Organometallics

Papers
(The median citation count of Organometallics is 3. The table below lists those papers that are above that threshold based on CrossRef citation counts [max. 250 papers]. The publications cover those that have been published in the past four years, i.e., from 2020-03-01 to 2024-03-01.)
ArticleCitations
Synthesis and Structure of Arene Ru(II) NO-Chelating Complexes: In Vitro Cytotoxicity and Cancer Cell Death Mechanism131
An Update on Multiple Bonding between Heavier Main Group Elements: The Importance of Pauli Repulsion, Charge-Shift Character, and London Dispersion Force Effects84
Quantifying the Electronic and Steric Properties of 1,3-Imidazole-Based Mesoionic Carbenes (iMICs)46
Di-ortho-beryllated Carbodiphosphorane: A Compound with a Metal–Carbon Double Bond to an Element of the s-Block43
Carbon Dioxide Hydrogenation to Formate Catalyzed by a Bench-Stable, Non-Pincer-Type Mn(I) Alkylcarbonyl Complex43
Solvent-Free N-Alkylation and Dehydrogenative Coupling Catalyzed by a Highly Active Pincer-Nickel Complex40
Synthesis of Pyridines, Quinolines, and Pyrimidines via Acceptorless Dehydrogenative Coupling Catalyzed by a Simple Bidentate P^N Ligand Supported Ru Complex38
Bimetallic Aluminum Complexes Bearing Binaphthyl-Based Iminophenolate Ligands as Catalysts for the Synthesis of Polyesters37
A Comparison of Two Zinc Hydride Catalysts for Terminal Alkyne C–H Borylation/Hydroboration and the Formation of 1,1,1-Triborylalkanes by Tandem Catalysis Using Zn–H and B–H Compounds36
Ni(4-tBustb)3: A Robust 16-Electron Ni(0) Olefin Complex for Catalysis35
Ready Approach to Organophosphines from ArCl via Selective Cleavage of C–P Bonds by Sodium32
Coordination Behavior of Acylthiourea Ligands in Their Ru(II)–Benzene Complexes─Structures and Anticancer Activity32
Synthesis of Branched Polyethylene and Ethylene-MA Copolymers Using Unsymmetrical Iminopyridyl Nickel and Palladium Complexes32
Manganese-Catalyzed Hydrogenation of Ketones under Mild and Base-free Conditions31
Evaluation of the Electrocatalytic Reduction of Carbon Dioxide using Rhenium and Ruthenium Bipyridine Catalysts Bearing Pendant Amines in the Secondary Coordination Sphere30
Recent Advances in C(sp3)–C(sp3) Cross-Coupling Chemistry: A Dominant Performance of Nickel Catalysts29
Direct (Hetero)arylation of Heteroarenes Catalyzed by Unsymmetrical Pd-PEPPSI-NHC Complexes under Mild Conditions28
Lewis Acidic Telluronium Cations: Enhanced Chalcogen-Bond Donor Properties and Application to Transfer Hydrogenation Catalysis28
High Lewis Acidity at Planar, Trivalent, and Neutral Bismuth Centers28
Disubstituted Ferrocenyl Iodo- and Chalcogenoalkynes as Chiral Halogen and Chalcogen Bond Donors27
Tuning the Donor−π–Acceptor Character of Arylborane–Arylamine Macrocycles25
Manganese-Catalyzed C(α)-Alkylation of Oxindoles with Secondary Alcohols via Borrowing Hydrogen25
Synthesis and Characterization of a Tetradentate, N-Heterocyclic Carbene Copper(II) Complex and Its Use as a Chan–Evans–Lam Coupling Catalyst24
Effect of Quaternary Phosphonium Salts as Cocatalysts on Epoxide/CO2 Copolymerization Catalyzed by salen-Type Cr(III) Complexes24
Switchable β-alkylation of Secondary Alcohols with Primary Alcohols by a Well-Defined Cobalt Catalyst24
A Tutorial on Selectivity Determination in C(sp2)–H Oxidative Addition of Arenes by Transition Metal Complexes23
Probing the Limits of Oxidative Addition of C(sp3)–X Bonds toward Selected N,C,N-Chelated Bismuth(I) Compounds23
Diaryl Ether Formation Merging Photoredox and Nickel Catalysis23
Isolation and Reactivity of Chlorotetryliumylidenes Using a Bidentate Bis(N-heterocyclic imine) Ligand23
