Organometallics

Article	Citations
Synthesis, Characterization, and Reactivity of Thioether-Ligated Organoiron(II) Complexes	85
The Challenging Reaction of Cyclopropenones with Benzamide Catalyzed by Rh(III): A Computational Study	59
Flash Communication: Carbon Monoxide Insertion and Ligand Modification with Pyridine(diimine) Iron Alkyl Complexes	58
Bis(Tetrathiafulvalenes) with Mixed Phosphine and Silane Double Bridges	46
Issue Editorial Masthead	45
Issue Editorial Masthead	40
Issue Publication Information	39
Issue Publication Information	38
Hydroalumination of 1,8-Diethynylanthracenes–Al-based Bis-Lewis-Acids and their Isomerization and Complexation Behavior	37
Ylide-Functionalized Phosphine (YPhos) Platinum Complexes: Synthesis and Application in Hydrosilylations under Mild Conditions	36
Mechanism and Selectivity Investigation of [Cu]/[Pd] Synergistic Catalyzed Borylfluoroallylation of Alkyne: A DFT Study	34
Alkyllithium Reagents as a Hidden Source of Lithium Hydride	33
Catalyst Design for Rh-Catalyzed Arene and Alkane C–H Borylation: The NHC Affects the Induction Period, and Indenyl is Superior to Cp	32
Multisite Ligand Noninnocence of (CpN3)Fe(CO)3+ with Exogenous Hydride Donors: Kinetics and Mechanism	31
Formation of Bisvinylidene Complexes through Consecutive Alkyne–Vinylidene Rearrangements	29
Nickel-Catalyzed Arylation/Lactonization Cascade Reactions for the Synthesis of Bicyclo[3.2.1]lactones	29
Flash Communication: The [BPh 4 ] − Anion Is Stripped by Half-Sandwich Scandium Tetramethylalumina	28
Triptycepenes: Synthesis, Metal Complexes, and Their Reactivity in Catalytic Reactions	28
Impact of Halide (Cl vs I) Identity on the Preferred Positioning of Substituents between Al and M (M = Co, Rh, Ir) in PAlP Pincer Complexes	28
Ti-Catalyzed Multicomponent Synthesis of Pyrroles Using Allene Coupling Partners	27
Zintl Ions and Phases Promote the Catalytic Hydrophosphination of Alkynes, Alkenes, and Imines	26
Pitfalls for POCOP-Type Palladium Pincer Complexes in Catalytic Reduction of CO2 with Catecholborane	25
Multiple C–B Bond Cleavage Reactions at [BArF4]− Anions Mediated by Terphenyl Phosphine Gold Catalysts	25
Groups 9 and 10 Complexes of C–Donor Ligands Derived from Pyridinium-Stabilized Phosphorus Ylides	24
High-Throughput Approach in the Ring-Opening Polymerization of β-Butyrolactone Enables Rapid Evaluation of Yttrium Salan Catalysts	24

Ni(3,5-CF3stb)2(Et2O): A “Super-Naked” Nickel Complex	24
Activity Enhancement of Phenoxy-Imine Titanium Catalysts via σ–π Synergy and Para-Substituent Effect	23
Steric and Electronic Effects Responsible for N,O- or N,N-Chelating Coordination of Pyrazolones Containing a Pyridine Ring in Ruthenium Arene Systems	23
Oxidative Addition of Alkyl Iodides to [Sn(NMe2)2]2: In Situ Generation of RSn(NMe2)3 Compounds	23
Carbon Monoxide-Induced Mobility of Isolated Palladium Species on Silicon Dioxide at Room Temperature	23
Synthesis and Characterization of Rare-Earth Metal Complexes Bearing a 2-N,N-Dimethylamino-Ethylene-Imino-Functionalized Indolyl Ligand and Their Catalytic Activities Toward Hydrosilylat	23
PCP Pincer Complexes of Titanium in the +3 and +4 Oxidation States	22
Flash Communication: (Ph 3 P) 2 N 2 ─Aza-Wittig	22
