Organometallics

Papers
(The TQCC of Organometallics is 7. The table below lists those papers that are above that threshold based on CrossRef citation counts [max. 250 papers]. The publications cover those that have been published in the past four years, i.e., from 2020-04-01 to 2024-04-01.)
ArticleCitations
Synthesis and Structure of Arene Ru(II) NO-Chelating Complexes: In Vitro Cytotoxicity and Cancer Cell Death Mechanism133
An Update on Multiple Bonding between Heavier Main Group Elements: The Importance of Pauli Repulsion, Charge-Shift Character, and London Dispersion Force Effects85
Di-ortho-beryllated Carbodiphosphorane: A Compound with a Metal–Carbon Double Bond to an Element of the s-Block44
Carbon Dioxide Hydrogenation to Formate Catalyzed by a Bench-Stable, Non-Pincer-Type Mn(I) Alkylcarbonyl Complex43
Solvent-Free N-Alkylation and Dehydrogenative Coupling Catalyzed by a Highly Active Pincer-Nickel Complex40
Ni(4-tBustb)3: A Robust 16-Electron Ni(0) Olefin Complex for Catalysis36
A Comparison of Two Zinc Hydride Catalysts for Terminal Alkyne C–H Borylation/Hydroboration and the Formation of 1,1,1-Triborylalkanes by Tandem Catalysis Using Zn–H and B–H Compounds36
Coordination Behavior of Acylthiourea Ligands in Their Ru(II)–Benzene Complexes─Structures and Anticancer Activity33
Manganese-Catalyzed Hydrogenation of Ketones under Mild and Base-free Conditions33
Ready Approach to Organophosphines from ArCl via Selective Cleavage of C–P Bonds by Sodium33
Synthesis of Branched Polyethylene and Ethylene-MA Copolymers Using Unsymmetrical Iminopyridyl Nickel and Palladium Complexes32
Lewis Acidic Telluronium Cations: Enhanced Chalcogen-Bond Donor Properties and Application to Transfer Hydrogenation Catalysis30
Recent Advances in C(sp3)–C(sp3) Cross-Coupling Chemistry: A Dominant Performance of Nickel Catalysts29
High Lewis Acidity at Planar, Trivalent, and Neutral Bismuth Centers29
Direct (Hetero)arylation of Heteroarenes Catalyzed by Unsymmetrical Pd-PEPPSI-NHC Complexes under Mild Conditions28
Disubstituted Ferrocenyl Iodo- and Chalcogenoalkynes as Chiral Halogen and Chalcogen Bond Donors27
Switchable β-alkylation of Secondary Alcohols with Primary Alcohols by a Well-Defined Cobalt Catalyst26
Cationic PCP and PCN NHC Core Pincer-Type Mn(I) Complexes: From Synthesis to Catalysis25
Tuning the Donor−π–Acceptor Character of Arylborane–Arylamine Macrocycles25
Manganese-Catalyzed C(α)-Alkylation of Oxindoles with Secondary Alcohols via Borrowing Hydrogen25
Synthesis and Characterization of a Tetradentate, N-Heterocyclic Carbene Copper(II) Complex and Its Use as a Chan–Evans–Lam Coupling Catalyst24
Effect of Quaternary Phosphonium Salts as Cocatalysts on Epoxide/CO2 Copolymerization Catalyzed by salen-Type Cr(III) Complexes24
Update for Reactions of Group 4 Metallocene Bis(trimethylsilyl)acetylene Complexes: A Never-Ending Story?24
Isolation and Reactivity of Chlorotetryliumylidenes Using a Bidentate Bis(N-heterocyclic imine) Ligand24
Diaryl Ether Formation Merging Photoredox and Nickel Catalysis24
Bimetallic Bis-NHC-Ir(III) Complex Bearing 2-Arylbenzo[d]oxazolyl Ligand: Synthesis, Catalysis, and Bimetallic Effects23
Probing the Limits of Oxidative Addition of C(sp3)–X Bonds toward Selected N,C,N-Chelated Bismuth(I) Compounds23
Enantioselectivity in the Noyori–Ikariya Asymmetric Transfer Hydrogenation of Ketones23
A Dual Steric Enhancement Strategy in α-Diimine Nickel and Palladium Catalysts for Ethylene Polymerization and Copolymerization23
Dinuclear Gold(I) Complexes Bearing Alkyl-Bridged Bis(N-heterocyclic carbene) Ligands as Catalysts for Carboxylative Cyclization of Propargylamine: Synthesis, Structure, and Kinetic and Mechanistic Co23
