Chemical Reviews

Article	Citations
Correction to Depolymerization within a Circular Plastics System	1350
How Softness Matters in Soft Nanogels and Nanogel Assemblies	1234
Topological Materials Go Meta	1147
Introduction: “Noncanonical Amino Acids”	829
Cell-Free Gene Expression: Methods and Applications	803
Genetic Code Expansion Approaches to Decipher the Ubiquitin Code	701
Two-Dimensional Transition Metal Dichalcogenides: A Theory and Simulation Perspective	668
Effects of Crowding and Cosolutes on Biomolecular Function at Extreme Environmental Conditions	657
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Chemistry of Bis(trifluoromethyl)amines: Synthesis, Properties, and Applications	566
The Versatile and Strategic O-Carbamate Directed Metalation Group in the Synthesis of Aromatic Molecules: An Update	537
Cryo-electron Microscopic Analysis of Single-Pass Transmembrane Receptors	531
Nanomaterials for Flexible Neuromorphics	525
Electron Microscopy Studies of Soft Nanomaterials	518
Physicochemical Characterization of Asphaltenes Using Microfluidic Analysis	499
Phase Transitions and Dynamics in Mixed Three- and Low-Dimensional Lead Halide Perovskites	489
Solid-State NMR Investigations of Extracellular Matrixes and Cell Walls of Algae, Bacteria, Fungi, and Plants	483
Depolymerization within a Circular Plastics System	479
Review on the Degradation Mechanisms of Metal-N-C Catalysts for the Oxygen Reduction Reaction in Acid Electrolyte: Current Understanding and Mitigation Approaches	470
New Advances in Covalent Network Polymers via Dynamic Covalent Chemistry	464

Biomimetic Materials to Fabricate Artificial Cells	463
Electrocatalysis in Solid Oxide Fuel Cells and Electrolyzers	458
Connecting the Dots: Sintering of Liquid Metal Particles for Soft and Stretchable Conductors	456
Noncovalent Aggregation for Diverse Properties in Hydrogels: A Comprehensive Review	447
Impedance Spectroscopy of Metal Halide Perovskite Solar Cells from the Perspective of Equivalent Circuits	442
Hydrocarbon Extraction with Ionic Liquids	430
Tunable Chemical Disorder in Concentrated Alloys: Defect Physics and Radiation Performance	430
Coordination Chemistry of Modified Porphyrinoid Systems	426
The Promise and Challenges of Inverted Perovskite Solar Cells	425
Molecular Design Strategies toward Improvement of Charge Injection and Ionic Conduction in Organic Mixed Ionic–Electronic Conductors for Organic Electrochemical Transistors	424
Chemistry, Functionalization, and Applications of Recent Monoelemental Two-Dimensional Materials and Their Heterostructures	422
Ultrahigh-Throughput Enzyme Engineering and Discovery in In Vitro Compartments	422
Energy Applications of Ionic Liquids: Recent Developments and Future Prospects	422
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Diversification of Phage-Displayed Peptide Libraries with Noncanonical Amino Acid Mutagenesis and Chemical Modification	388
Biospecific Chemistry for Covalent Linking of Biomacromolecules	382
Creation from Confusion and Fusion in the Porphyrin World─The Last Three Decades of N-Confused Porphyrinoid Chemistry	381
Revisiting Airflow and Aerosol Transport Phenomena in the Deep Lungs with Microfluidics	374
Ionic Liquids for the Separation of Fluorocarbon Refrigerant Mixtures	367
Process Simulation and Optimization on Ionic Liquids	367
Carbon-based Biradicals: Structural and Magnetic Switching	362
Orbital-Free Density Functional Theory: An Attractive Electronic Structure Method for Large-Scale First-Principles Simulations	359
Neutron Scattering Studies of Heterogeneous Catalysis	359
Electron Diffraction of 3D Molecular Crystals	357
Engineered Proteins and Materials Utilizing Residue-Specific Noncanonical Amino Acid Incorporation	356
Nanoporous Gold: From Structure Evolution to Functional Properties in Catalysis and Electrochemistry	354
Recent Developments for the Deuterium and Tritium Labeling of Organic Molecules	348
Understanding the Electric Double-Layer Structure, Capacitance, and Charging Dynamics	347
Theoretical Modeling of Electrochemical Proton-Coupled Electron Transfer	346