Direct Stereoselective Synthesis of a Single (ebthi)Ti(BINOLate) Catalyst Enantiomer	22
Influence of the Counterion on the Activation of Nickel(σ-Aryl) Precatalysts	22
Ruthenium-Catalyzed Formic Acid/Formate Dehydrogenation and Carbon Dioxide/(bi)carbonate Hydrogenation in Water	21
Reactivity of Heterobimetallic Ion Pairs in Formic Acid Dehydrogenation	21
Influence of Indole-N Substitution of Thiosemicarbazones in Cationic Ru(II)(η6-Benzene) Complexes on Their Anticancer Activity	21
Cationic Half-Sandwich Ruthenium(II) Complexes of 2-Picolyl-Based N-Arylguanidines as Catalysts for the Aldehyde–Water Shift Reaction	21
Chromium(III) Amino-bis(phenolate) Catalysts for the Ring-Opening Copolymerization of Epoxides and Phthalic Anhydride: Effects of Cocatalysts and Cyclohexene Oxide Initiators on Copolymerization Activ	21
Synthesis, Reactivity, and Theoretical Insights of Co-Sb2 and Co-Bi2 Rings	21
(κ3-N∩N∩N)-Palladium Pincer Complex-Catalyzed Synthesis of Quinazolin-4(3H)-Ones Through the Acceptorless Dehydrogenation Process: Experimental Results and Computational Insights	20
Kinetic and Thermodynamic Pathways in the Reactions of Five-Membered Zircona- and Hafnacyclocumulenes with Acetonitrile. Structures and Mechanisms of Formation of the Obtained Complexes	20
Synthesis and Surface Attachment of Molecular Re(I) Hydride Species with Silatrane Functionalized Bipyridyl Ligands	20
Oxidative Coupling of Ruthenium Alkenyl Acetylide Complexes as a Route to Dinuclear Complexes Featuring Carbon-Rich Bridging Ligands	20
Steric and Electronic Properties of Phosphinimide-Based Silylenes─The Influence of the Phosphine Moiety	20
Stereoselective Epoxidation of Unfunctionalized Aliphatic Alkenes with a Macrocyclic Tetra-NHC Iron(II) Catalyst	20
Carborane-Functionalized Thiocarbohydrazones: Synthesis, Computational, and Anticancer Evaluation	19
Reactions of Nickel(0)–Olefin Pincer Complexes with Terminal Alkynes: Cooperative C–H Bond Activation and Alkyne Coupling	19
Understanding Precatalyst Activation and Speciation in Manganese-Catalyzed C–H Bond Functionalization Reactions	19
NIR-Absorbing TCBD and Expanded TCBD-Functionalized Ferrocene–Phenothiazine Conjugates	18
Issue Editorial Masthead	18
Variable Kinetic Isotope Effect Reveals a Multistep Pathway for Protonolysis of a Pt–Me Bond	18
Mechanism and Selectivity of Bi(V)-Aryl Oxyfunctionalization in Trifluoroacetic Acid Solvents	18
A Contiguous Tricyclic [P6]2– Framework Spanning Across Two Vanadium(III) Centers	18
Issue Publication Information	18
Back with the Flash Communication	18
Heteroleptic Bis(amido) Ca(II) and Yb(II) NHC Pincer Complexes: Synthesis, Characterization, and Catalytic Activity in Intermolecular Hydrofunctionalization of C═C Bonds	18
Mechanistic Insights into Rh-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Silazanes: The Origin of Enantioselectivity	18
Mechanism of Perfluoro-Nickelacyclopentane Formation from Tetrafluoroethylene: Effects of Ancillary Ligand Bite Angle	18
Issue Editorial Masthead	18
Heterometallic Clusters with Thorium–Rhodium Bonds Supported by Double-Layer Nitrogen–Phosphorus Ligands	18
Electrocatalytic Anaerobic Oxidation of Benzylic Amines Enabled by Ferrocene-Based Redox Mediators	18
Geometric Control of Carbon–Carbon Reductive Elimination from a Platinum(IV) Pincer Complex	18