A Tutorial on Selectivity Determination in C(sp2)–H Oxidative Addition of Arenes by Transition Metal Complexes23
A Rare Intramolecular Au···H–C(sp3) Interaction in a Gold(I) N-Heterocyclic Carbene22
Fragmentation of White Phosphorus by a Cyclic (Alkyl)(Amino)Alumanyl Anion22
Cyclometalated Ni(II) Complexes [Ni(NCN)X] of the Tridentate 2,6-di(2-pyridyl)phen-ide Ligand22
Non-Pincer-Type Arene Ru(II) Catalysts for the Direct Synthesis of Azines from Alcohols and Hydrazine under Aerobic Conditions22
Enhancing Thermal Stability in Aminopyridine Iron(II)-Catalyzed Polymerization of Conjugated Dienes22
Highly Selective Hydroboration of Carbonyls by a Manganese Catalyst: Insight into the Reaction Mechanism22
Switchable Imine and Amine Synthesis Catalyzed by a Well-Defined Cobalt Complex22
Synthesis of Overloaded Cyclopentadienyl Rhodium(III) Complexes via Cyclotetramerization of tert-Butylacetylene22
NHC-Palladium(II) Mononuclear and Binuclear Complexes Containing Phenylene-Bridged Bis(thione) Ligands: Synthesis, Characterization, and Catalytic Activities22
Synthesis of Anthracene-Bridged Dinuclear Phenoxyiminato Organotitanium Catalysts with Enhanced Activity, Thermal Stability, and Comonomer Incorporation Ability toward Ethylene (Co)polymerization22
Activation of Nitrogen-Rich Substrates by Low-Valent, Redox-Active Aluminum Species22
Influence of the Lewis Base Ph3PO on the Reactivity of the Uranium Phosphinidene (η5-C5Me5)2U(═P-2,4,6-iPr3C621
Pincer-Nickel Catalyzed Selective Guerbet-Type Reactions21
Structural and Redox Variations in Technetium Complexes Supported by m-Terphenyl Isocyanides21
Stable Au(III) Complexes Bearing Hemilabile PN and CN Ligands: Coordination of the Pendant Nitrogen upon Oxidation of Gold21
To Bind or Not to Bind: Mechanistic Insights into C–CO2 Bond Formation with Late Transition Metals21
Ligand-Controlled Regiodivergent Hydrosilylation of Conjugated Dienes Catalyzed by Mono(phosphine)palladium(0) Complexes21
Palladium(II) N^O Chelating Complexes Catalyzed One-Pot Approach for Synthesis of Quinazolin-4(3H)-ones via Acceptorless Dehydrogenative Coupling of Benzyl Alcohols and 2-Aminobenzamide21
Fluorescent Lewis Adducts: A Practical Guide to Relative Lewis Acidity21
C(sp2)–H Borylation of Heterocycles by Well-Defined Bis(silylene)pyridine Cobalt(III) Precatalysts: Pincer Modification, C(sp2)–H Activation, and Catalytically Relevant Intermedi20
5-C5Me5)2U(=P-2,4,6-tBu3C6H2)(OPMe3) Revisited—Its Intrinsic Reactivity toward Small Organic20
Catalytic Hydrogenation of Alkenes and Alkynes by a Cobalt Pincer Complex: Evidence of Roles for Both Co(I) and Co(II)20
An Illustrated Guide to Schlenk Line Techniques20
Tuning Activity and Selectivity during Alkyne Activation by Gold(I)/Platinum(0) Frustrated Lewis Pairs20
Two-Fold Reduction of Dibenzo[a,e]cyclooctatetraene with Group 1 Metals: From Lithium to Cesium20
Manganese Diphosphine and Phosphinoamine Complexes Are Effective Catalysts for the Production of Biofuel Alcohols via the Guerbet Reaction20
Methylene-Linked Bis-NHC Half-Sandwich Ruthenium Complexes: Binding of Small Molecules and Catalysis toward Ketone Transfer Hydrogenation20
Fe(0)-Mediated Reductive Disproportionation of CO220
Osmium- and Iridium-Promoted C–H Bond Activation of 2,2′-Bipyridines and Related Heterocycles: Kinetic and Thermodynamic Preferences20
Piano-Stool Iron Complexes as Precatalysts for gem-Specific Dimerization of Terminal Alkynes20
Rational Design of Cobalt Complexes Based on the trans Effect of Hybrid Ligands and Evaluation of their Catalytic Activity in the Cycloaddition of Carbon Dioxide with Epoxide19
