Organometallics

Article	Citations
Recent Advances in C(sp3)–C(sp3) Cross-Coupling Chemistry: A Dominant Performance of Nickel Catalysts	50
Carbon Dioxide Hydrogenation to Formate Catalyzed by a Bench-Stable, Non-Pincer-Type Mn(I) Alkylcarbonyl Complex	46
Coordination Behavior of Acylthiourea Ligands in Their Ru(II)–Benzene Complexes─Structures and Anticancer Activity	46
Manganese-Catalyzed Hydrogenation of Ketones under Mild and Base-free Conditions	40
Synthesis of Branched Polyethylene and Ethylene-MA Copolymers Using Unsymmetrical Iminopyridyl Nickel and Palladium Complexes	37
Lewis Acidic Telluronium Cations: Enhanced Chalcogen-Bond Donor Properties and Application to Transfer Hydrogenation Catalysis	36
An Illustrated Guide to Schlenk Line Techniques	36
A Tutorial on Selectivity Determination in C(sp2)–H Oxidative Addition of Arenes by Transition Metal Complexes	30
A Dual Steric Enhancement Strategy in α-Diimine Nickel and Palladium Catalysts for Ethylene Polymerization and Copolymerization	29
Stable Au(III) Complexes Bearing Hemilabile P∧N and C∧N Ligands: Coordination of the Pendant Nitrogen upon Oxidation of Gold	28
Cationic PCP and PCN NHC Core Pincer-Type Mn(I) Complexes: From Synthesis to Catalysis	28
Pincer-Nickel Catalyzed Selective Guerbet-Type Reactions	28
Switchable Imine and Amine Synthesis Catalyzed by a Well-Defined Cobalt Complex	28
Manganese-Catalyzed C(α)-Alkylation of Oxindoles with Secondary Alcohols via Borrowing Hydrogen	28
Synthesis of Overloaded Cyclopentadienyl Rhodium(III) Complexes via Cyclotetramerization of tert-Butylacetylene	27
Update for Reactions of Group 4 Metallocene Bis(trimethylsilyl)acetylene Complexes: A Never-Ending Story?	27
Switchable β-alkylation of Secondary Alcohols with Primary Alcohols by a Well-Defined Cobalt Catalyst	27
Synthesis, Structure, and Reactivity of a Superbulky Low-Valent β-Diketiminate Al(I) Complex	26
Enantioselectivity in the Noyori–Ikariya Asymmetric Transfer Hydrogenation of Ketones	26
Diaryl Ether Formation Merging Photoredox and Nickel Catalysis	26
Synthesis and Characterization of a Tetradentate, N-Heterocyclic Carbene Copper(II) Complex and Its Use as a Chan–Evans–Lam Coupling Catalyst	26
Tuning the Donor−π–Acceptor Character of Arylborane–Arylamine Macrocycles	26
Catalytic Hydrogenation of Alkenes and Alkynes by a Cobalt Pincer Complex: Evidence of Roles for Both Co(I) and Co(II)	25
Micellar Catalysis as a Tool for C–H Bond Functionalization toward C–C Bond Formation	24
Palladium(II) N^O Chelating Complexes Catalyzed One-Pot Approach for Synthesis of Quinazolin-4(3H)-ones via Acceptorless Dehydrogenative Coupling of Benzyl Alcohols and 2-Aminobenzamide	24

Two-Fold Reduction of Dibenzo[a,e]cyclooctatetraene with Group 1 Metals: From Lithium to Cesium	24
Enhancing Thermal Stability in Aminopyridine Iron(II)-Catalyzed Polymerization of Conjugated Dienes	24
Copper-Catalyzed Azide–Alkyne Cycloaddition (CuAAC) by Functionalized NHC-Based Polynuclear Catalysts: Scope and Mechanistic Insights	24
Activation of Nitrogen-Rich Substrates by Low-Valent, Redox-Active Aluminum Species	23
Ligand-Controlled Regiodivergent Hydrosilylation of Conjugated Dienes Catalyzed by Mono(phosphine)palladium(0) Complexes	23
Pd–PEPPSI N-Heterocyclic Carbene Complexes from Caffeine: Application in Suzuki, Heck, and Sonogashira Reactions	22
Additive-Free Formic Acid Dehydrogenation Catalyzed by a Cobalt Complex	22
Probing Electronic Properties of Triazolylidenes through Mesoionic Selones, Triazolium Salts, and Ir-Carbonyl-Triazolylidene Complexes	22
Development of Group 4 Metal Complexes Bearing Fused-Ring Amido-Trihydroquinoline Ligands with Improved High-Temperature Catalytic Performance toward Olefin (Co)polymerization	22