Update for Reactions of Group 4 Metallocene Bis(trimethylsilyl)acetylene Complexes: A Never-Ending Story?23
Cationic PCP and PCN NHC Core Pincer-Type Mn(I) Complexes: From Synthesis to Catalysis23
A Dual Steric Enhancement Strategy in α-Diimine Nickel and Palladium Catalysts for Ethylene Polymerization and Copolymerization23
Bimetallic Bis-NHC-Ir(III) Complex Bearing 2-Arylbenzo[d]oxazolyl Ligand: Synthesis, Catalysis, and Bimetallic Effects22
Dinuclear Gold(I) Complexes Bearing Alkyl-Bridged Bis(N-heterocyclic carbene) Ligands as Catalysts for Carboxylative Cyclization of Propargylamine: Synthesis, Structure, and Kinetic and Mechanistic Co22
Highly Selective Hydroboration of Carbonyls by a Manganese Catalyst: Insight into the Reaction Mechanism22
Synthesis of Overloaded Cyclopentadienyl Rhodium(III) Complexes via Cyclotetramerization of tert-Butylacetylene22
Fragmentation of White Phosphorus by a Cyclic (Alkyl)(Amino)Alumanyl Anion22
Cyclometalated Ni(II) Complexes [Ni(NCN)X] of the Tridentate 2,6-di(2-pyridyl)phen-ide Ligand22
Enantioselectivity in the Noyori–Ikariya Asymmetric Transfer Hydrogenation of Ketones22
Non-Pincer-Type Arene Ru(II) Catalysts for the Direct Synthesis of Azines from Alcohols and Hydrazine under Aerobic Conditions22
A Rare Intramolecular Au···H–C(sp3) Interaction in a Gold(I) N-Heterocyclic Carbene22
Activation of Nitrogen-Rich Substrates by Low-Valent, Redox-Active Aluminum Species22
NHC-Palladium(II) Mononuclear and Binuclear Complexes Containing Phenylene-Bridged Bis(thione) Ligands: Synthesis, Characterization, and Catalytic Activities21
Synthesis of Anthracene-Bridged Dinuclear Phenoxyiminato Organotitanium Catalysts with Enhanced Activity, Thermal Stability, and Comonomer Incorporation Ability toward Ethylene (Co)polymerization21
Stable Au(III) Complexes Bearing Hemilabile PN and CN Ligands: Coordination of the Pendant Nitrogen upon Oxidation of Gold21
Enhancing Thermal Stability in Aminopyridine Iron(II)-Catalyzed Polymerization of Conjugated Dienes21
Switchable Imine and Amine Synthesis Catalyzed by a Well-Defined Cobalt Complex21
A Bidentate Ru(II)-NC Complex as a Catalyst for Semihydrogenation of Alkynes to (E)-Alkenes with Ethanol21
To Bind or Not to Bind: Mechanistic Insights into C–CO2 Bond Formation with Late Transition Metals21
Catalytic Hydrogenation of Alkenes and Alkynes by a Cobalt Pincer Complex: Evidence of Roles for Both Co(I) and Co(II)20
Fluorescent Lewis Adducts: A Practical Guide to Relative Lewis Acidity20
Piano-Stool Iron Complexes as Precatalysts for gem-Specific Dimerization of Terminal Alkynes20
Influence of the Lewis Base Ph3PO on the Reactivity of the Uranium Phosphinidene (η5-C5Me5)2U(═P-2,4,6-iPr3C620
Methylene-Linked Bis-NHC Half-Sandwich Ruthenium Complexes: Binding of Small Molecules and Catalysis toward Ketone Transfer Hydrogenation20
Palladium(II) N^O Chelating Complexes Catalyzed One-Pot Approach for Synthesis of Quinazolin-4(3H)-ones via Acceptorless Dehydrogenative Coupling of Benzyl Alcohols and 2-Aminobenzamide20
Two-Fold Reduction of Dibenzo[a,e]cyclooctatetraene with Group 1 Metals: From Lithium to Cesium20
Structural and Redox Variations in Technetium Complexes Supported by m-Terphenyl Isocyanides20
An Illustrated Guide to Schlenk Line Techniques20
Pincer-Nickel Catalyzed Selective Guerbet-Type Reactions20
Fe(0)-Mediated Reductive Disproportionation of CO220
Mechanistic Insights into C–H Borylation of Arenes with Organoiridium Catalysts Embedded in a Microporous Metal–Organic Framework20
Manganese Diphosphine and Phosphinoamine Complexes Are Effective Catalysts for the Production of Biofuel Alcohols via the Guerbet Reaction20
