
Multimodal optoacoustic imaging: methods and contrast materials	302
Thermally activated structural phase transitions and processes in metal–organic frameworks	300
Hydrogen atoms in supramolecular chemistry: a structural perspective. Where are they, and why does it matter?	299
Back cover	293
Mechanism of oxidative stress and neurotoxicity associated with heme and copper–Aβ relevant to Alzheimer's disease	291
Electrochemical power sources enabled by multi-ion carriers	291
Daisy chain architectures: from discrete molecular entities to polymer materials	291
Recent advances in thermocatalytic acetylene selective hydrogenation	290
Interaction of SARS-CoV-2 with host cells and antibodies: experiment and simulation	289
Emerging ultrasmall luminescent nanoprobes forin vivobioimaging	287
Surface engineering for stable electrocatalysis	284
Aptamer-based assembly systems for SARS-CoV-2 detection and therapeutics	283
Nanoscale chemical characterization of materials and interfaces by tip-enhanced Raman spectroscopy	279
Enlightening dynamic functions in molecular systems by intrinsically chiral light-driven molecular motors	278
Metal–phenolic network composites: from fundamentals to applications	277
Recent development of gold(i) and gold(iii) complexes as therapeutic agents for cancer diseases	273
Optimizing photocatalysis via electron spin control	273
Hierarchical porous metal–organic gels and derived materials: from fundamentals to potential applications	272
Catalytic asymmetric synthesis of 1,2-diamines	271
Plasmonic silver and gold nanoparticles: shape- and structure-modulated plasmonic functionality for point-of-caring sensing, bio-imaging and medical therapy	269
Metallodrugs in cancer nanomedicine	267
The uptake of metal–organic frameworks: a journey into the cell	266
Polymer nano-systems for the encapsulation and delivery of active biomacromolecular therapeutic agents	265
Unlocking the potential: machine learning applications in electrocatalyst design for electrochemical hydrogen energy transformation	265
Light/X-ray/ultrasound activated delayed photon emission of organic molecular probes for optical imaging: mechanisms, design strategies, and biomedical applications	264
Selectivity control by zeolites during methanol-mediated CO2 hydrogenation processes	263
Back cover	262
Front cover	262
Back cover	259
Contents list	257
Contents list	252
Front cover	248
Contents list	246
Contents list	244
Back cover	244
Front cover	239
Front cover	237
A tutorial on the modeling of the heterogenous captured CO2 electroreduction reaction and first principles electrochemical modeling	237
Low oxidation state and hydrido group 2 complexes: synthesis and applications in the activation of gaseous substrates	235
Synthetic applications of hydride abstraction reactions by organic oxidants	235
Front cover	235
SERS microscopy as a tool for comprehensive biochemical characterization in complex samples	234
Molecular-level understandings and device strategies for FAPbI3-based perovskite solar cells	232
Design, characterization and applications of nanocolloidal hydrogels	232
Focusing on a nickel hydrocorphinoid in a protein matrix: methane generation by methyl-coenzyme M reductase with F430 cofactor and its models	229
Unravelling the benefits of transition-metal-co-doping in lanthanide upconversion nanoparticles	228
Ketones as strategic building blocks for the synthesis of natural product-inspired compounds	225
Recent advances in super-resolution optical imaging based on aggregation-induced emission	224

Progress in organocatalysis with hypervalent iodine catalysts	223
Radical sulfonylation with sulfur dioxide surrogates	223
Pt utilization in proton exchange membrane fuel cells: structure impacting factors and mechanistic insights	220
High-performance five-ring-fused organic semiconductors for field-effect transistors	219
Skin bioelectronics towards long-term, continuous health monitoring	219
Cu-based S-scheme photocatalysts	217
Defect engineering of two-dimensional materials for advanced energy conversion and storage	215
SERS in 3D cell models: a powerful tool in cancer research	215
Supramolecular and molecular capsules, cages and containers	215
Metal nitrides for seawater electrolysis	213
Photoinduced electron transfer (PeT) based fluorescent probes for cellular imaging and disease therapy	213
Advanced plasmonic technologies for multi-scale biomedical imaging	211
Correction: Main group metal polymerisation catalysts	210
Back cover	207
Contents list	207
Ionomeric binders in polymer electrolyte fuel cells: roles, challenges, and advances	206
Back cover	206
Front cover	206
Metal–metal bond in lanthanide single-molecule magnets	204
The mechanism of visible light-induced C–C cross-coupling by Csp3–H bond activation	204
Three-phase microenvironment modification by optimizing ionomer towards high-performance proton exchange membrane fuel cells	203
