Journal of the American Chemical Society

Article	Citations
Solvation Structure Design for Aqueous Zn Metal Batteries	863
Tailoring Acidic Oxygen Reduction Selectivity on Single-Atom Catalysts via Modification of First and Second Coordination Spheres	575
Full-Color, Narrowband, and High-Efficiency Electroluminescence from Boron and Carbazole Embedded Polycyclic Heteroaromatics	542
Regulating Surface Termination for Efficient Inverted Perovskite Solar Cells with Greater Than 23% Efficiency	471
Photocatalytic Molecular Oxygen Activation by Regulating Excitonic Effects in Covalent Organic Frameworks	409
Non-Bonding Interaction of Neighboring Fe and Ni Single-Atom Pairs on MOF-Derived N-Doped Carbon for Enhanced CO2 Electroreduction	392
Co-Solvent Electrolyte Engineering for Stable Anode-Free Zinc Metal Batteries	382
Short-Range Ordered Iridium Single Atoms Integrated into Cobalt Oxide Spinel Structure for Highly Efficient Electrocatalytic Water Oxidation	353
One-Step Synthesis of SnI2·(DMSO)x Adducts for High-Performance Tin Perovskite Solar Cells	348
Proton-Coupled Electron Transfer Guidelines, Fair and Square	321
Strongly Reducing (Diarylamino)benzene-Based Covalent Organic Framework for Metal-Free Visible Light Photocatalytic H2O2 Generation	321
Highly Selective CO2 Electroreduction to C2H4 Using a Metal–Organic Framework with Dual Active Sites	305
Potential-Driven Restructuring of Cu Single Atoms to Nanoparticles for Boosting the Electrochemical Reduction of Nitrate to Ammonia	300
Large-Area, Flexible, Transparent, and Long-Lived Polymer-Based Phosphorescence Films	296
Boosting the Kinetics and Stability of Zn Anodes in Aqueous Electrolytes with Supramolecular Cyclodextrin Additives	291
Dynamic Behavior of Single-Atom Catalysts in Electrocatalysis: Identification of Cu-N3 as an Active Site for the Oxygen Reduction Reaction	290
Stabilizing Highly Active Ru Sites by Suppressing Lattice Oxygen Participation in Acidic Water Oxidation	288
Photocatalytic C–C Coupling from Carbon Dioxide Reduction on Copper Oxide with Mixed-Valence Copper(I)/Copper(II)	281
Sub-2 nm Ultrasmall High-Entropy Alloy Nanoparticles for Extremely Superior Electrocatalytic Hydrogen Evolution	280
Steric Effect Tuned Ion Solvation Enabling Stable Cycling of High-Voltage Lithium Metal Battery	278
Modulating Coordination Environment of Single-Atom Catalysts and Their Proximity to Photosensitive Units for Boosting MOF Photocatalysis	277
Development of Antibody-Based PROTACs for the Degradation of the Cell-Surface Immune Checkpoint Protein PD-L1	274
A High-Rate Two-Dimensional Polyarylimide Covalent Organic Framework Anode for Aqueous Zn-Ion Energy Storage Devices	272
High Efficiency (15.8%) All-Polymer Solar Cells Enabled by a Regioregular Narrow Bandgap Polymer Acceptor	268
Confining and Highly Dispersing Single Polyoxometalate Clusters in Covalent Organic Frameworks by Covalent Linkages for CO2 Photoreduction	266

Accelerated Synthesis and Discovery of Covalent Organic Framework Photocatalysts for Hydrogen Peroxide Production	264
Synthesis of Atropisomers by Transition-Metal-Catalyzed Asymmetric C–H Functionalization Reactions	258
The Progress and Outlook of Metal Single-Atom-Site Catalysis	254
Identification of the Highly Active Co–N4 Coordination Motif for Selective Oxygen Reduction to Hydrogen Peroxide	254
Design Rules of Hydrogen-Bonded Organic Frameworks with High Chemical and Thermal Stabilities	253