σ-Bond Migration Assisted Decarboxylative Activation of Vinylene Carbonate in Rh-Catalyzed 4 + 2 Annulation: A Theoretical Study19
Synthesis of a Molybdenum Hydrido(hydrogermylene) Complex and Its Conversion to a Germylyne Complex: Another Route through Dehydrogenation with Nitriles19
Computational Investigations of Enantioselection in Carbon–Carbon Bond Forming Reactions of Ruthenium Guanidinobenzimidazole Second Coordination Sphere Hydrogen Bond Donor Catalysts19
Reactivity of [Pt(PtBu3)2] with Zinc(I/II) Compounds: Bimetallic Adducts, Zn–Zn Bond Cleavage, and Cooperative Reactivity19
Chiral NCN Pincer Iridium(III) Complexes with Bis(imidazolinyl)phenyl Ligands: Synthesis and Application in Enantioselective C–H Functionalization of Indoles with α-Aryl-α-diazoacetates19
Cobalt-Catalyzed Ammonia Borane Dehydrogenation: Mechanistic Insight and Isolation of a Cobalt Hydride-Amidoborane Complex19
Cationic Nickel(II)-Catalyzed Hydrosilylation of Alkenes: Role of P, N-Type Ligand Scaffold on Selectivity and Reactivity19
Probing Electronic Properties of Triazolylidenes through Mesoionic Selones, Triazolium Salts, and Ir-Carbonyl-Triazolylidene Complexes19
[CNC]-Pincer Cobalt Hydride Catalyzed Distinct Selective Hydrosilylation of Aryl Alkene and Alkyl Alkene19
Platinum(II) 1,2,4-Triazolin-5-ylidene Complexes: Stereoelectronic Influences on Their Catalytic Activity in Hydroelementation Reactions18
Expanding the Scope of Palladium-Catalyzed B–N Cross-Coupling Chemistry in Carboranes18
Bis(tridentate) Iron(II) Complexes with a Cyclometalating Unit: Photophysical Property Enhancement with Combinatorial Strong Ligand Field Effect18
Comparative Insertion Reactivity of CO, CO2, tBuCN, and tBuNC into Thorium– and Uranium–Phosphorus Bonds18
Computational Assessment of Counterion Effect of Borate Anions on Ethylene Polymerization by Zirconocene and Hafnocene Catalysts18
Cross-Dehydrocoupling of Amines and Silanes Catalyzed by Magnesocenophanes18
Hetero- and Homobimetallic Complexes Bridged by a Bis(NHC) Ligand: Synthesis via Selective Sequential Metalation and Catalytic Applications in Tandem Organic Transformations18
Copolymerization of Ethylene and Long-Chain Functional α-Olefins by Dinuclear Zirconium Catalysts18
Styryl-Functionalized Cage Silsesquioxanes as Nanoblocks for 3-D Assembly18
Development of Group 4 Metal Complexes Bearing Fused-Ring Amido-Trihydroquinoline Ligands with Improved High-Temperature Catalytic Performance toward Olefin (Co)polymerization18
Additive-Free Formic Acid Dehydrogenation Catalyzed by a Cobalt Complex17
Upgrading of Ethanol to n-Butanol via a Ruthenium Catalyst in Aqueous Solution17
Synthesis of Carbophosphinocarbene and Their Donating Ability: Expansion of the Carbone Class17
Aromaticity of 1-Heterocyclopropenes Containing an Atom of Group 14 or 417
Deoxygenation of Primary Amides to Amines with Pinacolborane Catalyzed by Ca[N(SiMe3)2]2(THF)217
Synthesis, Structure and Physical Properties of “Wire-like” Metal Complexes17
Cationic α-Diimine Nickel and Palladium Complexes Incorporating Phenanthrene Substituents: Highly Active Ethylene Polymerization Catalysts and Mechanistic Studies of syn/anti Isomerizati17
Bis(phosphine)cobalt-Catalyzed Highly Regio- and Stereoselective Hydrosilylation of 1,3-Diynes17
Copper-Catalyzed Azide–Alkyne Cycloaddition (CuAAC) by Functionalized NHC-Based Polynuclear Catalysts: Scope and Mechanistic Insights17
Photophysical Properties of Phosphorescent Mono- and Bimetallic Platinum(II) Complexes with CC* Cyclometalating NHC Ligands17
Bridging the Gap from Mononuclear PdII Precatalysts to Pd Nanoparticles: Identification of Intermediate Linear [Pd3(XPh3)4]2+ Clusters as Catalyt17