Influence of the Lewis Base Ph3PO on the Reactivity of the Uranium Phosphinidene (η5-C5Me5)2U(═P-2,4,6-iPr3C6	22
N-Heterocyclic Carbene Complexes of Nickel, Palladium, and Iridium Derived from Nitron: Synthesis, Structures, and Catalytic Properties	22
Cross-Dehydrocoupling of Amines and Silanes Catalyzed by Magnesocenophanes	22
Effects of Axial Solvent Coordination to Dirhodium Complexes on the Reactivity and Selectivity in C–H Insertion Reactions: A Computational Study	22
A Mild One-Pot Reduction of Phosphine(V) Oxides Affording Phosphines(III) and Their Metal Catalysts	21
Synthesis, Structure, and Reactivity of the Uranium Bipyridyl Complex [{η5-1,2,4-(Me3Si)3C5H2}2U(bipy)]	21
Reactivity of [Pt(PtBu3)2] with Zinc(I/II) Compounds: Bimetallic Adducts, Zn–Zn Bond Cleavage, and Cooperative Reactivity	21
Understanding Catalyst Structure–Selectivity Relationships in Pd-Catalyzed Enantioselective Methoxycarbonylation of Styrene	21
(η5-C5Me5)2U(=P-2,4,6-tBu3C6H2)(OPMe3) Revisited—Its Intrinsic Reactivity toward Small Organic	21
Methylene-Linked Bis-NHC Half-Sandwich Ruthenium Complexes: Binding of Small Molecules and Catalysis toward Ketone Transfer Hydrogenation	20
Impact of Biphenyl Benzhydrazone-Incorporated Arene Ru(II) Complexes on Cytotoxicity and the Cancer Cell Death Mechanism	20
Vanadium(V) Arylimido Alkylidene N-Heterocyclic Carbene Alkyl and Perhalophenoxy Alkylidenes for the Cis, Syndiospecific Ring Opening Metathesis Polymerization of Norbornene	20
Beyond Ni{N(SiMe3)2}2: Synthesis of a Stable Solvated Sodium Tris-Amido Nickelate	20
Hetero- and Homobimetallic Complexes Bridged by a Bis(NHC) Ligand: Synthesis via Selective Sequential Metalation and Catalytic Applications in Tandem Organic Transformations	20
Experimental and Computational Analysis of CO2 Addition Reactions Relevant to Copper-Catalyzed Boracarboxylation of Vinyl Arenes: Evidence for a Phosphine-Promoted Mechanism	20
Palladacycle-Catalyzed Olefinic C–P Cross-Coupling of Alkenylsulfonium Salts with Diarylphosphines to Access Alkenylphosphines	20
Hypercrosslinked Polymer Platform-Anchored Single-Site Heterogeneous Pd–NHC Catalysts for Diverse C–H Functionalization	20
Upgrading of Ethanol to n-Butanol via a Ruthenium Catalyst in Aqueous Solution	20
Pincer-Cobalt-Catalyzed Guerbet-Type β-Alkylation of Alcohols in Air under Microwave Conditions	19
Influence of the 1,3-Bis(trimethylsilyl)cyclopentadienyl Ligand on the Reactivity of the Uranium Phosphinidene [η5-1,3-(Me3Si)2C5H3]2U	19
Photophysical Properties of Phosphorescent Mono- and Bimetallic Platinum(II) Complexes with C∧C* Cyclometalating NHC Ligands	19
Deoxygenation of Primary Amides to Amines with Pinacolborane Catalyzed by Ca[N(SiMe3)2]2(THF)2	19
Fluorinated Cycloplatinated(II) Complexes Bearing Bisphosphine Ligands as Potent Anticancer Agents	19
Comparison of Magnesium and Zinc in Cationic π-Arene and Halobenzene Complexes	19
Reactivities of Silaimines with Boranes: From Cooperative B–H Bond Activation to Donor Stabilized Silyl Cation	19
Catalytic Deoxygenation of Nitroarenes Mediated by High-Valent Molybdenum(VI)–NHC Complexes	19
Synthesis of Carbophosphinocarbene and Their Donating Ability: Expansion of the Carbone Class	19
Expanding the Scope of Palladium-Catalyzed B–N Cross-Coupling Chemistry in Carboranes	19
Synthesis, Structure and Physical Properties of “Wire-like” Metal Complexes	18
Group 6 Metal Carbonyl Complexes Supported by a Bidentate PN Ligand: Syntheses, Characterization, and Catalytic Hydrogenation Activity	18
Knölker Iron Catalysts for Hydrogenation Revisited: A Nonspectator Solvent and Fine-Tuning	18
Cobalt-Catalyzed Alkylation of Nitriles with Alcohols	18
Bis(phosphine)cobalt-Catalyzed Highly Regio- and Stereoselective Hydrosilylation of 1,3-Diynes	18
