Organometallics

Article	Citations
Synthesis, Characterization, and Reactivity of Thioether-Ligated Organoiron(II) Complexes	92
The Challenging Reaction of Cyclopropenones with Benzamide Catalyzed by Rh(III): A Computational Study	49
Flash Communication: Carbon Monoxide Insertion and Ligand Modification with Pyridine(diimine) Iron Alkyl Complexes	45
Bis(Tetrathiafulvalenes) with Mixed Phosphine and Silane Double Bridges	42
Issue Editorial Masthead	39
Issue Editorial Masthead	39
Issue Publication Information	39
Issue Publication Information	35
Hydroalumination of 1,8-Diethynylanthracenes–Al-based Bis-Lewis-Acids and their Isomerization and Complexation Behavior	34
Mechanism and Selectivity Investigation of [Cu]/[Pd] Synergistic Catalyzed Borylfluoroallylation of Alkyne: A DFT Study	33
Alkyllithium Reagents as a Hidden Source of Lithium Hydride	32
Multisite Ligand Noninnocence of (CpN3)Fe(CO)3+ with Exogenous Hydride Donors: Kinetics and Mechanism	30
Formation of Bisvinylidene Complexes through Consecutive Alkyne–Vinylidene Rearrangements	30
Nickel-Catalyzed Arylation/Lactonization Cascade Reactions for the Synthesis of Bicyclo[3.2.1]lactones	30
Flash Communication: The [BPh 4 ] − Anion Is Stripped by Half-Sandwich Scandium Tetramethylalumina	29
Impact of Halide (Cl vs I) Identity on the Preferred Positioning of Substituents between Al and M (M = Co, Rh, Ir) in PAlP Pincer Complexes	29
Triptycepenes: Synthesis, Metal Complexes, and Their Reactivity in Catalytic Reactions	26
Ti-Catalyzed Multicomponent Synthesis of Pyrroles Using Allene Coupling Partners	26
Multiple C–B Bond Cleavage Reactions at [BArF4]− Anions Mediated by Terphenyl Phosphine Gold Catalysts	25
Pitfalls for POCOP-Type Palladium Pincer Complexes in Catalytic Reduction of CO2 with Catecholborane	25
Zintl Ions and Phases Promote the Catalytic Hydrophosphination of Alkynes, Alkenes, and Imines	25
Synthesis and Characterization of Rare-Earth Metal Complexes Bearing a 2-N,N-Dimethylamino-Ethylene-Imino-Functionalized Indolyl Ligand and Their Catalytic Activities Toward Hydrosilylat	24
Stereoselective Epoxidation of Unfunctionalized Aliphatic Alkenes with a Macrocyclic Tetra-NHC Iron(II) Catalyst	24
Oxidative Addition of Alkyl Iodides to [Sn(NMe2)2]2: In Situ Generation of RSn(NMe2)3 Compounds	24
Activity Enhancement of Phenoxy-Imine Titanium Catalysts via σ–π Synergy and Para-Substituent Effect	24

Ni(3,5-CF3stb)2(Et2O): A “Super-Naked” Nickel Complex	24
Direct Stereoselective Synthesis of a Single (ebthi)Ti(BINOLate) Catalyst Enantiomer	23
Carborane-Functionalized Thiocarbohydrazones: Synthesis, Computational, and Anticancer Evaluation	23
Flash Communication: (Ph 3 P) 2 N 2 ─Aza-Wittig	23
Reactions of Nickel(0)–Olefin Pincer Complexes with Terminal Alkynes: Cooperative C–H Bond Activation and Alkyne Coupling	23
Influence of Indole-N Substitution of Thiosemicarbazones in Cationic Ru(II)(η6-Benzene) Complexes on Their Anticancer Activity	22
Reactivity of Heterobimetallic Ion Pairs in Formic Acid Dehydrogenation	22
Synthesis and Surface Attachment of Molecular Re(I) Hydride Species with Silatrane Functionalized Bipyridyl Ligands	22
