Journal of the American Chemical Society

(The TQCC of Journal of the American Chemical Society is 64. The table below lists those papers that are above that threshold based on CrossRef citation counts. The publications cover those that have been published in the past four years, i.e., from 2019-03-01 to 2023-03-01.)
Cobalt in Nitrogen-Doped Graphene as Single-Atom Catalyst for High-Sulfur Content Lithium–Sulfur Batteries833
Two-Dimensional Hybrid Halide Perovskites: Principles and Promises751
Covalent Organic Frameworks: Chemistry beyond the Structure655
Ligand Exchange and the Stoichiometry of Metal Chalcogenide Nanocrystals: Spectroscopic Observation of Facile Metal-Carboxylate Displacement and Binding634
Self-Assembled Copper–Amino Acid Nanoparticles for in Situ Glutathione “AND” H2O2 Sequentially Triggered Chemodynamic Therapy597
Synthesis of Copper Peroxide Nanodots for H2O2 Self-Supplying Chemodynamic Therapy547
Molecule Self-Assembly Synthesis of Porous Few-Layer Carbon Nitride for Highly Efficient Photoredox Catalysis514
Element Replacement Approach by Reaction with Lewis Acidic Molten Salts to Synthesize Nanolaminated MAX Phases and MXenes496
Building Up a Picture of the Electrocatalytic Nitrogen Reduction Activity of Transition Metal Single-Atom Catalysts493
Understanding the Roadmap for Electrochemical Reduction of CO2 to Multi-Carbon Oxygenates and Hydrocarbons on Copper-Based Catalysts489
Hierarchical Nanoassembly of MoS2/Co9S8/Ni3S2/Ni as a Highly Efficient Electrocatalyst for Overall Water Splitting in a Wide pH Range469
Tuning the Coordination Environment in Single-Atom Catalysts to Achieve Highly Efficient Oxygen Reduction Reactions465
Tailoring Passivation Molecular Structures for Extremely Small Open-Circuit Voltage Loss in Perovskite Solar Cells454
Carboxylic Acids as A Traceless Activation Group for Conjugate Additions: A Three-Step Synthesis of (±)-Pregabalin413
UTSA-74: A MOF-74 Isomer with Two Accessible Binding Sites per Metal Center for Highly Selective Gas Separation410
Single-Atom Vacancy Defect to Trigger High-Efficiency Hydrogen Evolution of MoS2399
Single-Boron Catalysts for Nitrogen Reduction Reaction395
Decarboxylative Arylation of α-Amino Acids via Photoredox Catalysis: A One-Step Conversion of Biomass to Drug Pharmacophore392
Scalable Production of Efficient Single-Atom Copper Decorated Carbon Membranes for CO2 Electroreduction to Methanol392
Highly Efficient and Selective Generation of Ammonia and Hydrogen on a Graphdiyne-Based Catalyst385
A Covalent Organic Framework Bearing Single Ni Sites as a Synergistic Photocatalyst for Selective Photoreduction of CO2 to CO384
In Situ Observation of Active Oxygen Species in Fe-Containing Ni-Based Oxygen Evolution Catalysts: The Effect of pH on Electrochemical Activity375
Fabrication of COF-MOF Composite Membranes and Their Highly Selective Separation of H2/CO2370
Versatile Strategy for Tuning ORR Activity of a Single Fe-N4 Site by Controlling Electron-Withdrawing/Donating Properties of a Carbon Plane363
Bismuth Single Atoms Resulting from Transformation of Metal–Organic Frameworks and Their Use as Electrocatalysts for CO2 Reduction358
Molecular Motion in Aggregates: Manipulating TICT for Boosting Photothermal Theranostics358
MXene (Ti3C2) Vacancy-Confined Single-Atom Catalyst for Efficient Functionalization of CO2352
Engineering Interfacial Charge Transfer in CsPbBr3 Perovskite Nanocrystals by Heterovalent Doping351
Se-Doping Activates FeOOH for Cost-Effective and Efficient Electrochemical Water Oxidation344
Metal–Organic Frameworks as Catalysts for Organic Synthesis: A Critical Perspective343
Merging Photoredox and Nickel Catalysis: Decarboxylative Cross-Coupling of Carboxylic Acids with Vinyl Halides339
Adaptable Crosslinks in Polymeric Materials: Resolving the Intersection of Thermoplastics and Thermosets339
Macrocyclic Peptides as Drug Candidates: Recent Progress and Remaining Challenges326
Highly Active and Stable Metal Single-Atom Catalysts Achieved by Strong Electronic Metal–Support Interactions324
Activity–Selectivity Trends in the Electrochemical Production of Hydrogen Peroxide over Single-Site Metal–Nitrogen–Carbon Catalysts323
Photoredox α-Vinylation of α-Amino Acids and N-Aryl Amines317
Design Principle of Fe–N–C Electrocatalysts: How to Optimize Multimodal Porous Structures?306
14.7% Efficiency Organic Photovoltaic Cells Enabled by Active Materials with a Large Electrostatic Potential Difference305
Efficient and Long-Lived Room-Temperature Organic Phosphorescence: Theoretical Descriptors for Molecular Designs298
Highly Efficient Fullerene-Free Organic Solar Cells Operate at Near Zero Highest Occupied Molecular Orbital Offsets297
A Scalable General Synthetic Approach toward Ultrathin Imine-Linked Two-Dimensional Covalent Organic Framework Nanosheets for Photocatalytic CO2 Reduction295
Climbing the Apex of the ORR Volcano Plot via Binuclear Site Construction: Electronic and Geometric Engineering294
“Superaerophobic” Nickel Phosphide Nanoarray Catalyst for Efficient Hydrogen Evolution at Ultrahigh Current Densities294
Electrochemical Fragmentation of Cu2O Nanoparticles Enhancing Selective C–C Coupling from CO2 Reduction Reaction290
C3N5: A Low Bandgap Semiconductor Containing an Azo-Linked Carbon Nitride Framework for Photocatalytic, Photovoltaic and Adsorbent Applications289
Versatile Nanoemulsion Assembly Approach to Synthesize Functional Mesoporous Carbon Nanospheres with Tunable Pore Sizes and Architectures286
A Fine-Tuned Fluorinated MOF Addresses the Needs for Trace CO2 Removal and Air Capture Using Physisorption285
Functional DNA Regulated CRISPR-Cas12a Sensors for Point-of-Care Diagnostics of Non-Nucleic-Acid Targets284
A Cobalt–Iron Double-Atom Catalyst for the Oxygen Evolution Reaction283
J-Aggregates of Cyanine Dye for NIR-II in Vivo Dynamic Vascular Imaging beyond 1500 nm282
Broadband Emission in Two-Dimensional Hybrid Perovskites: The Role of Structural Deformation281
Universal Strategy for HF-Free Facile and Rapid Synthesis of Two-dimensional MXenes as Multifunctional Energy Materials281
Structural Sensitivities in Bimetallic Catalysts for Electrochemical CO2 Reduction Revealed by Ag–Cu Nanodimers278
Ultrahigh-Loading of Ir Single Atoms on NiO Matrix to Dramatically Enhance Oxygen Evolution Reaction278
Highly Active and Stable Single-Atom Cu Catalysts Supported by a Metal–Organic Framework275
Small-Molecule Fluorescent Probes for Live-Cell Super-Resolution Microscopy274
Regulating the Inner Helmholtz Plane for Stable Solid Electrolyte Interphase on Lithium Metal Anodes272
Rational Design of Near-Infrared Aggregation-Induced-Emission-Active Probes: In Situ Mapping of Amyloid-β Plaques with Ultrasensitivity and High-Fidelity269
Reverse Dual-Ion Battery via a ZnCl2 Water-in-Salt Electrolyte268
Fluorination Effects on Indacenodithienothiophene Acceptor Packing and Electronic Structure, End-Group Redistribution, and Solar Cell Photovoltaic Response266
Molecular Catalysis of the Electrochemical and Photochemical Reduction of CO2 with Earth-Abundant Metal Complexes. Selective Production of CO vs HCOOH by Switching of the Metal Center264
Properties of Pure Normal Alkanes in the C17 to C36 Range264
Metal–Organic Frameworks Mediate Cu Coordination for Selective CO2Electroreduction260
Application of a High-Throughput Analyzer in Evaluating Solid Adsorbents for Post-Combustion Carbon Capture via Multicomponent Adsorption of CO2, N2, and H2O257
Pore Space Partition within a Metal–Organic Framework for Highly Efficient C2H2/CO2 Separation255
Enhanced Activity of Enzymes Encapsulated in Hydrophilic Metal–Organic Frameworks255
Dimeric Drug Polymeric Nanoparticles with Exceptionally High Drug Loading and Quantitative Loading Efficiency251
Sintering-Resistant Single-Site Nickel Catalyst Supported by Metal–Organic Framework250
Hollow Multi-Shelled Structures of Co3O4 Dodecahedron with Unique Crystal Orientation for Enhanced Photocatalytic CO2 Reduction245
Semiconducting 2D Triazine-Cored Covalent Organic Frameworks with Unsubstituted Olefin Linkages244
Crystalline 2D Covalent Organic Framework Membranes for High-Flux Organic Solvent Nanofiltration243
Macro/Microporous Covalent Organic Frameworks for Efficient Electrocatalysis243
Supramolecular Assembly-Induced Emission Enhancement for Efficient Mercury(II) Detection and Removal241
Highly Efficient and Selective Photocatalytic CO2 Reduction by Iron and Cobalt Quaterpyridine Complexes237
Three-Dimensional Metal-Catecholate Frameworks and Their Ultrahigh Proton Conductivity237
Disphenoidal Zero-Dimensional Lead, Tin, and Germanium Halides: Highly Emissive Singlet and Triplet Self-Trapped Excitons and X-ray Scintillation236
Binding Site Diversity Promotes CO2 Electroreduction to Ethanol235
Ultrafine Titanium Monoxide (TiO1+x) Nanorods for Enhanced Sonodynamic Therapy234
Porous Crystalline Olefin-Linked Covalent Organic Frameworks233
Hybridization of Local Exciton and Charge-Transfer States Reduces Nonradiative Voltage Losses in Organic Solar Cells232
Photoelectrochemical Reduction of CO2 Coupled to Water Oxidation Using a Photocathode with a Ru(II)–Re(I) Complex Photocatalyst and a CoOx/TaON Photoanode232
Effect of MnO2 Crystal Structure on Aerobic Oxidation of 5-Hydroxymethylfurfural to 2,5-Furandicarboxylic Acid229
Breaking Long-Range Order in Iridium Oxide by Alkali Ion for Efficient Water Oxidation229
Electrochemical Reduction of N2 into NH3 by Donor–Acceptor Couples of Ni and Au Nanoparticles with a 67.8% Faradaic Efficiency225
Rapid Proton-Detected NMR Assignment for Proteins with Fast Magic Angle Spinning225
Biomedically Relevant Self-Assembled Metallacycles and Metallacages224
Stoichiometry-Controlled InP-Based Quantum Dots: Synthesis, Photoluminescence, and Electroluminescence223
Evaluation of Structure–Function Relationships of Aggregation-Induced Emission Luminogens for Simultaneous Dual Applications of Specific Discrimination and Efficient Photodynamic Killing of Gram-Posit222
In Situ Construction of a Cs2SnI6 Perovskite Nanocrystal/SnS2 Nanosheet Heterojunction with Boosted Interfacial Charge Transfer222
Shape of Glycine221
Ultrahigh Performance in Lead-Free Piezoceramics Utilizing a Relaxor Slush Polar State with Multiphase Coexistence220
Thermal Emitting Strategy to Synthesize Atomically Dispersed Pt Metal Sites from Bulk Pt Metal220
Two-Dimensional Amorphous TiO2 Nanosheets Enabling High-Efficiency Photoinduced Charge Transfer for Excellent SERS Activity219
Activation of C–H Bonds via the Merger of Photoredox and Organocatalysis: A Coupling of Benzylic Ethers with Schiff Bases218
Engineering Energy Level of Metal Center: Ru Single-Atom Site for Efficient and Durable Oxygen Reduction Catalysis215
Nanoscale ATP-Responsive Zeolitic Imidazole Framework-90 as a General Platform for Cytosolic Protein Delivery and Genome Editing214
Enhanced Charge Transport in 2D Perovskites via Fluorination of Organic Cation213
Molecular Cobalt Complexes with Pendant Amines for Selective Electrocatalytic Reduction of Carbon Dioxide to Formic Acid212
Open-Air Alkylation Reactions in Photoredox-Catalyzed DNA-Encoded Library Synthesis211
Two-Dimensional Chemiresistive Covalent Organic Framework with High Intrinsic Conductivity211
Pure Organic Room Temperature Phosphorescence from Excited Dimers in Self-Assembled Nanoparticles under Visible and Near-Infrared Irradiation in Water210
Engineering of Upconverted Metal–Organic Frameworks for Near-Infrared Light-Triggered Combinational Photodynamic/Chemo-/Immunotherapy against Hypoxic Tumors208
Ni Single Atom Catalysts for CO2 Activation208
Structural and Electronic Optimization of MoS2 Edges for Hydrogen Evolution208
Lead-Halide Perovskites for Photocatalytic α-Alkylation of Aldehydes206
Accelerated Discovery of Organic Polymer Photocatalysts for Hydrogen Evolution from Water through the Integration of Experiment and Theory206
Collapse of LiNi1–xyCoxMnyO2 Lattice at Deep Charge Irrespective of Nickel Content in Lithium-Ion Batteries206
Activatable NIR Fluorescence/MRI Bimodal Probes for in Vivo Imaging by Enzyme-Mediated Fluorogenic Reaction and Self-Assembly205
A Robust Ethane-Trapping Metal–Organic Framework with a High Capacity for Ethylene Purification205
Photoactivatable Organic Semiconducting Pro-nanoenzymes203
Triazine Functionalized Porous Covalent Organic Framework for Photo-organocatalytic EZ Isomerization of Olefins203
Superhydrophobic Materials for Tunable Drug Release: Using Displacement of Air To Control Delivery Rates202
Turning on Visible-Light Photocatalytic C−H Oxidation over Metal–Organic Frameworks by Introducing Metal-to-Cluster Charge Transfer201
Tunable Redox Chemistry and Stability of Radical Intermediates in 2D Covalent Organic Frameworks for High Performance Sodium Ion Batteries199