Ligand-Controlled Regiodivergent Hydrosilylation of Conjugated Dienes Catalyzed by Mono(phosphine)palladium(0) Complexes20
C(sp2)–H Borylation of Heterocycles by Well-Defined Bis(silylene)pyridine Cobalt(III) Precatalysts: Pincer Modification, C(sp2)–H Activation, and Catalytically Relevant Intermedi20
A Positive Charge in the Outer Coordination Sphere of an Artificial Enzyme Increases CO2 Hydrogenation19
σ-Bond Migration Assisted Decarboxylative Activation of Vinylene Carbonate in Rh-Catalyzed 4 + 2 Annulation: A Theoretical Study19
Osmium- and Iridium-Promoted C–H Bond Activation of 2,2′-Bipyridines and Related Heterocycles: Kinetic and Thermodynamic Preferences19
Tuning Activity and Selectivity during Alkyne Activation by Gold(I)/Platinum(0) Frustrated Lewis Pairs19
Probing Electronic Properties of Triazolylidenes through Mesoionic Selones, Triazolium Salts, and Ir-Carbonyl-Triazolylidene Complexes19
Chiral NCN Pincer Iridium(III) Complexes with Bis(imidazolinyl)phenyl Ligands: Synthesis and Application in Enantioselective C–H Functionalization of Indoles with α-Aryl-α-diazoacetates19
Synthesis of a Molybdenum Hydrido(hydrogermylene) Complex and Its Conversion to a Germylyne Complex: Another Route through Dehydrogenation with Nitriles19
Computational Investigations of Enantioselection in Carbon–Carbon Bond Forming Reactions of Ruthenium Guanidinobenzimidazole Second Coordination Sphere Hydrogen Bond Donor Catalysts19
5-C5Me5)2U(=P-2,4,6-tBu3C6H2)(OPMe3) Revisited—Its Intrinsic Reactivity toward Small Organic19
[CNC]-Pincer Cobalt Hydride Catalyzed Distinct Selective Hydrosilylation of Aryl Alkene and Alkyl Alkene19
Cobalt-Catalyzed Ammonia Borane Dehydrogenation: Mechanistic Insight and Isolation of a Cobalt Hydride-Amidoborane Complex19
Cationic Nickel(II)-Catalyzed Hydrosilylation of Alkenes: Role of P, N-Type Ligand Scaffold on Selectivity and Reactivity18
Platinum(II) 1,2,4-Triazolin-5-ylidene Complexes: Stereoelectronic Influences on Their Catalytic Activity in Hydroelementation Reactions18
Computational Assessment of Counterion Effect of Borate Anions on Ethylene Polymerization by Zirconocene and Hafnocene Catalysts18
Styryl-Functionalized Cage Silsesquioxanes as Nanoblocks for 3-D Assembly18
Reactivity of [Pt(PtBu3)2] with Zinc(I/II) Compounds: Bimetallic Adducts, Zn–Zn Bond Cleavage, and Cooperative Reactivity18
Investigation into the Organobismuth Dismutation and Its Use for Rational Synthesis of Heteroleptic Triarylbismuthanes, Ar12Ar2Bi18
Rational Design of Cobalt Complexes Based on the trans Effect of Hybrid Ligands and Evaluation of their Catalytic Activity in the Cycloaddition of Carbon Dioxide with Epoxide18
Comparative Insertion Reactivity of CO, CO2, tBuCN, and tBuNC into Thorium– and Uranium–Phosphorus Bonds18
Hetero- and Homobimetallic Complexes Bridged by a Bis(NHC) Ligand: Synthesis via Selective Sequential Metalation and Catalytic Applications in Tandem Organic Transformations18
Development of Group 4 Metal Complexes Bearing Fused-Ring Amido-Trihydroquinoline Ligands with Improved High-Temperature Catalytic Performance toward Olefin (Co)polymerization17
Expanding the Scope of Palladium-Catalyzed B–N Cross-Coupling Chemistry in Carboranes17
Catalytic Deoxygenation of Amine and Pyridine N-Oxides Using Rhodium PCcarbeneP Pincer Complexes17
Single-Crystal-to-Single-Crystal [2 + 2] Photodimerization Involving B←N Coordination with Generation of a Thiophene Host17
Upgrading of Ethanol to n-Butanol via a Ruthenium Catalyst in Aqueous Solution17
Aromaticity of 1-Heterocyclopropenes Containing an Atom of Group 14 or 417
Bridging the Gap from Mononuclear PdII Precatalysts to Pd Nanoparticles: Identification of Intermediate Linear [Pd3(XPh3)4]2+ Clusters as Catalyt17