CO Complexation by Ru(II) and Os(II) Porphyrin Complexes Sheds Light on the Relative Importance of Thermodynamic Stability and Kinetic Lability for CO Poisoning Antidotes	17
Correction to “DFT Study on the Mechanisms of Iron-Catalyzed Ortho C–H Homoallylation of Aromatic Ketones with Methylenecyclopropanes”	17
Revisiting C–C and C–H Bond Activation in Rhodium Pincer Complexes: Thermodynamics and Kinetics Involving a Common Agostic Intermediate	17
Flash Communication: Ir Complexes with a PhN(CH2CH2PiPr2)2 Pincer Ligand for Reversible CO2 Hydrogenation	17
Pentamethylcyclopentadienyl Metalloradical Iron Complexes Containing Redox Noninnocent α-Diimine-Type Ligands: Synthesis, Molecular, and Electronic Structures	17
Issue Editorial Masthead	17
Mechanism of Nickel-Catalyzed Dual C–O Bond Activation in the Deoxygenation of Ethers via Reductive Cross-Coupling Reaction: A DFT Study	17
DFT Studies on the Early-Transition-Metal-Catalyzed Polymerization of Polar Monomers with a Methylene Spacer between Vinyl and Functional Groups	17
Bifunctional Hydroboration Catalyst Activation Using a Co SNS Amido Complex Bearing an Abnormal-NHC Ligand	17
Metallapolycycles from the Coupling of Two Re–C Bonds	16
Carbene–Calcium Silylamides and Amidoboranes	16

Diamidoamine Aluminum Complex as Effective Initiator for Random Copolymerization of Substituted Carbonate with L-Lactide	16
Flash Communication: Strained and Bimetallic Structures of Rhodium and Iridium Germyl Complexes with Phosphinoamido Ligands	16
Mechanistic Aspects of Rhodium-Catalyzed Isoprene Hydroformylation: A Computational Study	16
Flash Communication: Density Functional Theory (DFT) Calculations Indicate an Unconventional Anagostic Complex for the Initial Stage of the Reported Sc3+ Boosted C–H Bond Activation of 3,4-	16
High-Temperature Solution-Phase Ethylene (Co)polymerization Catalyzed by a [O–N–P]TiBn2 Complex	16
Trapping an Unusual Ring-Opened Product of THF within a Lithium Hydrido Aluminate	16
Catalytic Hydrogenation of Terminal Alkenes by a (PPP) Pincer-Ligated Cobalt(II) Complex	16
Photochemistry of RMn(CO)5 Complexes as Precursor Candidates for Photoassisted Chemical Vapor Deposition	16
Phosphine-Mediated Cleavage of Sulfur–Sulfur Bonds	16
Tetramethylethylenediamine Stabilizes Organozinc Surface Intermediates against Chemical Etching but Not against Protodemetalation	16
Divergent Approach for Tris-Heteroleptic Cyclometalated Iridium Complexes Using Triisopropylsilylethynyl-Substituted Synthons	16
Synthesis and Reactivity of Oxorhenium(V) Complexes Incorporating 2,6-Bis[(diphenyl)methyl]diamidopyridine (DPMDAP) Pincer Ligands as the Basic Component of Transition Metal Frustrated Lewi	16
Ligand Modifications on a Cp(quinolate)Ru Catalyst to Improve Its Stability in a Bio-orthogonal Deprotection Reaction	15
Tailoring Catalyst Activity and Substrate Scope via Modular Design of Adaptive Tridentate Ligands for Alkyne Metathesis	15
The Intrinsic Barrier for N≡N Bond Cleavage or Formation Mediated by the Cp*Cr(dmpe) Fragment Is Insurmountable	15
Alternative Si–F Elimination and Fluoride Abstraction Pathways in Selective Monodefluorination of Me3SiCF3 and Me3SiCF2H	15