Copolymerization of Ethylene and Long-Chain Functional α-Olefins by Dinuclear Zirconium Catalysts	18
Mechanistic Insights into the Nickel-Catalyzed Regioselective Carboxylation of Allylic Alcohols	18
Repercussion of a 1,3-Hydrogen Shift in a Hydride-Osmium-Allenylidene Complex	18
Cationic α-Diimine Nickel and Palladium Complexes Incorporating Phenanthrene Substituents: Highly Active Ethylene Polymerization Catalysts and Mechanistic Studies of syn/anti Isomerizati	18
Benzylnickel(II) Complexes of 2-Iminopyrrolyl Chelating Ligands: Synthesis, Structure, and Catalytic Oligo-/Polymerization of Ethylene to Hyperbranched Polyethylene	18
Bulky o-Phenylene-Bridged Bimetallic α-Diimine Ni(II) and Pd(II) Catalysts in Ethylene (Co)polymerization	18
NNO Pincer Ligand-Supported Palladium(II) Complexes: Direct Synthesis of Quinazolines via Acceptorless Double Dehydrogenative Coupling of Alcohols	18
Bridging the Gap from Mononuclear PdII Precatalysts to Pd Nanoparticles: Identification of Intermediate Linear [Pd3(XPh3)4]2+ Clusters as Catalyt	17

Synthesis of an NHC-Coordinated Dialkyldisilavinylidene and Its Oxidation Providing a Silicon Analog of an Acetolactone	17
Adaptive Aromaticity in Metallasilapentalynes	17
Structural Features of Polymer Ligand Environments Dramatically Affect the Mechanical and Room-Temperature Self-Healing Properties of Cobalt(II)-Incorporating Polysiloxanes	17
Well-Defined Cationic Cobalt(I) Precatalyst for Olefin-Alkyne [2 + 2] Cycloaddition and Olefin-Diene Hydrovinylation Reactions: Experimental Evidence for Metallacycle Intermediates	17
16-Electron Nickel(0)-Olefin Complexes in Low-Temperature C(sp2)–C(sp3) Kumada Cross-Couplings	17
Diboron-Promoted Reduction of Ni(II) Salts: Precatalyst Activation Studies Relevant to Ni-Catalyzed Borylation Reactions	17
Behavior of Lewis Bases toward Diphenylberyllium	17
Synthesis of NHC-Iridium(III) Complexes Based on N-Iminoimidazolium Ylides and Their Use for the Amine Alkylation by Borrowing Hydrogen Catalysis	17
Aggregation and Significant Difference in Reactivity Therein: Blocking the CO2-to-CH3OH Reaction	16
Carbon–Carbon Bond Coupling of Vinyl Molecules with an Allenyl Ligand at a Diruthenium Complex	16
Influence of Indole-N Substitution of Thiosemicarbazones in Cationic Ru(II)(η6-Benzene) Complexes on Their Anticancer Activity	16
Synthesis of Heterobimetallic Complexes through Chemoselective 2,4-Metalation of a Thiazolium Salt	16
Iron Versus Ruthenium: Evidence for the Distinct Differences in the Electronic Structures of Hexa-1,3,5-triyn-1,6-diyl-bridged Complexes [Cp*(dppe)M}{μ-(C≡C)3}{M(dppe)Cp*}]+ (M =	16
Vanadium- and Chromium-Catalyzed Dehydrogenative Synthesis of Imines from Alcohols and Amines	16
Terminal-Selective C(sp3)–H Arylation: NiH-Catalyzed Remote Hydroarylation of Unactivated Internal Olefins	16
Flexible Axial Shielding Strategy for the Synthesis of High-Molecular-Weight Polyethylene and Polar Functionalized Polyethylene with Pyridine-Imine Ni(II) and Pd(II) Complexes	16
Synthesis, Reactivity, and Coordination of Semihomologous dppf Congeners Bearing Primary Phosphine and Primary Phosphine Oxide Groups	16
N-Heterocyclic Carbene Complexes of Nickel(II) from Caffeine and Theophylline: Sustainable Alternative to Imidazol-2-ylidenes	16
A Robust Vanadium(V) Tris(2-pyridyl)borate Catalyst for Long-Lived High-Temperature Ethylene Polymerization	16
Accessing Mononuclear Triphenylcyclopentadienyl Lanthanide Complexes by Using Tridentate Nitrogen Ligands: Synthesis, Structure, Luminescence, and Catalysis	16
Reactivity of an Unprotected Mesoionic N-Heterocyclic Olefin	16
Mono- and Dinuclear α-Diimine Nickel(II) and Palladium(II) Complexes in C–S Cross-Coupling	16
