Accounts of Chemical Research

Article	Citations
Heavy-Atom-Free Photosensitizers: From Molecular Design to Applications in the Photodynamic Therapy of Cancer	376
Chemistry of Lipid Nanoparticles for RNA Delivery	342
Strategy for Treatment of Infected Diabetic Foot Ulcers	336
Fused-Ring Electron Acceptors for Photovoltaics and Beyond	294
Advanced Platinum-Based Oxygen Reduction Electrocatalysts for Fuel Cells	292
Radical Carboxylative Cyclizations and Carboxylations with CO2	262
Organocatalytic Atroposelective Synthesis of Indole Derivatives Bearing Axial Chirality: Strategies and Applications	226
Long-Lived Organic Room-Temperature Phosphorescence from Amorphous Polymer Systems	225
Selectivity in Electrochemical CO2 Reduction	222
Supramolecular Purely Organic Room-Temperature Phosphorescence	218
Expanding the Boundary of Biorefinery: Organonitrogen Chemicals from Biomass	213
Chemically Stable Metal–Organic Frameworks: Rational Construction and Application Expansion	213
Data-Driven Strategies for Accelerated Materials Design	208
Achieving High Performance Metal–Organic Framework Materials through Pore Engineering	203
Confinement in a Zeolite and Zeolite Catalysis	198
Metalloporphyrins as Catalytic Models for Studying Hydrogen and Oxygen Evolution and Oxygen Reduction Reactions	196
Reticular Chemistry for Highly Porous Metal–Organic Frameworks: The Chemistry and Applications	195
Navigating the Unnatural Reaction Space: Directed Evolution of Heme Proteins for Selective Carbene and Nitrene Transfer	194
High-Performance Second-Harmonic-Generation (SHG) Materials: New Developments and New Strategies	190
Iron- and Cobalt-Catalyzed Asymmetric Hydrofunctionalization of Alkenes and Alkynes	186
Transition Metal (Ni, Cu, Pd)-Catalyzed Alkene Dicarbofunctionalization Reactions	184
Electrochemical Approaches for CO2 Conversion to Chemicals: A Journey toward Practical Applications	173
Electrolyte Effects on CO2 Electrochemical Reduction to CO	172
Theory of Long-Lived Room-Temperature Phosphorescence in Organic Aggregates	172
Synthetic and Mechanistic Implications of Chlorine Photoelimination in Nickel/Photoredox C(sp3)–H Cross-Coupling	171

Innovative Approaches to Li-Argyrodite Solid Electrolytes for All-Solid-State Lithium Batteries	170
Applications of Deep Learning in Molecule Generation and Molecular Property Prediction	168
Supramolecularly Engineered J-Aggregates Based on Perylene Bisimide Dyes	163
From C4 to C7: Innovative Strategies for Site-Selective Functionalization of Indole C–H Bonds	158
Prospects of an Electroactive Carbon Nanotube Membrane toward Environmental Applications	156
UV/Chlorine Process: An Efficient Advanced Oxidation Process with Multiple Radicals and Functions in Water Treatment	156
Cyclodextrin Metal–Organic Frameworks and Their Applications	154
Chiral Pd-Catalyzed Enantioselective Syntheses of Various N–C Axially Chiral Compounds and Their Synthetic Applications	150
Mechanism-Guided Development of Transition-Metal-Catalyzed C–N Bond-Forming Reactions Using Dioxazolones as the Versatile Amidating Source	150
Azulene-Based π-Functional Materials: Design, Synthesis, and Applications	149
Zeolite Fixed Metal Nanoparticles: New Perspective in Catalysis	149
Layered Oxide Cathodes for Sodium-Ion Batteries: Storage Mechanism, Electrochemistry, and Techno-economics	149
Asymmetric Catalytic Rearrangements with α-Diazocarbonyl Compounds	146
Organocatalytic Enantioselective Synthesis of Axially Chiral Molecules: Development of Strategies and Skeletons	141
Metal Halide Superionic Conductors for All-Solid-State Batteries	140
Thermo-, Electro-, and Photocatalytic CO2 Conversion to Value-Added Products over Porous Metal/Covalent Organic Frameworks	138