Molecular Weight Determination of Relevant Organometallic Catalysts in Solution by DOSY-NMR to Monitor Reactivity	15
Skeletal Rearrangement of a μ–η2:η4-Hexatrienyl Ligand at a Diruthenium Site via a μ–η5-Ruthenacyclohexadienyl Intermediate	15
Noninnocent Cyclopentadienyl Reactivity in an Al/Cr Heterobimetallic Complex	15
Saturated NHC-Stabilized Borenium, Boronium, Hydride-Bridged Boron Cations, and a Bora-Acyl Chloride	15
Ligand Reorganization in the Coordination Sphere of a CCC-NHC Pincer Fe Complex and Transient Absorption Spectroscopic Characterization of [(BuCiCiCBu)	15
Metal Identity Effects in the Pincer Complex-Catalyzed Dehydrogenative Coupling of Formamides with Alcohols to Form Carbamates	15
Rhodium-Catalyzed Arene Alkenylation Using Benzoquinone Derivatives as Oxidants	15
p-Aryl-Substituted Iminopyridine Chromium Complexes as Precatalysts for Ethylene Polymerization: The Question of the Physical Oxidation State Examined by Experimental and Density Functional Stu	15
Synthesis and Reactivity of Low-Coordinate Iron(II) Alkyl Complexes toward Alkene Hydrogenation	15
Amines as Activating Ligands for Phosphine Palladium(II) Precatalysts: Effect of Amine Ligand Identity on the Catalyst Efficiency	14
Carbon Nanotube-Supported Iron Complex Catalyzes 1-Hexene Dimerization	14
Organic Allene vs Organometallic Allene─Preference Toward Allylic Anionic Delocalization, Dative Bonding, and Tunable Reactivity	14
Dehydrogenation of Formic Acid Catalyzed by an Osmium-Polyhydride: Relevance of Acid Assistance in the CO2 Formation Stage	14
Application of Bis(amido)alkyl Magnesiates toward the Synthesis of Molecular Rubidium and Cesium Hydrido-magnesiates	14
Issue Editorial Masthead	14
Pioneers and Influencers in Organometallic Chemistry: Professor John E. Ellis Takes Metals to the Limit	14
Iron–Aryloxide Complex Bearing Bis(dipyrromethene) Ligands for the Ring-Opening Polymerization of ε-Caprolactone	14
Cytotoxicity of Ruthenium(II) Arene Complexes Containing Functionalized Ferrocenyl β-Diketonate Ligands	14
Arene Insertion into the M–Cl Bond vs Addition-like Behavior of Arene and M–Cl Bond (M = Cu/Fe): A DFT Investigation of the Cu/Fe SET Mechanism of Arene sp2 C–H Chlorination	14
Issue Publication Information	14
Synthesis of Mo(IV) para-Substituted Styrene Complexes and an Exploration of Their Conversion to 1-Phenethylidene Complexes	14
Hydrogen Bond Patterning and Biological Activity of Ferrocene Conjugates with Homo- and Heterochiral Ala–Pro Dipeptides	13
Compounds with Chelating 3-Dimethylamino-1-propyl Ligands as Chemical Vapor Deposition Precursors. Synthesis and Characterization of M[(CH2)3NMe2]2 Complexe	13
Reductive Elimination from Sterically Encumbered Ni–Polypyridine Complexes	13
Synthesis and Characterization of Uranium Complexes Supported by Substituted Aryldimethylsilylanilide Ligands	13
Flash Communication: Bismuthinidenes as Lewis Bases in Reversible C(sp3)–O Bond Cleavage	13
Methyl-Branched Polyethylene Produced by Hafnocene Complexes Exhibiting Unconventional Dialkoxy Bridges	13
Synthesis and Reactivity of Dipalladated Derivatives of Terephthalaldehyde	13
N–N Double-Bond Cleavage and Azobenzene Rearrangement with C–C Bond Formation Induced by a Germylene	13
Reduction of Nitrous Oxide and Binding of Carbon Dioxide by Acenaphthene-1,2-diimine Aluminum Compounds	13