Cationic Half-Sandwich Ruthenium(II) Complexes of 2-Picolyl-Based N-Arylguanidines as Catalysts for the Aldehyde–Water Shift Reaction	22
Catalyst Design for Rh-Catalyzed Arene and Alkane C–H Borylation: The NHC Affects the Induction Period, and Indenyl is Superior to Cp	21
Steric and Electronic Effects Responsible for N,O- or N,N-Chelating Coordination of Pyrazolones Containing a Pyridine Ring in Ruthenium Arene Systems	21
Influence of the Counterion on the Activation of Nickel(σ-Aryl) Precatalysts	21
PCP Pincer Complexes of Titanium in the +3 and +4 Oxidation States	21
High-Throughput Approach in the Ring-Opening Polymerization of β-Butyrolactone Enables Rapid Evaluation of Yttrium Salan Catalysts	21
Understanding Precatalyst Activation and Speciation in Manganese-Catalyzed C–H Bond Functionalization Reactions	21
NIR-Absorbing TCBD and Expanded TCBD-Functionalized Ferrocene–Phenothiazine Conjugates	20
(κ3-N∩N∩N)-Palladium Pincer Complex-Catalyzed Synthesis of Quinazolin-4(3H)-Ones Through the Acceptorless Dehydrogenation Process: Experimental Results and Computational Insights	20
Effects of Alkyne Substituents and X-Ligands on Alkyne Insertion Reactions of RuHX(CO)(PPh 3 ) 3	20
Steric and Electronic Properties of Phosphinimide-Based Silylenes─The Influence of the Phosphine Moiety	20
Synthesis and Characterization of a Series of (PP R P)Co Complexes and Comparison of their Electronic Properties and Catalytic Activities	20
Synthesis, Reactivity, and Theoretical Insights of Co-Sb2 and Co-Bi2 Rings	19
Groups 9 and 10 Complexes of C–Donor Ligands Derived from Pyridinium-Stabilized Phosphorus Ylides	19
Chromium(III) Amino-bis(phenolate) Catalysts for the Ring-Opening Copolymerization of Epoxides and Phthalic Anhydride: Effects of Cocatalysts and Cyclohexene Oxide Initiators on Copolymerization Activ	19
Carbon Monoxide-Induced Mobility of Isolated Palladium Species on Silicon Dioxide at Room Temperature	19
Kinetic and Thermodynamic Pathways in the Reactions of Five-Membered Zircona- and Hafnacyclocumulenes with Acetonitrile. Structures and Mechanisms of Formation of the Obtained Complexes	19
Ruthenium-Catalyzed Formic Acid/Formate Dehydrogenation and Carbon Dioxide/(bi)carbonate Hydrogenation in Water	19
Ylide-Functionalized Phosphine (YPhos) Platinum Complexes: Synthesis and Application in Hydrosilylations under Mild Conditions	19
Oxidative Coupling of Ruthenium Alkenyl Acetylide Complexes as a Route to Dinuclear Complexes Featuring Carbon-Rich Bridging Ligands	19
Issue Editorial Masthead	18
Issue Editorial Masthead	18
A Contiguous Tricyclic [P6]2– Framework Spanning Across Two Vanadium(III) Centers	18
Back with the Flash Communication	18
Variable Kinetic Isotope Effect Reveals a Multistep Pathway for Protonolysis of a Pt–Me Bond	18
Heteroleptic Bis(amido) Ca(II) and Yb(II) NHC Pincer Complexes: Synthesis, Characterization, and Catalytic Activity in Intermolecular Hydrofunctionalization of C═C Bonds	18
Issue Publication Information	18
Heterometallic Clusters with Thorium–Rhodium Bonds Supported by Double-Layer Nitrogen–Phosphorus Ligands	18
Mechanism and Selectivity of Bi(V)-Aryl Oxyfunctionalization in Trifluoroacetic Acid Solvents	18