Cross-Dehydrocoupling of Amines and Silanes Catalyzed by Magnesocenophanes17
Photophysical Properties of Phosphorescent Mono- and Bimetallic Platinum(II) Complexes with CC* Cyclometalating NHC Ligands17
Bis(phosphine)cobalt-Catalyzed Highly Regio- and Stereoselective Hydrosilylation of 1,3-Diynes17
Bidentate NHC-Cobalt Catalysts for the Hydrogenation of Hindered Alkenes17
Synthesis, Structure and Physical Properties of “Wire-like” Metal Complexes17
Cationic α-Diimine Nickel and Palladium Complexes Incorporating Phenanthrene Substituents: Highly Active Ethylene Polymerization Catalysts and Mechanistic Studies of syn/anti Isomerizati17
Synthesis of Carbophosphinocarbene and Their Donating Ability: Expansion of the Carbone Class17
Proton-responsive Ruthenium(II) Catalysts for the Solvolysis of Ammonia-Borane17
Bis(tridentate) Iron(II) Complexes with a Cyclometalating Unit: Photophysical Property Enhancement with Combinatorial Strong Ligand Field Effect17
Catalytic C–H Bond Alkylation of Azoles with Alkyl Halides Mediated by Nickel(II) Complexes of Phenanthridine-Based N^N^N Pincer Ligands17
Cobalt(−I)- and Rhodium(−I)-Mediated Dearylation of N-Aryl N-Heterocyclic Carbene Ligands16
Repercussion of a 1,3-Hydrogen Shift in a Hydride-Osmium-Allenylidene Complex16
Additive-Free Formic Acid Dehydrogenation Catalyzed by a Cobalt Complex16
Adaptive σ Aromaticity and Triplet Ground State in Tetraatomic Boron Species16
Alkali-Metal Compounds with Bio-Based Ligands as Catalysts for Isoselective Lactide Polymerization: Influence of the Catalyst Aggregation on the Polymerization Control16
Silane Activation with Cobalt on the POCOP Pincer Ligand Platform16
Adaptive Aromaticity in Metallasilapentalynes16
Experimental and Computational Analysis of CO2 Addition Reactions Relevant to Copper-Catalyzed Boracarboxylation of Vinyl Arenes: Evidence for a Phosphine-Promoted Mechanism16
Synthesis of Boryl-Substituted Disilane, Disilene, and Silyl Cation16
Deoxygenation of Primary Amides to Amines with Pinacolborane Catalyzed by Ca[N(SiMe3)2]2(THF)216
Structural, Electronic, and Catalytic Modulation of Chelating Pyridylideneamide Ruthenium(II) Complexes16
Alkaline Earth Metal Aluminates as Catalysts for Imine Hydrogenation16
Synthesis of NHC-Iridium(III) Complexes Based on N-Iminoimidazolium Ylides and Their Use for the Amine Alkylation by Borrowing Hydrogen Catalysis16
Copolymerization of Ethylene and Long-Chain Functional α-Olefins by Dinuclear Zirconium Catalysts16
Comparison of Magnesium and Zinc in Cationic π-Arene and Halobenzene Complexes16
An Annelated Mesoionic Carbene (MIC) Based Ru(II) Catalyst for Chemo- and Stereoselective Semihydrogenation of Internal and Terminal Alkynes16
An Air-Stable N-Heterocyclic [PSiP] Pincer Iron Hydride and an Analogous Nitrogen Iron Hydride: Synthesis and Catalytic Dehydration of Primary Amides to Nitriles16
Pd–PEPPSI N-Heterocyclic Carbene Complexes from Caffeine: Application in Suzuki, Heck, and Sonogashira Reactions16
Cooperativity in Highly Active Ethylene Dimerization by Dinuclear Nickel Complexes Bearing a Bifunctional PN Ligand16
C–H Bond Activation via U(II) in the Reduction of Heteroleptic Bis(trimethylsilyl)amide U(III) Complexes16
Fluorinated Cycloplatinated(II) Complexes Bearing Bisphosphine Ligands as Potent Anticancer Agents16
Carboxylation of the Ni–Me Bond in an Electron-Rich Unsymmetrical PCN Pincer Nickel Complex16
Chiral-at-Metal Ruthenium Complexes with Guanidinobenzimidazole and Pentaphenylcyclopentadienyl Ligands: Synthesis, Resolution, and Preliminary Screening as Enantioselective Second Coordination Sphere16