Catalytic C–H Bond Alkylation of Azoles with Alkyl Halides Mediated by Nickel(II) Complexes of Phenanthridine-Based N^N^N Pincer Ligands17
C–H Bond Activation via U(II) in the Reduction of Heteroleptic Bis(trimethylsilyl)amide U(III) Complexes17
Understanding Catalyst Structure–Selectivity Relationships in Pd-Catalyzed Enantioselective Methoxycarbonylation of Styrene17
Fluorinated Cycloplatinated(II) Complexes Bearing Bisphosphine Ligands as Potent Anticancer Agents17
Bidentate NHC-Cobalt Catalysts for the Hydrogenation of Hindered Alkenes17
Single-Crystal-to-Single-Crystal [2 + 2] Photodimerization Involving B←N Coordination with Generation of a Thiophene Host17
Synthesis, Structure, and Reactivity of the Uranium Bipyridyl Complex [{η5-1,2,4-(Me3Si)3C5H2}2U(bipy)]17
Pd–PEPPSI N-Heterocyclic Carbene Complexes from Caffeine: Application in Suzuki, Heck, and Sonogashira Reactions17
Diboron-Promoted Reduction of Ni(II) Salts: Precatalyst Activation Studies Relevant to Ni-Catalyzed Borylation Reactions16
Repercussion of a 1,3-Hydrogen Shift in a Hydride-Osmium-Allenylidene Complex16
Micellar Catalysis as a Tool for C–H Bond Functionalization toward C–C Bond Formation16
Vanadium(V) Arylimido Alkylidene N-Heterocyclic Carbene Alkyl and Perhalophenoxy Alkylidenes for the Cis, Syndiospecific Ring Opening Metathesis Polymerization of Norbornene16
Carboxylation of the Ni–Me Bond in an Electron-Rich Unsymmetrical PCN Pincer Nickel Complex16
An Annelated Mesoionic Carbene (MIC) Based Ru(II) Catalyst for Chemo- and Stereoselective Semihydrogenation of Internal and Terminal Alkynes16
Dihydroboration of Alkyl Nitriles Catalyzed by an Osmium-Polyhydride: Scope, Kinetics, and Mechanism16
Cobalt(−I)- and Rhodium(−I)-Mediated Dearylation of N-Aryl N-Heterocyclic Carbene Ligands16
Cooperativity in Highly Active Ethylene Dimerization by Dinuclear Nickel Complexes Bearing a Bifunctional PN Ligand16
Structural, Electronic, and Catalytic Modulation of Chelating Pyridylideneamide Ruthenium(II) Complexes16
Alkali-Metal Compounds with Bio-Based Ligands as Catalysts for Isoselective Lactide Polymerization: Influence of the Catalyst Aggregation on the Polymerization Control16
Comparison of Magnesium and Zinc in Cationic π-Arene and Halobenzene Complexes16
Adaptive Aromaticity in Metallasilapentalynes16
Silane Activation with Cobalt on the POCOP Pincer Ligand Platform16
Synthesis of Boryl-Substituted Disilane, Disilene, and Silyl Cation16
Adaptive σ Aromaticity and Triplet Ground State in Tetraatomic Boron Species16
Alkaline Earth Metal Aluminates as Catalysts for Imine Hydrogenation16
Synthesis of NHC-Iridium(III) Complexes Based on N-Iminoimidazolium Ylides and Their Use for the Amine Alkylation by Borrowing Hydrogen Catalysis16
Experimental and Computational Analysis of CO2 Addition Reactions Relevant to Copper-Catalyzed Boracarboxylation of Vinyl Arenes: Evidence for a Phosphine-Promoted Mechanism16
Chiral-at-Metal Ruthenium Complexes with Guanidinobenzimidazole and Pentaphenylcyclopentadienyl Ligands: Synthesis, Resolution, and Preliminary Screening as Enantioselective Second Coordination Sphere16
Design and Synthesis of Luminescent Bis(isocyanoborato) Rhenate(I) Complexes as a Selective Sensor for Cyanide Anion15
Effects of Axial Solvent Coordination to Dirhodium Complexes on the Reactivity and Selectivity in C–H Insertion Reactions: A Computational Study15
Bulky o-Phenylene-Bridged Bimetallic α-Diimine Ni(II) and Pd(II) Catalysts in Ethylene (Co)polymerization15
Iron Versus Ruthenium: Evidence for the Distinct Differences in the Electronic Structures of Hexa-1,3,5-triyn-1,6-diyl-bridged Complexes [Cp*(dppe)M}{μ-(C≡C)3}{M(dppe)Cp*}]+ (M =15