Design Strategy of Fluorescent Probes for Live Drug-Induced Acute Liver Injury Imaging	137
Programmable Morphing Hydrogels for Soft Actuators and Robots: From Structure Designs to Active Functions	137
Exploring Multifunctional Hydrogen-Bonded Organic Framework Materials	135
Giant Rylene Imide-Based Electron Acceptors for Organic Photovoltaics	135
2-(Pyridin-2-yl)isopropyl (PIP) Amine: An Enabling Directing Group for Divergent and Asymmetric Functionalization of Unactivated Methylene C(sp3)–H Bonds	134
2D Conjugated Covalent Organic Frameworks: Defined Synthesis and Tailor-Made Functions	133
Rational Design of Electrochemiluminescent Devices	133
Heterogeneous Molecular Catalysts of Metal Phthalocyanines for Electrochemical CO2 Reduction Reactions	133
Bioinspired Applications of Porphyrin Derivatives	130
Lithium–Air Batteries: Air-Electrochemistry and Anode Stabilization	130
Carbon Shell on Active Nanocatalyst for Stable Electrocatalysis	128
Promoting Rechargeable Batteries Operated at Low Temperature	127
Issues and Advances in Scaling up Sulfide-Based All-Solid-State Batteries	126
Alkyne-Palladium(II)-Catalyzed Living Polymerization of Isocyanides: An Exploration of Diverse Structures and Functions	124
Making ATRP More Practical: Oxygen Tolerance	124
Reductive Cross-Coupling of Unreactive Electrophiles	123
Atropisomerism in the Pharmaceutically Relevant Realm	122
Halide Ion Migration in Perovskite Nanocrystals and Nanostructures	119
The RaPID Platform for the Discovery of Pseudo-Natural Macrocyclic Peptides	118
CO2 Reduction Using Water as an Electron Donor over Heterogeneous Photocatalysts Aiming at Artificial Photosynthesis	117
Lipid Nanoparticle–mRNA Formulations for Therapeutic Applications	115
Strategies to Combat Multi-Drug Resistance in Tuberculosis	112
Supramolecular Chirality in Metal–Organic Complexes	112
n-Type Organic and Polymeric Semiconductors Based on Bithiophene Imide Derivatives	111
Stimuli-Responsive Crystalline Smart Materials: From Rational Design and Fabrication to Applications	109
Nano–Bio Interactions in Cancer: From Therapeutics Delivery to Early Detection	108
Engineering Catalyst–Electrolyte Microenvironments to Optimize the Activity and Selectivity for the Electrochemical Reduction of CO2 on Cu and Ag	107
Exploiting Heavier Organochalcogen Compounds in Donor–Acceptor Cyclopropane Chemistry	106
Photobiocatalysis for Abiological Transformations	105
Chemical Interface Damping of Surface Plasmon Resonances	104
Exotic Topological Bands and Quantum States in Metal–Organic and Covalent–Organic Frameworks	103
Modular Organoboron Catalysts Enable Transformations with Unprecedented Reactivity	103
Selenium-Containing Organic Photovoltaic Materials	103
Carboxylic Acids as Adaptive Functional Groups in Metallaphotoredox Catalysis	103

Ferritin: A Multifunctional Nanoplatform for Biological Detection, Imaging Diagnosis, and Drug Delivery	103
NiH-Catalyzed Functionalization of Remote and Proximal Olefins: New Reactions and Innovative Strategies	102
Tetracoordinate Boron Intermediates Enable Unconventional Transformations	102
Copper-Catalyzed Carbonylative Coupling of Alkyl Halides	102
Current Strategies for Modulating Aβ Aggregation with Multifunctional Agents	99
Ultralong Organic Phosphorescence: From Material Design to Applications	99
Development and Evolution of Energetic Cocrystals	99
Aromatic π-Components for Enantioselective Heck Reactions and Heck/Anion-Capture Domino Sequences	98
Enantioselective Synthesis of Atropisomers via Vinylidene ortho-Quinone Methides (VQMs)	97
Development of Multimodal Machine Learning Potentials: Toward a Physics-Aware Artificial Intelligence	97