Engineering Janus Interfaces of Ceramic Electrolyte via Distinct Functional Polymers for Stable High-Voltage Li-Metal Batteries199
Titanium-Based Nanoscale Metal–Organic Framework for Type I Photodynamic Therapy197
Integrating Suitable Linkage of Covalent Organic Frameworks into Covalently Bridged Inorganic/Organic Hybrids toward Efficient Photocatalysis196
Ion/Molecule Transportation in Nanopores and Nanochannels: From Critical Principles to Diverse Functions196
Spin density in a nitronyl nitroxide free radical. Polarized neutron diffraction investigation and ab initio calculations196
Size-Controllable Synthesis of Uniform Spherical Covalent Organic Frameworks at Room Temperature for Highly Efficient and Selective Enrichment of Hydrophobic Peptides195
Functional Role of Fe-Doping in Co-Based Perovskite Oxide Catalysts for Oxygen Evolution Reaction194
Enhanced Superoxide Generation on Defective Surfaces for Selective Photooxidation194
Electrochemically Driven, Ni-Catalyzed Aryl Amination: Scope, Mechanism, and Applications194
A Fast and Selective Near-Infrared Fluorescent Sensor for Multicolor Imaging of Biological Nitroxyl (HNO)193
Rotation Restricted Emission and Antenna Effect in Single Metal–Organic Frameworks193
Nickel-Catalyzed Asymmetric Reductive Cross-Coupling Between Vinyl and Benzyl Electrophiles192
The Second Quantum Revolution: Role and Challenges of Molecular Chemistry192
Solvent-Free, Single Lithium-Ion Conducting Covalent Organic Frameworks191
Two-Dimensional Hybrid Perovskite-Type Ferroelectric for Highly Polarization-Sensitive Shortwave Photodetection191
Branched Copper Oxide Nanoparticles Induce Highly Selective Ethylene Production by Electrochemical Carbon Dioxide Reduction190
Ultrathin Black Phosphorus-on-Nitrogen Doped Graphene for Efficient Overall Water Splitting: Dual Modulation Roles of Directional Interfacial Charge Transfer190
Crystalline Lithium Imidazolate Covalent Organic Frameworks with High Li-Ion Conductivity189
An Emerging Molecular Design Approach to Heavy-Atom-Free Photosensitizers for Enhanced Photodynamic Therapy under Hypoxia188
Rh(III)-Catalyzed Asymmetric Synthesis of Axially Chiral Biindolyls by Merging C–H Activation and Nucleophilic Cyclization188
Wet-Chemistry Strong Metal–Support Interactions in Titania-Supported Au Catalysts188
Catalytic asymmetric nitroaldol reaction using optically active rare earth BINOL complexes: investigation of the catalyst structure187
A Near-IR Uncaging Strategy Based on Cyanine Photochemistry185
Nickel-Catalyzed Asymmetric Reductive Cross-Coupling To Access 1,1-Diarylalkanes184
Symmetry in Cascade Chirality-Transfer Processes: A Catalytic Atroposelective Direct Arylation Approach to BINOL Derivatives184
Phenazine-Based Covalent Organic Framework Cathode Materials with High Energy and Power Densities184
Uniform Alignment of Non-π-Conjugated Species Enhances Deep Ultraviolet Optical Nonlinearity183
Single Site Cobalt Substitution in 2D Molybdenum Carbide (MXene) Enhances Catalytic Activity in the Hydrogen Evolution Reaction181
Self-Adjusting Activity Induced by Intrinsic Reaction Intermediate in Fe–N–C Single-Atom Catalysts181
Surface Plasmon Enabling Nitrogen Fixation in Pure Water through a Dissociative Mechanism under Mild Conditions181
Highly Efficient Photo- and Electroluminescence from Two-Coordinate Cu(I) Complexes Featuring Nonconventional N-Heterocyclic Carbenes180
X-ray and UV Dual Photochromism, Thermochromism, Electrochromism, and Amine-Selective Chemochromism in an Anderson-like Zn7 Cluster-Based 7-Fold Interpenetrated Framework179
Tuning P2-Structured Cathode Material by Na-Site Mg Substitution for Na-Ion Batteries179
Photoreforming of Nonrecyclable Plastic Waste over a Carbon Nitride/Nickel Phosphide Catalyst178
Selective C–C Coupling in Carbon Dioxide Electroreduction via Efficient Spillover of Intermediates As Supported by Operando Raman Spectroscopy178
De Novo Design of Chemical Stability Near-Infrared Molecular Probes for High-Fidelity Hepatotoxicity Evaluation In Vivo178
Sustained Solar H2 Evolution from a Thiazolo[5,4-d]thiazole-Bridged Covalent Organic Framework and Nickel-Thiolate Cluster in Water178
Photocatalytic CO2 Conversion of M0.33WO3 Directly from the Air with High Selectivity: Insight into Full Spectrum-Induced Reaction Mechanism178
Asymmetric Nanopore Electrode-Based Amplification for Electron Transfer Imaging in Live Cells177
The Dynamic Character of the BCL2 Promoter i-Motif Provides a Mechanism for Modulation of Gene Expression by Compounds That Bind Selectively to the Alternative DNA Hairpin Structure177
Fluorogenic Probes for Multicolor Imaging in Living Cells176
Chiral BINOL-Based Covalent Organic Frameworks for Enantioselective Sensing176
Synergy of Single-Atom Ni1 and Ru1 Sites on CeO2 for Dry Reforming of CH4175
Surface-Confined Electrochemiluminescence Microscopy of Cell Membranes174
Single Cell Electrochemiluminescence Imaging: From the Proof-of-Concept to Disposable Device-Based Analysis173
Product Selectivity Controlled by Nanoporous Environments in Zeolite Crystals Enveloping Rhodium Nanoparticle Catalysts for CO2 Hydrogenation173
The Transcriptional Complex Between the BCL2 i-Motif and hnRNP LL Is a Molecular Switch for Control of Gene Expression That Can Be Modulated by Small Molecules172
Site-Selective Growth of Crystalline Ceria with Oxygen Vacancies on Gold Nanocrystals for Near-Infrared Nitrogen Photofixation171
Superoxide Radical Photogenerator with Amplification Effect: Surmounting the Achilles’ Heels of Photodynamic Oncotherapy170
Enhanced Tumor-Specific Disulfiram Chemotherapy by In Situ Cu2+ Chelation-Initiated Nontoxicity-to-Toxicity Transition170
Noncovalently Functionalized Monolayer Graphene for Sensitivity Enhancement of Surface Plasmon Resonance Immunosensors169
C60-Adsorbed Single-Walled Carbon Nanotubes as Metal-Free, pH-Universal, and Multifunctional Catalysts for Oxygen Reduction, Oxygen Evolution, and Hydrogen Evolution169
Ionization and Anion−π+ Interaction: A New Strategy for Structural Design of Aggregation-Induced Emission Luminogens169
Accumulation of Glassy Poly(ethylene oxide) Anchored in a Covalent Organic Framework as a Solid-State Li+ Electrolyte169
Nickel-Catalyzed Asymmetric Reductive Cross-Coupling between Heteroaryl Iodides and α-Chloronitriles168
DNA-Functionalized Metal–Organic Framework Nanoparticles for Intracellular Delivery of Proteins168
Fast Ion Transport Pathway Provided by Polyethylene Glycol Confined in Covalent Organic Frameworks168
Chiral Molecule-mediated Porous CuxO Nanoparticle Clusters with Antioxidation Activity for Ameliorating Parkinson’s Disease168
Chemistry for Covalent Modification of Endogenous/Native Proteins: From Test Tubes to Complex Biological Systems167
Investigating the Origin of Enhanced C2+ Selectivity in Oxide-/Hydroxide-Derived Copper Electrodes during CO2 Electroreduction166
High Proton Conduction at above 100 °C Mediated by Hydrogen Bonding in a Lanthanide Metal–Organic Framework166
Unprecedented Ultralow Detection Limit of Amines using a Thiadiazole-Functionalized Zr(IV)-Based Metal–Organic Framework166
Two-Dimensional Dion–Jacobson Hybrid Lead Iodide Perovskites with Aromatic Diammonium Cations166
Tuning of Trifunctional NiCu Bimetallic Nanoparticles Confined in a Porous Carbon Network with Surface Composition and Local Structural Distortions for the Electrocatalytic Oxygen Reduction, Oxygen an166
Few-Nanometer-Sized α-CsPbI3 Quantum Dots Enabled by Strontium Substitution and Iodide Passivation for Efficient Red-Light Emitting Diodes165
Near-Infrared Fluorescent Macromolecular Reporters for Real-Time Imaging and Urinalysis of Cancer Immunotherapy165
Aromatic Saddles Containing Two Heptagons163
N-Heterocyclic Carbene-Catalyzed Decarboxylative Alkylation of Aldehydes163
Construction of a Multiple-Aptamer-Based DNA Logic Device on Live Cell Membranes via Associative Toehold Activation for Accurate Cancer Cell Identification163
Strong Phonon–Phonon Interactions Securing Extraordinary Thermoelectric Ge1–xSbxTe with Zn-Alloying-Induced Band Alignment163
High-Efficiency, Hysteresis-Less, UV-Stable Perovskite Solar Cells with Cascade ZnO–ZnS Electron Transport Layer163
Direct β-Alkylation of Aldehydes via Photoredox Organocatalysis162
Stimuli-Responsive, Pentapeptide, Nanofiber Hydrogel for Tissue Engineering162
Alcohols as Latent Coupling Fragments for Metallaphotoredox Catalysis: sp3–sp2 Cross-Coupling of Oxalates with Aryl Halides161
A NIR Light Gated DNA Nanodevice for Spatiotemporally Controlled Imaging of MicroRNA in Cells and Animals161
In Situ Monitoring Apoptosis Process by a Self-Reporting Photosensitizer161
Multicomponent [5 + 2] Cycloaddition Reaction for the Synthesis of 1,4-Diazepines: Isolation and Reactivity of Azomethine Ylides160
A Metal–Organic Framework of Organic Vertices and Polyoxometalate Linkers as a Solid-State Electrolyte160
Ordered Macro–Microporous Metal–Organic Framework Single Crystals and Their Derivatives for Rechargeable Aluminum-Ion Batteries159
Ensemble Effect in Bimetallic Electrocatalysts for CO2 Reduction159
Photocarboxylation of Benzylic C–H Bonds158
Why Do Simple Molecules with “Isolated” Phenyl Rings Emit Visible Light?158
Welding Metallophthalocyanines into Bimetallic Molecular Meshes for Ultrasensitive, Low-Power Chemiresistive Detection of Gases158
Polycyclic Arene Synthesis by Annulative π-Extension158
Convincing Synthesis of Atomically Thin, Single-Crystalline InVO4 Sheets toward Promoting Highly Selective and Efficient Solar Conversion of CO2 into CO157
Metal–Organic Framework Coating Enhances the Performance of Cu2O in Photoelectrochemical CO2 Reduction157
Unveiling Electronic Properties in Metal–Phthalocyanine-Based Pyrazine-Linked Conjugated Two-Dimensional Covalent Organic Frameworks156
Uniaxial Expansion of the 2D Ruddlesden–Popper Perovskite Family for Improved Environmental Stability156
Direct and Selective Photocatalytic Oxidation of CH4 to Oxygenates with O2 on Cocatalysts/ZnO at Room Temperature in Water155
Unifying the Hydrogen Evolution and Oxidation Reactions Kinetics in Base by Identifying the Catalytic Roles of Hydroxyl-Water-Cation Adducts154
Cage-Interconnected Metal–Organic Framework with Tailored Apertures for Efficient C2H6/C2H4 Separation under Humid Conditions154
Challenges and Solutions in Developing Ultrasensitive Biosensors154
Rapid Covalent-Probe Discovery by Electrophile-Fragment Screening154
Enantioselective Trapping of Pd-Containing 1,5-Dipoles by Photogenerated Ketenes: Access to 7-Membered Lactones Bearing Chiral Quaternary Stereocenters154
Stereodefined Codoping of sp-N and S Atoms in Few-Layer Graphdiyne for Oxygen Evolution Reaction153
Tunable Photocatalytic Water Splitting by the Ferroelectric Switch in a 2D AgBiP2Se6 Monolayer153
Toward an Atomic-Scale Understanding of Electrochemical Interface Structure and Dynamics152
1T′ Transition Metal Telluride Atomic Layers for Plasmon-Free SERS at Femtomolar Levels152
A General Strategy for Fabricating Isolated Single Metal Atomic Site Catalysts in Y Zeolite152
Perylene-Based Covalent Organic Frameworks for Acid Vapor Sensing151
Acid Responsive Hydrogen-Bonded Organic Frameworks151
Nanoscale Surface Structure–Activity in Electrochemistry and Electrocatalysis150
Dynamical Transformation of Two-Dimensional Perovskites with Alternating Cations in the Interlayer Space for High-Performance Photovoltaics150
New Family of Argyrodite Thioantimonate Lithium Superionic Conductors149
Ferroptosis Accompanied by OH Generation and Cytoplasmic Viscosity Increase Revealed via Dual-Functional Fluorescence Probe149
Cobalt-Modulated Molybdenum–Dinitrogen Interaction in MoS2 for Catalyzing Ammonia Synthesis148
Enantiopure Peptide-Functionalized Metal–Organic Frameworks147
Designer HF-Based Fluorination Reagent: Highly Regioselective Synthesis of Fluoroalkenes and gem-Difluoromethylene Compounds from Alkynes147
Valence Engineering via Selective Atomic Substitution on Tetrahedral Sites in Spinel Oxide for Highly Enhanced Oxygen Evolution Catalysis147
Ga-Doped and Pt-Loaded Porous TiO2–SiO2 for Photocatalytic Nonoxidative Coupling of Methane147
Modular o-Quinone Catalyst System for Dehydrogenation of Tetrahydroquinolines under Ambient Conditions146
Renaissance of Fused Porphyrins: Substituted Methylene-Bridged Thiophene-Fused Strategy for High-Performance Dye-Sensitized Solar Cells146
Unraveling Oxygen Evolution on Iron-Doped β-Nickel Oxyhydroxide: The Key Role of Highly Active Molecular-like Sites146
A Bulky Chiral N-Heterocyclic Carbene Palladium Catalyst Enables Highly Enantioselective Suzuki–Miyaura Cross-Coupling Reactions for the Synthesis of Biaryl Atropisomers145
Highly Polarizable Hg2+ Induced a Strong Second Harmonic Generation Signal and Large Birefringence in LiHgPO4145