Reactivity of an Unprotected Mesoionic N-Heterocyclic Olefin15
Making Base-Assisted C–H Bond Activation by Cp*Co(III) Effective: A Noncovalent Interaction-Inclusive Theoretical Insight and Experimental Validation15
Mechanistic Study of Alkene Hydrosilylation Catalyzed by a β-Dialdiminate Cobalt(I) Complex15
Dual Photoredox-/Palladium-Catalyzed Cross-Electrophile Couplings of Polyfluoroarenes with Aryl Halides and Triflates15
Osmium-Promoted Transformation of Alkyl Nitriles to Secondary Aliphatic Amines: Scope and Mechanism15
N–H and C–H Bond Activations of an Isoindoline Promoted by Iridium- and Osmium-Polyhydride Complexes: A Noninnocent Bridge Ligand for Acceptorless and Base-Free Dehydrogenation of Secondary Alcohols15
Highly Reactive Cationic Molybdenum Alkylidyne N-Heterocyclic Carbene Catalysts for Alkyne Metathesis15
A Mild One-Pot Reduction of Phosphine(V) Oxides Affording Phosphines(III) and Their Metal Catalysts15
N-Heterocyclic Carbene Complexes of Nickel, Palladium, and Iridium Derived from Nitron: Synthesis, Structures, and Catalytic Properties15
Palladacycle-Catalyzed Olefinic C–P Cross-Coupling of Alkenylsulfonium Salts with Diarylphosphines to Access Alkenylphosphines15
Use of Ligand Steric Properties to Control the Thermodynamics and Kinetics of Oxidative Addition and Reductive Elimination with Pincer-Ligated Rh Complexes15
Syntheses of “Phosphine-Free” Molybdenum Oxo Alkylidene Complexes through Addition of Water to Alkylidyne Complexes15
Synthesis of an NHC-Coordinated Dialkyldisilavinylidene and Its Oxidation Providing a Silicon Analog of an Acetolactone15
N,N′-Dipp-o-phenylene-diamido Dianion: A Versatile Ligand for Main Group Metal–Metal-Bonded Compounds15
Metallacarborane Assemblies as Effective Antimicrobial Agents, Including a Highly Potent Anti-MRSA Agent15
Benzylnickel(II) Complexes of 2-Iminopyrrolyl Chelating Ligands: Synthesis, Structure, and Catalytic Oligo-/Polymerization of Ethylene to Hyperbranched Polyethylene15
Mechanistic Insights into the Nickel-Catalyzed Regioselective Carboxylation of Allylic Alcohols15
Metal-Free Room-Temperature Phosphorescence from Amorphous Triarylborane-Based Biphenyl15
Reactivities of Silaimines with Boranes: From Cooperative B–H Bond Activation to Donor Stabilized Silyl Cation15
A DFT Protocol for the Prediction of 31P NMR Chemical Shifts of Phosphine Ligands in First-Row Transition-Metal Complexes15
Catalytic Deoxygenation of Nitroarenes Mediated by High-Valent Molybdenum(VI)–NHC Complexes15
Pd-Catalyst Containing a Hemilabile P,C-Hybrid Ligand in Amino Dicarbonylation of Aryl Halides for Synthesis of α-Ketoamides15
Influence of the 1,3-Bis(trimethylsilyl)cyclopentadienyl Ligand on the Reactivity of the Uranium Phosphinidene [η5-1,3-(Me3Si)2C5H3]2U15
Synthesis, Reactivity, and Coordination of Semihomologous dppf Congeners Bearing Primary Phosphine and Primary Phosphine Oxide Groups15
1,2-Disubstituted Planar Chiral Ferrocene Derivatives from Sulfonamide-Directed ortho-Lithiation: Synthesis, Absolute Configuration, and Chiroptical Properties14
Synthesis of the Cationic Gallium Phthalocyanines and Their Catalytic Application in Gallium(III)-Activated Processes for Donor–Acceptor Substrates14
A Practical Synthesis of [(tmeda)Ni(CH3)2], Isotopically Labeled [(tmeda)Ni(13CH3)2], and Neutral Chelated-Nickel Methyl Complexes14
A Robust Vanadium(V) Tris(2-pyridyl)borate Catalyst for Long-Lived High-Temperature Ethylene Polymerization14
A Proton-Responsive Annulated Mesoionic Carbene (MIC) Scaffold on Ir Complex for Proton/Hydride Shuttle: An Experimental and Computational Investigation on Reductive Amination of Aldehyde14