Dynamic Core–Shell and Alloy Structures of Multimetallic Nanomaterials and Their Catalytic Synergies	95
Effect of Surface Ligands in Perovskite Nanocrystals: Extending in and Reaching out	95
Transition Metal-Catalyzed Biaryl Atropisomer Synthesis via a Torsional Strain Promoted Ring-Opening Reaction	94
Fuzziness and Frustration in the Energy Landscape of Protein Folding, Function, and Assembly	94
Autonomous Chemical Experiments: Challenges and Perspectives on Establishing a Self-Driving Lab	93
The Optoelectronic Nose	93
Functional Regulation and Stability Engineering of Three-Dimensional Covalent Organic Frameworks	92
Advanced Pt-Based Core–Shell Electrocatalysts for Fuel Cell Cathodes	92
Time and Pot Economy in Total Synthesis	91
Non-liver mRNA Delivery	90
A Strategy for Selective Catalytic B–H Functionalization of o-Carboranes	90
Hierarchically Porous MOFs Synthesized by Soft-Template Strategies	89
Energy-Transfer-Enabled Dearomative Cycloaddition Reactions of Indoles/Pyrroles via Excited-State Aromatics	88
Photocatalytic Systems for CO2 Reduction: Metal-Complex Photocatalysts and Their Hybrids with Photofunctional Solid Materials	87
Predicting Reaction Yields via Supervised Learning	87
Stimuli-Induced Reversible Proton Transfer for Stimuli-Responsive Materials and Devices	87
Pillararene-Inspired Macrocycles: From Extended Pillar[n]arenes to Geminiarenes	87
Self-Assembling Supramolecular Dendrimers for Biomedical Applications: Lessons Learned from Poly(amidoamine) Dendrimers	86
Biphen[n]arenes: Modular Synthesis, Customizable Cavity Sizes, and Diverse Skeletons	85
Two-Dimensional Nanofluidic Membranes toward Harvesting Salinity Gradient Power	85
Reimagining Druggability Using Chemoproteomic Platforms	85
Achieving Efficient n-Doping of Conjugated Polymers by Molecular Dopants	84
The Surface Chemistry and Structure of Colloidal Lead Halide Perovskite Nanocrystals	84
The Discovery of Multifunctional Chiral P Ligands for the Catalytic Construction of Quaternary Carbon/Silicon and Multiple Stereogenic Centers	83
Plasma-Enhanced Chemical Vapor Deposition of Two-Dimensional Materials for Applications	83
The Pauli Repulsion-Lowering Concept in Catalysis	82
Opportunity of Atomically Thin Two-Dimensional Catalysts for Promoting CO2 Electroreduction	82
Large Cages of Zeolitic Imidazolate Frameworks	81
Methane Oxidation to Methanol in Water	81
Intrinsically Porous Molecular Materials (IPMs) for Natural Gas and Benzene Derivatives Separations	80
N-Triftosylhydrazones: A New Chapter for Diazo-Based Carbene Chemistry	80
Molecular Triangles: A New Class of Macrocycles	80
N-Functionalized Pyridinium Salts: A New Chapter for Site-Selective Pyridine C–H Functionalization via Radical-Based Processes under Visible Light Irradiation	79
Developing Biodegradable Lipid Nanoparticles for Intracellular mRNA Delivery and Genome Editing	79
General-Purpose Machine Learning Potentials Capturing Nonlocal Charge Transfer	79
The Importance of Highly Connected Building Units in Reticular Chemistry: Thoughtful Design of Metal–Organic Frameworks	78
Double-Cable Conjugated Polymers with Pendant Rylene Diimides for Single-Component Organic Solar Cells	78
Manipulating the Dynamics of Dark Excited States in Organic Materials for Phototheranostics	78
Emerging Electrochemical Techniques for Probing Site Behavior in Single-Atom Electrocatalysts	77
Toward the Copolymerization of Propylene with Polar Comonomers	77
Mimicking Color-Changing Organisms to Enable the Multicolors and Multifunctions of Smart Fluorescent Polymeric Hydrogels	77
From Low to No O2-Dependent Hypoxia Photodynamic Therapy (hPDT): A New Perspective	76