Crucial Role of Surface Hydroxyls on the Activity and Stability in Electrochemical CO2 Reduction145
Supramolecular Polymorphism in One-Dimensional Self-Assembly by Kinetic Pathway Control144
Dramatic Differences in Aggregation-Induced Emission and Supramolecular Polymerizability of Tetraphenylethene-Based Stereoisomers144
Getting into Shape: Reflections on a New Generation of Cylindrical Nanostructures’ Self-Assembly Using Polymer Building Blocks144
Three-dimensional Salphen-based Covalent–Organic Frameworks as Catalytic Antioxidants144
Structural Evolution and Dynamics of an In2O3 Catalyst for CO2 Hydrogenation to Methanol: An Operando XAS-XRD and In Situ TEM Study144
Boosted Oxygen Evolution Reactivity by Igniting Double Exchange Interaction in Spinel Oxides144
Testing the Vesicular Morphology to Destruction: Birth and Death of Diblock Copolymer Vesicles Prepared via Polymerization-Induced Self-Assembly143
Rh-Catalyzed Decarbonylative Coupling with Alkynes via C–C Activation of Isatins143
Iron-Catalyzed C–H Borylation of Arenes143
Metal–Organic-Framework-Derived Co–Fe Bimetallic Oxygen Reduction Electrocatalysts for Alkaline Fuel Cells143
Synthesis and Magnetism of Neutral, Linear Metallocene Complexes of Terbium(II) and Dysprosium(II)143
Unconventional p–d Hybridization Interaction in PtGa Ultrathin Nanowires Boosts Oxygen Reduction Electrocatalysis143
pH and Amphiphilic Structure Direct Supramolecular Behavior in Biofunctional Assemblies142
Rectification of Concentration Polarization in Mesopores Leads To High Conductance Ionic Diodes and High Performance Osmotic Power142
Cation-Dependent Hot Carrier Cooling in Halide Perovskite Nanocrystals141
λ-DNA- and Aptamer-Mediated Sorting and Analysis of Extracellular Vesicles141
Highly Enantioselective Cross-Electrophile Aryl-Alkenylation of Unactivated Alkenes141
Single-Atom Mn–N4 Site-Catalyzed Peroxone Reaction for the Efficient Production of Hydroxyl Radicals in an Acidic Solution141
A Carbon Nitride/Fe Quaterpyridine Catalytic System for Photostimulated CO2-to-CO Conversion with Visible Light140
N-Heterocyclic Carbene-Catalyzed Radical Relay Enabling Vicinal Alkylacylation of Alkenes140
Observation of Acetylcholinesterase in Stress-Induced Depression Phenotypes by Two-Photon Fluorescence Imaging in the Mouse Brain140
Electrochemiluminescence-Based Capacitance Microscopy for Label-Free Imaging of Antigens on the Cellular Plasma Membrane139
Stable Radical Cation-Containing Covalent Organic Frameworks Exhibiting Remarkable Structure-Enhanced Photothermal Conversion139
Stereodivergent Coupling of 1,3-Dienes with Aldimine Esters Enabled by Synergistic Pd and Cu Catalysis139
Metal–Organic Frameworks as Surface Enhanced Raman Scattering Substrates with High Tailorability139
Anion Recognition in Water by Charge-Neutral Halogen and Chalcogen Bonding Foldamer Receptors138
Mechanism of Ni-Catalyzed Reductive 1,2-Dicarbofunctionalization of Alkenes138
“Quick-Silver” from a Systematic Study of Highly Luminescent, Two-Coordinate, d10 Coinage Metal Complexes138
Rational Design via Synergistic Combination Leads to an Outstanding Deep-Ultraviolet Birefringent Li2Na2B2O5 Material with an Unvalued B2O5<138
Reversible, Room-Temperature C—C Bond Activation of Benzene by an Isolable Metal Complex137
Electron Accumulation Induces Efficiency Bottleneck for Hydrogen Production in Carbon Nitride Photocatalysts137
Cryogenic CO Oxidation on TiO2-Supported Gold Nanoclusters Precovered with Atomic Oxygen137
Evolution Pathway from Iron Compounds to Fe1(II)–N4 Sites through Gas-Phase Iron during Pyrolysis137
KLi(HC3N3O3)·2H2O: Solvent-drop Grinding Method toward the Hydro-isocyanurate Nonlinear Optical Crystal136
Biodegradation-Mediated Enzymatic Activity-Tunable Molybdenum Oxide Nanourchins for Tumor-Specific Cascade Catalytic Therapy136
A Highly Selective Electrochemical DNA-Based Sensor That Employs Steric Hindrance Effects to Detect Proteins Directly in Whole Blood136
Unimolecular Chemo-fluoro-luminescent Reporter for Crosstalk-Free Duplex Imaging of Hepatotoxicity136
Highly Chemoselective, Transition-Metal-Free Transamidation of Unactivated Amides and Direct Amidation of Alkyl Esters by N–C/O–C Cleavage136
Two Non-π-Conjugated Deep-UV Nonlinear Optical Sulfates136
Perspective and Prospectus on Single-Entity Electrochemistry135
Controlling Supramolecular Chirality of Two-Component Hydrogels by J- and H-Aggregation of Building Blocks135
Inducing Disorder in Order: Hierarchically Porous Covalent Organic Framework Nanostructures for Rapid Removal of Persistent Organic Pollutants135
Two-Dimensional Organic–Inorganic Hybrid Rare-Earth Double Perovskite Ferroelectrics135
Ligand-Controlled Chemoselective C(acyl)–O Bond vs C(aryl)–C Bond Activation of Aromatic Esters in Nickel Catalyzed C(sp2)–C(sp3) Cross-Couplings134
Triplet Energy Transfer from CsPbBr3 Nanocrystals Enabled by Quantum Confinement134
Lithium-Doping Stabilized High-Performance P2–Na0.66Li0.18Fe0.12Mn0.7O2 Cathode for Sodium Ion Batteries134
Mechanism of Photocatalytic CO2 Reduction by Bismuth-Based Perovskite Nanocrystals at the Gas–Solid Interface134
In Situ Photoconversion of Multicolor Luminescence and Pure White Light Emission Based on Carbon Dot-Supported Supramolecular Assembly133
Physiological-Temperature Distance Measurement in Nucleic Acid using Triarylmethyl-Based Spin Labels and Pulsed Dipolar EPR Spectroscopy133
Tailoring Lattice Oxygen Binding in Ruthenium Pyrochlores to Enhance Oxygen Evolution Activity132
In Situ Infrared Spectroscopy Reveals Persistent Alkalinity near Electrode Surfaces during CO2 Electroreduction132
Enzyme Encapsulation in a Porous Hydrogen-Bonded Organic Framework132
Interpenetrating Liquid-Crystal Polyurethane/Polyacrylate Elastomer with Ultrastrong Mechanical Property132
Synthesis of Cyclobutane-Fused Angular Tetracyclic Spiroindolines via Visible-Light-Promoted Intramolecular Dearomatization of Indole Derivatives132
Trapping a Highly Reactive Nonheme Iron Intermediate That Oxygenates Strong C—H Bonds with Stereoretention132
Crystal Facets Make a Profound Difference in Polyoxometalate-Containing Metal–Organic Frameworks as Catalysts for Biodiesel Production131
De Novo Design and Facile Synthesis of 2D Covalent Organic Frameworks: A Two-in-One Strategy131
Postsynthetic Metalation of a Robust Hydrogen-Bonded Organic Framework for Heterogeneous Catalysis131
Correlated Electrochemical and Optical Detection Reveals the Chemical Reactivity of Individual Silver Nanoparticles130
Highly Stable Lead-Free Perovskite Field-Effect Transistors Incorporating Linear π-Conjugated Organic Ligands130
An Optical/Photoacoustic Dual-Modality Probe: Ratiometric in/ex Vivo Imaging for Stimulated H2S Upregulation in Mice130
Assembling a Natural Small Molecule into a Supramolecular Network with High Structural Order and Dynamic Functions130
New Horizons of Nonclassical Crystallization129
Catalytic Enantioselective Addition of Prochiral Radicals to Vinylpyridines129
Ni-Catalyzed Reductive Dicarbofunctionalization of Nonactivated Alkenes: Scope and Mechanistic Insights129
Two-Dimensional Anti-Van’t Hoff/Le Bel Array AlB6 with High Stability, Unique Motif, Triple Dirac Cones, and Superconductivity129
Microporous 3D Covalent Organic Frameworks for Liquid Chromatographic Separation of Xylene Isomers and Ethylbenzene129
Selective Ethane/Ethylene Separation in a Robust Microporous Hydrogen-Bonded Organic Framework129
Polymer Crystallinity Controls Water Uptake in Glycol Side-Chain Polymer Organic Electrochemical Transistors128
High Exciton Diffusion Coefficients in Fused Ring Electron Acceptor Films128
Three-Dimensional Phthalocyanine Metal-Catecholates for High Electrochemical Carbon Dioxide Reduction128
Asymmetric Propargylic Radical Cyanation Enabled by Dual Organophotoredox and Copper Catalysis128
Covalent Design for Dye-Sensitized H2-Evolving Photocathodes Based on a Cobalt Diimine–Dioxime Catalyst127
A Redox Strategy for Light-Driven, Out-of-Equilibrium Isomerizations and Application to Catalytic C–C Bond Cleavage Reactions127
Robust, Highly Luminescent Au13 Superatoms Protected by N-Heterocyclic Carbenes127
Pyrazine-Flanked Diketopyrrolopyrrole (DPP): A New Polymer Building Block for High-Performance n-Type Organic Thermoelectrics127
Fluorine Substitution Induced High Tc of Enantiomeric Perovskite Ferroelectrics: (R)- and (S)-3-(Fluoropyrrolidinium)MnCl3127
High Efficiency Mesoscopic Solar Cells Using CsPbI3 Perovskite Quantum Dots Enabled by Chemical Interface Engineering127
A Single-Crystal Open-Capsule Metal–Organic Framework126
Micrometer-Sized Water Droplets Induce Spontaneous Reduction126
4-Hydroxyproline-Derived Sustainable Polythioesters: Controlled Ring-Opening Polymerization, Complete Recyclability, and Facile Functionalization126
New Mechanism for N2 Reduction: The Essential Role of Surface Hydrogenation126
Molecular Design Strategy to Construct the Near-Infrared Fluorescent Probe for Selectively Sensing Human Cytochrome P450 2J2126
Vinylene-Bridged Two-Dimensional Covalent Organic Frameworks via Knoevenagel Condensation of Tricyanomesitylene125
Functionalized Acrylonitriles with Aggregation-Induced Emission: Structure Tuning by Simple Reaction-Condition Variation, Efficient Red Emission, and Two-Photon Bioimaging125
Site-Selective Catalytic Deaminative Alkylation of Unactivated Olefins125
Anion Transport with Pnictogen Bonds in Direct Comparison with Chalcogen and Halogen Bonds125
Mechanosensitive Fluorescent Probes to Image Membrane Tension in Mitochondria, Endoplasmic Reticulum, and Lysosomes125
Continuous Partial Oxidation of Methane to Methanol Catalyzed by Diffusion-Paired Copper Dimers in Copper-Exchanged Zeolites125
Rhodium-Catalyzed Atroposelective C–H Arylation: Efficient Synthesis of Axially Chiral Heterobiaryls125
Molecular Self-Assembly of Bioorthogonal Aptamer-Prodrug Conjugate Micelles for Hydrogen Peroxide and pH-Independent Cancer Chemodynamic Therapy125
Ir-Catalyzed Intermolecular Branch-Selective Allylic C–H Amidation of Unactivated Terminal Olefins124
Uniformity Is Key in Defining Structure–Function Relationships for Atomically Dispersed Metal Catalysts: The Case of Pt/CeO2124
n-Pentenyl glycosides permit the chemospecific liberation of the anomeric center123
Chiral Cyclopentadienyl Cobalt(III) Complexes Enable Highly Enantioselective 3d-Metal-Catalyzed C–H Functionalizations123
New Bisoxazoline Ligands Enable Enantioselective Electrocatalytic Cyanofunctionalization of Vinylarenes123
Light-Induced Protein Degradation with Photocaged PROTACs123
Enhancing the Performance of a Fused-Ring Electron Acceptor by Unidirectional Extension123
Monoammonium Porphyrin for Blade-Coating Stable Large-Area Perovskite Solar Cells with >18% Efficiency123
A Robust Squarate-Based Metal–Organic Framework Demonstrates Record-High Affinity and Selectivity for Xenon over Krypton123
Cu/Chiral Phosphoric Acid-Catalyzed Asymmetric Three-Component Radical-Initiated 1,2-Dicarbofunctionalization of Alkenes123
Aggregation-Induced Emission and Light-Harvesting Function of Tetraphenylethene-Based Tetracationic Dicyclophane122
Nanochannels of Covalent Organic Frameworks for Chiral Selective Transmembrane Transport of Amino Acids122
Crystalline Liquid-like Behavior: Surface-Induced Secondary Grain Growth of Photovoltaic Perovskite Thin Film122
Synthesis of Enantioenriched Allylic Silanes via Nickel-Catalyzed Reductive Cross-Coupling121
Metformin-Induced Stromal Depletion to Enhance the Penetration of Gemcitabine-Loaded Magnetic Nanoparticles for Pancreatic Cancer Targeted Therapy121
Enhanced Gas Uptake in a Microporous Metal–Organic Framework via a Sorbate Induced-Fit Mechanism121
Porphyrinic Silver Cluster Assembled Material for Simultaneous Capture and Photocatalysis of Mustard-Gas Simulant121
In Vivo Albumin Traps Photosensitizer Monomers from Self-Assembled Phthalocyanine Nanovesicles: A Facile and Switchable Theranostic Approach121
Three-Component Olefin Dicarbofunctionalization Enabled by Nickel/Photoredox Dual Catalysis120
Ligand Rigidification for Enhancing the Stability of Metal–Organic Frameworks120
Block Copolymer Vitrimers120
Two-Dimensional Layered Perovskite Ferroelectric with Giant Piezoelectric Voltage Coefficient120
Direct Silyl Ether Metathesis for Vitrimers with Exceptional Thermal Stability119
Synthesis of Self-Healing Polymers by Scandium-Catalyzed Copolymerization of Ethylene and Anisylpropylenes119
Self-Assembled Fluorescent Pt(II) Metallacycles as Artificial Light-Harvesting Systems119
A Highly Luminescent Chiral Tetrahedral Eu4L4(L′)4 Cage: Chirality Induction, Chirality Memory, and Circularly Polarized Luminescence119
Oxygen-Dependent Regulation of Excited-State Deactivation Process of Rational Photosensitizer for Smart Phototherapy119