Revisiting C–C and C–H Bond Activation in Rhodium Pincer Complexes: Thermodynamics and Kinetics Involving a Common Agostic Intermediate	17
DFT Studies on the Early-Transition-Metal-Catalyzed Polymerization of Polar Monomers with a Methylene Spacer between Vinyl and Functional Groups	17
Carbene–Calcium Silylamides and Amidoboranes	17
Pentamethylcyclopentadienyl Metalloradical Iron Complexes Containing Redox Noninnocent α-Diimine-Type Ligands: Synthesis, Molecular, and Electronic Structures	17
CO Complexation by Ru(II) and Os(II) Porphyrin Complexes Sheds Light on the Relative Importance of Thermodynamic Stability and Kinetic Lability for CO Poisoning Antidotes	17
Metallapolycycles from the Coupling of Two Re–C Bonds	17
Mechanism of Nickel-Catalyzed Dual C–O Bond Activation in the Deoxygenation of Ethers via Reductive Cross-Coupling Reaction: A DFT Study	17
Correction to “DFT Study on the Mechanisms of Iron-Catalyzed Ortho C–H Homoallylation of Aromatic Ketones with Methylenecyclopropanes”	17
Flash Communication: Ir Complexes with a PhN(CH2CH2PiPr2)2 Pincer Ligand for Reversible CO2 Hydrogenation	17
Flash Communication: Density Functional Theory (DFT) Calculations Indicate an Unconventional Anagostic Complex for the Initial Stage of the Reported Sc3+ Boosted C–H Bond Activation of 3,4-	17
Photochemistry of RMn(CO)5 Complexes as Precursor Candidates for Photoassisted Chemical Vapor Deposition	16
Synthesis and Reactivity of Oxorhenium(V) Complexes Incorporating 2,6-Bis[(diphenyl)methyl]diamidopyridine (DPMDAP) Pincer Ligands as the Basic Component of Transition Metal Frustrated Lewi	16
p-Aryl-Substituted Iminopyridine Chromium Complexes as Precatalysts for Ethylene Polymerization: The Question of the Physical Oxidation State Examined by Experimental and Density Functional Stu	16

Tetramethylethylenediamine Stabilizes Organozinc Surface Intermediates against Chemical Etching but Not against Protodemetalation	16
Trapping an Unusual Ring-Opened Product of THF within a Lithium Hydrido Aluminate	16
Ligand Modifications on a Cp(quinolate)Ru Catalyst to Improve Its Stability in a Bio-orthogonal Deprotection Reaction	16
Diamidoamine Aluminum Complex as Effective Initiator for Random Copolymerization of Substituted Carbonate with L-Lactide	16
Divergent Approach for Tris-Heteroleptic Cyclometalated Iridium Complexes Using Triisopropylsilylethynyl-Substituted Synthons	16
Rhodium-Catalyzed Arene Alkenylation Using Benzoquinone Derivatives as Oxidants	16
Flash Communication: Strained and Bimetallic Structures of Rhodium and Iridium Germyl Complexes with Phosphinoamido Ligands	15
Saturated NHC-Stabilized Borenium, Boronium, Hydride-Bridged Boron Cations, and a Bora-Acyl Chloride	15
Mechanistic Aspects of Rhodium-Catalyzed Isoprene Hydroformylation: A Computational Study	15
Amines as Activating Ligands for Phosphine Palladium(II) Precatalysts: Effect of Amine Ligand Identity on the Catalyst Efficiency	15
Noninnocent Cyclopentadienyl Reactivity in an Al/Cr Heterobimetallic Complex	15
Ligand Reorganization in the Coordination Sphere of a CCC-NHC Pincer Fe Complex and Transient Absorption Spectroscopic Characterization of [(BuCiCiCBu)	15
Alternative Si–F Elimination and Fluoride Abstraction Pathways in Selective Monodefluorination of Me3SiCF3 and Me3SiCF2H	15