Dihydroboration of Alkyl Nitriles Catalyzed by an Osmium-Polyhydride: Scope, Kinetics, and Mechanism16
Design and Synthesis of Luminescent Bis(isocyanoborato) Rhenate(I) Complexes as a Selective Sensor for Cyanide Anion15
Effects of Axial Solvent Coordination to Dirhodium Complexes on the Reactivity and Selectivity in C–H Insertion Reactions: A Computational Study15
Reactivities of Silaimines with Boranes: From Cooperative B–H Bond Activation to Donor Stabilized Silyl Cation15
Mechanistic Study of Alkene Hydrosilylation Catalyzed by a β-Dialdiminate Cobalt(I) Complex15
Syntheses of “Phosphine-Free” Molybdenum Oxo Alkylidene Complexes through Addition of Water to Alkylidyne Complexes15
N,N′-Dipp-o-phenylene-diamido Dianion: A Versatile Ligand for Main Group Metal–Metal-Bonded Compounds15
Understanding Catalyst Structure–Selectivity Relationships in Pd-Catalyzed Enantioselective Methoxycarbonylation of Styrene15
Osmium-Promoted Transformation of Alkyl Nitriles to Secondary Aliphatic Amines: Scope and Mechanism15
A Mild One-Pot Reduction of Phosphine(V) Oxides Affording Phosphines(III) and Their Metal Catalysts15
Mechanistic Insights into the Nickel-Catalyzed Regioselective Carboxylation of Allylic Alcohols15
Iron Versus Ruthenium: Evidence for the Distinct Differences in the Electronic Structures of Hexa-1,3,5-triyn-1,6-diyl-bridged Complexes [Cp*(dppe)M}{μ-(C≡C)3}{M(dppe)Cp*}]+ (M =15
Pd-Catalyst Containing a Hemilabile P,C-Hybrid Ligand in Amino Dicarbonylation of Aryl Halides for Synthesis of α-Ketoamides15
Making Base-Assisted C–H Bond Activation by Cp*Co(III) Effective: A Noncovalent Interaction-Inclusive Theoretical Insight and Experimental Validation15
Vanadium(V) Arylimido Alkylidene N-Heterocyclic Carbene Alkyl and Perhalophenoxy Alkylidenes for the Cis, Syndiospecific Ring Opening Metathesis Polymerization of Norbornene15
Benzylnickel(II) Complexes of 2-Iminopyrrolyl Chelating Ligands: Synthesis, Structure, and Catalytic Oligo-/Polymerization of Ethylene to Hyperbranched Polyethylene15
Metal-Free Room-Temperature Phosphorescence from Amorphous Triarylborane-Based Biphenyl15
N-Heterocyclic Carbene Complexes of Nickel, Palladium, and Iridium Derived from Nitron: Synthesis, Structures, and Catalytic Properties15
Catalytic Deoxygenation of Nitroarenes Mediated by High-Valent Molybdenum(VI)–NHC Complexes15
Micellar Catalysis as a Tool for C–H Bond Functionalization toward C–C Bond Formation15
Organometallic Uranyl Complexes Featuring a Carbodicarbene Ligand15
Synthesis, Reactivity, and Coordination of Semihomologous dppf Congeners Bearing Primary Phosphine and Primary Phosphine Oxide Groups15
Oxidative Addition of Aryl Halides to a Triphosphine Ni(0) Center to Form Pentacoordinate Ni(II) Aryl Species14
Carbon–Carbon Bond Coupling of Vinyl Molecules with an Allenyl Ligand at a Diruthenium Complex14
Dual Photoredox-/Palladium-Catalyzed Cross-Electrophile Couplings of Polyfluoroarenes with Aryl Halides and Triflates14
N–H and C–H Bond Activations of an Isoindoline Promoted by Iridium- and Osmium-Polyhydride Complexes: A Noninnocent Bridge Ligand for Acceptorless and Base-Free Dehydrogenation of Secondary Alcohols14
One-Electron Reduction of Ti(IV) Complex by Dialkylaluminum(I) Anion Giving the Ti(III) Species14
Structural Features of Polymer Ligand Environments Dramatically Affect the Mechanical and Room-Temperature Self-Healing Properties of Cobalt(II)-Incorporating Polysiloxanes14
Beyond Ni{N(SiMe3)2}2: Synthesis of a Stable Solvated Sodium Tris-Amido Nickelate14
Enantioconvergent and Regioselective Synthesis of Allenylsilanes by Nickel-Catalyzed C(sp2)–C(sp3) Cross-Coupling Starting from Racemic α-Silylated Propargylic Bromides14