All Wrapped up: Stabilization of Enzymes within Single Enzyme Nanoparticles118
Selective C–F Functionalization of Unactivated Trifluoromethylarenes118
Sulfonamide Synthesis through Electrochemical Oxidative Coupling of Amines and Thiols118
Nanopore-Based Single-Biomolecule Interfaces: From Information to Knowledge118
CuH-Catalyzed Enantioselective Ketone Allylation with 1,3-Dienes: Scope, Mechanism, and Applications118
Atomically Dispersed Pt1–Polyoxometalate Catalysts: How Does Metal–Support Interaction Affect Stability and Hydrogenation Activity?118
An Unprecedented Biaxial Trilayered Hybrid Perovskite Ferroelectric with Directionally Tunable Photovoltaic Effects118
Covalent Self-Assembly in Two Dimensions: Connecting Covalent Organic Framework Nanospheres into Crystalline and Porous Thin Films118
trans-Hydrogenation, gem-Hydrogenation, and trans-Hydrometalation of Alkynes: An Interim Report on an Unorthodox Reactivity Paradigm118
(4+1) vs (4+2): Catalytic Intramolecular Coupling between Cyclobutanones and Trisubstituted Allenes via C–C Activation116
Breaking the Base Barrier: An Electron-Deficient Palladium Catalyst Enables the Use of a Common Soluble Base in C–N Coupling116
Ferromagnetic van der Waals Crystal VI3116
Ultrathin Pd–Au Shells with Controllable Alloying Degree on Pd Nanocubes toward Carbon Dioxide Reduction116
Three-Dimensional Tetrathiafulvalene-Based Covalent Organic Frameworks for Tunable Electrical Conductivity116
Copper-Catalyzed Radical 1,4-Difunctionalization of 1,3-Enynes with Alkyl Diacyl Peroxides and N-Fluorobenzenesulfonimide116
Fine-Tuning Semiconducting Polymer Self-Aggregation and Crystallinity Enables Optimal Morphology and High-Performance Printed All-Polymer Solar Cells116
Kinetically Stable Single Crystals of Perovskite-Phase CsPbI3115
Zn-Mediated Fragmentation of Tertiary Alkyl Oxalates Enabling Formation of Alkylated and Arylated Quaternary Carbon Centers115
Internal Catalysis in Covalent Adaptable Networks: Phthalate Monoester Transesterification As a Versatile Dynamic Cross-Linking Chemistry114
Metallophilicity-Driven Dynamic Aggregation of a Phosphorescent Gold(I)–Silver(I) Cluster Prepared by Solution-Based and Mechanochemical Approaches114
Evolving Fluorophores into Circularly Polarized Luminophores with a Chiral Naphthalene Tetramer: Proposal of Excimer Chirality Rule for Circularly Polarized Luminescence114
Harnessing Alkylpyridinium Salts as Electrophiles in Deaminative Alkyl–Alkyl Cross-Couplings114
Iridium-Catalyzed Enantioselective C(sp3)–H Amidation Controlled by Attractive Noncovalent Interactions114
Direct-Bandgap 2D Silver–Bismuth Iodide Double Perovskite: The Structure-Directing Influence of an Oligothiophene Spacer Cation114
Ultrafast Spectroscopy: State of the Art and Open Challenges114
Extending the Lifetime of Organic Flow Batteries via Redox State Management114
Electronegativity Seen as the Ground-State Average Valence Electron Binding Energy114
Lithium Deficiencies Engineering in Li-Rich Layered Oxide Li1.098Mn0.533Ni0.113Co0.138O2 for High-Stability Cathode114
Realizing High Thermoelectric Performance in p-Type SnSe through Crystal Structure Modification114
Glycocalyx Remodeling with Proteoglycan Mimetics Promotes Neural Specification in Embryonic Stem Cells113
Constructing Robust Covalent Organic Frameworks via Multicomponent Reactions113
van der Waals Stacking Induced Transition from Schottky to Ohmic Contacts: 2D Metals on Multilayer InSe113
Synthesis and Characterization of π-Extended Triangulene113
Hydrolyzable Polyureas Bearing Hindered Urea Bonds112
Enantioselective Total Synthesis of (+)-Psiguadial B112
UV-Induced Proton Transfer between DNA Strands112
How To Maximize Birefringence and Nonlinearity of π-Conjugated Cyanurates112
Two-Dimensional Organic–Inorganic Perovskite Ferroelectric Semiconductors with Fluorinated Aromatic Spacers112
Two-Dimensional PC6 with Direct Band Gap and Anisotropic Carrier Mobility112
Metal–Organic Framework Containing Planar Metal-Binding Sites: Efficiently and Cost-Effectively Enhancing the Kinetic Separation of C2H2/C2H4112
[Ag48(C≡CtBu)20(CrO4)7]: An Atomically Precise Silver Nanocluster Co-protected by Inorganic and Organic Ligands112
Redox-Neutral α-Oxygenation of Amines: Reaction Development and Elucidation of the Mechanism111
Shape-Persistent Actuators from Hydrazone Photoswitches111
Targeting RNA with Small Molecules To Capture Opportunities at the Intersection of Chemistry, Biology, and Medicine111
Reticular Access to Highly Porous acs-MOFs with Rigid Trigonal Prismatic Linkers for Water Sorption111
Sulfonyl Fluoride Synthesis through Electrochemical Oxidative Coupling of Thiols and Potassium Fluoride111
“Dual-Key-and-Lock” Ruthenium Complex Probe for Lysosomal Formaldehyde in Cancer Cells and Tumors111
A Radical Approach to Anionic Chemistry: Synthesis of Ketones, Alcohols, and Amines111
Toward Long-Term Stability: Single-Crystal Alloys of Cesium-Containing Mixed Cation and Mixed Halide Perovskite111
Impact of Oxygen Vacancy Occupancy on Charge Carrier Dynamics in BiVO4 Photoanodes111
Significant Improvement of Unipolar n-Type Transistor Performances by Manipulating the Coplanar Backbone Conformation of Electron-Deficient Polymers via Hydrogen Bonding110
Endogenous Reactive Oxygen Species-Triggered Morphology Transformation for Enhanced Cooperative Interaction with Mitochondria110
Nickel-catalyzed Enantioselective Hydroarylation and Hydroalkenylation of Styrenes110
Creating Well-Defined Hexabenzocoronene in Zirconium Metal–Organic Framework by Postsynthetic Annulation110
Ultrathin Conductor Enabling Efficient IR Light CO2 Reduction110
Electrochemical Dearomative 2,3-Difunctionalization of Indoles109
Insight into the Complexity of the i-Motif and G-Quadruplex DNA Structures Formed in the KRAS Promoter and Subsequent Drug-Induced Gene Repression109
Direct In Situ Raman Spectroscopic Evidence of Oxygen Reduction Reaction Intermediates at High-Index Pt(hkl) Surfaces109
Shape Amphiphiles:  Mixing Rods and Disks in Liquid Crystals108
Fusing of Seven HBCs toward a Green Nanographene Propeller108
Stereodivergent Construction of Tertiary Fluorides in Vicinal Stereogenic Pairs by Allylic Substitution with Iridium and Copper Catalysts108
Poly(oxime–ester) Vitrimers with Catalyst-Free Bond Exchange108
Mechanistic Interplay between Light Switching and Guest Binding in Photochromic [Pd2Dithienylethene4] Coordination Cages108
Imidazole-Linked Crystalline Two-Dimensional Polymer with Ultrahigh Proton-Conductivity108
Regio- and Enantioselective C–H Cyclization of Pyridines with Alkenes Enabled by a Nickel/N-Heterocyclic Carbene Catalysis108
Palladium/XuPhos-Catalyzed Enantioselective Carboiodination of Olefin-Tethered Aryl Iodides108
Metal Oxide/(oxy)hydroxide Overlayers as Hole Collectors and Oxygen-Evolution Catalysts on Water-Splitting Photoanodes108
Automated Glycan Assembly: A Perspective107
Elastic Frustration Causing Two-Step and Multistep Transitions in Spin-Crossover Solids: Emergence of Complex Antiferroelastic Structures107
A Mono-cuboctahedral Series of Gold Nanoclusters: Photoluminescence Origin, Large Enhancement, Wide Tunability, and Structure–Property Correlation107
Nanoribbons with Nonalternant Topology from Fusion of Polyazulene: Carbon Allotropes beyond Graphene107
Revealing Energetics of Surface Oxygen Redox from Kinetic Fingerprint in Oxygen Electrocatalysis107
Scalable and Template-Free Aqueous Synthesis of Zirconium-Based Metal–Organic Framework Coating on Textile Fiber107
Light-Controlled Generation of Singlet Oxygen within a Discrete Dual-Stage Metallacycle for Cancer Therapy106
Squeezing All Elements in the Periodic Table: Electron Configuration and Electronegativity of the Atoms under Compression106
Helicene Quinones: Redox-Triggered Chiroptical Switching and Chiral Recognition of the Semiquinone Radical Anion Lithium Salt by Electron Nuclear Double Resonance Spectroscopy106
Interplay between Short-Range Attraction and Long-Range Repulsion Controls Reentrant Liquid Condensation of Ribonucleoprotein–RNA Complexes106
Keteniminium Ion-Initiated Cascade Cationic Polycyclization105
Two-Step Design of a Single-Doped White Phosphor with High Color Rendering105
C–N Cross-Couplings for Site-Selective Late-Stage Diversification via Aryl Sulfonium Salts105
Quaternary Piperazine-Substituted Rhodamines with Enhanced Brightness for Super-Resolution Imaging105
Self-Assembled Responsive Bilayered Vesicles with Adjustable Oxidative Stress for Enhanced Cancer Imaging and Therapy105
Molecular Magnetic Resonance Imaging with Gd(III)-Based Contrast Agents: Challenges and Key Advances104
Chiral Molecular Ruby [Cr(dqp)2]3+ with Long-Lived Circularly Polarized Luminescence104
Topology Exploration in Highly Connected Rare-Earth Metal–Organic Frameworks via Continuous Hindrance Control104
Pocketlike Active Site of Rh1/MoS2 Single-Atom Catalyst for Selective Crotonaldehyde Hydrogenation104
Amino Analogs of Firefly Luciferin and Biological Activity Thereof1104
Pb2GaF2(SeO3)2Cl: Band Engineering Strategy by Aliovalent Substitution for Enlarging Bandgap while Keeping Strong Second Harmonic Generation Response104
Quadruplex Turncoats: Cation-Dependent Folding and Stability of Quadruplex-DNA Double Switches103
A Highly Efficient Catalyst for Selective Oxidative Scission of Olefins to Aldehydes: Abnormal-NHC–Ru(II) Complex in Oxidation Chemistry103
Multimetallic Cooperativity in Uranium-Mediated CO2 Activation103
Realization of High Thermoelectric Figure of Merit in Solution Synthesized 2D SnSe Nanoplates via Ge Alloying103
Assembly of Atomically Precise Silver Nanoclusters into Nanocluster-Based Frameworks103
LiCl-Accelerated Multimetallic Cross-Coupling of Aryl Chlorides with Aryl Triflates103
Boosting Enantioselectivity of Chiral Organocatalysts with Ultrathin Two-Dimensional Metal–Organic Framework Nanosheets103
Quantitatively Visualizing Tumor-Related Protease Activity in Vivo Using a Ratiometric Photoacoustic Probe103
Probing the Transformation of Boron Nitride Catalysts under Oxidative Dehydrogenation Conditions103
Coordination-Driven Self-Assembled Metallacycles Incorporating Pyrene: Fluorescence Mutability, Tunability, and Aromatic Amine Sensing102
Amyloid β-Protein Assembly and Alzheimer’s Disease: Dodecamers of Aβ42, but Not of Aβ40, Seed Fibril Formation102
C–H Activation/Functionalization Catalyzed by Simple, Well-Defined Low-Valent Cobalt Complexes102
Chalcogen–Chalcogen Bonding Catalysis Enables Assembly of Discrete Molecules102
Direct 12-Electron Oxidation of Ethanol on a Ternary Au(core)-PtIr(Shell) Electrocatalyst102
Pd(II) Coordination Sphere Engineering: Pyridine Cages, Quinoline Bowls, and Heteroleptic Pills Binding One or Two Fullerenes102
Enhanced Photoelectrochemical Performance of Cuprous Oxide/Graphene Nanohybrids101
meta-Selective C–H Borylation of Benzamides and Pyridines by an Iridium–Lewis Acid Bifunctional Catalyst101
Mechanistic Insights into Ruthenium-Pincer-Catalyzed Amine-Assisted Homogeneous Hydrogenation of CO2 to Methanol101
Chemical and Structural Diversity of Hybrid Layered Double Perovskite Halides101
Chiral Core–Shell Upconversion Nanoparticle@MOF Nanoassemblies for Quantification and Bioimaging of Reactive Oxygen Species in Vivo101
Oriented Two-Dimensional Covalent Organic Framework Films for Near-Infrared Electrochromic Application101
Plastic/Ferroelectric Crystals with Easily Switchable Polarization: Low-Voltage Operation, Unprecedentedly High Pyroelectric Performance, and Large Piezoelectric Effect in Polycrystalline Forms101
Cell-Membrane-Anchored DNA Nanoplatform for Programming Cellular Interactions100
Hydroalkylation of Olefins To Form Quaternary Carbons100
Long-Range Electron Transfer Triggers Mechanistic Differences between Iron(IV)-Oxo and Iron(IV)-Imido Oxidants100
Unprecedented High Oxygen Evolution Activity of Electrocatalysts Derived from Surface-Mounted Metal–Organic Frameworks100
Enantioselective [2+2] Cycloadditions of Cinnamate Esters: Generalizing Lewis Acid Catalysis of Triplet Energy Transfer100
Operando Insight into the Correlation between the Structure and Composition of CuZn Nanoparticles and Their Selectivity for the Electrochemical CO2 Reduction100
Organic Cation Rotation and Immobilization in Pure and Mixed Methylammonium Lead-Halide Perovskites100
Engineering of Bioinspired, Size-Controllable, Self-Degradable Cancer-Targeting DNA Nanoflowers via the Incorporation of an Artificial Sandwich Base100
Highly Selective Artificial K+ Channels: An Example of Selectivity-Induced Transmembrane Potential99
Cobalt-Based Nitride-Core Oxide-Shell Oxygen Reduction Electrocatalysts99
Bi(I)-Catalyzed Transfer-Hydrogenation with Ammonia-Borane99