Fluorescent Probes for Biological Species and Microenvironments: from Rational Design to Bioimaging Applications	76
Enzyme-Laden Bioactive Hydrogel for Biocatalytic Monitoring and Regulation	76
Large π-Extended and Curved Carbon Nanorings as Carbon Nanotube Segments	75
Bioinspired Superspreading Surface: From Essential Mechanism to Application	75
Excited-State Engineering in Heteroleptic Ionic Iridium(III) Complexes	75
Inorganometallic Photocatalyst for CO2 Reduction	74
Corannulene: A Curved Polyarene Building Block for the Construction of Functional Materials	74
Catalytic Chemo- and Enantioselective Transformations of gem-Diborylalkanes and (Diborylmethyl)metallic Species	73
Fluorination Promotes the Cytosolic Delivery of Genes, Proteins, and Peptides	72
Palladium-Catalyzed Enantioselective β-C(sp3)–H Activation Reactions of Aliphatic Acids: A Retrosynthetic Surrogate for Enolate Alkylation and Conjugate Addition	72
Charge Transport in Organic Semiconductors: The Perspective from Nonadiabatic Molecular Dynamics	72
Visualizing the Sensitive Lithium with Atomic Precision: Cryogenic Electron Microscopy for Batteries	71
Tumor-Targeted Nanomedicine for Immunotherapy	71
Theories for Electrolyte Effects in CO2 Electroreduction	71
A Type of Structurally Adaptable Aromatic Spiroketal Based Chiral Diphosphine Ligands in Asymmetric Catalysis	71
Nickel-Catalyzed Reductive Carboxylation and Amidation Reactions	70
Recent Advances in Theoretical Studies on Transition-Metal-Catalyzed Carbene Transformations	70
Modulation of Metal Halide Structural Units for Light Emission	70
Fluorescent Probes for Lipid Membranes: From the Cell Surface to Organelles	69
Metal-Free Organic Phosphors toward Fast and Efficient Room-Temperature Phosphorescence	69
Atropisomers with Axial and Point Chirality: Synthesis and Applications	69
Symmetry-Breaking Sites for Activating Linear Carbon Dioxide Molecules	69
The Genesis of Molecular Volcano Plots	69
Functional Nucleic Acids for Pathogenic Bacteria Detection	69
Zirconium Metal–Organic Cages: Synthesis and Applications	68
Digitizing Chemistry Using the Chemical Processing Unit: From Synthesis to Discovery	68
Guiding CO2RR Selectivity by Compositional Tuning in the Electrochemical Double Layer	68
Oriented Attachment: From Natural Crystal Growth to a Materials Engineering Tool	68

Design Principles for Efficient and Stable Water Splitting Photoelectrocatalysts	68
Nickel-Catalyzed Ligand-Controlled Selective Reductive Cyclization/Cross-Couplings	67
Strategies for the Photocatalytic Generation of Carbanion Equivalents for Reductant-Free C–C Bond Formations	67
Adsorption Enthalpies for Catalysis Modeling through Machine-Learned Descriptors	67
Asymmetric Synthesis of Fluoro, Fluoromethyl, Difluoromethyl, and Trifluoromethylcyclopropanes	66
4D-STEM of Beam-Sensitive Materials	66
High-Throughput Raman Flow Cytometry and Beyond	66
Cobalt Carbide Nanocatalysts for Efficient Syngas Conversion to Value-Added Chemicals with High Selectivity	66
DNA G-Quadruplex in Human Telomeres and Oncogene Promoters: Structures, Functions, and Small Molecule Targeting	66
Automated Experimentation Powers Data Science in Chemistry	65
CO2 Electrolysis System under Industrially Relevant Conditions	65
Black-Box Optimization for Automated Discovery	65
N–O Bond Activation by Energy Transfer Photocatalysis	64
Advances in Molecular Understanding of α-Helical Membrane-Active Peptides	64
Solar-Driven CO2 Reduction Using a Semiconductor/Molecule Hybrid Photosystem: From Photocatalysts to a Monolithic Artificial Leaf	64
Ionic-Liquid-Catalyzed Approaches under Metal-Free Conditions	64
LAURDAN since Weber: The Quest for Visualizing Membrane Heterogeneity	64