Stabilizing Cu2+ Ions by Solid Solutions to Promote CO2 Electroreduction to Methane	253
Interfacial Chemistry Enables Stable Cycling of All-Solid-State Li Metal Batteries at High Current Densities	248
Oxygen Vacancy-Mediated Selective C–N Coupling toward Electrocatalytic Urea Synthesis	243
Altering Ligand Fields in Single-Atom Sites through Second-Shell Anion Modulation Boosts the Oxygen Reduction Reaction	243
Atomic Metal–Support Interaction Enables Reconstruction-Free Dual-Site Electrocatalyst	243
High Entropy Alloy Electrocatalytic Electrode toward Alkaline Glycerol Valorization Coupling with Acidic Hydrogen Production	243
Identification of Cu(100)/Cu(111) Interfaces as Superior Active Sites for CO Dimerization During CO2 Electroreduction	240
Two-Dimensional Covalent Organic Frameworks with Cobalt(II)-Phthalocyanine Sites for Efficient Electrocatalytic Carbon Dioxide Reduction	239
Terahertz Wave Enhances Permeability of the Voltage-Gated Calcium Channel	235
Engineering Single-Atom Active Sites on Covalent Organic Frameworks for Boosting CO2 Photoreduction	235
Self-Luminescent Lanthanide Metal–Organic Frameworks as Signal Probes in Electrochemiluminescence Immunoassay	234
Hydrogen Spillover-Bridged Volmer/Tafel Processes Enabling Ampere-Level Current Density Alkaline Hydrogen Evolution Reaction under Low Overpotential	230
Thermal Atomization of Platinum Nanoparticles into Single Atoms: An Effective Strategy for Engineering High-Performance Nanozymes	223
Origin of Selective Production of Hydrogen Peroxide by Electrochemical Oxygen Reduction	222
Isolated Cobalt Centers on W18O49 Nanowires Perform as a Reaction Switch for Efficient CO2 Photoreduction	221
Hierarchical Copper with Inherent Hydrophobicity Mitigates Electrode Flooding for High-Rate CO2 Electroreduction to Multicarbon Products	220
Unraveling the Structure and Function of Melanin through Synthesis	214
Enhanced Cuprophilic Interactions in Crystalline Catalysts Facilitate the Highly Selective Electroreduction of CO2to CH4	214
Metal-Free Catalysis: A Redox-Active Donor–Acceptor Conjugated Microporous Polymer for Selective Visible-Light-Driven CO2 Reduction to CH4	213
Superdurable Bifunctional Oxygen Electrocatalyst for High-Performance Zinc–Air Batteries	211
The Role of Machine Learning in the Understanding and Design of Materials	211
Metal–Organic Framework Based Hydrogen-Bonding Nanotrap for Efficient Acetylene Storage and Separation	211
Single Iridium Atom Doped Ni2P Catalyst for Optimal Oxygen Evolution	205
Air-Stable Chiral Single-Molecule Magnets with Record Anisotropy Barrier Exceeding 1800 K	204
Semi-Immobilized Molecular Electrocatalysts for High-Performance Lithium–Sulfur Batteries	201
Suppression of Hydrogen Evolution in Acidic Electrolytes by Electrochemical CO2 Reduction	201
Co–Cu Bimetallic Metal Organic Framework Catalyst Outperforms the Pt/C Benchmark for Oxygen Reduction	201
Highly Efficient Degradation of Persistent Pollutants with 3D Nanocone TiO2-Based Photoelectrocatalysis	200
Copper Catalyzed C(sp3)–H Bond Alkylation via Photoinduced Ligand-to-Metal Charge Transfer	199
Monolayer NiIr-Layered Double Hydroxide as a Long-Lived Efficient Oxygen Evolution Catalyst for Seawater Splitting	199
Boronic Ester Based Vitrimers with Enhanced Stability via Internal Boron–Nitrogen Coordination	199
Strong Electronic Oxide–Support Interaction over In2O3/ZrO2 for Highly Selective CO2 Hydrogenation to Methanol	197
Single Carbon Vacancy Traps Atomic Platinum for Hydrogen Evolution Catalysis	197