Flow Rhodaelectro-Catalyzed Alkyne Annulations by Versatile C–H Activation: Mechanistic Support for Rhodium(III/IV)99
Asymmetric Counter-Anion-Directed Aminomethylation: Synthesis of Chiral β-Amino Acids via Trapping of an Enol Intermediate99
Highly Stable Zr(IV)-Based Metal–Organic Frameworks with Chiral Phosphoric Acids for Catalytic Asymmetric Tandem Reactions99
Pd(II)-Catalyzed Enantioselective Alkynylation of Unbiased Methylene C(sp3)–H Bonds Using 3,3′-Fluorinated-BINOL as a Chiral Ligand99
Cooperative Effects between Hydrophilic Pores and Solvents: Catalytic Consequences of Hydrogen Bonding on Alkene Epoxidation in Zeolites99
Exciton Self-Trapping in Hybrid Lead Halides: Role of Halogen98
Force-Dependent Multicolor Mechanochromism from a Single Mechanophore98
Rational Design of Topographical Helix Mimics as Potent Inhibitors of Protein–Protein Interactions98
Electrocatalytic Hydrogen Evolution from a Cobaloxime-Based Metal–Organic Framework Thin Film98
Nitric Oxide-Activated “Dual-Key–One-Lock” Nanoprobe for in Vivo Molecular Imaging and High-Specificity Cancer Therapy98
Electrochemistry-Enabled Ir-Catalyzed Vinylic C–H Functionalization98
A Simple Molecular Design Strategy for Delayed Fluorescence toward 1000 nm98
Corannurylene Pentapetalae98
Amino Acid-Assisted Construction of Single-Crystalline Hierarchical Nanozeolites via Oriented-Aggregation and Intraparticle Ripening98
Direct Identification of Active Surface Species for the Water–Gas Shift Reaction on a Gold–Ceria Catalyst98
Nucleation and Growth Mechanism of Lithium Metal Electroplating98
Hydrogenation of CO2 to Methanol by Pt Nanoparticles Encapsulated in UiO-67: Deciphering the Role of the Metal–Organic Framework98
Catalyst-Free Synthesis of Borylated Lactones from Esters via Electrophilic Oxyboration97
Strongly Lewis Acidic Metal–Organic Frameworks for Continuous Flow Catalysis97
Future of Supramolecular Copolymers Unveiled by Reflecting on Covalent Copolymerization97
Switching on and off Interlayer Correlations and Porosity in 2D Covalent Organic Frameworks97
Expanding Reactivity in DNA-Encoded Library Synthesis via Reversible Binding of DNA to an Inert Quaternary Ammonium Support97
Thiol–Chromene “Click” Reaction Triggered Self-Immolative for NIR Visualization of Thiol Flux in Physiology and Pathology of Living Cells and Mice97
Shortwave Infrared Imaging with J-Aggregates Stabilized in Hollow Mesoporous Silica Nanoparticles96
A Twice-As-Smart Synthetic G-Quartet: PyroTASQ Is Both a Smart Quadruplex Ligand and a Smart Fluorescent Probe96
Dehydroxymethylation of Alcohols Enabled by Cerium Photocatalysis96
Oligosaccharide Synthesis and Translational Innovation96
Aminoxyl-Catalyzed Electrochemical Diazidation of Alkenes Mediated by a Metastable Charge-Transfer Complex96
Three Models To Encapsulate Multicomponent Dyes into Nanocrystal Pores: A New Strategy for Generating High-Quality White Light96
Histidine-Specific Peptide Modification via Visible-Light-Promoted C–H Alkylation96
Asymmetric Induction and Enantiodivergence in Catalytic Radical C–H Amination via Enantiodifferentiative H-Atom Abstraction and Stereoretentive Radical Substitution96
Investigation of Oxygen Passivation for High-Performance All-Inorganic Perovskite Solar Cells96
Pressure-Induced Emission (PIE) of One-Dimensional Organic Tin Bromide Perovskites96
Cascade Reactions in Nanozymes: Spatially Separated Active Sites inside Ag-Core–Porous-Cu-Shell Nanoparticles for Multistep Carbon Dioxide Reduction to Higher Organic Molecules96
General Mild Reaction Creates Highly Luminescent Organic-Ligand-Lacking Halide Perovskite Nanocrystals for Efficient Light-Emitting Diodes96
Alkoxyboration: Ring-Closing Addition of B–O σ Bonds across Alkynes95
Mechanistic Investigation of Enantioconvergent Kumada Reactions of Racemic α-Bromoketones Catalyzed by a Nickel/Bis(oxazoline) Complex95
High Li+ and Mg2+ Conductivity in a Cu-Azolate Metal–Organic Framework95
Gold-Nanoshell-Functionalized Polymer Nanoswimmer for Photomechanical Poration of Single-Cell Membrane95
Disparate Catalytic Scaffolds for Atroposelective Cyclodehydration95
Ru-bda: Unique Molecular Water-Oxidation Catalysts with Distortion Induced Open Site and Negatively Charged Ligands95
Synergetic Organocatalysis for Eliminating Epimerization in Ring-Opening Polymerizations Enables Synthesis of Stereoregular Isotactic Polyester95
Structural Insights into Thioether Bond Formation in the Biosynthesis of Sactipeptides94
A Phosphole Oxide-Containing Organogold(III) Complex for Solution-Processable Resistive Memory Devices with Ternary Memory Performances94
Ultrafast Delivery of Aggregation-Induced Emission Nanoparticles and Pure Organic Phosphorescent Nanocrystals by Saponin Encapsulation94
Geminiarene: Molecular Scale Dual Selectivity for Chlorobenzene and Chlorocyclohexane Fractionation94
Metal Doping of Au25(SR)18 Clusters: Insights and Hindsights94
Vanadium Catalyst on Isostructural Transition Metal, Lanthanide, and Actinide Based Metal–Organic Frameworks for Alcohol Oxidation94
Impact of Antifouling PEG Layer on the Performance of Functional Peptides in Regulating Cell Behaviors94
Azulene-Derived Fluorescent Probe for Bioimaging: Detection of Reactive Oxygen and Nitrogen Species by Two-Photon Microscopy94
Oxalic Diamides and tert-Butoxide: Two Types of Ligands Enabling Practical Access to Alkyl Aryl Ethers via Cu-Catalyzed Coupling Reaction93
Lowering Charge Transfer Barrier of LiMn2O4 via Nickel Surface Doping To Enhance Li+ Intercalation Kinetics at Subzero Temperatures93
Lemniscular [16]Cycloparaphenylene: A Radially Conjugated Figure-Eight Aromatic Molecule93
Stable Ultraconcentrated and Ultradilute Colloids of CsPbX3 (X = Cl, Br) Nanocrystals Using Natural Lecithin as a Capping Ligand93
Ionic and Electronic Conduction in TiNb2O793
Early Stages of Electrochemical Oxidation of Cu(111) and Polycrystalline Cu Surfaces Revealed by in Situ Raman Spectroscopy93
Tuning the Intermolecular Electron Transfer of Low-Dimensional and Metal-Free BCN/C60 Electrocatalysts via Interfacial Defects for Efficient Hydrogen and Oxygen Electrochemistry93
Kinetics of Photoelectrochemical Oxidation of Methanol on Hematite Photoanodes93
Mechanistic Characterization of (Xantphos)Ni(I)-Mediated Alkyl Bromide Activation: Oxidative Addition, Electron Transfer, or Halogen-Atom Abstraction93
Metal Substitution as the Method of Modifying Electronic Structure of Metal–Organic Frameworks93
A Highly Efficient Silole-Containing Dithienylethene with Excellent Thermal Stability and Fatigue Resistance: A Promising Candidate for Optical Memory Storage Materials92
Conduction and Reactivity in Heterogeneous-Molecular Catalysis: New Insights in Water Oxidation Catalysis by Phosphate Cobalt Oxide Films92
Unexpected Hydrated Electron Source for Preparative Visible-Light Driven Photoredox Catalysis92
Electrocatalysis at Organic–Metal Interfaces: Identification of Structure–Reactivity Relationships for CO2 Reduction at Modified Cu Surfaces92
Nature of Oxygen-Containing Groups on Carbon for High-Efficiency Electrocatalytic CO2 Reduction Reaction92
Two-Step Carbothermal Welding To Access Atomically Dispersed Pd1 on Three-Dimensional Zirconia Nanonet for Direct Indole Synthesis92
Circularly Polarized Luminescence from Achiral Single Crystals of Hybrid Manganese Halides92
Facile Synthesis of Stable and Highly Luminescent Methylammonium Lead Halide Nanocrystals for Efficient Light Emitting Devices92
Polymeric, Cost-Effective, Dopant-Free Hole Transport Materials for Efficient and Stable Perovskite Solar Cells92
Schottky Barrier Induced Coupled Interface of Electron-Rich N-Doped Carbon and Electron-Deficient Cu: In-Built Lewis Acid–Base Pairs for Highly Efficient CO2 Fixation92
Molecular Recognition with Resorcin[4]arene Cavitands: Switching, Halogen-Bonded Capsules, and Enantioselective Complexation91
Designing Solid Materials from Their Solute State: A Shift in Paradigms toward a Holistic Approach in Functional Materials Chemistry91
Probing Size and Substrate Effects on the Hydrogen Evolution Reaction by Single Isolated Pt Atoms, Atomic Clusters, and Nanoparticles91
Reduction of Carbon Dioxide by a Molybdenum-Containing Formate Dehydrogenase: A Kinetic and Mechanistic Study91
Energy Transfer to Ni-Amine Complexes in Dual Catalytic, Light-Driven C–N Cross-Coupling Reactions91
Reactive Matrix-Assisted Laser Desorption/Ionization Mass Spectrometry Imaging Using an Intrinsically Photoreactive Paternò–Büchi Matrix for Double-Bond Localization in Isomeric Phospholipids91
From {AuI···AuI}-Coupled Cages to the Cage-Built 2-D {AuI···AuI} Arrays: AuI···AuI Bonding Interaction Driven Self-Assembly and Their 91
Self-Healing Hyper-Cross-Linked Metal–Organic Polyhedra (HCMOPs) Membranes with Antimicrobial Activity and Highly Selective Separation Properties91
Enantioselective Intermolecular Excited-State Photoreactions Using a Chiral Ir Triplet Sensitizer: Separating Association from Energy Transfer in Asymmetric Photocatalysis91
Elucidation of a Redox-Mediated Reaction Cycle for Nickel-Catalyzed Cross Coupling91
Mesoporous Cages in Chemically Robust MOFs Created by a Large Number of Vertices with Reduced Connectivity91
Electro-Oxidative C–C Alkenylation by Rhodium(III) Catalysis90
Enabling Förster Resonance Energy Transfer from Large Nanocrystals through Energy Migration90
Electrochemical CO Reduction: A Property of the Electrochemical Interface90
Mechanically Triggered Small Molecule Release from a Masked Furfuryl Carbonate90
Meltable Mixed-Linker Zeolitic Imidazolate Frameworks and Their Microporous Glasses: From Melting Point Engineering to Selective Hydrocarbon Sorption90
Ruthenium(II)-Catalyzed Enantioselective γ-Lactams Formation by Intramolecular C–H Amidation of 1,4,2-Dioxazol-5-ones90
Bis-Monophospholyl Dysprosium Cation Showing Magnetic Hysteresis at 48 K90
Controlled Assembly Synthesis of Atomically Precise Ultrastable Silver Nanoclusters with Polyoxometalates90
Genesis and Stability of Hydronium Ions in Zeolite Channels90
Perspective of Chiral Colloidal Semiconductor Nanocrystals: Opportunity and Challenge90
Multivariate Metal–Organic Frameworks for the Simultaneous Capture of Organic and Inorganic Contaminants from Water90
Unraveling the Reaction Mechanisms of SiO Anodes for Li-Ion Batteries by Combining in Situ 7Li and ex Situ 7Li/29Si Solid-State NMR Spectroscopy90
Selective Methane Oxidation to Methanol on Cu-Oxo Dimers Stabilized by Zirconia Nodes of an NU-1000 Metal–Organic Framework90
Core–Shell Gold Nanorod@Zirconium-Based Metal–Organic Framework Composites as in Situ Size-Selective Raman Probes90
Stabilizing Highly Active Ru Sites by Suppressing Lattice Oxygen Participation in Acidic Water Oxidation90
Tip-Enhanced Raman Imaging of Single-Stranded DNA with Single Base Resolution90
Architecture-Controlled Ring-Opening Polymerization for Dynamic Covalent Poly(disulfide)s89
Cell-Penetrating, Guanidinium-Rich Oligophosphoesters: Effective and Versatile Molecular Transporters for Drug and Probe Delivery89
Catalytic Hydrothiolation: Counterion-Controlled Regioselectivity89
Unraveling the Impact of Halide Mixing on Perovskite Stability89
DNA Framework-Programmed Cell Capture via Topology-Engineered Receptor–Ligand Interactions89
A Latent Mechanoacid for Time-Stamped Mechanochromism and Chemical Signaling in Polymeric Materials89
Atomic-Level Nanorings (A-NRs) Therapeutic Agent for Photoacoustic Imaging and Photothermal/Photodynamic Therapy of Cancer89
Chemical Requirement for Extracting Energetic Charge Carriers from Plasmonic Metal Nanoparticles to Perform Electron-Transfer Reactions89
Core–Shell ZnO@SnO2 Nanoparticles for Efficient Inorganic Perovskite Solar Cells89
Intermediate Binding Control Using Metal–Organic Frameworks Enhances Electrochemical CO2Reduction88
Transformable Nanostructures of Platinum-Containing Organosilane Hybrids: Non-covalent Self-Assembly of Polyhedral Oligomeric Silsesquioxanes Assisted by Pt···Pt and π–π Stacking Interactions of Alkyn88
Pathway Dependence in the Fuel-Driven Dissipative Self-Assembly of Nanoparticles88
Synergistic Effects of Imidazolium-Functionalization on fac-Mn(CO)3 Bipyridine Catalyst Platforms for Electrocatalytic Carbon Dioxide Reduction88
Hydrocarbon Synthesis via Photoenzymatic Decarboxylation of Carboxylic Acids88
The Crystal Structure of Rhombohedral Acetamide88
In Situ X-ray Absorption Spectroscopy of a Synergistic Co–Mn Oxide Catalyst for the Oxygen Reduction Reaction88
From One to Two: In Situ Construction of an Ultrathin 2D-2D Closely Bonded Heterojunction from a Single-Phase Monolayer Nanosheet88
Plasmonic p–n Junction for Infrared Light to Chemical Energy Conversion88
Forging C(sp3)–C(sp3) Bonds with Carbon-Centered Radicals in the Synthesis of Complex Molecules88