Ruthenium Bis-Sulfonate Complexes: Synthesis and Application in Asymmetric Hydrogenation	13
Cobalt-Catalyzed Regio- and Stereoselective Hydrosilylation of Alk-2-ynes with Tertiary Silanes	13
Heteroditopic Chelating NHC Ligand-Supported CoIII Complexes: Catalysts for the Reductive Functionalization of Carbon Dioxide under Ambient Conditions	13
Alkaline Earth Catalyzed CO2 Hydroboration into Acetal Derivatives Leading to C–S Bond Formation	12
Methane Activation by Different Early Actinide (Ac, Th, Pa, U, and Np) Oxides and Their Ions: A Density Functional Theory Investigation	12
Synthesis and Single-Crystal X-ray Structures of Sterically Hindered Three Half-Sandwich (η6-p-Cymene)ruthenium(II) Schiff Base Complexes: Catalytic Applications in Selective Monoalk	12
Updates to the Organometallics Team	12
Understanding and Designing of Bent Aromatic Heterometallabenzenes	12
Correction to “On the Possibility of Using Aza-Cryptands to Design Superalkalis”	12
Importance of Ligand Fine-Tuning: Alkyne Metathesis with Molybdenum Alkylidyne Complexes Supported by Phenyl-tert-butoxysilanolate Ligands	12
Reactions of TcI(NO) and TcVN Complexes with Alkynes and Alkynides	12
Detection of the BICT State in a Borafluorene with High Stokes Shift Fluorescence	12
Issue Publication Information	12
Influencing α-Olefin Selectivity and PE-Wax Suppression Using Cyclohexyl-Fused 2-Imino-1,10-phenanthroline-iron Ethylene Oligomerization Catalysts	12
Photochemical Synthesis of Five-Membered Zirconacyclocumulene Complex and Its Reactions with Ketones	12
Maurice Brookhart: A Legacy to Organometallic Chemistry	12
Living cis-1,4-Selective Polymerization of 1,3-Dienes by Enamino-Oxazolinate Rare-Earth Metal Complexes	12
Controlled Polymerization of 3-Hexyne, 4-Octyne, and 5-Decyne by Nb(CHCMe2Ph)(NC6F5)[OC(CF3)3](PMe3)2 Catalyst: Structural	12
Structural Evidence for Aromatic Heterocycle N–O Bond Activation via Oxidative Addition	12
Development of Sandwich Compound-Based Planar Chiral Six-Membered NHC Ligands with Quaternary Carbon at α-Position of Nitrogen	12
True Homogeneous “Ligand-Free” Catalysis in Mizoroki–Heck Mono- and Double Arylations with Nonreactive Aryl Chlorides	12
Bridging Bis(boryl) and Borylene Species Stabilized in the Coordination Sphere of Ruthenium Metals	12
Anionic Property Is Crucial for the High Activities of Metalloligand Catalysts	12
Computational Study on the Role of Zn(II) Z-Type Ligands in Facilitating Diaryl Reductive Elimination from Pt(II)	12
Cycloheptyl-Fused Iminopyridine-Iron Catalysts for Isoprene Polymerization with Enhanced Activity and Thermal Stability	12
Structural Variety, Isomerism, and Interconversions of Polynuclear Samarium Complexes with Reduced 9,10-Phenanthrenequinone Ligand	11
(NHC)M Cores as Catalysts for the Olefin Aziridination Reaction (M = Cu, Ag, Au): Evidencing a Concerted Mechanism for the Nitrene Transfer Process	11
Carbon Dioxide Reduction by N -Phosphinoamidinate-Stabilized Silylenes	11
Ethylene Polymerization with Thermally Robust Vanadium(III) Tris(2-pyridyl)borate Complexes	11
Synthesis of [Fe2[(μ-SeCH2)2NH](CN)2(CO)4]2– and Related Iron Selenoates	11
Issue Publication Information	11