Pd-Catalyst Containing a Hemilabile P,C-Hybrid Ligand in Amino Dicarbonylation of Aryl Halides for Synthesis of α-Ketoamides	16
Dual Photoredox-/Palladium-Catalyzed Cross-Electrophile Couplings of Polyfluoroarenes with Aryl Halides and Triflates	16
Role of Solvent Coordination on the Structure and Dynamics of ansa-Zirconocenium Ion Pairs in Aromatic Hydrocarbons	16
Investigation of Iron Silyl Complexes as Active Species in the Catalytic Hydrosilylation of Aldehydes and Ketones	16
Highly Reactive Cationic Molybdenum Alkylidyne N-Heterocyclic Carbene Catalysts for Alkyne Metathesis	16
Progress of Ring-Opening Polymerization of Cyclic Esters Catalyzed by Iron Compounds	16
Cooperativity in Highly Active Ethylene Dimerization by Dinuclear Nickel Complexes Bearing a Bifunctional PN Ligand	16
Chain-Straightening Polymerization of Olefins to Form Polar Functionalized Semicrystalline Polyethylene	16
C(sp2)-CF3 Reductive Elimination from Well-Defined Argentate(III) Complexes [nBu4N][Ag(Ar)(CF3)3]	15
Imidazoline-2-imine Functionalized Fluorenyl Rare-Earth Metal Complexes: Synthesis and Their Application in the Polymerization of ortho-Methoxystyrene	15
Synthesis, Characterization, and Antimicrobial Activity of RhIII and IrIII N-Heterocyclic Carbene Piano-Stool Complexes	15
[P,C]-Chelate Cobalt(III) Hydride Catalyzed Hydrosilylation of Alkenes	15
Rational Design of a Tripodal Ligand for U(IV): Synthesis and Characterization of a U–Cl Species and Insights into Its Reactivity	15
Highly Sterically Encumbered Gold Acyclic Diaminocarbene Complexes: Overriding Electronic Control in Regiodivergent Gold Catalysis	15
Mono- and Dinuclear Asymmetric Aluminum Guanidinates for the Catalytic CO2 Fixation into Cyclic Carbonates	15
The Effect of Added Ligands on the Reactions of [Ni(COD)(dppf)] with Alkyl Halides: Halide Abstraction May Be Reversible	15
Advances in the Synthesis and Applications of N-Heterocyclic Carbene Metal Complexes with a Focus on the Weak Base Route	15
Direct Evidence for Competitive C–H Activation by a Well-Defined Silver XPhos Complex in Palladium-Catalyzed C–H Functionalization	15
Influence of the N→Ru Coordinate Bond Length on the Activity of New Types of Hoveyda–Grubbs Olefin Metathesis Catalysts Containing a Six-Membered Chelate Ring Possessing a Ruthenium–Nitrogen Bond	15
Highly Selective Hydroboration of Terminal Alkenes Catalyzed by a Cobalt Pincer Complex Featuring a Central Reactive N-Heterocyclic Phosphido Fragment	15
Effect of Ligand Backbone on the Selectivity and Stability of Rhodium Hydroformylation Catalysts Derived from Phospholane-Phosphites	14
Ionic Cyclopropenium-Derived Triplatinum Cluster Complex [(Ph3C3)2Pt3(MeCN)4]2+(BF4–)2: Synthesis, St	14
Theoretical Elucidation of the Effect of Counteranions on the Olefin Polymerization Activity of (Pyridylamido)Hf(IV) Catalyst by QM and REMD Studies: MeB(C6F5)3–<	14
Discovery of the N–NHC Coupling Process under the Conditions of Pd/NHC- and Ni/NHC-Catalyzed Buchwald–Hartwig Amination	14
Tetraaminocyclopentadienone Iron Complexes as Hydrogenation Catalysts	14
Cobalt-Catalyzed (E)-Selective Hydrosilylation of 1,3-Enynes for the Synthesis of 1,3-Dienylsilanes	14
Low-Valent Molybdenum PNP Pincer Complexes as Catalysts for the Semihydrogenation of Alkynes	14
Tuning Organocerium Electrochemical Potentials by Extending Tris(cyclopentadienyl) Scaffolds with Terminal Halogenido, Siloxy, and Alkoxy Ligands	14
Controlled Activation of Dipicolinyl-Substituted Propargylic Alcohol by Ru(II) and Os(II) for Unprecedented Indolizine-Fused Metallafuran Complexes	14
Highly Modular Piano-Stool N-Heterocyclic Carbene Iron Complexes: Impact of Ligand Variation on Hydrosilylation Activity	14
Nickel Complexes Bearing N,N,O-Tridentate Salicylaldiminato Ligand: Efficient Catalysts for Imines Formation via Dehydrogenative Coupling of Primary Alcohols with Amines	14