Equivalent Circuits of a Self-Assembled Monolayer-Based Tunnel Junction Determined by Impedance Spectroscopy87
Mechanism of Iron Oxide-Induced Macrophage Activation: The Impact of Composition and the Underlying Signaling Pathway87
CuH-Catalyzed Enantioselective Alkylation of Indole Derivatives with Ligand-Controlled Regiodivergence87
Direct Growth of Highly Strained Pt Islands on Branched Ni Nanoparticles for Improved Hydrogen Evolution Reaction Activity87
π-Extended Pyrene-Fused Double [7]Carbohelicene as a Chiral Polycyclic Aromatic Hydrocarbon87
Cooperative Stabilization of the [Pyridinium-CO2-Co] Adduct on a Metal–Organic Layer Enhances Electrocatalytic CO2 Reduction87
Superoxide/Peroxide Chemistry Extends Charge Carriers’ Lifetime but Undermines Chemical Stability of CH3NH3PbI3 Exposed to Oxygen: Time-Domain ab Initio Analysi87
Nickel-Catalyzed Enantioconvergent Reductive Hydroalkylation of Olefins with α-Heteroatom Phosphorus or Sulfur Alkyl Electrophiles87
Photoreduction of CO2 with a Formate Dehydrogenase Driven by Photosystem II Using a Semi-artificial Z-Scheme Architecture86
Air-Persistent Monomeric (Amino)(carboxy) Radicals Derived from Cyclic (Alkyl)(Amino) Carbenes86
Carboxylation of Benzylic and Aliphatic C–H Bonds with CO2 Induced by Light/Ketone/Nickel86
Boosting Electrocatalytic Hydrogen Evolution Activity with a NiPt3@NiS Heteronanostructure Evolved from a Molecular Nickel–Platinum Precursor86
Metal–Organic Framework Photocatalyst Incorporating Bis(4′-(4-carboxyphenyl)-terpyridine)ruthenium(II) for Visible-Light-Driven Carbon Dioxide Reduction86
Para-Selective C–H Borylation of Common Arene Building Blocks Enabled by Ion-Pairing with a Bulky Countercation86
Enantioselective Construction of Quaternary All-Carbon Centers via Copper-Catalyzed Arylation of Tertiary Carbon-Centered Radicals86
Bioinformatic Mapping of Radical S-Adenosylmethionine-Dependent Ribosomally Synthesized and Post-Translationally Modified Peptides Identifies New Cα, Cβ, and Cγ-Linked Thioether-Containing Pept86
Stereodivergent Protein Engineering of a Lipase To Access All Possible Stereoisomers of Chiral Esters with Two Stereocenters86
Structure of Chemisorbed CO2 Species in Amine-Functionalized Mesoporous Silicas Studied by Solid-State NMR and Computer Modeling86
Untangling the Condensation Network of Organosiloxanes on Nanoparticles using 2D 29Si–29Si Solid-State NMR Enhanced by Dynamic Nuclear Polarization85
Control on Dimensions and Supramolecular Chirality of Self-Assemblies through Light and Metal Ions85
Polyoxometalate–Cyclodextrin Metal–Organic Frameworks: From Tunable Structure to Customized Storage Functionality85
Bimodal Fluorescence-Magnetic Resonance Contrast Agent for Apoptosis Imaging85
Alkyl Chain Length-Selective Vapor-Induced Fluorochromism of Pillar[5]arene-Based Nonporous Adaptive Crystals85
para-Selective C–H Olefination of Aniline Derivatives via Pd/S,O-Ligand Catalysis85
Chiroptical Activity Enhancement via Structural Control: The Chiral Synthesis and Reversible Interconversion of Two Intrinsically Chiral Gold Nanoclusters85
Iron Catalyzed Highly Enantioselective Epoxidation of Cyclic Aliphatic Enones with Aqueous H2O285
Asymmetric δ-Lactam Synthesis with a Monomeric Streptavidin Artificial Metalloenzyme85
The Myth of d8 Copper(III)85
Unassisted Photoelectrochemical Cell with Multimediator Modulation for Solar Water Splitting Exceeding 4% Solar-to-Hydrogen Efficiency85
Interfacial sp C–O–Mo Hybridization Originated High-Current Density Hydrogen Evolution85
Aminoboration: Addition of B–N σ Bonds across C–C π Bonds84
On the Remarkable Role of Surface Topography of the Bottom Electrodes in Blocking Leakage Currents in Molecular Diodes84
α-Synuclein-Induced Membrane Remodeling Is Driven by Binding Affinity, Partition Depth, and Interleaflet Order Asymmetry84
Strain-Release-Driven Homologation of Boronic Esters: Application to the Modular Synthesis of Azetidines84
Green-Light-Triggered Phase Transition of Azobenzene Derivatives toward Reversible Adhesives84
Three-Component Ruthenium-Catalyzed Direct Meta-Selective C–H Activation of Arenes: A New Approach to the Alkylarylation of Alkenes84
Precision Cancer Theranostic Platform by In Situ Polymerization in Perylene Diimide-Hybridized Hollow Mesoporous Organosilica Nanoparticles84
Diastereo- and Atroposelective Synthesis of Bridged Biaryls Bearing an Eight-Membered Lactone through an Organocatalytic Cascade84
Modulating Lattice Oxygen in Dual-Functional Mo–V–O Mixed Oxides for Chemical Looping Oxidative Dehydrogenation84
Ambient Reductive Amination of Levulinic Acid to Pyrrolidones over Pt Nanocatalysts on Porous TiO2 Nanosheets84
Economic Sulfur Conversion to Functional Polythioamides through Catalyst-Free Multicomponent Polymerizations of Sulfur, Acids, and Amines84
Organic Memory Devices Based on a Bis-Cyclometalated Alkynylgold(III) Complex83
Computational Study of Rh-Catalyzed Carboacylation of Olefins: Ligand-Promoted Rhodacycle Isomerization Enables Regioselective C–C Bond Functionalization of Benzocyclobutenones83
Cross-Electrophile Coupling of Unactivated Alkyl Chlorides83
Copper-Catalyzed Radical Aminotrifluoromethylation of Alkenes83
Spatial Photocontrol of the Optical Output from an Organic Crystal Waveguide83
Electrochemical Aminoxyl-Mediated Oxidation of Primary Alcohols in Lignin to Carboxylic Acids: Polymer Modification and Depolymerization83
Mechanism-Inspired Design of Bifunctional Catalysts for the Alternating Ring-Opening Copolymerization of Epoxides and Cyclic Anhydrides83
A Prolific Solvate Former, Galunisertib, under the Pressure of Crystal Structure Prediction, Produces Ten Diverse Polymorphs83
Ru Octahedral Nanocrystals with a Face-Centered Cubic Structure, {111} Facets, Thermal Stability up to 400 °C, and Enhanced Catalytic Activity83
Construction of Natural-Product-Like Cyclophane-Braced Peptide Macrocycles via sp3 C–H Arylation83
Base-Controlled Heck, Suzuki, and Sonogashira Reactions Catalyzed by Ligand-Free Platinum or Palladium Single Atom and Sub-Nanometer Clusters83
Free Amino Acid Recognition: A Bisbinaphthyl-Based Fluorescent Probe with High Enantioselectivity83
Atomic Structure of a Fluorescent Ag8 Cluster Templated by a Multistranded DNA Scaffold83
Catalyst-Free Dynamic Networks for Recyclable, Self-Healing Solid Polymer Electrolytes82
Copper-Catalyzed Trifluoromethylation of Alkyl Bromides82
Identifying Active Sites for CO2 Reduction on Dealloyed Gold Surfaces by Combining Machine Learning with Multiscale Simulations82
Three-Stage Evolution from Nonscalable to Scalable Optical Properties of Thiolate-Protected Gold Nanoclusters82
Electrochemical Measurements of Reactive Oxygen and Nitrogen Species inside Single Phagolysosomes of Living Macrophages82
Lithium Thiophosphate Functionalized Zirconium MOFs for Li–S Batteries with Enhanced Rate Capabilities82
Helical Sulfono-γ-AApeptides with Aggregation-Induced Emission and Circularly Polarized Luminescence82
Multicolor Mechanochromism of a Polymer/Silica Composite with Dual Distinct Mechanophores82
Enabling Two-Electron Pathways with Iron and Cobalt: From Ligand Design to Catalytic Applications82
Near Infrared Electrochemiluminescence of Rod-Shape 25-Atom AuAg Nanoclusters That Is Hundreds-Fold Stronger Than That of Ru(bpy)3 Standard82
A [2]Rotaxane-Based Circularly Polarized Luminescence Switch82
The Tandem Photoredox Catalysis Mechanism of [Ir(ppy)2(dtb-bpy)]+ Enabling Access to Energy Demanding Organic Substrates82
Endo- and Exo-Functionalized Tetraphenylethylene M12L24 Nanospheres: Fluorescence Emission inside a Confined Space82
Solid-State Dynamic Nuclear Polarization at 9.4 and 18.8 T from 100 K to Room Temperature81
Mechanism-Based Design of a High-Potential Catholyte Enables a 3.2 V All-Organic Nonaqueous Redox Flow Battery81
Synthesis, Structures, and Properties of Heptabenzo[7]circulene and Octabenzo[8]circulene81
Record-Setting Sorbents for Reversible Water Uptake by Systematic Anion Exchanges in Metal–Organic Frameworks81
High-Temperature Antiferroelectric of Lead Iodide Hybrid Perovskites81
Aminal-Linked Covalent Organic Frameworks through Condensation of Secondary Amine with Aldehyde81
Durable Solar-Powered Systems with Ni-Catalysts for Conversion of CO2 or CO to CH481
Bioinspired Thiophosphorodichloridate Reagents for Chemoselective Histidine Bioconjugation81
Electrochemical Hole Injection Selectively Expels Iodide from Mixed Halide Perovskite Films81
Controlling Protein Orientation at Interfaces Using Histidine Tags:  An Alternative to Ni/NTA81
Silicon-Mediated Selective Homo- and Heterocoupling of Carbon Monoxide81
Visible-Light-Induced Organocatalytic Borylation of Aryl Chlorides80
Hierarchical-Coassembly-Enabled 3D-Printing of Homogeneous and Heterogeneous Covalent Organic Frameworks80
Guest-Dependent Dynamics in a 3D Covalent Organic Framework80
Photochemically Cross-Linked Quantum Well Ligands for 2D/3D Perovskite Photovoltaics with Improved Photovoltage and Stability80
Molecular Magnetic Resonance Imaging Using a Redox-Active Iron Complex80
Unraveling Concomitant Packing Polymorphism in Metallosupramolecular Polymers80
Integration of Metal–Organic Frameworks on Protective Layers for Destruction of Nerve Agents under Relevant Conditions80
Directed Evolution of a Cytochrome P450 Carbene Transferase for Selective Functionalization of Cyclic Compounds80
Temperature- and Mn2+ Concentration-Dependent Emission Properties of Mn2+-Doped ZnSe Nanocrystals80
Acetylene-Selective Hydrogenation Catalyzed by Cationic Nickel Confined in Zeolite80
Face-Sharing Archimedean Solids Stacking for the Construction of Mixed-Ligand Metal–Organic Frameworks80
Engineering the Electronic Structure of Submonolayer Pt on Intermetallic Pd3Pb via Charge Transfer Boosts the Hydrogen Evolution Reaction80
Highly Efficient Degradation of Persistent Pollutants with 3D Nanocone TiO2-Based Photoelectrocatalysis80
Crystallographic and lithium-6 and nitrogen-15 NMR studies of a chiral bidentate lithium amide. An effect of aggregation states on an enantioselective deprotonation reaction79
BDPA-Nitroxide Biradicals Tailored for Efficient Dynamic Nuclear Polarization Enhanced Solid-State NMR at Magnetic Fields up to 21.1 T79
A Mechanosensor Mechanism Controls the G-Quadruplex/i-Motif Molecular Switch in the MYC Promoter NHE III179
Site-Selective Functionalization of Pyridinium Derivatives via Visible-Light-Driven Photocatalysis with Quinolinone79
C–H Alkylation via Multisite-Proton-Coupled Electron Transfer of an Aliphatic C–H Bond79
Hydrogen Bonding Phase-Transfer Catalysis with Potassium Fluoride: Enantioselective Synthesis of β-Fluoroamines79
Amyloid β-Protein C-Terminal Fragments: Formation of Cylindrins and β-Barrels79
Interfacial Frustrated Lewis Pairs of CeO2 Activate CO2 for Selective Tandem Transformation of Olefins and CO2 into Cyclic Carbonates79
Millimeter-Scale Single-Crystalline Semiconducting MoTe2via Solid-to-Solid Phase Transformation79
Atomic-Level Microstructure of Efficient Formamidinium-Based Perovskite Solar Cells Stabilized by 5-Ammonium Valeric Acid Iodide Revealed by Multinuclear and Two-Dimensional Solid-State NMR79
Supramolecular Block Copolymers by Seeded Living Polymerization of Perylene Bisimides78
α-Functionalization of Cyclic Secondary Amines: Lewis Acid Promoted Addition of Organometallics to Transient Imines78
Synthesis of Luminescent Platinum(II) 2,6-Bis(N-dodecylbenzimidazol-2′-yl)pyridine Foldamers and Their Supramolecular Assembly and Metallogel Formation78
Regulating Key Variables and Visualizing Lithium Dendrite Growth: An Operando X-ray Study78
Radical Addition to Strained σ-Bonds Enables the Stereocontrolled Synthesis of Cyclobutyl Boronic Esters78
Biocatalytic N-Alkylation of Amines Using Either Primary Alcohols or Carboxylic Acids via Reductive Aminase Cascades78
Self-Assembly of a Highly Emissive Pure Organic Imine-Based Stack for Electroluminescence and Cell Imaging78
Fluorogenic Squaraine Dimers with Polarity-Sensitive Folding As Bright Far-Red Probes for Background-Free Bioimaging78
Quantifying Visible-Light-Induced Electron Transfer Properties of Single Dye-Sensitized ZnO Entity for Water Splitting78
Catalysis through Dynamic Spacer Installation of Multivariate Functionalities in Metal–Organic Frameworks78
Synthesis of Highly Efficient Multivalent Disaccharide/[60]Fullerene Nanoballs for Emergent Viruses78
Efficient Hydrogen Production from Methanol Using a Single-Site Pt1/CeO2 Catalyst78
Hybrid Silver Nanocubes for Improved Plasmon-Enhanced Singlet Oxygen Production and Inactivation of Bacteria78
Modification of Indacenodithiophene-Based Polymers and Its Impact on Charge Carrier Mobility in Organic Thin-Film Transistors78
A Dual Purpose Strategy to Endow Gold Nanoclusters with Both Catalysis Activity and Water Solubility78
