Accounts of Chemical Research

Article	Citations
Heavy-Atom-Free Photosensitizers: From Molecular Design to Applications in the Photodynamic Therapy of Cancer	339
Strategy for Treatment of Infected Diabetic Foot Ulcers	299
Chemistry of Lipid Nanoparticles for RNA Delivery	288
Fused-Ring Electron Acceptors for Photovoltaics and Beyond	282
Transition Metal-Catalyzed Tandem Reactions of Ynamides for Divergent N-Heterocycle Synthesis	273
Advanced Platinum-Based Oxygen Reduction Electrocatalysts for Fuel Cells	267
Radical Carboxylative Cyclizations and Carboxylations with CO2	238
Cross-Electrophile Couplings of Activated and Sterically Hindered Halides and Alcohol Derivatives	236
New Perspectives to Trigger and Modulate Circularly Polarized Luminescence of Complex and Aggregated Systems: Energy Transfer, Photon Upconversion, Charge Transfer, and Organic Radical	232
Radical-Mediated Remote Functional Group Migration	221
Supramolecular Purely Organic Room-Temperature Phosphorescence	201
Expanding the Boundary of Biorefinery: Organonitrogen Chemicals from Biomass	195
Selectivity in Electrochemical CO2 Reduction	193
Long-Lived Organic Room-Temperature Phosphorescence from Amorphous Polymer Systems	193
Organocatalytic Atroposelective Synthesis of Indole Derivatives Bearing Axial Chirality: Strategies and Applications	193
Data-Driven Strategies for Accelerated Materials Design	190
Chemically Stable Metal–Organic Frameworks: Rational Construction and Application Expansion	189
Polymer Acceptors Containing B←N Units for Organic Photovoltaics	188
Atomic Insights into the Fundamental Interactions in Lithium Battery Electrolytes	184
Confinement in a Zeolite and Zeolite Catalysis	180
Achieving High Performance Metal–Organic Framework Materials through Pore Engineering	179
Reticular Chemistry for Highly Porous Metal–Organic Frameworks: The Chemistry and Applications	178
Navigating the Unnatural Reaction Space: Directed Evolution of Heme Proteins for Selective Carbene and Nitrene Transfer	178
Mixed Electronic States in Molecular Dimers: Connecting Singlet Fission, Excimer Formation, and Symmetry-Breaking Charge Transfer	175
High-Performance Second-Harmonic-Generation (SHG) Materials: New Developments and New Strategies	175

Metalloporphyrins as Catalytic Models for Studying Hydrogen and Oxygen Evolution and Oxygen Reduction Reactions	174
Designing High Performance Organic Batteries	171
Iron- and Cobalt-Catalyzed Asymmetric Hydrofunctionalization of Alkenes and Alkynes	171
Covalent Organic Frameworks: Pore Design and Interface Engineering	167
Three-Dimensional Covalent Organic Frameworks: From Topology Design to Applications	166
Transition Metal (Ni, Cu, Pd)-Catalyzed Alkene Dicarbofunctionalization Reactions	165
Eutectic Electrolytes as a Promising Platform for Next-Generation Electrochemical Energy Storage	163
Theory of Long-Lived Room-Temperature Phosphorescence in Organic Aggregates	161
Synthetic and Mechanistic Implications of Chlorine Photoelimination in Nickel/Photoredox C(sp3)–H Cross-Coupling	158
Supramolecularly Engineered J-Aggregates Based on Perylene Bisimide Dyes	155
Applications of Deep Learning in Molecule Generation and Molecular Property Prediction	155
Prospects of an Electroactive Carbon Nanotube Membrane toward Environmental Applications	154
Metal-Catalyzed Approaches toward the Oxindole Core	151
Innovative Approaches to Li-Argyrodite Solid Electrolytes for All-Solid-State Lithium Batteries	149
Electrolyte Effects on CO2 Electrochemical Reduction to CO	148
UV/Chlorine Process: An Efficient Advanced Oxidation Process with Multiple Radicals and Functions in Water Treatment	144