Oxidation State and Surface Reconstruction of Cu under CO2 Reduction Conditions from In Situ X-ray Characterization	197
Atomically Dispersed Ni/α-MoC Catalyst for Hydrogen Production from Methanol/Water	196
2D MOF Periodontitis Photodynamic Ion Therapy	196
Unraveling Two Pathways for Electrochemical Alcohol and Aldehyde Oxidation on NiOOH	195
Metal–Organic Framework Membranes Encapsulating Gold Nanoparticles for Direct Plasmonic Photocatalytic Nitrogen Fixation	194
Using High-Entropy Configuration Strategy to Design Na-Ion Layered Oxide Cathodes with Superior Electrochemical Performance and Thermal Stability	194
Pd-Modified ZnO–Au Enabling Alkoxy Intermediates Formation and Dehydrogenation for Photocatalytic Conversion of Methane to Ethylene	193
Intrinsic Activity of Metal Centers in Metal–Nitrogen–Carbon Single-Atom Catalysts for Hydrogen Peroxide Synthesis	193
Significantly Enhanced Overall Water Splitting Performance by Partial Oxidation of Ir through Au Modification in Core–Shell Alloy Structure	192
Unassisted Photoelectrochemical Cell with Multimediator Modulation for Solar Water Splitting Exceeding 4% Solar-to-Hydrogen Efficiency	192
Defect Engineering Enables Synergistic Action of Enzyme-Mimicking Active Centers for High-Efficiency Tumor Therapy	191
Disulfide-Mediated Reversible Polymerization toward Intrinsically Dynamic Smart Materials	191

Boosting Oxygen Electrocatalytic Activity of Fe–N–C Catalysts by Phosphorus Incorporation	191
Dynamically Stable Active Sites from Surface Evolution of Perovskite Materials during the Oxygen Evolution Reaction	190
Accelerating CO2 Electroreduction to Multicarbon Products via Synergistic Electric–Thermal Field on Copper Nanoneedles	190
B,N-Embedded Double Hetero[7]helicenes with Strong Chiroptical Responses in the Visible Light Region	189
Targeted Solvatochromic Fluorescent Probes for Imaging Lipid Order in Organelles under Oxidative and Mechanical Stress	189
Noninvasive In Situ NMR Study of “Dead Lithium” Formation and Lithium Corrosion in Full-Cell Lithium Metal Batteries	187
Tailoring Binding Abilities by Incorporating Oxophilic Transition Metals on 3D Nanostructured Ni Arrays for Accelerated Alkaline Hydrogen Evolution Reaction	186
Overturning CO2 Hydrogenation Selectivity with High Activity via Reaction-Induced Strong Metal–Support Interactions	186
Single Biomolecule Imaging by Electrochemiluminescence	186
The Role of Cation Acidity on the Competition between Hydrogen Evolution and CO2 Reduction on Gold Electrodes	186
Linear Conjugated Polymers for Solar-Driven Hydrogen Peroxide Production: The Importance of Catalyst Stability	186
Trilayer Metal–Organic Frameworks as Multifunctional Electrocatalysts for Energy Conversion and Storage Applications	185
Piperazine-Linked Metalphthalocyanine Frameworks for Highly Efficient Visible-Light-Driven H2O2 Photosynthesis	185
Atomically Precise Dinuclear Site Active toward Electrocatalytic CO2 Reduction	185
Main Group Redox Catalysis of Organopnictogens: Vertical Periodic Trends and Emerging Opportunities in Group 15	185
Interfacial sp C–O–Mo Hybridization Originated High-Current Density Hydrogen Evolution	184
Simultaneous Two-Color Visualization of Lipid Droplets and Endoplasmic Reticulum and Their Interplay by Single Fluorescent Probes in Lambda Mode	184
Phototheranostic Metal-Phenolic Networks with Antiexosomal PD-L1 Enhanced Ferroptosis for Synergistic Immunotherapy	183