High-Temperature Solution-Phase Ethylene (Co)polymerization Catalyzed by a [O–N–P]TiBn2 Complex	15
Mechanism of Perfluoro-Nickelacyclopentane Formation from Tetrafluoroethylene: Effects of Ancillary Ligand Bite Angle	15
Synthesis and Reactivity of Low-Coordinate Iron(II) Alkyl Complexes toward Alkene Hydrogenation	15
Skeletal Rearrangement of a μ–η2:η4-Hexatrienyl Ligand at a Diruthenium Site via a μ–η5-Ruthenacyclohexadienyl Intermediate	15
Application of Bis(amido)alkyl Magnesiates toward the Synthesis of Molecular Rubidium and Cesium Hydrido-magnesiates	15
Metal Identity Effects in the Pincer Complex-Catalyzed Dehydrogenative Coupling of Formamides with Alcohols to Form Carbamates	15
Tailoring Catalyst Activity and Substrate Scope via Modular Design of Adaptive Tridentate Ligands for Alkyne Metathesis	15
The Intrinsic Barrier for N≡N Bond Cleavage or Formation Mediated by the Cp*Cr(dmpe) Fragment Is Insurmountable	15
Catalytic Hydrogenation of Terminal Alkenes by a (PPP) Pincer-Ligated Cobalt(II) Complex	14
Electrocatalytic Anaerobic Oxidation of Benzylic Amines Enabled by Ferrocene-Based Redox Mediators	14
Arene Insertion into the M–Cl Bond vs Addition-like Behavior of Arene and M–Cl Bond (M = Cu/Fe): A DFT Investigation of the Cu/Fe SET Mechanism of Arene sp2 C–H Chlorination	14
Bifunctional Hydroboration Catalyst Activation Using a Co SNS Amido Complex Bearing an Abnormal-NHC Ligand	14
Mechanistic Insights into Rh-Catalyzed Asymmetric Synthesis of Silicon-Stereogenic Silazanes: The Origin of Enantioselectivity	14
Revisiting the Fe(0) Sandwich Complex [Fe(C6Me6)2], Structural Solution to a 64-Year-Old Mystery	14
Molecular Weight Determination of Relevant Organometallic Catalysts in Solution by DOSY-NMR to Monitor Reactivity	14
Flash Communication: Termination of Carbodiimide ROMP with Isothiocyanates	14
Cytotoxicity of Ruthenium(II) Arene Complexes Containing Functionalized Ferrocenyl β-Diketonate Ligands	14
Issue Editorial Masthead	14
Issue Publication Information	13
Cycloheptyl-Fused Iminopyridine-Iron Catalysts for Isoprene Polymerization with Enhanced Activity and Thermal Stability	13
Iron–Aryloxide Complex Bearing Bis(dipyrromethene) Ligands for the Ring-Opening Polymerization of ε-Caprolactone	13
Reductive Elimination from Sterically Encumbered Ni–Polypyridine Complexes	13
Issue Editorial Masthead	13
Issue Publication Information	13
Organic Allene vs Organometallic Allene─Preference Toward Allylic Anionic Delocalization, Dative Bonding, and Tunable Reactivity	13
Issue Editorial Masthead	13
Carbon Nanotube-Supported Iron Complex Catalyzes 1-Hexene Dimerization	13
Pioneers and Influencers in Organometallic Chemistry: Professor John E. Ellis Takes Metals to the Limit	13
Issue Publication Information	12
Detection of the BICT State in a Borafluorene with High Stokes Shift Fluorescence	12
Structural Evidence for Aromatic Heterocycle N–O Bond Activation via Oxidative Addition	12
Synthesis and Characterization of Uranium Complexes Supported by Substituted Aryldimethylsilylanilide Ligands	12
Reduction of Nitrous Oxide and Binding of Carbon Dioxide by Acenaphthene-1,2-diimine Aluminum Compounds	12