From C4 to C7: Innovative Strategies for Site-Selective Functionalization of Indole C–H Bonds	144
Electrochemical Approaches for CO2 Conversion to Chemicals: A Journey toward Practical Applications	143
Nanoscale Metal–Organic Frameworks for Cancer Immunotherapy	141
Mechanism-Guided Development of Transition-Metal-Catalyzed C–N Bond-Forming Reactions Using Dioxazolones as the Versatile Amidating Source	140
Chiral Pd-Catalyzed Enantioselective Syntheses of Various N–C Axially Chiral Compounds and Their Synthetic Applications	140
Engineered Nanoparticles for Cancer Vaccination and Immunotherapy	140
Cyclodextrin Metal–Organic Frameworks and Their Applications	139
Silica-Based Nanoparticles for Biomedical Applications: From Nanocarriers to Biomodulators	138
Azulene-Based π-Functional Materials: Design, Synthesis, and Applications	138
Hydrogen Generation upon Nanocatalyzed Hydrolysis of Hydrogen-Rich Boron Derivatives: Recent Developments	131
Zeolite Fixed Metal Nanoparticles: New Perspective in Catalysis	131
Giant Rylene Imide-Based Electron Acceptors for Organic Photovoltaics	130
2-(Pyridin-2-yl)isopropyl (PIP) Amine: An Enabling Directing Group for Divergent and Asymmetric Functionalization of Unactivated Methylene C(sp3)–H Bonds	128
Asymmetric Catalytic Rearrangements with α-Diazocarbonyl Compounds	128
Design Strategy of Fluorescent Probes for Live Drug-Induced Acute Liver Injury Imaging	127
Lanthanide-Activated Nanoparticles: A Toolbox for Bioimaging, Therapeutics, and Neuromodulation	127
N-Heterocyclic Carbenes: A Door Open to Supramolecular Organometallic Chemistry	125
Palladium-Catalyzed Asymmetric Allylic C–H Functionalization: Mechanism, Stereo- and Regioselectivities, and Synthetic Applications	125
Rational Design of Electrochemiluminescent Devices	124
Chiral Induced Spin Selectivity Gives a New Twist on Spin-Control in Chemistry	122
Metal Halide Superionic Conductors for All-Solid-State Batteries	122
Thermo-, Electro-, and Photocatalytic CO2 Conversion to Value-Added Products over Porous Metal/Covalent Organic Frameworks	121
Lithium–Air Batteries: Air-Electrochemistry and Anode Stabilization	121
Heterogeneous Molecular Catalysts of Metal Phthalocyanines for Electrochemical CO2 Reduction Reactions	119
How the Ligand Field in Lanthanide Coordination Complexes Determines Magnetic Susceptibility Anisotropy, Paramagnetic NMR Shift, and Relaxation Behavior	119
Programmable Morphing Hydrogels for Soft Actuators and Robots: From Structure Designs to Active Functions	119
Bioinspired Applications of Porphyrin Derivatives	118
Organocatalytic Enantioselective Synthesis of Axially Chiral Molecules: Development of Strategies and Skeletons	117
Making ATRP More Practical: Oxygen Tolerance	115
Issues and Advances in Scaling up Sulfide-Based All-Solid-State Batteries	114
2D Conjugated Covalent Organic Frameworks: Defined Synthesis and Tailor-Made Functions	114
Halide Ion Migration in Perovskite Nanocrystals and Nanostructures	113
Exploring Multifunctional Hydrogen-Bonded Organic Framework Materials	113
Carbon Shell on Active Nanocatalyst for Stable Electrocatalysis	112

Promoting Rechargeable Batteries Operated at Low Temperature	112
Alkyne-Palladium(II)-Catalyzed Living Polymerization of Isocyanides: An Exploration of Diverse Structures and Functions	111
Layered Oxide Cathodes for Sodium-Ion Batteries: Storage Mechanism, Electrochemistry, and Techno-economics	110
n-Type Organic and Polymeric Semiconductors Based on Bithiophene Imide Derivatives	109
Vanadium-Based Materials: Next Generation Electrodes Powering the Battery Revolution?	104