Contents list	203
Porphyrinoid actinide complexes	200
Understanding molecular and electrochemical charge transfer: theory and computations	199
Glycan microarrays from construction to applications	198
Nanobiocatalysis: a materials science road to biocatalysis	197
iSERS: from nanotag design to protein assays and ex vivo imaging	197
Functional materials for aqueous redox flow batteries: merits and applications	197
Reactive oxygen nanobiocatalysts: activity-mechanism disclosures, catalytic center evolutions, and changing states	196
Inside front cover	195
Biodistribution, degradability and clearance of 2D materials for their biomedical applications	195
PROTACs: past, present and future	195
Synthesis of Xenes: physical and chemical methods	194
Multivalent glycosystems for human lectins	192
Biomedical SERS – the current state and future trends	191
Ionogels: recent advances in design, material properties and emerging biomedical applications	190
2D graphdiyne: an emerging carbon material	189
Green metrics in mechanochemistry	186
Extrinsically conducting MOFs: guest-promoted enhancement of electrical conductivity, thin film fabrication and applications	186
The mechanochemical synthesis of polymers	185
Tunable metal–organic frameworks assist in catalyzing DNAzymes with amplification platforms for biomedical applications	184
Reactive capture and electrochemical conversion of CO2 with ionic liquids and deep eutectic solvents	184
Strategies for designing biocatalysts with new functions	184
Ether-based electrolytes for sodium ion batteries	183
Tailoring Cu-based small-pore zeolites towards NH3-SCR for NOx abatement	183
Covalent connections between metal–organic frameworks and polymers including covalent organic frameworks	183
“Bottom-up” and “top-down” strategies toward strong cellulose-based materials	183
Contents list	181
Contents list	180
Back cover	180
Back cover	180
Back cover	179
Contents list	179
Inside front cover	177
Inside back cover	177
Front cover	177
Contents list	175
Delivery strategies in treatments of leukemia	173
Geoinspired syntheses of materials and nanomaterials	173
High energy density lithium battery systems: from key cathode materials to pouch cell design	169
A surface chemistry perspective on SERS: revisiting the basics to push the field forward	168
New opportunities for immunomodulation of the tumour microenvironment using chemical tools	168
DNA-mediated precise regulation of SERS hotspots for biosensing and bioimaging	167
Chemically engineering cells for precision medicine	164
The emerging chemistry of self-electrified water interfaces	162
Mixed-valence metal–organic frameworks: concepts, opportunities, and prospects	162
Metal–organic frameworks (MOFs) toward SO2 detection	160
Implantable hydrogels as pioneering materials for next-generation brain–computer interfaces	160
Fluorinated metal–organic frameworks for gas separation	160
Photoelectrochemical energy storage materials: design principles and functional devices towards direct solar to electrochemical energy storage	160
Versatile polyphenolic platforms in regulating cell biology	160
Advanced systems for enhanced CO2 electroreduction	158
Dissecting the role of protein phosphorylation: a chemical biology toolbox	156
Multicharged cyclodextrin supramolecular assemblies	155
Zn-based batteries for sustainable energy storage: strategies and mechanisms	154
Advancements in antimicrobial nanoscale materials and self-assembling systems	153
Front cover	151
Front cover	151
Front cover	151
Inside front cover	151

Back cover	147
Front cover	146
Back cover	146
Correction: Surface functionalization of inorganic nanoparticles with ligands: a necessary step for their utility	146
Diastereodivergence in catalytic asymmetric conjugate addition of carbon nucleophiles	145
Multifunctional carbon nitride nanoarchitectures for catalysis	145
Chemistries of bifunctional PROTAC degraders	144
Strategies to engineer various nanocarrier-based hybrid catalysts for enhanced chemodynamic cancer therapy	142
Navigating the functionalization of unactivated alkenes via visible light photocatalysis	142
Double-cavity cucurbiturils: synthesis, structures, properties, and applications	141
Advances in small-molecule fluorescent probes for the study of apoptosis	140
Guidelines derived from biomineralized tissues for design and construction of high-performance biomimetic materials: from weak to strong	140
Photoelectrochemistry of oxygen in rechargeable Li–O2 batteries	139
Homogeneous catalysis with polyhydride complexes	138
Synthetic progress of organic thermally activated delayed fluorescence emitters via C–H activation and functionalization	138
Contents list	138
Methods to characterize and discover molecular degraders in cells	138
Sixty years of electrochemical optical spectroscopy: a retrospective	137