Methyl-Branched Polyethylene Produced by Hafnocene Complexes Exhibiting Unconventional Dialkoxy Bridges	12
Heteroditopic Chelating NHC Ligand-Supported CoIII Complexes: Catalysts for the Reductive Functionalization of Carbon Dioxide under Ambient Conditions	12
Methane Activation by Different Early Actinide (Ac, Th, Pa, U, and Np) Oxides and Their Ions: A Density Functional Theory Investigation	12
Alkaline Earth Catalyzed CO2 Hydroboration into Acetal Derivatives Leading to C–S Bond Formation	12
Influencing α-Olefin Selectivity and PE-Wax Suppression Using Cyclohexyl-Fused 2-Imino-1,10-phenanthroline-iron Ethylene Oligomerization Catalysts	12
Synthesis of Mo(IV) para-Substituted Styrene Complexes and an Exploration of Their Conversion to 1-Phenethylidene Complexes	12
Synthesis and Reactivity of Dipalladated Derivatives of Terephthalaldehyde	12
Ruthenium Bis-Sulfonate Complexes: Synthesis and Application in Asymmetric Hydrogenation	12
Cobalt-Catalyzed Regio- and Stereoselective Hydrosilylation of Alk-2-ynes with Tertiary Silanes	12
Synthesis and Single-Crystal X-ray Structures of Sterically Hindered Three Half-Sandwich (η6-p-Cymene)ruthenium(II) Schiff Base Complexes: Catalytic Applications in Selective Monoalk	12
Controlled Polymerization of 3-Hexyne, 4-Octyne, and 5-Decyne by Nb(CHCMe2Ph)(NC6F5)[OC(CF3)3](PMe3)2 Catalyst: Structural	12
Development of Sandwich Compound-Based Planar Chiral Six-Membered NHC Ligands with Quaternary Carbon at α-Position of Nitrogen	12
Dehydrogenation of Formic Acid Catalyzed by an Osmium-Polyhydride: Relevance of Acid Assistance in the CO2 Formation Stage	12
Hydrogen Bond Patterning and Biological Activity of Ferrocene Conjugates with Homo- and Heterochiral Ala–Pro Dipeptides	12
Compounds with Chelating 3-Dimethylamino-1-propyl Ligands as Chemical Vapor Deposition Precursors. Synthesis and Characterization of M[(CH2)3NMe2]2 Complexe	12
NMR and DFT Characterization of Pd Complexes Observed during Pd-Catalyzed Arylation of Hydrodisilanes	11
Anionic Property Is Crucial for the High Activities of Metalloligand Catalysts	11
Manganese(I) Pincer Complexes as Catalysts for Dehydrogenative Annulation: Direct Access to Biologically Relevant Heterocycles from Alcohols and 2′-Aminoacetophenones	11
Issue Editorial Masthead	11
Cesium Reduction of a Lithium Diamidochloroberyllate	11
Palladium-Catalyzed Carbonylation of Amines with Mo(CO)6 as the Carbonyl Source	11
Unsymmetrical Diborane(4) as a Precursor to PBP Boryl Pincer Complexes: Synthesis and Cu(I) and Pt(II) PBP Complexes with Unusual Structural Features	11
Computational Study on the Role of Zn(II) Z-Type Ligands in Facilitating Diaryl Reductive Elimination from Pt(II)	11
(NHC)M Cores as Catalysts for the Olefin Aziridination Reaction (M = Cu, Ag, Au): Evidencing a Concerted Mechanism for the Nitrene Transfer Process	11
Living cis-1,4-Selective Polymerization of 1,3-Dienes by Enamino-Oxazolinate Rare-Earth Metal Complexes	11
True Homogeneous “Ligand-Free” Catalysis in Mizoroki–Heck Mono- and Double Arylations with Nonreactive Aryl Chlorides	11
Flash Communication: Bismuthinidenes as Lewis Bases in Reversible C(sp3)–O Bond Cleavage	11