Supramolecular Chirality in Metal–Organic Complexes	104
The RaPID Platform for the Discovery of Pseudo-Natural Macrocyclic Peptides	103
Nano–Bio Interactions in Cancer: From Therapeutics Delivery to Early Detection	102
Lipid Nanoparticle–mRNA Formulations for Therapeutic Applications	101
Atropisomerism in the Pharmaceutically Relevant Realm	101
Exploiting Heavier Organochalcogen Compounds in Donor–Acceptor Cyclopropane Chemistry	99
Reductive Cross-Coupling of Unreactive Electrophiles	98
Modular Organoboron Catalysts Enable Transformations with Unprecedented Reactivity	98
CO2 Reduction Using Water as an Electron Donor over Heterogeneous Photocatalysts Aiming at Artificial Photosynthesis	98
New Multiphase Chemical Processes Influencing Atmospheric Aerosols, Air Quality, and Climate in the Anthropocene	98
Engineering Catalyst–Electrolyte Microenvironments to Optimize the Activity and Selectivity for the Electrochemical Reduction of CO2 on Cu and Ag	97
Engineering of Norbornadiene/Quadricyclane Photoswitches for Molecular Solar Thermal Energy Storage Applications	97
Chemical Interface Damping of Surface Plasmon Resonances	97
Selenium-Containing Organic Photovoltaic Materials	96
Exotic Topological Bands and Quantum States in Metal–Organic and Covalent–Organic Frameworks	96
Tetracoordinate Boron Intermediates Enable Unconventional Transformations	95
Photobiocatalysis for Abiological Transformations	95
Strategies to Combat Multi-Drug Resistance in Tuberculosis	95
Current Strategies for Modulating Aβ Aggregation with Multifunctional Agents	94
Development and Evolution of Energetic Cocrystals	93
Molecular Photoswitching in Confined Spaces	93
Copper-Catalyzed Carbonylative Coupling of Alkyl Halides	93
Fuzziness and Frustration in the Energy Landscape of Protein Folding, Function, and Assembly	92
Metal Chalcogenide Supertetrahedral Clusters: Synthetic Control over Assembly, Dispersibility, and Their Functional Applications	91
Local and Targeted Delivery of Immune Checkpoint Blockade Therapeutics	91
Ferritin: A Multifunctional Nanoplatform for Biological Detection, Imaging Diagnosis, and Drug Delivery	90
Solvation and Mobilization of Copper Active Sites in Zeolites by Ammonia: Consequences for the Catalytic Reduction of Nitrogen Oxides	90
The Prodigious Hydrogen Bonds with Sulfur and Selenium in Molecular Assemblies, Structural Biology, and Functional Materials	90
Dynamic Core–Shell and Alloy Structures of Multimetallic Nanomaterials and Their Catalytic Synergies	89
Effect of Surface Ligands in Perovskite Nanocrystals: Extending in and Reaching out	89
Development of Multimodal Machine Learning Potentials: Toward a Physics-Aware Artificial Intelligence	88
Electrochemical Conversion of CO2 to Syngas with Palladium-Based Electrocatalysts	88
The Role of Carbonate in Catalytic Oxidations	88
Stimuli-Responsive Crystalline Smart Materials: From Rational Design and Fabrication to Applications	86
NiH-Catalyzed Functionalization of Remote and Proximal Olefins: New Reactions and Innovative Strategies	85
NMR Calculations with Quantum Methods: Development of New Tools for Structural Elucidation and Beyond	85
Aromatic π-Components for Enantioselective Heck Reactions and Heck/Anion-Capture Domino Sequences	84
Stimuli-Induced Reversible Proton Transfer for Stimuli-Responsive Materials and Devices	84
Biomaterials as Local Niches for Immunomodulation	84
Time and Pot Economy in Total Synthesis	83
Advanced Pt-Based Core–Shell Electrocatalysts for Fuel Cell Cathodes	82
A Strategy for Selective Catalytic B–H Functionalization of o-Carboranes	82
Crystal Phase Control of Gold Nanomaterials by Wet-Chemical Synthesis	82