Nickel-Catalyzed Suzuki–Miyaura Cross-Coupling Facilitated by a Weak Amine Base with Water as a Cosolvent	14
Synthesis and Reactivity of Side-Arm Phosphine Functionalized Amidinatosilylene- and Amidinatogermylene-Supported Nickel(0) Complexes	14
Carbodiphosphorane-Catalyzed Hydroboration of Ketones and Imines	14
Combined Experimental and Computational Study of the Mechanism of Acceptorless Alcohol Dehydrogenation by POCOP Iridium Pincer Complexes	14
Synthesis of Vanadium Oxo Alkylidene Complex and Its Reactivity in Ring-Closing Olefin Metathesis Reactions	14
Technetium Hydrides Revisited: Syntheses, Structures, and Reactions of [TcH3(PPh3)4] and [TcH(CO)3(PPh3)2]	14
Achieving a Favorable Activation of the C–F Bond over the C–H Bond in Five- and Six-Membered Ring Complexes by a Coordination and Aromaticity Dually Driven Strategy	14
Enantioconvergent and Regioselective Synthesis of Allenylsilanes by Nickel-Catalyzed C(sp2)–C(sp3) Cross-Coupling Starting from Racemic α-Silylated Propargylic Bromides	14
α-Methylation of Ketones and Indoles Catalyzed by a Manganese(I) PCNHCP Pincer Complex with Methanol as a C1 Source	14
N-Heterocyclic Carbene-Based Tetradentate Pd(II) Complexes for Deep-Blue Phosphorescent Materials	14
Gold(I) and Silver(I) π-Complexes with Unsaturated Hydrocarbons	14
1,2-Disubstituted Planar Chiral Ferrocene Derivatives from Sulfonamide-Directed ortho-Lithiation: Synthesis, Absolute Configuration, and Chiroptical Properties	14
Solvate-Assisted Grinding: Metal Solvates as Solvent Sources in Mechanochemically Driven Organometallic Reactions	13
Tetrylenes: Electronic Structure, Stability, Reactivity, and Ligand Properties—A Comparative DFT Study	13
Tetraorganylargentate(III) Complexes: Key Intermediates in Silver-Mediated Cross-Coupling Reactions	13
Functionalization of N,N-Dialkylferrocenesulfonamides toward Substituted Derivatives	13
Zn Metal–Organic Framework with High Stability and Sorption Selectivity for CO2	13
Synthesis of Carbamoylphosphates from Isocyanates Catalyzed by Rare-Earth-Metal Alkyl Complexes with a Silicon-Linked Diarylamido Ligand	13
Mono(hydrosilylation) of N-Heterocycles Catalyzed by B(C6F5)3 and Silylium Ion	13
Examination of a Series of Ir and Rh PXL Pincer Complexes as (Pre)catalysts for Aromatic C–H Borylation	13
Vanadium Imido NHC Complexes for Ring-Closing Olefin Metathesis Reactions	13
Electroreduction of Benzaldehyde with a Metal–Ligand Bifunctional Hydroxycyclopentadienyl Molybdenum(II) Hydride	13
Solvent-Free Hydrosilylation of Alkenes Catalyzed by Well-Defined Low-Valent Cobalt Catalysts	13
Synthesis and Catalytic Reactivity of Cobalt Pincer Nitrosyl Hydride Complexes	13
Synthesis, Structure, and Hydroboration Reactivity of Anionic Nickel(0) Complexes Supported by Bidentate NHC-Pyridone Ligands	13
Homoleptic Cobalt(II) Phenoxyimine Complexes for Hydrosilylation of Aldehydes and Ketones without Base Activation of Cobalt(II)	13
Pd-Catalyzed Etherification of Nitroarenes	13

A Cobalt-Catalyzed Enantioconvergent Radical Negishi C(sp3)–C(sp2) Cross-Coupling with Chiral Multidentate N,N,P-Ligand	13
Diagonal Relationship among Organometallic Transition-Metal Complexes	13
{MI(CO)X(CNArDArF2)4} (DArF = 3,5-(CF3)2C6H3; M = Re and Tc; X = Br and Cl) Complexes: Convenient Platforms for the Synthes	12
Reusable Single Homogeneous Ir(III)–NHC Catalysts for Bidirectional Hydrogenation–Dehydrogenation of N-Heteroarenes in Water	12
Wrapping Rhodium in a Borane Canopy: Implications for Hydride Formation and Transfer	12
Copper–Ligand Cooperativity in H2 Activation Enables the Synthesis of Copper Hydride Complexes	12
Photocatalytic CO2 Reduction Using an Iron–Bipyridyl Complex Supported by Two Phosphines for Improving Catalyst Durability	12