Structural Variety, Isomerism, and Interconversions of Polynuclear Samarium Complexes with Reduced 9,10-Phenanthrenequinone Ligand	11
Stable Hydrogen Energy Carrier That Stores One Electron in a Cobalt(I) Complex for More Than 3 Months	11
Catalytic Synthesis and Cyclometalation of (4-Ferrocenylphenyl)pyridines	11
Structural and Reactivity Studies of a Homologous Series of Crown Ether-Supported Alkali-Metal Silyl Complexes	11
Issue Publication Information	11
Synthesis, Electrochemistry, XPS, and DFT Calculations of α-Carbon-Bonded Gold(I) Ferrocenyl- and Ruthenocenyl-Containing β-Diketonato Complexes	11
Issue Editorial Masthead	11

Flash Communication: Multinuclear Zwitterionic Germylene with Ge4 Chain Motif	11
Importance of Ligand Fine-Tuning: Alkyne Metathesis with Molybdenum Alkylidyne Complexes Supported by Phenyl-tert-butoxysilanolate Ligands	11
Updates to the Organometallics Team	11
Issue Editorial Masthead	11
Carbon Dioxide Reduction by N -Phosphinoamidinate-Stabilized Silylenes	11
Ion Pair Effects of Zwitterionic Ni/Pd Allyl Complexes Bearing an α-Sulfonate-β-diimine Ligand by Binding of B(C6F5)3 on Norbornene Polymerization	11
Synthesis, Characterization, and Photophysical Properties of Dimethylgallium(III) 9,10-Dioxoanthraceneolates	11
Overview of the Synthesis and Catalytic Reactivity of Transition Metal Complexes Based on C═P Bond Systems	11
A Hybrid Benzothiazolyl-NHC Ligand with a Flexible −CH2– Linker and Its Cationic Rh(I) Complex That Catalyzes the Olefin Hydrosilylation	11
Issue Editorial Masthead	11
Employing a Two-Step Carbonylation and Condensation Approach to Expand the Scope of Hydroesterificative Polymerization	11
A Dinuclear Ir(III) Bis(thiophosphinite) Complex Formed by Unusual meta-C–H Activation at a Pincer Ligand	11
Maurice Brookhart: A Legacy to Organometallic Chemistry	11
[B(O2C2(CF3)4)2]− ([FPB]−): Repurposing This Weakly Coordinating Anion for Solid-State Molecular Organometallic (SMOM) Chem	10
Mechanism of Photocatalytic CO2 Reduction by Iron Spin-Crossover Complex with Copper Photosensitizer	10
Flash Communication: Pd2Zn2 Clusters from the Reduction of Palladium(II) Dichloride Precursors with Metallic Zinc	10
Understanding and Designing of Bent Aromatic Heterometallabenzenes	10
Photochemical Synthesis of Five-Membered Zirconacyclocumulene Complex and Its Reactions with Ketones	10
Nickel-Catalyzed Hydrocarboxylation of Terminal Unactivated Alkenes: Formation of Branched Carboxylic Acids and Competing Catalyst Deactivation from CO2 Reduction to CO	10
Flash Communication: Well-Defined Paramagnetic Polyhydrido-Bridged Iron–Iridium Clusters	10
ZnEt2 as a Precatalyst for the Addition of Alcohols to Carbodiimides	10
Thiol-isocyanate Click Reaction for Rapid and Efficient Generation of a Library of Organofunctional Silanes	10
Competitive Double Friedel–Crafts 2,5- and 1′,2-Diacylation of Monophosphaferrocenes	10
Issue Publication Information	10
Bridging Bis(boryl) and Borylene Species Stabilized in the Coordination Sphere of Ruthenium Metals	10
Iron-Catalyzed Hydrogenation of Alkyl Formates and Carbon Dioxide	10
Well-Defined ENENES Re and Mn Complexes and Their Application in Catalysis: The Role of Potassium tert-Butoxide	10
Issue Publication Information	10
