Accounts of Chemical Research

Article	Citations
Molecular Packing: Another Key Point for the Performance of Organic and Polymeric Optoelectronic Materials	545
When Light Meets Nitrogen-Centered Radicals: From Reagents to Catalysts	338
Synergistic Modulation of Non-Precious-Metal Electrocatalysts for Advanced Water Splitting	314
Metal–Organic Framework Derived Nanozymes in Biomedicine	307
Heavy-Atom-Free Photosensitizers: From Molecular Design to Applications in the Photodynamic Therapy of Cancer	302
Fused-Ring Electron Acceptors for Photovoltaics and Beyond	264
Mechanisms of Nickel-Catalyzed Coupling Reactions and Applications in Alkene Functionalization	261
Transition Metal-Catalyzed Tandem Reactions of Ynamides for Divergent N-Heterocycle Synthesis	259
Strategy for Treatment of Infected Diabetic Foot Ulcers	246
Polyphenol-Mediated Assembly for Particle Engineering	244
Advanced Platinum-Based Oxygen Reduction Electrocatalysts for Fuel Cells	240
Chemistry of Lipid Nanoparticles for RNA Delivery	233
CuH-Catalyzed Olefin Functionalization: From Hydroamination to Carbonyl Addition	232
New Perspectives to Trigger and Modulate Circularly Polarized Luminescence of Complex and Aggregated Systems: Energy Transfer, Photon Upconversion, Charge Transfer, and Organic Radical	212
Cross-Electrophile Couplings of Activated and Sterically Hindered Halides and Alcohol Derivatives	212
Radical Carboxylative Cyclizations and Carboxylations with CO2	207
Radical-Mediated Remote Functional Group Migration	204
Expanding the Boundary of Biorefinery: Organonitrogen Chemicals from Biomass	183
Supramolecular Purely Organic Room-Temperature Phosphorescence	181
Polymer Acceptors Containing B←N Units for Organic Photovoltaics	176
Atomic Insights into the Fundamental Interactions in Lithium Battery Electrolytes	172
Narrowing the Band Gap: The Key to High-Performance Organic Photovoltaics	172
Chemically Stable Metal–Organic Frameworks: Rational Construction and Application Expansion	170
Data-Driven Strategies for Accelerated Materials Design	169
Confinement in a Zeolite and Zeolite Catalysis	161

Achieving High Performance Metal–Organic Framework Materials through Pore Engineering	160
Navigating the Unnatural Reaction Space: Directed Evolution of Heme Proteins for Selective Carbene and Nitrene Transfer	160
Organocatalytic Atroposelective Synthesis of Indole Derivatives Bearing Axial Chirality: Strategies and Applications	158
Long-Lived Organic Room-Temperature Phosphorescence from Amorphous Polymer Systems	158
Designing High Performance Organic Batteries	157
Catalytic Asymmetric Reactions with N-Metallated Azomethine Ylides	156
Iron- and Cobalt-Catalyzed Asymmetric Hydrofunctionalization of Alkenes and Alkynes	155
Mixed Electronic States in Molecular Dimers: Connecting Singlet Fission, Excimer Formation, and Symmetry-Breaking Charge Transfer	154
Selectivity in Electrochemical CO2 Reduction	154
Covalent Organic Frameworks: Pore Design and Interface Engineering	152
High-Performance Second-Harmonic-Generation (SHG) Materials: New Developments and New Strategies	151
Theory of Long-Lived Room-Temperature Phosphorescence in Organic Aggregates	149
Reticular Chemistry for Highly Porous Metal–Organic Frameworks: The Chemistry and Applications	149
Prospects of an Electroactive Carbon Nanotube Membrane toward Environmental Applications	149
Three-Dimensional Covalent Organic Frameworks: From Topology Design to Applications	149
Transition Metal (Ni, Cu, Pd)-Catalyzed Alkene Dicarbofunctionalization Reactions	148
Metalloporphyrins as Catalytic Models for Studying Hydrogen and Oxygen Evolution and Oxygen Reduction Reactions	147