Selective, Base-Free Hydrogenation of Aldehydes Catalyzed by Ir Complexes Based on Proton-Responsive Lutidine-Derived CNP Ligands	12
Cobalt-Catalyzed Asymmetric Hydrogenation of Enamides: Insights into Mechanisms and Solvent Effects	12
Creating, Preserving, and Directing Carboxylate Radicals in Ni-Catalyzed C(sp3)–H Acyloxylation of Ethers, Ketones, and Alkanes with Diacyl Peroxides	12
A Non-innocent Ligand Supported Germylene and Its Diverse Reactions	12
Methylidyne Transfer as a Plausible Deactivation Pathway for Ynene Metathesis	12
Cobalt-Catalyzed 1,1,3-Triborylation of Terminal Alkynes	12
Carbonyl and Isocyanide Complexes of Copper and Silver Supported by Fluorinated Poly(pyridyl)borates	12
Catalyst-Controlled Regioselectivity in Pd-Catalyzed Aerobic Oxidative Arylation of Indoles	12
Predicting Dinitrogen Activation by Carborane-Based Frustrated Lewis Pairs	12
Routes to High-Performing Ruthenium–Iodide Catalysts for Olefin Metathesis: Ligand Lability Is Key to Efficient Halide Exchange	12
Stability and Solution Behavior of [(dpp-Bian)Ln] and [(dpp-Bian)LnX] (Ln = Yb, Tm, or Dy; X = I, F, or N3)	12
Zinc Catalyzed Hydroelementation (HE; E = B, C, N, and O) of Carbodiimides: Intermediates Isolation and Mechanistic Insights	12
Cyclic Amide-Anchored NHC-Based Cp*Ir Catalysts for Bidirectional Hydrogenation–Dehydrogenation with CO2/HCO2H Couple	12
Substituent Effects on the Activity of Cp*Ir(pyridine-carboxylate) Water Oxidation Catalysts: Which Ligand Fragments Remain Coordinated to the Active Ir Centers?	12
A Strategy to Conjugate Bioactive Fragments to Cytotoxic Diiron Bis(cyclopentadienyl) Complexes	12
Ylide-Substituted Phosphines with a Cyclic Ylide-Backbone: Angle Dependence of the Donor Strength	12
[closo-B10H8-1,10-(CN)2]2– as a Conduit of Electronic Effects: Comparative Studies of Fe···Fe Communication in [{(η5-Cp)(dpp	12
PCP Pincer Carbene Nickel(II) Chloride, Hydride, and Thiolate Complexes: Hydrosilylation of Aldehyde, Ketone, and Nitroarene by the Thiolate Complex	12
Application of Indazolin-3-ylidenes in Catalysis: Steric Tuning of Nonclassical Formally Normal N-Heterocyclic Carbenes with Dual Electronic Character for Catalysis	12
Role of dppf Monoxide in the Transmetalation Step of the Suzuki–Miyaura Coupling Reaction	12
Impact of the Electronic Environment in Carbazole-Appended o-Carboranyl Compounds on the Intramolecular-Charge-Transfer-Based Radiative Decay Efficiency	12
Comparative CO2 Hydrogenation Catalysis with MACHO-type Manganese Complexes	12
Selectivity in Competitive Csp2–Csp3 versus Csp3–Csp3 Reductive Eliminations at Pt(IV) Complexes: Experimental a	12
Thermally Stable Rare-Earth Metal Complexes Supported by Chelating Silylene Ligands	12
Reactivity of Heterobimetallic Ion Pairs in Formic Acid Dehydrogenation	12
Heteroscorpionate Rare-Earth Catalysts for the Low-Pressure Coupling Reaction of CO2 and Cyclohexene Oxide	11
Bimetallic Nickel Complexes Containing Benzotriazole-Derived Diamine-Bisphenolate Ligands as Highly Active Catalysts for the Copolymerization of Carbon Dioxide with Cyclohexene Oxide: Synthesis, Catal	11
Tetra- and Pentaisopropylcyclopentadienyl Complexes of Group 15 Elements	11
Stepwise Nucleophilic Substitution to Access Saturated N-heterocyclic Carbene Haloboranes with Boron–Methyl Bonds	11
Zinc Complexes with an Ethylene-Bridged Bis(β-diketiminate) Ligand: Syntheses, Structures, and Applications as Catalysts in the Borylation of Aryl Iodides	11
Sitting Out the Halogen Dance. Room-Temperature Formation of 2,2′-Dilithio-1,1′-dibromoferrocene. TMEDA and Related Lithium Complexes: A Synthetic Route to Multiply Substituted Ferrocenes	11