Organogermanes as Orthogonal Coupling Partners in Synthesis and Catalysis	81
Predicting Reaction Yields via Supervised Learning	81
Transition Metal-Catalyzed Biaryl Atropisomer Synthesis via a Torsional Strain Promoted Ring-Opening Reaction	80
Enantioselective Synthesis of Atropisomers via Vinylidene ortho-Quinone Methides (VQMs)	80
The Surface Chemistry and Structure of Colloidal Lead Halide Perovskite Nanocrystals	79
Development of Triggerable, Trackable, and Targetable Carbon Monoxide Releasing Molecules	79
Ultralong Organic Phosphorescence: From Material Design to Applications	79
Carboxylic Acids as Adaptive Functional Groups in Metallaphotoredox Catalysis	78
Yne–Enones Enable Diversity-Oriented Catalytic Cascade Reactions: A Rapid Assembly of Complexity	78
Fluorinated Ylides/Carbenes and Related Intermediates from Phosphonium/Sulfonium Salts	78
Plasma-Enhanced Chemical Vapor Deposition of Two-Dimensional Materials for Applications	78
Self-Assembling Supramolecular Dendrimers for Biomedical Applications: Lessons Learned from Poly(amidoamine) Dendrimers	78
Opportunity of Atomically Thin Two-Dimensional Catalysts for Promoting CO2 Electroreduction	78
N-Triftosylhydrazones: A New Chapter for Diazo-Based Carbene Chemistry	78
The Optoelectronic Nose	78
Latest Advances in Flexible Symmetric Supercapacitors: From Material Engineering to Wearable Applications	77
Large Cages of Zeolitic Imidazolate Frameworks	77
Non-liver mRNA Delivery	77
Neutral Nickel(II) Catalysts: From Hyperbranched Oligomers to Nanocrystal-Based Materials	77
Two-Dimensional Nanofluidic Membranes toward Harvesting Salinity Gradient Power	77
Photocatalytic Systems for CO2 Reduction: Metal-Complex Photocatalysts and Their Hybrids with Photofunctional Solid Materials	77
Recent Advances in Stimuli-Responsive Platforms for Cancer Immunotherapy	76
Biphen[n]arenes: Modular Synthesis, Customizable Cavity Sizes, and Diverse Skeletons	76
The Pauli Repulsion-Lowering Concept in Catalysis	76
Toward the Copolymerization of Propylene with Polar Comonomers	76
Molecular Triangles: A New Class of Macrocycles	75
Methane Oxidation to Methanol in Water	75
Double-Cable Conjugated Polymers with Pendant Rylene Diimides for Single-Component Organic Solar Cells	75
Energy-Transfer-Enabled Dearomative Cycloaddition Reactions of Indoles/Pyrroles via Excited-State Aromatics	74
Achieving Efficient n-Doping of Conjugated Polymers by Molecular Dopants	74
The Importance of Highly Connected Building Units in Reticular Chemistry: Thoughtful Design of Metal–Organic Frameworks	74
Intrinsically Porous Molecular Materials (IPMs) for Natural Gas and Benzene Derivatives Separations	74

Cobalt-Catalyzed Cross-Couplings between Alkyl Halides and Grignard Reagents	74
General-Purpose Machine Learning Potentials Capturing Nonlocal Charge Transfer	73
Autonomous Chemical Experiments: Challenges and Perspectives on Establishing a Self-Driving Lab	73
Pillararene-Inspired Macrocycles: From Extended Pillar[n]arenes to Geminiarenes	73
Mapping Materials and Molecules	73
Reimagining Druggability Using Chemoproteomic Platforms	73
Functional Regulation and Stability Engineering of Three-Dimensional Covalent Organic Frameworks	73
Excitons and Polarons in Organic Materials	72
The Discovery of Multifunctional Chiral P Ligands for the Catalytic Construction of Quaternary Carbon/Silicon and Multiple Stereogenic Centers	72
Mimicking Color-Changing Organisms to Enable the Multicolors and Multifunctions of Smart Fluorescent Polymeric Hydrogels	72
Density Functional Theory Based Methods for the Calculation of X-ray Spectroscopy	72