Metal-Catalyzed Approaches toward the Oxindole Core	146
Synthetic and Mechanistic Implications of Chlorine Photoelimination in Nickel/Photoredox C(sp3)–H Cross-Coupling	144
Eutectic Electrolytes as a Promising Platform for Next-Generation Electrochemical Energy Storage	144
Supramolecularly Engineered J-Aggregates Based on Perylene Bisimide Dyes	141
Tailored Porous Organic Polymers for Task-Specific Water Purification	135
Applications of Deep Learning in Molecule Generation and Molecular Property Prediction	132
Nanoscale Metal–Organic Frameworks for Cancer Immunotherapy	130
Chiral Pd-Catalyzed Enantioselective Syntheses of Various N–C Axially Chiral Compounds and Their Synthetic Applications	129
Silica-Based Nanoparticles for Biomedical Applications: From Nanocarriers to Biomodulators	129
From C4 to C7: Innovative Strategies for Site-Selective Functionalization of Indole C–H Bonds	128
Engineered Nanoparticles for Cancer Vaccination and Immunotherapy	126
Mechanism-Guided Development of Transition-Metal-Catalyzed C–N Bond-Forming Reactions Using Dioxazolones as the Versatile Amidating Source	124
Exploring Anion−π Interactions and Their Applications in Supramolecular Chemistry	124
Giant Rylene Imide-Based Electron Acceptors for Organic Photovoltaics	123
Cyclodextrin Metal–Organic Frameworks and Their Applications	123
Azulene-Based π-Functional Materials: Design, Synthesis, and Applications	123
Hydrogen Generation upon Nanocatalyzed Hydrolysis of Hydrogen-Rich Boron Derivatives: Recent Developments	122
Lanthanide-Activated Nanoparticles: A Toolbox for Bioimaging, Therapeutics, and Neuromodulation	122
Small-Molecule Modulators of Toll-like Receptors	122
UV/Chlorine Process: An Efficient Advanced Oxidation Process with Multiple Radicals and Functions in Water Treatment	121
Responsive Metal Complex Probes for Time-Gated Luminescence Biosensing and Imaging	121
Innovative Approaches to Li-Argyrodite Solid Electrolytes for All-Solid-State Lithium Batteries	121
Palladium-Catalyzed Asymmetric Allylic C–H Functionalization: Mechanism, Stereo- and Regioselectivities, and Synthetic Applications	120
Zeolite Fixed Metal Nanoparticles: New Perspective in Catalysis	119
Design Strategy of Fluorescent Probes for Live Drug-Induced Acute Liver Injury Imaging	118
N-Heterocyclic Carbenes: A Door Open to Supramolecular Organometallic Chemistry	117
Asymmetric Catalytic Rearrangements with α-Diazocarbonyl Compounds	117
Electrolyte Effects on CO2 Electrochemical Reduction to CO	113
2-(Pyridin-2-yl)isopropyl (PIP) Amine: An Enabling Directing Group for Divergent and Asymmetric Functionalization of Unactivated Methylene C(sp3)–H Bonds	111
How the Ligand Field in Lanthanide Coordination Complexes Determines Magnetic Susceptibility Anisotropy, Paramagnetic NMR Shift, and Relaxation Behavior	110
Rational Design of Electrochemiluminescent Devices	109
Electrochemical Approaches for CO2 Conversion to Chemicals: A Journey toward Practical Applications	109
Metal Halide Superionic Conductors for All-Solid-State Batteries	107

Bioinspired Applications of Porphyrin Derivatives	106
Emerging Potassium Metal Anodes: Perspectives on Control of the Electrochemical Interfaces	105
Exploring the Chemistry of Spiroindolenines by Mechanistically-Driven Reaction Development: Asymmetric Pictet–Spengler-type Reactions and Beyond	105
Alkyne-Palladium(II)-Catalyzed Living Polymerization of Isocyanides: An Exploration of Diverse Structures and Functions	105
Lithium–Air Batteries: Air-Electrochemistry and Anode Stabilization	105
Heterogeneous Molecular Catalysts of Metal Phthalocyanines for Electrochemical CO2 Reduction Reactions	102
Chiral Induced Spin Selectivity Gives a New Twist on Spin-Control in Chemistry	102