Effectiveness and Mechanism of the Ene(amido) Group in Activating Iron for the Catalytic Asymmetric Transfer Hydrogenation of Ketones	11
Formation of Allylpalladium Complexes and Asymmetric Allylation Involving Modular Bridging Diamidophosphite-Sulfides Based on 1,4-Thioether Alcohols	11
Syntheses and Reactivity of Piano-Stool Iron Complexes of Picolyl-Functionalized N-Heterocyclic Carbene Ligands	11
Synthesis, Electrochemistry, and Optical Properties of Highly Conjugated Alkynyl-Ferrocenes and -Biferrocenes	11
Dissimilarity in the Chemical Behavior of Osmaoxazolium Salts and Osmaoxazoles: Two Different Aromatic Metalladiheterocycles	11
Ancillary Tethering Influences σ3-P vs σ5-P Speciation and Enables Intermolecular S–H Oxidative Addition to Nontrigonal Phosphorus Compounds	11
σ/π Plasticity of NHCs on the Ruthenium–Phosphine and Ruthenium═Ylidene Bonds in Olefin Metathesis Catalysts	11
Cycloneophylpalladium(IV) Complexes: Formation by Oxidative Addition and Selectivity of Their Reductive Elimination Reactions	11
Bimetallic Co–M (M = Cu, Ag, and Au) Carbonyl Complexes Supported by N-Heterocyclic Carbene Ligands: Synthesis, Structures, Computational Investigation, and Catalysis for Ammonia Borane Dehydro	11
Polyethylene Waxes with Short Chain Branching via Steric and Electronic Tuning of an 8-(Arylimino)-5,6,7-trihydroquinoline-nickel Catalyst	11
Cobalt Complexes of Bulky PNP Ligand: H2 Activation and Catalytic Two-Electron Reactivity in Hydrogenation of Alkenes and Alkynes	11
Heterocoupling of Different Aryl Nitrenes to Produce Asymmetric Azoarenes Using Iron–Alkoxide Catalysis and Investigation of the Cis–Trans Isomerism of Selected Bulky Asymmetric Azoarenes	11
Release of CO and Production of 1O2 from a Mn-BODIPY Photoactivated CO Releasing Molecule with Visible Light	11
Dinuclear Nickel and Cobalt Complexes Containing Biocompatible Carboxylate Derivatives as Effective Catalysts for Coupling of Carbon Dioxide with Epoxides: Synthesis, Characterization, and Catalysis	11
Ring-Opening of THF via an Intramolecular P/Al-Based Frustrated Lewis Pair: Assistance by C6F5 Groups beyond Electronegativity?	11
Imine-Palladacycles as Phosphine-Free Precatalysts for Low-Temperature Suzuki–Miyaura Synthesis of Nucleoside Analogues in Aqueous Media	11
Testing the Potential of the Ferrocene Chromophore as a Circular Dichroism Probe for the Assignment of the Screw-Sense Preference of Tripeptides	10
Rare-Earth Metal Complexes Bearing Pyridyl-Functionalized Amidinate Ligands for Highly trans-1,4-Selective Living (Co)Polymerization of 1,3-Conjugated Dienes	10
Ambiphilic Nature of Dipyrrolylpyridine-Supported Divalent Germanium and Tin Compounds	10
Regiocontrolled Coupling of Alkynes and Dipolar Reagents: Iron-Mediated [3 + 2] Cycloadditions Revisited	10
CF3O-Functionalized Bis(arylimino)pyridine–Cobalt Ethylene Polymerization Catalysts: Harnessing Solvent Effects on Performance and Polymer Properties	10
Immobilized Platinum Hydride Species as Catalysts for Olefin Isomerizations and Enyne Cycloisomerizations	10
Iron-Catalyzed Alkyne Carboamination via an Isolable Iron Imide Complex	10
Reactivity of a Dinuclear PdI Complex [Pd2(μ-PPh2)(μ2-OAc)(PPh3)2] with PPh3: Implications for Cross-Coupling Catalysis Usi	10
A Ruthenium Protic N-Heterocyclic Carbene Complex as a Precatalyst for the Efficient Transfer Hydrogenation of Aryl Ketones	10
Synthesis and Reactivity of NNNNN-Pincer Multidentate Pyrrolyl Rare-Earth-Metal Amido-Chloride or Dialkyl Complexes	10
Modular Ni(0)/Silane Catalytic System for the Isomerization of Alkenes	10
Substrate, Catalyst, and Solvent: The Triune Nature of Multitasking Reagents in Hydroboration and Cyanosilylation	10
Photochemical CO2-to-Formate/CO Conversion Catalyzed by Half-Metallocene Ir(III) Catalyst and Its Mechanistic Investigation	10