Flash Communication: Well-Defined Paramagnetic Polyhydrido-Bridged Iron–Iridium Clusters	11
Manganese(I) Pincer Complexes as Catalysts for Dehydrogenative Annulation: Direct Access to Biologically Relevant Heterocycles from Alcohols and 2′-Aminoacetophenones	11
Issue Editorial Masthead	11

Flash Communication: Multinuclear Zwitterionic Germylene with Ge4 Chain Motif	11
Employing a Two-Step Carbonylation and Condensation Approach to Expand the Scope of Hydroesterificative Polymerization	11
Synthesis, Electrochemistry, XPS, and DFT Calculations of α-Carbon-Bonded Gold(I) Ferrocenyl- and Ruthenocenyl-Containing β-Diketonato Complexes	11
Unsymmetrical Diborane(4) as a Precursor to PBP Boryl Pincer Complexes: Synthesis and Cu(I) and Pt(II) PBP Complexes with Unusual Structural Features	11
Phosphine-Phenoxide Nickel Catalysts for Ethylene/Acrylate Copolymerization: Olefin Coordination and Complex Isomerization Studies Relevant to the Mechanism of Catalysis	11
[B(O2C2(CF3)4)2]− ([FPB]−): Repurposing This Weakly Coordinating Anion for Solid-State Molecular Organometallic (SMOM) Chem	11
Issue Editorial Masthead	11
Issue Editorial Masthead	11
A Dinuclear Ir(III) Bis(thiophosphinite) Complex Formed by Unusual meta-C–H Activation at a Pincer Ligand	11
Cesium Reduction of a Lithium Diamidochloroberyllate	11
Iron-Catalyzed Hydrogenation of Alkyl Formates and Carbon Dioxide	11
A Hybrid Benzothiazolyl-NHC Ligand with a Flexible −CH2– Linker and Its Cationic Rh(I) Complex That Catalyzes the Olefin Hydrosilylation	11
Synthesis, Characterization, and Photophysical Properties of Dimethylgallium(III) 9,10-Dioxoanthraceneolates	11
Thiol-isocyanate Click Reaction for Rapid and Efficient Generation of a Library of Organofunctional Silanes	10
Issue Publication Information	10
Lewis Base and Metal Cation-Assisted Isomerization of Disilyne	10
Mechanism of Photocatalytic CO2 Reduction by Iron Spin-Crossover Complex with Copper Photosensitizer	10
Ion Pair Effects of Zwitterionic Ni/Pd Allyl Complexes Bearing an α-Sulfonate-β-diimine Ligand by Binding of B(C6F5)3 on Norbornene Polymerization	10
Nickel-Catalyzed Hydrocarboxylation of Terminal Unactivated Alkenes: Formation of Branched Carboxylic Acids and Competing Catalyst Deactivation from CO2 Reduction to CO	10
ZnEt2 as a Precatalyst for the Addition of Alcohols to Carbodiimides	10
Stable Hydrogen Energy Carrier That Stores One Electron in a Cobalt(I) Complex for More Than 3 Months	10
Well-Defined ENENES Re and Mn Complexes and Their Application in Catalysis: The Role of Potassium tert-Butoxide	10
Accessing Phase-Transfer Catalysts and a Phosphoramidite Ligand via the Asymmetric Intramolecular Hydroamination Reaction	10
Sn,P-Peri-Substituted Naphthalene as a Ligand for Transition Metals	10
Flash Communication: Flexibility of a Biologically Inspired Ligand Framework for Intramolecular C–H Activation	10
Issue Publication Information	10
Advancing Base Metal Catalysis through Data Science: Insight and Predictive Models for Ni-Catalyzed Borylation through Supervised Machine Learning	10
Elemental Aspects of Transition Metals Pertinent to Organometallic Chemistry: Properties, Periodicity, Curiosities, and Related Main Group Issues	10
Palladium-Catalyzed Carbonylation of Amines with Mo(CO)6 as the Carbonyl Source	10