Importance of Engineered and Learned Molecular Representations in Predicting Organic Reactivity, Selectivity, and Chemical Properties	63
Collective Behaviors of Magnetic Active Matter: Recent Progress toward Reconfigurable, Adaptive, and Multifunctional Swarming Micro/Nanorobots	63
Anion-Coordination-Driven Assembly	62
The Dawn of Metal-Oxo Clusters as Artificial Proteases: From Discovery to the Present and Beyond	62
The Power of Fiber Twist	62
Enhancing Triplet–Triplet Annihilation Upconversion: From Molecular Design to Present Applications	61
Immunogenicity of In Vitro-Transcribed RNA	61
Alkylammonium Halides for Facet Reconstruction and Shape Modulation in Lead Halide Perovskite Nanocrystals	60
Cross-Coupling Reactions of Nitroarenes	60
Local Polarity-Induced Assembly of Second-Order Nonlinear Optical Materials	60
Chemoenzymatic Total Synthesis of Natural Products	60
Synergic Heterodinuclear Catalysts for the Ring-Opening Copolymerization (ROCOP) of Epoxides, Carbon Dioxide, and Anhydrides	59
Learning to Approximate Density Functionals	59
Photoreactive Crystals Exhibiting [2 + 2] Photocycloaddition Reaction and Dynamic Effects	59
Deconstructive Synthesis of Bridged and Fused Rings via Transition-Metal-Catalyzed “Cut-and-Sew” Reactions of Benzocyclobutenones and Cyclobutanones	59
Molecular Insight into Efficient Charge Generation in Low-Driving-Force Nonfullerene Organic Solar Cells	59
Self-Assembly and Regrowth of Metal Halide Perovskite Nanocrystals for Optoelectronic Applications	58
Toward an Atomic-Level Understanding of Ceria-Based Catalysts: When Experiment and Theory Go Hand in Hand	58
Modeling Non-adiabatic Dynamics in Nanoscale and Condensed Matter Systems	58
Electronic Structure-Based Descriptors for Oxide Properties and Functions	58
A Journey in Lanthanide Coordination Chemistry: From Evaporable Dimers to Magnetic Materials and Luminescent Devices	58
Synthesis of C2+ Chemicals from CO2 and H2 via C–C Bond Formation	58
Road Map for the Construction of High-Valued N-Heterocycles via Denitrogenative Annulation	57
Fundamentals of the Intrinsic DNA Fluorescence	57
Degradable Vinyl Polymers for Combating Marine Biofouling	57
Data Science Meets Physical Organic Chemistry	57
Rhodium-Catalyzed C–H Alkenylation/Electrocyclization Cascade Provides Dihydropyridines That Serve as Versatile Intermediates to Diverse Nitrogen Heterocycles	57
Emergence of Pyrimidine-Based meta-Directing Group: Journey from Weak to Strong Coordination in Diversifying meta-C–H Functionalization	56
Shaping Copper Nanocatalysts to Steer Selectivity in the Electrochemical CO2 Reduction Reaction	56
Photothermal Nanomaterial-Mediated Photoporation	56
Macrocyclic Supramolecular Assemblies Based on Hyaluronic Acid and Their Biological Applications	56
Multiplexed Biosensing and Bioimaging Using Lanthanide-Based Time-Gated Förster Resonance Energy Transfer	55
Electron-rich Coordination Receptors Based on Tetrathiafulvalene Derivatives: Controlling the Host–Guest Binding	55
Principles of Cation−π Interactions for Engineering Mussel-Inspired Functional Materials	55
Electroinduced Surfactant Self-Assembly Driven to Vertical Growth of Oriented Mesoporous Films	55
Macrocycle-Based Solid-State Supramolecular Polymers	55
Glycosyl Oxocarbenium Ions: Structure, Conformation, Reactivity, and Interactions	55
A New Paradigm in Enantioselective Cobalt Catalysis: Cationic Cobalt(I) Catalysts for Heterodimerization, Cycloaddition, and Hydrofunctionalization Reactions of Olefins	54
Boron-Doped Diamond Electrodes: Fundamentals for Electrochemical Applications	54
Plasmon-Driven Chemistry on Mono- and Bimetallic Nanostructures	54