A closer look at amyloid ligands, and what they tell us about protein aggregates	136
Plasmonic nanomaterials with responsive polymer hydrogels for sensing and actuation	135
Chemistries and materials for atmospheric water harvesting	135
Degrader-antibody conjugates	134
Zeolites and metal–organic frameworks for gas separation: the possibility of translating adsorbents into membranes	134
Applications of covalent chemistry in targeted protein degradation	133
Encapsulation engineering of porous crystalline frameworks for delayed luminescence and circularly polarized luminescence	133
Activatable fluorescent probes for in situ imaging of enzymes	133
Recent advances in proton exchange membrane water electrolysis	133
Noncancerous disease-targeting AIEgens	133
Breaking symmetry for better catalysis: insights into single-atom catalyst design	133
Recent advances in conductive hydrogels: classifications, properties, and applications	130
Advances in the photon avalanche luminescence of inorganic lanthanide-doped nanomaterials	130
The entropy-controlled strategy in self-assembling systems	130
Platonic and Archimedean solids in discrete metal-containing clusters	129
Front cover	127
Inside back cover	127
Inside front cover	127
Contents list	126
Back cover	126
Front cover	126
Contents list	125
Inside front cover	124
Front cover	123
Back cover	123
Front cover	123
Inside front cover	122
Metal-free bioorthogonal click chemistry in cancer theranostics	121
Contents list	121
Porphyrinoids, a unique platform for exploring excited-state aromaticity	120
Interfacial design for detection of a few molecules	120
Nanostructured particles assembled from natural building blocks for advanced therapies	119
Ionic porous materials: from synthetic strategies to applications in gas separation and catalysis	118
Functional gel materials for next-generation electrochromic devices and applications	118
Surface functionalization of inorganic nanoparticles with ligands: a necessary step for their utility	118
Single-atom catalysts: promotors of highly sensitive and selective sensors	118
Current trends in the detection and removal of heavy metal ions using functional materials	116
Thermo-photo catalysis: a whole greater than the sum of its parts	116
Nanoscale engineering of solid-state materials for boosting hydrogen storage	116
A bright future for engineering piezoelectric 2D crystals	115
Ultrasound mechanisms and their effect on solid synthesis and processing: a review	115
Front cover	115
Supramolecular catalysis with emerging, functional organic macrocycles and cages	115
Protein desulfurization and deselenization	115
Supramolecular gels: a versatile crystallization toolbox	114
Superconducting single-photon detectors in the mid-infrared for physical chemistry and spectroscopy	114
Recent progress and prospects of dimer and multimer acceptors for efficient and stable polymer solar cells	114
Front cover	114
Covalent organic frameworks as superior adsorbents for the removal of toxic substances	113
Targeted delivery of oligonucleotides using multivalent protein–carbohydrate interactions	113
Gating effect for gas adsorption in microporous materials—mechanisms and applications	112
Insights into the mechanism of 3d transition-metal-catalyzed directed C(sp3)–H bond functionalization reactions	112
Photoresponsive DNA materials and their applications	112
Evolving aprotic Li–air batteries	112
Reactivity descriptors for sulfur redox kinetics in lithium–sulfur batteries: from mechanistic insights to machine learning driven catalyst design	111
Unlocking the catalytic potential of heterogeneous nonprecious metals for selective hydrogenation reactions	111
Noncovalently bound and mechanically interlocked systems using pillar[n]arenes	111
Emerging degrader technologies engaging lysosomal pathways	111
Organic photosensitizers for antimicrobial phototherapy	110
The transition metal-catalysed hydroboration reaction	110
Advancing flexible thermoelectrics for integrated electronics	109
Contents list	109
Front cover	109
Inside front cover	108
Back cover	108
Front cover	107
Outstanding Reviewers for Chemical Society Reviews in 2022	107
Contents list	107
Contents list	107
Front cover	107
Contents list	107
Metal–organic framework (MOF)-, covalent-organic framework (COF)-, and porous-organic polymers (POP)-catalyzed selective C–H bond activation and functionalization reactions	106
Carrier diversity and chemical ligations in the toolbox for designing tumor-associated carbohydrate antigens (TACAs) as synthetic vaccine candidates	106
Emerging applications and mechanistic insights of copper mediated electrocatalysts in organic transformations	106
Nanostructured perovskites for nonvolatile memory devices	106
Cyclic voltammetry and chronoamperometry: mechanistic tools for organic electrosynthesis	105
Biocatalysis making waves in organic chemistry	105