Forging Odd-Membered Rings: Palladium-Catalyzed Asymmetric Cycloadditions of Trimethylenemethane	101
Charge Transport in Zirconium-Based Metal–Organic Frameworks	101
Intramolecularly Cross-Linked Polymers: From Structure to Function with Applications as Artificial Antibodies and Artificial Enzymes	100
The Concept of Chemical Generators: On-Site On-Demand Production of Hazardous Reagents in Continuous Flow	99
n-Type Organic and Polymeric Semiconductors Based on Bithiophene Imide Derivatives	99
Halide Ion Migration in Perovskite Nanocrystals and Nanostructures	98
Issues and Advances in Scaling up Sulfide-Based All-Solid-State Batteries	98
Organocatalytic Enantioselective Synthesis of Axially Chiral Molecules: Development of Strategies and Skeletons	97
2D Conjugated Covalent Organic Frameworks: Defined Synthesis and Tailor-Made Functions	97
Programmable Morphing Hydrogels for Soft Actuators and Robots: From Structure Designs to Active Functions	96
Nano–Bio Interactions in Cancer: From Therapeutics Delivery to Early Detection	95
Making ATRP More Practical: Oxygen Tolerance	94
Thermo-, Electro-, and Photocatalytic CO2 Conversion to Value-Added Products over Porous Metal/Covalent Organic Frameworks	92
Exploiting Heavier Organochalcogen Compounds in Donor–Acceptor Cyclopropane Chemistry	92
Supramolecular Chirality in Metal–Organic Complexes	92
Engineering of Norbornadiene/Quadricyclane Photoswitches for Molecular Solar Thermal Energy Storage Applications	91
Vanadium-Based Materials: Next Generation Electrodes Powering the Battery Revolution?	91
New Multiphase Chemical Processes Influencing Atmospheric Aerosols, Air Quality, and Climate in the Anthropocene	90
Promoting Rechargeable Batteries Operated at Low Temperature	90
Exploring Multifunctional Hydrogen-Bonded Organic Framework Materials	88
Fuzziness and Frustration in the Energy Landscape of Protein Folding, Function, and Assembly	88
Spray-Drying Synthesis of MOFs, COFs, and Related Composites	87
Metal Chalcogenide Supertetrahedral Clusters: Synthetic Control over Assembly, Dispersibility, and Their Functional Applications	87
Lipid Nanoparticle–mRNA Formulations for Therapeutic Applications	87
Carbon Shell on Active Nanocatalyst for Stable Electrocatalysis	87
Selenium-Containing Organic Photovoltaic Materials	87
Molecular Photoswitching in Confined Spaces	86
Copper-Catalyzed Carbonylative Coupling of Alkyl Halides	86
Tetracoordinate Boron Intermediates Enable Unconventional Transformations	86
Chemical Interface Damping of Surface Plasmon Resonances	86
Modular Organoboron Catalysts Enable Transformations with Unprecedented Reactivity	86
Reductive Cross-Coupling of Unreactive Electrophiles	86
Current Strategies for Modulating Aβ Aggregation with Multifunctional Agents	86
The Prodigious Hydrogen Bonds with Sulfur and Selenium in Molecular Assemblies, Structural Biology, and Functional Materials	85
Development and Evolution of Energetic Cocrystals	85
NMR Calculations with Quantum Methods: Development of New Tools for Structural Elucidation and Beyond	83
Mechanisms of Thermal Atomic Layer Etching	82
Engineering Catalyst–Electrolyte Microenvironments to Optimize the Activity and Selectivity for the Electrochemical Reduction of CO2 on Cu and Ag	82
Exotic Topological Bands and Quantum States in Metal–Organic and Covalent–Organic Frameworks	82
Electrochemical Conversion of CO2 to Syngas with Palladium-Based Electrocatalysts	82
Local and Targeted Delivery of Immune Checkpoint Blockade Therapeutics	82
Strategies to Combat Multi-Drug Resistance in Tuberculosis	81
Dynamic Core–Shell and Alloy Structures of Multimetallic Nanomaterials and Their Catalytic Synergies	80