Hierarchically Porous MOFs Synthesized by Soft-Template Strategies	71
Enzyme-Laden Bioactive Hydrogel for Biocatalytic Monitoring and Regulation	71
Manipulating the Dynamics of Dark Excited States in Organic Materials for Phototheranostics	71
Developing Biodegradable Lipid Nanoparticles for Intracellular mRNA Delivery and Genome Editing	71
Large-Scale Atomic Simulation via Machine Learning Potentials Constructed by Global Potential Energy Surface Exploration	71
N-Functionalized Pyridinium Salts: A New Chapter for Site-Selective Pyridine C–H Functionalization via Radical-Based Processes under Visible Light Irradiation	70
Low Temperature Activation of Methane on Metal-Oxides and Complex Interfaces: Insights from Surface Science	70
Inorganometallic Photocatalyst for CO2 Reduction	70
Excited-State Engineering in Heteroleptic Ionic Iridium(III) Complexes	70
Large π-Extended and Curved Carbon Nanorings as Carbon Nanotube Segments	69
Bifunctional Iminophosphorane Superbase Catalysis: Applications in Organic Synthesis	69
Emerging Electrochemical Techniques for Probing Site Behavior in Single-Atom Electrocatalysts	68
Bioinspired Superspreading Surface: From Essential Mechanism to Application	68
Carbon Nanotube Photoluminescence Modulation by Local Chemical and Supramolecular Chemical Functionalization	67
Recent Advances in Theoretical Studies on Transition-Metal-Catalyzed Carbene Transformations	67
A Type of Structurally Adaptable Aromatic Spiroketal Based Chiral Diphosphine Ligands in Asymmetric Catalysis	66
Polymerized Molecular Receptors as Adsorbents to Remove Micropollutants from Water	66
Tumor-Targeted Nanomedicine for Immunotherapy	66
From Low to No O2-Dependent Hypoxia Photodynamic Therapy (hPDT): A New Perspective	65
Corannulene: A Curved Polyarene Building Block for the Construction of Functional Materials	65
Fluorescent Probes for Biological Species and Microenvironments: from Rational Design to Bioimaging Applications	65
Oriented Attachment: From Natural Crystal Growth to a Materials Engineering Tool	65
Strategies for the Photocatalytic Generation of Carbanion Equivalents for Reductant-Free C–C Bond Formations	65
Catalytic Chemo- and Enantioselective Transformations of gem-Diborylalkanes and (Diborylmethyl)metallic Species	64
Fluorination Promotes the Cytosolic Delivery of Genes, Proteins, and Peptides	64
Adsorption Enthalpies for Catalysis Modeling through Machine-Learned Descriptors	64
Palladium-Catalyzed Enantioselective β-C(sp3)–H Activation Reactions of Aliphatic Acids: A Retrosynthetic Surrogate for Enolate Alkylation and Conjugate Addition	64
Modulation of Metal Halide Structural Units for Light Emission	64
Visualizing the Sensitive Lithium with Atomic Precision: Cryogenic Electron Microscopy for Batteries	64
Digitizing Chemistry Using the Chemical Processing Unit: From Synthesis to Discovery	63
Functional Nucleic Acids for Pathogenic Bacteria Detection	63
Smart Nanosized Drug Delivery Systems Inducing Immunogenic Cell Death for Combination with Cancer Immunotherapy	63
Coupling without Coupling Reactions: En Route to Developing Phenols as Sustainable Coupling Partners via Dearomatization–Rearomatization Processes	63
Ionic-Liquid-Catalyzed Approaches under Metal-Free Conditions	62
The Genesis of Molecular Volcano Plots	62
Charge Transport in Organic Semiconductors: The Perspective from Nonadiabatic Molecular Dynamics	62
Cobalt Carbide Nanocatalysts for Efficient Syngas Conversion to Value-Added Chemicals with High Selectivity	61
High-Throughput Raman Flow Cytometry and Beyond	61
Automated Experimentation Powers Data Science in Chemistry	61
Nickel-Catalyzed Reductive Carboxylation and Amidation Reactions	61