Mono- and Dinuclear α-Diimine Nickel(II) and Palladium(II) Complexes in C–S Cross-Coupling14
Generation of a Ni3 Phosphinidene Cluster from the Ni(0) Synthon, Ni(η3-CPh3)214
Synthesis, Characterization, and Antimicrobial Activity of RhIII and IrIII N-Heterocyclic Carbene Piano-Stool Complexes14
Mixed Arylolefin/NHC Complexes of Platinum(II): Syntheses, Characterizations, and In Vitro Cytotoxicities14
Hypercrosslinked Polymer Platform-Anchored Single-Site Heterogeneous Pd–NHC Catalysts for Diverse C–H Functionalization14
Beyond Ni{N(SiMe3)2}2: Synthesis of a Stable Solvated Sodium Tris-Amido Nickelate14
Enantioconvergent and Regioselective Synthesis of Allenylsilanes by Nickel-Catalyzed C(sp2)–C(sp3) Cross-Coupling Starting from Racemic α-Silylated Propargylic Bromides14
Knölker Iron Catalysts for Hydrogenation Revisited: A Nonspectator Solvent and Fine-Tuning14
Comparative Mechanistic Study on the [Au(NHC)]+-Catalyzed Hydration of Alkynes, Alkenes, and Allenes14
Oxidative Addition of Aryl Halides to a Triphosphine Ni(0) Center to Form Pentacoordinate Ni(II) Aryl Species14
Carbon–Carbon Bond Coupling of Vinyl Molecules with an Allenyl Ligand at a Diruthenium Complex14
One-Electron Reduction of Ti(IV) Complex by Dialkylaluminum(I) Anion Giving the Ti(III) Species14
Structural Features of Polymer Ligand Environments Dramatically Affect the Mechanical and Room-Temperature Self-Healing Properties of Cobalt(II)-Incorporating Polysiloxanes14
Synthesis and Ethylene Reactivity of Dinuclear Iron and Cobalt Complexes Supported by Macrocyclic Bis(pyridine-diimine) Ligands Containing o-Terphenyl Linkers14
Electrochemically Driven and Acid-Driven Pyridine-Directed ortho-Phosphorylation of C(sp2)–H Bonds14
Influence of the N→Ru Coordinate Bond Length on the Activity of New Types of Hoveyda–Grubbs Olefin Metathesis Catalysts Containing a Six-Membered Chelate Ring Possessing a Ruthenium–Nitrogen Bond14
Behavior of Lewis Bases toward Diphenylberyllium14
Rational Design of a Tripodal Ligand for U(IV): Synthesis and Characterization of a U–Cl Species and Insights into Its Reactivity13
Iron-Mediated C–C Bond Formation via Reductive Coupling with Carbon Dioxide13
Synthesis, Reactivity, and Insights into the Lewis Acidity of Mononuclear Titanocene Imido Complexes Bearing Sterically Demanding Terphenyl Moieties13
[P,C]-Chelate Cobalt(III) Hydride Catalyzed Hydrosilylation of Alkenes13
A Stiboranyl Platinum Triflate Complex as an Electrophilic Catalyst13
Effects of Tuning Intramolecular Proton Acidity on CO2 Reduction by Mn Bipyridyl Species13
Activation of an α-Diimine Ni(II) Precatalyst with AlMe3 and AliBu3: Catalytic and NMR and EPR Spectroscopy Studies13
Lewis Acid Effects on Calculated Ligand Electronic Parameters13
Cationic Copper Iminophosphorane Complexes as CuAAC Catalysts: A Mechanistic Study13
Effect of Ligand Backbone on the Selectivity and Stability of Rhodium Hydroformylation Catalysts Derived from Phospholane-Phosphites13
Well-Defined Cationic Cobalt(I) Precatalyst for Olefin-Alkyne [2 + 2] Cycloaddition and Olefin-Diene Hydrovinylation Reactions: Experimental Evidence for Metallacycle Intermediates13
Controlled Activation of Dipicolinyl-Substituted Propargylic Alcohol by Ru(II) and Os(II) for Unprecedented Indolizine-Fused Metallafuran Complexes13
Electrochemical CO2 Reduction — The Effect of Chalcogenide Exchange in Ni-Isocyclam Complexes13
Synthesis of Heterobimetallic Complexes through Chemoselective 2,4-Metalation of a Thiazolium Salt13
Pincer-Cobalt-Catalyzed Guerbet-Type β-Alkylation of Alcohols in Air under Microwave Conditions13
Palladium-Catalyzed Cyclobutanation of Aryl Sulfonates through both C–O and C–H Cleavage13