Atropisomerism in the Pharmaceutically Relevant Realm	80
CO2 Reduction Using Water as an Electron Donor over Heterogeneous Photocatalysts Aiming at Artificial Photosynthesis	80
Development of Multimodal Machine Learning Potentials: Toward a Physics-Aware Artificial Intelligence	79
The Role of Carbonate in Catalytic Oxidations	78
Solvation and Mobilization of Copper Active Sites in Zeolites by Ammonia: Consequences for the Catalytic Reduction of Nitrogen Oxides	78
The RaPID Platform for the Discovery of Pseudo-Natural Macrocyclic Peptides	78
Crystal Phase Control of Gold Nanomaterials by Wet-Chemical Synthesis	77
A Strategy for Selective Catalytic B–H Functionalization of o-Carboranes	77
Fluorinated Ylides/Carbenes and Related Intermediates from Phosphonium/Sulfonium Salts	76
Photobiocatalysis for Abiological Transformations	76
Organogermanes as Orthogonal Coupling Partners in Synthesis and Catalysis	75
Time and Pot Economy in Total Synthesis	75
Stimuli-Induced Reversible Proton Transfer for Stimuli-Responsive Materials and Devices	74
Biomaterials as Local Niches for Immunomodulation	74
Effect of Surface Ligands in Perovskite Nanocrystals: Extending in and Reaching out	74
Ferritin: A Multifunctional Nanoplatform for Biological Detection, Imaging Diagnosis, and Drug Delivery	73
Opportunity of Atomically Thin Two-Dimensional Catalysts for Promoting CO2 Electroreduction	73
Predicting Reaction Yields via Supervised Learning	73
The Pauli Repulsion-Lowering Concept in Catalysis	73
Latest Advances in Flexible Symmetric Supercapacitors: From Material Engineering to Wearable Applications	72
Yne–Enones Enable Diversity-Oriented Catalytic Cascade Reactions: A Rapid Assembly of Complexity	71
The Surface Chemistry and Structure of Colloidal Lead Halide Perovskite Nanocrystals	71
Toward the Copolymerization of Propylene with Polar Comonomers	71
Large Cages of Zeolitic Imidazolate Frameworks	71
Stimuli-Responsive Crystalline Smart Materials: From Rational Design and Fabrication to Applications	71
Layered Oxide Cathodes for Sodium-Ion Batteries: Storage Mechanism, Electrochemistry, and Techno-economics	70
Recent Advances in Stimuli-Responsive Platforms for Cancer Immunotherapy	70
Aromatic π-Components for Enantioselective Heck Reactions and Heck/Anion-Capture Domino Sequences	70
Mapping Materials and Molecules	70
Neutral Nickel(II) Catalysts: From Hyperbranched Oligomers to Nanocrystal-Based Materials	69

Enantioselective Synthesis of Atropisomers via Vinylidene ortho-Quinone Methides (VQMs)	69
The Discovery of Multifunctional Chiral P Ligands for the Catalytic Construction of Quaternary Carbon/Silicon and Multiple Stereogenic Centers	69
Methane Oxidation to Methanol in Water	69
Cobalt-Catalyzed Cross-Couplings between Alkyl Halides and Grignard Reagents	69
Biphen[n]arenes: Modular Synthesis, Customizable Cavity Sizes, and Diverse Skeletons	69
Self-Assembling Supramolecular Dendrimers for Biomedical Applications: Lessons Learned from Poly(amidoamine) Dendrimers	69
Development of Triggerable, Trackable, and Targetable Carbon Monoxide Releasing Molecules	69
Large-Scale Atomic Simulation via Machine Learning Potentials Constructed by Global Potential Energy Surface Exploration	68
N-Triftosylhydrazones: A New Chapter for Diazo-Based Carbene Chemistry	68
Manipulating the Dynamics of Dark Excited States in Organic Materials for Phototheranostics	68
Intrinsically Porous Molecular Materials (IPMs) for Natural Gas and Benzene Derivatives Separations	67
Two-Dimensional Nanofluidic Membranes toward Harvesting Salinity Gradient Power	67
Double-Cable Conjugated Polymers with Pendant Rylene Diimides for Single-Component Organic Solar Cells	67