A DFT Protocol for the Prediction of 31P NMR Chemical Shifts of Phosphine Ligands in First-Row Transition-Metal Complexes14
Synthesis, Structure, and Reactivity of the Uranium Bipyridyl Complex [{η5-1,2,4-(Me3Si)3C5H2}2U(bipy)]14
Comparative Mechanistic Study on the [Au(NHC)]+-Catalyzed Hydration of Alkynes, Alkenes, and Allenes14
Use of Ligand Steric Properties to Control the Thermodynamics and Kinetics of Oxidative Addition and Reductive Elimination with Pincer-Ligated Rh Complexes14
1,2-Disubstituted Planar Chiral Ferrocene Derivatives from Sulfonamide-Directed ortho-Lithiation: Synthesis, Absolute Configuration, and Chiroptical Properties14
Influence of the 1,3-Bis(trimethylsilyl)cyclopentadienyl Ligand on the Reactivity of the Uranium Phosphinidene [η5-1,3-(Me3Si)2C5H3]2U14
A Practical Synthesis of [(tmeda)Ni(CH3)2], Isotopically Labeled [(tmeda)Ni(13CH3)2], and Neutral Chelated-Nickel Methyl Complexes14
Synthesis of PdII Complexes Bearing pNHC Ligands by Oxidative Addition of 8-Halogenotheophyllines and 8-Bromoadenine to Pd014
Synthesis and Ethylene Reactivity of Dinuclear Iron and Cobalt Complexes Supported by Macrocyclic Bis(pyridine-diimine) Ligands Containing o-Terphenyl Linkers14
Diboron-Promoted Reduction of Ni(II) Salts: Precatalyst Activation Studies Relevant to Ni-Catalyzed Borylation Reactions14
Influence of the N→Ru Coordinate Bond Length on the Activity of New Types of Hoveyda–Grubbs Olefin Metathesis Catalysts Containing a Six-Membered Chelate Ring Possessing a Ruthenium–Nitrogen Bond14
Palladacycle-Catalyzed Olefinic C–P Cross-Coupling of Alkenylsulfonium Salts with Diarylphosphines to Access Alkenylphosphines14
Synthesis, Characterization, and Antimicrobial Activity of RhIII and IrIII N-Heterocyclic Carbene Piano-Stool Complexes14
Synthesis of the Cationic Gallium Phthalocyanines and Their Catalytic Application in Gallium(III)-Activated Processes for Donor–Acceptor Substrates14
Hypercrosslinked Polymer Platform-Anchored Single-Site Heterogeneous Pd–NHC Catalysts for Diverse C–H Functionalization14
Metallacarborane Assemblies as Effective Antimicrobial Agents, Including a Highly Potent Anti-MRSA Agent14
Copper-Catalyzed Azide–Alkyne Cycloaddition (CuAAC) by Functionalized NHC-Based Polynuclear Catalysts: Scope and Mechanistic Insights14
A Proton-Responsive Annulated Mesoionic Carbene (MIC) Scaffold on Ir Complex for Proton/Hydride Shuttle: An Experimental and Computational Investigation on Reductive Amination of Aldehyde14
Bulky o-Phenylene-Bridged Bimetallic α-Diimine Ni(II) and Pd(II) Catalysts in Ethylene (Co)polymerization14
Electrochemically Driven and Acid-Driven Pyridine-Directed ortho-Phosphorylation of C(sp2)–H Bonds14
Generation of a Ni3 Phosphinidene Cluster from the Ni(0) Synthon, Ni(η3-CPh3)214
Reactivity of an Unprotected Mesoionic N-Heterocyclic Olefin14
Controlled Activation of Dipicolinyl-Substituted Propargylic Alcohol by Ru(II) and Os(II) for Unprecedented Indolizine-Fused Metallafuran Complexes13
Lewis Acid Effects on Calculated Ligand Electronic Parameters13
A Robust Vanadium(V) Tris(2-pyridyl)borate Catalyst for Long-Lived High-Temperature Ethylene Polymerization13
Pincer-Cobalt-Catalyzed Guerbet-Type β-Alkylation of Alcohols in Air under Microwave Conditions13
A Stiboranyl Platinum Triflate Complex as an Electrophilic Catalyst13
Ferrocene Adsorbed on Silica and Activated Carbon Surfaces: A Solid-State NMR Study of Molecular Dynamics and Surface Interactions13
[P,C]-Chelate Cobalt(III) Hydride Catalyzed Hydrosilylation of Alkenes13
Highly Reactive Cationic Molybdenum Alkylidyne N-Heterocyclic Carbene Catalysts for Alkyne Metathesis13