Optical Phenomena in Molecule-Based Magnetic Materials	343
Thermal Stability of Cellulose Nanomaterials	340
Metal Ion-Directed Functional Metal–Phenolic Materials	337
Light–Matter Interactions in Hybrid Material Metasurfaces	337
Cross-Linking Mass Spectrometry for Investigating Protein Conformations and Protein–Protein Interactions─A Method for All Seasons	336
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How to Propose a Great Chemical Reviews Article	318
Soft Biological Actuators for Meter-Scale Homeostatic Biohybrid Robots	315
Correction to Molecular Chirality and Its Monitoring by Ultrafast X-ray Pulses	312
Embracing Heterogeneity: Challenging the Paradigm of Replisomes as Deterministic Machines	304
Introduction: Persistent and Stable Organic Radicals	297
Macromolecular Crowding, Phase Separation, and Homeostasis in the Orchestration of Bacterial Cellular Functions	292

Engineering Pyrrolysine Systems for Genetic Code Expansion and Reprogramming	291
Topological Insulator Metamaterials	291
Shortening Synthetic Routes to Small Molecule Active Pharmaceutical Ingredients Employing Biocatalytic Methods	290
Oxide Ion-Conducting Materials Containing Tetrahedral Moieties: Structures and Conduction Mechanisms	288
Large-Area Epitaxial Growth of Transition Metal Dichalcogenides	287
Charge Transfer from Quantum-Confined 0D, 1D, and 2D Nanocrystals	285
Two-Dimensional Field-Effect Transistor Sensors: The Road toward Commercialization	283
The Past and the Future of Langmuir and Langmuir–Blodgett Films	280
Single-Crystalline Anode Materials: Growth, Applications, Fabrication, and Recycling	279
The Biologically Relevant Coordination Chemistry of Iron and Nitric Oxide: Electronic Structure and Reactivity	278
Hydrothermal Treatment of Biomass Feedstocks for Sustainable Production of Chemicals, Fuels, and Materials: Progress and Perspectives	277
Proton Exchange Membrane (PEM) Water Electrolysis: Cell-Level Considerations for Gigawatt-Scale Deployment	275
The Chemical Reactivity of Membrane Lipids	271
Recent Development of Halide Perovskite Materials and Devices for Ionizing Radiation Detection	271
Defect Chemistry of Titanium Dioxide (Rutile). Progress Toward Sustainable Energy	270
Advances on the Merger of Electrochemistry and Transition Metal Catalysis for Organic Synthesis	269
Insights into Single-Electron-Transfer Processes in Frustrated Lewis Pair Chemistry and Related Donor–Acceptor Systems in Main Group Chemistry	268
Fundamental Aspects of Phase-Separated Biomolecular Condensates	267
Electrochemical Carbon Dioxide Capture and Concentration	266
Colloidal Synthesis of Metal Nanocrystals: From Asymmetrical Growth to Symmetry Breaking	266
Soft Bioelectronics Based on Nanomaterials	263
Electrolytes in Organic Batteries	261
Organic Synthesis Using Nitroxides	259
Emerging Electrochromic Materials and Devices for Future Displays	258
Second-Sphere Lattice Effects in Copper and Iron Zeolite Catalysis	257
Genetic Code Expansion History and Modern Innovations	256
Bioinspired Multifunctional and Dynamic Color-Tuning Photonic Devices	256
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Benchmarking Quantum Gates and Circuits	251
Electrical Stimulation of Cells: Drivers, Technology, and Effects	249
Selective Noncovalent Catalysis with Small Molecules	248
Theory of Anisotropic Metal Nanostructures	248
Glycoinformatics in the Artificial Intelligence Era	246
Spectrochemistry of Firefly Bioluminescence	243
Iodoarene Activation: Take a Leap Forward toward Green and Sustainable Transformations	242
Demystifying the O-GlcNAc Code: A Systems View	241
Metal-Based Photosensitizers as Inducers of Regulated Cell Death Mechanisms	237
Shining New Light on Biological Systems: Luminescent Transition Metal Complexes for Bioimaging and Biosensing Applications	237
Deuteration for High-Resolution Detection of Protons in Protein Magic Angle Spinning (MAS) Solid-State NMR	237
Synthesis and Deconstruction of Polyethylene-type Materials	237
Therapeutic Hydrogels: Properties and Biomedical Applications	234
Fifty Shades of Phenanthroline: Synthesis Strategies to Functionalize 1,10-Phenanthroline in All Positions	233