The Optoelectronic Nose	67
NiH-Catalyzed Functionalization of Remote and Proximal Olefins: New Reactions and Innovative Strategies	66
General-Purpose Machine Learning Potentials Capturing Nonlocal Charge Transfer	65
Developing Scaling Relationships for Molecular Electrocatalysis through Studies of Fe-Porphyrin-Catalyzed O2 Reduction	65
Pillararene-Inspired Macrocycles: From Extended Pillar[n]arenes to Geminiarenes	65
Molecular Triangles: A New Class of Macrocycles	65
Low Temperature Activation of Methane on Metal-Oxides and Complex Interfaces: Insights from Surface Science	65
Advanced Pt-Based Core–Shell Electrocatalysts for Fuel Cell Cathodes	65
Plasma-Enhanced Chemical Vapor Deposition of Two-Dimensional Materials for Applications	64
Achieving Efficient n-Doping of Conjugated Polymers by Molecular Dopants	64
N-Functionalized Pyridinium Salts: A New Chapter for Site-Selective Pyridine C–H Functionalization via Radical-Based Processes under Visible Light Irradiation	64
Transition Metal-Catalyzed Biaryl Atropisomer Synthesis via a Torsional Strain Promoted Ring-Opening Reaction	64
Reimagining Druggability Using Chemoproteomic Platforms	64
Bifunctional Iminophosphorane Superbase Catalysis: Applications in Organic Synthesis	64
Carbon Nanotube Photoluminescence Modulation by Local Chemical and Supramolecular Chemical Functionalization	63
Tumor-Targeted Nanomedicine for Immunotherapy	63
Excitons and Polarons in Organic Materials	63
Energy-Transfer-Enabled Dearomative Cycloaddition Reactions of Indoles/Pyrroles via Excited-State Aromatics	63
Smart Nanosized Drug Delivery Systems Inducing Immunogenic Cell Death for Combination with Cancer Immunotherapy	63
Functional Regulation and Stability Engineering of Three-Dimensional Covalent Organic Frameworks	63
Photocatalytic Systems for CO2 Reduction: Metal-Complex Photocatalysts and Their Hybrids with Photofunctional Solid Materials	62
The Importance of Highly Connected Building Units in Reticular Chemistry: Thoughtful Design of Metal–Organic Frameworks	62
Carboxylic Acids as Adaptive Functional Groups in Metallaphotoredox Catalysis	62
Non-liver mRNA Delivery	62
Recent Advances in Theoretical Studies on Transition-Metal-Catalyzed Carbene Transformations	62
Mimicking Color-Changing Organisms to Enable the Multicolors and Multifunctions of Smart Fluorescent Polymeric Hydrogels	62
Developing Biodegradable Lipid Nanoparticles for Intracellular mRNA Delivery and Genome Editing	61
Modulation of Metal Halide Structural Units for Light Emission	61
Density Functional Theory Based Methods for the Calculation of X-ray Spectroscopy	60
Polymerized Molecular Receptors as Adsorbents to Remove Micropollutants from Water	60
Enzyme-Laden Bioactive Hydrogel for Biocatalytic Monitoring and Regulation	60
A Type of Structurally Adaptable Aromatic Spiroketal Based Chiral Diphosphine Ligands in Asymmetric Catalysis	60
Corannulene: A Curved Polyarene Building Block for the Construction of Functional Materials	60
Catalytic Chemo- and Enantioselective Transformations of gem-Diborylalkanes and (Diborylmethyl)metallic Species	60
Digitizing Chemistry Using the Chemical Processing Unit: From Synthesis to Discovery	60
Large π-Extended and Curved Carbon Nanorings as Carbon Nanotube Segments	59
Inorganometallic Photocatalyst for CO2 Reduction	59
Oriented Attachment: From Natural Crystal Growth to a Materials Engineering Tool	59
Emerging Electrochemical Techniques for Probing Site Behavior in Single-Atom Electrocatalysts	59
Visualizing the Sensitive Lithium with Atomic Precision: Cryogenic Electron Microscopy for Batteries	59