Titanium-Catalyzed Hydrodehalogenation of Alkyl Halides	10
Flash Communication: Selective Benzylidene Insertion Reactions in Organoplatinum Complexes	10
Fluorinated N-Heterocyclic Carbene Silver(I) Complexes with High Cancer Cell Selectivity	10
Reversible C–CN Bond Cleavage by a Formal Dinickel(I) Hydride Cation	10
Competitive Double Friedel–Crafts 2,5- and 1′,2-Diacylation of Monophosphaferrocenes	10
Flash Communication: Pd2Zn2 Clusters from the Reduction of Palladium(II) Dichloride Precursors with Metallic Zinc	10
Issue Editorial Masthead	10
Structural and Reactivity Studies of a Homologous Series of Crown Ether-Supported Alkali-Metal Silyl Complexes	10
Catalytic Synthesis and Cyclometalation of (4-Ferrocenylphenyl)pyridines	10
Ring-Closing and Ring-Opening of closo -B 12 -Fused Carboxonium Ions: PIDA-Mediated Synthesis and Reac	10
Mechanistic Insights into Nickel–NHC-Catalyzed Alkene Isomerization: A Computational Study on Selectivity and Reactivity	10
Reactivity of Nickel Complexes Bearing P(C═X)P Ligands (X = O, N) Toward Diazoalkanes: Evidence for Phosphorus Ylide Intermediates	10
Overview of the Synthesis and Catalytic Reactivity of Transition Metal Complexes Based on C═P Bond Systems	10
Metallocenium Lewis Acid Catalysts for Use in Friedel–Crafts Alkylation and Diels–Alder Reactions	10
Palladacycle Catalyst Based on a Cyclopropane Monophosphine Ligand for the Suzuki–Miyaura Cross-Coupling Reaction	9
Synthesis and Chemical Redox Studies of Half-Sandwich Chromium Carbonyl Azobenzenes	9
Ring Size Effects on the Structures of Sandwich Compounds with a Stoichiometry of C12H12M (M = Ti–Ni)	9
Heterobimetallic Au I /M (M = Ru II , Ir III )	9
Ir-Catalyzed Selective Reductive N-Formylation and Transfer Hydrogenation of N-Heteroarenes	9
Advances in the Synthesis and Applications of N-Heterocyclic Carbene Metal Complexes with a Focus on the Weak Base Route	9
Tuning the Pyridone Scaffold within a Rhodium-NHC Platform for gem-Specific Alkyne Dimerization via a Ligand-Assisted Proton Shuttle Mechanism	9
Synthesis, Characterization, and Light Sensitivity in Titanium Piano Stool Alkyl and Sulfur Complexes, [(C5Me5)TiMe2R]n− (R = Me, SCPh3, S	9
Issue Editorial Masthead	9
Bis(N-cyclopropenio)-imidazol-2-ylidene: An N-Heterocyclic Carbene Bearing Two N-Cationic Substituents	9
Cobalt-Catalyzed Hydrogermylation of Nonactivated Alkenes Enabled by Photoirradiation	9
Theoretical Studies on Relative Stability of Cationic 1,10-Phenanthroline Palladium Complexes Bearing Alkyl Groups by Using Designed Alkane Templates	9
Ferrocene-Containing Desmuramylpeptides Adopt A Flexible Conformation and Exhibit NOD2 Agonistic Activity	9
Flash Communication: Synthesis and Characterization of an Iron(V) Thiolate Complex	9
Alkyne Hydrofunctionalization Mechanism Including an Off-Cycle Alkoxycarbene Deactivation Complex	9
Activation Mechanism of Nickel(0) N -Heterocyclic Carbene Catalysts Stabilized by Fumarate Ligands	9
Issue Editorial Masthead	9
Prospects for the Use of Al/Mg Cocatalysts (AlknAlCl3–n + Alk2Mg) in the Polymerization of Olefins. Studies of the Interactions between the Ac	9
Cationic Ni(II) Species and Their Application in Olefin Polymerizations	9
Understanding the Reaction Mechanism of Nickel-Catalyzed Enantioselective Arylative Activation of the Aromatic C–O Bond	9