Understanding the Use of Phosphine-(EWO) Ligands in Negishi Cross-Coupling: Experimental and Density Functional Theory Mechanistic Study	10
Is the Electrophilicity of the Metal Nitrene the Sole Predictor of Metal-Mediated Nitrene Transfer to Olefins? Secondary Contributing Factors as Revealed by a Library of High-Spin Co(II) Reagents	10
Iron, Cobalt, and Nickel Complexes Supported by a iPrPNPhP Pincer Ligand	10
Reactivity of Lutetacyclopropene toward Benzyl, Benzoyl, and Trimethylsilyl Nitriles Affording Diversified Lutetium Complexes	10
Catalytic Alkyne and Diyne Metathesis with Mixed Fluoroalkoxy-Siloxy Molybdenum Alkylidyne Complexes	10
Selenium-Directed Ortho C–H Activation of Benzyl Selenide by a Selenated NHC–Half-Pincer Ruthenium(II) Complex	10
Diverse C-Coordination Modes of NHC-Tricyclohexylphosphonium Ylide Ligands in Palladium(II) Complexes	10
Synthesis and Application of Silylene-Stabilized Low-Coordinate Ag(I)–Arene Cationic Complexes	10
Characterization of Cr-Hydrocarbyl Species via Pulse EPR in the Study of Ethylene Tetramerization Catalysis	10
Access to a Variety of Ge(II) and Sn(II) Compounds through Substitution of Hypersilyl Moiety	10
Catalytic Deuteration of C(sp2)–H Bonds of Substituted (Hetero)arenes in a Pt(II) CNN-Pincer Complex/2,2,2-Trifluoroethanol-d1 System: Effect of Substituents on the Reacti	10
Design of Benzimidazolyl Phosphines Bearing AlterableP,OorP,N-Coordination: Synthesis, Characterization, and Insights into Their Reactivity	10
Advancing Base Metal Catalysis through Data Science: Insight and Predictive Models for Ni-Catalyzed Borylation through Supervised Machine Learning	10
NNN Pincer-Manganese-Catalyzed Guerbet-Type β-Alkylation of Alcohols under Microwave Irradiation	10
DFT Approach for Predicting 13C NMR Shifts of Atoms Directly Coordinated to Nickel	10
Consequent Construction of C–C and C–N Bonds via Palladium-Catalyzed Dual C–H Activation: Synthesis of Benzo[c]cinnoline Derivatives	10
Syntheses, Structures, Reactivities, and Dynamic Properties of Gyroscope-like Complexes Consisting of Rh(CO)(X) or Rh(CO)2(I) Rotators and Cage-likeTransAliphatic Dibridgehead Diphos	10
Cytotoxicity of Ruthenium(II) Arene Complexes Containing Functionalized Ferrocenyl β-Diketonate Ligands	10
Palladium(II) Complexes of a Neutral CCC-Tris(N-heterocyclic carbene) Pincer Ligand: Synthesis and Catalytic Applications	10
Mononuclear Copper Complexes with Tridentate Tris(N-heterocyclic carbene): Synthesis and Catalysis of Alkyne–Azide Cycloaddition	10
Access to a Chiral Phosphine–NHC Palladium(II) Complex via the Asymmetric Hydrophosphination of Achiral Vinyl Azoles	10
Amine Functionalized Pincer-like Azo-aromatic Complexes of Cobalt and Their Catalytic Activities in the Synthesis of Quinoline via Acceptorless Dehydrogenation of Alcohols	10
Monocationic Bis-Alkyl and Bis-Allyl Yttrium Complexes: Synthesis, 89Y NMR Characterization, Ethylene or Isoprene Polymerization, and Modeling	10
Synthesis and Characterization of N,N,C and N,N,O Tridentate β-Diketiminato Rare-Earth Metal Alkyl Complexes and Their Catalytic Performances on the Dimerizat	10
Palladium-Catalyzed Denitrogenative Carbonylation of Benzotriazoles with Cr(CO)6 as the Carbonyl Source	10
Synthesis of Platinum-Containing Conjugated Polymers Bearing Chiral Phosphine Ligands. Study of Geometries and Intermolecular Interactions Leading to Aggregation	10
Synthesis, Characterization, and Catalytic Activity of Dinuclear Rare-Earth Metal Alkyl Complexes Bearing 2,6-Diisopropylphenylamidomethyl Functionalized Pyrrolyl Ligand	10
Mechanism of 8-Aminoquinoline-Directed Ni-Catalyzed C(sp3)–H Functionalization: Paramagnetic Ni(II) Species and the Deleterious Effect of Carbonate as a Base	10