Terminal-Selective C(sp3)–H Arylation: NiH-Catalyzed Remote Hydroarylation of Unactivated Internal Olefins13
16-Electron Nickel(0)-Olefin Complexes in Low-Temperature C(sp2)–C(sp3) Kumada Cross-Couplings13
Catalytic Activity of a Zr MOF Containing POCOP-Pd Pincer Complexes12
Group 6 Metal Carbonyl Complexes Supported by a Bidentate PN Ligand: Syntheses, Characterization, and Catalytic Hydrogenation Activity12
Mechanochemically Activated Liebeskind–Srogl (L-S) Cross-Coupling Reaction: Green Synthesis of meso-Substituted BODIPYs12
Benzimidazolin-2-iminato Hafnium Complexes: Synthesis, Characterization, and Catalytic Addition of Alcohols to Carbodiimides12
Impact of the Electronic Environment in Carbazole-Appended o-Carboranyl Compounds on the Intramolecular-Charge-Transfer-Based Radiative Decay Efficiency12
C(sp2)-CF3 Reductive Elimination from Well-Defined Argentate(III) Complexes [nBu4N][Ag(Ar)(CF3)3]12
Mono- and Dinuclear Asymmetric Aluminum Guanidinates for the Catalytic CO2 Fixation into Cyclic Carbonates12
Synthesis of Norbornene-Based Phosphine-Stabilized Silylium Ions Behaving as Masked Frustrated Lewis Pairs12
N-Heterocyclic Carbene-Based Tetradentate Pd(II) Complexes for Deep-Blue Phosphorescent Materials12
Catalytic C(sp2)–H Amination Reactions Using Dinickel Imides12
Highly Selective Hydroboration of Terminal Alkenes Catalyzed by a Cobalt Pincer Complex Featuring a Central Reactive N-Heterocyclic Phosphido Fragment12
Role of Solvent Coordination on the Structure and Dynamics of ansa-Zirconocenium Ion Pairs in Aromatic Hydrocarbons12
Half-Sandwich Ru(II) Complexes with N,O-Chelate Ligands: Diverse Catalytic Activity for Amine Synthesis in Water12
Zn Metal–Organic Framework with High Stability and Sorption Selectivity for CO212
N-Heterocyclic Carbene Complexes of Nickel(II) from Caffeine and Theophylline: Sustainable Alternative to Imidazol-2-ylidenes12
Decomposition of Vanadium(V) Alkylidenes Relevant to Olefin Metathesis12
Application of Indazolin-3-ylidenes in Catalysis: Steric Tuning of Nonclassical Formally Normal N-Heterocyclic Carbenes with Dual Electronic Character for Catalysis12
Accessing Mononuclear Triphenylcyclopentadienyl Lanthanide Complexes by Using Tridentate Nitrogen Ligands: Synthesis, Structure, Luminescence, and Catalysis12
Tetraaminocyclopentadienone Iron Complexes as Hydrogenation Catalysts12
Selective, Base-Free Hydrogenation of Aldehydes Catalyzed by Ir Complexes Based on Proton-Responsive Lutidine-Derived CNP Ligands12
Role of dppf Monoxide in the Transmetalation Step of the Suzuki–Miyaura Coupling Reaction12
Tuning Organocerium Electrochemical Potentials by Extending Tris(cyclopentadienyl) Scaffolds with Terminal Halogenido, Siloxy, and Alkoxy Ligands12
Combined Experimental and Computational Study of the Mechanism of Acceptorless Alcohol Dehydrogenation by POCOP Iridium Pincer Complexes12
Tris(carbene) Stabilization of Monomeric Magnesium Cations: A Neutral, Nontethered Ligand Approach12
Direct Synthesis of Hydrogen Peroxide in Water by Means of a Rh-Based Catalyst12
Wrapping Rhodium in a Borane Canopy: Implications for Hydride Formation and Transfer12
{MI(CO)X(CNArDArF2)4} (DArF = 3,5-(CF3)2C6H3; M = Re and Tc; X = Br and Cl) Complexes: Convenient Platforms for the Synthes12
Hemisphere and Distance-Dependent Steric Analysis of PNN Iron Pincer Complexes Using SambVca 2.1 and Its Influence on Alkene Hydrosilylation12
Synthesis and Catalytic Reactivity of Cobalt Pincer Nitrosyl Hydride Complexes12
Vanadium- and Chromium-Catalyzed Dehydrogenative Synthesis of Imines from Alcohols and Amines12
Cobalt-Catalyzed (E)-Selective Hydrosilylation of 1,3-Enynes for the Synthesis of 1,3-Dienylsilanes12