Nonprecious Metal Borides: Emerging Electrocatalysts for Hydrogen Production	54
Local Charge Distributions, Electric Dipole Moments, and Local Electric Fields Influence Reactivity Patterns and Guide Regioselectivities in α-Ketoglutarate-Dependent Non-heme Iron Dioxygenases	54
Layered Hybrid Formamidinium Lead Iodide Perovskites: Challenges and Opportunities	54
Bringing Inherent Charges into Aggregation-Induced Emission Research	53
Indane-Based Chiral Aryl Chalcogenide Catalysts: Development and Applications in Asymmetric Electrophilic Reactions	53
Quantum Dots: A Promising Fluorescent Label for Probing Virus Trafficking	53
Lessons from Natural Product Total Synthesis: Macrocyclization and Postcyclization Strategies	53
Wearable E-Textiles Using a Textile-Centric Design Approach	53
Facilitating Compound Entry as a Means to Discover Antibiotics for Gram-Negative Bacteria	53
Dendritic Fibrous Nanosilica: Discovery, Synthesis, Formation Mechanism, Catalysis, and CO2 Capture–Conversion	53
Manipulating Particle Chemistry for Hollow Carbon-based Nanospheres: Synthesis Strategies, Mechanistic Insights, and Electrochemical Applications	52
Rotaxane Dendrimers: Alliance between Giants	52
Atropisomerism in Drug Discovery: A Medicinal Chemistry Perspective Inspired by Atropisomeric Class I PI3K Inhibitors	52
Transition-Metal Chemistry of the Heavier Alkaline Earth Atoms Ca, Sr, and Ba	52
Ideality in Context: Motivations for Total Synthesis	52
Enabling Multiplexed Electrochemical Detection of Biomarkers with High Sensitivity in Complex Biological Samples	52
Mechanistic Diversity of Low-Valent Chromium Catalysis: Cross-Coupling and Hydrofunctionalization	52
Catalyst Control over Twofold and Higher-Order Stereogenicity by Atroposelective Arene Formation	52
The Chemistry and Applications of Heteroisoindigo Units as Enabling Links for Semiconducting Materials	51
Transformations of Ionic Nanocrystals via Full and Partial Ion Exchange Reactions	51
Metal Nanoparticles Immobilized on Molecularly Modified Surfaces: Versatile Catalytic Systems for Controlled Hydrogenation and Hydrogenolysis	51
Metalla-aromatics: Planar, Nonplanar, and Spiro	51
Two-Dimensional Nanomaterial-Templated Composites	50
Exploiting Photoionization Reflectron Time-of-Flight Mass Spectrometry to Explore Molecular Mass Growth Processes to Complex Organic Molecules in Interstellar and Solar System Ice Analogs	50
Understanding Discrete Growth in Semiconductor Nanocrystals: Nanoplatelets and Magic-Sized Clusters	50
Exploiting Plasmonic Hot Spots in Au-Based Nanostructures for Sensing and Photocatalysis	50
Advancing X-ray Luminescence for Imaging, Biosensing, and Theragnostics	50
The Future of Ligand Engineering in Colloidal Semiconductor Nanocrystals	50
Merging Carbonyl Addition with Photocatalysis	50
Considering the Influence of Polymer–Catalyst Interactions on the Chemical Microenvironment of Electrocatalysts for the CO2 Reduction Reaction	50
Diversity and Tailorability of Photoelectrochemical Properties of Carbon Dots	50
Lewis Base–Boryl Radicals Enabled Borylation Reactions and Selective Activation of Carbon–Heteroatom Bonds	49
Heme Detoxification in the Malaria Parasite: A Target for Antimalarial Drug Development	49
Nitrogen-Containing Perylene Diimides: Molecular Design, Robust Aggregated Structures, and Advances in n-Type Organic Semiconductors	49
From Macrocycles to Quantum Rings: Does Aromaticity Have a Size Limit?	49
Membranized Coacervate Microdroplets: from Versatile Protocell Models to Cytomimetic Materials	49
On the Role of Flexibility for Adsorptive Separation	49
SARS-CoV-2 Main Protease Drug Design, Assay Development, and Drug Resistance Studies	48