Synthesis of [Fe2[(μ-SeCH2)2NH](CN)2(CO)4]2– and Related Iron Selenoates	10
Crystal-Field Properties of Pentalene Ligands in Erbium(III) Sandwich Complexes	10
Flash Communication: Selective Benzylidene Insertion Reactions in Organoplatinum Complexes	10
Titanium-Catalyzed Hydrodehalogenation of Alkyl Halides	10
Fluorinated N-Heterocyclic Carbene Silver(I) Complexes with High Cancer Cell Selectivity	10
Reversible C–CN Bond Cleavage by a Formal Dinickel(I) Hydride Cation	10
Elemental Aspects of Transition Metals Pertinent to Organometallic Chemistry: Properties, Periodicity, Curiosities, and Related Main Group Issues	10
Mechanistic Insights into Nickel–NHC-Catalyzed Alkene Isomerization: A Computational Study on Selectivity and Reactivity	10
Ethylene Polymerization with Thermally Robust Vanadium(III) Tris(2-pyridyl)borate Complexes	10
Metallocenium Lewis Acid Catalysts for Use in Friedel–Crafts Alkylation and Diels–Alder Reactions	10
Issue Editorial Masthead	10
Reactivity of Nickel Complexes Bearing P(C═X)P Ligands (X = O, N) Toward Diazoalkanes: Evidence for Phosphorus Ylide Intermediates	10
Flash Communication: Flexibility of a Biologically Inspired Ligand Framework for Intramolecular C–H Activation	10
Ring-Closing and Ring-Opening of closo -B 12 -Fused Carboxonium Ions: PIDA-Mediated Synthesis and Reac	10
Issue Publication Information	10
Assembly of 3,5-Dihydroxy-4 H -selenopyran-4-one Core via Recyclization of Allomaltol Derivatives under Action of Triselenium Dicyanide	10
Sn,P-Peri-Substituted Naphthalene as a Ligand for Transition Metals	10
Activation of S–H Bond with Electrophilic Phosphinidenes	9
Alternate Geometries in the Cobalt-Catalyzed Hydroacylation of Dienes Facilitate a High Spin Mechanism: A Density Functional Theory Study	9
Comprehensive Mechanistic Analysis of Bismuth and Chloride Effects in Palladium-Catalyzed Aldol Reactions	9
A Higher-Yielding Route for the Synthesis of Molecular Precursors to Thin Films of Gold by Atomic Layer Deposition	9
Heterobimetallic Au I /M (M = Ru II , Ir III )	9
Understanding the Reaction Mechanism of Nickel-Catalyzed Enantioselective Arylative Activation of the Aromatic C–O Bond	9
Coordination Ability of Phosphavinyl(oxo and thioxo)phosphoranes (P═C–P═X; X = O, S) toward Transition Metals	9
Reactivity of Methyl Diruthenium Complexes with the Bis(diphenylphosphino)methane (dppm) Ligand and Formation of Dinitrogen and Dihydrogen Complexes via Methane Loss	9
Ir-Catalyzed Selective Reductive N-Formylation and Transfer Hydrogenation of N-Heteroarenes	9
Substitution at a Coordinatively Saturated Aluminum Center Stabilized by Imidazolidin-2-imine	9
Palladacycle Catalyst Based on a Cyclopropane Monophosphine Ligand for the Suzuki–Miyaura Cross-Coupling Reaction	9
Accessing Phase-Transfer Catalysts and a Phosphoramidite Ligand via the Asymmetric Intramolecular Hydroamination Reaction	9
Synthesis of Mono- and Acyclic Bis-aminoboranes via Controlled Hydroboration of Imines	9
Flash Communication: Synthesis and Characterization of an Iron(V) Thiolate Complex	9
Issue Editorial Masthead	9
Issue Editorial Masthead	9
Early Transition Metals in Organometallic Chemistry	9