Zirconium-Based Metal–Organic Frameworks for the Removal of Protein-Bound Uremic Toxin from Human Serum Albumin77
Fragment-Based Covalent Ligand Screening Enables Rapid Discovery of Inhibitors for the RBR E3 Ubiquitin Ligase HOIP77
Site-Selective and Stereoselective C–H Alkylations of Carbohydrates via Combined Diarylborinic Acid and Photoredox Catalysis77
Uniform Biodegradable Fiber-Like Micelles and Block Comicelles via “Living” Crystallization-Driven Self-Assembly of Poly(l-lactide) Block Copolymers: The Importance of Reducing Unimer Self-77
Chiral Bidentate Boryl Ligand Enabled Iridium-Catalyzed Asymmetric C(sp2)–H Borylation of Diarylmethylamines77
Advancing Solutions to the Carbohydrate Sequencing Challenge77
Highly Selective and Catalytic Generation of Acyclic Quaternary Carbon Stereocenters via Functionalization of 1,3-Dienes with CO277
Ferroelectricity and Rashba Effect in a Two-Dimensional Dion-Jacobson Hybrid Organic–Inorganic Perovskite77
Boron Nitride Nanotubes for Ammonia Synthesis: Activation by Filling Transition Metals77
Spatial Presentation of Cholesterol Units on a DNA Cube as a Determinant of Membrane Protein-Mimicking Functions77
Comprehensive Synthesis of Monohydroxy–Cucurbit[n]urils (n = 5, 6, 7, 8): High Purity and High Conversions77
Light-Responsive, Shape-Switchable Block Copolymer Particles76
Identification of Dynamic Modes in an Intrinsically Disordered Protein Using Temperature-Dependent NMR Relaxation76
Tunable Low-LUMO Boron-Doped Polycyclic Aromatic Hydrocarbons by General One-Pot C–H Borylations76
Conformational Ensembles of an Intrinsically Disordered Protein Consistent with NMR, SAXS, and Single-Molecule FRET76
Autocatalytic Morphology Transformation Platform for Targeted Drug Accumulation76
Copper-Catalyzed, N-Directed Csp3–H Trifluoromethylthiolation (−SCF3) and Trifluoromethylselenation (−SeCF3)76
Ethylenediammonium-Based “Hollow” Pb/Sn Perovskites with Ideal Band Gap Yield Solar Cells with Higher Efficiency and Stability76
Catalytic Enantioselective Boryl and Silyl Substitution with Trifluoromethyl Alkenes: Scope, Utility, and Mechanistic Nuances of Cu–F β-Elimination76
Enantiodivergent α-Amino C–H Fluoroalkylation Catalyzed by Engineered Cytochrome P450s76
Mechanism of Catalytic O2 Reduction by Iron Tetraphenylporphyrin76
Efficient Photocatalytic CO2 Reduction by a Ni(II) Complex Having Pyridine Pendants through Capturing a Mg2+ Ion as a Lewis-Acid Cocatalyst76
Non-C2-Symmetric Chiral-at-Ruthenium Catalyst for Highly Efficient Enantioselective Intramolecular C(sp3)–H Amidation76
Dehydration–Hydration Switching of Single-Molecule Magnet Behavior and Visible Photoluminescence in a Cyanido-Bridged DyIIICoIII Framework76
Connecting Microscopic Structures, Mesoscale Assemblies, and Macroscopic Architectures in 3D-Printed Hierarchical Porous Covalent Organic Framework Foams76
Open-Shell Nonbenzenoid Nanographenes Containing Two Pairs of Pentagonal and Heptagonal Rings76
Circularly Polarized Luminescence of Achiral Cyanine Molecules Assembled on DNA Templates76
Cobaloxime Catalysis: Selective Synthesis of Alkenylphosphine Oxides under Visible Light76
Water Enables Efficient CO2 Capture from Natural Gas Flue Emissions in an Oxidation-Resistant Diamine-Appended Metal–Organic Framework76
Homochiral Metal–Organic Frameworks for Enantioselective Separations in Liquid Chromatography76
Origin of High Activity and Durability of Twisty Nanowire Alloy Catalysts under Oxygen Reduction and Fuel Cell Operating Conditions76
Experimental Evidence for pKa-Driven Asynchronicity in C–H Activation by a Terminal Co(III)–Oxo Complex75
Cooperative Au/Ag Dual-Catalyzed Cross-Dehydrogenative Biaryl Coupling: Reaction Development and Mechanistic Insight75
Enhanced Stability and CO/Formate Selectivity of Plasma-Treated SnOx/AgOx Catalysts during CO2 Electroreduction75
Theoretical and Experimental Understanding of Hydrogen Evolution Reaction Kinetics in Alkaline Electrolytes with Pt-Based Core–Shell Nanocrystals75
Mechanistic Aspects of the Polymerization of Lactide Using a Highly Efficient Aluminum(III) Catalytic System75
Exciton Dissociation and Suppressed Charge Recombination at 2D Perovskite Edges: Key Roles of Unsaturated Halide Bonds and Thermal Disorder75
Exploiting Excited-State Aromaticity To Design Highly Stable Singlet Fission Materials75
Wafer-Sized Ultrathin Gallium and Indium Nitride Nanosheets through the Ammonolysis of Liquid Metal Derived Oxides75
Discrete Dimers of Redox-Active and Fluorescent Perylene Diimide-Based Rigid Isosceles Triangles in the Solid State75
What Are the Radical Intermediates in Oxidative N-Heterocyclic Carbene Organocatalysis?74
Enantioselective Total Synthesis of (−)-Maoecrystal V74
Realization of Thermally Stimulated Delayed Phosphorescence in Arylgold(III) Complexes and Efficient Gold(III) Based Blue-Emitting Organic Light-Emitting Devices74
Synthesis of a Carbon Nanocone by Cascade Annulation74
Addressing Drug Resistance in Cancer with Macromolecular Chemotherapeutic Agents74
Discovery of Unclustered Fungal Indole Diterpene Biosynthetic Pathways through Combinatorial Pathway Reassembly in Engineered Yeast74
Catalytic C–H Amination Mediated by Dipyrrin Cobalt Imidos74
SiRA: A Silicon Rhodamine-Binding Aptamer for Live-Cell Super-Resolution RNA Imaging74
Oxidatively Induced Reductive Elimination: Exploring the Scope and Catalyst Systems with Ir, Rh, and Ru Complexes74
Intrinsic Activity of Oxygen Evolution Catalysts Probed at Single CoFe2O4 Nanoparticles74
Formation of a Supramolecular Polymeric Adhesive via Water–Participant Hydrogen Bond Formation74
Ni(I)–X Complexes Bearing a Bulky α-Diimine Ligand: Synthesis, Structure, and Superior Catalytic Performance in the Hydrogen Isotope Exchange in Pharmaceuticals74
Iridium-Catalyzed Asymmetric Borylation of Unactivated Methylene C(sp3)–H Bonds74
Triarylmethane Fluorophores Resistant to Oxidative Photobluing74
Elucidation and Structural Modeling of CD71 as a Molecular Target for Cell-Specific Aptamer Binding74
Tuning Li2O2 Formation Routes by Facet Engineering of MnO2 Cathode Catalysts74
Interplay of Guanine Oxidation and G-Quadruplex Folding in Gene Promoters74
Epitaxial Growth and Integration of Insulating Metal–Organic Frameworks in Electrochemistry74
Unexpected Roles of Triethanolamine in the Photochemical Reduction of CO2 to Formate by Ruthenium Complexes74
Chemistry and Quantum Mechanics in 2019: Give Us Insight and Numbers73
Enantioselective Allylation Using Allene, a Petroleum Cracking Byproduct73
Solar Hydrogen Production by Amorphous Silicon Photocathodes Coated with a Magnetron Sputter Deposited Mo2C Catalyst73
Tuning the Structure and Electronic Properties of B–N Fused Dipyridylanthracene and Implications on the Self-Sensitized Reactivity with Singlet Oxygen73
A Strategy for Increasing the Efficiency of the Oxygen Reduction Reaction in Mn-Doped Cobalt Ferrites73
Nanorg Microbial Factories: Light-Driven Renewable Biochemical Synthesis Using Quantum Dot-Bacteria Nanobiohybrids73
Multivariate Stratified Metal–Organic Frameworks: Diversification Using Domain Building Blocks73
SO2-Induced Selectivity Change in CO2 Electroreduction73
Polymer Infiltration into Metal–Organic Frameworks in Mixed-Matrix Membranes Detected in Situ by NMR73
Impact of Stereo- and Regiochemistry on Energetic Materials73
Bulk Photovoltaic Effect in a Pair of Chiral–Polar Layered Perovskite-Type Lead Iodides Altered by Chirality of Organic Cations73
P-Chiral Phosphines Enabled by Palladium/Xiao-Phos-Catalyzed Asymmetric P–C Cross-Coupling of Secondary Phosphine Oxides and Aryl Bromides73
Two-Dimensional Mesoporous Heterostructure Delivering Superior Pseudocapacitive Sodium Storage via Bottom-Up Monomicelle Assembly73
A Focused DNA-Encoded Chemical Library for the Discovery of Inhibitors of NAD+-Dependent Enzymes73
Bispecific Aptamer Induced Artificial Protein-Pairing: A Strategy for Selective Inhibition of Receptor Function72
From Fundamental Theories to Quantum Coherences in Electron Transfer72
Transition from Ferromagnetic Semiconductor to Ferromagnetic Metal with Enhanced Curie Temperature in Cr2Ge2Te6 via Organic Ion Intercalation72
Rh(III)-Catalyzed meta-C–H Alkenylation with Alkynes72
Site-Selective Functionalization of Linear Diterpenoids through U-Shaped Folding in a Confined Artificial Cavity72
Converting Unstable Imine-Linked Network into Stable Aromatic Benzoxazole-Linked One via Post-oxidative Cyclization72
Interplay between Conformational Entropy and Solvation Entropy in Protein–Ligand Binding72
ExTzBox: A Glowing Cyclophane for Live-Cell Imaging72
Computationally Assisted Design of Polarizing Agents for Dynamic Nuclear Polarization Enhanced NMR: The AsymPol Family71
Geometry Mismatch and Reticular Chemistry: Strategies To Assemble Metal–Organic Frameworks with Non-default Topologies71
Pressure-Engineered Structural and Optical Properties of Two-Dimensional (C4H9NH3)2PbI4 Perovskite Exfoliated nm-Thin Flakes71
Mechanistic Studies of Hydride Transfer to Imines from a Highly Active and Chemoselective Manganate Catalyst71
Reticular Synthesis of Multinary Covalent Organic Frameworks71
Mechanism and Scope of Nickel-Catalyzed Decarbonylative Borylation of Carboxylic Acid Fluorides71
Low-Temperature Synthesis of Perovskite Oxynitride-Hydrides as Ammonia Synthesis Catalysts71
Selective, Fast-Response, and Regenerable Metal–Organic Framework for Sampling Excess Fluoride Levels in Drinking Water71
Mechanistically Guided Predictive Models for Ligand and Initiator Effects in Copper-Catalyzed Atom Transfer Radical Polymerization (Cu-ATRP)71
Unusual Behavior of Donor–Acceptor Stenhouse Adducts in Confined Space of a Water-Soluble PdII8 Molecular Vessel71
Enantioselective Radical Construction of 5-Membered Cyclic Sulfonamides by Metalloradical C–H Amination71
Stereodivergent Synthesis through Catalytic Asymmetric Reversed Hydroboration71
In Situ Small-Angle X-ray Scattering Studies During Reversible Addition–Fragmentation Chain Transfer Aqueous Emulsion Polymerization71
A Programmable DNA Origami Platform to Organize SNAREs for Membrane Fusion71
A Conformationally Restricted Aza-BODIPY Platform for Stimulus-Responsive Probes with Enhanced Photoacoustic Properties71
Porous Molecular Conductor: Electrochemical Fabrication of Through-Space Conduction Pathways among Linear Coordination Polymers71
The Electronic Structures of Square-Planar Metal Complexes. III. High-Spin Planar Cobalt(I) and Iron(I)71
All-Visible-Light-Activated Dithienylethenes Induced by Intramolecular Proton Transfer71
Enol Ethers Are Effective Monomers for Ring-Opening Metathesis Polymerization: Synthesis of Degradable and Depolymerizable Poly(2,3-dihydrofuran)71
Cooking Chemistry Transforms Proteins into High-Strength Adhesives71
Mechanism and Kinetics of Propane Dehydrogenation and Cracking over Ga/H-MFI Prepared via Vapor-Phase Exchange of H-MFI with GaCl371
Selection of DNA-Encoded Libraries to Protein Targets within and on Living Cells70
Direct Imaging of Tunable Crystal Surface Structures of MOF MIL-101 Using High-Resolution Electron Microscopy70
Noncovalent Modulation of the Inverse Temperature Transition and Self-Assembly of Elastin-b-Collagen-like Peptide Bioconjugates70
Protein Flexibility and Stiffness Enable Efficient Enzymatic Catalysis70
Structure Property Analysis of the Solution and Solid-State Properties of Bistable Photochromic Hydrazones70
Turn-On Mode Fluorescence Switch by Using Negative Photochromic Imidazole Dimer70
Epoxidation of Cyclooctene Using Water as the Oxygen Atom Source at Manganese Oxide Electrocatalysts70
Visible-Light-Induced, Metal-Free Carbene Insertion into B–H Bonds between Acylsilanes and Pinacolborane70
Computer-Guided Discovery of a pH-Responsive Organic Photocatalyst and Application for pH and Light Dual-Gated Polymerization70
Pickering Emulsion-Derived Liquid–Solid Hybrid Catalyst for Bridging Homogeneous and Heterogeneous Catalysis70
Native Ion Mobility-Mass Spectrometry Reveals the Formation of β-Barrel Shaped Amyloid-β Hexamers in a Membrane-Mimicking Environment70
Transition-Metal-Free C–C, C–O, and C–N Cross-Couplings Enabled by Light70
Water Networks Can Determine the Affinity of Ligand Binding to Proteins70
Triplet Sensitization by “Self-Trapped” Excitons of Nontoxic CuInS2 Nanocrystals for Efficient Photon Upconversion70
Adaptive Coordination-Driven Supramolecular Syntheses toward New Polymetallic Cu(I) Luminescent Assemblies70
Molecular Cursor Caliper: A Fluorescent Sensor for Dicarboxylate Dianions70
Multicolor Tunable Polymeric Nanoparticle from the Tetraphenylethylene Cage for Temperature Sensing in Living Cells70
Metal-Free Catalysis: A Redox-Active Donor–Acceptor Conjugated Microporous Polymer for Selective Visible-Light-Driven CO2 Reduction to CH470