Pore Engineering for One-Step Ethylene Purification from a Three-Component Hydrocarbon Mixture	181
Interfacial Engineering of Bi19Br3S27 Nanowires Promotes Metallic Photocatalytic CO2 Reduction Activity under Near-Infrared Light Irradiation	180
Quasi-Covalently Coupled Ni–Cu Atomic Pair for Synergistic Electroreduction of CO2	180
Halogenated Zn2+ Solvation Structure for Reversible Zn Metal Batteries	178
Tracking the Role of Defect Types in Co3O4 Structural Evolution and Active Motifs during Oxygen Evolution Reaction	178
Electrocatalytic CO2-to-C2+ with Ampere-Level Current on Heteroatom-Engineered Copper via Tuning *CO Intermediate Coverage	178
Chemo-physical Strategies to Advance the in Vivo Functionality of Targeted Nanomedicine: The Next Generation	178
Ultrahigh Stable Methanol Oxidation Enabled by a High Hydroxyl Concentration on Pt Clusters/MXene Interfaces	177
Accessing Organonitrogen Compounds via C–N Coupling in Electrocatalytic CO2 Reduction	177
Sulfur-Based Aqueous Batteries: Electrochemistry and Strategies	176
Chemically Modified Gold/Silver Superatoms as Artificial Elements at Nanoscale: Design Principles and Synthesis Challenges	175
Circularly Polarized Organic Room Temperature Phosphorescence from Amorphous Copolymers	175
Metallic Two-Dimensional MoS2 Composites as High-Performance Osmotic Energy Conversion Membranes	174
Perspectives in Dye Chemistry: A Rational Approach toward Functional Materials by Understanding the Aggregate State	174
Carbon Dioxide Capture Chemistry of Amino Acid Functionalized Metal–Organic Frameworks in Humid Flue Gas	173
A Perspective on Late-Stage Aromatic C–H Bond Functionalization	173
Molecular Design of Stretchable Polymer Semiconductors: Current Progress and Future Directions	173
Electronic Spin Moment As a Catalytic Descriptor for Fe Single-Atom Catalysts Supported on C2N	172
Electroreductive Carbofunctionalization of Alkenes with Alkyl Bromides via a Radical-Polar Crossover Mechanism	172
Crown Ether Modulation Enables over 23% Efficient Formamidinium-Based Perovskite Solar Cells	171
Operando Investigation of Toluene Oxidation over 1D Pt@CeO2 Derived from Pt Cluster-Containing MOF	170
One-Shot Synthesis of Expanded Heterohelicene Exhibiting Narrowband Thermally Activated Delayed Fluorescence	170
Asymmetric Triple-Atom Sites Confined in Ternary Oxide Enabling Selective CO2 Photothermal Reduction to Acetate	169
Bridging Interparticle Li+ Conduction in a Soft Ceramic Oxide Electrolyte	169
Chlorophyll Derivative-Sensitized TiO2 Electron Transport Layer for Record Efficiency of Cs2AgBiBr6 Double Perovskite Solar Cells	169
Bottom-Up Synthesis of 8-Connected Three-Dimensional Covalent Organic Frameworks for Highly Efficient Ethylene/Ethane Separation	168
Detection of SARS-CoV-2 Viral Particles Using Direct, Reagent-Free Electrochemical Sensing	168
Renal Clearable Ultrasmall Single-Crystal Fe Nanoparticles for Highly Selective and Effective Ferroptosis Therapy and Immunotherapy	168
Non-innocent Radical Ion Intermediates in Photoredox Catalysis: Parallel Reduction Modes Enable Coupling of Diverse Aryl Chlorides	168
Stable Bimetallic Polyphthalocyanine Covalent Organic Frameworks as Superior Electrocatalysts	167
Atomic Indium Catalysts for Switching CO2 Electroreduction Products from Formate to CO	167
Immobilization of Lewis Basic Sites into a Stable Ethane-Selective MOF Enabling One-Step Separation of Ethylene from a Ternary Mixture	166
Electrochemically Enabled, Nickel-Catalyzed Dehydroxylative Cross-Coupling of Alcohols with Aryl Halides	165