Synthesis, Characterization, and Light Sensitivity in Titanium Piano Stool Alkyl and Sulfur Complexes, [(C5Me5)TiMe2R]n− (R = Me, SCPh3, S	9
Pioneers and Influencers in Organometallic Chemistry: Alexander Nesmeyanov (1899–1980). Carbon and Hydrogen Are Good but What about the Other 100 Elements?	9
Aerobic Electrochemical Csp3–N Coupling between Aliphatic Carboxylic Acids and N-heterocycles	9
Ring Size Effects on the Structures of Sandwich Compounds with a Stoichiometry of C12H12M (M = Ti–Ni)	9
Prospects for the Use of Al/Mg Cocatalysts (AlknAlCl3–n + Alk2Mg) in the Polymerization of Olefins. Studies of the Interactions between the Ac	9
Lewis Base and Metal Cation-Assisted Isomerization of Disilyne	9
Ferrocene-Containing Desmuramylpeptides Adopt A Flexible Conformation and Exhibit NOD2 Agonistic Activity	9
Activation Mechanism of Nickel(0) N -Heterocyclic Carbene Catalysts Stabilized by Fumarate Ligands	9
Bis(N-cyclopropenio)-imidazol-2-ylidene: An N-Heterocyclic Carbene Bearing Two N-Cationic Substituents	9
Homo- and Heteroleptic Silylstannylenes: Synthesis, Structure and Use as Precursors to Bimetallic Compounds	9
Synthesis and Chemical Redox Studies of Half-Sandwich Chromium Carbonyl Azobenzenes	9
Tuning the Pyridone Scaffold within a Rhodium-NHC Platform for gem-Specific Alkyne Dimerization via a Ligand-Assisted Proton Shuttle Mechanism	9
Empowering Women in Organic Chemistry (EWOC) at Five Years: Giving Back and Getting Back	9
Cationic Ni(II) Species and Their Application in Olefin Polymerizations	9
A Three-Coordinate Cobalt(-I) Dinitrogen Complex	9
Advances in the Synthesis and Applications of N-Heterocyclic Carbene Metal Complexes with a Focus on the Weak Base Route	9
Structural Investigation of the Anion Effect in Ruthenium(II) Arene Complexes Bearing Pyridyl-Triazole Ligands: Implications for Transfer Hydrogenation Catalysis	9
Issue Editorial Masthead	8
Isolation of Base-Coordinated 1,4-Disilaquinones	8
Advances and Applications in Catalysis with Earth-Abundant Metals	8
Catalyst Activation and Speciation Involving DyadPalladate Precatalysts in Suzuki–Miyaura and Buchwald–Hartwig Cross-Couplings	8
Unusual Regioselectivity in Palladium-Catalyzed Cyclization of 6-(Pronucleophile-tethered)-3-bromo-1,3-hexadienes: Experimental Observations and Theoretical Rationales	8
Issue Editorial Masthead	8
Synthesis and Cooperative Reactivity of Sterically Encumbered Silyl and Silylene ( t Bu	8
Structural and Electronic Properties of Star-like Compounds with a Central Planar Carbon Atom and D nh	8
Silox Titanium(II) and Masked Ti(II) Derivatives (Silox = t Bu 3 SiO): Titanacycles, Dinitrogen Sp	8
Expanding the Utility of β-Diketiminate Ligands in Heavy Group VI Chemistry of Molybdenum and Tungsten	8
Redox Activation of Acyclic (Aryl)(amino)carbene Gold(I) Complexes	8
Reactivity of Cyclopropenylaluminates	8
Mechanistic Insights into Regioselective Arene Insertion Using Bis(phosphine) Cobalt(I) Hydrides to Form 1,3-Cyclohexadienes	8
Reductive Head-to-Head Coupling of Phenylacetylenes in the Coordination Sphere of an Osmium-Polyhydride	8
Controllable Hydrosilylation and Dehydrogenative Silylation of Alkenes Catalyzed by a Manganese Alkyl Complex	8
Flash Communication: Isolable Stibinidene Chalcogenide Radical Anions	8