Catalytic Defluorination of Perfluorinated Aromatics under Oxidative Conditions Using N-Bridged Diiron Phthalocyanine69
Sensitizing Singlet Fission with Perovskite Nanocrystals69
Arm Growth and Facet Modulation in Perovskite Nanocrystals69
Substitution Activated Precise Phototheranostics through Supramolecular Assembly of AIEgen and Calixarene69
General Way To Construct Micro- and Mesoporous Metal–Organic Framework-Based Porous Liquids69
Nitrogen Bridged Diazocines: Photochromes Switching within the Near-Infrared Region with High Quantum Yields in Organic Solvents and in Water69
Chiral Bidentate Boryl Ligand Enabled Iridium-Catalyzed Enantioselective C(sp3)–H Borylation of Cyclopropanes69
Aerobic Carbon–Carbon Bond Cleavage of Alkenes to Aldehydes Catalyzed by First-Row Transition-Metal-Substituted Polyoxometalates in the Presence of Nitrogen Dioxide69
Iron-Catalyzed Dihydrosilylation of Alkynes: Efficient Access to Geminal Bis(silanes)69
Tuning the Molecular and Cationic Affinity in a Series of Multifunctional Metal–Organic Frameworks Based on Dodecanuclear Zn(II) Carboxylate Wheels69
Coupled Cation–Anion Dynamics Enhances Cation Mobility in Room-Temperature Superionic Solid-State Electrolytes69
In Situ Generation of Azonia-Containing Polyelectrolytes for Luminescent Photopatterning and Superbug Killing69
Photocatalytic CO2 Reduction Mediated by Electron Transfer via the Excited Triplet State of Zn(II) Porphyrin69
How Size and Aggregation of Ice-Binding Proteins Control Their Ice Nucleation Efficiency68
Catalytic Strategy for Regioselective Arylethylamine Synthesis68
Manganese Catalyzed Hydrogenation of Carbamates and Urea Derivatives68
Unmasking the Ligand Effect in Manganese-Catalyzed Hydrogenation: Mechanistic Insight and Catalytic Application68
Enzyme-Catalyzed Inverse-Electron Demand Diels–Alder Reaction in the Biosynthesis of Antifungal Ilicicolin H68
All-Scale Hierarchically Structured p-Type PbSe Alloys with High Thermoelectric Performance Enabled by Improved Band Degeneracy68
Catalytic Ring Expansions of Cyclic Alcohols Enabled by Proton-Coupled Electron Transfer68
Chemical On/Off Switching of Mechanically Planar Chirality and Chiral Anion Recognition in a [2]Rotaxane Molecular Shuttle68
Self-Assembly of Anionic Polyoxometalate–Organic Architectures Based on Lacunary Phosphomolybdates and Pyridyl Ligands68
Ruthenium-Catalyzed Enantioselective C–H Functionalization: A Practical Access to Optically Active Indoline Derivatives68
Streamlined Synthesis of C(sp3)-Rich N-Heterospirocycles Enabled by Visible-Light-Mediated Photocatalysis68
Two-in-One Chemogene Assembled from Drug-Integrated Antisense Oligonucleotides To Reverse Chemoresistance68
Nucleophile-Dependent Z/E- and Regioselectivity in the Palladium-Catalyzed Asymmetric Allylic C–H Alkylation of 1,4-Dienes68
Soft Porous Crystal Based upon Organic Cages That Exhibit Guest-Induced Breathing and Selective Gas Separation68
Postsynthetic Covalent and Coordination Functionalization of Rhodium(II)-Based Metal–Organic Polyhedra68
Mechanical Properties of a Metal–Organic Framework formed by Covalent Cross-Linking of Metal–Organic Polyhedra68
Cobalt-Catalyzed Electrophilic Aminations with Anthranils: An Expedient Route to Condensed Quinolines68
Multi-Stimuli-Responsive Charge-Transfer Hydrogel for Room-Temperature Organic Ferroelectric Thin-Film Devices67
Photochromic Heterocycle-Fused Thieno[3,2-b]phosphole Oxides as Visible Light Switches without Sacrificing Photoswitching Efficiency67
Versatile Design Strategy for Highly Luminescent Vacuum-Evaporable and Solution-Processable Tridentate Gold(III) Complexes with Monoaryl Auxiliary Ligands and Their Applications for Phosphorescent Org67
Simulation-Guided Rational de Novo Design of a Small Pore-Forming Antimicrobial Peptide67
Site-Selective 1,1-Difunctionalization of Unactivated Alkenes Enabled by Cationic Palladium Catalysis67
Metal–Organic Layers as Multifunctional Two-Dimensional Nanomaterials for Enhanced Photoredox Catalysis67
Reductive Coupling between C–N and C–O Electrophiles67
Helical Oligourea Foldamers as Powerful Hydrogen Bonding Catalysts for Enantioselective C–C Bond-Forming Reactions67
Chirality-Selected Chemical Modulation of Amyloid Aggregation67
Anti-Markovnikov Hydroamination of Unactivated Alkenes with Primary Alkyl Amines67
A Selective, Protein-Based Fluorescent Sensor with Picomolar Affinity for Rare Earth Elements67
Multistep Solid-State Organic Synthesis of Carbamate-Linked Covalent Organic Frameworks67
Unexpectedly Strong Chiral Amplification of Chiral/Achiral and Chiral/Chiral Copolymers of Biphenylylacetylenes and Further Enhancement/Inversion and Memory of the Macromolecular Helicity67
Para-Selective, Iridium-Catalyzed C–H Borylations of Sulfated Phenols, Benzyl Alcohols, and Anilines Directed by Ion-Pair Electrostatic Interactions67
Universal Oxide Shell Growth Enables in Situ Structural Studies of Perovskite Nanocrystals during the Anion Exchange Reaction67
Improving Photocatalysis for the Reduction of CO2 through Non-covalent Supramolecular Assembly67
Operando Characterization of Iron Phthalocyanine Deactivation during Oxygen Reduction Reaction Using Electrochemical Tip-Enhanced Raman Spectroscopy67
Ultrafast Electron Diffraction Tomography for Structure Determination of the New Zeolite ITQ-5867
Charge Transfer Band Gap as an Indicator of Hysteresis in Li-Disordered Rock Salt Cathodes for Li-Ion Batteries67
Ni-Catalyzed Asymmetric Allylation of Secondary Phosphine Oxides67
Phase Control on Surface for the Stabilization of High Energy Cathode Materials of Lithium Ion Batteries67
Quadruply B←N-Fused Dibenzo-azaacene with High Electron Affinity and High Electron Mobility67
Discovery, X-ray Crystallography and Antiviral Activity of Allosteric Inhibitors of Flavivirus NS2B-NS3 Protease67
A Self-Assembled Platform Based on Branched DNA for sgRNA/Cas9/Antisense Delivery67
Structural Determination and Nonlinear Optical Properties of New 1T‴-Type MoS2 Compound67
Room Temperature Metallic Conductivity in a Metal–Organic Framework Induced by Oxidation67
Single-Atom Fluorescence Switch: A General Approach toward Visible-Light-Activated Dyes for Biological Imaging67
Csp3–Csp3 Bond-Forming Reductive Elimination from Well-Defined Copper(III) Complexes67
3D Covalent Organic Frameworks of Interlocking 1D Square Ribbons67
Trilayered Lead Chloride Perovskite Ferroelectric Affording Self-Powered Visible-Blind Ultraviolet Photodetection with Large Zero-Bias Photocurrent67
Photoinduced Electrochemiluminescence at Silicon Electrodes in Water66
Catalytic Cross-Coupling of Secondary Alcohols66
Molecular Complex of Tb in the +4 Oxidation State66
Wavelength-Dependent Energy and Charge Transfer in MOF: A Step toward Artificial Porous Light-Harvesting System66
Photoluminescent Anisotropy Amplification in Polymorphic Organic Nanocrystals by Light-Harvesting Energy Transfer66
Interrogating Kinetic versus Thermodynamic Topologies of Metal–Organic Frameworks via Combined Transmission Electron Microscopy and X-ray Diffraction Analysis66
Facet-Dependent in Situ Growth of Nanoparticles in Epitaxial Thin Films: The Role of Interfacial Energy66
Dehydrogenation of n-Alkanes by Solid-Phase Molecular Pincer-Iridium Catalysts. High Yields of α-Olefin Product66
Rotational Cluster Anion Enabling Superionic Conductivity in Sodium-Rich Antiperovskite Na3OBH466
Defect-Mediated Phase Transformation in Anisotropic Two-Dimensional PdSe2 Crystals for Seamless Electrical Contacts66
Construction of Active Site in a Sintered Copper–Ceria Nanorod Catalyst66
A New Tool for NMR Crystallography: Complete 13C/15N Assignment of Organic Molecules at Natural Isotopic Abundance Using DNP-Enhanced Solid-State NMR65
Selective Defluoroallylation of Trifluoromethylarenes65
Thermodynamic-Driven Self-Assembly: Heterochiral Self-Sorting and Structural Reconfiguration in Gold(I)–Sulfido Cluster System65
Assembly of Gold Nanoparticles into Chiral Superstructures Driven by Circularly Polarized Light65
Hydrogen-Bonding and Hydrophobic Groups Contribute Equally to the Binding of Hyperactive Antifreeze and Ice-Nucleating Proteins to Ice65
Cooperative Silver Ion-Pair Recognition by Peralkylated Pillar[5]arenes65
The Oxidation of Platinum under Wet Conditions Observed by Electrochemical X-ray Photoelectron Spectroscopy65
Discovery and Elucidation of Counteranion Dependence in Photoredox Catalysis65
Titanium Hydroxide Secondary Building Units in Metal–Organic Frameworks Catalyze Hydrogen Evolution under Visible Light65
Direct Radiation Detection by a Semiconductive Metal–Organic Framework65
Metal–Organic Framework Nanoparticle-Assisted Cryopreservation of Red Blood Cells65
Unraveling Oxygen Evolution in Li-Rich Oxides: A Unified Modeling of the Intermediate Peroxo/Superoxo-like Dimers65
Design, Isolation, and Spectroscopic Analysis of a Tetravalent Terbium Complex65
Synthesis of Belt- and Möbius-Shaped Cycloparaphenylenes by Rhodium-Catalyzed Alkyne Cyclotrimerization65
Open-Shell and Antiaromatic Character Induced by the Highly Symmetric Geometry of the Planar Heptalene Structure: Synthesis and Characterization of a Nonalternant Isomer of Bisanthene65
Engineering Aptamer with Enhanced Affinity by Triple Helix-Based Terminal Fixation65
Excited-State Dynamics in Fully Conjugated 2D Covalent Organic Frameworks65
Two-Dimensional Kagome Lattices Made of Hetero Triangulenes Are Dirac Semimetals or Single-Band Semiconductors65
Electrochemical Synthesis of Hindered Primary and Secondary Amines via Proton-Coupled Electron Transfer65
Photoactivation Mechanism, Timing of Protein Secondary Structure Dynamics and Carotenoid Translocation in the Orange Carotenoid Protein65
Earth-Abundant Molecular Z-Scheme Photoelectrochemical Cell for Overall Water-Splitting64
Ultrasensitive Detection of Attomolar Protein Concentrations by Dropcast Single Molecule Assays64
Catalytic α-Selective Deuteration of Styrene Derivatives64
Highly Electroconductive Metal–Organic Framework: Tunable by Metal Ion Sorption Quantity64
Stereodivergent Intramolecular Cyclopropanation Enabled by Engineered Carbene Transferases64
Formation of 1D Infinite Chains Directed by Metal–Metal and/or π–π Stacking Interactions of Water-Soluble Platinum(II) 2,6-Bis(benzimidazol-2′-yl)pyridine Double Complex Salts64
CisTrans Selectivity of Haloalkene Isomers in Nonporous Adaptive Pillararene Crystals64
Preparation of Chiral Allenes through Pd-Catalyzed Intermolecular Hydroamination of Conjugated Enynes: Enantioselective Synthesis Enabled by Catalyst Design64
MoS2–OH Bilayer-Mediated Growth of Inch-Sized Monolayer MoS2 on Arbitrary Substrates64
Ni-Catalyzed Arylboration of Unactivated Alkenes: Scope and Mechanistic Studies64
Chiral Bifunctional Phosphine Ligand Enabling Gold-Catalyzed Asymmetric Isomerization of Alkyne to Allene and Asymmetric Synthesis of 2,5-Dihydrofuran64
Catalytic Deuterium Incorporation within Metabolically Stable β-Amino C–H Bonds of Drug Molecules64
Reductive Trimerization of CO to the Deltate Dianion Using Activated Magnesium(I) Compounds64
CUB-5: A Contoured Aliphatic Pore Environment in a Cubic Framework with Potential for Benzene Separation Applications64
Designed Conformation and Fluorescence Properties of Self-Assembled Phenazine-Cored Platinum(II) Metallacycles64
Barbier Hyperbranching Polymerization-Induced Emission toward Facile Fabrication of White Light-Emitting Diode and Light-Harvesting Film64
Synergistic Effect of High-Frequency Ultrasound with Cupric Oxide Catalyst Resulting in a Selectivity Switch in Glucose Oxidation under Argon64
Efficient Triplet–Triplet Annihilation Upconversion with an Anti-Stokes Shift of 1.08 eV Achieved by Chemically Tuning Sensitizers64
Lewis Acid Dominant Windmill-Shaped V8 Clusters: A Bifunctional Heterogeneous Catalyst for CO2 Cycloaddition and Oxidation of Sulfides64
Deep Tumor Penetration of Drug-Loaded Nanoparticles by Click Reaction-Assisted Immune Cell Targeting Strategy64
Efficient and Stable Low-Bandgap Perovskite Solar Cells Enabled by a CsPbBr3-Cluster Assisted Bottom-up Crystallization Approach64
Directed Copper-Catalyzed Intermolecular Aminative Difunctionalization of Unactivated Alkenes64
Enzymatic Intermolecular Hetero-Diels–Alder Reaction in the Biosynthesis of Tropolonic Sesquiterpenes64
Strategy to Lengthen the On-Time of Photochromic Rhodamine Spirolactam for Super-resolution Photoactivated Localization Microscopy64
Coordination-Driven Stereospecific Control Strategy for Pure Cycloisomers in Solid-State Diene Photocycloaddition64
Photoactivation of Cu Centers in Metal–Organic Frameworks for Selective CO2 Conversion to Ethanol64
Cooperative Supramolecular Block Copolymerization for the Synthesis of Functional Axial Organic Heterostructures64