Empowering Women in Organic Chemistry (EWOC) at Five Years: Giving Back and Getting Back	9
Reactivity of Methyl Diruthenium Complexes with the Bis(diphenylphosphino)methane (dppm) Ligand and Formation of Dinitrogen and Dihydrogen Complexes via Methane Loss	9
Substitution at a Coordinatively Saturated Aluminum Center Stabilized by Imidazolidin-2-imine	9
Predicting Dinitrogen Activation by Carborane-Based Frustrated Lewis Pairs	9
Activation of S–H Bond with Electrophilic Phosphinidenes	9
Silver Instead of Gold in Nitronyl Nitroxide Chemistry	9
Mechanistic Study of Silylacetylene Hydroboration Catalyzed by a Cobalt PN5P Pincer Complex: Catalytic Cycles Altering the Reaction Efficiency	9
Aerobic Electrochemical Csp3–N Coupling between Aliphatic Carboxylic Acids and N-heterocycles	9
Homo- and Heteroleptic Silylstannylenes: Synthesis, Structure and Use as Precursors to Bimetallic Compounds	9
A Three-Coordinate Cobalt(-I) Dinitrogen Complex	9
A Higher-Yielding Route for the Synthesis of Molecular Precursors to Thin Films of Gold by Atomic Layer Deposition	9
Alternate Geometries in the Cobalt-Catalyzed Hydroacylation of Dienes Facilitate a High Spin Mechanism: A Density Functional Theory Study	9
Coordination Ability of Phosphavinyl(oxo and thioxo)phosphoranes (P═C–P═X; X = O, S) toward Transition Metals	9
Conversion of an NHC-Stabilized Silyliumylidene to a Dicationic Silicon(IV) Complex Capable of CO2 Activation	9
Cp2Ti(II) Mediated Rearrangement of Cyclopropyl Imines	9
Early Transition Metals in Organometallic Chemistry	9
Pioneers and Influencers in Organometallic Chemistry: Alexander Nesmeyanov (1899–1980). Carbon and Hydrogen Are Good but What about the Other 100 Elements?	9
IPr# Complexes─Highly-Hindered, Sterically-Bulky Cu(I) and Ag(I) N-Heterocyclic Carbenes: Synthesis, Characterization, and Reactivity	9
Synthesis of Mono- and Acyclic Bis-aminoboranes via Controlled Hydroboration of Imines	9
Comparing Square-Planar RhI and IrI: Metal–Ligand Proton Tautomerism, Fluxionality, and Reactivity	8
Isolation of Base-Coordinated 1,4-Disilaquinones	8
Mechanistic Insights into Regioselective Arene Insertion Using Bis(phosphine) Cobalt(I) Hydrides to Form 1,3-Cyclohexadienes	8
Hydroxycarbonylation of Alkenes with Formic Acid Catalyzed by a Rhodium(III) Hydride Diiodide Complex Bearing a Bidentate Phosphine Ligand	8
Bifluorene-Bridged Ti(IV) Complex Via Titanium-Mediated In Situ C–C Coupling: Expanding the Structural Landscape of Olefin Polymerization Catalysts	8
Functionalization Strategy in 2D Flexible Zn(BTTB)-MOF for Improving Storage and Release of Anticancer Drugs: A Comprehensive Computational Investigation	8
Synthesis and Reactivity of a Dimeric Ni(I) Methyl Complex	8
Structural and Electronic Properties of Star-like Compounds with a Central Planar Carbon Atom and D nh	8
Issue Publication Information	8
Expanding the Utility of β-Diketiminate Ligands in Heavy Group VI Chemistry of Molybdenum and Tungsten	8
Advances and Applications in Catalysis with Earth-Abundant Metals	8
Synthesis and Cooperative Reactivity of Sterically Encumbered Silyl and Silylene ( t Bu	8
Copper-Catalyzed Domino Three-Component Benzannulation: Access to Isoquinolines	8