Hierarchically Porous MOFs Synthesized by Soft-Template Strategies	59
Strategies for the Photocatalytic Generation of Carbanion Equivalents for Reductant-Free C–C Bond Formations	59
Palladium-Catalyzed Enantioselective β-C(sp3)–H Activation Reactions of Aliphatic Acids: A Retrosynthetic Surrogate for Enolate Alkylation and Conjugate Addition	59
Ionic-Liquid-Catalyzed Approaches under Metal-Free Conditions	58
Black-Box Optimization for Automated Discovery	57
Liquid–Liquid Phase Separation in Supermicrometer and Submicrometer Aerosol Particles	57
Excited-State Engineering in Heteroleptic Ionic Iridium(III) Complexes	57
Advances in Rhodium-Catalyzed Oxidative Arene Alkenylation	57
Light-Induced Voltages in Catalysis by Plasmonic Nanostructures	56
Charge Transport in Organic Semiconductors: The Perspective from Nonadiabatic Molecular Dynamics	56
Cobalt Carbide Nanocatalysts for Efficient Syngas Conversion to Value-Added Chemicals with High Selectivity	56
Autonomous Chemical Experiments: Challenges and Perspectives on Establishing a Self-Driving Lab	55
Theories for Electrolyte Effects in CO2 Electroreduction	55
Bioinspired Superspreading Surface: From Essential Mechanism to Application	55
Nanomedicines for Renal Management: From Imaging to Treatment	55
High-Throughput Raman Flow Cytometry and Beyond	55
The Genesis of Molecular Volcano Plots	54
Functional Nucleic Acids for Pathogenic Bacteria Detection	54
Fluorination Promotes the Cytosolic Delivery of Genes, Proteins, and Peptides	54
New Twists in Nazarov Cyclization Chemistry	54
Adsorption Enthalpies for Catalysis Modeling through Machine-Learned Descriptors	54
Guiding CO2RR Selectivity by Compositional Tuning in the Electrochemical Double Layer	54
Automated Experimentation Powers Data Science in Chemistry	54
Alkylammonium Halides for Facet Reconstruction and Shape Modulation in Lead Halide Perovskite Nanocrystals	54
Coupling without Coupling Reactions: En Route to Developing Phenols as Sustainable Coupling Partners via Dearomatization–Rearomatization Processes	54
A Journey in Lanthanide Coordination Chemistry: From Evaporable Dimers to Magnetic Materials and Luminescent Devices	53
Ultralong Organic Phosphorescence: From Material Design to Applications	53
Sulfono-γ-AApeptides as Helical Mimetics: Crystal Structures and Applications	53
Collective Behaviors of Magnetic Active Matter: Recent Progress toward Reconfigurable, Adaptive, and Multifunctional Swarming Micro/Nanorobots	53
Symmetry-Breaking Sites for Activating Linear Carbon Dioxide Molecules	53
Combining Computational Modeling with Reaction Kinetics Experiments for Elucidating the In Situ Nature of the Active Site in Catalysis	53
The Power of Fiber Twist	52
Asymmetric Synthesis of Fluoro, Fluoromethyl, Difluoromethyl, and Trifluoromethylcyclopropanes	52
Design Principles for Efficient and Stable Water Splitting Photoelectrocatalysts	52
The Dawn of Metal-Oxo Clusters as Artificial Proteases: From Discovery to the Present and Beyond	51
Engineering Strategies for Lymph Node Targeted Immune Activation	51
Controlling Defect-State Photophysics in Covalently Functionalized Single-Walled Carbon Nanotubes	51
Rhodium-Catalyzed C–H Alkenylation/Electrocyclization Cascade Provides Dihydropyridines That Serve as Versatile Intermediates to Diverse Nitrogen Heterocycles	51
Nickel-Catalyzed Reductive Carboxylation and Amidation Reactions	51
Self-Assembly and Regrowth of Metal Halide Perovskite Nanocrystals for Optoelectronic Applications	51
Engineering the Bio–Nano Interface Using a Multifunctional Coordinating Polymer Coating	51
Electron-rich Coordination Receptors Based on Tetrathiafulvalene Derivatives: Controlling the Host–Guest Binding	50