Design Principles for Efficient and Stable Water Splitting Photoelectrocatalysts	61
Theories for Electrolyte Effects in CO2 Electroreduction	61
Asymmetric Synthesis of Fluoro, Fluoromethyl, Difluoromethyl, and Trifluoromethylcyclopropanes	60
Black-Box Optimization for Automated Discovery	60
Guiding CO2RR Selectivity by Compositional Tuning in the Electrochemical Double Layer	59
Nanomedicines for Renal Management: From Imaging to Treatment	59
Light-Induced Voltages in Catalysis by Plasmonic Nanostructures	59
LAURDAN since Weber: The Quest for Visualizing Membrane Heterogeneity	59
Collective Behaviors of Magnetic Active Matter: Recent Progress toward Reconfigurable, Adaptive, and Multifunctional Swarming Micro/Nanorobots	58
Alkylammonium Halides for Facet Reconstruction and Shape Modulation in Lead Halide Perovskite Nanocrystals	58
Synthesis of C2+ Chemicals from CO2 and H2 via C–C Bond Formation	58
CO2 Electrolysis System under Industrially Relevant Conditions	58
The Power of Fiber Twist	58
Importance of Engineered and Learned Molecular Representations in Predicting Organic Reactivity, Selectivity, and Chemical Properties	58
Road Map for the Construction of High-Valued N-Heterocycles via Denitrogenative Annulation	57
Symmetry-Breaking Sites for Activating Linear Carbon Dioxide Molecules	57
Learning to Approximate Density Functionals	57
DNA G-Quadruplex in Human Telomeres and Oncogene Promoters: Structures, Functions, and Small Molecule Targeting	57
Atropisomers with Axial and Point Chirality: Synthesis and Applications	57
Sulfono-γ-AApeptides as Helical Mimetics: Crystal Structures and Applications	57
Cross-Coupling Reactions of Nitroarenes	57
New Twists in Nazarov Cyclization Chemistry	57
Engineering Strategies for Lymph Node Targeted Immune Activation	57
Synergic Heterodinuclear Catalysts for the Ring-Opening Copolymerization (ROCOP) of Epoxides, Carbon Dioxide, and Anhydrides	56
Solar-Driven CO2 Reduction Using a Semiconductor/Molecule Hybrid Photosystem: From Photocatalysts to a Monolithic Artificial Leaf	56
Advances in Molecular Understanding of α-Helical Membrane-Active Peptides	56
The Dawn of Metal-Oxo Clusters as Artificial Proteases: From Discovery to the Present and Beyond	55
Fundamentals of the Intrinsic DNA Fluorescence	55
Self-Assembly and Regrowth of Metal Halide Perovskite Nanocrystals for Optoelectronic Applications	55
Combining Computational Modeling with Reaction Kinetics Experiments for Elucidating the In Situ Nature of the Active Site in Catalysis	55
Zirconium Metal–Organic Cages: Synthesis and Applications	55
A Journey in Lanthanide Coordination Chemistry: From Evaporable Dimers to Magnetic Materials and Luminescent Devices	55
Metal-Free Organic Phosphors toward Fast and Efficient Room-Temperature Phosphorescence	55
Chemoenzymatic Total Synthesis of Natural Products	54
Anion-Coordination-Driven Assembly	54
4D-STEM of Beam-Sensitive Materials	54
Rhodium-Catalyzed C–H Alkenylation/Electrocyclization Cascade Provides Dihydropyridines That Serve as Versatile Intermediates to Diverse Nitrogen Heterocycles	54
Data Science Meets Physical Organic Chemistry	54
Controlling Defect-State Photophysics in Covalently Functionalized Single-Walled Carbon Nanotubes	54
Immunogenicity of In Vitro-Transcribed RNA	54
Modeling Non-adiabatic Dynamics in Nanoscale and Condensed Matter Systems	53
Degradable Vinyl Polymers for Combating Marine Biofouling	53
Molecular Insight into Efficient Charge Generation in Low-Driving-Force Nonfullerene Organic Solar Cells	53
Fluorescent Probes for Lipid Membranes: From the Cell Surface to Organelles	53