Tuning the Intermolecular Electron Transfer of Low-Dimensional and Metal-Free BCN/C60 Electrocatalysts via Interfacial Defects for Efficient Hydrogen and Oxygen Electrochemistry	164
Radical Chain Reduction via Carbon Dioxide Radical Anion (CO2•–)	164
Large Second-Harmonic Response and Giant Birefringence of CeF2(SO4) Induced by Highly Polarizable Polyhedra	164
Intermediate Binding Control Using Metal–Organic Frameworks Enhances Electrochemical CO2 Reduction	163
Multiexcitonic Emission in Zero-Dimensional Cs2ZrCl6:Sb3+ Perovskite Crystals	163
Molecular Pumps and Motors	162
Synergistic Effect of Fluorinated Passivator and Hole Transport Dopant Enables Stable Perovskite Solar Cells with an Efficiency Near 24%	161
Molecular Interaction Regulates the Performance and Longevity of Defect Passivation for Metal Halide Perovskite Solar Cells	161
Dynamically Formed Surfactant Assembly at the Electrified Electrode–Electrolyte Interface Boosting CO2 Electroreduction	161
Nickel–Platinum Nanoparticles as Peroxidase Mimics with a Record High Catalytic Efficiency	160
Maximizing the Synergistic Effect of CoNi Catalyst on α-MoC for Robust Hydrogen Production	160
Impregnating Subnanometer Metallic Nanocatalysts into Self-Pillared Zeolite Nanosheets	160
Hydrogen-Intercalation-Induced Lattice Expansion of Pd@Pt Core–Shell Nanoparticles for Highly Efficient Electrocatalytic Alcohol Oxidation	159
Electrostatic Attraction-Driven Assembly of a Metal–Organic Framework with a Photosensitizer Boosts Photocatalytic CO2 Reduction to CO	159
Chemical Recycling of Polystyrene to Valuable Chemicals via Selective Acid-Catalyzed Aerobic Oxidation under Visible Light	159
“Two Ships in a Bottle” Design for Zn–Ag–O Catalyst Enabling Selective and Long-Lasting CO2 Electroreduction	159
Single-Layered MXene Nanosheets Doping TiO2 for Efficient and Stable Double Perovskite Solar Cells	159
Cascade Reactions by Nitric Oxide and Hydrogen Radical for Anti-Hypoxia Photodynamic Therapy Using an Activatable Photosensitizer	159
General Method for Enantioselective Three-Component Carboarylation of Alkenes Enabled by Visible-Light Dual Photoredox/Nickel Catalysis	158
4CzIPN-tBu-Catalyzed Proton-Coupled Electron Transfer for Photosynthesis of Phosphorylated N-Heteroaromatics	158
Cancer Selective Target Degradation by Folate-Caged PROTACs	157
Covalent Organic Frameworks for Carbon Dioxide Capture from Air	157
Hierarchical Tuning of the Performance of Electrochemical Carbon Dioxide Reduction Using Conductive Two-Dimensional Metallophthalocyanine Based Metal–Organic Frameworks	157
Molecular Sizes and Antibacterial Performance Relationships of Flexible Ionic Liquid Derivatives	157
Regulating the Spin State of FeIII Enhances the Magnetic Effect of the Molecular Catalysis Mechanism	156
Perovskite Quantum Dots Encapsulated in a Mesoporous Metal–Organic Framework as Synergistic Photocathode Materials	156
Chromium Ion Pair Luminescence: A Strategy in Broadband Near-Infrared Light-Emitting Diode Design	155
Pt–Co@Pt Octahedral Nanocrystals: Enhancing Their Activity and Durability toward Oxygen Reduction with an Intermetallic Core and an Ultrathin Shell	155
Unveiling Extreme Photoreduction Potentials of Donor–Acceptor Cyanoarenes to Access Aryl Radicals from Aryl Chlorides	154

Na2S2O8 Nanoparticles Trigger Antitumor Immunotherapy through Reactive Oxygen Species Storm and Surge of Tumor Osmolarity

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