Iron-Mediated C–C Bond Formation via Reductive Coupling with Carbon Dioxide13
Cationic Copper Iminophosphorane Complexes as CuAAC Catalysts: A Mechanistic Study13
Knölker Iron Catalysts for Hydrogenation Revisited: A Nonspectator Solvent and Fine-Tuning13
Well-Defined Cationic Cobalt(I) Precatalyst for Olefin-Alkyne [2 + 2] Cycloaddition and Olefin-Diene Hydrovinylation Reactions: Experimental Evidence for Metallacycle Intermediates13
Synthesis of an NHC-Coordinated Dialkyldisilavinylidene and Its Oxidation Providing a Silicon Analog of an Acetolactone13
Electrochemical CO2 Reduction — The Effect of Chalcogenide Exchange in Ni-Isocyclam Complexes13
Activation of an α-Diimine Ni(II) Precatalyst with AlMe3 and AliBu3: Catalytic and NMR and EPR Spectroscopy Studies13
Synthesis, Reactivity, and Insights into the Lewis Acidity of Mononuclear Titanocene Imido Complexes Bearing Sterically Demanding Terphenyl Moieties13
Terminal-Selective C(sp3)–H Arylation: NiH-Catalyzed Remote Hydroarylation of Unactivated Internal Olefins13
Behavior of Lewis Bases toward Diphenylberyllium13
Effect of Ligand Backbone on the Selectivity and Stability of Rhodium Hydroformylation Catalysts Derived from Phospholane-Phosphites13
Mono- and Dinuclear α-Diimine Nickel(II) and Palladium(II) Complexes in C–S Cross-Coupling12
Role of dppf Monoxide in the Transmetalation Step of the Suzuki–Miyaura Coupling Reaction12
Highly Selective Hydroboration of Terminal Alkenes Catalyzed by a Cobalt Pincer Complex Featuring a Central Reactive N-Heterocyclic Phosphido Fragment12
16-Electron Nickel(0)-Olefin Complexes in Low-Temperature C(sp2)–C(sp3) Kumada Cross-Couplings12
Group 6 Metal Carbonyl Complexes Supported by a Bidentate PN Ligand: Syntheses, Characterization, and Catalytic Hydrogenation Activity12
Wrapping Rhodium in a Borane Canopy: Implications for Hydride Formation and Transfer12
Rational Design of a Tripodal Ligand for U(IV): Synthesis and Characterization of a U–Cl Species and Insights into Its Reactivity12
Accessing Mononuclear Triphenylcyclopentadienyl Lanthanide Complexes by Using Tridentate Nitrogen Ligands: Synthesis, Structure, Luminescence, and Catalysis12
Hemisphere and Distance-Dependent Steric Analysis of PNN Iron Pincer Complexes Using SambVca 2.1 and Its Influence on Alkene Hydrosilylation12
Vanadium- and Chromium-Catalyzed Dehydrogenative Synthesis of Imines from Alcohols and Amines12
Selective, Base-Free Hydrogenation of Aldehydes Catalyzed by Ir Complexes Based on Proton-Responsive Lutidine-Derived CNP Ligands12
Cobalt-Catalyzed (E)-Selective Hydrosilylation of 1,3-Enynes for the Synthesis of 1,3-Dienylsilanes12
Synthesis of Cationic, Dimeric α-Diimine Nickel Hydride Complexes and Relevance to the Polymerization of Olefins12
Palladium-Catalyzed Cyclobutanation of Aryl Sulfonates through both C–O and C–H Cleavage12
Effects of Tuning Intramolecular Proton Acidity on CO2 Reduction by Mn Bipyridyl Species12
Direct Synthesis of Hydrogen Peroxide in Water by Means of a Rh-Based Catalyst12
Tricyclic Sulfoxide–Alkene Hybrid Ligands for Chiral Rh(I) Complexes: The “Matched” Diastereomer Catalyzes Asymmetric C–C Bond Formations12
Impact of the Electronic Environment in Carbazole-Appended o-Carboranyl Compounds on the Intramolecular-Charge-Transfer-Based Radiative Decay Efficiency12
Mechanistic Investigation of the Nickel-Catalyzed Carbonylation of Alcohols12
Tetraaminocyclopentadienone Iron Complexes as Hydrogenation Catalysts12
Synthesis of Norbornene-Based Phosphine-Stabilized Silylium Ions Behaving as Masked Frustrated Lewis Pairs12
The Effect of Added Ligands on the Reactions of [Ni(COD)(dppf)] with Alkyl Halides: Halide Abstraction May Be Reversible12