Metal–Organic Network-Forming Glasses	232
Molecular Views on Mechanisms of Brønsted Acid-Catalyzed Reactions in Zeolites	230
Natural and Synthetic Flavylium-Based Dyes: The Chemistry Behind the Color	228
Ultrafast Magic Angle Spinning Solid-State NMR Spectroscopy: Advances in Methodology and Applications	228
Quinolinate Synthase: An Example of the Roles of the Second and Outer Coordination Spheres in Enzyme Catalysis	227
Issue Editorial Masthead	225
Intelligent Photodetectors: Postmanufacturing Tunability toward Enhanced Performance and Advanced Functions	224
From Protein Film Electrochemistry to Nanoconfined Enzyme Cascades and the Electrochemical Leaf	222
First-Generation Organic Reaction Intermediates in Zeolite Chemistry and Catalysis	220
Electronic Structure and Excited State Dynamics of Cadmium Chalcogenide Nanorods	218
Electrochemical and Non-Electrochemical Pathways in the Electrocatalytic Oxidation of Monosaccharides and Related Sugar Alcohols into Valuable Products	218
Topology in Thermal, Particle, and Plasma Diffusion Metamaterials	218
Stereodynamic Strategies to Induce and Enrich Chirality of Atropisomers at a Late Stage	218
Microenvironment Engineering of Heterogeneous Catalysts for Liquid-Phase Environmental Catalysis	217
Bioinspired and Bioderived Aqueous Electrocatalysis	215
Rare Earth Starting Materials and Methodologies for Synthetic Chemistry	215
Bioadhesive Technology Platforms	212
Atomic Scale Design of MXenes and Their Parent Materials─From Theoretical and Experimental Perspectives	212
Solution-Processable and Printable Two-Dimensional Transition Metal Dichalcogenide Inks	211
Mechanisms and Delivery of tRNA Therapeutics	210
Aryl Transfer Strategies Mediated by Photoinduced Electron Transfer	210
Transition Metal Catalysis Controlled by Hydrogen Bonding in the Second Coordination Sphere	208
Evolution of Copolymers of Epoxides and CO2: Catalysts, Monomers, Architectures, and Applications	207
Design Rules for Obtaining Narrow Luminescence from Semiconductors Made in Solution	206
From Mining to Manufacturing: Scientific Challenges and Opportunities behind Battery Production	206
Nitrogen-Centered Radicals in Functionalization of sp2 Systems: Generation, Reactivity, and Applications in Synthesis	204
Fluorine Chemistry in Rechargeable Batteries: Challenges, Progress, and Perspectives	203
Solid-State Reaction Synthesis of Nanoscale Materials: Strategies and Applications	203
Catalysis of Alloys: Classification, Principles, and Design for a Variety of Materials and Reactions	203
Advances in Bioresorbable Triboelectric Nanogenerators	202
Recent Progress of Amorphous Nanomaterials	202
Recent Advances in the Enantioselective Synthesis of Chiral Amines via Transition Metal-Catalyzed Asymmetric Hydrogenation	201
Ionic Liquids: New Forms of Active Pharmaceutical Ingredients with Unique, Tunable Properties	200
Chiral Induced Spin Selectivity	200
Paramagnetic Chemical Probes for Studying Biological Macromolecules	198

Characterizing Electrode Materials and Interfaces in Solid-State Batteries	197
Hydrolysis, Ligand Exchange, and Redox Properties of Vanadium Compounds: Implications of Solution Transformation on Biological, Therapeutic, and Environmental Applications	196
Flexible Microinterventional Sensors for Advanced Biosignal Monitoring	195
Nondestructive Analysis of Commercial Batteries	194
Unraveling Materials Synthesis Mechanisms Using In Situ Transmission Electron Microscopy and Neutron Scattering	194
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From Angstroms to Nanometers: Measuring Interatomic Distances by Solid-State NMR	184
Polymers without Petrochemicals: Sustainable Routes to Conventional Monomers	182
Carbon Nanodots from an In Silico Perspective	182
The Role of In Situ/Operando IR Spectroscopy in Unraveling Adsorbate-Induced Structural Changes in Heterogeneous Catalysis	181
Colloidal Synthesis of Plasmonic Complex Metal Nanoparticles: Sequential Execution of Multiple Chemical Toolkits Increases Morphological Complexity	180
Recent Advances in the Total Synthesis of the Tetrahydroisoquinoline Alkaloids (2002–2020)	179