The Effect of Added Ligands on the Reactions of [Ni(COD)(dppf)] with Alkyl Halides: Halide Abstraction May Be Reversible12
Synthesis of Cationic, Dimeric α-Diimine Nickel Hydride Complexes and Relevance to the Polymerization of Olefins12
Synthesis, Electrochemistry, and Optical Properties of Highly Conjugated Alkynyl-Ferrocenes and -Biferrocenes11
Reinvestigating Catalytic Alcohol Dehydrogenation with an Iridium Dihydroxybipyridine Catalyst11
Imidazoline-2-imine Functionalized Fluorenyl Rare-Earth Metal Complexes: Synthesis and Their Application in the Polymerization of ortho-Methoxystyrene11
Cyclometalated NHCs Pt(II) Compounds with Chelating P^P and S^S Ligands: From Blue to White Luminescence11
Impact of Biphenyl Benzhydrazone-Incorporated Arene Ru(II) Complexes on Cytotoxicity and the Cancer Cell Death Mechanism11
Tetraorganylargentate(III) Complexes: Key Intermediates in Silver-Mediated Cross-Coupling Reactions11
Molybdenum Benzylidyne Complexes for Olefin Metathesis Reactions11
Bimetallic Nickel Complexes Containing Benzotriazole-Derived Diamine-Bisphenolate Ligands as Highly Active Catalysts for the Copolymerization of Carbon Dioxide with Cyclohexene Oxide: Synthesis, Catal11
Naphthyl-Derived Orthometalated RuII-NHC Complexes: Effect of the NHC Donors and/or Substitution Pattern on Their Synthesis and Catalytic Activity11
Functionalization of N,N-Dialkylferrocenesulfonamides toward Substituted Derivatives11
Technetium Hydrides Revisited: Syntheses, Structures, and Reactions of [TcH3(PPh3)4] and [TcH(CO)3(PPh3)2]11
Aggregation Behavior of Lithionaphthalenes in Solution: Experimental and Theoretical Study11
Antiproliferative Activity and Associated DNA Interactions of [Co2L3]6+ Cylinders Derived from Bis(bidentate) 2-Pyridyl-1,2,3-triazole Ligands11
NNO Pincer Ligand-Supported Palladium(II) Complexes: Direct Synthesis of Quinazolines via Acceptorless Double Dehydrogenative Coupling of Alcohols11
Carbodiphosphorane-Catalyzed Hydroboration of Ketones and Imines11
Cobalt-Catalyzed Alkylation of Nitriles with Alcohols11
Hydration of Aromatic Nitriles Catalyzed by Mn-OH Complexes: A Rationalization from Quantum Chemical Investigations11
Cobalt Complexes of Bulky PNP Ligand: H2 Activation and Catalytic Two-Electron Reactivity in Hydrogenation of Alkenes and Alkynes11
Synthesis of Vanadium Oxo Alkylidene Complex and Its Reactivity in Ring-Closing Olefin Metathesis Reactions11
Electroreduction of Benzaldehyde with a Metal–Ligand Bifunctional Hydroxycyclopentadienyl Molybdenum(II) Hydride11
Influence of Indole-N Substitution of Thiosemicarbazones in Cationic Ru(II)(η6-Benzene) Complexes on Their Anticancer Activity11
Synthesis, Structure, and Reactivity of a Superbulky Low-Valent β-Diketiminate Al(I) Complex11
Direct Evidence for Competitive C–H Activation by a Well-Defined Silver XPhos Complex in Palladium-Catalyzed C–H Functionalization11
Effectiveness and Mechanism of the Ene(amido) Group in Activating Iron for the Catalytic Asymmetric Transfer Hydrogenation of Ketones11
Radical Capture at Nickel(II) Complexes: C–C, C–N, and C–O Bond Formation11
Heteroscorpionate Rare-Earth Catalysts for the Low-Pressure Coupling Reaction of CO2 and Cyclohexene Oxide11
Heterocoupling of Different Aryl Nitrenes to Produce Asymmetric Azoarenes Using Iron–Alkoxide Catalysis and Investigation of the Cis–Trans Isomerism of Selected Bulky Asymmetric Azoarenes11
endo-Selective Iron Catalysts for Intramolecular Alkyne Hydrofunctionalization11
A Cobalt-Catalyzed Enantioconvergent Radical Negishi C(sp3)–C(sp2) Cross-Coupling with Chiral Multidentate N,N,P-Ligand11
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