Mixed Arylolefin/NHC Complexes of Platinum(II): Syntheses, Characterizations, and In Vitro Cytotoxicities12
Tris(carbene) Stabilization of Monomeric Magnesium Cations: A Neutral, Nontethered Ligand Approach12
Synthesis of Heterobimetallic Complexes through Chemoselective 2,4-Metalation of a Thiazolium Salt12
Decomposition of Vanadium(V) Alkylidenes Relevant to Olefin Metathesis12
Benzimidazolin-2-iminato Hafnium Complexes: Synthesis, Characterization, and Catalytic Addition of Alcohols to Carbodiimides12
C(sp2)-CF3 Reductive Elimination from Well-Defined Argentate(III) Complexes [nBu4N][Ag(Ar)(CF3)3]12
Synthesis and Catalytic Reactivity of Cobalt Pincer Nitrosyl Hydride Complexes12
Carbodiphosphorane-Catalyzed Hydroboration of Ketones and Imines11
Tetraorganylargentate(III) Complexes: Key Intermediates in Silver-Mediated Cross-Coupling Reactions11
Molybdenum Benzylidyne Complexes for Olefin Metathesis Reactions11
Electroreduction of Benzaldehyde with a Metal–Ligand Bifunctional Hydroxycyclopentadienyl Molybdenum(II) Hydride11
Synthesis, Electrochemistry, and Optical Properties of Highly Conjugated Alkynyl-Ferrocenes and -Biferrocenes11
Reinvestigating Catalytic Alcohol Dehydrogenation with an Iridium Dihydroxybipyridine Catalyst11
Mono(hydrosilylation) of N-Heterocycles Catalyzed by B(C6F5)3 and Silylium Ion11
NNO Pincer Ligand-Supported Palladium(II) Complexes: Direct Synthesis of Quinazolines via Acceptorless Double Dehydrogenative Coupling of Alcohols11
Mono- and Dinuclear Asymmetric Aluminum Guanidinates for the Catalytic CO2 Fixation into Cyclic Carbonates11
Radical Capture at Nickel(II) Complexes: C–C, C–N, and C–O Bond Formation11
Heteroscorpionate Rare-Earth Catalysts for the Low-Pressure Coupling Reaction of CO2 and Cyclohexene Oxide11
Synthesis of Vanadium Oxo Alkylidene Complex and Its Reactivity in Ring-Closing Olefin Metathesis Reactions11
Catalytic C(sp2)–H Amination Reactions Using Dinickel Imides11
Influence of Indole-N Substitution of Thiosemicarbazones in Cationic Ru(II)(η6-Benzene) Complexes on Their Anticancer Activity11
Catalytic Activity of a Zr MOF Containing POCOP-Pd Pincer Complexes11
Synthesis, Structure, and Hydroboration Reactivity of Anionic Nickel(0) Complexes Supported by Bidentate NHC-Pyridone Ligands11
Aggregation Behavior of Lithionaphthalenes in Solution: Experimental and Theoretical Study11
Cyclometalated NHCs Pt(II) Compounds with Chelating P^P and S^S Ligands: From Blue to White Luminescence11
Hydration of Aromatic Nitriles Catalyzed by Mn-OH Complexes: A Rationalization from Quantum Chemical Investigations11
Silver(I) N-Heterocyclic Carbene Complexes Derived from Clotrimazole: Antiproliferative Activity and Interaction with an Artificial Membrane-Based Biosensor11
Naphthyl-Derived Orthometalated RuII-NHC Complexes: Effect of the NHC Donors and/or Substitution Pattern on Their Synthesis and Catalytic Activity11
Functionalization of N,N-Dialkylferrocenesulfonamides toward Substituted Derivatives11
CO2 (De)Activation in Carboxylation Reactions: A Case Study Using Grignard Reagents and Nucleophilic Bases11
Theoretical Elucidation of the Effect of Counteranions on the Olefin Polymerization Activity of (Pyridylamido)Hf(IV) Catalyst by QM and REMD Studies: MeB(C6F5)3–<11
Imidazoline-2-imine Functionalized Fluorenyl Rare-Earth Metal Complexes: Synthesis and Their Application in the Polymerization of ortho-Methoxystyrene11
Antiproliferative Activity and Associated DNA Interactions of [Co2L3]6+ Cylinders Derived from Bis(bidentate) 2-Pyridyl-1,2,3-triazole Ligands11
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